(1) Field of the Invention
The invention concerns an electrical battery that is in particular intended for electrical or hybrid motor vehicle traction, that is to say comprising an electric motor driving the driven wheels combined with a thermal engine driving these wheels or possibly other driven wheels.
(2) Prior Art
In particular, the invention applies to a high degree of hybridisation of thermal vehicles which may go as far as complete electrification of the traction chain. In this case, the batteries do not then merely serve to assist the vehicles in the acceleration phases but also to provide movement of the vehicle autonomously over greater or lesser distances.
To guarantee the levels of power and energy required for the applications in question, it is necessary to create batteries comprising a plurality of electrical energy generating elements.
However, when these elements are charged and discharged, the result is a production of heat which, when it is not controlled, may have the effect of reducing the service life of the elements, or even giving rise, under extreme conditions, to risks of thermal runaway for certain chemical components of elements, leading to deterioration of the battery.
Thus, in order to optimize the performance and service life of the batteries, thermal conditioning systems for the elements are integrated in the batteries. In particular, the thermal conditioning systems may comprise a circulation path for a thermal conditioning liquid, said path being formed essentially around the generating elements.
In addition, in the automobile application envisaged, the efficacy of the systems must be high since the thermal dissipation peaks depend on the current densities and their variations, which may reach very high values, in particular during phases of high acceleration, regenerative breaking, rapid discharges of the battery or motorway functioning in electrical mode.
The generating elements conventionally comprise at least one electrochemical cell, for example of the lithium-ion or lithium-polymer type, which is formed by a stack of electroactive layers acting successively as cathodes and anodes, said layers being put in contact by means of an electrolyte.
These electrochemical cells are generally packaged in rigid, hermetically sealed containers in order to protect them from external attacks. In particular, these containers may be manufactured from deep-drawn metal sheets in order to form cups which, after the introduction of a winding of stacked layers, can be closed by welding of a cover.
This type of packaging has certain drawbacks, including high manufacturing costs as well as the need to electrically insulate at least one of the electrodes of the metal cup and to add discharge valves for releasing the pressure in the event of overcharging or overheating of an element.
To resolve these drawbacks, it has been proposed to form a generating element by packaging a flat stack of electroactive layers in a sealed flexible envelope. In addition, this type of generating element typically has a prismatic geometry that increases the exchange surfaces with the thermal conditioning liquid.
However, with such an envelope, the mechanical strength of the elements is significantly weakened, which runs counter to the current constraints in the automotive industry, in particular relating to crashes.
In addition, the stack is then liable to deform, in particular with movements of the layers with respect to one another. In particular, such a deformation may be caused by the change in the volume of the active materials serving as anodes or cathodes according to its lithium-ion insertion rate.
The result of these movements is variations in the contact resistances between said layers, said variations producing additional heating that may lead to premature aging, a limitation to the energy available and risks of triggering of thermal runaway.
The invention aims to improve the prior art by proposing an electrical battery that combines the advantages of the use of generating elements with a flexible element with a mechanical and thermal packaging system that improves the service life and safety of the battery both from the point of view of electrochemical behaviour and vis-a-vis current constraints in the automotive industry, and particular those concerning crashes.
To this end, the invention proposes an electrical battery comprising a plurality of electrical energy generating elements formed from at least one electrochemical cell packaged in a flexible sealed envelope, said battery also comprising a system for mechanical and thermal packaging of said elements, said packaging system forming a structural body made from heat-conducting material, said body having two longitudinal members and a plurality of cross-members connecting said longitudinal members so as to form between said cross-members housings in which respectively a generating element is disposed, said body including a circulation path for a thermal conditioning fluid, said path comprising two channels respectively upstream and downstream formed respectively in a longitudinal member and passages formed in each of the cross-members, said passages being in fluid communication on each side with respect to the upstream channel and the downstream channel.
Other particularities and advantages of the invention will emerge in the following description given with reference to the accompanying figures, in which:
In the description, the words positioning and space are taken with reference to the positioning of the battery shown in
In relation to the figures, an electrical battery is described below comprising a plurality of electrical energy generating elements 1 formed from at least one electrochemical cell 2 that is packaged in a flexible sealed envelope 3. In particular, the electrochemical cells 2 are of the lithium-ion or lithium-polymer type.
The battery is more particularly intended to supply a motor vehicle traction electric motor, whether it be a case of an electrical vehicle or of the electrical/thermal hybrid type. However, the battery according to the invention can also find its application for the storage of electrical energy in other transport modes, in particular in aeronautics. Moreover, in stationary applications such as for windmills, the battery according to the invention can also be used advantageously.
In relation to
The envelope 3 comprises two sheets, the top 6 and lateral 7 edges of which are heat-welded to each other and the bottom edges 8 of which are folded in order to form the bottom of said envelope. In particular the sheets are formed with a multi-layer film disposed around the stack of electroactive layers 4, said sheets enclosing said stack, in particular producing the vacuum inside the envelope 3 prior to heat welding.
Moreover, the film is optimized in order to resist electrolyte and solvent attacks, the heat welding being arranged to resist attacks by air and moisture in order to ensure longevity for the electrochemical cell 2. This is because the chemistry of the lithium-ion or lithium-polymer cells is sensitive to water and air, which leads to premature oxidation resulting in an increase in internal resistances and pressure inside the envelope 3.
The battery comprises a system for the mechanical and thermal packaging of the generating elements, said system make it possible firstly to condition said elements for temperature and secondly to hold them in a reinforcing structure. Thus the system provides the electrical safety of the battery vis-a-vis risks relating to temperature, the functioning of the battery in an optimum temperature range and safety relating to risks of crashes, which are inherent in the application particularly considered.
To provide the mechanical packaging, the system forms a structural body 9 made from conductive material, in particular metal such as aluminium, which also has the advantage of a low weight. Structural means that the body 9 provides the mechanical strength of the generating elements 1, in particular relating to the current test crash constraints in the automotive industry but also in relation to other forms of mechanical stresses that the battery has to undergo in a car.
The body 9 has two longitudinal members 10, 11 that extend longitudinally while being disposed laterally at each side of the battery. The body 9 also has a plurality of cross-members 12 that extend transversely while connecting said longitudinal members so as to form between said cross-members housings 13 in which respectively a generating element 1 is disposed.
In addition, in order to provide the thermal conditioning, the envelope 3 includes a circulation path for a thermal conditioning fluid, said path comprising two channels, respectively upstream 14 and downstream 15, which are formed respectively in a longitudinal member 10, 11, and passages 16 formed in each of the cross-members 12, said passages being in fluid communication on each side with respectively the upstream channel 14 and the downstream channel 15. Thus the cross-members 12 form heat exchangers between the generating elements 1 and one of the same channels 14, 15 serves respectively for the supply and discharge of fluid for the passages 16 of all the cross-members 12.
In the embodiments depicted, the cross-members 12 are adjacent longitudinally so as to form the housings 13 between them, the upstream 14 and downstream 15 channels extending longitudinally in respectively a longitudinal member 10, 11. In addition, a single housing element 13 is formed between two adjacent cross-members 12.
In addition, the battery can comprise a fluidtight vessel 17, in particular made from plastic, in which the structural body 9 and the generating elements 1 are disposed, said vessel being arranged to allow its installation in the vehicle. In addition, a vacuum can be produced inside the vessel 17 in order to increase the thermal insulation and to increase the service life of the generating elements 1 by limiting the migration of air and moisture over said elements.
The battery also comprises a device (not shown) for circulating said fluid so as to provide the thermal conditioning of the elements 1, for example a pump that pressurises the fluid in a closed circuit, and also possibly a heat exchanger.
More precisely, the battery comprises means of supplying the upstream channel 14 with fluid and means of discharging fluid from the downstream channel 15 after said fluid has passed through the cross-members 12. In particular the passages 16 of each of the cross-members 12 can thus be supplied in parallel by a single upstream channel 14, so that the fluid running through each of the cross-members 12 issues directly from the upstream channel 14, without previously having to pass through another cross-member 12. The result is therefore excellent homogeneity while avoiding the accumulation of heat related to a succession of heat exchangers.
The fluid may be a gas, in particular air, or a liquid, in particular a dielectric liquid with a low vapour tension, or water, possibly glycolated. Thermal conditioning means both adding and withdrawing heat so as to maintain the generating elements 1 in a temperature operating range that is optimum. In particular, the conditioning system makes it possible to rapidly and effectively provide an addition or withdrawal of heat in the battery, so as to ensure thermal regulation whatever the conditions of use.
According to an embodiment shown in particular in
To do this, the modules 18 shown comprise: two portions of longitudinal members 10, 11 in each of which a channel portion 14, 15 is formed; and a cross-member 12 on the edges of which respectively a longitudinal member portion 10, 11 is associated, the passages 16 of said cross-member being in fluid communication with said channel portions.
In addition, the association of the modules 18 is arranged so as to put the channel portions 14, 15 in fluid communication so as to form the upstream 14 and downstream 15 channels on each side of the passages 16.
In a variant shown in
In
In addition, the thickness of the frames 19 is greater than that of the plates 21 in order to form the housings 13 between two adjacent cross-members 12. In addition, the thickness of the hollow plate 21 is limited, for example around 0.5 mm, in order to promote heat exchanges with the generating elements 1 and contribute to the compactness of the battery.
Next the modules 18 are associated with one another, in particular forming means of association on the frame 19. In the embodiment shown in
In a variant that is not shown, the module can comprise a plate pressed so as to have a central part surrounded on each side by an opening, another plate being secured to the central part, forming fluid passages between said plates.
According to an embodiment in
More precisely, the size of the hollow of the male frame 19a is equal to the external dimension of the female frame 19b, so as to allow the embedding of said female frame in said hollow, putting the channel portions 14, 15 in fluid communication.
In particular, it is thus possible to produce a body 9: having excellent rigidity propitious to resistance to automobile vibration stresses, without risk of having screws loosening over time; intrinsically fluidtight and not requiring the addition of any seal the resistance over time of which is known to be open to improvement and for which it is difficult to guarantee efficacy in terms of sealing during severe mechanical stresses; compact and lightweight without needing to add screws; the assembly time of which is greatly reduced.
To allow dismantling of the modules 18, a specific tool (for example of the wheel puller type) can be used to exert a sufficient traction force on the assembly to disconnect said modules. In addition, a plastic ring 41 can advantageously be added at the interface between the frames 19. This being removed, for example by cutting, after each dismantling, in order to be replaced with a new one that will guarantee once again the mechanical quality of the body after reassembly.
The embodiment shown provides a first type of module 18a having two male hollow frames 19a and a second type of module 18b having two female hollow frames 19b, the structural body 9 being formed by the alternate embedding of each of the types of module 18a, 18b (see
In a variant not shown, each module 18 can have a male hollow frame 19a and a female hollow frame 19b, the structural body 9 being formed by the embedding of said modules in opposite orientations.
In the embodiment shown, the generating element 1 comprises two electrochemical cells 2 according to
In addition, the generating elements 1 can be bonded to the cross-members 12, in particular by means of a thermal adhesive, so as to improve the mechanical holding of the generating elements 1 in the housings 13 while assisting heat transfers between said elements and said cross-members. In addition, the generating elements 1 can be arranged in the housings 13 so as to limit the movements of the electroactive layers 4 with respect to one another.
As shown in
The packaging system also comprises a structural matrix 28 made from polymer resin, said matrix at least partially filling the housing 13 in order to clad the generating elements 1. Thus the generating elements 1 are held in the structural body 9 by the matrix 28, which also contributes to the mechanical strength of the whole.
In addition, the matrix 28 helps to limit the deformation of the generating elements 1 and therefore the possible increase in their internal strength. The matrix 28 also contributes to the fluidtightness of the envelope 3 and therefore to the protection of the electroactive layers 4 relative to the external environment (entry of moisture or air, leakage of electrolyte).
In addition, the matrix 28 can be thermally conductive in order also to fulfil a function of heat transfer between the generating elements 1 and the fluid circulating in the path, and/or electrically insulating for a function of electrical safety between said elements. Concerning the heat transfer, the important characteristic is the conductance, which is the ratio between the thermal conductivity of the matrix 28 and its thickness. In one example embodiment, the matrix 28 has a thermal conductivity of around 1 W/m/° C. and a thickness of around 2 mm.
As a polymer resin for the matrix 28, it is possible to use all types of polymer material having structural properties and in particular adhesives that have the advantage of increasing the rigidity of the battery and holding the generating elements 1 in said battery. The adhesives may for example be in the epoxy, silicone, polyurethane or acrylic etc family, to which inorganic components having thermal conduction properties can be added, such as Al2O3, AlN, MgO, ZnO, BeO, BN, Si3N4. SiC and/or SiO2. In one example embodiment, a two-component epoxy resin of the type reference 2605 from the company 3M can be used.
For using it, after arrangement of the generating elements 1 in the housings 13, the fluid resin is disposed in said housings, said resin then being solidified in order to form the structural matrix 28. To facilitate the recyclability of the battery, a coating of primer, containing a migrating agent, can also be applied to the surface of the generating elements 1. This migrating agent must be capable of migrating over one of the connection interfaces in order to generate a low-cohesion layer. This migration is made possible by thermal activation, which also makes it possible to dismantle the bonded assemblies. This migrating agent can also be used in a primer, but also in the resin itself. The migrating agent may for example be a polyolefin, or more particularly PTSH (paratoluenesulfohydrazide), which is known to provide separation by addition of heat as described in particular by the document WO-2004/087829.
In addition, the matrix 28 can have phase change properties in a range of temperatures improving the temperature conditioning of the generating elements 1. Moreover, the matrix 28 can also have self-extinguishing properties.
In the embodiment in
In relation to
The discharge of this overpressure prevents additional overheating that might lead to thermal runaway of the battery. In addition, this possibility of allowing the gases to escape becomes all the more important when the generating elements 1 are confined in a rigid environment that makes it possible to reduce the increases in internal resistance and thus improves their service life.
In the embodiment shown, a portion of the periphery of the envelope 3 is not clad in resin so as to form a rupture zone 29 located on a lateral edge 7 in the vicinity of the bottom 8, which is reinforced by bending. In addition, the bottom of the envelope 3 has no resin cladding. In a variant, not shown, the rupture zone can be formed mechanically, for example by scoring the envelope and/or the resin, or by a local reduction in the thickness of a cladding of resin surrounding the entire envelope 3.
In relation to
In
According to the invention, the excellent homogeneity in temperature in the battery makes it possible both to increase the level of equilibrium between the generating elements 1 and to be able to regulate the battery thermally with great precision in order to reduce as much as possible the internal resistances of the generating elements 1 without impairing their service life. The optimisation of thermal management then makes it possible to increase the energy and power of the battery, without having to add additional generating elements 1.
In addition, the conditioning system affords dissipation of the thermal energy coming from the thermal packaging of a generating element 1, without this excess heat being transferred to the adjacent generating elements 1 in a proportion that may lead to spread of the thermal runaway phenomenon. This thermal confinement role makes it possible to prevent the risks of thermal runaway propagating to the whole battery, which is very critical for high-energy batteries.
Moreover, the packaging system is capable of functioning with boiling water without risk of blockage of the channels 14, 15 or the passages 16; which has a great advantage for protection of the battery. This is because, in the event of fire or thermal runaway of a generating element 1, the water vaporisation phenomenon will make it possible to maintain the temperature of the battery at a fixed value, preventing the appearance of widespread runaway phenomena. This vaporisation temperature will depend on the nature of the fluid used, whether it be water or a fluid having a lower boiling point.
Number | Date | Country | Kind |
---|---|---|---|
08 01937 | Apr 2008 | FR | national |
Number | Name | Date | Kind |
---|---|---|---|
3246689 | Remde et al. | Apr 1966 | A |
3816181 | Buckethal | Jun 1974 | A |
3870563 | Ruben | Mar 1975 | A |
4107402 | Dougherty et al. | Aug 1978 | A |
4678725 | Kikuchi et al. | Jul 1987 | A |
5212025 | Shibata et al. | May 1993 | A |
5268242 | Morandi | Dec 1993 | A |
5278002 | Hiers | Jan 1994 | A |
5283137 | Ching | Feb 1994 | A |
5378552 | Dixon, Jr. | Jan 1995 | A |
5510203 | Hamada et al. | Apr 1996 | A |
5510207 | Grivel et al. | Apr 1996 | A |
5558960 | Mitchell | Sep 1996 | A |
5674640 | Mrotek et al. | Oct 1997 | A |
5756227 | Suzuki et al. | May 1998 | A |
5800945 | Grivel et al. | Sep 1998 | A |
5885732 | Verhoog | Mar 1999 | A |
5985483 | Verhoog et al. | Nov 1999 | A |
6013374 | Watanabe et al. | Jan 2000 | A |
6033800 | Ichiyanagi et al. | Mar 2000 | A |
6042961 | Verhoog et al. | Mar 2000 | A |
6444353 | Takaki et al. | Sep 2002 | B1 |
6482542 | Takaki et al. | Nov 2002 | B1 |
6569561 | Kimura et al. | May 2003 | B1 |
6864013 | Gow et al. | Mar 2005 | B2 |
20020028375 | Morishita et al. | Mar 2002 | A1 |
20030077516 | Macklin et al. | Apr 2003 | A1 |
20030232236 | Mitchell et al. | Dec 2003 | A1 |
20040069620 | Bitsche et al. | Apr 2004 | A1 |
20050170240 | German et al. | Aug 2005 | A1 |
20050170241 | German et al. | Aug 2005 | A1 |
20060127735 | Sabin et al. | Jun 2006 | A1 |
20090020620 | Douarre | Jan 2009 | A1 |
20090220850 | Bitsche et al. | Sep 2009 | A1 |
20100119926 | Gaben et al. | May 2010 | A1 |
20100119929 | Gaben et al. | May 2010 | A1 |
Number | Date | Country |
---|---|---|
19849491 | Jan 2000 | DE |
102007010742 | Aug 2008 | DE |
0522981 | Jan 1993 | EP |
0881696 | Dec 1998 | EP |
1397841 | Mar 2004 | EP |
2694136 | Jan 1994 | FR |
2742002 | Jun 1997 | FR |
2867613 | Sep 2005 | FR |
2870387 | Nov 2005 | FR |
2895838 | Jul 2007 | FR |
WO-9402969 | Feb 1994 | WO |
WO-0011730 | Mar 2000 | WO |
0227816 | Apr 2002 | WO |
WO-2006093010 | Sep 2006 | WO |
2006108529 | Oct 2006 | WO |
Number | Date | Country | |
---|---|---|---|
20090253026 A1 | Oct 2009 | US |