1. Field of the Invention
The invention relates to a connecting arrangement for connecting a fiber composite component to a second component.
Furthermore, the invention relates to a method for producing such a connecting arrangement.
2. Discussion of Background Information
The combination of fiber composite components of any shape and size that are made of a fiber composite material with components made of other fiber composite materials or of non-fiber composite materials such as metal or plastic is well known.
As is known, the connection of fiber composite components of any shape and size that are made of a fiber composite material with components made of other fiber composite materials or of non-fiber composite materials such as plastic or metal or metallic structures is realized mainly by means of gluing, screw or rivet connection or by sewing. Connections of fiber composite components with components made of other plastics or fiber composite materials are mostly glued.
The publication DE 102 38 669 A1 describes a three-dimensional component which consists of a first component made from a metallic material connected to a component made from a fiber composite material. The disadvantage of such connections for which gluing has been used is often an insufficient or unreliable cohesiveness of the connection.
Connections of materials such as duraplastic fiber composite components with a thermoplastic component are very difficult to realize as well. The cohesiveness achieved is generally not satisfactory.
The production of screw and rivet connections of these components is also time-consuming and costly. Notably, a special connection component is needed for the production of these screw and rivet connections for the provision of which a separate production process is necessary and which has to be inserted during a further production stage. This has a strong influence on the manufacturing time and cost of the connection. In addition, this kind of connections is generally material-intensive, and despite this fact, a weakening of the material of the components, in particular of the fiber composite material of the fiber composite component can be observed.
The publication DE 196 08 127 A1 describes a method for the production of a three-dimensionally formed fiber composite component for which unformed layers of fiber are sewn together with local reinforcement parts such as metallic fixing components to form a planar, integral semi-finished fiber product. This semi-finished product is then formed into the three-dimensional component geometry and consolidated in a molding tool under the influence of pressure and heat.
The disadvantage of the connection of semi-finished fiber products by sewing is that separate machinery is needed for this production step and the sewing process is very time-consuming and costly. The sewing thread is an additional material which can influence the quality of the connection in an uncontrolled manner. Possible imperfections of the seam can represent a danger for the safety of the connection.
The invention has therefore the objective to create a low-complexity, cost-effective and high-strength connection between a component of fiber composite material and a second component of another fiber composite material or a non-fiber composite material and to provide a cost-effective process for the production of such a connection.
The objective according to the invention is achieved through a connecting arrangement with the characteristics of patent claim 1. The second component—which consists of another material than the fiber composite component—has hereby at least one flat section with one or more cut-out(s) which pass through the flat section. And this flat section is placed between at least two sublayers of the fiber composite component and at least one of these sublayers is moulded into the cut-out(s).
This solution creates a form fit of the fiber composite component with the second component. The form fit is hereby achieved by undercutting at least one of the two sublayers of the fiber composite component which lies flat against the second component in the area of the cut-out(s) of the second component. The embossment(s) or cut-out(s) of the adjoining sublayer and the connection of the two sublayers of the fiber composite component result in a secure and firm hold of the connection that has been formed once the fiber composite component is finished and hardened.
The invention is designed in such a way that there is a choice of undercutting both sublayers of the fiber composite component that lie flat against both sides of the second component in the area of the cut-out(s) of the second component. This would then create a double-sided form fit of the fiber composite component with the second component.
The form-fit connection of the flat sections of these components improves the quality of the connection of the component considerably without making additional special connecting elements or additional glues necessary.
The invention provides a solution for the objective through a method for producing this connecting arrangement with the features of patent claim 9.
According to the invention, the method in accordance with patent claim 9 suggests that
The form fit and, if possible, also substance-to-substance bond between the fiber composite component with at least two sublayers and the second component is achieved through the enclosing of the flat section of the second component by the upper and lower sublayer of the fiber composite component. The form fit connection is created between the upper and lower sublayer in the area of the cut-out(s) of the second component.
During the forming process of at least one sublayer of the pre-form of the fiber composite component, the form fit connection is achieved in the shape of embossments in the sublayer(s) which are realised by means of a molding tool in the cut-out(s) of the second component which is inserted into the molding tool at the same time.
The connection is created simultaneously with the molding of the fiber composite component. This minimises the necessary production steps for the creation of the connecting arrangement.
In one process step the fiber composite component is formed and connected to the second component during which an undercut is created in the transition area between the embossment of the sublayer(s) and the second component. Preferably, the forming of the sublayers of the fiber composite component happens in the presence of or by adding matrix material with the result that the excess matrix material fills the remaining cavities of the undercut connection. The excess matrix material serves as filler material and contributes additionally to the stability of the connecting arrangement once the material is hardened.
During the consolidation of the pre-form of the fiber composite component that has been connected to the second component, i.e. during the setting or hardening process of the fiber composite material, the matrix material is carried over into a solid state and at the same time the two sublayers in the area of the cut-out(s) are fixed form-fit and preferably glued in one of the joint contact areas. During the consolidation and in the presence or by adding matrix material, one of the two sublayers can be glued to the second component at least in the flat border area around the cut-out.
The process according to the invention reduces the auxiliary materials and the necessary production steps for the production of the connecting arrangement, as no additional drilling, riveting or sewing is required due to the form fit and possibly also the substance-to-substance bond created. Despite the saving of special connecting elements and the corresponding production steps, an advantageous, high-strength connection between the components is achieved.
Preferably, a form fit connecting arrangement that is inherently stable is created already during the pre-form stage and can be removed from the molding tool before the consolidation. This reduces the production time in the molding tool and increases the utilisation rate of the molding tool.
After a positive further development of the method according to the invention the high-strength connection of the connecting arrangement between the fiber composite component and the second component can be realised by means of two parts of the tool. One or both tool surfaces for the molding of the sublayer(s) can be built inherently stable or unstable. The shape of the embossment in the sublayer(s) can be varied by means of different designs of the molding tool or the parts of the tool.
Further positive designs and further developments of the connecting arrangement and the production method according to the invention can be seen in the dependent claims and also in the descriptions and the associated drawings.
The connecting arrangement and the method for its production according to the invention are explained in more detail with the help of application examples below. The attached drawings show in a stylised presentation in
The flat section 3 of the metallic component 2 has a cut-out 6 in the shape of a hole 6 with a round hole cross-section that passes through the component 2. The diameter of the hole dHole of the cut-out 6 in the application example is clearly larger than the thickness SM of the flat section 3 of the metallic component 2. The upper and the lower sublayers 4, 5 that are made of fiber composite material lie against an upper surface and a lower surface respectively of the flat section 3 of the metallic component 2. The upper as well as the lower sublayers 4, 5 of the fiber composite component 1 are moulded into the cut-out 6 and have embossments 7, 8 with a round cross-section which correspond to the form of the cut-out 6. In addition, the shape of the embossments 7, 8 of the upper and lower sublayers 4, 5 is determined by the thickness SM of the flat section 3 of the metallic component 2 and the layer thickness SF of the sublayers 4, 5 of the fiber composite component 1.
The embossments 7, 8 of the sublayers 4, 5 overlap in the area of the cut-out 6. The sublayers 4, 5 of the fiber composite component 1 are very stable and form-constant as an end product, which leads to a form-fit connection between the fiber composite component 1 and the metallic component 2. In the application example the embossments 7, 8 of the sublayers 4, 5 reach so far into the cut-out 6 that a common contact area 9 is formed and the cut-out 6 is enclosed completely.
The embossments 7, 8 of the upper and lower sublayers 4, 5 are, in addition, designed in the same way and reach approximately as deep, so that they form a mirror-symmetric arrangement and shape in the cut-out 6.
The connecting arrangement as shown in
The ring-shaped hollow space 10 which appears in the border area between the embossments 7, 8 of the upper and lower sublayers 4, 5 and the cut-out 6, is filled with the filler material 11, in particular with excess matrix material or other glue. In the hardened state of the filler material 11, the sublayers 4, 5 of the fiber composite component 1 are glued to each other and to the metallic component 2. This means that there is a substance-to-substance bond in addition to the form-fit connection between the fiber composite component 1 and the metallic component 2. The hardened filler material 11 in the ring-shaped hollow space 10 increases also the stability of the embossments 7, 8 of the upper and lower sublayers 4, 5 in the area of the cut-out 6 and supports therefore the form-fit connection. The hardened filler material 11 contributes therefore positively to the stability of the connecting arrangement in many ways.
In contrast to the connecting arrangement of
Accordingly, the connecting arrangement of
The realization of the embossment only in one sublayer—in the application example in the upper sublayer 4—reduces the pre-processing time and cost with respect to the shaping of the opposite layer, here the lower sublayer 5.
In addition, the lower sublayer 5 does not need to be as mouldable as the upper sublayer 4 which has to be mouldable in order to achieve the complete embossing depth.
The connecting arrangement of
On the one hand, the sublayers 4, 5 are additionally connected to each other in the contact area 9 by means of excess matrix material or other glue. On the other hand, there is an adhesion surface 12 in the border area around the cut-out 6 on the upper surface of the flat section 3 of the metallic component 2, on which the upper sublayer 4 of the fiber composite component 1 is additionally bonded substance-to-substance with the metallic component 2.
The extra substance-to-substance bonding increases the stability of the connecting arrangement further.
Alternatively, an advantageous connecting arrangement with an asymmetrical embossment shape of the sublayers 4, 5 of the fiber composite component 1, which has not been shown, is planned. Hereby, the upper and lower sublayers 4, 5 have dissimilar embossments 7, 8 with especially different depths.
This connecting arrangement can be created by using upper and lower sublayers 4, 5 which consist in different mouldable, textile semi-finished products.
In a third application example as in
The connecting arrangement of
The fiber composite component 1 also has a straight component edge 15 which, in the application example, runs parallel with the component edge 14 of the metallic component.
Between the component edge 15 of the fiber composite component 1 and the component edge 14 of the metallic component 2 there is a linear overlap area 16 with a width lO, in which the flat border area of the metallic component 2 is covered on both sides by the upper and lower sublayer 4, 5 of the fiber composite component 1 (see
The upper and the lower sublayers 4, 5 of the fiber composite component 1 have each several embossments 7, 8 that correspond to the number, direction and shape of the cut-outs 6. The embossments 7, 8 of the upper and lower sublayer 4, 5 reach approximately equally deep into the cut-outs 6, thus forming a mirror-symmetrical embossment form P1 of the sublayers 4, 5 in the cut-outs 6. The high number of cut-outs 6 and embossments 7, 8 that are arranged at equal distance from each other and correspond to each other enhance considerably the quality of the form-fit connection between the fiber composite component 1 and the metallic component 2.
In the overlap area 16, an adhesion surface 12 is available on the upper and the lower sides of the flat section 3 of the metallic component 2 for a material connection of the metallic component 2 with the upper and/or lower sublayer 4, 5 of the fiber composite component 1. The linear overlap area 16 stretches with such a width lO that a sufficiently large adhesion surface 12 is guaranteed for the adhesive bond. A width of lO of the overlap area 16 that is greater than the double of the dHole diameter of the hole (1Ü>2×dHole) has proven particularly advantageous.
The upper and the lower sublayer 4, 5 of the fiber composite component 1 are additionally connected materially in the area of all cut-outs 6 as well as beyond the component edge 14 of the metallic component 2 (cf.
In the ring-shaped hollow spaces 10 of the cut-outs 6 as well as in a longitudinally orientated hollow space 17 which is situated in the border area between the component edge 14 of the metallic component 2 and the upper and lower sublayer 4, 5, is filled up with filler material 11 according to the description of
With this application, a high-strength form-fit and firmly bonded connecting arrangement has been realized.
In contrast to the application as shown in
The application arrangement as described in the fourth application example has a rivet-like metallic component 2′, a so-called Bighead 2′, which includes a circular disc-shaped, rotationally symmetrical section 3′ and a bar-shaped section 20. The Bighead 2′ serves in the application example as shown in
The upper and lower sublayer 4, 5 of the fiber composite component 1 has a round opening with a circumferential edge 23. In the overlap area 16 of the upper and lower sublayer 4, 5 with the circular disc-shaped section 3′ of the metallic component 2′, the sublayers 4, 5 have each eight embossments 7, 8 that correspond to the arrangement and form of the holes 6. The embossments 7, 8 of the upper and lower sublayers 4, 5 reach all equally far into the holes 6, so that they form a mirror symmetrical embossment form P1 of the sublayers 4, 5 in the holes 6 (cf.
The top view as shown in
The Bighead 2′ that is integrated into the circular disc-shaped section 24 of the fiber composite component 1′ analogously with the connecting arrangement as shown in
A circular cut-out 6 with a diameter of the hole dHole was first drilled into the flat section 3 of the metallic component 2 which is to be connected to the fiber composite component 1.
For this application example, the starting products for the pre-form of the fiber composite component 1 are two sublayers 4, 5 made of so-called “organic sheet”. The organic sheets are flat sheets made of thermoplastic material (e.g. PP-polypropylene, PA-polyamide or the like), which are provided with a mesh reinforcement (e.g. carbon or fiber glass). These organic sheets are first made mouldable. To this effect, the matrix material contained in them is melted e.g. by means of thermal radiation under an infrared field and converted into a liquid or highly viscous state of aggregation (not shown).
After that, the flat section 3 of the metallic component 2 is positioned between the two heated pre-form sublayers 4, 5, in such a way that the cut-out 6 of the metallic component 2 is situated in an overlap area 16 of the sublayers 4, 5 of the fiber composite component 1, and the two sublayers 4, 5 lie flat against the flat section 3.
After having been prepared in this way, the arrangement of the pre-form of the fiber composite component 1 and the flat section 3 of the metallic component 2 are placed between the—preferably cold—tool parts 27, 28.
The upper and the lower tool parts 27, 28 of the molding tool 26 have each a dimensionally stable tool surface 29, 30 with each a nub 31, 32 which are of equal size and form and pointing towards each other. The nubs 31, 32 correspond to the form of the cut-out 6 of the metallic component 2 and are therefore of round shape with a certain nub diameter dNub.
For the production of connecting arrangements with several cut-outs 6 in the flat section 3 of the metallic component 2, a suitable molding tool (not shown) with 6 correspondent nubs depending on the number, arrangement and shape of the cut-outs shall be provided.
The prepared pre-form of the fiber composite component 1 with the flat section 3 of the metallic component 2 is positioned between the tool parts 27, 28 in such a way that the cut-out 6 is placed centrically to the nubs 31, 32.
When the forming tool 26 is closed during the production phase as shown in
The shape of the embossments 7, 8 in the sublayers 4, 5 of the fiber composite component 1 and with it that of the nubs 31, 32 of the tool parts 27, 28 depends significantly on the layer thickness sF of the sublayers 4, 5, the thickness sM of the flat section 3 of the metallic component 2 and on the shape and size of the hole 6 in the metallic component 2. This means, the diameter of the nubs 31, 32 dNub with reference to the diameter of the hole dHole should preferably not be larger than the diameter of the hole dhole minus the double layer thickness sF of the sublayers 4, 5 (dNub≤dHole−2×sF). This serves to largely avoid fiber damage in the formed fiber composite component 1.
During the production phase as shown in
The two embossments 7, 8 of the sublayers 4, 5 are made so deep that they touch and form a contact area 9. In order to be able to create this contact area 9 of the embossments 7, 8 of the sublayers 4, 5, it is an advantage if the diameter of the hole dHole of the cut-out 6 is not made wider than the thickness sM of the flat section 3 of the metallic component 2.
In addition, the nub diameter dNub and consequently the diameter of the hole dHole of the cut-out 6 should be so wide that a sufficiently large adhesion surface 12 is available in the contact area 9 between the embossments 7, 8 of the upper and the lower sublayer 4, 5.
As an alternative to the application example in
The alternative method has the advantage that the molding tool 26′ is more cost-effective. The production of tool part 28′ used with an even tool surface 33 costs less time and effort and the allocation of the tool parts 27′, 28′ to each other is simpler. Apart from that, the method illustrated by
In
Already during the closing of the tool parts 27, 28 in the production phase shown in
Preferably, the matrix material 11 is cooled down even quicker by an additional permanent cooling of the two tool parts 27, 28, so that the consolidation is sped up.
After the forming and consolidation process, the connecting arrangement is kept in the molding tool 26 as long as it takes for the sublayers 4, 5 of the fiber composite component 1 to cool down enough to be able to remove the bonded components 1, 2 from the opened tool parts 27, 28 without damaging them while retaining the shape of the connecting arrangement. This production phase is shown in
This process can be carried out with little effort and is based on the use of simple tools and few technical aids. The result of this process is the creation of an effective form fit and substance-to substance bond between the fiber composite component 1 and the metallic component 2 and therefore the achievement of a high-strength connection between the components 1, 2.
A further essential advantage of this process according to this application example is that selected areas that need to be connected (contact area 9 between the sublayers 4, 5 to each other and adhesion surfaces between the sublayers 4, 5 and the flat segment 3 of the metallic component 2) can be heated up even before the forming and cooled down already during the forming process. As a result, particularly short cycle times can be achieved for the production of the connecting arrangement.
The process described above and as shown in
In a first process variant, the flat section 3 of the metallic component 2 is placed between two dry mesh sublayers 4′, 5′ of a pre-form of the fiber composite component, using an infiltration process. The connecting arrangement prepared in this way is then positioned immediately between the tool parts 27, 28. When the two tool parts 27, 28 are closed according to
In a second process variant, pre-impregnated mesh sublayers 4″, 5″ of a pre-form of the fiber composite component 1 are used, applying a “prepreg method”. These contain already a matrix material 11, e.g. a thermosetting two-component mixture, which is provided in a frozen state (at ca. −18° C.) and becomes mouldable and consolidable only under application of heat.
After arranging the flat section 3 of the metallic component 2 and the two pre-impregnated mesh sublayers 4″, 5″ next to each other, the positioning of the arrangement between the two tool parts 27, 28 is carried out immediately according to
At a temperature that is favourable to the thermosetting matrix material 11, the fiber composite material of the pre-impregnated mesh sublayers 4″, 5″ is made mouldable. This can be brought about either by tempering the mesh sublayers 4″, 5″ at room temperature or by heating the tool parts 27, 28 or by means of a special heating unit 37 that shall not be described here. By using heated tool parts 27, 28, the complete fiber composite structure of the sublayers 4″, 5″ is heated. This means that the forming of the sublayers 4″, 5″ and the creation of the bond happen at the same time.
The thermosetting two-component mixture that was frozen at the start is melted by the tempering or heating. When the tool parts are closed, pressure is applied and the mesh sublayers 4″, 5″ are moulded in the cut-out 6. The chemical reaction of the matrix material 11 that starts at the same time makes the matrix material pass on into a solid state of aggregation and consolidate. In addition to this, one or both tool parts 27, 28 can be cooled during this phase of the production. After the consolidation has taken place, the finished Connecting arrangement can be removed from the mould.
The heating unit 37 for the heating of the pre-impregnated mesh sublayers 4″, 5″ can be installed upstream of the tool parts 27, 28, so that the areas of the mesh sublayers 4″, 5″ can be inserted between the tool parts 27, 28 already preheated. A more detailed description of such a heating unit 37 can be seen in
In order to avoid repetition we shall describe below only the features and components that are different from the process shown in
In contrast to the process shown in
A prepared arrangement consisting of the pre-form of the fiber composite component 1 with two sublayers 4, 5 and the flat section 3 of the metallic component 2 that is positioned in-between, is placed between the tool parts 28′, 27″ (
At the start of the subsequent molding process as shown in
As a result of the pressurization, the pressure foil 34 rests against the upper sublayer 4 of the prepared pre-form of the fiber composite component 1 with the flat section 3 of the metallic component 2, whilst the lower tool 28′ with the inherently stable even tool surface 33—resting against the lower sublayer 5—creates the counteracting force. Due to the pressurisation of the pressure foil 34, the fiber composite material of the upper sublayer 4 is moulded against the flat section 3 of the metallic component 2 and into the hole 6 in the flat section 3. This leads to the creation of an embossment 7′ of the upper sublayer 4 the dimensions of which depend on the form and width of the hole 6 and on the thickness sF of the sublayer 4 and the thickness sM of the flat section 3 of the metallic component 2.
When the matrix material 11 involved is consolidated and has passed from a liquid into a solid state of aggregation, the pressure in the pressure pillow 35 can be reduced until the pressure pillow 35 is depressurised. Then the tool parts 28′, 27″ can be opened, the pressure foil 34 can be removed and the completed connecting arrangement withdrawn (
The method that uses tool parts 27″ with an inherently unstable tool surface 34 has the advantage that the pressure pillow 35 adapts always to the shape and depth of the cut-out 6 at hand. This means that it is not necessary to provide costly milled molding tools which reproduce each of the nubs required for each possible application. This reduces the cost of the production of the molding tools considerably.
In an alternative process variation of the above process shown in
Once the prepared arrangement consisting of a pre-form of the fiber composite component 1 and the flat section 3 of the metallic component 2 that is positioned in-between, has been placed between the tool parts 28″, 27″, the pressure foil 34 which surrounds the arrangement to be connected is joint together pressure-tight with the lower tool part 28′. Then an all-sided pressure is produced on the pressure foil 34 and the lower tool part 28′ by the autoclave, which pushes together the upper tool part 27″ with the pressure foil 34 and the lower tool part 28′ with the even tool surface 33 and the arrangement to be connected is pressed in analogously with the application example described above in
If a tempering of the sublayers 4, 5 is planned, the temperature in the autoclave and with it the temperature of the tool parts 28′, 27″ can be increased parallel to the pressure increase.
After the matrix material 11 involved has consolidated, the pressure and the temperature in the autoclave can be decreased, the pressure foil 34 can be removed and the finished connecting arrangements can be withdrawn.
The production plant 36 has a heating unit 37 for the local preheating of the sublayers 4, 5, preferably the sublayer 4 and a molding tool 26′ which is positioned downstream of the heating unit 37. As shown in
The production plant 36 comprises the flat border area of the metallic component 2 which has several cut-outs 6 which are arranged in a line and at equal distance of each other, according to the connecting arrangement to be joined together as shown in
Whilst, according to
The preheating of the sublayer 4 accelerates the subsequent forming process in the molding tool 26′. In addition, the inline production of preheating and forming of sublayer 4 leads to a significant minimisation of the clock cycle for the complete procedure.
The heating unit 37 works preferably with the help of ultrasound, microwave, contact heat or infrared radiation, which makes a directed, local heating up of the area of sublayer 4 that is to be moulded possible. The process of making sublayer 4 mouldable is carried out precisely and very fast, which leads to a saving of energy and further minimisation of the clock cycle of the procedure.
As soon as it has left the molding tool 26′, the form-fit and firmly bonded connection can cool down and harden completely at the first joint, while in the closed molding tool 26′ at the second joint a further form-fit and firmly bonded connection is moulded and glued in the asymmetrical embossing mould P2. Parallel, the sublayer 4 is preheated at the third joint in the area of the third cut-out that is to be moulded.
The pulsing of the procedures is repeated practically continuously until all cut-outs 6 of the longitudinally orientated, flat border area of the metallic component 2 have been connected with the fiber composite component 1 in the way described above.
Number | Date | Country | Kind |
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102011120360.9 | Dec 2011 | DE | national |
Filing Document | Filing Date | Country | Kind |
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PCT/DE2012/100372 | 12/7/2012 | WO | 00 |
Publishing Document | Publishing Date | Country | Kind |
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WO2013/083124 | 6/13/2013 | WO | A |
Number | Name | Date | Kind |
---|---|---|---|
4613393 | Cattanach | Sep 1986 | A |
4891176 | Drysdale | Jan 1990 | A |
20040119188 | Lowe | Jun 2004 | A1 |
20040130072 | Sekido | Jul 2004 | A1 |
20040197534 | Miller | Oct 2004 | A1 |
20050269016 | Oldani | Dec 2005 | A1 |
20060266713 | Gearhart | Nov 2006 | A1 |
20090278371 | Fuchs | Nov 2009 | A1 |
20130122246 | Berger | May 2013 | A1 |
Number | Date | Country |
---|---|---|
644411 | Jul 1984 | CH |
19608127 | Sep 1997 | DE |
19922799 | Nov 2000 | DE |
10238669 | Mar 2004 | DE |
0254363 | Jan 1988 | EP |
1995040 | Nov 2008 | EP |
2783195 | Mar 2000 | FR |
2004020912 | Mar 2004 | WO |
2005054018 | Jun 2005 | WO |
Entry |
---|
Gardiner, G., “Thermoformable Composite Panels”, available on-line at https://web.archive.org/web/20110813010236/http://www.flexformtech.com/News/pdfs/Composites-World-Thermoformable-Composite-Panels.pdf, published on-line Mar. 7, 2011. |
Machine translation of French Patent Publication No. FR-2783195A1, originally published Mar. 2000, 17 pages (Year: 2000). |
Machine translation of German Patent Publication No. DE-19922799A1, originally published Nov. 23, 2000, 15 pages (Year: 2000). |
Number | Date | Country | |
---|---|---|---|
20140352880 A1 | Dec 2014 | US |