Patent Application
20140009838
This invention relates generally to decorative films having unique appearances, with particular application to such films that incorporate Fresnel lenses. The invention also relates to associated articles, systems, and methods.
About 200 years ago, French physicist Augustin-Jean Fresnel is said to have developed thinner, lighter lenses for use in early 19th century lighthouses. We refer to these lenses today as Fresnel lenses. Since that time, Fresnel lenses have been used in a multitude of applications to provide focusing of light in a thinner and lighter form than could be provided by a bulk optical lens.
We have developed a family of decorative articles in which at least two optical films are combined in a stack, each film having a structured surface with facets that define a plurality of Fresnel lenses that extend parallel to an in-plane axis. The optical films are rotated relative to each other such that first and second in-plane axes of respective first and second optical films are not parallel to each other. The stack may also include one or more diffusers and/or indicia. The Fresnel lenses provide the article with a 3-dimensional appearance. The combination of the differently oriented Fresnel lens films produces visually distinctive decorative patterns.
In addition to the stacked configuration, optical films having the extended Fresnel lenses may be used individually, and optionally in combination with one or more other components that may not be or comprise another Fresnel lens film. The extended Fresnel lenses in the optical film may be arranged in a pattern of alternating focusing and defocusing Fresnel lenses which may be contiguous with each other. The structured surface defining the Fresnel lenses may have transmissive facets arranged in a cyclic (e.g. sinusoidal) slope sequence from substantially zero to a maximum positive slope to substantially zero to a maximum negative slope and back to substantially zero, the sequence repeating over some or all of the structured surface. Distinctive decorative patterns can be obtained by combining the optical film with indicia that may be fixed in position relative to the optical film with a light-transmissive plate or window. The plate may have a thickness tailored so that an axial distance from the Fresnel lenses to the indicia satisfies a given relationship relative to a focal length or distance of the Fresnel lenses.
We describe herein, inter alia, film stacks that include a first film having first transmissive facets formed thereon that define first Fresnel lenses, and a second film having second transmissive facets formed thereon that define second Fresnel lenses, the second film being disposed to intercept light transmitted by the first Fresnel lenses. Each of the first Fresnel lenses extend generally parallel to a first in-plane axis, and each of the second Fresnel lenses extend generally parallel to a second in-plane axis that is non-parallel to the first in-plane axis. The stack may also include a diffuser disposed to scatter light transmitted by the first and/or second Fresnel lenses. The diffuser may, similar to an indicia layer, be printed on another layer in a spatially uniform manner or according to a desired spatial pattern.
The diffuser may have a haze in a range from 10% to 90%. In some cases, the diffuser may scatter light preferentially along a third in-plane axis, and the diffuser may be oriented such that the third in-plane axis is disposed within less than 60 degrees of the first and second in-plane axes. The diffuser may be incorporated into the first film and/or the second film.
The first and second in-plane axes may form an angle in a range from 2 to 90 degrees. The first Fresnel lenses may be characterized by a first average width, and the second Fresnel lenses may be characterized by a second average width different from the first average width. The first Fresnel lenses may be characterized by a first average pitch and the plurality of second Fresnel lenses is characterized by a second average pitch different from the first average pitch. At least some of the first Fresnel lenses, and at least some of the second Fresnel lenses, may be configured to focus incident parallel light. At least some of the first Fresnel lenses, and at least some of the second Fresnel lenses, may be configured to defocus incident parallel light. The first Fresnel lenses may be arranged to alternate between positive Fresnel lenses configured to focus incident parallel light and negative Fresnel lenses configured to defocus incident parallel light. The positive and negative Fresnel lenses may be contiguous to each other. The first Fresnel lenses may each have a length-to-width aspect ratio greater than 10. The first Fresnel lenses may each be straight in plan view, the second Fresnel lenses may also each be straight in plan view, and the first and second Fresnel lenses in combination may produce an undulating pattern in plan view.
Also disclosed are decorative film articles that include a structured surface having transmissive facets formed thereon that are arranged in a slope sequence from a first substantially zero slope to increasingly positive slopes to a maximum positive slope to diminishing positive slopes to a second substantially zero slope to increasingly negative slopes to a maximum negative slope to diminishing negative slopes to the first substantially zero slope. The slope sequence may be substantially sinusoidal, and may repeat in a substantially uninterrupted fashion across some or all of the structured surface, and the transmissive facets may define a plurality of focusing Fresnel lenses alternating with defocusing Fresnel lenses. The facets, the focusing Fresnel lenses, and the defocusing Fresnel lenses may each extend generally parallel to a first in-plane axis.
The Fresnel lenses may each be straight in plan view, or they may each deviate from a straight line in plan view. Each Fresnel lens may define an undulating path. The decorative film article may include a low refractive index planarization layer covering the transmissive facets.
The film article may be combined with indicia, e.g. disposed on a given surface of the article, to produce distinctive visual effects. The indicia may include one or more features that extend generally parallel to a second in-plane axis disposed at an angle relative to the first in-plane axis, the angle being in a range from 2 to 88 degrees. The indicia may be disposed an axial distance D1 from the focusing Fresnel lenses, and at least some of the focusing Fresnel lenses may have focal points disposed at an axial distance D2 from the focusing Fresnel lenses, D1 may be greater than (D2)/10, or in a range from (D2)/3 to D2, or can be greater than D2. In other cases, the indicia may be disposed on, and in contact with, the structured surface of the Fresnel lens film.
The film article may include a diffuser disposed to scatter light transmitted by the focusing and defocusing Fresnel lenses. The film article may include visible light diffractive elements tailored to separate visible light transmitted by the decorative film into its constituent colors to produce a multicolored visual effect, and the visible light diffractive elements may extend generally parallel to a second in-plane axis that is generally parallel to the first in-plane axis.
Related methods, systems, and articles are also discussed.
These and other aspects of the present application will be apparent from the detailed description below. In no event, however, should the above summaries be construed as limitations on the claimed subject matter, which subject matter is defined solely by the attached claims, as may be amended during prosecution.
a is a plan view of the structured surface including Fresnel lenses of
In the figures, like reference numerals designate like elements.
We have found that certain optical films, with certain configurations of Fresnel lenses, can be combined in new and different ways to produce distinctive decorative patterns and visual effects. Two such optical films 112, 162 are illustrated schematically in the side or sectional view of
Films 112, 162 are both Fresnel lens films, because they incorporate structured surfaces whose transmissive facets 116, 166 are arranged in slope sequences that define lenses that focus and/or defocus incident parallel light, such lenses sometimes referred to as positive and negative lenses respectively. The facets 116, 166 are shown in
The optical film 162 is disposed to intercept light transmitted by the optical film 112. Although the films 112, 162 are shown separately, they can be readily combined to form a stack using light-transmissive adhesives or other suitable bonding agents. Such stack may also be applied to a workpiece 105 such as a window, wall, or partition. Preferably, the workpiece 105 is transparent or otherwise light transmissive, such that the visual effects of the Fresnel lenses in the films 112, 162 are more noticeable to a user or observer 139.
The film 112 includes a first layer 113, a second layer 114, an adhesive layer 109, and a release liner 108 which allows the film 112 to be handled before being adhered to the workpiece 105. A thin layer of prisms (not labeled in
Similar to film 112, the film 162 includes a first layer 163, a second layer 164, and a structured or faceted surface with transmissive facets 166 formed between the first and second layers. Also similar to film 112, a thin layer of prisms (not labeled in
In practice, the films 112, 162 may be manufactured and sold separately to a customer or other user. The user may initially remove the release liner 108 and apply the optical film 112 to the workpiece in a particular orientation. Next, the user may wish to evaluate a range of different relative rotation angles of the two films (refer to angle in
The film stack may also include other components or elements such as a diffuser that is disposed to scatter light transmitted by the Fresnel lenses. The diffuser may take the form of a distinct diffuser layer that is added to the films 112, 162, or it may be incorporated into one or more existing layers of one or both of those films. The diffuser may be or comprise a volume diffuser, e.g. a polymer layer within and throughout which particles, voids, or other scattering elements are dispersed, and/or it may be or comprise a surface diffuser such as a textured or otherwise non-smooth surface.
If included in the construction, the diffuser preferably scatters light to a degree that is not too great. If the diffuser scatters light too strongly, it may obliterate the focusing or defocusing characteristics of the Fresnel lenses, and thus eliminate the 3-dimensional appearance of the article provided by the lenses. In some cases, however, some minimal amount of diffusion may be desired to avoid an overly harsh appearance. Light scattering can be characterized by quantities known as haze, transmission, and clarity. For light that is normally incident on an article, film, or layer, the haze may, unless otherwise indicated, refer to the ratio of the transmitted light that deviates from the normal direction by more than 4 degrees to the total transmitted light. The optical haze value can be measured by any suitable means, e.g., using a Haze-Gard Plus haze meter, available from BYK-Gardner, Columbia, Md.
Diffusers may be categorized as symmetric (or isotropic) diffusers or as asymmetric (or anisotropic) diffusers. Symmetric diffusers scatter a normally incident collimated light beam into a scattered beam whose divergence angle is substantially the same along all in-plane directions. We have found that for symmetric diffusers, a haze level in a range from 0 to 90%, more preferably 20% to 80%, provides an appropriate amount of light diffusion in typical cases. An asymmetric diffuser scatters a normally incident light preferentially along a particular in-plane direction, referred to as a scattering axis. Such a diffuser may be oriented such that the scattering axis is not perpendicular to any Fresnel lens elongation direction in any of the optical films in the stack. Preferably, the scattering axis is oriented to be parallel to, or at least roughly aligned with (e.g. at an angle of less than 60, 45, 30, or 20 degrees), the direction of elongation of the Fresnel lenses in one or both optical films. In this manner, the asymmetric diffuser can provide the article with a softer (hazier) appearance with less disruption of the focusing or defocusing characteristics of the Fresnel lenses, which focusing or defocusing occurs in a plane perpendicular to the elongation axis of the lens. We have found that for asymmetric diffusers, a haze level in a range from 0 to 99% can provide an appropriate amount of light diffusion in typical cases. If light diffusion is provided in the form of a separate diffuser layer, the transmission of such a layer is preferably greater than 50% over some or all of the visible light spectrum. The clarity of a diffuser is often not critical for films or layers that are in contact or close proximity to each other, and thus may be tailored as desired, or left unspecified. When an asymmetric diffuser is used with two Fresnel lens films whose axes of prism elongation are not parallel to each other, the preferred orientation of the scattering axis of the asymmetric diffuser is between the prism elongation axes of the two Fresnel lens films, and preferably halfway between the two prism elongation axes.
Another factor that affects the appearance of such a film stack is the relative spacing or pitch of the different sets of Fresnel lenses.
For simplicity, we assume the Fresnel lenses in the back film have a uniform center-to-center spacing or pitch p1. We also assume for simplicity that the Fresnel lenses in the front film have a uniform center-to-center spacing or pitch p2. Fresnel films with uniform spacing are convenient to work with because they can be cut or otherwise converted into any desired size or shape without concern for where the cut should be made on the film. (Fresnel lens films with nonuniform spacing can, however, also be used.) The values of p1 and p2 may be selected as desired to produce a pleasing visual effect. In some cases p1 may be equal to p2, within manufacturing tolerances. For example, the magnitude of (p2−p1)/p1 may be less than 1%. We have found that particularly interesting visual effects are produced when p1 and p2 are moderately different from each other, e.g., p1/p2 or its reciprocal may be in a range from 1.5 to 3.
Whether or not either set of Fresnel lenses has uniform center-to-center spacings, the pitches p1, p2 may alternatively refer to average values. Thus, p1 may be the average pitch of the Fresnel lenses in the back film, and p2 may be the average pitch of the Fresnel lenses in the front film, and p1 and p2 may be the same or different as set forth above. The Fresnel lenses may also be characterized in terms of their plan-view widths. Such widths are discussed further below in connection with
If desired, the Fresnel films of the film stack may be specifically adapted to adhere to each other in a laminate. In some cases, the Fresnel films of the stack may be sold separately, and applied to each other at any desired orientation (rotation angle) by a contractor, customer, or other end-user.
Turning now to
The article 410 has opposed major surfaces 410a, 410b, which may correspond to a front and back major surface, or vice versa. The first film 412 is located at or near the surface 410b, and includes the first layer 413 and the second layer 414. An interface 415 between these layers is configured as a faceted surface with individual facets 416, 418. The faceted surface can be considered a type of structured surface. The facets 416, 418 are transmissive as well as refractive, as the result of a difference in refractive index between the layers 413, 414. At least the facets 416 are typically substantially flat or planar, and are oriented at a variety of different angles and arranged in a particular sequence, referred to as a slope sequence, such that they collectively form Fresnel lenses 417. The lenses 417 are shown to all have the same arrangement of facets, and are thus assumed to be all of the same type, e.g. they are all focusing-type lenses or defocusing-type lenses. For purposes of this discussion we presume the layer 413 has a greater refractive index than layer 414, in which case the lenses 417 will all be defocusing-type lenses as a result of the configuration of facets 416 shown in
Either one of the layers 413, 414 may be embossed or cast against a suitable structured tool to impart the desired geometry of the faceted interface 415, and the other layer (413 or 414) may be added or coated on later as a planarization layer. For example, in some cases the layer 414 may be formed first by embossing or casting the layer against a structured tool to provide a structured surface, followed by planarizing the layer 414 with the layer 413 such that the structured surface becomes the faceted interface 415. Alternatively, the layer 413 may first be embossed or cast to provide a structured surface, and later the layer 414 may be added as a planarization layer so that the structured surface again becomes the faceted interface 415. In either case, the layers 413, 414 are preferably clear or otherwise suitably light transmissive and of sufficiently different refractive indices so that incident light can be refracted at the interface 415 and pass through the article 410 to the eye of the observer.
In general, the strength or optical power of a Fresnel lens, whether focusing or defocusing, is increased for a given facet geometry if the refractive index difference between the layers in increased, and decreased if the refractive index difference between the layers is decreased. It may be desirable in some cases to design the Fresnel lens film to have a relatively weak optical power, by selecting materials for the first and second layers that have refractive indices close in value. In other cases, it is desirable to design the Fresnel lens film to have a stronger optical power by selecting materials with widely separated refractive indices. From a design standpoint, increasing the refractive index difference also allows a Fresnel lens of a specified focal length or optical power to employ facets with decreased orientations or slopes. Examples of polymer materials that may be used in the light transmissive first and/or second layers include, but are not limited to: high index resins such as those used in prismatic brightness enhancement films made for use in liquid crystal displays, such resins having refractive indices in a range from about n≈1.55 to n≈1.70; ultra low index (ULI) nanovoided materials discussed in patent application publications WO 2010/120864 (Hao et al.) and WO 2011/088161 (Wolk et al.), having refractive indices in a range from about n≈1.15 to n≈1.35; PMMA (n≈1.49); polycarbonate (n≈1.59); silicones (n≈1.4), including silicone adhesives; and fluorocarbon materials (n≈1.35).
Note also that real materials may exhibit a non-negligible dispersion in their refractive indices over the visible spectrum. In some cases, adjacent layers that form the Fresnel prism interface (e.g. layers 113 and 114 in
The article 410 is depicted in the context of a Cartesian x,y,z coordinate system. Preferably, the facets 416 and the Fresnel lenses 417 are linear or otherwise elongated along the y-direction, i.e., they extend along an axis perpendicular to the plane of the drawing. This is shown in the plan view of the article 410 provided in
If desired, the article 410 may also include a diffuser disposed to scatter light transmitted by the Fresnel lenses. From a visual standpoint, the diffuser has the effect of softening or dulling the refraction from the Fresnel lenses to avoid an overly harsh appearance. The diffuser may be incorporated into any one or more of layers 413, 414, 420, or it may be attached to or included within the article 410 as an additional, distinct diffuser layer. The diffuser layer may for example be or comprise a layer of light transmissive matrix material within which is dispersed particles and/or voids to promote scattering of visible light. Suitable particles may include transparent microbeads of suitable size distribution and having a higher or lower refractive index at visible wavelengths than that of the matrix material. The diffuser may be symmetric or asymmetric. If asymmetric, the scattering axis of the diffuser is preferably at least roughly aligned with the elongation axis of the Fresnel lenses, as discussed above. For example, in
The article 410 may also include other layers or components, such as an indicia layer. The indicia layer may be or comprise a base film to which a coating of ink or other suitable material has been printed or otherwise applied to form indicia. The indicia layer may be included in the article 410 so as to intercept light transmitted by the Fresnel lenses 417.
Since the Fresnel structures described herein can be used for decorative applications, indicia can play an important and synergistic role in enhancing the films, film stacks, and film articles for aesthetic purposes. The Fresnel structures provide a basis for interesting and decorative optical effects, and indicia can be added to complement the periodic structure of the Fresnel lens arrays, or alternatively the indicia can be applied to break up the repetitiveness of a periodic lens array. Indicia also provide a convenient means with which to customize a given array of Fresnel lenses. As described elsewhere herein, indicia can be formed using a variety of different techniques, and can be incorporated into or onto one or more constituent layers or surfaces of the articles.
Referring to content and style, the term indicia can include a wide range of types of patterns that can be applied to the decorative films described herein. The indicia can be images of real objects or abstract designs. In order to either complement or break up the periodic appearance of the Fresnel lens arrays, the indicia can alternatively be, for example, known geometric shapes such as lines, rectangles, squares, circles, etc. formed by a non-continuous areal application of printed inks or pigments, diffusers, or the elimination or absence of Fresnel prisms, that are applied in registration with the lens or mirror arrays. The registration can be in terms of distance along the x-axis and the indicia can also be discontinuous along the y-axis. In such cases, the indicia may be tailored to cover less than 10% or less than 25% or less than 50% of the total area of the film in plan view.
In
Other than the change in the Fresnel lens design, the components of article 510 may be similar to, or the same as, corresponding components of article 410. Thus, for example, article 510, which has opposed major surfaces 510a, 510b, includes a first film 512 located at or near the surface 510b, the first film 512 including a first layer 513 and a second layer 514, between which an interface 515 is configured as a faceted surface with individual facets 516. The first film 512, first and second layers 513, 514, and facets 516 may be the same as or similar to first film 412, first and second layers 413, 414, and facets 416, respectively, and the orientation or slope sequence of the facets 516 may be the same as that of facets 416 so as to form defocusing Fresnel lenses 517, assuming the refractive index of layer 513 is greater than that of layer 514. The facets 516 and Fresnel lenses 517 are preferably substantially linear and elongated along the y-axis, analogous to the view of
Similar to the article 410, the article 510 may also include additional layers or elements, such as a diffuser and/or indicia, as discussed elsewhere herein.
In
Other than the change in the Fresnel lens arrangement, the components of article 610 may be similar to, or the same as, corresponding components of article 510. Thus, for example, article 610, which has opposed major surfaces 610a, 610b, includes a first film 612 located at or near the surface 610b, the first film 612 including a first layer 613 and a second layer 614, between which an interface 615 is configured as a faceted surface with individual facets 616. The first film 612, first and second layers 613, 614, and facets 616 may be the same as or similar to first film 512, first and second layers 513, 514, and facets 516, respectively, except that the orientation or slope sequence of the facets 616 is different.
The slope sequence of facets 616 is cyclic, e.g., sinusoidal, such that the facets form focusing lenses 617a that alternate with defocusing lenses 617b. (If the refractive index of layer 614 is greater than that of layer 613, then lenses 617a are defocusing and lenses 617b are focusing.) Evaluating the slope sequence of facets 616 along the interface 615, we see that the slope ranges from a zero slope (e.g. in the center of lens 617b), to increasingly negative slopes, to a maximum negative slope (e.g. at the boundary between lens 617b and 617a), to diminishing negative slopes, to a zero slope (e.g. in the center of lens 617a), to increasingly positive slopes, to a maximum positive slope (e.g. at the boundary between lens 617a and 617b), to diminishing positive slopes, to a zero slope (e.g. in the center of lens 617b). (Note that other descriptions of this slope sequence are also possible by shifting the evaluation region, e.g., the slope sequence can be described as ranging from a first zero slope to increasingly positive slopes to a maximum positive slope to diminishing positive slopes to a second zero slope to increasingly negative slopes to a maximum negative slope to diminishing negative slopes to the first zero slope. A “zero slope” need not be precisely horizontal but may be within a few degrees of horizontal.) Due to the repetitive nature of the shape of the interface 615, this slope sequence may repeat in a substantially uninterrupted fashion across the interface 615.
In this regard,
Referring again to
Similar to the article 510, the article 610 may also include additional layers or elements, such as a diffuser and/or indicia, as discussed elsewhere herein.
Numerous modifications can be made to the articles described herein. For example, a diffuser may comprise multiple distinct layers rather than only one layer. An indicia layer may likewise comprise multiple distinct layers. Alternatively, a diffuser and indicia layer may be combined into only a single layer. If distinct diffusers and indicia layers are provided, they may be arranged in any order relative to the Fresnel lenses. An asymmetric diffuser can be cut into an embossing or casting tool by creating a low amplitude, high frequency undulation of the prism height along the length axis of each prism or portions of the prisms.
In a given embodiment, Fresnel lenses of a given type may be uniformly the same, or they may be different from each other, or they may be some combination thereof. For example, the Fresnel lenses 417 in
The Fresnel lenses need not be precisely linear in plan view. For example, the Fresnel lenses (and the prisms or facets that make up the lenses) may follow paths that are curved, and/or paths that extend generally along a particular in-plane direction but that oscillate (e.g. sinusoidally or in any other periodic or near-periodic fashion) or wander (e.g. characterized by deviations that are low in frequency, small in amplitude, and not periodic) with respect to that direction. Tooling used for embossing or casting/curing (e.g. an embossing drum or casting wheel) can be fabricated with non-linear patterns such as a wandering sand dune appearance. Although this can be accomplished with diamond tooling on a drum using multiple passes with a fast plunging tool, an alternative method is to use gray scale lithography wherein the prisms are created by the variable depth exposure of a photoresist with rastered laser beams. The non-linear patterns can also be achieved by forming pliable prisms on an elastic substrate which can then be non-uniformly stretched in different areas across a surface. Such a construction was made by casting prisms of a pliable resin onto a pliable substrate such as, for example, vinyl, urethane, or silicone films. Pliable Fresnel lenses are also useful when applying the films to non-planar surfaces that are curved along both in-plane axes, i.e., compound curved surfaces. Some examples are lighting fixtures, luminaires, automobile exterior or interior surfaces, computer mouse surfaces and mobile handheld electronic devices such as some phones, notepads or notebook computers.
The Fresnel lenses may have a plan view aspect ratio that is limited only by the outer physical boundaries or edges of the article, i.e., each of the Fresnel lenses may extend from one such boundary or edge to an opposite boundary or edge. Alternatively, the Fresnel lenses may each extend along a particular direction but have a length that is truncated relative to the physical boundaries of the article. When truncated Fresnel lenses are used, it may be desirable for aesthetic purposes to arrange them such that small blank areas (e.g. small flat window areas, characterized by the absence of any tilted or angled prism facets) separate adjacent Fresnel lenses, which small blank areas may be spaced regularly or randomly along a given row of truncated Fresnel lenses. The small blank areas can be achieved in at least two ways. In one case, the metal tool can be cut such that the cutting tool is retracted and does not cut a set of adjacent prisms for a predetermined length on the tool, or the prisms can be later machined flat on the metal tool at the predetermined lengths. Alternatively, if the prisms are cut continuously on a tool, the resulting cast polymer replicate of the tool can be planarized in local areas (corresponding to the small blank areas) by coating (planarizing) the prisms with a second film in those chosen areas. For Fresnel lenses, if a planarizing polymer coating is used, it should be transparent and relatively close to (in comparison to air or ULI material) the refractive index of the prisms, e.g. Δn<0.2. With either method of effectively eliminating prisms in local areas, random or image forming patterns can be made via the absence of a prismatic structure on the film. Such spatial patterns can be considered indicia for the Fresnel films.
Fresnel lenses that are elongated along a particular direction may have a plan view aspect ratio of at least 2, 5, 10, 20, or 50, for example. In some cases, the Fresnel lenses may have circular, square, or other non-elongated shapes in plan view.
Exemplary embodiments of the disclosed articles comprise thin polymer-based films that are laminated, coextruded, and/or coated such that the article is self-supporting, flexible, and conformable to a target surface or object. In this regard, the disclosed articles may be configured such that the back surface of the article attaches to a window, wall, or other object of interest, and light may enter the article through the back surface and exit through the front surface, but light may also or alternatively enter and exit through the front surface. The disclosed articles may include additional layers and coatings to facilitate such applications, including e.g. planarization layer(s), adhesive layer(s), release liner(s), hard coat(s), and the like. Colored and/or neutral gray dyes, pigments, and the like can be added to one or more of the constituent layers for further visual effect. Reflective color films such as multilayer interference films can provide striking visual effects when combined with the Fresnel lens films. Narrow band color mirror films, examples of which can be found in U.S. Pat. No. 6,531,230 (Weber et al.), “Color Shifting Film”, have been found to be particularly attractive in this construction. Narrow band mirrors have a transmission that is high (e.g. greater than 50%) when averaged over the visible spectrum, but a low transmission and high reflectivity (e.g. at least 30, 50, 60, 70, 80, 90, or 95% reflectivity) over a narrow spectral band in the visible, where the narrow spectral band may have a full width at half maximum (FWHM) of less than 150, or less than 100, or less than 70, or less than 50 nm, or in a range from any of these values to 10 nm. When laminated to or otherwise combined with the Fresnel lens films disclosed herein, such narrow band mirrors can produce a colored flash, e.g. of blue, green, or red, at given observation angle. In addition, the appearance is different when viewed from opposite sides of the laminate due to the differing angles of incidence and transmission of light for the mirror film depending on whether the narrow band mirror is in front of or behind the Fresnel lens film, or, whether light passes through the Fresnel lens before or after passing through the narrow band mirror. The disclosed articles may be made of any suitable materials now known or later developed, including materials other than polymer-based films. The articles may include one or more thick and/or rigid and/or brittle component such that the resulting article is rigid rather than flexible.
In cases where a reflective layer has a high reflectivity over a portion of the visible spectrum and a low reflectivity and high transmission over another portion of the visible spectrum, the resulting construction, which can be referred to as a dichroic Fresnel mirror, functions as a Fresnel mirror for those visible wavelengths having a high reflectivity, and functions as a Fresnel lens for those visible wavelengths having a low reflectivity. Dichroic Fresnel mirrors are thus a class or subset of the larger group of Fresnel mirrors.
The appearance of film stacks having misaligned sets of linear Fresnel lenses can be modeled or simulated. The result of one such simulation is provided in
For purposes of
For the simulation, the first Fresnel lens film was represented by a first sine wave of the form
sin(t+2πx),
where
t=3 sin(x2),
and x is the position along the (in-plane) x-axis, which we may assume is the cross-web direction for a polymer film. The second Fresnel lens film was represented by a second sine wave, of the form
sin(2πx′).
Here, x′ is the position along an (in-plane) x′ axis, the x′ axis being rotated relative to the x-axis by an angle, hence:
x′=x cos(φ)+y sin(φ), and
y′=−x sin(φ)+y cos(φ).
The sum of the two functions can be used to simulate the combined appearance of the two functions, i.e., of a first Fresnel lens film and a second Fresnel lens film rotated by an angle:
z=0.2 sin(t+2πx)+0.2 sin(2πx′),
where z in this equation is a measure of the apparent height of a three dimensional surface, but we may also interpret z as representing brightness for purposes of the simulation. If we select the angle to be about 6 degrees, the simulated brightness from the above equations is as shown in
The reader is again cautioned that the z-axis in
Some articles having a decorative appearance were made and evaluated. Each of these articles incorporated at least one linear Fresnel lens film.
In a first example, a film stack was made using two differing Fresnel lens films and a diffuser.
The Fresnel lens films were made by a casting and UV curing process using a metal roll tool that had been diamond turned. Grooves in the metal tool defined two adjacent regions of different sinusoidal groove patterns: a short periodicity pattern and a long periodicity pattern. When this tool was used to cast and cure a prism layer on a film substrate, the grooves produced small linear prisms defining two adjacent regions of the prism layer, each region having parallel linear prisms whose individual prism slopes changed along the cross-web direction in a sinusoidal fashion. In each of the regions, the prisms had a constant pitch (center-to-center prism distance) of 75 microns, and slopes that changed with cross-web direction in a sinusoidal manner, one cycle of each sinusoidal pattern having slopes that ranged from a maximum of +14.3 degrees, then diminishing to substantially zero degrees, then diminishing further to a minimum of −14.3 degrees, then increasing to substantially zero degrees, and then increasing still further back to the maximum of +14.3 degrees. Any given sinusoidal cycle in either of these regions defined a set of one focusing Fresnel lens contiguous to one defocusing Fresnel lens. In the short periodicity region, the period of each one of the sinusoids was 20 mm, and in the long periodicity region the period of each one of the sinusoids was 40 mm. The cross-web width of the short periodicity region was about 23 cm, i.e., 11.5 pairs of the narrower focusing/defocusing linear Fresnel lenses. The cross-web width of the long periodicity region was also about 23 cm, i.e., almost 6 pairs of the wider focusing/defocusing linear Fresnel lenses. In addition to the focusing and defocusing Fresnel lenses within each region being contiguous to each other, the two regions were also contiguous to each other, along a shared linear boundary. The Fresnel lenses in the short periodicity region had a first uniform focal length (magnitude), and those in the long periodicity region had a second uniform focal length (magnitude), the first focal length being about 16 mm and the second focal length being about 35 mm.
Several optical films were made having these Fresnel structures formed in a prism layer atop a flat 2 mil (50 micron) thick PET base film, the prism layer being made of a UV-cured resin of refractive index n≈1.65. The resin was filled with nano-zirconia particles in order to achieve the high index of refraction. Such resin is described for example in U.S. Pat. No. 7,264,872 (Walker, Jr. et al.). The optical films were cut or slit to produce: a first Fresnel lens film whose structured surface was substantially completely characterized by the 40 mm period sinusoid and the wider focusing/defocusing linear Fresnel lenses whose focal length was about 35 mm; and a second Fresnel lens film whose structured surface was substantially completely characterized by the 20 mm period sinusoid and the narrower focusing/defocusing linear Fresnel lenses whose focal length was about 16 mm. An acrylic plate with a soft diffusing surface was also obtained. The acrylic plate had a thickness of 3 mm and a haze of 46%, the haze being substantially symmetric.
For this first example, a film stack was made by placing together in a stack the first Fresnel lens film, the second Fresnel lens film, and the acrylic diffuser plate, with no adhesive between the three components, and with the Fresnel lenses of both optical films exposed to air. The relative orientation of the Fresnel lenses in the two optical films could be changed by rotating one optical film relative to the other, and interesting visual patterns were obtained over a wide range of relative rotation angles.
In a second example, a film stack was made using two similar Fresnel lens films.
For this second example, Fresnel lens films were made in substantially the same way as in the first example, except that the optical films were cut or slit to produce: a first Fresnel lens film whose structured surface was substantially completely characterized by the 20 mm period sinusoid and the narrower focusing/defocusing linear Fresnel lenses whose focal length was about 16 mm; and a second Fresnel lens film whose structured surface was substantially the same as the first Fresnel lens film. The Fresnel lenses on both of these films were planarized with a ULI material of refractive index 1.17, and the planarized films were then laminated together with the prisms of the two films facing inwards, using 3M™ Optically Clear Adhesive 8171. After planarization with the ULI coating, the focal length of the lenses was approximately 30 mm.
The relative orientation of the Fresnel lenses in the two optical films could be changed by rotating one optical film relative to the other before lamination, and interesting visual patterns were obtained over a wide range of relative rotation angles. The stack produced gentle wave-like patterns, similar to
In a third example, the visual appearance of only one Fresnel lens film was evaluated.
For this third example, a Fresnel lens film was made in substantially the same way as in the first and second examples, except that the optical film was cut or slit to produce a Fresnel lens film whose structured surface was substantially completely characterized by the 40 mm period sinusoid and the wider focusing/defocusing linear Fresnel lenses; furthermore, the structured surface, rather than being exposed to air, was planarized with an ultra low index (ULI) coating of refractive index 1.17. The ULI planarization layer caused the focal length of the focusing/defocusing lenses to increase to approximately 60 mm.
Optical films that have alternating focusing and defocusing linear Fresnel lenses, e.g. by utilizing a sinusoidal slope sequence for the prism facets, can also be combined with indicia to provide still more visually interesting products. The most interesting visual effects have been found to occur when the indicia is located at a particular distance or range of distances relative to the Fresnel lenses, which range of distances is related to the focal length or focal distance of the lenses. An exemplary arrangement is shown in
In
In order to maintain a desired distance between the Fresnel lenses (e.g. the structured surface 1215) and the indicia layer 1226, the optical film 1210 and the indicia layer 1226 may be adhered or otherwise attached to opposing major surfaces of a light-transmissive plate 1225 of suitable thickness. The plate 1225 may be window glass, an acrylic partition, or another suitable light-transmissive solid structure. Alternatively, the indicia may be physically separated from the Fresnel lenses by a much larger space, e.g., the indicia may be placed on a wall or other object that is physically distant from, e.g. at least 1 meter from, the Fresnel lenses.
The indicia layer 1226 is preferably at least partially light transmissive, and in some cases it has a high optical transmission over some or all of the visible light spectrum. The indicia layer may be made with a gray scale of black and white inks, and it may also or alternatively be made with colored inks, such as blue, green, yellow, and/or red, and so forth. In other cases, however, it may have a low optical transmission, and it may even be opaque. We have found that several features of the indicia layer 1226 can have a significant impact on the appearance of the construction. One feature is the axial distance from the indicia layer 1226 to the Fresnel lenses. The other feature is the orientation of the indicia layer relative to the Fresnel lenses, particularly when the lenses are elongated along a first in-plane axis and the indicia comprises indicia features that are elongated parallel to a second in-plane axis.
With regard to the distance from the indicia layer to the Fresnel lenses, we have observed that if the indicia layer is placed too close to the prism film, particularly in relation to the focal length or focal distance of the Fresnel lenses, the Fresnel lenses provide little or no visual distortion of the indicia. Little or no distortion in the context of decorative film articles may be considered uninteresting and disadvantageous. For example, if the focal length of the lenses is much greater than the thickness of the optical film 1210, which is typically the case, and the thick plate 1225 is omitted from the construction of
The relative position of the indicia relative to the Fresnel lenses can be quantified by comparing the axial distance D1 from the Fresnel lenses to the indicia layer to a distance associated with the focal length of the Fresnel lenses. The latter focal length-related distance may be complicated by the fact that the actual focal point or focus of a given Fresnel lens is influenced by the optical thickness (physical thickness multiplied by refractive index) of the layer(s) to which it is attached. In the case of the embodiment of
With this background, we can quantify the distance relationships for which we have found the Fresnel lenses to provide significant distortion of the indicia. Noticeable visual effects are observed when D1 is in a range from about D2′/3 to about D2′/10. More interesting visual effects are observed when D1 is greater than D2′/3. Striking visual effects are observed when D1 is greater than D2′/1.5. Therefore, D1 is preferably greater than about D2′/10, or in a range from (D2′)/3 to D2′, or, in some cases, greater than D2′. In many practical embodiments, the difference between D2′ and D2, and between F′ and F, is relatively small. Thus, the foregoing relationships can also be satisfied where D2′ is replaced by D2.
Another feature of the indicia layer 1226 that can have a significant impact on the appearance of the construction is the orientation of the indicia layer relative to the Fresnel lenses, particularly when the lenses are elongated along a first in-plane axis and the indicia comprises indicia features that are elongated parallel to a second in-plane axis. In such cases, the visual appearance can be substantially enhanced by orienting the second in-plane axis to be neither parallel nor perpendicular to the first in-plane axis, but oriented at an angle that is oblique. For example, may be selected to be in a range from 45 to 89 degrees, or from 30 to 89 degrees. The desired value of may depend on the distance D1 described above, but in many cases the effect is attractive if is between 60 and 90 degrees, and causes distortion that is still appealing at angles that are less than 45 degrees but at least about 30 degrees.
The effect of the relative orientation angle and the relative position of the indicia layer were evaluated in connection with a fourth example. In the fourth example, a linear Fresnel lens film was combined with an indicia layer having linear indicia features.
For this fourth example, a Fresnel lens film was made in substantially the same way as in the third example, except that the structured surface of the optical film was not planarized with the ULI coating. This Fresnel lens film thus had a structured surface that was substantially completely characterized by the 40 mm period sinusoid and the wider focusing/defocusing linear Fresnel lenses, the focal length of each of these being about 35 mm. An indicia film was then obtained. The indicia film was an 80 micron thick vinyl film on which was printed simulated wood grain indicia, the vinyl film also being embossed on one side with small elongated depressions similar to wood texture. This indicia film was substantially the same as an indicia film used as a component in simulated woodgrain film products sold more than one year ago in the United States by 3M Company as 3M™ DI-NOC™ Film. The wood-grain indicia features were substantially elongated along a particular in-plane axis.
The Fresnel lens film was held in front of the indicia film and the combination was observed. If the films were oriented such that the wood-grain axis was parallel or perpendicular to the lens axis, little distortion of the wood-grain pattern was observed. Also, if the Fresnel lens film was held too close to the indicia film, little distortion of the wood-grain pattern was observed. More distortion, which produced a visually interesting wavy appearance, was observed when the orientation angle was oblique and when the Fresnel lens film was held at a substantial distance from the indicia film (the films being separated by a thick air gap).
In a fifth example, additional combinations of Fresnel lens films and indicia films, attached to opposite sides of thick acrylic plates, were investigated.
For this fifth example, a Fresnel lens film was made in substantially the same way as in the second example, such that optical film had a structured surface substantially completely characterized by the 20 mm period sinusoid and the narrower focusing/defocusing linear Fresnel lenses. The focal length of the focusing/defocusing lenses was about 16 mm. A sample of 3M™ Fasara™ Decorative Window Film, consisting of straight parallel lines on a transparent film, was used as an indicia layer. A 12 mm thick acrylic plate was then obtained, and the Fresnel lens film and the indicia layer were laminated to the opposed major surfaces of the plate. The Fresnel lens film was oriented such that facets of the Fresnel lenses were exposed to air. Further, the films were oriented such that the elongation axis of the indicia made an angle of about 45 degrees relative to the lens axis. This same construction was repeated for a 6 mm thick acrylic plate, and for a 3 mm thick acrylic plate. A wavy appearance was observed in all three cases, but with diminishing amplitude as the plate thickness diminished from 12 to 6 to 3 mm. The wave amplitude for the 3 mm plate was rather small.
In a sixth example, additional combinations of Fresnel lens films, indicia films, and acrylic plates, similar to those of the fifth example, were investigated.
For this sixth example, the same Fresnel lens film, indicia film, and acrylic plates were used as those of the fifth example, except that the structured surface of the Fresnel lens film was planarized with a ultra low index (ULI) coating, having a refractive index of about 1.18. This increased the focal length of the Fresnel lenses from the original 16 mm to about 30 mm. Three samples were again evaluated, with the Fresnel lens film and indicia film attached to opposite sides of the acrylic plate and oriented at an angle of about 45 degrees relative to each other, and 12 mm, 6 mm, and 3 mm acrylic plates were again used. A wavy appearance was again observed in all three cases, but with reduced amplitudes relative to those of the fifth example. For example, the embodiment in this sixth example using the 6 mm plate had a wave amplitude about the same as the wave amplitude of the 3 mm plate embodiment in the fifth example. For the embodiment in this sixth example using the 3 mm plate, the effect is quite small.
In a seventh example, additional combinations of Fresnel lens films, indicia films, and acrylic plates, similar to those of the fifth example, were investigated.
For this seventh example, a Fresnel lens film was made in a similar way as in the fifth example, except that a different tool was used which produced a different geometry of linear Fresnel lenses in the Fresnel lens film. In this case, the Fresnel lenses were again composed of linear parallel prisms of the same high index (n=1.65) material on the same 50 micron PET base film, and the prisms again had a slope sequence that changed with cross-web direction in a sinusoidal manner, each sinusoidal cycle defining a set of one focusing Fresnel lens contiguous to one defocusing Fresnel lens, and the periodicity of the sinusoids was again 20 mm. However, for this Fresnel lens film, the prism facets were more strongly tilted, such that the slope sequence ranged from a maximum of +26 degrees, then diminishing to substantially zero degrees, then diminishing further to a minimum of −26 degrees, then increasing to substantially zero degrees, and then increasing still further back to the maximum of +26 degrees. These Fresnel lenses had a focal length of about 10 mm.
Similar to the fifth and sixth examples, the Fresnel lens film was then attached to one major surface of an acrylic plate (with prism facets exposed to air), and the indicia film with linear markings was attached to the opposite major surface of the plate, the linear markings of the indicia film oriented at an angle of about 45 degrees relative to the axis of the Fresnel lenses. Acrylic plates of 12 mm, 6 mm, and 3 mm thickness were again used. A significant wavy appearance was observed in all three cases, and the wave amplitudes were greater and more noticeable relative to those of the fifth example for corresponding plate thicknesses.
The Fresnel lens films and combinations thereof described herein can also comprise visible light diffractive elements that are tailored to separate visible light into its constituent wavelengths or colors to produce a multicolored or rainbow-like visual effect. The visible light diffractive elements may comprise grooves, ridges, prisms, or other features sized to provide one or more diffraction gratings. When used with a Fresnel mirror film and/or a Fresnel lens film having linearly extending Fresnel structures (mirrors or lenses, respectively), the diffraction grating(s) may also extend linearly e.g. using straight linear grooves or other diffractive features. The axis of elongation of the diffraction grating(s) may be oriented as desired with respect to the elongation axis of the Fresnel structures of the Fresnel mirror film and/or Fresnel lens film. In some cases, the diffracting grating axis may be substantially parallel to the axis of the Fresnel structures. In some cases, the diffracting grating axis may be substantially perpendicular to the axis of the Fresnel structures. In some cases, the diffracting grating axis may be oriented at an oblique angle relative to the axis of the Fresnel structures.
If a diffraction grating is included, it can be laminated to the Fresnel film, or in the case of the diffractive grooves parallel to the Fresnel prism grooves, the diffractive grooves can be cut directly into the face of some or all of the larger grooves on an embossing/casting tool. In one example, equilateral triangle-shaped prisms (60 degree apex angle) with a 600 nm repeat distance and width were cut into the face of each groove on a copper tool, the copper tool otherwise being substantially the same as that used above for the first example. Thus, the copper tool had 75 micron wide grooves whose groove angles were arranged in a sinusoidal slope sequence having a period of 40 mm, and each groove also included the smaller 600 nm diffractive grooves. The diffractive grooves produced diffractive sub-structures on the Fresnel prisms in replicated polymer films. Brilliant rainbow patterns were observed on both the copper tool and on the cast and cured polymer films made with this tool. The diffractive Fresnel lens film can be combined with other components such as another Fresnel lens film (either with the diffractive features or without) in the same manner as described above.
In some cases, patterned planarization of the faceted or structured surface can be implemented to provide additional visually distinctive features to the disclosed films and combinations. For example, selected portions of the structured surface can be image-wise coated with a polymer material or other suitable material whose thickness is great enough to planarize the structured surface. In the resulting product, Fresnel lenses may be formed everywhere on the structured surface except for the selected portions that had been planarized by the image-wise coating, or Fresnel lenses may be formed in the selected portions but with substantially diminished optical power due to a substantially diminished refractive index difference on opposite sides of the structured surface, compared to the refractive index difference for the remainder (non-image-wise coated portions) of the structured surface. The absence of Fresnel lenses (or reduced Fresnel lens power) in the selected portions provides a noticeable image that can add to the visual distinctiveness of the article. The image-wise coating can have any desired image or pattern. Such spatial patterns, formed by planarizing the prisms with index matching or near-matching materials in selected areas, can be considered indicia for the Fresnel films.
We have observed that, for the purpose of forming an image, the image forming planarizing material can but need not precisely match the refractive index of the prisms. Rather, it may only have a refractive index that is substantially different than that of the material (or air) in contact with the remaining portions of the prism surfaces. For example, an adhesive of refractive index 1.49 was laminated in small circular areas on a sinewave Fresnel lens surface whose prisms had a refractive index n=1.65. The remainder of the lens surface was in contact with air. Even though the adhesive did not match the refractive index of the Fresnel prisms, the mismatch or difference in refractive index between the adhesive and the prisms was much less than the mismatch or difference in refractive index between air and the prisms for the remainder of the structured surface, which was sufficient to render the circle patterns clearly observable. When used in a laminate, the remainder of the prism surface can be planarized by coating with a ULI material or other material having a refractive index substantially different than the image forming planarizing layer. The image-wise coating can be a patterned adhesive layer that is used to bond the Fresnel film to a surface or to another Fresnel film in the absence of a low index planarization layer. In this manner, the remainder of the Fresnel prism surface remains in contact with air after lamination.
The transparent image-wise planarization pattern can be formed with clear, or color tinted, adhesives, post-curable polymeric layers, epoxies, or printing inks, using any suitable printing technique such as flexographic, gravure, screen, or ink jet.
Unless otherwise indicated, all numbers expressing quantities, measurement of properties, and so forth used in the specification and claims are to be understood as being modified by the term “about”. Accordingly, unless indicated to the contrary, the numerical parameters set forth in the specification and claims are approximations that can vary depending on the desired properties sought to be obtained by those skilled in the art utilizing the teachings of the present application. Not as an attempt to limit the application of the doctrine of equivalents to the scope of the claims, each numerical parameter should at least be construed in light of the number of reported significant digits and by applying ordinary rounding techniques. Notwithstanding that the numerical ranges and parameters setting forth the broad scope of the invention are approximations, to the extent any numerical values are set forth in specific examples described herein, they are reported as precisely as reasonably possible. Any numerical value, however, may well contain errors associated with testing or measurement limitations.
Various modifications and alterations of this invention will be apparent to those skilled in the art without departing from the spirit and scope of this invention, and it should be understood that this invention is not limited to the illustrative embodiments set forth herein. For example, the disclosed transparent conductive articles may also include an anti-reflective coating and/or a protective hard coat. The reader should assume that features of one disclosed embodiment can also be applied to all other disclosed embodiments unless otherwise indicated. It should also be understood that all U.S. patents, patent application publications, and other patent and non-patent documents referred to herein are incorporated by reference, to the extent they do not contradict the foregoing disclosure.
