This application claims priority under 35 U.S.C. §119 to German Patent Application DE 10 2009 030 468.1, filed Jun. 2, 2009. The contents of this applications is hereby incorporated by reference in its entirety.
The disclosure pertains to optical devices for optical spectrometry, with a reference surface, a light source for illuminating a sample position and for illuminating the reference surface, a spectrally resolving detector (spectrometer), an optical deflector upstream from the input of the detector, a measuring beam from the sample position to a first input of the deflector and a reference beam from the reference surface to a second input of the deflector, wherein the deflector can be switched between a first position for the coupling of the measuring beam onto the detector input and a second position for the coupling of the reference beam onto the detector input, and mechanical switches for the setting of one of at least two defined switching positions of a movable part exhibiting a motor and a stop for the movable part for the definition of the first switching position, with a first permanent magnet being attached to the movable part. The spectrally resolving detector may be designed as a single-channel or simultaneous multi-channel scanner.
Optical spectometry is used to characterize the spectral reflecting power or transmission capability of measuring objects across a certain wavelength range of interest, in which one or multiple reflectivity and/or transmission intensity spectrums are captured in the form of a so-called radiation function. The radiation function can be used to obtain information about optical as well as non-optical properties of the measuring objects, which can then be used to evaluate the measuring objects in question. In this process, the emission characteristics of the light sources are not constant, due to aging or fluctuations in the supply voltage or the ambient temperature, for example. The spectral response curve of the detectors being used also varies with the ambient temperature and operating time, and so do the analog electronic detection circuits. A spectrometry device therefore can desirably be calibrated in order to obtain reproducible readings. This could also be used to compare the radiation functions of the same measuring object having been measured with two different light sources, for example. The calibration can be performed, for example, using one or multiple reference measuring objects (standards), which may be placed manually or automatically into the path of the measuring beam or alternately with a measuring object onto the sample position. For calibration, the measuring beam is used as the reference beam.
DE 195 28 855 A1 describes a device allowing repeated referencing between the measurements with little effort. For this purpose, a separate reference beam is used and the measuring beam is merged with the separate reference beam via a fiberoptic Y-cable, wherein inside of every branch of the cable is a switchable shutter. The fiberoptic Y-cable with the switchable shutters can be called an “optical deflector”, wherein the cross-section of the joint optical path between the deflector and the spectrometer is divided into the reference beam and the measuring beam. This joint optical path is coupled into the entry opening of the spectrometer. Due to the separate reference beam, the device can be quickly referenced since no reference measuring object desirably is placed into the sample position (internal serial referencing). However, due to the joint feed into the spectrometer by way of a fiberoptic Y-cable, the etendues (collecting powers) of the measuring beam and the reference beam are low since the entry opening of the spectrometer can be utilized only proportionately. A low etendue often involves long integration times, which may lead to an accumulation of errors. Due to the proportionate utilization of the entry opening, the reference light and the measuring light are also distributed inhomogeneously inside the entry opening, which further reduces the accuracy of detection.
An alternative to serial referencing or as an additional measure for the correction of short-term fluctuations of device properties is simultaneous referencing by way of a second spectrometer, as known from DE 100 10 213 A1, for example. In this case, any differences between the measuring and the reference spectrometers desirably is compensated by reference measurements. Although in this case, the etendue is high, there can be the particular drawback of the larger number of desired spectrometers.
A general problem of spectrometric measurements can also be that the radiation functions measured in the form of reflection and/or transmission depend on the optical transmission properties of the detection channels, which vary across the measured wavelengths: For example, the transmission characteristics of optical fibers may change due to mechanical or thermal influences (signal drift), in particular between the time of the reference measurement and time of the actual measurement. Especially problematic can be transmission differences between the measuring beam and the reference beam if they are designed to be separate. These problems exist independently of the reference measurement being performed in serial fashion or simultaneously. The accuracy of the measurements may be affected in any case.
When moving a mechanic component into one or more defined display positions there is the problem of bouncing back from a respective stop. There are various approaches to the debouncing of mechanical switches. Known from DE 25 32 563 A1, for example, is a device where a permanent magnet is attached to a pivoting part of a component, on which by way of two solenoids a switching force is applied to rotate the component between two stops. Here, the solenoids themselves serve as stops. With proper control, the bouncing of the rotating component can be reduced or completely eliminated. However, this device can exhibit the disadvantage that two solenoids are desired, and that a complex control sequence is involved to change the switching position.
The disclosure provides a device of the type described above, which can optionally involve a small number of spectrometers while at the same time allowing referencing and measuring with high accuracy, and to provide a switch of the type described above, allowing low-effort toggling with reduced bouncing into at least one switching position. The disclosure provides a device for optical spectrometry, wherein the reference beam and the measuring beam between the deflector and the detector input, in particular between the deflector output and the detector or between a device connecting the optical paths and the detector exhibit the same (the identical) etendue and the same (the identical) optical axis. This means that they are running longitudinally along the same optical path. For this purpose, the inputs and the output of the deflector may have appropriate coupling optics, for example lenses or optionally imaging mirrors. The etendue of an optical path is defined by the product of the solid angle and cross-sectional surface of the path. If the joint optical path is formed by several optical fibers, the identity of the etendue and the optical axis of every single fiber is desired.
The disclosure is based on the realization that when an optical coupling path to the detector is used, which is identical for the reference and the measuring, the entry opening can be used evenly and nearly to the full extent, so that a maximum etendue is achieved at maximum homogeneity of the transmitted light. This permits short integration times. Furthermore, differences in the transmission of the reference beam and of the measuring beam affecting the accuracy of the measurements are reduced. Especially thermal or mechanical changes affect both optical paths when the optical paths are identical. The disclosure involves only one spectrometer (per spectral range).
The earlier the reference beam and the measuring beam are coupled onto the joint optical path, the greater these advantages will be. The deflector can therefore be positioned directly after the input optics of the measuring beam or only reflectors are positioned between the input optics and the deflector, in particular the inputs of the deflector. The same applies to the reference beam.
Devices in which the measuring beam, in particular also the reference beam, is free of optical fibers can be used. This minimizes thermal and mechanical influences on the measuring accuracy. The device is thermally and mechanically more resilient. There are only small signal drifts in the reference beam and the measuring beam. The device exhibits a continuously high etendue warranting highly accurate readings.
The deflector can be free of optical fibers because when coupled by optical Y-fibers, the fibers for the reference beam and the measuring beam run parallel to the detector, thereby not having the same optical path and exhibiting different optical axes resulting in the described disadvantages of the current the state of the art.
The entire device, including the reference surface (internal referencing) is purposefully enclosed inside a housing against environmental influences; the light from the light source and/or the light from the sample position is able to exit/enter the housing only via one or two windows.
For the compensation of dark currents and sensitivity variations, the reference surface can be referenced as internal white standard on one hand, and as a dark state on the other hand. The internal referencing of the dark state is especially easy if the deflector can be switched into a third position, in which it couples neither the reference beam nor the measuring beam into the detector input. In this position, the detector measures only its dark signals.
In some embodiments, the deflector exhibits a mechanical switch for the setting of the three deflector positions, wherein the switch has a recess, a light-tight first blade and a light-tight and light-absorbing second blade, wherein the recess and the blades can be alternatively moved into the measuring beam by operating the switch. The recess may also be called a gap between the two blades. For this reason, only a single switch is involved to couple the beams into one jointly usable optical path to the detector. The first blade can be mirrored on one side (or equipped with a mirrored part), so that in the positioned state the blade reflects one of the beams to the detector input while blocking the other beam, and the recess lets in the positioned state pass one beam into a light-trap and the other beam to the detector, while the second blade blocks both beams in the positioned state. This allows the switch to have simple design. For example, the blades are configured in a plane such that when the measuring beam and the reference beam are coming in at a right angle to each other, the positioned blade divides the right angle symmetrically. The blades and the recess can be located on the same pivoted part, thus involving only a single drive.
In certain embodiments, the first light input of the deflector has a first switchable optical shutter and the second light input has second switchable optical shutter, and the deflector comprises a beam splitter with a reflectance of less than 100%. This allows the coupling into the jointly used optical path with available, low-cost components. Due to a non-symmetrical divider ratio, the intensity reaching the detector can easily be specified, like based on the type and thickness of an optical coating, for example. In this case, the shutters are part of the deflector and also the inputs of the deflector.
In embodiments of the device, in which the light source, the reference surface, the sample position, the reference beam and the measuring beam are configured such that light from the sample position to the first light input and light from the reference surface to the second light input is conducted simultaneously.
This allows these components to be stationary and drives are not required. Measurement and internal referencing can be selected via the deflector only.
For this purpose, the reference surface and the input optics of the reference beam each are shaded against the light coming from the sample position, in particular by tilting the reference surface toward the light from the sample position and/or by placing the measuring surface and/or the input optics into a recess. This has the advantage that light scattered back from the sample cannot interfere with the reference beam, thus preventing any falsification of the reference and achieving highly accurate readings.
In some embodiments of the device, in which the measuring beam, optionally also the reference beam, as well as the deflector are free of optical fibers, the optical path between the deflector and the detector may advantageously be designed free of optical fibers and the detector may, in addition to spectrally resolving also spatially resolution for at least one dimension. Due to the fiber-free design, the spectrometer can be used to measure multiple points at the sample position along the spatially resolved dimension.
The disclosure provides a mechanical switch, wherein away from the movable part a second permanent magnet is attached such that in the respective switching position opposite magnetic poles of the first permanent magnet and the second permanent magnet are facing each other without touching each other, and which move away from each other every time, the movable part is deflected from the respective switching position. The disclosure comprises in particular a switchable, optical shutter with at least one blade for the blocking of an optical beam, which is either attached to the movable part of such switch or designed together with the switch in one piece.
The configuration of two permanent magnets located at a distance from each other and attracting each other significantly reduces bouncing due to the steep edges of the magnetic potential caused by the high reset forces during deflection. In strong magnets like magnets made of neodymium, for example, the potential at the center is on top of that very low, so that the switching position can be defined with high accuracy.
When the movable part is exclusively pivoted, only a single (bi-directional) drive is involved.
In another switching position, away from the movable part a third permanent magnet may advantageously be attached such that in the respective switching position opposite magnetic poles of the first permanent magnet and of the third permanent magnet are facing each other without touching each other, and which move away from each other every time, the movable part is deflected from the respective switching position. This allows the highly accurate definition of a second switching position. Additional switching positions can be defined accordingly. A step counter and/or one or multiple position sensors can be used to differentiate the individual switching positions. Alternatively, a purely pivoted component with two switching positions could be continuously switched into the same direction, thus toggling between the two switching positions without the need for additional devices.
The disclosure also includes an operating procedure for an inventive device, namely for reference measurements using the reference surface as white standard and the blocked reference beams and measuring beams as a dark state on one hand, as well as for measurements utilizing such referencing, in particular with serial in-between reference measurements, on the other hand.
In the following, the disclosure will be explained based on exemplary embodiments and drawings, in which:
Identical parts are in all drawings indicated by the same numbers.
The lighting unit 3 includes, for example, a halogen lamp 3.3, a reflector 3.2 and optics 3.1 for the collimated lighting of the reference surface 4 and the sample 2 at the sample position. The detector 5 includes input optics 5.1, an entry gap as entry opening 5.2, an imaging grid 5.3, and a two-dimensionally spatially resolving opto-electronic sensor 5.4. From the reference surface 4, a reference beam R passes to the second shutter 6.2, continues focused through the beam splitter 6.3 and the input optics 5.1 to entry opening 5.2, from where incident light from the grid 5.3—under spatial-spectral resolution along a first dimension of sensor 5.4—is mapped onto the sensor 5.4 (here suggested for a single wavelength). A measuring beam M runs accordingly from the sample position (of sample 2) to the first shutter 6.1, continues via the beam splitter 6.3, and on the same optical path as the reference beam R through the input optics 5.1 to entry opening 5.2.
The beam splitter 6.3 is configured at an angle of 45° to the R and M beams, so that it principally connects the R and M beams as a connecting element, and where the reference beam R and the measuring beam M use the same optical path between the deflector 6 and the detector input 5.2. The splitter 6.3 has an asymmetric splitting ratio of 8:92, for example (reference beam to measuring beam). The shutters 6.1, 6.2 can be closed via the control unit 8 alternately or simultaneously, so that only one of the M/R beams reaches the detector 5.
The intensity values are measured as a function of the blocking and unblocking of the M/R transmission paths (beams) as follows, wherein in this embodiment the intensities are spectrally measured and wavelength-dependent:
with:
IW being the intensity of the light reflected by the external white standard 11,
IWi being the intensity of the light reflected by the internal white reference surface 4,
ID being the intensity when the detector surface is not illuminated,
IS being the intensity of the light reflected by the external black standard 12, and
IP being the intensity of the light reflected by the sample 2.
The following applies to the reflected intensities:
I
W
=I·(RF+RW·[1−RF]2)+ID
I
S
=I·(RF+RS·[1−RF]2)+ID
I
P
=I·(RF+RP·[1−RF]2)+ID
I
Wi
=I
i
·R
Wi
+I
D
with
I: Intensity of radiation component A to the external sample position,
Iw: Intensity of radiation component B to the internal reference surface 10,
Rw: Reflectance of the external white standard 11,
Rwi: Reflectance of the internal white reference surface 4,
Rs: Reflectance of the external black standard 12,
RP: Reflectance of sample 2,
RF: Reflectance of the measuring head window 9.
The lighting unit 3, for example, permanently illuminates the reference surface 4 and simultaneously the sample 2. The optical paths M and R permanently capture light from sample 2 (the sample position) and, respectively, from the reference surface 4, guiding it to the deflector 6. For (initial or repeated) internal white referencing, the first shutter 6.1 at the first deflector input is closed and the second shutter 6.2 at the second input is opened (
Regarding the measuring sequence and to determine the reflectance we refer to DE 10 2007 061 213, whose disclosure content shall be included here in its entirety.
Furthermore provided inside the measuring head 1 are fiberoptic cables 14, 15, and 16. Provided upstream from fiberoptic cable 14 is a coupling optic 18 which is positioned to capture the scattered reflection from the internal white surface 4 and to couple it into fiberoptic cable 14. The light that is coupled into fiberoptic cable 14 via coupling optic 18 reaches the light entry side of a shutter 6.2 at the second input of an optical deflector 6 with a mirrored beam splitter 6.3, whose light-exiting side is connected to fiberoptic cable 15 via coupling optic 17. Fiberoptic cable 15 is connected to a first entry gap 5.2 of a spectrometer 5.
Provided upstream from fiberoptic cable 16 is a coupling optic 19 for the capture of light being reflected from the sample position—there either from the white standard 6, the black standard 7 or the surface of the sample 8 located on the sample holder 5—and which enters the measuring head 1 through the measuring head window 9. The light coupled into fiberoptic cable 16 by coupling optic 19 is forwarded inside fiberoptic cable 16 to the light entry side of a first shutter 6.1 at the first input of the deflector 6 and enters through the open first shutter 6.1 from the light-exiting side of the deflector 6 via coupling optic 17 into fiber optic cable 15. The optical path of the measuring beam M between the beam splitter 6.3 and the detector input 5.2 is therefore the same as for the reference beam R.
From
Referencing, calibration and measurement take place as described with regard to
In
The following table provides an overview over possible variations of joint optical path, connecting component in the deflector, selection of the M/R beams, light energy reaching the detector on the selected sample, as well as the type of reference and measuring beam (Position “Off” stands for the blocking of both M/R beams as internal dark state):
Number | Date | Country | Kind |
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102009030468.1 | Jun 2009 | DE | national |