Digital film processing solutions and method of digital film processing

Information

  • Patent Grant
  • 6733960
  • Patent Number
    6,733,960
  • Date Filed
    Monday, February 11, 2002
    22 years ago
  • Date Issued
    Tuesday, May 11, 2004
    20 years ago
Abstract
An aqueous developer solution for use in digital film processing. The developer solution includes a developing agent and at least one surfactant or thickener. A method of processing a photographic film is also provided, and includes the steps of coating an aqueous developer solution containing at least one surfactant or thickener onto the film, thereby developing the film, and scanning the film through the coating of developer solution.
Description




FIELD OF THE INVENTION




The present invention relates generally to digital film processing systems, and more particularly to a digital film processing solution and method of digital film processing.




BACKGROUND OF THE INVENTION




Images are used to communicate information and ideas. Images, including print pictures, film negatives, documents and the like, are often digitized to produce a digital image that can then be instantly communicated, viewed, enhanced, modified, printed or stored. The increasing use and flexibility of digital images, as well as the ability to instantly communicate digital images, has led to a rising demand for improved systems and methods for film processing and the digitization of film based images into digital images. Film based images are traditionally digitized by electronically scanning a film negative or film positive that has been conventionally developed using a wet chemical developing process.




In a traditional wet chemical developing process, the film is immersed and agitated in a series of tanks containing various processing solutions. The temperature and concentration level of the particular processing solution is strictly controlled to ensure uniformity of the development process. The film is immersed in each tank for a specific period of time.




The various processing solutions are expensive and become contaminated during the development process. These contaminated solutions form environmentally hazardous materials and various governmental regulations govern the disposal of the contaminated solutions. In addition, criminal penalties may attach to the improper disposal of the contaminated solutions. As a result, the costs associated with developing film continue to increase.




A relatively new process is digital film processing (DFP). DFP systems scan the film during the development process. DFP systems apply a thin coat of one or more film processing solutions to the film and then scan the film through the coating. Neither the processing solutions nor the silver compounds within the film are washed from the film. One problem faced by DFP systems is the properties and application of the processing solution. In particular, the processing solutions are applied to the film in an open environment instead of being immersed and agitated in tanks of processing solutions. The properties of the processing solution are a compromise between the various requirements of the DFP system. For example, a low viscosity solution would have a tendency to run-off the film and possibly contaminate the DFP system. Similarly, variations in the surface of the processing solution should be minimized to reduce variations produced during the scanning process.




SUMMARY OF THE INVENTION




One implementation of the present invention is an aqueous developer solution for use in digital film processing, comprising a developing agent and at least one surfactant or thickener. In a particular embodiment, the developer solution includes both at least one surfactant and at least one thickener. In another embodiment, the developer solution may have a surface tension of less than about 30 dynes/cm and/or a viscosity of between about 5,000 and about 30,000 cP. Suitable surfactants for use in the developer solution include, but are not limited to, fluorosurfactants. Suitable thickeners include, but are not limited to, solubilized cellulose. The developer solution may further comprise a buffered solution having a pH greater than or equal to about 8, and may include a variety of other components such as one or more activators, restrainers, preservatives, antifoggants or accelerators. In yet another embodiment, the developer solution includes both a color developing agent, as well as a developing agent which is not a color developing agent.




Another implementation of the invention is a method of processing a photographic film, comprising the steps of coating an aqueous developer solution containing at least one surfactant or thickener onto the film, thereby developing the film, and scanning the film through the coating of developer solution. The developer solution may comprise, for example, any of the embodiments described in the previous paragraph. Another embodiment of the processing method includes the step of coating at least one additional processing solution onto the film. The additional processing solution may comprise, for example, a stop solution, an inhibitor solution, an accelerator solution, a bleach solution, a fixer solution, a blix solution, and a stabilizer solution. In another embodiment, the additional processing solution may be coated onto the film prior to the scanning step. The additional processing solution may have a surface tension of less than about 30 dynes/cm, and/or a viscosity of between about 10,000 and about 30,000 cP.




Yet another implementation of the invention is a film processing system comprising: a film loader operable to received exposed film; an applicator operable to coat 100-10,000 micrometers of a developer solution onto the film, wherein the developer solution includes a developing agent and at least one surfactant or thickener; and a scanning system operable to digitize at least one image contained on the film and produce at least one digital image. The scanning system may operate to digitize at least one image contained on the film through the coating of developer solution. By way of example, the scanning system may digitize at least one image contained on the film with light within at least a portion of the visible portion of the electromagnetic spectrum and/or light within the infrared portion of the electromagnetic spectrum. The film processing system may further include a halt station operable to apply at least one additional processing solution onto the film, and the at least one additional processing solution maybe chosen from the group consisting of: a stop solution, an inhibitor solution, an accelerator solution, a bleach solution, a fixer solution, a blix solution, and a stabilizer solution.




Another embodiment of the film processing system further comprises a development station operable to control the temperature and humidity of the film after the application of the developer solution. The film processing system may also include a printer operable to print the at least one digital image, such as an ink jet type of printer. A communication system operable to communicate the at least one digital image over a network (such as the Internet) may even be includes in the film processing system. The film processing system may also include a memory device operable to store the at least one digital image, such as a CD, a DVD, a removable hard drive, or an optical disk. The film processing system may be embodied as a self-service kiosk or a photolab.




Another implementation of the invention is a method for processing film comprising the steps of: receiving an exposed film; coating 100-10,000 micrometers of a developer solution onto the film, wherein the developer solution has a viscosity between about 5,000 and about 30,000 cP; illuminating the film with light; measuring a light intensity from the film and producing sensor data; and processing the sensor data to produce at least one digital image. In one embodiment of this method, the film is illuminated through the coating of developer solution. By way of example, the light may be within at least a portion of the visible portion of the electromagnetic spectrum and/or within the infrared portion of the electromagnetic spectrum. The method may further include controlling the temperature and humidity of the film after coating the film with developer solution.











BRIEF DESCRIPTION OF THE DRAWINGS




For a more complete understanding of the invention and the advantages thereof, reference is now made to the following description taken in conjunction with the accompanying drawings, wherein like reference numerals represent like parts, in which:





FIG. 1

is a schematic diagram of an improved digital film development system in accordance with the invention;





FIG. 2A

is a schematic diagram illustrating one embodiment of a development system shown in

FIG. 1

;





FIG. 2B

is a schematic diagram illustrating another embodiment of the development system shown in

FIG. 1

;





FIGS. 2B-1

through


2


B-


4


are schematic diagrams illustrating various embodiments of a halt station shown in

FIG. 2B

;





FIG. 3

is a schematic diagram illustrating a scanning system shown in

FIG. 1

;





FIGS. 4A-4D

are schematic diagrams illustrating various embodiments of a scanning station shown in

FIG. 3

; and





FIGS. 5A-5B

are flow charts illustrating various methods of digital color dye film processing in accordance with the invention.











DETAILED DESCRIPTION OF THE INVENTION




In the following detailed description, reference is made to the accompanying drawings which form a part hereof, and in which is shown by way of illustration specific preferred embodiments in which the invention may be practiced. These embodiments are described in sufficient detail to enable those skilled in the art to practice the invention, and it is to be understood that other embodiments may be utilized and that logical, mechanical and electrical changes may be made without departing from the spirit or scope of the invention. To avoid detail not necessary to enable those skilled in the art to practice the invention, the description may omit certain information known to those skilled in the art. The following detailed description is, therefore, not to be taken in a limiting sense, and the scope of the present invention is defined only by the appended claims.





FIG. 1

is an example of one embodiment of a digital film development system


100


. In this embodiment, the system


100


comprises a data processing system


102


and a film processing system


104


that operates to develop and digitize a film


106


to produce a digital image


108


that can be output to an output device


110


. Film


106


, as used herein, includes color, black and white, x-ray, infrared or any other type of film and is not meant to refer to any specific type of film or a specific manufacturer.




Data processing system


102


comprises any type of computer or processor operable to process data. For example, data processing system


102


may comprise a personal computer manufactured by Apple Computing, Inc. of Cupertino, Calif., or International Business Machines of New York. Data processing system


102


may also comprise any number of computers or individual processors, such as application specific integrated circuits (ASICs). Data processing system


102


may include an input device


112


operable to allow a user to input information into the system


100


. Although input device


112


is illustrated as a keyboard, input device


112


may comprise any input device, such as a keypad, mouse, point-of-sale device, voice recognition system, memory reading device such as a flash card reader, or any other suitable data input device.




Data processing system


102


includes image processing software


114


resident on the data processing system


102


. Data processing system


102


receives sensor data


116


from film processing system


104


. As described in greater detail below, sensor data


116


is representative of the colors (or silver in the case of black and white film) in the film


106


at each discrete location, or pixel, of the film


106


. The sensor data


116


is processed by image processing software


114


to produce the digital image


108


.




The specific embodiment of the image processing software


114


is dependent upon the embodiment of the film processing system


104


, and in particular, the specific embodiment of the scanning system, as described below. In an embodiment in which metallic silver grains and/or silver halide remains within the film


106


, the image processing software


114


operates to compensate for the silver or silver halide in the film


106


. In this embodiment, digitally compensating for the silver in the film


106


instead of chemically removing the elemental silver and/or silver halide from film


106


substantially reduces or eliminates the production of hazardous chemical effluents that are generally produced during conventional film processing methods. Although the image processing software


114


is described in terms of actual software, the image processing software


114


may be embodied as hardware, such as an ASIC. The color records for each pixel form the digital image


108


, which is then communicated to one or more output devices


110


.




Output device


110


may comprise any type or combination of suitable devices for displaying, storing, printing, transmitting or otherwise outputting the digital image


108


. For example, as illustrated, output device


110


may comprise a monitor


110




a


, a printer


110




b


, a network system


110




c


, a mass storage device


110




d


, a computer system


110




e


, or any other suitable output device. Network system


110




c


may be any network system, such as the Internet, a local area network, and the like. Mass storage device


110




d


may be a magnetic or optical storage device, such as a floppy drive, hard drive, removable hard drive, optical drive, CD-ROM drive, and the like. Computer system


110




e


maybe used to further process or enhance the digital image


108


.




As described in greater detail below, film processing system


104


operates to develop and electronically scan the developed film


106


to produce the sensor data


116


. As illustrated, film processing system


104


comprises a transport system


120


, a development system


122


, and a scanning system


124


. Transport system


120


operates to dispense and move the film


106


through the film processing system


104


. In a preferred embodiment, the transport system


120


comprises a leader transport system in which a leader is spliced to the film


106


and a series of rollers pulls the film


106


through the film processing system


104


, with care taken that the image surface of the film


106


is not contacted. Similar transport systems


120


are found in film products manufactured by, for example, Noritsu Koki Co. of Wakayama, Japan, and are available to those skilled in the art.




The development system


122


operates to apply one or more digital film processing solutions to the film and develop the film


106


, as described in greater detail in connection with FIG.


2


. One or more types of processing solutions may be used, depending upon the configuration of the development system


122


. In general, a developer solution is first coated onto the film


106


to develop the film


106


. The coated film


106


is transported through a developer station that controls the developing conditions of the film


106


. In the case of color film, the developer chemically interacts with the chemicals within the film


106


to produce dye clouds and the metallic silver grains within the film


106


. The development system


122


may also apply other suitable film processing solutions, such as a stop solution, inhibitors, accelerators, bleach solution, fixer solution, blix solution (combines the functionality of a bleach solution and a fixer solution), stabilizer solution and the like. In a preferred embodiment, one of the digital film processing solutions comprises a viscous developer solution, as described below, that produces the metallic silver grains and the magenta, cyan and yellow dye images within the film


106


.




The scanning system


124


scans the film


106


through the processing solutions applied to the film


106


, as described in greater detail in connection with FIG.


3


. In other words, the processing solutions are not necessarily removed from the film


106


prior to the scanning process. In contrast, conventional film processing systems remove the elemental silver and silver halide from the film, as well as the processing solutions, to create a conventional film image prior to any digitization process.




The scanning system


124


may be configured to scan the film


106


using any form or combination of electromagnetic energy, referred to generically herein as light. In the preferred embodiment, the film


106


is scanned with light within the visible portion of the electromagnetic spectrum. A disadvantage of scanning with visible light is that any remaining silver halide within the film


106


will react with the light and fog the film


106


. The visible light allows the density of the colored dye clouds to be measured, as well as any silver halide and/or elemental silver remaining in the film


106


. In particular, one or more wavelength bands of visible light may be used to scan the film


106


. For example, the film


106


may be scanned using visible light within the red, green and/or blue portions of the electromagnetic radiation spectrum. The film


106


may also be scanned using infrared light. The dye clouds within the film


106


are generally transparent to infrared light, but any elemental silver and/or silver halide is not transparent to infrared light. In addition, infrared light does not substantially fog the film. As a result, the infrared light allows the density of any remaining elemental silver and/or silver halide within the film


106


to be measured without damaging the film


106


. In at least one embodiment, a satisfactory digital image


108


has been obtained by scanning the film


106


solely with infrared light. In an embodiment in which visible light and infrared light is used, the infrared light allows any elemental silver and/or silver halide to be compensated for by the image processing software


114


. In contrast, conventional film processing systems remove substantially all of the silver, both silver halide and elemental silver, from the film prior to drying the film and conventionally scanning the film.




In operation, exposed, but undeveloped film


106


is fed into the transport system


120


. The film


106


is transported through the development system


122


. The development system


122


applies a processing solution to the film


106


that develops the film


106


. The transport system


120


moves the film


106


through the scanning system


124


. The scanning system


124


scans the film


106


and produces sensor data


116


. The sensor data


116


represents the images on the film


106


at each pixel. The sensor data


116


is communicated to data processing system


102


. The data processing system


102


processes the sensor data


116


using image processing software


114


to produce the digital image


108


. The data processing system


102


may also operate to enhance or otherwise modify the digital image


108


. For example, the digital image


108


maybe modified in accordance with input from the user. The data processing system


102


communicates the digital image


108


to the output device


110


for viewing, storage, printing, communicating, or any combination of the above.




In a particular embodiment of the digital film development system


100


the system


100


is configured as a self-service film processing system, such as a kiosk. Such a self-service film processing system is uniquely suited to new locations because no plumbing is required to operate the self-service film processing system. In addition, the developed images


108


can be prescreened by the user before they are printed, thereby reducing costs and improving user satisfaction. The self-service film processing system can also be packaged in a relatively small size to reduce the amount of floor space required. As a result of these advantages, a self-service film processing system can be located in hotels, college dormitories, airports, copy centers, or any other suitable location. In other embodiments, the system


100


may be used for commercial film lab processing applications. Again, because there is no plumbing and the environmental impact of processing the film


106


is substantially reduced or eliminated, the installation cost and the legal liability for operating such a film lab is reduced. The system


100


can be adapted to any suitable application without departing from the scope and spirit of the invention.





FIG. 2A

illustrates one embodiment of the development system


122


. In this preferred embodiment, a development system


122




a


comprises an applicator station


200


and a development station


202


. The applicator station


200


operates to coat a processing solution (or developer solution)


204


onto the film


106


. The processing solution


204


includes one or more developing agents.




A developing agent is any component (or group of components) capable of reducing an exposed emulsion grain (silver halide crystal) to metallic silver. The developing agent(s) interacts with latent image centers, which are elemental silver, to produce visible silver grains. In the case of color developing agents used on color film, the by-product of this chemical reaction then reacts with one or more dye precursors (couplers) in the emulsion layers of the film


106


to produce the appropriate dye clouds.




Any of a wide variety of developing agents may be employed in developer solution


204


. In fact, developer solution


204


may comprise a conventional color developer solution, such as Flexicolor Developer for Process C-


41


available from the Eastman Kodak Company, that has been suitably modified (particularly as to its viscosity and surface tension) as described further herein. Suitable developing agents include, but are not limited to:




various aminophenols, such as:




p-methylaminophenol sulfate




N-methyl-p-aminophenol




diaminophenol




various 3-pyrazolidones, such as:




1-phenyl-3-pyrazolidone




1-phenyl-4,4-dimethyl-3-pyrazolidone




4-hydroxymethyl-4-methyl-1-phenyl-3-pyrazolidone




various dihydroxybenzenes, such as:




hydroquinone




2-chloro-hydroquinone




o-dihydroxybenzene




various phenylenediamines (including salts thereof), such as:




N,N-diethyl-p-phenylenediamine sulfate




4-Amino-3-methyl-N-ethyl-N-(β-hydroxyethyl)-aniline sulfate;




2-Amino-5-diethylaminotoluene Monohydrochloride; and




4-Amino-3-methyl-N-ethyl-N-(β-methanesulfonamidoethyl)-m-toluidine sesquisulfate monohydrate.




The phenylenediamines are color developing agents in that they not only reduce exposed silver halide grains to metallic silver, the by-product of this reaction will react with one or more dye precursors in the film to form a dye image. The above list of suitable developing agents is not exhaustive, and is merely intended to identify exemplary developing agents. Suitable developing agents include any compound or combination of compounds capable of reducing an exposed emulsion grain (silver halide crystal) to metallic silver, including, but not limited to, compounds used as developing agents in conventional black and white and color film development. The developer solution may include multiple developing agents, such as a color developing agent and a developing agent which is not capable of reacting with couplers in the film to form dye clouds.




The concentration of developing agent(s) in the developer solution can vary widely depending upon the particular developing agent(s) employed, the type of film being developed, and processing conditions (such as temperature). However, the amount of developing agent(s) should be sufficient to provide adequate development activity prior to scanning. In addition, the amount of developing agent(s) should not be so high that the developer solution crystallizes or the film fogs or overdevelops Most developing agents require a source of alkalinity, and the level of alkali in the developer solution of the present should also be stabilized. Therefore, the developer solution should generally comprise a buffered solution having a pH greater than or equal to about 8. In most instances, an alkali (activator) should be included in order to provide a source of alkalinity. A buffer may also be included, however, some activators also act as buffers. Suitable activators include sodium hydroxide, potassium hydroxide, potassium carbonate, sodium carbonate and sodium tetraborate. Of course any source of alkali which does not otherwise interfere with film development or scanning may be used as an activator. The amount of alkali will depend, in part, on the particular developing agent(s) employed. The alkali concentration should not be so high as to cause fogging, and should be sufficient to ensure proper development (i.e., too little activator may result in slow, weak development). As for buffers, sodium carbonate and sodium tetraborate not only provide alkali but also act as buffers, and therefore a separate buffer may not be necessary when either of these compounds is used as an activator. Another suitable buffer is potassium phosphate (tribasic). Likewise, any buffer which does not interfere with film development may be used in order to stabilize the alkali level, as necessary. It should be noted that some developing agents (notably, diaminophenol) may not require an activator or buffer.




The developer solution may also include one or more preservatives in order to prevent oxidation of the developing agent, thereby prolonging the useful life of the developer solution and preventing staining of the film. Suitable preservatives include sodium sulfite, potassium sulfite, hydroxylamine sulfate and sodium ascorbate (which can also serve as a developing agent). The amount of preservative should be chosen to adequately prevent oxidation of the developing agent while not interfering with the development process.




Developer solution


204


may further include one or more restrainers. Restrainers act to balance the activity of the developing agent, thereby controlling both the development of the film as well as the development of fog. Suitable restrainers include sodium bromide and potassium bromide. In order to further control fog formation, the digital film processing solution may include one or more antifoggants. Suitable antifoggants include:




Benzotriazole




5-Methyl-benzotriazole




1-Phenyl-5-mercaptotetrazole




6-Nitrobenzimidazole Nitrate




5-Nitroindazole




5-Nitrobezimidazole




3-Methylbenzothiazolium p-toluenesulfonate




2-Benzimidazolethiol




3,5-Dinitrobenzoic acid.




The amount of restrainer and antifoggant should be chosen to adequately prevent fog formation while not excessively retarding development of the image.




Developer solution


204


may also include other additives typically used in film developers. Examples include accelerators which increase the rate of development (such as triethanolamine, sodium thiocyanate or laurylpyridinium chloride). A variety of other additives may further be included in order to provide any of a variety of properties. These additional additives may include one or more organic solvents, image tone modifiers, auxiliary antioxidants, water softeners (sequestering agents), dye couplers, competing couplers, auxiliary developing agents, color dyes, fragrances, hardeners, dichroic fog reducers, and the like.




Any substantial unevenness in the layer of developer solution


204


on the film can adversely affect the scanning process. For example, if a conventional film processing solution were employed in the methods and systems of the present invention, edge beads would typically form on the film and the processing solution may even pull itself into the center portions of the film


106


. The applicants have found that a more even layer of the developer solution


204


will be formed if the surface tension of the developer solution


204


is less than about 30 dynes/cm (measured at 25° C.). In particular, optimal results are obtained when the surface tension of the developer solution


204


is less than about 25 dynes/cm, more preferably less than about 22 dynes/cm. Although specific surface tension measurements are provided, these values should not be considered as exact values and can vary within the spirit and scope of the invention.




One method for reducing the surface tension is to add one or more surfactants to the processing solution. Surfactants are wetting agents that reduce surface tension and allow for uniform wetting of the surface of the film. While any of a variety of surfactants may be used, the preferred embodiments of the processing solutions of the present invention utilize fluorosurfactants, particularly fluorosurfactants which do not interfere with the other properties of the processing solution (such as the speed of film development). Suitable fluorosurfactants may be partially or fully fluorinated, and are commercially available from a number of sources. Typically, commercially available surfactants are provided as a mixture of water, one or more surfactants, and one or more optional ingredients (such as a solvent). In addition, the specific structures of the surfactants in commercially-available surfactant solutions are proprietary. Therefore, the surfactant(s) in the processing solutions of the present invention may be provided by using one or more commercially-available surfactant solutions which provide the desired surface tension and do not interfere with the other properties of the processing solution. Suitable commercially-available surfactant solutions (and their publicly-available compositions) include, but are not limited to:


















DuPont Zonyl FSO







Telomer B Monoether with Polyethylene Glycol




     50%






Ethylene Glycol




     25%






Water




     25%






1,4-Dioxane




  <0.1%






DuPont Zonyl FS-300






Fluoroalkyl Alcohol Substituted Polyethylene Glycol




     40%






Water




     60%






1,4-Dioxane




  <0.1%






3M Fluorad Fluorochemical Surfactant FC-129






Water




     32%






2-Butoxyethanol




     14%






Ethanol




      4%






Potassium Fluoroalkyl Carboxylate (C8)




     42% approx






Potassium Fluoroalkyl Carboxylate (C7)




    3.0% approx






Potassium Fluoroalkyl Carboxylate (C6)




    3.0% approx






Potassium Fluoroalkyl Carboxylate (C5)




    3.0% approx






Potassium Fluoroalkyl Carboxylate (C4)




    3.0% approx






Kodak Photo Flo 200






Water




   60-70%






Propylene Glycol




   25-30%






p-tert-Octylphenoxypolyethoxyethyl Alcohol




    5-10%














It should be noted that Kodak Photo Flo 200 does not include a fluorosurfactant. It should also be kept in mind that the surface tension is dependent upon not only the amount of surfactant in the processing solution, but also the type and amounts of other components in the processing. Accordingly, the amount of surfactant(s) needed to achieve the desired surface tension will vary depending upon the composition of the particular processing solution.




In the system of the present invention, the film is not developed while immersed in a tank of solution. Rather, the processing solution is applied to the film, and the film is then scanned through the layer of processing solution, either wet or dry. Therefore, the processing solution should be applied to the film, and remain thereon, in a uniform manner. The thickness of the developer solution


204


as applied onto the film


106


should generally be greater than about 100 micrometers. A coating thickness which is too great may result in a tendency for the processing solution to run off the film


106


. Therefore, the thickness of the developer solution


204


as applied onto the film


106


may be between about 100 and about 1000 micrometers, more preferably between about 150 and about 400 micrometers, and most preferably about 250 micrometers.




As further described herein, the developer solution


204


of the present invention (as well as the other processing solutions described herein) may be applied to the film in a variety of ways. For example, the developer solution


204


may be applied to the film using an applicator which operates to coat the film with a thin even layer of developer solution. One particular type of applicator which may be used is a slot coater. In order to facilitate coating the film using a slot coater or similar types of applicators, and to ensure a thin, even layer of developer solution on the film, a viscous developer solution may be employed. The term “viscous” simply means that the viscosity of the developer solution is greater than the viscosity of a developer solution formulated for conventional film processing using comparable developer solution components.




In general, one or more thickeners are needed in order to achieve the desired viscosity. In one embodiment, the viscosity of the processing solution may be about 5,000 to about 30,000 cP (measured at 45±4° C.), more preferably between about 10,000 and about 20,000 cP, most preferably about 16,000 cP. It should be pointed out that the processing solutions of the present invention having one or more of the thickeners described herein will typically be a non-Newtonian fluid. Therefore, viscosity measurements will depend greatly on the testing apparatus and methods, particularly the shear rate used during testing The viscosity measurements reported herein may be measured using a Brookfield LVDV-E viscometer, and a shear rate of approximately 0.84 sec


−1


. The use of other equipment and/or other methods, however, may result in a wide variation in measured viscosity. Therefore, the above viscosity ranges are intended to approximate suitable values.




As used herein, the term thickener refers to any component or components which provide the desired viscosity for the developer solution, and do not otherwise interfere with development of the film or scanning. Therefore, the thickener(s) employed should be chosen to ensure that the processing solution remains substantially optically clear during use (i.e., at the temperature during scanning). Particularly suitable thickeners include polyvinyl alcohol (PVA), and solubilized cellulose, such as carboxymethylcellulose or hydroxyethylcellulose.




The following provides one example of a developer solution


204


suitable for use with color film in accordance with one embodiment of the present invention:



















Water




500




ml






Potassium carbonate, anhyd.




20.0




g






Sodium sulfite, anhyd.




4.25




g






Potassium bromide




6.0




g






4-hydroxymethyl-4-methyl-1-phenyl-3-pyrazolidone




0.12




g






4-Amino-3-methyl-N-ethyl-N-(β-hydroxyethyl)-




9.5




g






aniline sulfate






DuPont FSO Fluorosurfactant, 50% active solution




0.2




ml






Potassium hydroxide,






as needed to provide a pH of approx. 10.4 at 22.0° C.






2-Hydroxyethyl cellulose (MW 1.3 × 10


6


)




14.5




g






Water to make 1000 ml














The surface tension of this developer solution was approximately 20 dynes/cm, and its viscosity was approximately 18,000 cP (as measured in the manner described previously). The above example is not intended to limit in any way the scope of the present invention, and merely provides one suitable example of a developer solution in accordance with the present invention.




As further described herein, in addition to the developer solution


204


described above, the development system


122


may also apply other film processing solutions, such as a stop solution, inhibitor solution, accelerator solution, bleach solution, fixer solution, blix solution (combines the functionality of a bleach solution and a fixer solution), stabilizer solution and the like. These additional solutions may be formulated similar to conventional film processing solutions, however, the surface tension and viscosity should be modified in the manner described previously with respect to the developer solution (i.e., by the addition of one or more surfactants and one or more thickeners).




By way of example, a stop solution comprising a dilute, acidic, aqueous solution may be employed in order to neutralize any alkali remaining on the film, thereby halting development of the film. Typically, stop solutions employ a combination of sodium acetate and acetic acid, however, sodium bisulfite, citric acid, and/or sodium acid sulfate may be employed in various combinations well-known to those skilled in the art. A stop solution used in the present invention, however, may also include one or more surfactants and one or more thickeners, such that the stop solution has the surface tension and viscosity specified above with respect to the developer solution. One exemplary stop solution is as follows:






















Water




700




ml







Sodium Acetate




139.0




g







Acetic Acid, glacial




100.0




ml







DuPont FSO Fluorosurfactant, 50% active solution




0.2




ml







2-Hydroxyethyl cellulose (MW 1.3 × 10


6


)




15




g







Water to make




1000




ml















By way of further example, another suitable processing solution which may be employed in the present invention is a fixer. After development, the film remains sensitive to light, since it contains undeveloped silver halide. Therefore, a fixer solution may be employed to remove the undeveloped silver halide. Typically, fixer solutions include one or more fixing agents which act to dissolve undeveloped silver halide, such as sodium or potassium thiocyanate or ammonium thiosulfate. Fixer solutions may also include acetic acid and/or sodium acetate, or similar functional compounds, in order to control the acidity of the fixer solution. A fixer solution used in the present invention, however, may also include one or more surfactants and one or more thickeners, such that the fixer solution has the surface tension and viscosity specified above with respect to the developer solution. Two exemplary fixer solutions are as follows:






















Fixer #1









Water




500




ml







Potassium Thiocyanate




550.0




g







Sodium Acetate




55.6




g







Ethyl Alcohol




180




ml







DuPont FSO Fluorosurfactant, 50% active solution




0.2




ml







2-Hydroxyethyl cellulose (MW 1.3 × 10


6


)




15




g







Water to make




1000




ml







Fixer #2







Water




500




ml







Ammonium Thiosulfate, dry




194.3




g







DuPont FSO Fluorosurfactant, 50% active solution




0.2




ml







2-Hydroxyethyl cellulose (MW 1.3 × 10


6


)




15




g







Water to make




1000




ml















Yet another suitable processing solution which may be employed in the present invention is a bleach solution. After development of color film, the developed silver grains remain in the film along with the dye clouds. As with conventional color film development, it may be desirable to fully or partially oxidize the developed silver to improve the light transmission of the film. A bleach solution includes one or more bleaching agents which convert the developed silver into silver salts which may later be removed using a fixer solution. Typical bleach solutions employ strong oxidizers such as Potassium Ferricyanide, Potassium Permanganate, Ferric Ammonium Ethylenediaminetetraacetic Acid, Ferric Ammonium Propylenediaminetetraacetic Acid, or Cupric Sulfate, and may optionally include one or more additional components (such as acetic acid) in order to adjust the pH of the bleach solution. A bleach solution used in the present invention, however, may also include one or more surfactants and one or more thickeners, such that the bleach solution has the surface tension and viscosity specified above with respect to the developer solution. An exemplary bleach solution is as follows:






















Water




500




ml







Ammonium Bromide




250.0




g







Ferric Ammonium EDTA




160.0




g







Diammonium EDTA




9.0




g







Acetic Acid, glacial




12.0




ml







DuPont FSO Fluorosurfactant, 50% active solution




0.2




ml







2-Hydroxyethyl cellulose (MW 1.3 × 10


6


)




15




g







Water to make




1000




ml















As is known to those skilled in the art, a combined fixer and bleach solution (often referred to as a “blix” solution) may also be employed. In this manner, a separate fixer solution need not be applied to the film after the bleach solution if it is desirable to remove the insoluble silver salts resulting from the bleach step. Such a blix solution may comprise a combination of the components of a fixer and bleach solution. A blix solution used in the present invention, however, may also include one or more surfactants and one or more thickeners, such that the blix solution has the surface tension and viscosity specified above with respect to the developer solution. An exemplary blix solution is as follows:






















Water




500




ml







Ferric Ammonium EDTA




194




g







Diammonium EDTA




11.0




g







Ammonium Thiosulfate, 60% solution




350




ml







Ammonium Sulfite, monohyd.




40.0




g







DuPont FSO Fluorosurfactant, 50% active solution




0.2




ml







2-Hydroxyethyl cellulose (MW 1.3 × 10


6


)




15




g







Water to make




1000




ml















Referring again to

FIG. 2A

, the applicator station


200


generally includes an applicator


206


, a fluid delivery system


208


, and a reservoir


210


. The applicator


206


operates to coat the film


106


with a thin even layer of processing solution


204


. The preferred embodiment of the applicator


206


comprises a slot coater device. In alternative embodiments, the applicator


206


comprises an ink jet applicator, a tank, an aerosol applicator, drip applicator, or any other suitable device for applying the processing solution


204


to the film


106


. The fluid delivery system


208


delivers the processing solution


204


from the reservoir


210


to the applicator


206


. In an embodiment in which the applicator


206


comprises a slot coater device, the fluid delivery system


208


generally delivers the processing solution


204


at a constant volumetric flow rate to help insure uniformity of coating of processing solution


204


on the film


106


.




The reservoir


210


may contain a sufficient volume of processing solution


204


to process multiple rolls of film


106


. As described in greater detail below, the reservoir


210


maybe refillable or replaceable within the development system


122


, and may comprise a closed system that substantially prevents air and other contaminates from contacting the digital film processing solution


204


. In one embodiment, the reservoir


210


comprises a replaceable cartridge. In other embodiments, the reservoir


210


comprises a refillable tank. The applicator station


200


may comprise other suitable systems and devices for applying the processing solution


204


to the film


106


. For example, the applicator station


200


may comprise a tank filled with processing solution


204


in which the film


106


is transported through the tank, effectively dipping the film


106


into the processing solution


204


. In yet another embodiment, the reservoir


210


may comprise a flexible bladder that collapses as the digital film processing solution


204


is dispensed. In this manner, air is not introduced into the reservoir


210


and the digital film processing solution


204


is not contaminated by the air or other contaminates.




The development station


202


operates to develop the coated film within a controlled air environment. As used herein, air refers generally to a gaseous environment, which may include a nitrogen environment or any other suitable gaseous environment. It has been discovered that in an air environment, the temperature of the developing film


106


strongly affects the development of the film


106


. If the temperature is not controlled, the may develop unevenly and the resulting image will be overdeveloped in areas where the temperature was highest and underdeveloped in areas where the temperature was coolest. Testing has also shown that the humidity surrounding the film


106


affects the development of the film


106


. This is believed to be due to the cooling effect of the processing solution evaporating from the film


106


, thereby causing unpredictable and uneven temperature gradients across the film


106


. Again, conventional development stations do not control the humidity surrounding the film during development.




In one embodiment of the present invention, the development station


202


includes a heating system


212


. The heating system


212


operates to heat, or maintain the temperature of, the film


106


. In a preferred embodiment wherein a heater is employed, the film


106


is heated and/or maintained at a temperature within the range of 40-80 degrees Centigrade. In the preferred embodiment, the coated film


106


is heated and/or maintained at a temperature within the range of 45-55 degrees Centigrade, and more preferably at approximately 50 degrees Centigrade. The specific temperature is not as important as consistently maintaining a repeatable temperature profile during the development process. In one embodiment, the temperature is maintained within profile by +/−5 degrees Centigrade. In a preferred embodiment, the temperature is maintained within profile by +/−1 degree Centigrade, and more preferably within +/−0.2 degrees Centigrade. It should be understood that the temperature and temperature profile may comprise any suitable temperature and temperature profile without departing from the scope of the present invention.




In a particular embodiment, the heating system


212


includes multiple individual heating elements that allow the temperature of the heating system


212


to be varied during development. In this embodiment, the temperature of the developing film


106


can be varied to optimize the development of the film


106


. For example, infrared light and sensors may be used to monitor the development of the film


106


. Based on the sensor readings, the heating system


212


can increase or decrease the temperature of the developing film


106


to compensate for the effects of temperature, type of film, film manufacturer, or other processing variable.




In one embodiment, the heating system


212


contacts the film


106


on the side opposite the coating of processing solution


204


. Because of the physical contact between the film


106


and the heating system


212


, i.e., conductive heat transfer, the film


106


can be efficiently heated so that evaporation, or humidity, will not substantially effect the processing of the film


106


. As a result, a housing forming a development tunnel, as described in greater detail below, is not required, but may be used to further control the development process. In a particular embodiment, the heating system


212


includes a heated roller


212




a


and a heating element


212




b


. In the embodiment illustrated, the heated roller


212




a


heats the film


106


as the processing solution


204


is applied to the film


106


and the heating element


212




b


maintains the temperature of the coated film


106


during development.




In another embodiment, the development station


202


includes a development tunnel


214


. The development tunnel


214


comprises a housing


216


that forms a development chamber


218


through which the coated film


106


is transported. The development chamber


218


preferably forms a minimum volume surrounding the coated film


106


. The development tunnel


214


is preferably shaped and disposed such that air circulation through the development chamber


218


is minimized. In particular, the development chamber


218


is preferably oriented horizontally to reduce chimney effects, i.e., hot air rising. In addition, the housing forms an entry and exit having in the development chamber


218


having a minimum cross section to reduce circulation of air through the development chamber


218


.




In a preferred embodiment, the housing


216


is insulated. As a result, the development tunnel


214


does not necessarily require a heating system


212


. However, in a preferred embodiment, the development tunnel


214


includes a heating system


212


to heat and/or maintain the temperature of the coated film


106


. In this embodiment, the heating system


212


does not necessarily contact the coated film


106


within the development tunnel


214


. For example, the heating system


212


may comprise a heating element


212




b


located within the development tunnel


214


to heat and/or maintain the temperature of the film


106


. The heating system


212


may also comprise a forced air heating system that forces heated air through the development tunnel


214


.




The humidity surrounding the coated film


106


may also be controlled. As discussed above, evaporation of the processing solution


204


from the film


106


can negatively effect the consistent development or processing of the film


106


. In one embodiment, the humidity is maintained within a range of 80 to 100 percent humidity, and preferably within a range of 95 to 100 percent humidity, and more preferably at approximately 100 percent humidity. The humidity is preferably controlled within the development chamber


218


. The minimum volume of the development chamber


218


facilitates controlling the humidity. As discussed above, one embodiment of the transport system


120


comprises a leader transport system. In this embodiment, the processing solution


204


can be applied to the film leader. This allows the evaporation of the processing solution


204


on the film leader to saturate and stabilize the humidity within the development chamber


218


. In another embodiment, the humidity is controlled by a humidification system


220


. In a particular embodiment, the humidification system


220


comprises a wicking system that uses a water reservoir to supply humidity to the development chamber


218


. The humidification system


220


may comprise other suitable devices or systems for supplying humidity to the development chamber


218


. For example, the humidification system


220


may comprise a jet that injects an atomized spray of water into the development chamber


218


. The humidification system


220


may also operate to reduce the humidity within the development chamber


218


. Too much humidity within the development chamber


218


can result in pooling of water within the development chamber


218


, which can negatively affect development and scanning of the film


106


.




The development station


202


may also include a control system to monitor and control the temperature and humidity within the development chamber


214


. The development station


202


is also light sealed to prevent external light and light from the scanning station


204


from exposing the film


106


. The development station


202


may include other suitable devices and systems without departing from the scope of the present invention. For example, the development station


202


is described in terms of a developer solution, but it is also applicable to other processing solutions, such as a fix solution, bleach solution, blix solution, halt solution, and the like.




In operation, transport system


120


transports the film


106


through the applicator station


200


. Fluid delivery system


208


dispenses the processing solution


204


from the reservoir


210


through the applicator


206


onto the film


106


. The processing solution


204


develops the film


106


. The coated film


106


is then transported through the development tunnel


214


of the development station


202


. The development tunnel


214


operates to give the film


106


time to develop within a controlled temperature and humidity environment within the development chamber


218


. Upon development, the coated film


106


is transported by the transport system


120


to the scanning system


124


.





FIG. 2B

illustrates an alternative development system


122




b


. In this embodiment, the development system


122




b


comprises an applicator station


200


, a development station


202


, and a halt station


222


. The developer applicator station


200


and the development station


202


were previously discussed in connection with FIG.


2


A. The applicator station


200


again applies the developer solution


204


to the film


106


that develops the film


106


. The development station


202


maintains a controlled environment around the film


106


during development of the film


106


. Halt station


222


operates to retard or substantially stop the continued development of the film


106


. Retarding or substantially stopping the continued development of the film


106


increases the amount of time the film


106


can be exposed to visible light without fogging of the film


106


. As discussed in greater detail below, the film


106


may be scanned using visible light, and increasing the time the film


106


can be scanned without negatively affecting the film


106


may be advantageous in some embodiments of the improved film processing system


100


. FIGS.


2


B-


1


-


2


B


4


illustrate different examples of the halt station


222


.





FIG. 2B-1

illustrates a halt station


222




a


that operates to apply at least one halt solution


224


to the film


106


coated with processing solution


204


. The halt solution


224


retards or substantially stops the continued development of the film


106


. In the embodiment illustrated, the halt station


222




a


comprises an applicator


206




b


, a fluid delivery system


208




b


, and a reservoir


210




b


, similar in function and design as described in FIG.


2


A. Although a single applicator


206




b


, fluid delivery system


208




b


, and reservoir


210




b


are illustrated, the halt station


222




a


may comprise any number of applicators


206




b


, fluid delivery systems


208




b


, and reservoirs


210




b


that apply other suitable halt solutions


224


and other suitable solutions.




In one embodiment, the halt solution


224


comprises a bleach solution. In this embodiment, the bleach solution substantially oxidizes the metallic silver grains forming the silver image into a silver compound, which may improve the transmission of light through the film


106


during the scanning operation. In another embodiment, the halt solution


224


comprises a fixer solution. In this embodiment, the fixer solution substantially dissolves the undeveloped or unused silver halide, which can also improve the transmission of light through the film


106


. In yet another embodiment, multiple halt solutions


224


are applied to the film


106


. For example, a fixer solution can be applied to the film


106


and then a stabilizer solution can be applied to the film


106


. In this example, the addition of the stabilizer desensitizes the silver halide within the film


106


and may allow the film


106


to be stored for long periods of time without sensitivity to light. In order to apply multiple halt solutions, the halt station


222




a


may include multiple applicators


206




b


to apply the different halt solutions


224


to the film


106


. Alternatively, a single applicator capable of applying multiple layers of processing solution to the film may be employed. The halt solution


224


may comprise any other suitable processing solution. For example, the halt solution


224


may comprise water, a blix solution , a stop solution, or any other suitable solution or combination of processing solutions for retarding or substantially stopping the continued development of the film


106


.





FIG. 2B-2

illustrates a halt station


222




b


that operates to chill the developing film


106


. Chilling the developing film


106


substantially slows the chemical developing action of the processing solution


204


. In the embodiment illustrated, the chill station


222




b


comprises an electrical cooling plate


226


and insulation shield


228


. In this embodiment, the cooling plate


226


is electronically maintained at a cool temperature that substantially arrests the chemical reaction of the processing solution


204


. The insulation shield


228


substantially reduces the heat transfer to the cooling plate


226


. The chill halt station


222




b


may comprise any other suitable system and device for chilling the developing film


106


.





FIG. 2B-3

illustrates a halt station


222




c


that operates to dry the processing solution


204


on the coated film


106


. Drying the processing solution


204


substantially stops further development of the film


106


. In the embodiment illustrated, the halt station


222




c


comprises an optional cooling plate


226


, as described in

FIG. 2B-2

, and a drying system


228


. Although heating the coated film


106


would facilitate drying the processing solution


204


, the higher temperature would also have the effect of accelerating the chemical reaction of the processing solution


204


and film


106


. Accordingly, in the preferred embodiment, the film


106


is cooled to retard the chemical action of the processing solution


204


and then dried to effectively freeze-dry the coated film


106


. Although chilling the film


106


is preferred, heating the film


106


to dry the film


106


can also be accomplished by incorporating the accelerated action of the heated developer solution


204


into the development time for the film


106


. In another embodiment in which a suitable halt solution


224


is applied to the film


106


, the chemical action of the processing solution


204


is already minimized and the film


106


can be dried using heat without substantially effecting the development of the film


106


. As illustrated, the drying system


228


circulates air over the film


106


to dry the processing solution


204


and depending upon the embodiment, the halt solution


224


. The halt station


222




c


may comprise any other suitable system for drying the film


106


.





FIG. 2B-4

illustrates a halt station


222




d


that operates to substantially remove excess processing solution


204


, and any excess halt solution


224


, from the film


106


. The halt station


222




d


does not remove the solutions


204


,


224


that are absorbed into the film


106


. In other words, even after the wiping action, the film


106


includes some solution


204


,


224


. Removing any excess processing solution


204


will retard the continued development of the film


106


. In addition, wiping any excess solutions


204


,


224


from the film


106


may improve the light reflectance and transmissivity properties of the coated film


106


. In particular, removal of the excess solutions


204


,


224


may reduce any surface irregularities in the coating surface, which can degrade the scanning operations described in detail in

FIGS. 3 and 4

. In the embodiment illustrated, the halt station


222




d


comprises a wiper


230


operable to substantially remove excess processing solution


204


and any halt solution


224


. In a particular embodiment, the wiper


230


includes an absorbent material that wicks away the excess solutions


204


,


224


. In another embodiment, the wiper


230


comprises a squeegee that mechanically removes the substantially all the excess solutions


204


,


224


. The halt station


222




d


may comprise any suitable device or system operable to substantially remove any excess solutions


204


,


224


.




Although specific embodiments of the halt station


222


have been described above, the halt station


222


may comprise any suitable device or system for retarding or substantially stopping the continued development of the film


106


. In particular, the halt station


222


may comprise any suitable combination of the above embodiments. For example, the halt station


222


may comprise an applicator


206




b


for applying a halt solution


224


, a cooling plate


226


, and a drying system


228


. As another example, the halt station


222


may comprise a wiper


230


and a drying system


228


.





FIG. 3

is a diagram of the scanning system


124


. Scanning system


124


comprises one or more scanning stations


300


. Individual scanning stations


300


may have the same or different architectures and embodiments. Each scanning station


300


comprises a lighting system


302


and a sensor system


304


. The lighting system


302


includes one or more light sources


306


and optional optics


308


. The sensor system


304


includes one or more detectors


310


and optional optics


312


. In operation, the lighting system


302


operates to produce suitable light


320


that is directed onto the film


106


. The sensor system


304


operates to measure the light


320


from the film


106


and produce sensor data


116


that is communicated to the to the data processing system


102


.




Each scanning station


300


utilizes electromagnetic radiation, i.e., light, to scan the film


106


. Individual scanning stations


300


may have different architectures and scan the film


106


using different colors, or frequency bands (wavelengths), and color combinations. In particular, different colors of light interact differently with the film


106


. Visible light interacts with the dye image and silver within the film


106


. Whereas, infrared light interacts with any elemental silver and/or silver halide, but the dye image is generally transparent to infrared light. The term “color” is used to generally describe specific frequency bands of electromagnetic radiation, including visible and non-visible light.




Visible light, as used herein, means electromagnetic radiation having a wavelength band generally between about 400 nm and about 700 nm. Visible light can be separated into specific bandwidths. For example, the color red is generally associated with light within a frequency band of approximately 600 nm to 700 nm, the color green is generally associated with light within a frequency band of approximately 500 nm to 600 nm, and the color blue is generally associated with light having a wavelength of approximately 400 nm to 500 nm. Near infrared light is generally associated with radiation having a wavelength of approximately 700 nm to 1500 nm. Although specific colors and wavelengths are described herein, the scanning station


300


may utilize other suitable colors and wavelengths (frequency) ranges without departing from the spirit and scope of the invention.




The light source


306


may comprise one or more devices or a system that produces suitable light


320


. In the preferred embodiment, the light source


306


comprises an array of light-emitting diodes (LEDs). In this embodiment, different LEDs within the array may be used to produce different colors of light


320


, including infrared light. In particular, specific colors of LEDs can be controlled to produce short duration pulses of light


320


. In another embodiment, the light source


306


comprises a broad spectrum light source


306


, such as a Xenon, fluorescent, incandescent, tungsten-halogen, direct gas discharge lamps, and the like. In this embodiment, the sensor system


304


may include filters for spectrally separating the colors of light


320


from the film


106


. For example, as described below, a RGB filtered trilinear array of detectors may be used to spectrally separate the light


320


from the film


106


. In another embodiment of a broad-spectrum light source, the light source


306


includes a filter, such as a color wheel, to produce the specified colors of light


320


. In another embodiment, the light is filtered into specific bands after the light has interacted with the film


106


. For example, a hot or cold mirror can be used to separate the infrared light from the visible light. The visible light can then be separated into its constituent colors to produce sensor data


116


. In yet another embodiment, the light source


306


comprises a point light source, such as a laser. For example, the point light source may be a gallium arsenide or an indium gallium phosphide laser. In this embodiment, the width of the laser beam is preferably the same size as a pixel on the film


106


(˜12 microns). Filters, such as a color wheel, or other suitable wavelength modifiers or limiters maybe used to provide the specified color or colors of light


320


.




Optional optics


308


for the lighting system


302


directs the light


320


to the film


106


. In the preferred embodiment, the optics


308


comprises a waveguide that directs the light


320


onto the film


106


. In another embodiment, the optics


320


includes a lens system for focusing the light


320


. In a particular embodiment, the lens system includes a polarizing filter to condition the light


320


. The optics


308


may also include a light baffle


322




a


. The light baffle


322




a


constrains illumination of the light


320


within a scan area in order to reduce light leakage that could cause fogging of the film


106


. In one embodiment, the light baffle


322




a


comprises a coated member adjacent the film


106


. The coating is generally a light absorbing material to prevent reflecting light


320


that could cause fogging of the film


106


.




The detector


310


comprises one or more photodetectors that convert light


320


from the film


106


into data signals


116


. In the preferred embodiment, the detector


310


comprises a linear charge coupled device (CCD) array. In another embodiment, the detector


310


comprises an area array. The detector


310


may also comprise a photodiode, phototransistor, photoresistor, and the like. The detector


310


may include filters to limit the bandwidth, or color, detected by individual photodetectors. For example, a trilinear array often includes separate lines of photodetectors with each line of photodetectors having a color filter to allow only one color of light to be measured by the photodetector. Specifically, in a trilinear array, the array generally includes individual red, green, and blue filters over separate lines in the array. This allows the simultaneous measurement of red, green, and blue components of the light


320


. Other suitable types of filters may be used. For example, a hot mirror and a cold mirror can be used to separate infrared light from visible light.




Optional optics


312


for the sensor system


304


directs the light


320


from the film


106


onto the detector


310


. In the preferred embodiment, the optics


312


comprises lens system that directs the light


320


from the film


106


onto the detector


310


. In a particular embodiment, the optics


312


include polarized lenses. The optics


312


may also include a light baffle


322




b


. The light baffle


322




b


is similar in function to light baffle


322




a


to help prevent fogging of the film


106


.




As discussed previously, individual scanning stations


300


may have different architectures. For example, light


320


sensed by the sensor system


304


maybe transmitted light or reflected light. Light


320


reflected from the film


106


is generally representative of the emulsion layer on the same side of the film


106


as the sensor system


304


. Specifically, light


320


reflected from the front side (emulsion side) of the film


106


represents the blue sensitive layer and light


320


reflected from the back side of the film


106


represents the red sensitive layer. Light


320


transmitted through the film


106


collects information from all layers of the film


106


. Different colors of light


320


are used to measure different characteristics of the film


106


. For example, visible light interacts with the dye image and silver within the film


106


, and infrared light interacts with the silver in the film


106


.




Different architectures and embodiments of the scanning station


300


may scan the film


106


differently. In particular, the lighting system


302


and sensor system


304


operate in concert to illuminate and sense the light


320


from the film


106


to produce suitable sensor data


116


. In one embodiment, the lighting system


302


separately applies distinct colors of light


320


to the film


106


. In this embodiment, the sensor system


304


generally comprises a non-filtered detector


310


that measures in series the corresponding colors of light


320


from the film


106


. In another embodiment, multiple unique color combinations are simultaneously applied to the film


106


, and individual color records are derived from the sensor data


116


. In another embodiment, the lighting system


302


simultaneously applies multiple colors of light


320


to the film


106


. In this embodiment, the sensor system


304


generally comprises a filtered detector


310


that allows the simultaneous measurement of individual colors of light


320


. Other suitable scanning methods may be used to obtain the required color records.




The use of the halt station


222


may improve the scanning properties of the film


106


in addition to retarding or substantially stopping the continued development of the film


106


. For example, the intensity of light


320


transmitted through the film


106


maybe partially blocked, or occluded, by the silver within the film


106


. In particular, both the silver image and silver halide within the film


106


occlude light


320


. On the whole, the silver image within the film


106


absorbs light


320


, and the silver halide reflects light


320


. The halt solutions


224


may be used to improve the scanning properties of the film


106


. For example, applying a bleach solution to the film


106


reduces the optical density of the silver image within the film


106


. Applying a fixer solution to the film


106


reduces optical density of silver halide within the film


106


. Another method for improving the scanning properties of the film


106


is drying the film


106


. Drying the film


106


improves the clarity of the film


106


.




As described above, the scanning system


124


may include one or more individual scanning stations


300


. Specific examples of scanner station


300


architectures are illustrated in

FIGS. 4A-4D

. The scanning system


124


may comprise any illustrated example, combination of examples, or other suitable method or system for scanning the film


106


.





FIG. 4A

is a schematic diagram illustrating a scanning station


300




a


having a transmission architecture. As illustrated, the transmission scanning station


300




a


comprises a lighting system


302




a


and a sensor system


304




a


. Lighting system


302




a


produces light


320




a


that is transmitted through the film


106


and measured by the sensor system


304




a


. The sensor system


304




a


produces sensor data


116




a


that is communicated to the data processing system


102


. Lighting system


302




a


and sensor system


304




a


are similar in design and function as lighting system


302


and sensor system


304


, respectively. Although

FIG. 4A

illustrates the light


320




a


being transmitted through the film


106


from the backside to the frontside of the film


106


, the light


320




a


can also be transmitted through the film


106


from the frontside to the backside of the film


106


without departing from the scope of the invention.




In one embodiment of the scanning station


300




a


, the light


320




a


produced by the lighting system


302




a


comprises visible light. The visible light


320




a


may comprise broadband visible light, individual visible light colors, or combinations of visible light colors. The visible light


320




a


interacts with any elemental silver and/or silver halide and at least one dye cloud within the film


106


.




In an embodiment in which the visible light


320




a


interacts with the magenta, cyan and yellow dye images within the film


106


, as well as elemental silver and/or silver halide within the film


106


, the sensor system


304




a


records the intensity of visible light


320




a


from the film


106


and produces sensor data


116




a


. The sensor data


116




a


generally comprises a red, green, and blue record corresponding to the magenta, cyan, and yellow dye images. Each of the red, green, and blue records includes a silver record. As previously discussed, the elemental silver and/or silver halide partially blocks the visible light


320




a


being transmitted through the film


106


. Accordingly, the red, green, and blue records are generally processed by the data processing system


102


to correct the records for the blockage caused by the elemental silver and/or silver halide in the film


106


.




In another embodiment of the transmission scanning station


300




a


, the light


320




a


produced by the lighting system


302




a


comprises visible light and infrared light. As discussed above, the visible light may comprise broadband visible light, individual visible light colors, or combinations of visible light colors. The infrared light may comprise infrared, near infrared, or any suitable combination. The visible light


320




a


interacts with the elemental silver and/or silver halide and at least one dye image, i.e. cyan, magenta, or yellow dye images, within the film


106


to produce a red, green, and blue record that includes a silver record. The infrared light interacts with the elemental silver and/or silver halide within the film


106


and produces a silver record. The silver image record can then be used to remove, at least in part, the silver metal record contained in the red, green, and blue records. In this embodiment, the silver is analogous to a defect that obstructs the optical path of the infrared light. The amount of blockage is used as a basis for modifying the color records. For example, in pixels having a high silver density, the individual color records are significantly increased, whereas in pixels having a low silver density, the individual color records are relatively unchanged.




In yet another embodiment of the transmission scanning station


300




a


, the light produced by the lighting system


302




a


comprises infrared or near infrared light. In this embodiment, the infrared light


320




a


interacts with the silver record in the film


106


but does not substantially interact with the dye images within the film


106


. In this embodiment, the sensor data


116




a


does not spectrally distinguish the magenta, cyan, and yellow dye images. An advantage of this embodiment is that the infrared light


320




a


does not fog the film


106


. In a particular embodiment, the advantage of not fogging the film


106


allows the film


106


to be scanned at multiple development times without negatively affecting the film


106


. In this embodiment, the scanning station


300




a


can be used to determine the optimal development time for the film


106


. This embodiment may optimally be used to determine the optimal development time of the film


106


, which can then be scanned using another scanning station


300







FIG. 4B

is a schematic diagram illustrating a scanning station


300




b


having a reflection architecture. The reflective scanning station


300




b


comprises a lighting system


302




b


and a sensor system


304




b


. Lighting system


302




b


produces light


320




b


that is reflected from the film


106


and measured by the sensor system


304




b


. The sensor system


304




b


produces sensor data


116




b


that is communicated to the data processing system


102


. Lighting system


302




b


and sensor system


304




b


are similar to lighting system


302


and sensor system


304


, respectively.




In one embodiment of the reflective scanning station


300




b


used to scan the blue emulsion layer of the film


106


, the light


320




b


produced by the lighting system


302




b


comprises blue light. In this embodiment, the blue light


320




b


scans the elemental silver and/or silver halide and dye image within the blue layer of the film


106


. The blue light


320




b


interacts with the yellow dye image and also the elemental silver and/or silver halide in the blue emulsion layer. In particular, the blue light


320




b


is reflected from the silver halide and measured by the sensor system


304




b


to produce a blue record. Many conventional films


106


include a yellow filter below the blue emulsion layer that blocks the blue light


320




a


from illuminating the other emulsion layers of the film


106


. As a result, noise created by cross-talk between the blue emulsion layer and the red and green emulsion layers is substantially reduced.




In another embodiment of the reflective scanning station


300




b


used to scan the blue emulsion layer of the film


106


, the light


320




b


produced by the lighting system


302




b


comprises non-blue light. It has been determined that visible light other than blue light interacts in substantially the same manner with the various emulsion layers. In this embodiment, infrared light also interacts in substantially the same manner as non-blue light, with the exception that infrared light will not fog the emulsion layers of the film


106


. In this embodiment, the non-blue light


320




b


interacts with the elemental silver and/or silver halide in the blue emulsion layer of the film


106


, but is transparent to the yellow dye within the blue emulsion layer of the film


106


. This embodiment is prone to higher noise levels created by cross-talk between the blue and green emulsion layers of the film


106


.




In yet another embodiment of the reflective scanning station


300




b


, the light


320




b


produced by the lighting system


302




b


comprises visible and infrared light. In this embodiment, blue light interacts with the yellow dye image and the elemental silver and/or silver halide in the blue emulsion layer, green light interacts with magenta dye image and the silver in the green emulsion layer, red light interacts with the cyan dye image and the silver in the red emulsion layer, and the infrared light interacts with the silver in each emulsion layer of the film


106


. In this embodiment, the sensor system


304




b


generally comprises a filtered detector


310




b


(not expressly shown) that measures the red, green, blue, and infrared light


320




b


from the film


106


to produce red, green, blue, and infrared records as sensor data


116




b.






Although the scanning station


300




b


is illustrated with the sensor system


304




b


located on front side of the film


106


, the sensor system


304




b


may also be located on the back side of the film


106


. In one embodiment, the light


320




b


produced by the lighting system


302




b


may comprise red light. The red light largely interacts with the cyan dye image and silver in the red emulsion layer of the film


106


to produce a red record of the sensor data


116




b.







FIG. 4C

is a schematic diagram illustrating a scanning station


300




c


having a transmission-reflection architecture. In this embodiment, the scanning station


300




c


comprises a first lighting system


302




c


, a second lighting system


302




d


, and a sensor system


304




c


. In the preferred embodiment, the lighting system


302




c


operates to illuminate the front side of the film


106


with light


320




c


, the second lighting system


302




d


operates to illuminate the backside of the film


106


with light


320




d


, and the sensor system


304




c


operates to measure the light


320




c


reflected from the film


106


and the light


320




d


transmitted through the film


106


. Based on the measurements of the light


320




b


,


320




d


, the sensor system


304




c


produces sensor data


116




c


that is communicated to the data processing system


102


. Lighting system


302




c


and


302




d


are similar to lighting system


302


, and sensor system


304




c


is similar to the sensor system


304


. Although scanning station


300




c


is illustrated with lighting systems


302




c


,


302




d


, a single light source may be used to produce light that is directed through a system of mirrors, shutters, filters, and the like, to illuminate the film


106


with the front side of the film


106


with light


320




c


and illuminate the back side of the film


106


with light


320




d


. The light


302




c


,


302




d


may comprise any color or color combinations, including infrared light.




This embodiment of the scanning station


300




c


utilizes many of the positive characteristics of the transmission architecture scanning station


300




a


and the reflection architecture scanning station


300




b


. For example, the blue emulsion layer is viewed better by light


320




c


reflected from the film


106


than by light


320




d


transmitted through the film


106


; the green emulsion layer is viewed better by light


320




d


transmitted through the film


106


than by light


320




c


reflected from the film


106


; and the red emulsion layer is adequately viewed by light


320




d


transmitted through the film


106


. In addition, the cost of the scanning station


300




c


is minimized through the use of a single sensor system


304




c.






In the preferred embodiment of the scanning station


300




c


, the light


320




c


comprises blue light, and light


320




d


comprises red, green, and infrared light. The blue light


320




c


interacts with the yellow dye image and silver in the blue emulsion layer of the film


106


. The sensor system


304




c


measures the light


302




c


from the film


106


and produces a blue-silver record. The red and green light


320




d


interacts with the cyan and magenta dye images, respectively, as well as the silver in the film


106


. The infrared light


320




d


interacts with the silver, but does not interact with the dye clouds within the film


106


. As discussed previously, the silver contained within the film


106


may comprise silver grains, silver halide, or both. The red, green, and infrared light


320




d


transmitted through the film


106


is measured by the sensor system


304




c


, which produces a red-silver, green-silver, and silver record. The blue-silver, red-silver, green-silver, and silver records form the sensor data


116




c


that is communicated to the data processing system


102


. The data processing system


102


utilizes the silver record to facilitate removal of the silver component from the red, green, and blue records.




In another embodiment, the light


320




c


comprises blue light and infrared light, and light


320




d


comprises red, green, and infrared light. As discussed previously, the blue light


320




c


mainly interacts with the yellow dye image and silver within the blue emulsion layer of the film


106


. The infrared light


320




c


interacts with mainly the silver in the blue emulsion layer of the film


106


. The sensor system


304




c


measures the blue and infrared light


320




c


from the film


106


and produces a blue-silver record and a front side silver record, respectively. The red, green, and infrared light


320




d


interact with the film


106


and are measured by the sensor system


304




c


to produce red-silver, green-silver and transmitted-silver records as discussed above. The blue-silver, red-silver, green-silver, and both silver records form the sensor data


116




c


that is communicated to the data processing system


102


. In this embodiment, the data processing system


102


utilizes the front side silver record of the blue emulsion layer to facilitate removal of the silver component from the blue-silver record, and the transmission-silver record is utilized to facilitate removal of the silver component from the red and green records.




Although the scanning station


300




c


is described in terms of specific colors and color combinations of light


320




c


and light


320




d


, the light


320




c


and light


320




d


may comprise other suitable colors and color combinations of light without departing from the scope of the invention. For example, light


320




c


may comprise non-blue light, infrared light, broadband white light, or any other suitable light. Likewise, light


320




d


may include blue light, broadband white light, or another other suitable light. Scanning station


300




c


may also comprise other suitable embodiments without departing from the scope of the invention. For example, although the scanning station


300




c


is illustrated with two lighting systems


302


and a single sensor system


304


, the scanning station


300




c


could be configured with a single lighting system


302


and two sensor systems


304


, wherein one sensor system measures light


320


reflected from the film


106


and the second sensory system


304


measures light


320


transmitted through the film


106


. In addition, as discussed above, the scanning station


300


may comprise a single lighting system that illuminates the film


106


with light


320




c


and light


320




d.







FIG. 4D

is a schematic diagram illustrating a scanning station


300




d


having a reflection-transmission-reflection architecture. In this embodiment, the scanning station


300




d


comprises a first lighting system


302




e


, a second lighting system


302




f


, a first sensor system


304




e


, and a second sensor system


304




f


. In the embodiment illustrated, the lighting system


302




e


operates to illuminate the front side of the film


106


with light


320




e


, the second lighting system


302




f


operates to illuminate the back side of the film


106


with light


320




f


, the first sensor system


304




e


operates to measure the light


320




e


reflected from the film


106


and the light


320




f


transmitted through the film


106


, and the second sensor system


304




f


operates to measure the light


320




f


reflected from the film


106


and the light


320




e


transmitted through the film


106


. Based on the measurements of the light


320




e


and


320




f


, the sensor systems


304




e


,


304




f


produce sensor data


116




ef


that is communicated to the data processing system


102


. Lighting systems


302




e


,


302




f


are similar to lighting systems


302


, and sensor systems


304




e


,


304




f


are similar to the sensor system


304


. Although scanning station


300




d


is illustrated with lighting systems


302




e


,


302




f


, and sensor systems


304




e


,


304




f


, a single lighting system and/or sensory system, respectively, may be used to produce light that is directed through a system of mirrors, shutters, filters, and the like, to illuminate the film


106


with the frontside of the film


106


with light


320




e


and illuminate the backside of the film


106


with light


320




f.






This embodiment of the scanning station


300




d


expands upon the positive characteristics of the transmission-reflection architecture of scanning station


300




c


. For example, as discussed in reference to

FIG. 4C

, the blue emulsion layer is viewed better by light


320




e


reflected from the film


106


and the green emulsion layer is viewed better by light


320




e


or


320




f


transmitted through the film


106


. Second scanning station


300




f


allows viewing of the red emulsion layer by light


320




f


reflected from the film


106


, which generally produces better results than viewing the red emulsion layer by light


320




e


or light


320




f


transmitted through the film


106


.




In the preferred embodiment of the scanning station


300




d


, the sensor systems


304




e


,


304




f


include a trilinear array of filtered detectors, and the light


320




e


and the light


320




f


comprises broadband white light and infrared light. The trilinear array operates to simultaneously measure the individual red, green, and blue components of the broadband white light


320




e


,


320




f


. The infrared light is measured separately and can be measured through each filtered detector


310


of the sensor systems


304




e


,


304




f


. The broadband white light


320




e


,


320




f


interacts with the silver and magenta, cyan, and yellow color dyes in the film


106


, respectively, and the infrared light


320




e


,


320




f


interacts with the silver within the film


106


. The first sensor system


304




e


measures the light


320




e


reflected from the front side of the film


106


and the light


320




f


transmitted through the film


106


, and the second sensor system


304




f


measures the light


320




f


reflected from the back side of the film


106


and the light


320




e


transmitted through the film


106


. The reflected white light


320




e


measured by the first sensor system


304




e


includes information corresponding to the yellow dye image and the silver in the blue emulsion layer of the film


106


. In particular, the blue component of the broadband white light


320




e


measured by the blue detector of the sensor system


304




e


corresponds to the yellow dye image, and the non-blue components of the broadband white light


320




e


measured by the red and green detectors corresponds to the silver within the blue emulsion layer of the film


106


. Similarly, the red component of the broadband white light


320




f


measured by the red detector of the sensor system


304




f


corresponds to the cyan dye image, and the non-red components of the broadband white light


320




e


measured by the blue and green detectors corresponds to the silver within the red emulsion layer of the film


106


. The white light


320




e


,


320




f


transmitted through the film


106


interacts with each color dye image within the film


106


and the red, green, and blue light components are measured by the red, green, and blue detectors of the sensor systems


304




e


,


304




f


to produce individual red, green and blue light records that include the silver. The infrared light


320




e


reflected from the film


106


and measured by the sensor system


304




e


corresponds to the silver in the blue emulsion layer of the film


106


, and the infrared light


320




f


reflected from the film


106


and measured by the sensor system


304




f


corresponds to the silver in the red emulsion layer of the film


106


. The infrared light


320




e


,


320




f


transmitted through the film


106


measured by the sensor systems


304




e


,


304




f


corresponds to the silver in the red, green, and blue emulsion layers of the film


106


. The individual measurements of the sensor systems


304




e


,


304




f


are communicated to the data processing system


102


as sensor data


116




d


. The data processing system


102


processes the sensor data


116




d


and constructs the digital image


108


using the various sensor system measurements. For example, the blue signal value for each pixel can be calculated using the blue detector data from the reflected light


320




e


and the blue detector data from the transmitted light


320




f


, as modified by non-blue detector data from the reflected light


320




e


, the infrared data from the reflected light


320




e


and the non-blue detector data from the transmitted light


320




f


. The red and green signal values for each pixel can be similarly calculated using the various measurements.




In another embodiment of the scanning station


300




d


, the sensor systems


304




e


,


304




f


include a trilinear array of filtered detectors, and the light


320




e


and the light


320




f


comprises broadband white light. This embodiment of the scanning station


300




d


operates in a similar manner as discussed above, with the exception that infrared light is not measured or used to calculate the digital image


108


. Although the scanning station


300




d


is described in terms of a specific colors and color combinations of light


320




e


and light


320




f


, the light


320




e


and light


320




f


may comprise other suitable colors and color combinations of light without departing from the scope of the invention. Likewise, the scanning station


300




d


may comprise other suitable devices and systems without departing from the scope of the invention.





FIG. 5A

is a flowchart of one embodiment of a method for developing and processing film. This method may be used in conjunction with one or more embodiments of the improved film processing system


100


that includes a data processing system


102


and a film processing system


104


having a transport system


120


, a development system


122


, and a scanning system


124


. The development system


122


includes an applicator station


200


for applying a processing solution


204


to the film


106


and a development station


202


. The scanning system


124


comprises a single scanning station


300


operable to scan the film


106


with light


320


having a frequency within the visible light spectrum and produce sensor data


116


that is communicated to the data processing system


102


. The data processing system


102


processes the sensor data


116


to produce a digital image


108


that may be output to an output device


110


.




The method begins at step


500


, where the transport system


120


advances the film


106


to the applicator station


200


. Film


106


is generally fed from a conventional film cartridge and advanced by the transport system


120


through the various stations of the film processing system


104


. At step


502


, processing solution


204


is applied to the film


106


. The processing solution


204


initiates production of silver and at least one dye image within the film


106


. The processing solution


204


is generally applied as a thin coating onto the film


106


, which is absorbed by the film


106


. At step


504


, the film


106


is advanced through the development station


202


where the dye images and silver grains develop within the film


106


. The environmental conditions, such as the temperature and humidity, are controlled within the development station


202


. This allows the film


106


to develop in a controlled and repeatable manner and provides the proper development time for the film


106


. At step


506


, the film


106


is scanned by the scanning system


124


. The light interacts with the film


106


and is sensed by sensor system


304


. As discussed in reference to

FIGS. 4A-4D

, the film


106


can be scanned in a number of different ways embodied in a number of different architectures, each with their own advantages. Sensor data


116


is produced by the scanning system


124


and communicated the data processing system


102


. At step


508


, the sensor data


116


is processed to produce the digital image


108


. The data processing system


102


includes image processing software


114


that processes the sensor data


116


to produce the digital image


108


. The digital image


108


represents the photographic image recorded on the film


106


. At step


510


, the digital image


108


is output to one or more output devices


110


, such as monitor


110




a


, printer


110




b


, network system


110




c


, storage device


110




d


, computer system


110




e


, and the like.





FIG. 5B

is a flowchart of another embodiment of a method for developing and processing film. This method may be used with one or more embodiments of the improved film processing system


100


that includes the development system


122


having the halt station


222


. This method is similar to the method described in

FIG. 5A

, with the exception that development of the film


106


is substantially stopped by the halt station


222


.




The method begins at step


520


, where the transport system


120


advances the film


106


to the applicator station


200


. At step


522


, processing solution


204


is applied to the film


106


. The processing solution


204


initiates production of elemental silver grains and at least one dye image within the film


106


. At step


524


, the film


106


is advanced through the development station


202


where the film


106


is developed. At step


526


, the continued development of the film


106


is retarded or substantially stopped by the halt station


222


. Retarding or substantially stopping the continued development of the film


106


allows the film


106


to be scanned using visible light


320


without fogging the film


106


during the scanning process. For example, if the development of the film


106


is stopped, the film


106


can be exposed to visible light without negatively affecting the scanning process. The halt station


222


may comprise a number of embodiments. For example, the halt station


222


may apply a halt solution


232


, such as a bleach solution, fixer solution, blix solution, stop solution and the like. The halt solution


232


may also operate to stabilize the film


106


. The halt station


222


may also comprise a wiper, drying system, cooling system and the like. At step


528


, the film


106


is scanned by the scanning system


124


using light


320


having at least one frequency within the visible portion of the electromagnetic spectrum, i.e., visible light. At step


530


, the sensor data


116


is processed to produce the digital image


108


. At step


532


, the digital image


108


is output to one or more output devices


110


, such as monitor


110




a


, printer


110




b


, network system


110




c


, storage device


110




d


, computer system


110




e


, and the like.




While the invention has been particularly shown and described in the foregoing detailed description, it will be understood by those skilled in the art that various other changes in form and detail may be made without departing from the spirit and scope of the invention.



Claims
  • 1. An aqueous developer solution for use in digital film processing, comprising:a developing agent; at least one surfactant; and at least one thickener; wherein said developer solution has a surface tension of less than about 30 dynes/cm and a viscosity of between about 5.000 and about 30.000 cP.
  • 2. The developer solution of claim 1, wherein said surfactant comprises a fluorosurfactant.
  • 3. The developer solution of claim 1, wherein said developer solution comprises a buffered solution having a pH greater than or equal to about 8.
  • 4. The developer solution of claim 3, further comprising at least one activator.
  • 5. The developer solution of claim 3, further comprising at least one restrainer.
  • 6. The developer solution of claim 3, further comprising at least one preservative.
  • 7. The developer solution of claim 3, further comprising at least one antifoggant or accelerator.
  • 8. The developer solution of claim 1, wherein said thickener comprises a solubilized cellulose.
  • 9. The developer solution of claim 1, wherein said developer solution has a surface tension of less than about 25 dynes/cm.
  • 10. The developer solution of claim 1, wherein the viscosity of said developer solution is between about 10,000 and about 20,000 cP.
  • 11. The developer solution of claim 1, wherein said developing agent comprising a color developing agent which reduces exposed silver halide grains in photographic film to metallic silver, and reacts with one or more dye precursors in photographic film to form a dye image.
  • 12. The developer solution of claim 11, further comprising a developing agent which is not a color developing agent.
  • 13. The developer solution of claim 1, wherein said developer solution comprises a non-Newtonian fluid.
  • 14. A method of processing a photographic film, comprising:(a) coating an aqueous developer solution containing a developing agent, at least one surfactant, and at least one thickener onto said film, wherein said developer solution has a surface tension of less than about 30 dynes/cm and a viscosity of between about 5,000 and about 30,000 cP, thereby developing said film; and (b) scanning said film through the coating of developer solution.
  • 15. The method of claim 14, wherein said surfactant comprises a fluorosurfactant.
  • 16. The method of claim 14, wherein said developer solution comprises a buffered solution having a pH greater than or equal to about 8.
  • 17. The method of claim 14, wherein said thickener comprises a solubilized cellulose.
  • 18. The method of claim 14, wherein said developer solution has a surface tension of less than about 25 dynes/cm.
  • 19. The method of claim 14, wherein the viscosity of said developer solution is between about 10,000 and about 20,000 cP.
  • 20. The method of claim 14, further comprising the step of coating at least one additional processing solution onto said film.
  • 21. The method of claim 20, wherein said additional processing solution is chosen from the group consisting of: a stop solution, an inhibitor solution, an accelerator solution, a bleach solution, a fixer solution, a blix solution, and a stabilizer solution.
  • 22. The method of claim 21, wherein said additional processing solution is coated onto said film prior to said scanning step.
  • 23. The method of claim 21, wherein said additional processing solution has a surface tension of less than about 30 dynes/cm.
  • 24. The method of claim 21, wherein the viscosity of said additional processing solution is between about 10,000 and about 30,000 cP.
  • 25. A film processing system comprising:a film loader operable to received exposed film; an applicator operable to coat 100-10,000 micrometers of a developer solution onto the film, wherein the developer solution includes a developing agents, at least one surfactant, and at least one thickener, and has a surface tension of less than about 30 dynes/cm and a viscosity of between about 5,000 and about 30,000 cP; and a scanning system operable to digitize at least one image contained on the film and produce at least one digital image.
  • 26. The film processing system of claim 25, wherein the scanning system operates to digitize at least one image contained on the film through the coating of developer solution.
  • 27. The film processing system of claim 26, wherein the developer solution is a liquid.
  • 28. The film processing system of claim 25, wherein the scanning system operates to digitize at least one image contained on the film with light within at least a portion of the visible portion of the electromagnetic spectrum.
  • 29. The film processing system of claim 28, wherein the scanning system also operates to digitize the at least one image contained on the film with light within the infrared portion of the electromagnetic spectrum.
  • 30. The film processing system of claim 25, further comprising a halt station operable to apply at least one additional processing solution onto the film.
  • 31. The film processing system of claim 30, wherein the at least one additional processing solution is chosen from the group consisting of: a stop solution, an inhibitor solution, an accelerator solution, a bleach solution, a fixer solution, a blix solution, and a stabilizer solution.
  • 32. The film processing system of claim 25, further comprising a development station operable to control the temperature and humidity of the film after the application of the developer solution.
  • 33. The film processing system of claim 25, further comprising a printer operable to print the at least one digital image.
  • 34. The film processing system of claim 33, wherein the printer is an ink jet type of printer.
  • 35. The film processing system of claim 25, further comprising a communication system operable to communicate the at least one digital image over a network.
  • 36. The film processing system of claim 35, wherein the network comprises the Internet.
  • 37. The film processing system of claim 25, further comprising a memory device operable to store the at least one digital image.
  • 38. The film processing system of claim 37, wherein the memory device is chosen from the group consisting of: a CD, a DVD, a removable hard drive; and an optical disk.
  • 39. The film processing system of claim 25, wherein the film processing system is embodied as a self-service kiosk.
  • 40. The film processing system of claim 25, wherein the film processing system is embodied as a photolab.
  • 41. A method for processing film comprising: receiving an exposed film; coating 100-10,000 micrometers of a developer solution onto the film, wherein the developer solution comprises a developing agent, at least one surfactant, and at least one thickener, and has a surface tension of less than about 30 dynes/cm and a viscosity between about 5,000 and about 30,000 cP; illuminating the film with light; measuring a light intensity from the film and producing sensor data; and processing the sensor data to produce at least one digital image.
  • 42. The method of claim 41, wherein the film is illuminated through the coating of developer solution.
  • 43. The method of claim 41, wherein the light is within at least a portion of the visible portion of the electromagnetic spectrum.
  • 44. The method of claim 43, wherein the light is also within the infrared portion of the electromagnetic spectrum.
  • 45. The method of claim 41, further comprising a applying at least one additional processing solution onto the film.
  • 46. The method of claim 45, wherein the at least one additional processing solution is chosen from the group consisting of: a stop solution, an inhibitor solution, an accelerator solution, a bleach solution, a fixer solution, a blix solution, and a stabilizer solution.
  • 47. The method of claim 41, further comprising controlling the temperature and humidity of the film after coating the film with developer solution.
  • 48. The method of claim 41, further comprising printing at least one digital image.
  • 49. The method of claim 41, further comprising communicating the at least one digital image over a network.
  • 50. The method of claim 49, wherein the network comprises the Internet.
  • 51. The method of claim 41, further comprising storing the at least one digital image on a memory device.
  • 52. The method of claim 51, wherein the memory device is chosen from the group consisting of: a CD, a DVD, a removable hard drive; and an optical disk.
CROSS REFERENCE TO RELATED APPLICATIONS

This application claims benefit under 35 U.S.C. §119(e) of U.S. Provisional Application Serial No. 60/267,913, entitled Digital Film Processing Solution and Method of Digital Film Processing, which was filed on Feb. 9, 2001.

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