Patent Application
20220074851
The present invention relates to a concentration measurement device, and in particular, to a concentration measurement device for measuring a concentration of a gas in a measurement cell by detecting an intensity of light passed through the measurement cell.
Conventionally, a concentration measurement device (so called in-line type concentration measurement device) has been known, which is incorporated in the middle of a gas supply line for supplying an organometallic (MO) raw material gas etc. generated from a liquid material or a solid material to a semiconductor manufacturing equipment and is configured to measure a concentration of the gas flowing therein.
In this type of concentration measurement device, a light having a predetermined wavelength is made to enter from a light source through a light incident window into a measurement cell through which a measurement gas flows, and the light passing through the measurement cell is received by a light receiving element for measuring an absorbance. In addition, from the measured absorbance, the concentration of the measured gas can be determined according to Lambert-Beer law (for example, Patent Documents 1 to 3).
In the present specification, various transmitted light detection structures used for detecting the concentration of measurement gas are broadly referred to as measurement cells. The measurement cell includes not only a cell structure that is branched from a gas supply line and arranged separately, but also an in-line type transmitted light detection structure provided in the middle of the gas supply line as shown in Patent Documents 1 to 3.
In order to measure the gas concentration in the measurement cell based on the absorbance, it is necessary to make light having a wavelength adapted to the absorbance characteristics of the gas enter the measurement cell. In addition, the concentration of the measured gas is obtained by calculation based on the Lambert-Beer equation using an extinction coefficient that is a coefficient indicating the easiness of the gas absorption. The extinction coefficient used at this time is obtained in advance before the concentration measurement and is corresponded to the type of gas and the wavelength of the measurement light.
However, according to experiments by the present inventors, it has been found that absorption characteristics may differ even for the same type of gas depending on the gas temperature in the measurement cell and the characteristic difference of each concentration measurement device (hereinafter referred to as “machine difference”), and in this case, the measurement accuracy may be lowered by using the conventional method.
The present invention has been made in view of the above-mentioned problem, and its main object is to provide a concentration measurement device having improved measuring accuracy.
The concentration measurement device according to an embodiment of the present invention includes a measurement cell having a flow path through which a gas flows, a light source for generating light incident to the measurement cell, a photodetector for detecting light emitted from the measurement cell, a pressure sensor for detecting a gas pressure in the measurement cell, a temperature sensor for detecting a gas temperature in the measurement cell, and an arithmetic circuit for calculating the gas concentration based on an output of the pressure sensor, an output of the temperature sensor, an output of the photodetector, and a plurality of extinction coefficients stored in advance in a memory, wherein the arithmetic circuit is configured to calculate a concentration using an extinction coefficient determined from the plurality of extinction coefficients based on the output of the temperature sensor.
In an embodiment, the arithmetic circuit is configured to calculate the concentration using an absorption coefficient determined on the basis of the output of the temperature sensor and a peak wavelength of measurement light emitted from the light source.
In an embodiment, the arithmetic circuit is configured to calculate the concentration using any of nine extinction coefficients corresponding to a combination of three temperatures and three peak wavelengths of the measurement light.
In an embodiment, the arithmetic circuit is configured to determine the gas concentration C based on the following equation by using a determined extinction coefficient α, where I0 is an intensity of the incident light entering into the measurement cell, I is an intensity of the light passing through the measurement cell. R is a gas constant, T is a gas temperature in the measurement cell, L is an optical path length of the measurement cell, P is a gas pressure in the measurement cell.
C=ln(I0/I)×(R·T)/(α·L·P)
In an embodiment, the arithmetic circuit is configured to calculate the concentration by correcting the extinction coefficient of a reference gas using a correction factor set for each type of gas.
In an embodiment, the reference gas is acetone gas.
According to the embodiments of the present invention, it is possible to prevent accuracy deterioration caused by the gas temperature or the machine difference and perform concentration measurement more accurately.
Embodiments of the present invention will be described below with reference to the drawings, but the present invention is not limited to the following embodiments.
The gas unit 50A may be heated to, for example, about 100° C. to 150° C. depending on the type of the measurement gas. However, the gas unit 50A is not necessarily used at a high temperature, when a gas at a normal temperature (room temperature) or a temperature lower than the normal temperature is used, the gas unit may be used in a condition that is not at a high temperature (not to be heated). Also, the electric unit 50B spaced apart from the gaseous unit 50A is typically maintained at room temperature. To the electric unit 50B, an external control device for transmitting an operation control signal to the concentration measurement device 100 or receiving a measurement concentration signal from the concentration measurement device 100 may be connected.
In the gas unit 50A, a measurement cell 4 having an inlet 4a and an outlet 4b of the measurement gas, and a flow path 4c extending in the longitudinal direction is provided. Further, on one end portion of the measurement cell 4, a translucent window portion (here translucent plate) 3 is provided, and a reflecting member 5 is provided at another end of the measurement cell 4. In addition, in the present specification, the so-called light includes not only visible light but also at least infrared light and ultraviolet light, and it may include electromagnetic waves of any wavelength. Further, the translucency means that the internal transmittance in respect to the incident light to the measurement cell 4 is sufficiently high to be able to perform concentration measurement.
The window portion 3 of the measurement cell 4 is fixed to a cell main body 2 by a pressing member, and a collimator 6 connected to an optical fiber 10a is attached to the pressing member. The collimator 6 can make the light from the light source 1 as parallel light incident on the measurement cell 4 and receive the reflected light from the reflecting member 5. The collimator 6 is preferably designed so that concentration measurement can be performed with high accuracy even when the gas to be measured flowing through the measurement cell 4 is at an elevated temperature.
The inlet 4a and outlet 4b of the measuring cell 4 are arranged on both sides of the flow path 4c (left side and right side of the flow path 4c in the drawing), when incorporated in the gas supply line, the gas unit 50A is configured to flow the gas in a horizontal direction as a whole. On the other hand, the flow path 4c extends in a direction perpendicular to the entire flow direction in the gas supply line. In the present specification, such a configuration is referred to as a vertical measurement cell 4, when using the vertical measurement cell 4, it is possible to save space when incorporated in the gas supply line, and to obtain the advantage of easy maintenance. In addition, in the measurement cell 4 shown in the drawing, although the inlet 4a is provided in the vicinity of the reflecting member 5, and the outlet 4b is provided in the vicinity of the window portion 3, in another embodiment, the inlet 4a may be provided in the vicinity of the window portion 3, and the outlet 4b may be provided in the vicinity of the reflecting member 5. Further, the flow path 4c is not always necessary to extend in the direction perpendicular to the entire flow direction.
As the window portion 3, sapphire is suitably used, because it is resistant to detection light such as ultraviolet light used for concentration measurement, has a high transmittance, and is mechanically and chemically stable, but other stable materials such as quartz glass may also be used. The cell main body 2 (the portion to define the flow path) of the measuring cell 4 is made of SUS316L, for example.
The reflective member 5 is fixed to the lower surface of the cell main body 2 by a pressing member. The reflecting surface of the reflecting member 5 is provided so as to be perpendicular to the traveling direction of the incident light or the central axis of the flow path.
The reflecting member 5, for example, may be configured to have an aluminum layer formed as a reflective layer by sputtering on a back surface of a sapphire plate. Further, the reflecting member 5 may include a dielectric multilayer film as the reflecting layer, by using the dielectric multilayer film, it is possible to selectively reflect light having a specific wavelength range (e.g., near-ultraviolet). The dielectric multilayer film is composed of a laminate of a plurality of optical coatings having different refractive indices (a laminate of a high refractive index thin film and a low refractive index thin film), by appropriately selecting the thickness and the refractive index of each layer, it is possible to reflect or transmit light of a specific wavelength.
Further, since the dielectric multilayer film is possible to reflect light at an arbitrary ratio, for example, when the incident light is reflected by the reflecting member 5, rather than 100% of the incident light, a portion (e.g., 10%) is made to transmit, by a light detector or the like installed at the lower portion of the reflecting member 5 (the surface opposite to the surface in contact with the flow path 4c), the transmitted light can be received and utilized as a reference light, it can also substitute the reference light detector 9.
Moreover, in the gas unit 50A of the present embodiment, a pressure sensor 20 for detecting the pressure of the measurement gas flowing through the measurement cell 4, and a temperature sensor 22 for measuring the temperature of the measurement gas are provided. The gas unit 50A is configured to be able to measure the pressure and temperature of the measurement gas during the concentration measurement.
Outputs of the pressure sensor 20 and temperature sensor 22 are input to the arithmetic circuit 8 of the electric unit 50B via a sensor cable (not shown). A plurality of temperature sensors 22 may be provided. As the temperature sensor 22, a thermistor, a thermocouple, or the like, may be used in addition to a temperature measurement resistor. As the pressure sensor 20, for example, a silicon single crystal sensor chip built-in type pressure sensor having a diaphragm to form a pressure sensing surface is used. The pressure sensor 20 and the temperature sensor 22 may be provided at any location as long as the pressure and temperature of the gas present in the flow path 4c in the measurement cell 4 can be measured.
On the other hand, in the electric unit 50B, a light source l for generating light incident to the measuring cell 4, a measuring photodetector 7 for receiving light emitted from the measuring cell 4, an arithmetic circuit 8 configured to calculate the concentration of the measurement gas based on a detection signal output of the measuring photodetector 7 (a signal corresponding to the intensity of the received light), and a reference photodetector 9 for receiving a reference light from the light source 1 are provided.
In the present embodiment, the light source 1 includes two light-emitting elements (LEDs in this case) 1A and 1B that emit ultraviolet light having wavelengths differing from each other. Using an oscillation circuit, driving currents of different frequencies are applied in the light-emitting elements 1A and 1B, by performing frequency analysis (e.g., fast Fourier transform or wavelet transform), it is possible to measure the intensity of light corresponding to each wavelength component from the detection signal detected by the measurement photodetector 7. As the light-emitting elements 1A and 1B, a light-emitting element other than LED, for example, an LD (laser diode) may also be used. Further, instead of using a multiplexed light of a plurality of different wavelengths as the light source, it is also possible to utilize a light source having a single wavelength, in this case, the multiplexer and the frequency analysis circuit can be omitted. Three or more light-emitting elements may be provided, and it may be configured to generate incident light using only one selected light-emitting element among those provided. A temperature measuring resistor may be attached to the light source 1. Furthermore, the light emitted by the light emitting element may be visible light or infrared light rather than ultraviolet light.
The light source 1 and the reference photodetector 9 are attached to a beam splitter 11. The beam splitter 11 functions to make a portion of the light from the light source 1 incident on the reference photodetector 9, and to guide the remaining light to the measurement cell 4. As the light-receiving element constituting the measurement photodetector 7 and the reference photodetector 9, for example, a photodiode or a phototransistor is preferably used.
The arithmetic circuit 8 is configured by, for example, a processor or a memory provided on a circuit board, includes a computer program for executing a predetermined calculation based on an input signal, and can be realized by a combination of hardware and software. Although the arithmetic circuit 8 in the illustrated embodiment is incorporated in the electric unit 50B, it is needless to say that a part of the component (such as a CPU) or all of it may be provided in a device outside of the electric unit 50B.
In the concentration measurement device 100, the light from the light source 1 is guided to the window portion 3 of the measurement cell 4 through the optical fiber 10a. Further, in the measurement cell 4, the light reflected by the reflecting member 5 is guided to the measurement photodetector 7 by the optical fiber 10b. In the present embodiment, the optical fiber 10a for guiding the light to the measurement cell 4 and the optical fiber 10b for guiding the light emitted from the measurement cell 4 are provided separately, thereby making it possible to reduce the influence of stray light.
However, in another embodiment, by using a single optical transmission member serving for both the incident light and the emitted light, such as an optical fiber bundle, the light source and the measuring photodetector may be connected to the measurement cell. A reflection type concentration measurement device using such a single light-transmitting member is disclosed in, for example, Patent Literature 2, and it is also possible to employ the same configuration in other embodiments of the present invention.
In the measurement cell 4 described above, the optical path length of the light reciprocating in the measurement cell 4 can be defined by twice the distance between the window portion 3 and the reflecting member 5. In the concentration measurement device 100, the light of the wavelength λ incident to the measuring cell 4 and then reflected by the reflecting member 5 is absorbed by the gas present in the flow path 4c in the measuring cell 4 in dependence on the concentration of the gas. Then, the arithmetic circuit 8 is able to measure the absorbance Aλ at the wavelength λ, by frequency analysis of the detected signal from the measurement photodetector 7, further, based on the Lambert-Beer law shown in the following equation (1), it is possible to calculate the molar concentration CM from the absorbance Aλ.
Aλ=−log10(I/I0)=α′LCM (1)
In the above equation (1). I0 is the intensity of incident light on the measurement cell, I is the intensity of light passing through the gas in the measurement cell, α′ is the molar extinction coefficient (m2/mol), L is the optical path length (m) of the measurement cell, and CM is the molar concentration (mol/m3). The molar extinction coefficient α′ is a coefficient determined by substance. I/I0, generally referred to as transmission, has an absorbance Aλ of 0 when the transmission I/I0 is 100%, and the absorbance Aλ becomes infinity when the transmission I/I0 is 0%.
In addition, regarding the incident light intensity I0 in the above equation, when there is no absorbing gas in the measuring cell 4 (e.g., when a gas that does not absorb ultraviolet light is filled, or when it is vacuumed), the intensity of the light detected by the measuring photodetector 7 may be regarded as the incident light intensity I0.
The optical path length L of the measurement cell 4, as described above, may be defined as twice the distance between the window portion 3 and the reflecting member 5, so that twice of the optical path length may be obtained as compared with the concentration measurement device provided with the light incident window and the light emitting window at each end of the measurement cell. Thus, in spite of the miniaturization, the measurement accuracy may also be improved. Further, in the concentration measurement device 100, since the incident and emitted light are made only on the window portion 3 side of the measurement cell 4, the number of parts may be reduced.
As described above, the concentration measuring device 100 is possible to determine the molar concentration CM of the gas by using the Lambert-Beer equation (1). However, in order to further improve the measuring accuracy, in the present embodiment, the molar concentration CM is obtained from the equation (1) using not only a single molar absorption coefficient α′ set in advance, but also an absorption coefficient selected on the basis of the temperature output by the temperature sensor 22, and the concentration of the gas is also obtained by referring to the output of the temperature sensor 22 and the output of the pressure sensor 20. In addition, by storing the extinction coefficient in advance in the memory at the time of shipment before the concentration measurement is performed, the extinction coefficient can be read out from the memory and used at the time of performing the concentration measurement.
Hereinafter, in the present embodiment, a method of obtaining the extinction coefficient used for concentration calculation by flowing acetone gas having a known concentration will be described. In the following, light (specifically, near ultraviolet rays) having a predetermined wavelength absorbed corresponding to the concentration of the acetone gas is used as the light used for measurement, and the extinction coefficient corresponding to the wavelength is also obtained. In the case of acetone gas, the wavelength of the measurement light is set, for example, from 29% nm to 310 nm.
As described above, the following equation (1a) is satisfied from the Lambert-Beer equation (1). In equation (1a), as same as in the Lambert-Beer equation (1), I0 is the incident light intensity, I is the transmitted light intensity, α is the molar extinction coefficient, L is the optical path length, and CM is the molar concentration of the gas (here, acetone) to be measured. This equation (1a) shows that when the optical path length is constant, the absorbance is proportional to the molar concentration, and the extinction coefficient α corresponds to the slope of the first order function indicating the relationship between the molar concentration and the absorbance (the easiness of the absorbance of the substance)
The molar extinction coefficient α in the above equation (1a) is the molar extinction coefficient when a natural logarithm of the transmittance (I/I0) is used, and has a relationship of α′=0.434α with respect to the molar extinction coefficient α′ (molar extinction coefficient corresponding to the absorbance Aλ) when the common logarithm of the transmittance (I/I0) in the above equation (1) is used. This is because log10e=0.434. The following illustratively describes the molar extinction coefficient α when using the natural logarithm in (I/I0) of the transmittance, it is needless to say that the same description applies to the molar extinction coefficient α′ when using the common logarithmic log10(I/I0) of the transmittance.
The above molar concentration CM of acetone refers to the mass of gas per unit volume, so that CM can be expressed as CM=n/V, where n is the amount of substance (mol) of the gas, i.e. the number of moles, and V is the volume (m3) of the gas. Then, since the measurement object is gas, the molar concentration CM=n/V=P/RT is derived from the ideal gas law of PV=nRT, and this is substituted into the above equation (1), by applying −ln (I/I0)=ln(I0/I), the following equation (2) is derived. In equation (2), R is the gas constant=0.0623 (Torr·m3/K/mol), P is the pressure (Torr) and T is the temperature (K).
Here, the pressure that can be detected by the pressure sensor 20 is the total pressure Ptotal (Torr) of the mixed gas containing acetone and the carrier gas. However, only acetone is absorbed, and the pressure P in the above equation (2) corresponds to the partial pressure Pace of acetone. Therefore, if the partial pressure Pace of acetone is expressed by the equation (2) using Pace=Ptotal·Cace, which is an equation expressed by the acetone concentration Cace (volume %: hereinafter simply denoted as %) in the whole gas and the total pressure Ptotal, the relation between the concentration (%) of acetone and the absorbance considering the pressure and the temperature can be expressed by the following equation (3) using the extinction coefficient αace of acetone.
Also, by transforming the above equation (3), the following equation (4) is derived.
Therefore, according to the above equation (3) or (4), it is understood that the extinction coefficient αace corresponding to the acetone concentration (%) at the measurement light wavelength can be obtained on the basis of the respective measurement values (the gas temperature T, the total pressure Ptotal, and the transmitted light intensity I) when a gas having a known acetone concentration Cace (for example, the 100% concentration of acetone gas containing no carrier gas) is flowed.
Further, by storing the obtained extinction coefficient αace in the memory, the unknown concentration of the acetone concentration can be obtained by calculation based on the measured result of (T, Ptotal, I) according to the above equation (4). The above equations (3) and (4) are derived by applying the ideal gas law to the Lambert-Beer equation considering that the measurement object is a gas (here is acetone gas), and calculating the gas concentration (%) using the gas pressure (total pressure Ptotal) and the gas temperature T measurable by the pressure sensor 20 and the temperature sensor 22 of the concentration measuring device 100.
In the case where the concentration is calculated using the extinction coefficient αace obtained when the acetone gas of 100% concentration flows, the relation between the known concentration (set concentration) and the output concentration by the calculation may not be consistent. In this case, a correction value Jx (1 at the time of 100% concentration) for correcting the relationship between the set concentration and the output concentration may be set in advance for each concentration x %, and the linearity correction may be performed using the correction value Jx determined on the basis of the measured transmittance, and then the corrected concentration may be output.
As described above, by obtaining the extinction coefficient αace of acetone in advance, the acetone concentration can be calculated from the measured values (T, Ptotal, I). However, according to experiments conducted by the present inventors, it has been found that, even when the above equation (3) or (4) is used, errors of the concentration measurement are different due to the difference in the temperature of acetone. It should be noted that the above equation (4) is an equation taking the gas temperature T into consideration, but as a result of an experiment, it has been found that further correction is preferable in order to measure the concentration more accurately.
One of the reasons why the measurement error differs depending on the gas temperature is that the transmittance (I/I0) measured according to the gas temperature of the gas differs even if the acetone gas has the same concentration.
As shown in
For this reason, even though the same 100% concentration of acetone gas flows, transmittance and absorbance may be measured as different depending on the gas temperature. More specifically, as shown in
Therefore, when the concentration calculation is performed according to the above equation (4) using the extinction coefficient αace obtained when acetone gas of 100% concentration flows at 130° C., the concentration of the gas at 100° C. or 150° C. may not be accurately obtained. This is because, even at the same concentration, the ease of absorbance varies depending on the gas temperature.
In order to solve the above problem, in the present embodiment, the extinction coefficient αace at the respective temperature is obtained in advance and stored in the memory as a plurality of extinction coefficients αace associated with the temperatures, and when performing concentration measurement, the appropriate absorption coefficient αace is determined and used on the basis of the measured gas temperature at that time.
Graphs C1 to C3 of
As shown in graph C2, when the temperature of the acetone gas is 130° C., the error between the calculated concentration when using the extinction coefficient αace, T2, and the actual concentration becomes 0 (in other words, the extinction coefficient αace, T2, at which the error becomes 0, is used). On the other hand, as shown in graph C1, when the acetone gas is at 100° C., an error occurs between the concentration obtained by calculation using the extinction coefficient αace, T2 at 130° C. and the actual concentration. Similarly, as shown in graph C3, when the acetone gas is at 150° C., an error occurs between the concentration obtained by calculation using the extinction coefficient αace, T2 at 130° C. and the actual concentration.
More specifically, since an excessive extinction coefficient αace, T2 is used for the acetone gas at 100° C., as can be seen from Equation (4), the value smaller than the actual concentration is output as the calculated concentration. Also, an insufficient extinction coefficient αace, T2 is used for the acetone gas at 150° C., a value larger than the actual concentration is output as the calculated concentration. Thus the errors shown in the graphs C1 and C3 occur.
The magnitude of the above error is greatest when the acetone gas of 100% concentration flows, and the error becomes 0 when the acetone gas of 0% concentration flows (i.e., no absorbance), the relationship between concentration and magnitude of error is linear. Therefore, it can be understood that calculation results with less error can be obtained for any concentration if extinction coefficients αace, T1, αace, T2 other than the extinction coefficient at 100% concentration at the reference temperature are also obtained in advance, and the concentration calculation of the gas in the vicinity of 100° C. and in the vicinity of 150° C. are performed by using these values.
Similar to the extinction coefficient αace, T2, the extinction coefficients αace, T1 and αace, T3 can be calculated according to the equations (3) and (4) from each measured value (T, Ptotal, I) when 100% acetone gas flows at 100° C. and 150° C. respectively.
The table of
In the above description, the embodiment in which all the extinction coefficients at each temperature are stored in the memory has been described, but the present invention is not limited to this, and the concentration may be calculated by storing the extinction coefficient at 130° C. as the reference extinction coefficient, storing the correction coefficient at each temperature, and using the extinction coefficient multiplied by the correction coefficient determined on the basis of the measured temperature.
In addition, although the embodiment in which the extinction coefficient is determined for each of the temperatures T1, T2, and T3 has been described above, the embodiment of the present invention is not limited thereto. By using any number of two or more extinction coefficients associated with gas temperatures, concentration measurement errors that occur depending on the gas temperature may be reduced. Further, when the extinction coefficients αT1, αT2 are given for the two temperatures T1 and T2 respectively, and the measured temperature is between T1 and T2, the extinction coefficient can be obtained by substituting the measured temperature into a linear expression connecting to the orthogonal plane coordinates (T1, αT1) and (T2, αT2).
Next, an embodiment in which different extinction coefficients are set not only for the above-mentioned gas temperatures but also for the wavelengths of the measurement light will be described.
As shown in
In this case, when the concentration calculation is performed by applying the initially set extinction coefficient αace, T2 for the wavelength of 300 nm to the measurement results when the measurement light of different wavelengths (here, 297.5 nm and 302.5 nm) are used, an error may occur in the calculated concentration. This is because, as in the case of the above temperature, even though the acetone gas has the same 100% concentration, the transmittance becomes different depending on the measurement light wavelength. Specifically, as shown in
Therefore, as shown in
As described above, by using different extinction coefficients for the wavelengths L1, L2, and L3 respectively, the concentration can be measured regardless of the difference in the wavelength of the measurement light due to machine difference. By performing a step of detecting the peak of the measurement light wavelength prior to concentration measurement, the concentration measurement device can determine the extinction coefficient to be used in the device.
Further, although the concentration measurement using acetone gas has been described above, it is also the same for other types of gases, the accuracy of the concentration measurement can be improved by setting a plurality of extinction coefficients associated with the temperature or the measurement light wavelength in advance. In the case of measuring the concentration of another type of gas, the extinction coefficient may be set in advance as described above, but the extinction coefficient for the acetone gas may be stored in the memory, and the extinction coefficient for the gas type may be determined by correcting the extinction coefficient according to the type of gas.
While the concentration measurement device according to the embodiment of the present invention has been described above, the present invention is not limited to the above embodiments, and variations can be made without departing from the spirit of the present invention. For example, as the measurement light, in correspondence to the type of the gas, a light in a wavelength region other than the ultraviolet region can be used.
Further, the reflection-type concentration measurement device using a reflecting member has been described above, a transmission-type concentration measurement device without using a reflecting member, configured so that incident light comes from one end of the measurement cell, and the measurement light is taken out of the other end of the measurement cell.
The concentration measurement device according to the embodiment of the present invention is used for semiconductor manufacturing equipment or the like and is suitably utilized for measuring the concentration of various gases.
| Number | Date | Country | Kind |
|---|---|---|---|
| 2019-016404 | Jan 2019 | JP | national |
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/JP2020/001917 | 1/21/2020 | WO | 00 |
