Diffuser for LED light sources

Information

  • Patent Grant
  • 8981405
  • Patent Number
    8,981,405
  • Date Filed
    Monday, April 1, 2013
    11 years ago
  • Date Issued
    Tuesday, March 17, 2015
    9 years ago
Abstract
An LED light source is described. The light source includes an LED and a diffuser. The LED emits a light having a dominant wavelength. The diffuser includes a filler material, which includes particles. The mean diameter of the particles is at least as large as the dominant wavelength of the light emitted by the LED. The particles are configured to scatter the light emitted by the LED.
Description
FIELD OF THE INVENTION

The present invention relates to providing uniformly dispersed light from a light emitting diode (LED) source and to the efficient removal of the heat generated by the LEDs, and more particularly, to the uniform dispersion of the light generated by LEDs in a light source without substantial light loss, in order to provide a uniform illumination surface, and to permit the LEDs to be run at higher power.


BACKGROUND OF THE INVENTION

An LED consists of a semiconductor junction, which emits light due to a current flowing through the junction. A white LED is typically made by using a blue or ultraviolet LED die, and adding a plastic coat to it, the coat containing a phosphor. The phosphor is used to convert the blue or ultraviolet light emitted by the LED die to a spectrum of light that more or less closely resembles white light or blackbody radiation.


At first sight, it would seem that white LEDs should make an excellent replacement for the traditional lighting sources. At equal power, they give far more light output than do incandescent bulbs, or, what is the same thing, they use much less power for equal light; and their operational life is orders of magnitude larger, namely, 10-100 thousand hours vs. 1-2 thousand hours. Similarly, their ultimate efficiency is higher than that of fluorescent tubes, and their lifetime is also substantially longer than that of fluorescent tubes.


However, LEDs have a number of drawbacks that have prevented them, so far, from being widely adopted as traditional lighting sources. One of these is that LEDs are discrete sources of light. They produce intense light within the beam of their output, but dim light outside of that beam. Using multiple LEDs does not fully alleviate this problem, as there are then interference patterns in the light.


In the past, LEDs have had diffusers added to their shells or bodies to spread out the light from the LED as a solution to the point light source problem. Another method has been to roughen the surface of the LED package. Neither of these methods accomplishes uniform light distribution for an LED light source, and may lower luminous efficiency. Methods of accomplishing approximate angular uniformity may also involve partially absorptive processes, further lowering luminous efficacy.


Another drawback with LEDs is that although LEDs require substantially less power for a given light output than do incandescent bulbs, it still takes many watts to generate adequate light for illumination. An LED, being a semiconductor, is nearly a point source of heat, and cannot be allowed to get hotter than a range of approximately 85-150° C. The LED thus has a substantial heat problem.


One possible solution to this heat problem is to use a large metallic heat sink, attached to the LEDs. This heat sink would then extend out away from the bulb, removing the heat from the LEDs. However, this solution is undesirable, because the heat sink may make it difficult for the light source to fit in to the desired form factor.


SUMMARY OF THE INVENTION

This invention has the object of developing a diffuser for LEDs, such that the above-described primary problems are effectively solved. It aims at providing a diffuser that may be attached to an LED light source, the diffuser uniformly distributing the light over the surface of the light source with very little light loss, and also providing a large surface area for heat dissipation. The apparatus includes a sealed panel, preferentially formed of a plastic such as polycarbonate, and a filler material, preferentially formed of a fluid, plastic or gel. The fluid, gel or plastic is designed to either contain, or itself form, a system of Mie scatterers. Additionally, the fluid, gel or plastic is designed to be, or to contain, material that efficiently removes heat from the LEDs and conveys it to a suitable surface for removal.


In accordance with one embodiment, the sealed panel has a rectangular cross-section. The fluid, gel or plastic fills the panel to approximately 70-99%, or as suitable to provide room for thermal expansion. The panel may be built as an integral part of the LED light source assembly, or may be an add-on attached by any of several well-known methods.


In accordance with another embodiment, the fluid, gel or plastic may be distributed in the sealed panel with a non-uniform spatial distribution. This may be used to generate light that is more intense in one direction than another.





BRIEF DESCRIPTION OF THE DRAWINGS

The accompanying drawings are included to provide a further understanding of the invention, and are incorporated in and constitute a part of this specification. The drawings illustrate embodiments of the invention and, together with the description, serve to explain the principles of the invention.



FIG. 1 is a view of a present state-of-the-art LED light source showing the reason for its directionality of light output.



FIG. 2 is a cross-sectional view of light emitted from an LED having Mie scattering from supra-wavelength particles.



FIG. 3 is a cross-sectional view of an LED light source showing the diffuser mounted in front of the LEDs.



FIG. 4 is a cross-sectional view of an LED light source showing a diffuser with non-uniform spatial distribution.





DESCRIPTION OF THE PREFERRED EMBODIMENTS

Reference will now be made in detail to the present preferred embodiments of the invention, examples of which are illustrated in the accompanying drawings. Wherever possible, the same reference numbers are used in the drawings and the description to refer to the same or like parts.


According to the design characteristics, a detailed description of the current practice and preferred embodiments is given below.



FIG. 1 is a view of a present state-of-the-art LED light source 10 showing the reason for its directionality of light output and the construction used for removing heat. As shown in FIG. 1, the LEDs 20 are mounted on a circuit board 30. Since said LEDs are point sources of light, the light emitted from the said LED light source appears concentrated in beams. Said circuit board provides electrical interconnects for the LEDs 20, and may also provide electrical isolation. Wires 50 come from the circuit board to power the LEDs from a power source (not shown). The circuit board 30 is mounted to a heatsink 40, made of a low thermal-resistivity material, whose purpose is to provide a low thermal-resistance path to the ambient for heat generated by the LEDs 20. In the drawing, heatsink 40 has fins 42 protruding from it, but any shape of heatsink may be used.



FIG. 2 shows a cross-sectional view of light emitted from an LED having Mie scattering from a plurality of supra-wavelength particles 70 and an equal scattering of each of the wavelengths 80 according to a further embodiment. Typically, the incoming light 60 will include a plurality of wavelength components, including a wavelength 62 based on the light-emitting material used within the LED. For example, in a typical LED emission spectrum, the wavelength 62 emitted from the LED corresponding to the color blue will be approximately 410 to 450 nm. As shown in FIG. 2, the incoming light 60 impinges on a dispersed set or plurality of particles 70 having an effective diameter 90, wherein the effective diameter 90 is greater than a dominant wavelength 62 of light emitted from the LED. The effective diameter 90 of the dispersed particles 70 are preferably a size one to a few times larger than a dominant wavelength 62 of the light emitting source. For example, for an LED producing a blue light, the dispersed set of particles 70 can be alumina trihydrate having a mean diameter of approximately 1.1 microns. It can be appreciated that any suitable particles having an effective diameter 90, which is greater than the dominant wavelength 62 of the emitting light source or LED and creates Mie scattering can be used. It can be appreciated that the particles need not be spherical, or even approximately spherical, and that other shapes can be used such as disk or rod-shaped particles. This creates the condition for Mie scattering of the incoming light 60, wherein each of the incoming wavelengths 62 are scattered into an outgoing wavelength 80. The transmitted light or outgoing wavelengths 80 are thus dispersed in directions relative to the incoming light 60, without significantly affecting the light intensity.



FIG. 3 is a cross-sectional view of an LED light source 10 showing the diffuser 90 mounted in front of the LEDs. As shown in FIG. 3, the LEDs 20 are mounted on a circuit board 30, and have power wires 50 coming off to their power source, not shown. Placed in front of said LEDs is the diffuser panel 90. Said diffuser panel is shown as being form-fitted to the LEDs 20 and circuit board 30, providing a low-thermal resistance path for the heat both of said LEDs and for the heat of said LEDs being transferred to said circuit board. The heat conducted by the diffuser panel 90 may be transferred to ambient by conduction and radiation from the emitting surface 92. The diffuser panel 90 also spreads out the light from the LEDs 20, producing an approximately uniform light output on the emitting surface 92. It can be appreciated that the diffuser panel 90 need not be rectangular in cross-section, and that other shapes such as disk can be used. It can also be appreciated that the diffuser panel 90 need not have a flat emitting surface, and that other shapes such as hemispherical can be used. It can also be appreciated that the diffuser panel 90 need not be form-fitted to the LEDs 20, but may simply be placed in front of them.


As shown in FIG. 3, the LED light source 10 includes at least one LED, a panel 90 between the at least one LED 20 and a light emission surface of the light source, and a filler material 91 inside the panel 90 to scatter the light from the at least one LED 20. In accordance with one embodiment, the filler material 91 is a poly(acrylamide) hydrogel having a plurality of particles, which have been lightly coated with inorganic particles, such as calcium carbonate.


In accordance with another embodiment, the LED light source 10 includes at least one LED 20, a panel between the at least one LED 20 and a light emission surface of the light source 10, and a filler material 91 inside the panel 90 to scatter the light from the at least one LED 20, wherein the filler material 91 contains small Mie cells plus a second different density component. In accordance with an embodiment, the filler material 91 is comprised of a hydrocarbon-based oil, with said second different density component being composed of water and a small amount of a surfactant. It can be appreciated that the filler material 91 is composed of components that are individually each transparent to light.



FIG. 4 is a cross-sectional view of an LED light source, not shown, showing a diffuser 90 with non-uniform spatial distribution. As shown in FIG. 4, the diffuser 90 has two rectangular areas 94 in which the density of the fluid, gel or plastic filler material is lower than in the other areas 96 of said diffuser 90. The lower density filler material areas 94 may be formed with discrete boxes formed within the diffuser 90, or may simply be modulation in the density of the material used. The effect of the lower density filler material areas 94 is to produce light from those areas that is more direct and intense than in the other areas 96 of the diffuser 90. The other areas 96 produce a more diffuse and less intense light. It can be appreciated that the lower density filler material areas 94 need not be rectangular, and may be of other shapes such as circles and annuli. It can also be appreciated that the filler material may be of uniform density, and only the Mie scatterers may be varied in density.


It will be apparent to those skilled in the art that various modifications and variation can be made to the structure of the present invention without departing from the scope or spirit of the invention. In view of the foregoing, it is intended that the present invention cover modifications and variations of this invention provided they fall within the scope of the following claims and their equivalents.

Claims
  • 1. An LED light source comprising: at least one LED configured to emit a light, wherein the light has a dominant wavelength;a diffuser; andwherein the diffuser comprises a sealed panel having a first side configured to receive the light emitted by the at least one LED and a second side configured to emit light,wherein a filler material is disposed between the first side and the second side of the sealed panel,wherein the filler material is a fluid or gel,wherein the filler material comprises particles,wherein the mean diameter of the particles is at least as large as the dominant wavelength, andwherein the particles are configured to scatter the light emitted by the at least one LED.
  • 2. The LED light source of claim 1, wherein: the diffuser comprises a first area with a first density of the filler material and a second area with a second density of the filler material; andthe first density is not the same as the second density.
  • 3. The LED light source of claim 1, wherein: the diffuser comprises a first area with a first density of the particles and a second area with a second density of the particles; andthe first density is not the same as the second density.
  • 4. The LED light source of claim 1, wherein the particles comprise alumina trihydrate.
  • 5. The LED light source of claim 1, wherein the at least one LED is a blue or ultraviolet LED without a phosphor, and the filler material contains at least one phosphor.
  • 6. The LED light source of claim 1, wherein the filler material is a hydrogel.
  • 7. The LED light source of claim 1, wherein the particles have been coated with inorganic particles.
  • 8. An LED light source comprising: at least one LED configured to emit a light, wherein the light has a dominant wavelength;a diffuser; andwherein the diffuser comprises a poly(acrylamide) hydrogel including particles, and a sealed panel having a first side configured to receive the light emitted by the at least one LED and a second side configured to emit light,wherein a filler material is disposed between the first side and the second side of the sealed panel,wherein the filler material is a poly(acrylamide) hydrogel,wherein the filler material comprises particles,wherein the mean diameter of the particles is at least as large as the dominant wavelength, andwherein the particles are configured to scatter the light emitted by the at least one LED.
  • 9. The LED light source of claim 8, wherein: the diffuser comprises a first area with a first density of the particles and a second area with a second density of the particles; andthe first density is not the same as the second density.
  • 10. The LED light source of claim 8, wherein the particles comprise alumina trihydrate.
  • 11. The LED light source of claim 8, wherein the at least one LED is a blue or ultraviolet LED without a phosphor, and the poly(acrylamide) hydrogel contains at least one phosphor.
  • 12. The LED light source of claim 8, wherein the particles have been coated with inorganic particles.
  • 13. An LED light source comprising: at least one LED configured to emit a light, wherein the light has a dominant wavelength;a diffuser; andwherein the diffuser comprises a sealed panel having a first side configured to receive the light emitted by the at least one LED and a second side configured to emit light,wherein a filler material is disposed between the first side and the second side of the sealed panel,wherein the filler material is a hydrocarbon-based oil,wherein the filler material comprises particles,wherein the mean diameter of the particles is at least as large as the dominant wavelength, andwherein the particles are configured to scatter the light emitted by the at least one LED.
  • 14. The LED light source of claim 13, wherein the diffuser further comprises a surfactant.
  • 15. The LED light source of claim 13, wherein: the diffuser comprises a first area with a first density of the hydrocarbon-based oil and a second area with a second density of the hydrocarbon-based oil; andthe first density is not the same as the second density.
  • 16. The LED light source of claim 13, wherein: the diffuser comprises a first area with a first density of the particles and a second area with a second density of the particles; andthe first density is not the same as the second density.
US Referenced Citations (381)
Number Name Date Kind
3962675 Rowley et al. Jun 1976 A
4025290 Giangiulio May 1977 A
4039885 Van Boekhold et al. Aug 1977 A
4077076 Masters Mar 1978 A
4160929 Thorington et al. Jul 1979 A
4211955 Ray Jul 1980 A
4271458 George, Jr. Jun 1981 A
4289991 Schreurs Sep 1981 A
4290095 Schmidt Sep 1981 A
4325107 MacLeod Apr 1982 A
4336855 Chen Jun 1982 A
4346324 Yoldas Aug 1982 A
4346329 Schmidt Aug 1982 A
4405744 Greinecker et al. Sep 1983 A
4511952 Vanbragt Apr 1985 A
4539516 Thompson Sep 1985 A
4584428 Garlick Apr 1986 A
4611512 Honda Sep 1986 A
4647331 Koury, Jr. et al. Mar 1987 A
4650509 Vanbragt Mar 1987 A
4656564 Felder Apr 1987 A
4658532 McFarland et al. Apr 1987 A
4663558 Endo May 1987 A
4727289 Uchida Feb 1988 A
4728999 Dannatt et al. Mar 1988 A
4840383 Lombardo Jun 1989 A
4843266 Szanto et al. Jun 1989 A
4875852 Ferren Oct 1989 A
4876632 Osterhout et al. Oct 1989 A
4904991 Jones Feb 1990 A
4916352 Haim et al. Apr 1990 A
4942685 Lin Jul 1990 A
4947300 Wen Aug 1990 A
4967330 Bell et al. Oct 1990 A
4994705 Linder et al. Feb 1991 A
5008588 Nakahara Apr 1991 A
5065226 Kluitmans et al. Nov 1991 A
5065291 Frost et al. Nov 1991 A
5075372 Hille et al. Dec 1991 A
5119831 Robin et al. Jun 1992 A
5136213 Sacchetti Aug 1992 A
5140220 Hasegawa Aug 1992 A
5224773 Arimura Jul 1993 A
5237490 Ferng Aug 1993 A
5303124 Wrobel Apr 1994 A
5358880 Lebby et al. Oct 1994 A
5363009 Monto Nov 1994 A
5377000 Berends Dec 1994 A
5405208 Hsieh Apr 1995 A
5433738 Stinson Jul 1995 A
5463280 Johnson Oct 1995 A
5496184 Garrett et al. Mar 1996 A
5514627 Lowery et al. May 1996 A
5528474 Roney et al. Jun 1996 A
5561347 Nakamura et al. Oct 1996 A
5585783 Hall Dec 1996 A
5622423 Lee Apr 1997 A
5630660 Chen May 1997 A
5662490 Ogawa Sep 1997 A
5664866 Reniger et al. Sep 1997 A
5667295 Tsui Sep 1997 A
5684354 Gleckman Nov 1997 A
5685637 Chapman et al. Nov 1997 A
5688042 Madadi et al. Nov 1997 A
5726535 Yan Mar 1998 A
5803588 Costa Sep 1998 A
5807157 Penjuke Sep 1998 A
5813753 Vriens et al. Sep 1998 A
5887967 Chang Mar 1999 A
5890794 Abtahi et al. Apr 1999 A
5892325 Gleckman Apr 1999 A
5899557 McDermott May 1999 A
5905343 McCamant May 1999 A
5929568 Eggers Jul 1999 A
5931562 Arato Aug 1999 A
5931570 Yamuro Aug 1999 A
5936599 Reymond Aug 1999 A
5941626 Yamuro Aug 1999 A
5947588 Huang Sep 1999 A
5952916 Yamabe Sep 1999 A
5963126 Karlin et al. Oct 1999 A
5982059 Anderson Nov 1999 A
5984494 Chapman et al. Nov 1999 A
6003033 Amano et al. Dec 1999 A
6043591 Gleckman Mar 2000 A
6066861 Hohn et al. May 2000 A
6087764 Matei Jul 2000 A
6095671 Hutain Aug 2000 A
6102809 Nichols Aug 2000 A
6120312 Shu Sep 2000 A
6123631 Ginder Sep 2000 A
6147367 Yang et al. Nov 2000 A
6158451 Wu Dec 2000 A
6183310 Shu Feb 2001 B1
6184628 Ruthenberg Feb 2001 B1
6227679 Zhang et al. May 2001 B1
6254939 Cowan et al. Jul 2001 B1
6258699 Chang et al. Jul 2001 B1
6268801 Wu Jul 2001 B1
6273580 Coleman et al. Aug 2001 B1
6276822 Bedrosian et al. Aug 2001 B1
6277685 Lin et al. Aug 2001 B1
6313892 Gleckman Nov 2001 B2
6316911 Moskowitz et al. Nov 2001 B1
6332692 McCurdy Dec 2001 B1
6338647 Fernandez et al. Jan 2002 B1
6357902 Horowitz Mar 2002 B1
6382582 Brown May 2002 B1
6426704 Hutchison Jul 2002 B1
6471562 Liu Oct 2002 B1
6478449 Lee et al. Nov 2002 B2
6480389 Shie et al. Nov 2002 B1
6488392 Lu Dec 2002 B1
6496237 Gleckman Dec 2002 B1
6513955 Waltz Feb 2003 B1
6528954 Lys et al. Mar 2003 B1
6534988 Flory, IV Mar 2003 B2
6541800 Barnett et al. Apr 2003 B2
6547417 Lee Apr 2003 B2
6568834 Scianna May 2003 B1
6582100 Hochstein et al. Jun 2003 B1
6608272 Garcia Aug 2003 B2
6612712 Nepil Sep 2003 B2
6619829 Chen Sep 2003 B1
6626557 Taylor Sep 2003 B1
6639360 Roberts et al. Oct 2003 B2
6655810 Hayashi et al. Dec 2003 B2
6659632 Chen Dec 2003 B2
6685852 Setlur et al. Feb 2004 B2
6709132 Ishibashi Mar 2004 B2
6711426 Benaron et al. Mar 2004 B2
6713961 Honda et al. Mar 2004 B2
6734633 Matsuba et al. May 2004 B2
6741029 Matsubara et al. May 2004 B2
6742907 Funamoto et al. Jun 2004 B2
6746885 Cao Jun 2004 B2
6750824 Shen Jun 2004 B1
6773192 Chao Aug 2004 B1
6789348 Kneller et al. Sep 2004 B1
6791259 Stokes et al. Sep 2004 B1
6791283 Bowman et al. Sep 2004 B2
6793362 Tai Sep 2004 B2
6793363 Jensen Sep 2004 B2
6796698 Sommers et al. Sep 2004 B2
6805461 Witte Oct 2004 B2
6819049 Bohmer et al. Nov 2004 B1
6819056 Lin Nov 2004 B2
6828590 Hsiung Dec 2004 B2
6842204 Johnson Jan 2005 B1
6864513 Lin et al. Mar 2005 B2
6864554 Lin et al. Mar 2005 B2
6881980 Ting Apr 2005 B1
6886963 Lodhie May 2005 B2
6903380 Barnett et al. Jun 2005 B2
6905231 Dickie Jun 2005 B2
6910794 Rice Jun 2005 B2
6911678 Fujisawa et al. Jun 2005 B2
6911915 Wu et al. Jun 2005 B2
6926973 Suzuki et al. Aug 2005 B2
6927683 Sugimoto et al. Aug 2005 B2
6932638 Burrows et al. Aug 2005 B1
6936857 Doxsee et al. Aug 2005 B2
6943357 Srivastava et al. Sep 2005 B2
6948829 Verdes et al. Sep 2005 B2
6956243 Chin Oct 2005 B1
6963688 Nath Nov 2005 B2
6964878 Horng et al. Nov 2005 B2
6967445 Jewell et al. Nov 2005 B1
6971760 Archer et al. Dec 2005 B2
6974924 Agnatovech et al. Dec 2005 B2
6982518 Chou et al. Jan 2006 B2
6983506 Brown Jan 2006 B1
7022260 Morioka Apr 2006 B2
7042150 Yasuda May 2006 B2
7058103 Ishida et al. Jun 2006 B2
D525374 Maxik et al. Jul 2006 S
7073920 Konkle, Jr. et al. Jul 2006 B2
7074631 Erchak et al. Jul 2006 B2
7075112 Roberts et al. Jul 2006 B2
7078732 Reeh et al. Jul 2006 B1
D527119 Maxik et al. Aug 2006 S
7086756 Maxik Aug 2006 B2
7086767 Sidwell et al. Aug 2006 B2
D528673 Maxik et al. Sep 2006 S
D531740 Maxik Nov 2006 S
D532532 Maxik Nov 2006 S
7138666 Erchak et al. Nov 2006 B2
7161311 Mueller et al. Jan 2007 B2
7186016 Jao Mar 2007 B2
7213934 Zarian et al. May 2007 B2
7239080 Ng et al. Jul 2007 B2
7241039 Hulse Jul 2007 B2
7246919 Porchia et al. Jul 2007 B2
7261454 Ng Aug 2007 B2
7264527 Bawendi et al. Sep 2007 B2
7270446 Chang et al. Sep 2007 B2
7288798 Chang et al. Oct 2007 B2
7315119 Ng et al. Jan 2008 B2
7344279 Mueller et al. Mar 2008 B2
7350933 Ng et al. Apr 2008 B2
7367692 Maxik May 2008 B2
7396142 Laizure, Jr. et al. Jul 2008 B2
7489031 Roberts et al. Feb 2009 B2
7513669 Chua et al. Apr 2009 B2
7677765 Tajul et al. Mar 2010 B2
7884544 Takezawa et al. Feb 2011 B2
8154190 Ishii et al. Apr 2012 B2
8552448 Ichikawa Oct 2013 B2
20010008436 Gleckman Jul 2001 A1
20010009400 Maeno et al. Jul 2001 A1
20010019134 Chang et al. Sep 2001 A1
20010026447 Herrera Oct 2001 A1
20010035264 Padmanabhan Nov 2001 A1
20010053077 Anwly-Davies et al. Dec 2001 A1
20020021573 Zhang Feb 2002 A1
20020039872 Asai et al. Apr 2002 A1
20020068775 Munzenberger Jun 2002 A1
20020070449 Yagi et al. Jun 2002 A1
20020085379 Han et al. Jul 2002 A1
20020093287 Chen Jul 2002 A1
20020097586 Horowitz Jul 2002 A1
20020117692 Lin Aug 2002 A1
20020126491 Chen Sep 2002 A1
20020145863 Stultz Oct 2002 A1
20020149312 Roberts et al. Oct 2002 A1
20020153829 Asai et al. Oct 2002 A1
20020154449 Raphael et al. Oct 2002 A1
20020176246 Chen Nov 2002 A1
20020183438 Amarasekera et al. Dec 2002 A1
20020186538 Kase et al. Dec 2002 A1
20030025449 Rossner Feb 2003 A1
20030038596 Ho Feb 2003 A1
20030043579 Rong et al. Mar 2003 A1
20030048632 Archer Mar 2003 A1
20030058658 Lee Mar 2003 A1
20030067265 Srivastava et al. Apr 2003 A1
20030072156 Pohlert et al. Apr 2003 A1
20030079387 Derose May 2003 A1
20030111955 McNulty et al. Jun 2003 A1
20030128629 Stevens Jul 2003 A1
20030142508 Lee Jul 2003 A1
20030164666 Crunk Sep 2003 A1
20030185020 Stekelenburg Oct 2003 A1
20030193841 Crunk Oct 2003 A1
20030201903 Shen Oct 2003 A1
20030214233 Takahashi et al. Nov 2003 A1
20030230045 Krause, Sr. et al. Dec 2003 A1
20030231510 Tawa et al. Dec 2003 A1
20040001338 Pine Jan 2004 A1
20040004435 Hsu Jan 2004 A1
20040004441 Yano Jan 2004 A1
20040007980 Shibata Jan 2004 A1
20040008525 Shibata Jan 2004 A1
20040014414 Horie et al. Jan 2004 A1
20040039274 Benaron et al. Feb 2004 A1
20040039764 Gonikberg et al. Feb 2004 A1
20040056600 Lapatovich et al. Mar 2004 A1
20040085017 Lee May 2004 A1
20040085758 Deng May 2004 A1
20040101802 Scott May 2004 A1
20040105262 Tseng et al. Jun 2004 A1
20040113549 Roberts et al. Jun 2004 A1
20040114352 Jensen Jun 2004 A1
20040114367 Li Jun 2004 A1
20040125034 Shen Jul 2004 A1
20040125515 Popovich Jul 2004 A1
20040127138 Huang Jul 2004 A1
20040179355 Gabor Sep 2004 A1
20040183458 Lee Sep 2004 A1
20040187313 Zirk et al. Sep 2004 A1
20040189262 McGrath Sep 2004 A1
20040190305 Arik et al. Sep 2004 A1
20040201673 Asai Oct 2004 A1
20040207334 Lin Oct 2004 A1
20040208002 Wu Oct 2004 A1
20040211589 Chou et al. Oct 2004 A1
20040217693 Duggal et al. Nov 2004 A1
20040233661 Taylor Nov 2004 A1
20040245912 Thurk et al. Dec 2004 A1
20040257804 Lee Dec 2004 A1
20040264192 Nagata et al. Dec 2004 A1
20050007010 Lee Jan 2005 A1
20050007770 Bowman et al. Jan 2005 A1
20050011481 Naumann et al. Jan 2005 A1
20050015029 Kim Jan 2005 A1
20050018424 Popovich Jan 2005 A1
20050023540 Yoko et al. Feb 2005 A1
20050030761 Burgess Feb 2005 A1
20050031281 Nath Feb 2005 A1
20050036299 Tsai Feb 2005 A1
20050036616 Huang et al. Feb 2005 A1
20050047170 Hillburger et al. Mar 2005 A1
20050052885 Wu Mar 2005 A1
20050057187 Catalano Mar 2005 A1
20050063185 Monjo et al. Mar 2005 A1
20050067343 Zulauf et al. Mar 2005 A1
20050068776 Ge Mar 2005 A1
20050084229 Babbitt et al. Apr 2005 A1
20050099787 Hayes May 2005 A1
20050105302 Hofmann et al. May 2005 A1
20050110191 Lin May 2005 A1
20050110384 Peterson May 2005 A1
20050111234 Martin et al. May 2005 A1
20050117320 Leu et al. Jun 2005 A1
20050127385 Reeh et al. Jun 2005 A1
20050141221 Yu Jun 2005 A1
20050151664 Kolish et al. Jul 2005 A1
20050152136 Konkle, Jr. et al. Jul 2005 A1
20050162864 Verdes et al. Jul 2005 A1
20050174065 Janning Aug 2005 A1
20050174769 Yong et al. Aug 2005 A1
20050174780 Park Aug 2005 A1
20050179358 Soules et al. Aug 2005 A1
20050179379 Kim Aug 2005 A1
20050180136 Popovich Aug 2005 A9
20050180137 Hsu Aug 2005 A1
20050207152 Maxik Sep 2005 A1
20050207159 Maxik Sep 2005 A1
20050217996 Liu et al. Oct 2005 A1
20050224829 Negley et al. Oct 2005 A1
20050230691 Amiotti et al. Oct 2005 A1
20050233485 Shishov et al. Oct 2005 A1
20050237995 Puranik Oct 2005 A1
20050243539 Evans et al. Nov 2005 A1
20050243550 Stekelenburg Nov 2005 A1
20050255026 Barker et al. Nov 2005 A1
20050258446 Raos et al. Nov 2005 A1
20050259419 Sandoval Nov 2005 A1
20050265039 Lodhie et al. Dec 2005 A1
20050270780 Zhang Dec 2005 A1
20050276034 Malpetti Dec 2005 A1
20050276051 Caudle et al. Dec 2005 A1
20050276053 Nortrup et al. Dec 2005 A1
20050276072 Hayashi et al. Dec 2005 A1
20050285494 Cho et al. Dec 2005 A1
20060002110 Dowling et al. Jan 2006 A1
20060007410 Masuoka et al. Jan 2006 A1
20060012770 Dierichs Jan 2006 A1
20060022214 Morgan et al. Feb 2006 A1
20060034077 Chang Feb 2006 A1
20060044803 Edwards Mar 2006 A1
20060050514 Opolka Mar 2006 A1
20060061985 Elkins Mar 2006 A1
20060071591 Takezawa et al. Apr 2006 A1
20060092644 Mok et al. May 2006 A1
20060142946 Goujon et al. Jun 2006 A1
20060145172 Su et al. Jul 2006 A1
20060176699 Crunk Aug 2006 A1
20060187653 Olsson Aug 2006 A1
20060193121 Kamoshita Aug 2006 A1
20060193130 Ishibashi Aug 2006 A1
20060198147 Ge Sep 2006 A1
20060208260 Sakuma et al. Sep 2006 A1
20060226772 Tan et al. Oct 2006 A1
20060227537 Vanderschuit Oct 2006 A1
20060243997 Yang et al. Nov 2006 A1
20060250802 Herold Nov 2006 A1
20060255353 Taskar et al. Nov 2006 A1
20060261359 Huang Nov 2006 A1
20060273340 Lv Dec 2006 A1
20060274524 Chang et al. Dec 2006 A1
20060289884 Soules et al. Dec 2006 A1
20070018181 Steen et al. Jan 2007 A1
20070031685 Ko et al. Feb 2007 A1
20070086189 Raos et al. Apr 2007 A1
20070090391 Diamantidis Apr 2007 A1
20070090737 Hu et al. Apr 2007 A1
20070120879 Kanade et al. May 2007 A1
20070125982 Tian et al. Jun 2007 A1
20070139949 Tanda et al. Jun 2007 A1
20070291490 Tajul et al. Dec 2007 A1
20080013316 Chiang Jan 2008 A1
20080048200 Mueller et al. Feb 2008 A1
20080061687 Cok et al. Mar 2008 A1
20080070331 Ke Mar 2008 A1
20080074032 Yano et al. Mar 2008 A1
20080185600 Thomas Aug 2008 A1
20090001372 Arik et al. Jan 2009 A1
20090256167 Peeters et al. Oct 2009 A1
20090324875 Heikkila Dec 2009 A1
20100177534 Ryu et al. Jul 2010 A1
Foreign Referenced Citations (23)
Number Date Country
1834197 Sep 2006 CN
0658933 Oct 2001 EP
63086484 Apr 1988 JP
7-99372 Apr 1995 JP
10-127789 May 1998 JP
2000-293123 Oct 2000 JP
2001-36148 Feb 2001 JP
3351103 Nov 2002 JP
2004-520613 Jul 2004 JP
2004-341446 Dec 2004 JP
2006-32963 Feb 2006 JP
2009-540558 Nov 2009 JP
10-0693463 Mar 2007 KR
2002056111 Jul 2002 WO
02061805 Aug 2002 WO
2004100213 Nov 2004 WO
2005060309 Jun 2005 WO
2005104247 Nov 2005 WO
2007069119 Jun 2007 WO
2007130357 Nov 2007 WO
2007130359 Nov 2007 WO
2008007232 Jan 2008 WO
2009054948 Apr 2009 WO
Non-Patent Literature Citations (39)
Entry
Office Action received for European Patent Application No. 08842545.9, mailed on Dec. 12, 2013, 5 pages.
Office Action received for Chinese Patent Application No. 200880120370.1, mailed on Mar. 27, 2012, 3 pages. See Statement Under 37 CFR § 1.98(a) (3).
Office Action received for Chinese Patent Application No. 200880120370.1, mailed on Jul. 18, 2013, 7 pages. See Statement Under 37 CFR § 1.98(a) (3).
Office Action received for Japanese Patent Application No. 2010-531020, mailed on May 14, 2013, 4 pages (2 pages of English Translation and 2 pages of Official copy).
Office Action received for Korean Patent Application No. 10-2010-7011289, mailed on Jun. 27, 2014, 7 pages (3 pages of English Translation and 4 pages of KROA).
Office Action Received for Japanese Patent Application No. 2010-531020, mailed on Jul. 29, 2014, 9 pages (2 pages of English Translation and 7 pages of Official Copy).
Office Action received for Chinese Patent Application No. 200880120370.1, mailed on Jan. 30, 2014. (See Communication under 37 CFR § 1.98(a) (3)).
Non Final Office Action received for U.S. Appl. No. 12/299,088, mailed on Jun. 21, 2010, 11 pages.
Office Action received for Chinese Patent Application No. 200780015112.2, mailed on Apr. 8, 2010, 25 pages (9 pages of Office Action and 16 pages of English Translation).
Office Action received for Chinese Patent Application No. 200780015303.9, mailed on Jun. 8, 2010, 8 pages of English Translation.
Office Action received for NZ Patent Application No. 573336, mailed on Apr. 19, 2010, 2 pages.
International Preliminary Report on Patentability received for PCT Patent Application No. PCT/US2007/010467, issued on Nov. 27, 2008, 6 pages.
International Search Report received for PCT Patent Application No. PCT/US2007/010467, mailed on Aug. 27, 2008, 1 page.
International Preliminary Report on Patentability received for PCT Patent Application No. PCT/US2007/010469, issued on Nov. 4, 2008, 12 pages.
International Search Report received for PCT Patent Application No. PCT/US2007/010469, mailed on Aug. 7, 2008, 2 pages.
International Preliminary Report on Patentability received for PCT Patent Application No. PCT/US2008/010713, mailed on Mar. 25, 2010, 6 pages.
International Search Report received for PCT Patent Application No. PCT/US2008/010713, mailed on Nov. 21, 2008, 1 page.
International Search Report received for PCT Patent Application No. PCT/US2009/004662, mailed on Oct. 5, 2009, 2 pages.
International Search Report received for PCT Patent Application No. PCT/US2009/005030, mailed on Nov. 12, 2009, 2 pages.
Ryu et al., “Liquid Crystalline Assembly of Rod-Coil Molecules”, Structure & Bonding, vol. 128, 2008, pp. 63-98.
Non Final Office Action received for U.S. Appl. No. 12/299,049, mailed on Mar. 16, 2012, 11 pages.
Notice of Allowance received for U.S. Appl. No. 12/299,088, mailed on Apr. 3, 2012, 10 pages.
Non Final Office Action received for U.S. Appl. No. 13/059,394 on Jun. 28, 2012, 10 pages.
Non Final Office Action received for U.S. Appl. No. 13/476,986, mailed on Aug. 30, 2012, 10 pages.
Final Office Action received for U.S. Appl. No. 12/299,049, mailed on Sep. 5, 2012, 15 pages.
Extended European Search Report received for European Patent Application No. 08842545.9, mailed on Jul. 26, 2012, 7 pages.
Non Final Office Action received for U.S. Appl. No. 12/299,049, mailed on Jun. 16, 2011, 32 pages.
Final Office Action received for U.S. Appl. No. 12/299,049, mailed on Jan. 4, 2012, 20 pages.
Final Office Action received for U.S. Appl. No. 12/678,287, mailed on Oct. 11, 2011, 7 pages.
Non Final Office Action received for U. S. Appl. No. 12/678,287, mailed on Apr. 19, 2011, 5 pages.
International Preliminary Report on Patentability received for PCT Patent Application No. PCT/US2009/004662, mailed on Mar. 3, 2011, 9 pages.
International Preliminary Report on Patentability received for PCT Patent Application No. PCT/US2009/005030, mailed on Mar. 24, 2011, 9 pages.
Final Office Action received for U.S. Appl. No. 12/299,088, mailed on May 13, 2011, 18 pages.
International Preliminary Report on Patentability received for PCT Patent Application No. PCT/US2008/011984, mailed on May 6, 2010, 5 pages.
International Search Report received for PCT Patent Application No. PCT/US2008/011984, mailed on Jan. 15, 2009, 1 page.
Office Action received for Japanese Patent Application No. 2010-531020, mailed on Dec. 18, 2012, 8 pages (4 pages of English Translation and 4 pages of Office Action).
Non Final Office Action received for U.S. Appl. No. 12/739,944, mailed on May 16, 2012, 8 pages.
Notice of Allowance received for U.S. Appl. No. 12/739,944, mailed on Nov. 26, 2012, 7 pages.
Office Action Received for Canadian Patent Application No. 2,706,975, mailed on Sep. 25, 2014, 2 pages.
Related Publications (1)
Number Date Country
20130214313 A1 Aug 2013 US
Provisional Applications (1)
Number Date Country
60982314 Oct 2007 US
Continuations (1)
Number Date Country
Parent 12739944 US
Child 13854730 US