Patent Application
20200400371
The invention relates to a cooling system, preferably for use in or including a refrigeration plant and/or a liquefier plant, having a refrigeration circuit. The invention further relates to a method for producing a refrigerant usable in a refrigeration circuit.
Refrigeration plants, configured to achieve very low temperatures of 80 K or below, typically use hydrogen or helium as a refrigerant. An industrial hydrogen liquefaction plant is known from EP 3 163 236 A1, in which a hydrogen gas stream is cooled my means of a plurality of closed-loop cooling cycles to a temperature below a condensation point of hydrogen so as to provide a liquid hydrogen stream.
Refrigeration plants, adapted for temperatures below 80 K, usually apply a Brayton cycle or a Claude cycle with compression of the refrigerant at ambient temperature, heat exchange and refrigeration via expansion. The refrigerant is compressed via a screw type compressor, piston compressor or turbo-compressor. The turbo-compressor is favorable in view of efficiency, flow rate capacity and reliability.
If temperatures below 54 K need to be achieved, only hydrogen, helium, neon or mixtures thereof are applicable, because other fluids would freeze at such very low temperatures. Generally speaking, helium used in refrigeration plants is more efficient than neon. On the other hand, compression of helium and hydrogen via turbo-compressors is difficult or requires a large number of compression stages due to the low molecular weight of the hydrogen. The molar weight of neon, however, is larger than that of helium and hydrogen. Thus, neon is advantageous in view of compression when used in combination for instance with helium and/or hydrogen.
Such alternative refrigerants have been investigated, and it was found that mixtures of helium and neon, called “nelium”, allow processes with higher efficiency compared to pure neon; see Hans Quack, Christoph Haberstroh, Ilka Seemann, Marcel Klaus, “Nelium, a refrigerant with high potential for the temperature range between 27 and 70 K”, Physics Procedia 67 (2015) 176-182.
The industrial application of neon mixtures with helium and/or hydrogen in refrigeration plants (in particular of large scale) involves a number of technical and economic challenges.
Helium is obtained from a different plant via a second process line 110 which is locally separated from the first process line 100. Usually the helium is obtained and separated from natural gas, to which contains helium at a proportion of 1% or more, within a fractionating column 111. Helium is extracted and accumulated within a subsequent process stage 112 and thereafter stored in a helium-storage 113. The pure neon stored in the neon-storage 103 and the pure helium stored in the helium-storage 113 are mixed according to a desired ratio and supplied to a refrigeration plant 120.
Helium and neon, as well as mixtures thereof are rather expensive gases. Pure neon is considerably more expensive than helium and not available everywhere. Moreover, refrigeration systems are not completely leak-proof. Considerable quantities of the product may get lost especially during maintenance work. This implies substantial initial, operating and maintenance costs. Moreover, the technology and logistics are complicated. Helium is usually extracted from natural gas. Neon is separated from air by applying a complex process. Thus, both gases are usually extracted, transported and delivered separately and only subsequently mixed to be used in a refrigeration circuit or refrigeration plant.
To maintain the required characteristics in the refrigeration circuit or refrigeration plant, the mixture, particularly the ratio of neon and helium, has to be monitored and adjusted, which additionally implies technical challenges and costs regarding the analysis and gas management system.
It is an object of the present invention to provide a cooling system and a method for producing a refrigerant which solves or reduces at least one of the above mentioned problems.
The object is solved with a cooling system having the features of claim 1 and a method having the features of claim 9. Preferred embodiments are given by the dependent claims, the description and the drawings.
According to a first aspect of the invention, there is provided a cooling system including a refrigeration circuit configured to use a refrigerant including a mixture of helium and neon; wherein the refrigerant is based on a raw mixture, preferably the refrigerant comprises the raw mixture, and wherein the raw mixture extracted from air by an air separation plant.
The cooling system is preferably adapted for use in or including a refrigeration plant and/or a liquefiers. This for instance includes refrigeration plants for cooling high-temperature superconductors, precooling in refrigeration plants (e.g. shield cooling in particle accelerators) and liquefiers, particularly helium or hydrogen liquefiers, etc.
The cooling system according to the invention has a refrigeration circuit configured to use a refrigerant including a mixture of helium and neon. Preferably, the mixture comprises helium, neon and hydrogen. The refrigerant is based on a raw mixture, preferably is the raw mixture, including helium and neon, extracted from air by an air separation plant. Preferably, the cooling system has the air separation plant configured to extract from air the raw mixture including helium and neon. In other words, both components—helium and neon—are extracted from the air.
The extraction is preferably done by the same process and/or simultaneously such that after the process the raw mixture is present without any further processing. In particular, the raw mixture to be used as the refrigerant is provided by extracting it as such from air but not by supplying it by mixing two or more gases which are provided in separate processes or extracted from different raw materials such as air and natural gas.
Preferably, the raw mixture including helium and neon is extracted from air in rectification columns of the (cryogenic) air separation plant. The air separation plant may be locally separated from the refrigeration circuit. Further, the raw mixture may be extracted at any time and stored until usage. According to the invention, the raw mixture ex is directly used as the refrigerant or forms the basis of the refrigerant. In other words, the raw mixture including helium and neon (possibly as well as other components) is used as the refrigerant with or without further treatment, such as cleaning.
Importantly, the raw mixture including helium and neon is extracted from the air via the air separation plant. This helps solving the problem of availability and reduces technical complexity and costs as compared to the conventional processes for extracting helium and neon separately and subsequently mixing the two components. The logistics for obtaining the refrigerant is simplified since the desired raw mixture is provided via “one source”, i.e. air as the source not for the individual components but the raw mixture itself.
Preferably the raw mixture further includes nitrogen and/or hydrogen. A certain amount of nitrogen and/or hydrogen is permitted depending on the intended cooling temperatures. Maintaining nitrogen and/or hydrogen in the raw mixture and preferably also in the refrigerant helps further reducing the technical complexity, because the extracted raw mixture may be used without further treatment, particularly without purification, for instance in an adsorber. Hydrogen, which is present in ambient air in a concentration of usually 0.4 ppm, may be present in the raw mixture and/or refrigerant corresponding to the amount of 2% or below. Thus, the raw helium-neon mixture produced from the column(s) of the air separation plant (typically consisting of neon, nitrogen, helium and hydrogen) can directly be used without any further treatment in the refrigeration circuit preferably configured for cooling temperatures below 80 K to approximately 63 K (triple point of nitrogen).
Preferably, the cooling system further includes a purification device configured to remove impurities, to for example nitrogen, from the raw mixture. This provides a refrigerant suitable for lower cooling temperatures such as below 80 K, preferably below 70 K, to approximately 25 K. “Impurities” in this connotation are to be understood to refer to the components not desired in a refrigerant for a particular application but which are inherently included to the raw mixture in the process used to extract the raw mixture.
Preferably, the air separation plant is configured to extract the raw mixture from ambient air, wherein the raw mixture includes a neon/helium-ratio which is approximately equal to the neon/helium-ratio included in the ambient air, preferably of approximately 3.5. In this very preferred case of maintaining the natural ratio of neon and helium (present in a ratio of approximately 3.5 in ambient air), which is constant worldwide, there is no need for technical solutions regarding the mixture and management of the raw mixture and/or refrigerant. The logistics for obtaining the refrigerant is further simplified.
Preferably the refrigeration circuit is configured to implement a Brayton cycle or a Claude cycle which are particularly suitable for producing cryogenic refrigeration temperatures.
Preferably the refrigeration circuit includes one or more turbo-compressors. The refrigeration circuit for instance involves the compression, preferably in one or more turbo-compressors, the cooling, expansion and warming-up of the refrigerant mixture. The mixture including neon has a low freezing point and a high molar mass compared to pure helium and hydrogen. The mixture is therefore particularly advantageous with respect to turbo-compressors.
Preferably the cooling system is configured such that neither helium nor neon included in the raw mixture, preferably also in the refrigerant, is added by a source different from the air separation plant. Moreover, the helium and neon are preferably extracted from air together as if they were a single component. This further reduces technical complexity and costs and further simplifies the logistics for obtaining the refrigerant.
According to the invention, a method for producing a refrigerant usable in a refrigeration circuit, for instance as described above, is provided. The method comprises extracting a raw mixture including helium and neon from air and obtaining the refrigerant from the raw mixture.
The technical effects, preferred or optional features as well as technical contributions and advantages described with respect to the cooling system similarly apply to the method for producing the refrigerant.
A cooling method according to the invention utilizing the refrigerant as described above comprises: a process or method for producing the refrigerant according to the description above; and circulating the refrigerant in a refrigeration circuit, preferably used in or including a refrigeration plant and/or a condenser.
The technical effects, preferred or optional features as well as technical contributions and advantages described with respect to the cooling system similarly apply to the cooling method.
The present disclosure will be more readily appreciated by reference to the following detailed description when being considered in connection with the accompanying drawing.
In the following, preferred embodiments of the invention will be described with reference to the drawings. Elements that are identical, similar or have an identical or similar effect are provided with the same reference numerals in the figures. Repeating the description of such elements may be omitted in order to prevent redundant descriptions.
As has been discussed above,
It is proposed to use the mixture of helium and neon as a refrigerant preferably at a ratio as found in the ambient air (approximately 3.5). This advantageously implies that the mixture is provided by the air separation plant 2 without further treatment. The mixture is typically regarded as a waste product due to missing applications. The ratio between neon and helium is almost constant due to the natural occurrence in ambient air. Since an enormous technical effort is required to obtain pure neon from air, only a small number of air separation plants worldwide are operated to separate and accumulate neon from air. Thus, directly utilizing the “waste” helium-neon mixture supplied by the air separation plant 2 drastically reduces costs and technical equipment for obtaining the refrigerant.
The raw helium-neon mixture may be used as a refrigerant for cooling temperatures below 80 K to approximately 25 K. In this case the cooling system may be equipped with a purification device 3 or absorber stages configured to remove impurities (mainly nitrogen but also other impurities). Alternatively the raw helium-neon mixture, which is extracted from the column(s) of the air separation plant 2, i.e. typically a mixture of helium, neon, nitrogen and hydrogen, may be directly used as a refrigerant. The helium-neon mixture of neon, nitrogen, helium and hydrogen can be used in a refrigeration circuit 1 of a cooling system adapted for cooling temperatures below 80 K to 63 K (triple point of nitrogen). A small proportion of hydrogen does not interfere with the operation of the cooling system in the proposed temperature range above 25 K.
The raw mixture obtained from the rectification column(s) of the air separation plant 2 is used as a refrigerant (or basis for a refrigerant) for instance in a refrigeration circuit of a refrigeration plant and/or a liquefier. In particular, the raw mixture may be used in a low-temperature refrigeration circuit including expansion turbine(s) (Brayton circuit) and/or in a low-temperature refrigeration circuit including expansion turbine(s) and at least one further expansion stage for instance including an expansion valve or expansion device (Claude circuit).
In the following, cooling systems according to different embodiments applying the process and mixture described herein are described with respect to the
The refrigerant, preferably a mixture of helium, neon, nitrogen and hydrogen, is compressed via compressor 11, preferably configured as a turbo-compressor, and subsequently pre-cooled in a cooler 12 and heat exchanger 13a, preferably configured as a plate heat exchanger. Thereafter, the refrigerant is expanded via an expansion device 14. The expansion device 14 preferably includes a turbine or a number of turbine-stages. The work of the expansion is used to cool and/or liquefy an object 20 or fluid. The refrigerant is then heated in heat exchanger(s) 13a, 13b and supplied to the suction side of the compressor 11.
The helium-neon mixture as used in a process and refrigeration circuit 1 as illustrated in
The raw helium-neon mixture is compressed via compressor 11, preferably configured as a turbo-compressor, and subsequently pre-cooled in the cooler 12 and heat exchanger 13a, preferably configured as a plate heat exchanger. Thereafter, the raw helium-neon mixture is expanded via an expansion device 14a and expansion valve (Joule-Thomson valve) 14b. The refrigerant expanded in the expansion device 14a is used to further cool a partial flow of the refrigerant. Further, the raw helium-neon mixture is purified in an adsorber tank 15. In particular, nitrogen is separated from the raw helium-neon mixture. The refrigerant is cooled down in heat exchangers 13b, 13c and released in the expansion valve 14b. The work of the expansion is used to cool and/or liquefy object 20 or to fluid. The refrigerant is then heated in the heat exchanger(s) 13a, 13b, 13c and supplied to the suction side of the compressor 11.
The exemplary process illustrated in
The raw helium-neon mixture is purified in the purification device 3 by separating nitrogen. The resulting helium-neon-hydrogen mixture can then be used as a refrigerant in the refrigeration circuit 1″ as illustrated in
Possible applications for the helium-neon mixture extracted from the rectification column(s) of the air separation plant 2 include refrigeration plants for cooling of high-temperature superconductors (HTS, High Temperature Superconductor cooling) regarding temperatures below 80 K. Further applications include: precooling in refrigeration plants (e.g. shield cooling in particle accelerators) and liquefiers, particularly helium or hydrogen liquefiers. The refrigerant and process may be used in refrigeration plants adapted for cooling temperatures between 25 K and 80 K, preferably between 30 K and 75 K.
According to the described embodiments, an air separation plant 2 is directly used for producing the refrigerant or a raw mixture including helium and neon. This solves the problem of availability and reduces technical complexity and costs as compared to the conventional processes which are based on separately extracting helium and neon and subsequently mixing the two components.
In the preferred case of maintaining the natural ratio of neon and helium of approximately 3.5 which is present in ambient air and which is constant worldwide, there is no need for technical solutions regarding the mixture and management of the composition. The logistics for obtaining the refrigerant is simplified since the desired mixture is provided via “one source”, i.e. air as the source not for the individual components but the resulting mixture. It is possible to compress the raw helium-neon mixture via a turbo-compressor including a small number of compressor stages.
Adding or maintaining a slight amount of hydrogen (usually 0.4 ppm in ambient air) corresponding to 2% or below in the helium-neon mixture is possible. Thus, the raw helium-neon mixture produced from the column(s) of the air separation plant (typically consisting of neon, nitrogen, helium and hydrogen) can directly be used without any further treatment in a refrigeration circuit configured for cooling temperatures below 80 K to approximately 63 K (triple point of nitrogen).
It will be obvious for a person skilled in the art that the embodiments and items only depict examples of a plurality of possibilities. Hence, the embodiments shown here should not be understood to form a limitation of these features and configurations. Any possible combination and configuration of the described features can be chosen according to the scope of the invention.
| Number | Date | Country | Kind |
|---|---|---|---|
| 1803389.4 | Mar 2018 | GB | national |
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/EP2019/054634 | 2/25/2019 | WO | 00 |
