Patent Grant
12176579
This application claims the benefit of priority based on Korean Patent Application No. 10-2019-0056305, filed on May 14, 2019, and the entire contents of the Korean patent application are incorporated herein by reference.
The present invention relates to an electrode assembly capable of easily and accurately checking the tab folding and alignment of an electrode with the naked eye, and an inspection method thereof.
Secondary batteries that can be charged and discharged are attracting attention as a power source for devices requiring high power and large capacity, such as electric vehicles (EVs), hybrid electric vehicles (HEVs), and plug-in hybrid electric vehicles (Plug-In HEVs) that have been proposed as solutions to air pollution in diesel vehicles.
Typically, in terms of the shape of the battery, there is a high demand for a prismatic secondary battery and a pouch-type secondary battery that can be applied to products such as mobile phones with a small thickness. In terms of materials, there is a high demand for lithium secondary batteries such as lithium ion batteries and lithium ion polymer batteries having advantages such as high energy density, discharge voltage, and output stability.
Such secondary batteries are classified according to the structure of the electrode assembly having a positive electrode/separator/negative electrode structure. Representative examples thereof include a jelly-roll (wound) electrode assembly in which long sheet type positive electrodes and negative electrodes are wound with a separator interposed therebetween, a stacked electrode assembly in which a plurality of positive and negative electrodes cut in a predetermined size unit are sequentially stacked with a separator interposed therebetween, and a stacked/foldable electrode assembly in which bi-cells or full cells, in which positive and negative electrodes of a predetermined unit are stacked with a separator interposed therebetween, are wound with a separator sheet.
The secondary battery has a structure in which an electrode assembly made of a positive electrode, a negative electrode, and a separator interposed therebetween and an electrolyte are stored in a battery case. As the secondary battery is a device based on electrochemical reaction, it is inevitably sensitive to environmental factors. Further, since the secondary battery is manufactured through a series of processes in which small parts are precisely mounted and connected in a limited space, product quality may also deteriorate due to errors in some devices and incomplete work of some workers. In addition, in the manufacturing process of the secondary battery by the mass production system, serious defects may be caused by small defects in the process.
Accordingly, after every manufacturing process step and/or manufacturing finished products, inspection of the secondary battery should be closely conducted. This inspection is one of the most important parts in the production process of a secondary battery and is important in terms of quality control to check whether it provides desired performance and stability. Here, quality control is to check whether the secondary battery properly has a charge/discharge performance, produce good products, and select defective products. By performing such quality control well, it is possible to produce high quality secondary batteries.
Referring to
The plurality of positive electrode tabs 12 and 32 and negative electrode tab 22 are made of foil materials and may be tab-folded 12 as shown in
In addition, in the structure in which the electrode units 10 are stacked, the internal tab folding is not automatically inspected in appearance, and the internal short circuit caused by the tab folding is a fatal quality item that can cause stability issues and relies on manual inspection.
Particularly, as in an electrode assembly in which bi-cells of a positive electrode(negative electrode)/separator/negative electrode(positive electrode)/separator/positive electrode(negative electrode) structure are sequentially stacked and an electrode assembly in which full-cells of a positive electrode(negative electrode)/separator/negative electrode(positive electrode)/separator structure are sequentially stacked, in the electrode unit formed of a structure in which positive and negative electrodes are stacked in multiple layers, defects of the positions of internal electrodes cannot be checked, and it is difficult to find out defects such as electrode tab folding.
In order to solve the problems of the prior art as described above, an object of the present invention is to provide an electrode assembly capable of easily and accurately checking the tab folding and alignment of an electrode without disassembling the stacked electrode assembly, and an inspection method thereof.
An electrode assembly according to a first embodiment of the present invention has a structure in which at least one unit cell of a first electrode/a separator/a second electrode/separator/a third electrode structure is stacked, in which each of the first electrode and the third electrode includes a tab protruding toward an outer periphery of one side, and the second electrode includes a tab protruding toward an outer periphery of the other side facing the one side, each of the first electrode tab and the third electrode tab includes a through hole formed in an edge of one side, and an inclined portion forming a predetermined angle with respect to an virtual extension line extending from both outer peripheries adjacent to each other among outer peripheries of the tab in an edge of the other side, and the through hole of the first electrode tab and the inclined portion of the third electrode tab are arranged to overlap with each other.
At this time, the tab of the second electrode may be provided with a through hole in the edge of the one side and the edge of the other side facing the one side, respectively.
Further, the first electrode and the third electrode may have the same polarity, and the first electrode and the second electrode may have opposite polarities.
Further, an electrode assembly according to a second embodiment of the present invention has a structure in which at least one unit cell of a first electrode/a separator/a second electrode/separator structure is stacked, in which the first electrode includes a tab protruding toward an outer periphery of one side, and the second electrode includes a tab protruding toward an outer periphery of the other side facing the one side, and each of the first electrode tab and the second electrode tab includes a through hole formed in an edge of one side, and an inclined portion forming a predetermined angle with respect to an virtual extension line extending from both outer peripheries adjacent to each other among outer peripheries of the tab in an edge of the other side.
Further, in the electrode assembly, two or more of the unit cells may be stacked, the through hole of the first electrode tab in one unit cell and the inclined portion of the first electrode tab in an immediately adjacent unit cell may be arranged to overlap with each other, and the through hole of the second electrode tab in one unit cell and the inclined portion of the second electrode tab in an immediately adjacent unit cell may be arranged to overlap with each other.
Each of the inclined portions may be formed in a straight line forming the predetermined angle, and the predetermined angle is 10 to 80 degrees.
Each of the through holes may have a shape selected from the group consisting of a circle, a rectangle, and a square, respectively, and the shapes of the through holes may be the same.
In addition, a method for inspecting an electrode assembly according to the first embodiment of the present invention includes: a step of preparing the electrode assembly of claim 1; a step of vision-inspecting a shape of an inner surface of a through hole of a first electrode tab formed as the through hole of the first electrode tab overlaps with the inclined portion of the third electrode tab of the electrode assembly, and a shape of an inner surface of a through hole of the third electrode tab formed as the inclined portion of the first electrode tab overlaps with the through hole of the third electrode tab; and a step of determining whether the first electrode tab or the third electrode tab is folded from a result of the vision inspection.
In the step of determining whether the first electrode tab or the third electrode tab is folded, whether the first electrode tab or the third electrode tab is folded may be determined by determining whether the shape of the inner surface of the through hole of the first electrode tab and the shape of the inner surface of the through hole of the third electrode tab are symmetrical with respect to a longitudinal direction of the tab.
Further, if two or more unit cells are stacked in the electrode assembly, the method may further include: a step of measuring an area of inner surfaces of through holes after the vision-inspecting step; and a step of determining whether a position of the electrode tab is defective from the measured area.
In the step of determining whether the position is defective, the electrodes may be arranged to allow the areas of the inner surfaces of the through holes to coincide with each other.
Meanwhile, a method for inspecting an electrode assembly according to the second embodiment of the present invention may include: a step of vision-inspecting shapes of inner surfaces of through holes of a plurality of electrode tabs having the same polarity; and a step of determining whether the electrode tabs are folded from a result of the vision inspection.
In the step of determining whether the electrode tabs are folded, whether the electrode tabs are folded may be determined by determining whether the shapes of the inner surfaces of the two through holes are symmetrical to each other in a longitudinal direction of the tabs.
Further, after the vision-inspecting step, the method may further include: a step of measuring areas of the inner surfaces of the through holes; and a step of determining whether a stacking is defective from the measured area.
According an embodiment of the present invention, the electrode assembly according to the present invention has the advantage that it is possible to easily and accurately check the alignment of the electrode as well as the folding of the tab without disassembling the stacked electrodes and separators. Accordingly, during the manufacturing process of the secondary battery, the tab folding and alignment of the electrode assembly can be automatically inspected and checked.
As such, according to the electrode assembly and inspection method according to the present invention, despite the structure of multiple layers of positive and negative electrodes, it is possible to inspect the internal electrode position and automatically inspect defects such as internal electrode tab folding, thereby improving the ability to discriminate defective products.
As the inventive concept allows for various changes and numerous embodiments, particular embodiments will be illustrated in the drawings and described in detail in the text. However, this is not intended to limit the present invention to the specific form disclosed, and it should be understood to include all changes, equivalents, and substitutes included in the spirit and scope of the present invention.
In describing the drawings, similar reference numerals are used for similar elements. In the accompanying drawings, the dimensions of the structures are shown in an enlarged scale for clarity of the invention. Terms such as “first” and “second” may be used to describe various components, but the components should not be limited by the terms. The terms are used only for the purpose of distinguishing one component from another. For example, without departing from the scope of the present invention, a first component may be referred to as a second component, and similarly, the second component may also be referred to as the first component. Singular expressions include plural expressions unless the context clearly indicates otherwise.
In this application, it should be understood that terms such as “include” or “have” are intended to indicate that there is a feature, number, step, operation, component, part, or a combination thereof described on the specification, and they do not exclude in advance the possibility of the presence or addition of one or more other features or numbers, steps, operations, components, parts or combinations thereof. Also, when a portion such as a layer, a film, an area, a plate, etc. is referred to as being “on” another portion, this includes not only the case where the portion is “directly on” the another portion but also the case where further another portion is interposed therebetween. On the other hand, when a portion such as a layer, a film, an area, a plate, etc. is referred to as being “under” another portion, this includes not only the case where the portion is “directly under” the another portion but also the case where further another portion is interposed therebetween. In addition, to be disposed “on” in the present application may include the case disposed at the bottom as well as the top.
Hereinafter, an electrode assembly according to an embodiment of the present invention will be described in detail with reference to the drawings.
As illustrated in
As shown in
In the present invention, the bi-cell is a concept including both A-type and C-type bi-cells. The A-type bi-cell means a bi-cell having a positive electrode/separator/negative electrode/separator/positive electrode structure, and the C-type bi-cell means a bi-cell having a negative electrode/separator/positive electrode/separator/negative electrode structure. In addition, the positive electrode and the negative electrode should be understood as a concept including a double-sided positive electrode coated with a positive electrode active material on both sides of the current collector, and a double-sided negative electrode coated with a negative electrode active material on both sides of the current collector.
Referring to
The first electrode tab 130 may be provided with a through hole 131 formed at one edge of the second direction DR2, and an inclined portion 132 at the other edge of the second direction DR2. Here, as shown in
The second electrode 200 may have a second active material layer, which is generated active materials 221 and 222 are applied to both surfaces of the second electrode current collector 210, and have a second electrode tab 230 protruding toward the other outer periphery of the first direction DR1. In this case, the second electrode tab 230 may be provided with a pair of through holes 231 and 232 formed at both edges of the second direction DR2.
The third electrode 300 may have a third active material layer, which is generated active materials 321 and 322 are applied to both surfaces of the third electrode current collector 310, and have a third electrode tab 230 protruding toward one outer periphery of the first direction DR1.
The third electrode tab 330 may have a through hole 331 formed at one edge in the second direction DR2 and an inclined portion 332 at the other edge in the second direction DR2 as in the first electrode tab. Here, as shown in
Meanwhile, the first electrode 100 and the third electrode 300 have the same polarity, and the first electrode 100 and the second electrode 200 have opposite polarities.
In addition, the through holes 131, 231, 232, and 331 formed in the first electrode tab 130 to the third electrode tab 330 may each have a shape selected from the group consisting of a circle, a rectangle, and a square, and the shape of the through holes 131, 231, 232, and 331 may be the same.
In addition, as shown in
As illustrated in
As described above, as the through hole 131 of the first electrode tab 130 overlaps with the inclined portion 332 of the third electrode tab 330, the shape of the inner surface of the through hole 131 of the first electrode tab 130 is formed in a semicircle shape. In addition, as the inclined portion 132 of the first electrode tab 130 overlaps with the through hole 331 of the third electrode tab 330, the shape of the inner surface of the through hole 331 of the third electrode tab 330 is formed in a semicircle shape.
At this time, the shape of the inner surface of the through hole 131 of the first electrode tab 130 and the shape of the inner surface of the through hole 331 of the third electrode tab 330 are symmetrical with respect to the first direction DR1. In this case, it can be confirmed that there is no folding of the first electrode tab 130 or the third electrode tab 330.
Accordingly, it is possible to check whether the electrode tabs 130 and 330 are folded through the overlapping shape of the through holes 131 and 331 and the inclined portions 132 and 332.
On the other hand, referring to
Further, referring to
In addition, referring to
Hereinafter, an inspection method of the electrode assembly 1000 according to an embodiment of the present invention will be described in detail with reference to the drawings.
The inspection method of the electrode assembly 1000 may include: preparing the above-described electrode assembly 1000 (S100); vision-inspecting a shape of the inner surface of the through hole 131 of the first electrode tab 130, which is formed as the through hole 131 of the first electrode tab 130 of the electrode assembly 1000 overlaps with the inclined portion 332 of the third electrode tab 330, and a shape of the inner surface of the through hole 331 of the third electrode tab 330, with naked eyes (S200); and checking whether the first electrode tab 130 or the third electrode tab 330 is folded from the result of the vision inspection (S300).
Specifically, the step (S200) of visual inspection with the naked eye may include inspecting the inner surface shapes of the through holes 131 and 331 of the first electrode tab 130 and the third electrode tab 330 with the naked eye from the front, based on the third direction DR3 of the first electrode 100 of the electrode assembly 1000.
In addition, in the step (S300), it is possible to check whether or not the tab is folded by checking whether the shape of the inner surface of the through hole 131 of the first electrode tab 130 and the shape of the inner surface of the through hole 331 of the third electrode tab 330 are symmetrical based on the first direction (DR1), which is the longitudinal direction of the tab.
At this time, as shown in
On the other hand, as shown in
Referring to
Referring to
Meanwhile, as shown in
In the step of measuring the area (S210), the area of the inner surfaces of the through holes 131 and 331 may be measured using a light-transmitting sensor, but is not limited thereto. As the through hole of one electrode tab overlaps with the inclined portion of the other electrode tab, the through hole becomes a semicircle shape. At this time, the area of the empty space excluding the area occupied by the inclined portion is called the area of the inner surface. Referring to
In addition, as the left through hole 231 of the second electrode tab 230 overlaps with the inclined portion of the sixth electrode tab 330′, an empty space excluding the inclined portion is formed, and the area D3 of the inner surface, which is the empty space, can be measured. Further, as the right through hole 232 of the second electrode tab 230 overlaps with the inclined portion of the fourth electrode tab 130′, an empty space excluding the inclined portion is formed, and the area D4 of the inner surface, which is the empty space, can be measured. In addition, it is possible to check whether the positions of the electrode tabs are defective according to whether D3 and D4 match.
Specifically, when light is emitted from the light-transmitting sensor to the front surface of the third direction DR3 of the first electrode 100 of the electrode assembly 1000, the light passing through the electrode assembly 1000 does not transmit the electrode tabs and transmits the inner surface which is not overlapped by the inclined portion in the through holes. As such, the area of the inner surface of the through holes can be measured.
Herein, in the step (S220), it can be determined whether the positions of the electrodes are defective by checking whether the inner surface areas of the through holes 131 and 331 of the first electrode tab 130 and the third electrode tab 330 measured through the light-transmitting sensor coincide with each other and whether the inner surface areas of the through holes 231 and 232 of the second electrode tab coincide with each other. That is, when the inner surfaces of the through holes coincide with each other, it can be confirmed that the alignment of the electrodes is good. On the other hand, if the inner surfaces of the through holes do not coincide with each other, the electrodes are misaligned, so that the first to sixth electrodes can be aligned so that the areas of the inner surfaces of the through holes coincide with each other.
As described above, the electrode assembly according to the present invention has the advantage that it is possible to easily and accurately check the tab folding of the electrode and the misaligned position due to the poor stacking of the unit cells without disassembling the stacked electrodes and separators. Accordingly, during the manufacturing process of the secondary battery, the tab folding and alignment of the electrode assembly can be automatically inspected and checked.
Hereinafter, an electrode assembly according to another embodiment of the present invention will be described in detail with reference to the drawings.
As illustrated in
Referring to
In the electrode assembly 2000 of the full-cell structure of
The first electrode tab 630 may be provided with a through hole 631 formed at one edge of the second direction DR2, and an inclined portion 632 at the other edge of the second direction DR2. Here, the inclined portion 632 may have a structure that forms a predetermined angle with respect to virtual extension lines (not shown) respectively extending both outer peripheries adjacent to each other among the outer peripheries of the first electrode tab 630. In addition, the inclined portion 632 is made of a straight line forming a predetermined angle, and the predetermined angle may be 10 to 80 degrees.
The second electrode 700 may have a second active material layer, which is generated active materials 721 and 722 are applied to both surfaces of the second electrode current collector 710, and have a second electrode tab 730 protruding toward the other outer periphery of the first direction DR1. That is, the first electrode tab 630 and the second electrode tab 730 are structures protruding in opposite directions based on the first direction DR1.
At this time, the second electrode tab 730 may be provided with a through hole 731 formed at one edge of the second direction DR2, and an inclined portion 732 at the other edge of the second direction DR2. Here, the inclined portion 732 may have a structure that forms a predetermined angle with respect to virtual extension lines (not shown) respectively extending both outer peripheries adjacent to each other among the outer peripheries of the second electrode tab 730. In addition, the inclined portion 732 is made of a straight line forming a predetermined angle, and the predetermined angle may be 10 to 80 degrees.
Meanwhile, the electrode assembly 3000 of
The first electrode 800 of the full cell, which is the unit cell located at the bottom, is coated with active materials 821 and 822 on both sides of the first electrode current collector 810 to form a first active material layer 820, and includes a first electrode tab 830 protruding toward an outer periphery of one side of the first direction DR1.
The first electrode tab 830 may be provided with a through hole 831 formed at one edge of the second direction DR2, and an inclined portion 832 at the other edge of the second direction DR2. Here, the inclined portion 832 may have a structure that forms a predetermined angle with respect to virtual extension lines (not shown) respectively extending both outer peripheries adjacent to each other among the outer peripheries of the first electrode tab 830. In addition, the inclined portion 832 is made of a straight line forming a predetermined angle, and the predetermined angle may be 10 to 80 degrees.
The second electrode 900 of the full cell, which is the unit cell located at the bottom, is coated with active materials 921 and 922 on both sides of the second electrode current collector 910 to form a second active material layer 920, and includes a second electrode tab 930 protruding toward an outer periphery of one side of the first direction DR1.
At this time, the second electrode tab 930 may be provided with a through hole 931 formed at one edge of the second direction DR2, and an inclined portion 932 at the other edge of the second direction DR2. Here, the inclined portion 932 may have a structure that forms a predetermined angle with respect to virtual extension lines (not shown) respectively extending both outer peripheries adjacent to each other among the outer peripheries of the second electrode tab 930. In addition, the inclined portion 932 is made of a straight line forming a predetermined angle, and the predetermined angle may be 10 to 80 degrees.
Meanwhile, the first electrode 600 has the same polarity as that of the first electrodes 800 in an adjacent unit cell (full cell), the second electrode 700 has the same polarity as that of the second electrode 900 in an adjacent unit cell (full cell), and the first electrodes 600 and 800 and the second electrodes 700 and 900 have the opposite polarities.
In addition, the through holes 631, 731, 831, and 931 formed in the first electrode tab 630 to the second electrode tab 930 may each have a shape selected from the group consisting of a circle, a rectangle, and a square, and the shape of the through holes 631, 731, 831, and 931 may be the same.
Referring to
Referring to
In addition, the through hole 731 of the second electrode tab 730 protruding in the opposite direction to the first electrode tab may be disposed to overlap with the inclined portion 932 of the first electrode tab 930 of the adjacent unit cell, and the inclined portion 732 of the second electrode tab 730 may be disposed to overlap with the through hole 931 of the second electrode tab 930 of the adjacent unit cell.
As described above, as the through hole 631 of the first electrode tab 630 overlaps with the inclined portion 832 of the first electrode tab 830 of the adjacent unit cell, the shape of the inner surface of the through hole 631 of the first electrode tab 630 is formed in a semicircular shape. In addition, as the inclined portion 632 of the first electrode tab 630 overlaps with the through hole 831 of the first electrode tab 830 of the adjacent unit cell, the shape of the inner surface of the through hole 831 of the first electrode tab 830 of the adjacent unit cell is formed in a semicircle shape.
At this time, the shape of the inner surface of the through hole 631 of the first electrode tab 630 and the shape of the inner surface of the through hole 831 of the first electrode tab 830 of an adjacent unit cell are symmetrical with respect to the first direction DR1. In this case, it can be confirmed that there is no folding of the fourth electrode tab 630 or the sixth electrode tab 630.
The second electrode tab 730 and the second electrode tab 930 of the adjacent unit cell are only opposite to the first electrode tabs 630 and 830 in their directions, but the shapes in which the through holes and the inclined portions overlap are the same as described above.
Accordingly, it is possible to check whether the electrode tabs 630, 730, 830, and 930 are folded through the shape in which the through holes 631, 731, 831, and 931 and the inclined portions 632, 732, 832, and 932 overlap.
Hereinafter, an inspection method of the electrode assembly 3000 according to an embodiment of the present invention will be described in detail with reference to the drawings.
The method for inspecting the electrode assembly 3000 may include: a step of preparing the electrode assembly 3000; a step of vision-inspecting the shape of the inner surface of the through hole 631 of the first electrode tab 600, which is formed as the through hole 631 of the first electrode tab 600 of the electrode assembly 3000 overlaps with the inclined portion 832 of the first electrode tab 800 of the adjacent unit cell; and a step (S700) of determining whether the first electrode tab to the second electrode tabs 630, 730, 830 and 930 are folded from the result of the vision inspection.
Specifically, the step (S600) of visual inspection with the naked eye may include inspecting the inner surface shapes of the through holes 631, 731, 831 and 931 of the first electrode tab to the second electrode tabs 630, 730, 830 and 930 with the naked eye from the front, based on the third direction DR3 of the first electrode 600 of the electrode assembly 3000.
Further, in the step (S700) of determining whether the tab folding has occurred, whether the tab folding has occurred may be determined by determining whether the shape of the inner surface of the through hole 631 of the first electrode tab 630 and the shape of the inner surface of the through hole 831 of the first electrode tab 800 of the adjacent unit cell are symmetrical with each other based on the first direction DR1 which is the longitudinal direction of the tab and whether the shape of the inner surface of the through hole 731 of the second electrode tab 700 and the shape of the inner surface of the through hole 931 of the second electrode tab 900 of the adjacent unit cell are symmetrical with each other in the first direction which is the longitudinal direction of the tab.
At this time, as shown in
On the other hand, in the case that the shape of the inner surface of the through hole 631 of the first electrode tab 630 and the shape of the inner surface of the through hole 831 of the first electrode tab 830 of an adjacent unit cell are asymmetrical with respect to the first direction DR1, it can be confirmed that there is no folding of the first electrode tab 630 or the first electrode tab 630 of an adjacent unit cell. This also applies to the shape of the inner surface of the through hole 731 of the second electrode tab 730 and the shape of the inner surface of the through hole 931 of the second electrode tab 930 of the adjacent unit cell.
Further, after the vision inspection step (S500), the step (S510) of measuring the areas of the inner surfaces of the through holes 631, 731, 831 and 931 of the first electrode tabs 630 and 830 and the second electrode tabs 730 and 930; and a step (S520) of determining whether positions of the first electrode tabs 630 and 830 and the third electrode tabs 730 and 930 are defective from the measured areas may be further included.
In the step of measuring the area (S510), the areas of the inner surfaces of the through holes 631, 731, 831 and 931 of the first electrode tabs 630 and 830 and the second electrode tabs 730 and 930 may be measured using a light-transmitting sensor, but is not limited thereto.
In the step (S520) of checking whether the position is defective, poor stacking or poor positioning of electrodes can be checked by checking whether the inner surface areas of the through holes 631, 731, 831 and 931 of the first electrode tabs 630 and 830 and the second electrode tabs 730 and 930 measured by the light-transmitting sensor match each other.
Specifically, when the inner surface areas of the through holes 631 and 831 coincide with each other, and the inner surface areas of the through holes 731 and 931 coincide with each other, it can be confirmed that the alignment of the electrodes is good. On the other hand, if the inner surfaces of the through holes do not coincide with each other, the electrodes are misaligned, so that the electrodes can be aligned so that the areas of the inner surfaces of the through holes coincide with each other.
As described above, the electrode assembly according to the present invention has the advantage that it is possible to easily and accurately check the alignment of the electrode as well as the folding of the tab without disassembling the stacked electrodes and separators. Accordingly, during the manufacturing process of the secondary battery, the tab folding and alignment of the electrode assembly can be automatically inspected and checked.
As such, according to the electrode assembly and inspection method according to the present invention, despite the structure of multiple layers of positive and negative electrodes, it is possible to inspect the internal electrode position and automatically inspect defects such as internal electrode tab folding, thereby improving the ability to discriminate defective products.
Although the above has been described with reference to a preferred embodiment of the present invention, it can be understood that those skilled in the art can make various modifications and changes to the present invention without departing from the spirit and scope of the invention as set forth in the claims below.
Therefore, the technical scope of the present invention should not be limited to the contents described in the detailed description of the specification but should be defined by the claims.
| Number | Date | Country | Kind |
|---|---|---|---|
| 10-2019-0056305 | May 2019 | KR | national |
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/KR2020/005826 | 5/4/2020 | WO |
| Publishing Document | Publishing Date | Country | Kind |
|---|---|---|---|
| WO2020/231054 | 11/19/2020 | WO | A |
| Number | Name | Date | Kind |
|---|---|---|---|
| 5246797 | Imhof | Sep 1993 | A |
| 5667915 | Loustau | Sep 1997 | A |
| 20020195990 | Yang | Dec 2002 | A1 |
| 20030013012 | Ahn | Jan 2003 | A1 |
| 20090263709 | Nakamura | Oct 2009 | A1 |
| 20110014521 | Matsuyama | Jan 2011 | A1 |
| 20130196210 | Kim | Aug 2013 | A1 |
| 20150162590 | Takahashi et al. | Jun 2015 | A1 |
| Number | Date | Country |
|---|---|---|
| 101490873 | Jul 2009 | CN |
| 206293534 | Jun 2017 | CN |
| 06-11258 | Feb 1994 | JP |
| 2000-195539 | Jul 2000 | JP |
| 2004-079240 | Mar 2004 | JP |
| 2005-149882 | Jun 2005 | JP |
| 2006-032224 | Feb 2006 | JP |
| 2006-128038 | May 2006 | JP |
| 2006-164752 | Jun 2006 | JP |
| 2009-283342 | Dec 2009 | JP |
| 2011-108534 | Jun 2011 | JP |
| 2014-049193 | Mar 2014 | JP |
| 2017-084654 | May 2017 | JP |
| 10-1997-0054628 | Jul 1997 | KR |
| 10-2013-0116835 | Oct 2013 | KR |
| 10-2015-0061997 | Jun 2015 | KR |
| 10-2015-0072234 | Jun 2015 | KR |
| 2016-0079227 | Jul 2016 | KR |
| 10-1805529 | Nov 2017 | KR |
| 10-2018-0097243 | Aug 2018 | KR |
| 10-2018-0106367 | Oct 2018 | KR |
| 10-2019-0086942 | Jul 2019 | KR |
| 2015186169 | Dec 2015 | WO |
| Entry |
|---|
| Extended European Search Report dated Feb. 4, 2022 issued by the European Patent Office in a corresponding European Patent Application No. 20806202.6. |
| Number | Date | Country | |
|---|---|---|---|
| 20210344085 A1 | Nov 2021 | US |
