This application claims priority to PCT Application No. PCT/EP2013/061385 having a filing date of Jun. 3, 2013, based off of EP12173203.6 having a filing date of Jun. 22, 2012, the entire contents of which are hereby incorporated by reference.
The following relates to a method of and a coating tank for applying a coating of a specific, selected kind to a glass sleeve with an inner surface and an outer surface, the glass sleeve is configured as a part of a solar-receiver tube. Embodiments of the invention also relates to a method of and a fixing arrangement for fixing a glass sleeve configured as a part of a solar-receiver tube in an interior of a coating tank. Further, it concerns a glass sleeve with an inner surface and an outer surface, which glass sleeve is configured as a part of a solar-receiver tube.
Solar-receiver tubes are used in solar power plants, for example, parabolic-trough power plants, which convert solar energy into electric energy. In this type of a solar power plant, a parabolically curved reflector reflects the sunlight onto a solar-receiver tube positioned at its focal point. The main operational parts of a solar-receiver tube comprise a glass sleeve surrounding a metal absorber tube, by means of which solar energy is converted to thermal energy. The thermal energy is absorbed and stored by a fluid used as a heat transfer medium, which circulates in a closed pipeline system. By a heat exchanger the thermal energy is transferred from the fluid to water, which is then used to run a steam turbine producing electric energy.
The conversion process of solar energy to thermal energy by means of a solar-receiver tube is accompanied by a transmission loss concerning several elements of a glass sleeve which is a part of the solar-receiver tube.
Firstly, a part of the immitted light is reflected and absorbed by the wall of the glass sleeve. Therefore, at both surfaces of the glass sleeve, and anti-reflective coating is applied.
Secondly, a transmission loss is caused by a scratch-resistant coating, which is applied to protect the anti-reflective coatings at both surfaces. The increased durability of the anti-reflective coating is therefore accompanied by a decreased efficiency of the solar-receiver tube.
During the process of applying a coating to a glass sleeve in a coating tank forces take effect on the fragile glass sleeve, which can lead to its damage and breakage. Especially in areas, where interfaces designed to hold the glass sleeve in a predefined position are in close contact to the wall of the glass sleeve there is a risk of damage. In particular, this is the case during coating processes using dipping techniques when buoyancy forces the glass sleeve upwards and presses it against the contact interface.
An aspect relates to improving the efficiency of a solar-receiver tube. In particular, this improvement preferably relates to a reduction of the transmission loss of solar energy of a glass sleeve without diminishing its durability.
A further aspect relates to providing a better protection of glass sleeves against damage during the coating process and thus to reduce waste in the production process.
Accordingly, the above-mentioned method of applying a coating is characterized by the fact that the coating is solely applied to one of the inner and outer surfaces of the glass sleeve.
Each type of coating displays specific qualities. In order to acquire positive effects, the selection of a coating of one specific kind is made in accordance with its specific functions with respect to the component to be coated. With reference to glass sleeves surrounding absorber tubes, the method of applying a coating solely to one of the inner and outer surfaces of a glass sleeve provides for savings of material and for a more precise application of the coating. As the application of coatings to surfaces can have both advantageous and disadvantageous effects, the method just described results in a reduction of such disadvantageous effects. These are caused when one of the two surfaces is coated which does not profit (to a desired extent) from the possibly advantageous effects of a coating of a specific kind because the two surfaces fulfill different functions. Then consequently the whole device suffers from the disadvantageous effects of the coating applied to that side.
Throughout the description, the term “coating” therefore refers to one particular coating of a selected, i.e. designated, i.e. specific kind with a particular formulation and/or with one particular purpose or function with respect to the glass sleeve. That means that a glass sleeve can be coated with more than just one coating each of such selected kind, some coating of which can be applied to both surfaces of the glass sleeve. The coating in question will then be that coating that is solely applied to one surface.
In order to relate these general observations to the embodiments of the invention, the specific functions of the surfaces of a glass sleeve as part of a solar-receiver tube shall now be described.
The outer surface of the glass sleeve serves as protection and shield of the absorber tube against mechanical stress, whereas the inner surface provides for maintaining a vacuum in the space between the absorber tube and the glass sleeve and thus reduces the absorption of heat. The wall of the glass sleeve fulfills the functions of a transmission medium for electromagnetic radiation and of a thermal insulator and moreover represents a carrier for applying coatings in order to improve the qualities of its two surfaces.
The expression “solar-receiver tube” is used for a completely assembled solar-receiver tube, but also for a solar-receiver tube which is not yet completely assembled. Such is the case during the construction of solar-receiver tubes, whereby a solar-receiver tube comprises at least a glass sleeve and an absorber tube and parts or components of an interface between an absorber tube and a glass sleeve.
Generally, the method according to embodiments of the invention can be carried out manually, for instance by hermetically sealing an end section of the glass sleeve my means of a seal, possibly supported by a holding structure which holds the bellow. However, it is preferred to carry out the method automatically. Thus, embodiments of the invention also concern a coating tank of the above-mentioned kind, in particular for implementing the method, whereby the coating tank is configured to apply the coating solely to one of the inner and outer surfaces of the glass sleeve.
Thus, embodiments of the invention also concern the product of the coating tank put into operation, a glass sleeve of the above-mentioned kind, whereby the coating is solely applied to one of the inner and outer surfaces of the glass sleeve.
Further, embodiments of the invention relates to a method of fixing a glass sleeve configured as a part of a solar-receiver tube in an interior of a coating tank by means of a fixing arrangement, which fixing arrangement comprises an interface configured to connect to at least one contact interface of the glass sleeve when the glass sleeve is positioned in a designated operating position within the coating tank, whereby the interface comprises an elastic element in a bottom region of the coating tank, which in operation holds the glass sleeve elastically in its operating position.
The glass sleeve displays an increased fragility because of its thin walls. During the processes of introducing the glass sleeve into the coating tank and of applying a coating to the glass sleeve forces affect its surfaces, which can lead to its damage and even breakage. Firstly, placing the end section of the glass sleeve on the bottom of the tank creates a certain shock to its entire structure. Secondly, when using a dipping method for applying a coating, due to the differences in density of a liquid coating and a glass sleeve, a buoyancy is generated which mainly affects end section, in particular the bellows, of the glass sleeve and lifts it upwards.
In order to avoid tension and thus possible damages to the glass sleeve during the coating process, for instance an inflatable seal can serve as an elastic element and thus an elastic interface in the bottom region of the coating tank. Such inflatable seal shaped as an annular tube, for instance displays a diameter similar to the diameter of the annular end section of the glass sleeve. It rests in a bottom region of the coating tank while the end section of the glass sleeve rests on the inflatable seal. Such inflatable seal displays its quality of pretension even before being inflated. According to a particularly advantageous embodiment of the invention related to the described fixing arrangement, the buoyancy affecting the glass sleeve during the coating process in a coating tank is reduced to zero. This effect is reached by both the design of the end section, in particular a bellow, located at the bottom of the coating tank and the position of the elastic element at the end section of the glass sleeve.
Due to the fact, that the pressure of the coating liquid is affecting the whole surface of the glass sleeve to an equal degree in an equal depth, the special design of the end section, in particular a bellow, implies that the surface of the end section affected by buoyancy is equal to the surface of the end section affected by downforce pressure. The addition of both forces results in their neutralization. This method provides for a lower risk of damage or breakage of the glass sleeve and for a higher efficiency of the coating process as a whole.
Embodiments of the invention also concerns a fixing arrangement for implementing such method. Such fixing arrangement for fixing a glass sleeve as part of a solar-receiver tube in an interior of a coating tank, in particular a coating tank, comprises an interface configured to connect to at least one contact interface of the glass sleeve when the glass sleeve is positioned in a designated operating position within the coating tank, whereby the interface comprises an elastic element which holds the glass sleeve elastically in its operating position. Preferably such fixing arrangement is comprised by a coating tank.
The method of applying a coating to a glass sleeve realized as a solar-receiver tube advantageously comprises the steps of
This method proves advantageous because it demands few structural requirements compared to a solution which relies on dipping the glass sleeves into the coating tanks from above. Thus, the tilt mechanism of the coating device requires less interior height of production halls. Further, it makes cranes unnecessary, which introduce the glass sleeves into the coating tanks from a position above the tanks.
Particularly advantageous embodiments and features of the invention are given by the dependent claims, as revealed in the following description. Thereby, features revealed in the context of one of the methods may also be realized in the context of the respective other method and/or in the context of any one of the embodiments of the glass sleeve and/or coating tank and/or coating device and/or fixing arrangement unless the contrary is explicitly stated.
It is principally possible to apply the coating in form of a powder coating. It is however preferred to use a fluid coating because this can be considered an easy and well-proven application method.
Accordingly, instead of applying a coating by using a dipping process, one could rely on the alternative application method of spraying, for example by sputtering. The dipping method is however preferred as it is easy to handle and requires a comparatively low constructive effort. Thereby “dipping” also refers to a process in which the glass sleeve is not introduced into a dipping liquid but rather in which the dipping liquid is introduced into a coating tank in which the glass sleeve is already present.
Accordingly, in a preferred embodiment of the invention, the coating tank is flooded with a liquid coating after fastening the glass sleeve in a predefined operating position within the coating tank. This method is particularly advantageous because flow forces and buoyancy occur when introducing the coating, which could make the glass sleeve move uncontrolledly within the coating tank. In order to prevent possible damages due to contacts with the glass sleeve and the wall of the coating tank, the risk of movements can be diminished by fastening the sleeve before introducing the liquid coating.
Furthermore, it is preferred to permanently connect the coating to an anti-reflective layer applied on a surface of the glass sleeve. Such anti-reflective layer can also be realized as a functional coating. Depending on the specific qualities of the selected kind of coating, this method can provide for a protection of the anti-reflective coating and thus for an increased durability of the coated glass sleeve and less maintenance effort.
In particular, reference is made to a scratch-resistant coating: scratch-resistant coatings protect surfaces against mechanical stress and thus enhance their long-term durability and reduce the effort of maintenance. Glass sleeves as used in solar-receiver tubes are designed for a transmission of light, i.e. solar energy, through their translucent walls to the highest possible degree. As the outer surfaces of glass sleeves largely embody the outer surfaces of solar-receiver tubes, they are exposed to mechanical stress. As solar power plants are often located in desert areas, the anti-reflective coating applied to glass sleeves is damaged by friction caused by the grain of sand. However, the application of a scratch-resistant coating to a glass sleeve also causes an energy loss when electromagnetic radiation permeates through the wall of the glass sleeve because a scratch-resistant coating is not entirely transparent and thus a part of electromagnetic radiation is absorbed or reflected. This is contrary to the objective of the use of glass sleeves. Thus, applying a scratch-resistant coating solely to the outer surfaces of the glass sleeve leads to a substantial reduction of the transmission loss of solar energy, namely by half compared to the application of a scratch-resistant coating to both the inner and the outer surfaces of the glass sleeve. This leads to an increase of transmission through the glass sleeve of about 0.27%, which is a value well above the tolerance level.
The glass sleeve as part of a solar-receiver tube becomes more durable against mechanical stress through a scratch-resistant coating applied to the outer surface of the glass sleeve. On the other hand, the inner surface of the glass sleeve is not exposed to mechanical stress as an air-tight and water-tight sealing keeps a vacuum in the space between the wall of the absorber tube and the wall of the glass sleeve and prevents particles from entering into this space. Thus, a scratch-resistant coating on the inner surface is not necessary. As a consequence, the glass sleeve coated only on the outer surface by a scratch-resistant coating shows the same degree of resistance as one according to the state-of-the-art and at the same time an increased energy efficiency. An alternative solution, which could comprise the application of a scratch-resistant coating solely to the inner surface of the glass sleeve, would neither increase the durability of the anti-reflective coating applied to the glass sleeve nor increase efficiency.
The coating tank preferably comprises at least one seal realized and positioned to interface with an opening of the glass sleeve when the latter is positioned in a designated operating position within the coating tank. By such sealing mechanism the coating can be prevented from entering the interior (or in other cases: the exterior) of the glass sleeve. Thus, an application of a scratch-resistant coating solely to the outer surface of the sleeve can be realized.
As mentioned above, the at least one seal preferably comprises an inflatable seal. When inflated, the diameter of the seal extends and exerts a pressure on elements of the interface designed to hold the glass sleeve in its designated operating position. If this pressure and the corresponding counterpressure exerted by the said interface is higher than the pressure exerted by the surrounding liquid coating on the area covered by the inflated seal, a sealing mechanism is provided that prevents the liquid coating from entering the interior of the glass sleeve. A sealing through an inflatable seal requires a comparatively low constructive effort and provides for an easy handling.
Furthermore, the coating tank can comprise a shear pin which fixes an end section of the glass sleeve in a predefined position. Part of the fixing arrangement, the shear pin can be assembled in a position essentially rectangular to the wall of the glass sleeve when the sleeve is in an operating position. When buoyancy exerts a longitudinal loading on the glass sleeve this pressure is transferred to the shear pin by the end section of the sleeve from an essentially rectangular direction. The shear pin is preferably designed to break through already at a load which does not lead to a breakage of the glass sleeve. By protecting the sleeve, the shear pin shows a clear advantage over a fixed pin, which could alternatively be used as a fixing device.
In addition to the mentioned shear pin, which fixes the bottom end section of the glass sleeve in a predefined position within the coating tank, the above-mentioned inflatable seal can act as a further part of the fixing arrangement. When inflated, the inflatable seal exerts pressure both on the bottom cover of the coating tank and on an end section of the glass sleeve lying on it. As the bottom cover of the coating tank is rigid, the pressure exerted by the inflated seal lifts the glass sleeve if the latter is lighter than the pressure generated by inflating the seal. If this is the case, the bottom end section of the glass sleeve transfers the pressure to the shear pin, which exerts a counterpressure until it shears. This construction both acts as an arrangement for fixing the glass sleeve within the tank and provides a sealing mechanism by preventing the entering of the liquid coating into the interior of the glass sleeve. The shear pin prevents the glass sleeve from being damaged by shearing in the case of mechanical overload.
Further, the above-mentioned coating tank comprises at least the following elements:
Such adaptive fixing arrangement may comprise a movable interface which can be adjusted to different lengths of glass sleeves. In combination with these devices, the coating tank enables an easy and secure procedure of applying the coating to glass sleeves of different sizes and/or shapes while demanding a comparatively low constructive effort.
Some of the embodiments will be described in detail, with reference to the following figures, wherein like designations denote like members, wherein:
Although the present invention has been disclosed in the form of preferred embodiments and variations thereon, it will be understood that numerous additional modifications and variations could be made thereto without departing from the scope of the invention.
For the sake of clarity, it is to be understood that the use of “a” or “an” throughout this application does not exclude a plurality, and “comprising” does not exclude other steps or elements.
Number | Date | Country | Kind |
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12173203 | Jun 2012 | EP | regional |
Filing Document | Filing Date | Country | Kind |
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PCT/EP2013/061385 | 6/3/2013 | WO | 00 |
Publishing Document | Publishing Date | Country | Kind |
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WO2013/189727 | 12/27/2013 | WO | A |
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20030113448 | Tratzky | Jun 2003 | A1 |
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20070221313 | Franck | Sep 2007 | A1 |
20100330276 | Wang | Dec 2010 | A1 |
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20150136118 A1 | May 2015 | US |