DIRECT LIQUID INJECTOR DEVICE

Information

  • Patent Application
  • 20070194470
  • Publication Number
    20070194470
  • Date Filed
    February 19, 2007
    18 years ago
  • Date Published
    August 23, 2007
    17 years ago
Abstract
A device for mixing, vaporizing and communicating a precursor element in a highly conductive fashion to a remote processing environment. A supply meter admits a precursor liquid according to a piezo controlled valve, which communicates therewith for controlling flow into a mixing manifold. A vaporizer manifold in cooperation with a carrier gas supply provides a carrier gas for contemporaneous delivery into the mixing manifold. A vaporizing component having at least a heating element in communication with the mixing manifold, in cooperation with a mixing (frit) material provided in the vaporizer body, causes a phase change of the liquid precursor into a vapor output. Delivery of the vapor outlet occurs along at least one high conductance run/vent valve located downstream from the vaporizing body, typically built into the vaporizer manifold architecture, and provides for metering of the vapor into a remote process chamber.
Description

BRIEF DESCRIPTION OF THE DRAWINGS

Reference will now be made to the attached drawings, when read in combination with the following detailed description, wherein like reference numerals refer to like parts throughout the several views, and in which:



FIG. 1 is a perspective view of a single direct liquid injection DLI) device according to a first variant of the present inventions, and such as which can be incorporated into an atomic layer deposition (ALD) process associated with silicon wafer production;



FIG. 2 is a cross sectional illustration of the DLI device according to FIG. 1 and illustrating such features as manifold configuration for providing carrier gas inlet, the carrier gas/liquid interface in communication with the piezo valve controlled liquid vaporizer, the heating element, and the high conductance path vapor outlet controlled by the pair of run/vent valves;



FIG. 3 is a sectional perspective of the piezo controlled vaporizer component shown in FIG. 2;



FIG. 3A is a cutaway sectional perspective of the vaporizer component shown in FIG. 3;



FIG. 3B is an illustration of the piezo mixing valve assembled to the embarkation plate;



FIG. 3C is a further sectional perspective of an embarkation manifold component associated with the carrier annular region surrounding the liquid inlet port;



FIG. 3D is a cutaway sectional view of FIG. 3C;



FIG. 3E is a sectional perspective of the crossover manifold shown in FIG. 1 and in underlying communication with the inlet component of FIG. 3C;



FIG. 3F is a cutaway perspective of the crossover manifold shown in FIG. 3E



FIG. 4 is a perspective view of a vaporizer component base manifold illustrated in FIG. 1;



FIG. 4A is a cutaway sectional perspective of the manifold shown in FIG. 4;



FIG. 5 is a perspective view of a version of a bubbler component manifold;



FIG. 5A is a cutaway sectional perspective of the component manifold shown in FIG. 5;



FIG. 6 is a perspective view of the vaporizer component manifold shown in FIG. 1;



FIG. 6A is a cutaway sectional perspective of the vaporizer manifold shown in FIG. 6;



FIG. 7 is an assembled view of the heated cavity subassembly for assisting in phase change of the carrier gas/low vapor pressure liquid precursor mixture into the high conductance outlet vapor;



FIG. 7A is an exploded view of the heater subassembly of FIG. 7;



FIG. 8 is a perspective illustration of a further variant of a single direct liquid injection (DLI) device, illustrating a single bubbler component manifold installed and in joint communication with an associated pair of base manifolds;



FIG. 9 is a perspective illustration of a dual direct liquid injection (DLI) device according to a further variant of the present inventions;



FIG. 10 is a rotated perspective illustration of the device shown in FIG. 9;



FIG. 11 is a perspective illustration of the dual outlet manifold block according to a further sub-variant of the invention such as shown in FIG. 9 and illustrating both a central common path to an associated foreline, as well as first and second dilution inlets for associated first and second species of liquid injected precursor;



FIG. 11A is a cross sectional cutaway of the manifold block shown in FIG. 11;



FIG. 12 is a perspective illustration of a dual outlet, three base manifold DLI according to a yet further variant of the present inventions; and



FIG. 13 is a cross sectional view of FIG. 12 and showing the bubbler manifolds arranged atop the three base manifold configuration of FIG. 12.


Claims
  • 1. A direct liquid injector device comprising: a carrier gas inlet;a liquid metering valve delivering a liquid precursor into a volume of a carrier gas/liquid interface unit;a vaporizer body receiving a mixture of the liquid precursor and a carrier gas;a heating element in thermal contact with said vaporizer body;a matrix material within said vaporizer body;at least one high conductance run/vent valve located downstream from said vaporizing body for meter the mixture along a conduit for delivery into a remote process chamber.
  • 2. The device of claim 1, wherein the volume is located above said vaporizer body.
  • 3. The device of claim 1, wherein an annular gap allows the carrier gas to enter and sweep the liquid from the volume into said vaporizer body.
  • 4. The device of claim 1 further comprising a carrier gas heater.
  • 5. The device of claim 1 wherein said conduit is vertically displaced below said vaporizer body.
  • 6. The device of claim 1 wherein said conduit is linear.
  • 7. The device of claim 1 wherein said at least one high conductance run/vent valve further comprises at least one pair of valves.
  • 8. The device of claim 1 wherein the carrier gas flows downward through the volume into said vaporizing body.
  • 9. The device of claim 8 wherein said conduit extends orthogonal to a central axis of said vaporizing body.
  • 10. The device of claim 8 wherein said conduit extends parallel to a central axis of said vaporizing body.
  • 11. A device for mixing, vaporizing and communicating a precursor element in a highly conductive fashion to a remote processing environment, comprising: a supply meter for admitting a precursor liquid according to an associated rate;a control valve in communication with said supply meter for controlling said precursor liquid flow into a mixing manifold;a vaporizer manifold in cooperation with a carrier gas supply and providing a carrier gas for contemporaneous delivery into said mixing manifold;a vaporizing component including at least a heating element in communication with said mixing manifold and, in cooperation with a mixing material provided in said vaporizer body, causing a phase change of said liquid precursor into a vapor output; anddelivery of said vapor outlet along at least one high conductance run/vent valve located downstream from said vaporizing body for metering into a remote process chamber.
  • 12. The device as described in claim 11, further comprising at least one base manifold in communication with said bubbler manifold for delivery of said vapor.
  • 13. The device as described in claim 12, further comprising multiple base manifolds in communication with said bubbler manifold, at least one base manifold further comprising a diluted gas inlet line for further admixing said vapor.
  • 14. The device as described in claim 11, further comprising a secondary heating element in communication with said carrier gas supply prior to delivery to said mixing manifold.
  • 15. The device as described in claim 14, said heating elements each further comprising electrical coil resistance heaters associated with cavities through which at least one of said carrier gas and said pre-vaporous precursor/gas admixture passes.
  • 16. The device as described in claim 11, further comprising a bubbler manifold provided in cooperation with said vaporizer manifold for use with lower vapor pressure precursors.
  • 17. The device as described in claim 11, further comprising at least one pair of run/vent valves mounted to said vaporizer manifold in communicating with said downstream location from said vaporizing body.
  • 18. The device as described in claim 11, said mixing manifold having a specified shape and size and further comprising an annular shaped pathway which communicates said liquid precursor with a likewise circular shaped and mating configuration associated with a crossover manifold, the annular shaping of a cooperating gap created therebetween permitting carrier gas to enter and sweep the liquid into said mixing material including a heated frit located below, and without touching surrounding walls associated with said vaporizing component.
  • 19. The device as described in claim 18, further comprising said crossover manifold likewise incorporating a lengthwise path 66 extending to said annular shaped pathway communicating the carrier gas inlet.
  • 20. The device as described in claim 11, further comprising dual liquid injection supply meters, control valves and vaporizer manifolds for admixing and vaporizing at least one specific liquid precursor.
  • 21. The device as described in claim 20, further comprising a dual outlet, three base manifold exhibiting discrete outlets for two species of vapor created, with a common foreline connection.
  • 22. The device as described in claim 1, said vaporizer body further comprising at least one heated cavity arranged in communication with a crossover manifold and an embarkation manifold/control valve, each of said cavity and manifolds being sized and adapted for installation upon industry standard modular surface mount substrate components.
  • 23. The device as described in claim 11, further comprising said control valve utilizing a mechanical deformation of a piezo crystal in order to provide motion to said valve seat.
  • 24. The device as described in claim 11, said control valve utilizing an electromagnetic force to provide motion to said valve seat.
  • 25. The device as described in claim 11, said control valve utilizing a pneumatic actuation to provide motion to said valve seat.
  • 26. The device as described in claim 11, said supply meter further comprising an analog electronic sensing and control design.
  • 27. The device as described in claim 11, said supply meter further comprising a digital electronic sensing and control design
  • 28. A device for mixing, vaporizing and communicating a precursor element in a highly conductive fashion to a remote processing environment, comprising: a control valve in communication with said supply meter for controlling said precursor liquid flow into a mixing manifold;a vaporizer manifold in cooperation with a carrier gas supply and providing a carrier gas for contemporaneous delivery into said mixing manifold;a vaporizing component including at least a heating element in communication with said mixing manifold and, in cooperation with a mixing material provided in said vaporizer body, causing a phase change of said liquid precursor into a vapor output; anddelivery of said vapor outlet along at least one high conductance run/vent valve located downstream from said vaporizing body for metering into a remote process chamber.
  • 29. The device as described in claim 28, further comprising said control valve utilizing a mechanical deformation of a piezo crystal to provide motion to the valve seat.
  • 30. The device as described in claim 28, said control valve utilizing electromagnetic force to provide motion to said valve seat.
  • 31. The device as described in claim 28, said control valve utilizing pneumatic actuation to provide motion to said valve seat.
  • 32. The device as described in claim 28, said control valve further comprising a combination of analog and digital circuitry.
Provisional Applications (1)
Number Date Country
60774318 Feb 2006 US