Coaxial laser assisted cold spray nozzle

Information

  • Patent Grant
  • 9481933
  • Patent Number
    9,481,933
  • Date Filed
    Friday, December 3, 2010
    14 years ago
  • Date Issued
    Tuesday, November 1, 2016
    8 years ago
Abstract
A cold spray nozzle assembly for applying a coating of particles to a substrate includes a nozzle defining an inner passage with a nozzle exit. The nozzle assembly also includes a particle supply member in communication with the inner passage. The particle supply member supplies the particles to flow and accelerate through the inner passage and out of the nozzle via the nozzle exit toward the substrate to be coated thereon. Furthermore, the nozzle assembly includes a laser that emits a laser beam that is transmitted through the inner passage. The laser heats at least one of the particles and the substrate to promote coating of the substrate with the particles.
Description
FIELD

The present disclosure relates to thermal spray coating and, more particularly, to a coaxial laser assisted cold spray nozzle.


BACKGROUND

This section provides background information related to the present disclosure which is not necessarily prior art.


Thermal spraying is a technique used for coating a substrate, for instance, to protect the substrate against corrosion. Cold spraying is a type of thermal spraying in which a stream of solid particles is accelerated to high speeds by a carrier gas through a nozzle toward the substrate. The particles have enough kinetic energy upon impact with the substrate to deform plastically and bond metallurgically/mechanically to the substrate to form a coating.


The particles are accelerated to a critical velocity such that the coating can be created. This critical velocity can depend on the properties of the particles and the substrate (i.e., deformability, shape, size, temperature, etc.).


The particles can also be heated by the carrier gas in order to make the particles more plastic to deform upon impact. The amount of heat supplied from the gas can depend on the properties of the particles and the substrate.


Excessively hard substrates (e.g., tool steel) can be difficult to coat by cold spraying. This is because the substrate may not deform enough to allow the particles to bond and form the coating. The impact of the particles can also cause cracking of the substrate.


In addition, excessively soft substrates (e.g., polymers) can also be difficult to coat using cold spraying techniques. For instance, these substrates may be damaged by impact of the particles and/or the high temperatures of the gas used to accelerate the particles.


Furthermore, some particles may not be suitable for cold spraying. For instance, excessively hard particles (e.g., ceramics) may not deform sufficiently upon impact with the substrate to bond and coat the substrate.


SUMMARY

This section provides a general summary of the disclosure, and is not a comprehensive disclosure of its full scope or all of its features.


A cold spray nozzle assembly for applying a coating of particles to a substrate is disclosed. The nozzle assembly includes a nozzle defining an inner passage with a nozzle exit. The nozzle assembly also includes a particle supply member in communication with the inner passage. The particle supply member supplies the particles to flow and accelerate through the inner passage and out of the nozzle via the nozzle exit toward the substrate to be coated thereon. Furthermore, the nozzle assembly includes a laser that emits a laser beam that is transmitted through the inner passage. The laser heats at least one of the particles and the substrate to promote coating of the substrate with the particles.


Additionally, a method of applying a coating of particles to a substrate is disclosed. The method includes supplying the particles to flow and accelerate through an inner passage of a nozzle and out of the nozzle via a nozzle exit toward the substrate. The method further includes transmitting a laser beam through the inner passage to heat at least one of the particles and the substrate to promote coating of the substrate with the particles.


A cold spray nozzle assembly for applying a coating of particles to a substrate is also disclosed. The nozzle assembly includes a nozzle defining an inner passage with a nozzle entrance, a nozzle exit, and a substantially straight longitudinal axis that extends through both the nozzle entrance and the nozzle exit. The inner passage is rectangular in a cross section taken perpendicular to the longitudinal axis, and the cross section remains rectangular along the entire nozzle from the nozzle entrance to the nozzle exit. The inner passage also includes a convergent section adjacent the nozzle entrance and a divergent section adjacent the nozzle exit. The nozzle also includes a particle supply inlet that is in communication with the divergent section and that extends transverse to the longitudinal axis of the inner passage. The nozzle assembly also includes a particle supply member in communication with the particle supply inlet. The particle supply member supplies the particles to flow and accelerate through the inner passage and out of the nozzle via the nozzle exit toward the substrate to be coated thereon. Moreover, the nozzle assembly includes a gas supply member that supplies a gas to the inner passage to flow through the inner passage of the nozzle to accelerate the particles. Additionally, the nozzle assembly includes a laser that emits a laser beam that is transmitted into the nozzle via the nozzle entrance, through the inner passage, and out of the nozzle via the nozzle exit. The laser heats both the particles and the substrate to promote coating of the substrate with the particles. Furthermore, the nozzle assembly includes a handling device that moves at least one of the nozzle and the substrate relative to the other.


Further areas of applicability will become apparent from the description provided herein. The description and specific examples in this summary are intended for purposes of illustration only and are not intended to limit the scope of the present disclosure.





DRAWINGS

The drawings described herein are for illustrative purposes only of selected embodiments and not all possible implementations, and are not intended to limit the scope of the present disclosure.



FIG. 1 is a perspective view of a cold spray nozzle assembly according to various exemplary embodiments of the present disclosure;



FIG. 2 is a longitudinal section view of the cold spray nozzle assembly of FIG. 1;



FIG. 3 is a longitudinal section view of the cold spray nozzle assembly of FIG. 1, shown during operation of a laser thereof;



FIG. 4 is a longitudinal section view of a nozzle of the cold spray nozzle assembly of FIG. 1;



FIG. 5 is a photograph of a planar substrate that has been coated using the cold spray nozzle assembly of FIG. 1; and



FIG. 6 is a photograph of a tubular substrate that has been coated using the cold spray nozzle assembly of FIG. 1.





Corresponding reference numerals indicate corresponding parts throughout the several views of the drawings.


DETAILED DESCRIPTION

Example embodiments will now be described more fully with reference to the accompanying drawings.


Referring initially to FIGS. 1-4, a cold spray nozzle assembly 10 is illustrated according to various exemplary embodiments of the present disclosure. The cold spray nozzle assembly 10 can be used for applying a coating 11 of particles 12 to a substrate 14 (FIGS. 1, 5, and 6) as will be described in greater detail below.


The assembly 10 can include a nozzle 16 having a substantially straight longitudinal axis X. As shown in FIGS. 2-4, the nozzle 16 can define an inner passage 18 that extends parallel to the axis X. The inner passage 18 can also include a nozzle entrance 20 and a nozzle exit 22 at opposite ends thereof (FIGS. 2-4). As best shown in FIG. 4, the inner passage 18 can include a convergent section 24 adjacent the nozzle entrance 20 and a divergent section 26 adjacent the nozzle exit 22. More specifically, both the convergent and divergent sections 24, 26 can be tapered. The convergent section 24 narrows moving away from the entrance 20, and the divergent section 26 widens moving toward the exit 22. The convergent section 24 is connected to the divergent section 26 to define a shoulder 27 (FIG. 4). As will be discussed, the particles 12 flow through the inner passage 18, and the convergent and divergent sections 24, 26 ensure an appropriate flow field in the passage 18 such that the particles 12 move at a sufficient velocity to coat the substrate 14.


As shown in FIG. 1, the exit 22 can be substantially rectangular in shape. More specifically, the inner passage 18 can have a substantially rectangular cross section taken perpendicular to the axis X adjacent the exit 22. The entire inner passage 18 can have a similar substantially rectangular cross section along the entire axis X of the passage 18; however, it will be apparent that the area of such a cross section will change along the axis X due to the tapering of the convergent and divergent sections 24, 26. It will also be appreciated that the inner passage 18 and the exit 22 can alternatively have any suitable (non-rectangular) shape.


Furthermore, as shown in FIG. 4, the nozzle 16 can include one or more particle supply inlets 28a, 28b. The nozzle 16 can include any number of inlets 28a, 28b, and the inlets 28a, 28b can be disposed in any suitable location. In the embodiment shown, there are two inlets 28a, 28b disposed symmetrically on opposite sides of the axis X. The particle supply inlets 28a, 28b can each extend transverse to the axis X. For instance, the particle supply inlets 28a, 28b can each be disposed at a positive acute angle relative to the axis X and generally toward the exit 22.


As shown in FIG. 1, the assembly 10 can include a particle supply member, shown schematically at 30. The particle supply member 30 can be in (fluid) communication with the inner passage 18 of the nozzle 16 via the inlets 28a, 28b. For instance, the particle supply member 30 can include one or more tubes 29a, 29b (FIGS. 1-3) that are received in and operably coupled to the inlets 28a, 28b, respectively. Thus, as will be discussed, the particles 12 can be supplied from the tubes 29a, 29b of the supply member 30 to flow through the inlets 28a, 28b, through the inner passage 18, and out of the nozzle exit 22 toward the substrate 14 to coat the substrate 14 with the particles 12.


It will be appreciated that the particles 12 can be of any suitable type. For instance, the particles 12 can be metallic, polymeric, and/or ceramic powderized particles 12. Also, the particles 12 can be a composite mixture of metallic, polymeric, and/or ceramic particles 12.


Referring to FIGS. 1-3, the assembly 10 can further include a pressure tube 32. The pressure tube 32 can include a first branch 34, a second branch 36, and a third branch 38, each of which are hollow and that are in fluid communication with each other. The first, second, and third branches 34, 36, 38 can also be in fluid communication with the nozzle entrance 20. The first branch 34 can be directly fixed to the nozzle 16 so as to be coaxial with the axis X. The second branch 36 and the third branch 36, 38 can be disposed at an acute angle relative to the axis X and can be directed generally toward the nozzle entrance 20. The third branch 38 can be disposed between the second branch 36 and the nozzle entrance 20.


Moreover, as shown in FIG. 1, the assembly 10 can include a gas supply member 31. The gas supply member 31 can be in fluid communication with the second branch 36 of the pressure tube 32. The gas supply member 31 can supply any suitable gas to pressurize the inner passage 18 of the nozzle 16.


Moreover, the assembly 10 can include a laser 40. The laser 40 can be of any suitable type, such as a diode laser of a known type. The laser 40 can include a fiber-optic cable 42 and at least one or more (e.g., three) lenses 44a, 44b, 44c (FIG. 2). The laser 40 can be operably coupled to the first branch 34 of the pressure tube 32 so as to be substantially coaxial with the axis X. As will be discussed, the laser 40 can emit a laser beam 46 (FIGS. 1 and 3) that is transmitted through the entrance 20 of the inner passage 18 of the nozzle 16 and out of the nozzle 16 via the exit 22 toward the substrate 14. The laser beam 46 can be directed substantially parallel to and coaxial to the axis X toward the substrate 14, although some degree of spread of the beam 46 away from the axis X can occur.


As shown in FIG. 1, the assembly 10 can further include a platform 49 on which the pressure tube 32 and the laser 40 are mounted. The assembly 10 can also include a handling device 50 that moves the platform 49 and/or the substrate 14 relative to each other. In the embodiment shown, the handling device 50 is operably coupled to the platform 49 such that the platform 49 can move while the substrate 14 remains stationary; however, it will be appreciated that the handling device 50 could move the substrate 14 while the platform 49 remains stationary, or the handling device 50 could be configured to move both the platform 49 and the substrate 14 relative to each other. The handling device 50 can be of any suitable type, such as a robotic handling device 50. When the handling device 50 moves the platform 49, the laser 40, the pressure tube 32, and the nozzle 16 are moved as a unit relative to the substrate 14.


Additionally, the assembly 10 can include a controller 52. The controller 52 can be of any suitable type, such as a programmable computer. The controller 52 can be in communication with the laser 40, the handling device 50, the gas supply member 31, and the particle supply member 30 for operating each. The controller 52 can also be in communication with the third branch 38 for receiving feedback regarding the pressure inside the pressure tube 32 and the nozzle 16. For instance, a pressure sensor (not shown) can be operably coupled to the third branch 38 to detect pressure inside the pressure tube 32 and nozzle 16, and the pressure sensor can also provide correlative electronic feedback signals to the controller 52 for controlling the assembly 10.


During operation, the controller 52 can move the assembly 10 into a desired position relative to the substrate 14 using the handling device 50. When in proper position, the controller 52 can operate the laser 40 to emit the laser beam 46 through the pressure tube 32, through the nozzle 16, and toward the substrate 14. The energy of the laser beam 46 can heat the substrate 14 to make the substrate 14 more amenable to plastic deformation and to prepare the substrate 14 for coating. It will be appreciated that this “pre-treating” of the substrate 14 can be skipped in some embodiments, depending on the type of material of the substrate 14.


Also, in some embodiments, the controller 52 can cause the gas supply member 31 to supply gas into the inner passage 18 and to the substrate 14 before and during operation of the laser 40. As such, the gas can reduce the likelihood of oxidation of the substrate 14.


After the laser 40 has begun operating, the controller 52 can cause the particle supply member 30 to supply the particles 12. The particles 12 can be accelerated by the gas up to or beyond a critical velocity within the inner passage 18 and directed toward the substrate 14. The energy of the laser beam 46 can heat the particles 12 during flight toward the substrate 14. Because the particles 12 are heated, the particles 12 can plastically deform more readily when the particles 12 impact the substrate 14.


Furthermore, the energy of the laser beam 46 can continue to heat the substrate 14 as the particles 12 are ejected toward the substrate 14. Thus, the substrate 14 can plastically deform more readily.


The handling device 50 can continuously move the assembly 10 to evenly coat the substrate 14 with the particles 12 on predetermined areas. An example of the coating 11 on a planar substrate 14 is shown in FIG. 5, and an example of the coating 11 on a tubular substrate 14 is shown in FIG. 6.


Accordingly, the assembly 10 can be used to coat a substrate 14 with particles 12. A wider variety of substrates 14 can be used (e.g., harder or softer substrates 14) as compared with substrates typically used in cold spray coating processes. Specifically, the particles 12 can be supplied at relatively low pressures because heating of the particles 12 is caused by the laser 40 instead of just the high pressure gas as in prior art systems. Likewise, the critical velocity of the particles 12 can be reduced for the same reasons. For these reasons, the impact of the particles 12 is less likely to damage the substrate 14. Accordingly, the substrate 14 can be softer or harder than substrates typically coated by cold spray coating processes.


Also, a wider variety of particles 12 can be used (e.g., harder or softer composite particles 12) as compared with particles typically used in cold spray coating processes. This is because the laser 40 heats the particles 12 prior to impact with the substrate 14 and allows the particles 12 to more readily plastically deform.


In addition, the substrate 14 does not necessarily need to be protected from oxidation (e.g., in a protected environmental chamber). This is because the area of the substrate 14 affected by the laser beam 46 remains within the stream of gas supplied by the gas supply member 31.


Additionally, because of the rectangular cross section of the inner passage 18 and because of the rectangular shape of the nozzle exit 22, the particles 12 can be deposited at a fairly even thickness on the substrate 14 (see FIGS. 5 and 6) as compared with prior art systems. Accordingly, the finished part can be more aesthetically pleasing, can fit better to other parts, and can have better corrosion resistance due to in-situ annealing.


The foregoing description of the embodiments has been provided for purposes of illustration and description. It is not intended to be exhaustive or to limit the present disclosure. Individual elements or features of a particular embodiment are generally not limited to that particular embodiment, but, where applicable, are interchangeable and can be used in a selected embodiment, even if not specifically shown or described. The same may also be varied in many ways. Such variations are not to be regarded as a departure from the present disclosure, and all such modifications are intended to be included within the scope of the present disclosure.

Claims
  • 1. A cold spray nozzle assembly for applying a coating of particles to a substrate comprising: a nozzle defining an inner passage extending in a flow direction from a convergent section adjacent a nozzle entrance through a throat to a divergent section adjacent a nozzle exit, each of the convergent section, the throat, and the divergent section of the inner passage is substantially rectangular in cross sectional planes that intersect perpendicularly and transversely to a longitudinal axis of the inner passage thereby having opposing minor side faces and major side faces;a gas supply member supplying a gas to the inner passage of the nozzle to flow through the inner passage of the nozzle and accelerate through the inner passage by passage through the convergent section, the throat, and the divergent section;a particle supply member in direct communication with only the minor side face of the divergent section of the inner passage, the particle supply member supplying the particles to flow in the gas supplied by the gas supply member, accelerate within the divergent section, and out of the nozzle via the nozzle exit toward the substrate to coat the substrate; anda laser that emits a laser beam that is transmitted through the inner passage containing the supplied gas, the laser heats the particles below the particles' melting point only in and downstream of the divergent passage and heats the substrate to promote cold spray coating of the substrate with the particles.
  • 2. The cold spray nozzle assembly of claim 1, wherein the inner passage has a substantially straight longitudinal axis, and wherein the laser beam is directed substantially parallel and coaxial to the longitudinal axis, out of the nozzle exit, and toward the substrate.
  • 3. The cold spray nozzle assembly of claim 2, wherein the inner passage includes a nozzle entrance, wherein the longitudinal axis extends through both the nozzle entrance and the nozzle exit, and wherein the laser is operably coupled to the nozzle such that the laser beam is transmitted into the nozzle via the nozzle entrance.
  • 4. The cold spray nozzle assembly of claim 1, further comprising a pressure tube that is disposed between the laser and the nozzle, the pressure tube being in fluid communication with the inner passage, and further comprising a gas supply member that supplies a gas to the pressure tube to flow through the inner passage of the nozzle and out of the nozzle exit.
  • 5. A cold spray nozzle assembly for applying a coating of particles to a substrate comprising: a nozzle defining an inner passage with a nozzle entrance, a nozzle exit, and a substantially straight longitudinal axis that extends through both the nozzle entrance and the nozzle exit, the inner passage being substantially rectangular in cross sectional planes that intersect perpendicularly and transversely to the longitudinal axis along its entirety thereby having opposing minor side faces and major side faces, the inner passage also including a convergent section adjacent the nozzle entrance and a divergent section downstream of the convergent section and adjacent the nozzle exit, the nozzle also including a particle supply inlet that is in direct communication with only the minor side face of the divergent section;a particle supply member in communication with the particle supply inlet, the particle supply member supplying the particles to flow and accelerate within the divergent section, and out of the nozzle via the nozzle exit toward the substrate to be coated thereon;a gas supply member that supplies a gas to the inner passage to flow through the inner passage of the nozzle to accelerate the particles;a laser that emits a laser beam that is transmitted into the nozzle via the nozzle entrance, through the inner passage containing the supplied gas, and out of the nozzle via the nozzle exit, the laser heating both the particles below their melting point only in and downstream of the divergent passage and the substrate to promote cold spray coating of the substrate with the particles; anda handling device that moves at least one of the nozzle and the substrate relative to the other.
  • 6. The cold spray nozzle assembly of claim 1, wherein the divergent section is larger than the convergent section at the throat resulting in formation of a shoulder at the throat, the shoulder being a flat surface parallel to the vertical planes perpendicular to the longitudinal axis of the inner passage, and wherein the particle supply member in direct communication with the divergent section of the inner passage is downstream from the shoulder.
CROSS-REFERENCE TO RELATED APPLICATIONS

This application claims the benefit of U.S. Provisional Application No. 61/266,639, filed on Dec. 4, 2009. The entire disclosure of the above application is incorporated herein by reference.

GOVERNMENT RIGHTS

This invention was made with government support under grant number N00244-07-P-0553 awarded by the United States Navy. The government has certain rights in the invention.

US Referenced Citations (91)
Number Name Date Kind
3872279 Fairbairn Mar 1975 A
3947653 Fairbairn Mar 1976 A
3947654 Fairbairn Mar 1976 A
4050408 Beucherie Sep 1977 A
4200669 Schaefer et al. Apr 1980 A
4299860 Schaefer et al. Nov 1981 A
4323756 Brown et al. Apr 1982 A
4724299 Hammeke Feb 1988 A
4741286 Itoh May 1988 A
4927992 Whitlow et al. May 1990 A
4947463 Matsuda et al. Aug 1990 A
4958058 Scheidt et al. Sep 1990 A
4991541 Sugata et al. Feb 1991 A
5043548 Whitney et al. Aug 1991 A
5271965 Browning Dec 1993 A
5283990 Shank, Jr. Feb 1994 A
5302414 Alkhimov et al. Apr 1994 A
5306330 Nasikas Apr 1994 A
5356674 Henne Oct 1994 A
5418350 Freneaux et al. May 1995 A
5449536 Funkhouser et al. Sep 1995 A
5477026 Buongiorno Dec 1995 A
5704825 LeCompte Jan 1998 A
5795626 Gabel et al. Aug 1998 A
5814152 Thaler Sep 1998 A
5961862 Lewis et al. Oct 1999 A
6046426 Jeantette et al. Apr 2000 A
6074135 Tapphorn et al. Jun 2000 A
6122564 Koch et al. Sep 2000 A
6139913 Van Steenkiste Oct 2000 A
6203861 Kar et al. Mar 2001 B1
6396025 Pyritz et al. May 2002 B1
6402050 Kashirin Jun 2002 B1
6534745 Lowney Mar 2003 B1
6623796 Van Steenkiste Sep 2003 B1
6800226 Gerking Oct 2004 B1
6808755 Miyamoto et al. Oct 2004 B2
6894247 Renteria et al. May 2005 B2
6913207 Miyamoto et al. Jul 2005 B2
6994894 Hofmeister Feb 2006 B2
7043330 Toyserkani et al. May 2006 B2
7045738 Kovacevic et al. May 2006 B1
7108894 Renn Sep 2006 B2
7139633 Mazumder et al. Nov 2006 B2
7143967 Heinrich Dec 2006 B2
7259353 Guo Aug 2007 B2
7582846 Molz et al. Sep 2009 B2
7605346 Harris et al. Oct 2009 B2
7705264 Hoebel et al. Apr 2010 B2
7765022 Mazumder et al. Jul 2010 B2
7951412 Justin et al. May 2011 B2
8020509 Calla et al. Sep 2011 B2
8021715 Jensen et al. Sep 2011 B2
8117985 Whitfield Feb 2012 B2
8561668 Castle et al. Oct 2013 B2
20010042508 Kay et al. Nov 2001 A1
20030185995 Miyamoto et al. Oct 2003 A1
20040058065 Steenkiste Mar 2004 A1
20040164190 Baumann Aug 2004 A1
20040166247 Heinrich Aug 2004 A1
20040202797 Ginder Oct 2004 A1
20050077373 Ikeda Apr 2005 A1
20050077380 Miyamoto et al. Apr 2005 A1
20050214474 Han Sep 2005 A1
20050252450 Kowalsky et al. Nov 2005 A1
20060081570 Schildgen Apr 2006 A1
20060133947 DeBiccari et al. Jun 2006 A1
20060134347 Chiruvolu Jun 2006 A1
20060201418 Ko Sep 2006 A1
20070065678 Ko Mar 2007 A1
20070138147 Molz Jun 2007 A1
20070183919 Ayer et al. Aug 2007 A1
20070194085 Spinella et al. Aug 2007 A1
20070241060 Kolb Oct 2007 A1
20070243335 Belashchenko Oct 2007 A1
20090155461 Jabado Jun 2009 A1
20090288601 Bi et al. Nov 2009 A1
20090324401 Calla Dec 2009 A1
20100098845 Jensen et al. Apr 2010 A1
20100143700 Champagne et al. Jun 2010 A1
20100151124 Xue Jun 2010 A1
20100173087 Calla et al. Jul 2010 A1
20100183826 Janz et al. Jul 2010 A1
20100320176 Mohanty et al. Dec 2010 A1
20110052824 Venkatachalapathy Mar 2011 A1
20120021026 Glenn, Jr. Jan 2012 A1
20120199564 Washko et al. Aug 2012 A1
20120240852 Ewers Sep 2012 A1
20120269958 Subramanian et al. Oct 2012 A1
20130004673 Ikeda Jan 2013 A1
20140065320 Lin et al. Mar 2014 A1
Foreign Referenced Citations (9)
Number Date Country
101016610 Aug 2007 CN
101111630 Jan 2008 CN
101208447 Jun 2008 CN
2439934 Jan 2008 GB
2002016058 Jan 2002 JP
2008080323 Apr 2008 JP
2008540115 Nov 2008 JP
2008302317 Dec 2008 JP
WO-9116146 Oct 1991 WO
Non-Patent Literature Citations (13)
Entry
International Search Report dated Sep. 30, 2011, International Application No. PCT/US2010/058953, Interntional Filing Date: Dec. 3, 2010.
Written Opinion dated Sep. 30, 2011, International Application No. PCT/US2010/058953, Interntional Filing Date: Dec. 3, 2010.
Brückner, S., Viöl, W., and Wieneke, S., “Interaction of Short Laser Pulses with Gases and Ionized Gases,” Coherence and Ultrashort Pulse Laser Emission, Dr. F. J. Duarte (Ed.), (Nov. 2010), pp. 383-402, ISBN: 978-953-307-242-5, InTech, DOI: 10.5772/13102. Available from: http://www.intechopen.com/books/coherence-and-ultrashort-pulse-laser-emission/interaction-of-short-laser-pulses-with-gases-and-ionized-gases.
Ciarrocca, M., Marangos, J.P., Burgess, D.D., Hutchinson, M.H.R., Smith, R.A., Rae, S.C., Burnett, K., “Spectral and spatial modifications to an intense 1 μm laser pulse interacting with a dense argon gas,” Optics Communications 110 (3), (Aug. 1994), pp. 425-434.
Karthikeyan, J., “Cold Spray Process,” ASM Handbook vol. 5A, Thermal Spray Technology, R.C. Tucker, Jr., Editor, 2013, pp. 54-59.
Panarella, E., “Theory of Laser-Induced Gas Ionization,” Foundations of Physics, vol. 4, No. 2, 1974, pp. 227-259.
Rae, S.C., “Ionization-induced defocusing of intense laser pulses in high-pressure gases,” Optics Communications vol. 97, Isss. 1-2, (Mar. 1993), pp. 25-28.
Kuroda, S., Kaihara, S., Fuji, S., Kinoshita, T., Adachi, M., “Modeling of particle generation in laser ablation plasma,” Journal of Aerosol Science 50 (2012), pp. 38-56.
First Japanese Office Action, Application No. 2012-542224, dated May 20, 2014, Translation by Asamura Patent Office, p.c., dated Jun. 25, 2014, 7 pages.
Supplementary European Search Report in Correspondending International Application No. EP10835212.1, mailed Nov. 18, 2014, 6 pages.
First Office Action, Chinese Application No. 201080061809.5, dated Aug. 5, 2014, Translation by Unitalen Attorneys at Law, 21 pages.
Second Chinese Office Action regarding Chinese Application No. 201080061809.5, mailed Mar. 20, 2015. Translation provided by Unitalen Attorneys at Law.
Third Chinese Office Action regarding Chinese Application No. 201080061809.5, mailed Mar. 18, 2016.
Related Publications (1)
Number Date Country
20110300306 A1 Dec 2011 US
Provisional Applications (1)
Number Date Country
61266639 Dec 2009 US