The present invention relates to a composite material and a method for manufacturing the composite material. More specifically, the present invention pertains to a composite material that is suitable for a heat dissipating substrate on which electronic components, such as semiconductor devices, are mounted, and a method for manufacturing the composite material.
Since electronic components such as semiconductor devices produce heat during operation, such components need to be cooled so that the performance will not lowered. Therefore, semiconductor devices are typically mounted on a base member with a heat radiator plate (heat dissipating substrate) in between.
The metal matrix composite material used for the heat sink 42 is expensive and has low workability. Therefore, a different material for heat dissipating substrates that is inexpensive and has high workability has been proposed. For example, Japanese Laid-Open Patent Publication No. 6-77365 discloses a material for heat dissipating substrates, which is formed by integrating metal plates and a wire fabric sheet. The metal plates are made of Cu, Cu and W (tungsten), or Cu and Mo (molybdenum). The wire fabric sheet is woven with thin metal wires made of Mo or W.
Japanese Laid-Open Patent Publication No. 6-334074 discloses a substrate for semiconductor devices, which substrate includes a base member, in which holes are formed. The base member is made of metal or alloy, the thermal expansion coefficient of which is less than or equal to 8×10−6/° C. The holes are filled with highly thermal conductive material such as metal or alloy, the thermal conductivity of which is more than or equal to 210 W/(m·K). The highly thermal conductive material may be Cu, Al, Ag, Au or an alloy that is chiefly composed of Cu, Al, Ag, or Au. The base member may be an invar plate, which contains 30 to 50% Ni by weight and Fe making up the remaining proportion, or a super invar plate, which contains Co. The holes of the base member are formed by punching after processing the raw material into a flat shape. Alternatively, the holes are formed during casting by the precision casting (lost-wax process).
However, when the laminated plate 47 shown in
The volumetric ratio of metal having a low thermal expansion coefficient needs to be maximized to suppress the thermal expansion coefficient of the material for heat dissipating substrates. However, in a material using the wire fabric sheet 45, metal exists not only in the meshes, which correspond to holes, but also in portions 47a (see
The substrate for semiconductor devices disclosed in Japanese Laid-Open Patent Publication No. 6-334074 does not have the drawbacks caused when the wire fabric sheet 45 is used. If holes are formed by punching after processing a raw material into a flat plate, the yield rate decreases, which increases the material cost. Also, forming holes by precision casting (lost wax) increases the manufacturing cost.
Accordingly, it is a first objective of the present invention to provide a composite material that has an improved strength and a reliable thermal conductivity, and is suitable for heat dissipating substrate. A second objective of the present invention is to provide a method for manufacturing the composite, which method reduces the manufacturing cost.
To achieve the above-mentioned objective, the present invention provides a composite material. The composite material is formed by combining a first member and a second member. The first member is a plate of an expanded metal having a plurality of meshes. The linear expansion coefficient of the expanded metal is equal to or less than 8×10−6/° C. The second member is a metal plate. The thermal conductivity of the metal plate is equal to or more than 200 W/(m·K). The meshes of the expanded metal plate is filled with a material of the metal plate. The volumetric ratio of the expanded metal plate to the composite material is in a range between 20% and 70%, inclusive.
According to another aspect of the invention, a method for manufacturing a composite material is provided. The method includes overlaying at least one plate of an expanded metal and at least one metal plate on each other. The expanded metal plate has a plurality of meshes. The linear expansion coefficient of the expanded metal is equal to or less than 8×10−6/° C. The thermal conductivity of the metal plate is equal to or more than 200 W/(m·K). The method includes rolling and joining the expanded metal plate and the metal plate such that the material of the metal plate fills the meshes of the expanded metal plate. The volumetric ratio of the expanded metal plate to the composite material is in a range between 20% and 70%, inclusive.
Other aspects and advantages of the invention will become apparent from the following description, taken in conjunction with the accompanying drawings, illustrating by way of example the principles of the invention.
The invention, together with objects and advantages thereof, may best be understood by reference to the following description of the presently preferred embodiments together with the accompanying drawings in which:
a) is a schematic cross-sectional view showing a method for manufacturing a plate made of a composite material according to one embodiment of the present invention;
b) is also a schematic cross-sectional view showing the method of
a) is a horizontal cross-sectional view schematically showing the plate of the composite material;
b) is a vertical cross-sectional view schematically showing the plate of the composite material;
c) is a partially enlarged cross-sectional view of
a) is a schematic partial perspective view showing the expanded metal plate;
b) is a cross-sectional view taken along line 5(b)—5(b) of
a) is a schematic cross-sectional view showing a material for heat dissipating substrates according to a prior art; and
b) is a partially enlarged view of
One embodiment according to the present invention will now be described with reference to
b), 4(a), and 4(b) show a plate 11 of a composite material according to this embodiment. The composite material plate 11 is formed by arranging a first member, which is a plate 12 of an expanded metal, between two second members, which are two metal plates 13, and then rolling the expanded metal plate 12 and metal plates 13 so that the plate 12 and the plates 13 are integrated. More specifically, as shown in
Rolling and joining are not performed in a single stage, but in two or more stages (in this embodiment, two stages). In a first stage, or a filling step, meshes 12a of the expanded metal plate 12 are filled with part of the metal plates 13 as shown in
When the thickness of the composite material plate 11 and the thickness of the expanded metal plate 12 after rolling and joining are referred to as t1, t2 as shown in
By combining the expanded metal plate 12 and the metal plates 13, the composite material plate 11 formed with the expanded metal plate 12 and a matrix metal 15 surrounding the expanded metal plate 12 as shown in
The thicknesses of the expanded metal plate 12 and the metal plates 13, which are combined, and the size of the meshes 12a of the expanded metal plate 12 are determined such that the volumetric ratio Vf of the expanded metal plate 12 to the composite material plate 11 is between 20% and 70%, inclusive. If the volumetric ratio Vf is less than 20%, the linear expansion coefficient of the composite material will be insufficient. If the volumetric ratio Vf exceeds 70%, the thermal conductivity of the composite material will be insufficient.
The linear expansion coefficient of the expanded metal plate 12 is equal to or less than 8×10−6/° C. In this embodiment, the expanded metal plate 12 is made of an invar plate, which is an Fe and Ni based alloy including 36% Ni by weight. The thermal conductivity of the metal plates 13, which are combined with the expanded metal plate 12, is more than or equal to 200 W/(m·K). In this embodiment, the metal plates 13 made of Cu.
When manufacturing the composite material plate 11 having a desired thermal expansion coefficient, the shape of the expanded metal plate 12, the thickness of the expanded metal plate 12, and the thickness of the metal plates 13 are determined in the following manner. Through experiments, it has been confirmed that the thermal conductivity λ of the composite material is approximately expressed by the following equation (1), which is formulated on the assumption that the law of mixture holds.
λ=λCu(λCu(1−S)+λIvS)/(λCu(1−S+tS)+λIv(1−t)S) (1)
t represents the ratio of thickness of the invar plate, S represents the ratio of area of the invar plate,
λCu represents the thermal conductivity of Cu, λIv represents the thermal conductivity of the invar plate. The ratio of area S of the invar plate represents the ratio of the cross-sectional area of the expanded metal plate 12 to the total cross-sectional area of the composite material plate 11 shown in
The thermal expansion coefficient β of the composite material plate 11 is represented by the following equation (2) on the assumption that the rule of mixture holds.
β=(1−S)βCu+S((1−νIv)βCuECu(1−t)+(1−νCu)βIvEIvt)/ ((1−νIv)ECu(1−t)+(1−νCu)EIvt) (2)
βCu represents the thermal expansion coefficient of Cu, and βIv represents the thermal expansion coefficient of the invar plate. ECu represents the Young's modulus of Cu, and EIv represents the Young's modulus of the invar plate. νCu represents the Poisson's ratio of Cu, and νIv represents the Poisson's ratio of the invar plate.
Through experiments, it has been confirmed that the equation (2) is approximately the same as the Kerner equation containing the volumetric ratio VIV of the invar plate, and the thermal expansion coefficient β is represented by the following equation (3).
β=((1−νIv)βCuECu(1−VIV)+(1−νCu)βIvEIvVIV)/(((1−νIv)ECu(1−VIV)+(1−νCu)EIvVIV)) (3)
Therefore, at first, a value of the volumetric ratio VIV of the invar plate that corresponds to a target value of the thermal expansion coefficient β of the composite material plate 11 is selected. Also, a value of the ratio of area S of the invar plate that corresponds to a target value of the thermal conductivity λ of the composite material plate 11 is selected. When manufactured to satisfy these conditions, the composite material plate 11 is suitable for a heat dissipating substrate.
The volumetric ratio VIV of the invar plate in the composite material plate 11 is determined according to the thickness of the expanded metal plate 12 and the thickness of the metal plates 13, which are rolled and joined. The volumetric ratio VIV is represented by the following equation.
VIV=(net thickness of invar plate)/((thickness of Cu)−(thickness of a portion of Cu removed by surface grinding)+(net thickness of invar plate))
If no surface grinding is performed after rolling and joining, the volumetric ratio VIV of the invar plate in the composite material plate 11 is represented by the following equation.
VIV=(net thickness of invar plate)/((thickness of Cu)+(net thickness of invar plate))
The net thickness of the invar plate refers to the thickness of the invar plate when there is no space (mesh). The net thickness of the invar plate is computed in the following manner according to conditions of expanding.
Net thickness of invar plate=T/(SW/2 W)
For example, when the equation SW:LW:T:W:F=2.7:6:1:1.2:1 is satisfied and when T is 1 mm, the net thickness of the invar plate will be 0.89 mm.
SW represents the distance (mm) between the centers of adjacent meshes arranged along a lateral direction of the expanded metal plate (see
When manufacturing expanded metal plate 12, an apparatus a part of which is shown in
a) is a schematic partial perspective view showing one of the meshes 12a of the expanded metal plate 12.
The material plate 18, which has lines of alternately arranged slits, is expanded to form the expanded metal plate 12 with the meshes 12a. The surface of the expanded metal plate 12 is uneven. The expanded metal plate 12 is then rolled with flat rollers so that the strands 12b and the bonding portions 12c are in the same plane. Therefore, the sides of each strand 12b, which lie along the thickness direction of the composite material plate 11 formed of the expanded metal plate 12 and the metal plates 13, are not perpendicular to the surfaces of the composite material plate 11, but are inclined as shown in
The distance SW between the centers must be equal to or more than twice the thickness of the invar plate. In some sections of the composite material plate 11, only the matrix metal 15 exists along the thickness direction. In other sections, the matrix metal 15 and the expanded metal plate 12 exist along the thickness direction. Through experiments, it has been confirmed that, if the meshes 12a are too large, due to the difference in thermal expansion coefficient between these sections, the influence of thermal stress is increased, and that the distance SW between the centers is preferably twice to five times the thickness of the invar plate.
The rolling performed in this embodiment is hot rolling. The temperature of the hot rolling needs to be equal to or higher than a temperature at which diffusion boding occurs between the metal plates 13, and between each metal plate 13 and the expanded metal plate 12. Accordingly, the temperature of the hot rolling needs to be a temperature at which lattice diffusion of Cu, which forms the metal plates 13, occurs. That is, the temperature of the hot rolling needs to be equal to or higher than 0.8 times the melting point of Cu on a Kelvin basis. The temperature of the hot rolling is preferably equal to or higher than 800° C. However, if the temperature is excessively high, many Cu—Ni—Fe alloy layers, the thermal conductivity of which is about 50 W/(m·K), are formed between the metal plates 13 made of Cu and the expanded metal plate 12 made of the invar plate. Thus, the temperature the hot rolling needs to be as low as possible. In the hot rolling, it is difficult to maintain a constant temperature. If the target temperature is about 800° C., the actual temperature varies in a range of ±50° C. Thus, in consideration of the capacity of the apparatus, the target temperature is preferably 850° C.
This embodiment provides the following advantages.
(1) The expanded metal plate 12, the linear expansion coefficient of which is equal to or less than 8×10−6/° C., and the metal plates 13, the thermal conductivity of which is equal to or more than 200 W/(m·K), are overlaid on one another, and rolled to be joined. As a result, the volumetric ratio of the expanded metal plate 12 to the composite material plate 11 is 20 to 70%. Therefore, the manufactured composite material plate 11 is suitable for a heat dissipating substrate for mounting electronic components such as semiconductor devices. Also, the composite material plate 11 has improved thermal conductivity and strength compared to a case where a wire fabric sheet is used. Also, compared to cases where holes are formed in a flat metal plate by punching or precision casting, the illustrated embodiment reduces the costs.
(2) When the thickness of the composite material plate 11 and the thickness of the expanded metal plate 12 after rolling and joining are represented by t1 and t2, respectively, the thickness of the expanded metal plate 12 and each metal plate 13 prior to rolling and joining, and the reduction ratio of the rolling and joining are determined such that (t2)/(t1) is between 0.2 and 0.8, inclusive. As a result, it is easy to manufacture the composite material plate 11 having a linear expansion coefficient and a thermal conductivity that are suitable for a heat dissipating substrate to mount electronic components such as semiconductor devices.
(3) Rolling and joining of the materials are performed in two or more stages (in this embodiment, two stages). After the meshes 12a of the expanded metal plate 12 are filled with the material of the metal plates 13, the last stage is performed such that the reduction ratio has the maximum value in the permissible range of reduction ratio. Since unnecessary force does not need to be applied to the rollers 14 until the material of the metal plates 13 fills the meshes 12a of the expanded metal plate 12, the size of the apparatus is reduced compared to a case where the rolling and joining are completed in a single stage.
(4) The invar plate is used for the expanded metal plate 12, and Cu is used for the metal plates 13. Thus, the linear expansion coefficient of the composite material plate 11 can be adjusted such that the plate 11 is suitable for a heat dissipating substrate for mounting electronic components such as semiconductor devices.
(5) The composite material plate 11 is a plate in which the expanded metal plate 12 is surrounded by the matrix metal 15, which has a thermal conductivity equal to or more than 200 W/(m·K). Therefore, compared to a structure in which part of the expanded metal plate 12 is exposed on the surface of the composite material plate 11, the thermal conductivity in the horizontal direction is improved.
(6) Cu is used as the metal having a thermal conductivity equal to or more than 200 W/(m·K). Compared to a precious metal, Cu, which has a thermal conductivity equal to more than 200 W/(m·K), is inexpensive. Also, Cu improves the heat radiating property of the composite material plate 11.
(7) In this embodiment, an invar plate is used for the expanded metal plate 12, and Cu is used for the metal plates 13. Hot rolling is performed with a target temperature set at a temperature computed by adding the margin of variation of temperature control of the hot rolling apparatus to the 800° C. Therefore, even if the temperature of the hot rolling varies, many Cu—Ni—Fe alloy layers, the thermal conductivity of which is about low 50 W/(m·K) are prevented from being formed between the metal plates 13 made of Cu and the expanded metal plate 12 made of the invar plate.
The invention may be embodied in the following forms.
The rolling and joining of the expanded metal plate 12 and the metal plates 13 do not need to be performed in two stages, but may be performed in three or more stages. Alternatively, the rolling and joining may be performed in a single stage.
In the above illustrated embodiment, the single expanded metal plate 12 and the two metal plates 13 are rolled and joined. However, the present invention may be applied to a case where the number of the expanded metal plate 12 and the metal plate 13 are different from the above embodiment. For example, as shown in
When manufacturing the expanded metal plate 12, using a thinner material plate 18 makes it easier to form finer meshes 12a. Therefore, if the volumetric ratio of the expanded metal plate 12 to the matrix metal 15 is constant, using two or more expanded metal plates 12 as shown in
The material for the expanded metal plate 12 is not limited to the invar plate. That is, any type of metal plate may be used as long as the linear expansion coefficient is equal or less than 8×10−6/° C. For example, a plate of another invar alloy such as super invar and stainless invar, or fernico (54% Fe by weight, 31% Ni by weight, 15% Co by weight, the linear expansion coefficient of which is 5×10−6/° C.) may be used.
When using two or more expanded metal plates 12, the material of the expanded metal plates 12 may be different. However, parts of the expanded metal plates that are located at symmetrical positions with respect to a plane containing the center of the composite material plate 11 in the thickness direction are preferably made of the same material. This configuration prevents the composite material plate 11 from curling even if there is a difference in the thermal expansion coefficient in the different materials.
The matrix metal 15 does not need to be made of Cu. That is, the matrix metal 15 may be any metal as long as the coefficient of thermal conductivity is more than or equal to 200 W/(m·K). For example, aluminum-based metal or silver may be used. The aluminum-based metal refers to aluminum or aluminum alloy. The thermal conductivity of the aluminum-based metal is low as compared to that of Cu. The melting point of the aluminum-based metal (aluminum) is 660° C., which is significantly lower than the melting point of the copper, which is 1085° C. This reduces the manufacturing cost as compared to the copper. Aluminum-based metal is also preferable in view of weight reduction.
The composite material plate 11 may be applied to heat sinks other than a heat dissipating substrate for mounting semiconductor devices.
Therefore, the present examples and embodiments are to be considered as illustrative and not restrictive and the invention is not to be limited to the details given herein, but may be modified within the scope and equivalence of the appended claims.
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