Electronic cigarette and method

Information

  • Patent Grant
  • 10780236
  • Patent Number
    10,780,236
  • Date Filed
    Friday, December 29, 2017
    6 years ago
  • Date Issued
    Tuesday, September 22, 2020
    4 years ago
Abstract
An electronic smoking article includes a liquid supply including liquid material, a heater operable to heat the liquid material to a temperature sufficient to vaporize the liquid material and form an aerosol, a wick in communication with the liquid material and in communication with the heater such that the wick delivers the liquid material to the heater, and at least one air inlet operable to establish a predetermined resistance to draw under a prescribed test of said smoking article.
Description
SUMMARY OF SELECTED FEATURES

An electronic cigarette or cigar (collectively “smoking article”) is provided which includes a heater element which vaporizes liquid material to produce an aerosol or “vapor”. The heater element preferably comprises a resistive heater coil, with a wick extending therethrough. The heater coil is constructed in a manner and formed from a material such that the production of hot spots and excessive temperatures are avoided during a puff.


The electronic article preferably includes a mouth end insert that includes at least two, diverging outlets to impart a fuller mouthfeel from the vapor output. Preferably, the aforementioned multi-ported mouth end insert cooperates with a gasket. Upon being drawn through the gasket, the vapor output enters a space just upstream of the mouthpiece which allows the air stream to expand and decelerate before entering the passages of the mouth piece insert so as to substantially avoid perceptions of “hot” at or about the lips of the “smoker”.


The electronic article preferably includes a metal case portion and a precision-formed primary, air inlet port at a location along the metal case portion, preferably along a metal side wall portion of the article. The air inlet port is precision-formed within close tolerances and the air inlet port is sized so as to be the predominating source of pressure drop along an air pathway of communication between the air inlet and the source of vapor (the heater). Such arrangement assures that RTD remains essentially the same from one puff to the next and from one article to the next. To further enhance consistent performance, RTD of an article is checked in the course of its manufacture, and corrective measure undertaken, if necessary.





BRIEF DESCRIPTION OF THE DRAWINGS


FIG. 1 is a top planar view of an electronic cigarette according to a first embodiment;



FIG. 2 is a side cross-sectional view of the electronic cigarette shown in FIG. 1;



FIG. 3a is an exploded, perspective view of elements comprising the cartridge section of the electronic cigarette shown in FIG. 1;



FIG. 3b is a detailed view of an air inlet port of the cartridge section of the electronic cigarette shown in FIG. 1;



FIG. 4 is a perspective view of the mouth end insert of the electronic cigarette shown in FIG. 1;



FIG. 5 is a cross-sectional view along line A-A of the mouth end insert of FIG. 4;



FIG. 6 is a perspective view of an alternative embodiment of the mouth end insert of the electronic cigarette shown in FIG. 1;



FIG. 7 is a cross-sectional view along line B-B of the mouth end insert of FIG. 6;



FIG. 8 is an enlarged detail view of the heater assembly of the electronic cigarette shown in FIG. 1;



FIG. 9A is an enlarged view of the inner tube with a heater coil and wick assembly in position prior to positioning of a closure ring;



FIG. 9B is an enlarged view of the inner tube with a heater coil and wick assembly in position after positioning of a closure ring;



FIG. 10 is a cross-sectional view of a third embodiment of a mouth end insert for use with the electronic cigarette of FIG. 1;



FIG. 11 is an exploded view of the mouth end insert of FIG. 10;



FIG. 12 is a detailed view of an alternative connection arrangement assembly for use with the electronic cigarette of FIG. 1; and



FIG. 13 is a second embodiment of a connector cathode including a notch.



FIGS. 14A, 14B and 14C illustrate a third embodiment of a connector cathode including angled holes.



FIG. 15 is an illustration of a connector cathode and anode in which the anode is shortened to allow communication with air inlets.



FIG. 16 is a top view of an electronic cigarette including an aroma strip on an outer surface thereof.



FIG. 17 is a perspective view of a fourth embodiment of a mouth end insert for use with the electronic cigarette.



FIG. 18 is a cross-sectional view of an electronic cigarette according to the first embodiment and further including a sleeve assembly.



FIG. 19 is a side-view of an electronic cigarette according to another embodiment.





DETAILED DESCRIPTION

Electronic Cigarette Layout


Referring to FIGS. 1 and 2, a novel electronic cigarette (article) 60 is provided and comprises a replaceable cartridge (or first section) 70 and a reusable fixture (or second section) 72, which in the preferred embodiment are coupled together at a threaded connection 205 or by other convenience such as a snug-fit, detent, clamp and/or clasp. Generally, the second section 72 includes a puff sensor 16 responsive to air drawn into the second section 72 via an air inlet port 45 adjacent the free end or tip of the cigarette 60, a battery 1 and control circuitry. The disposable first section 70 includes a liquid supply region of 22 of liquid and a heater 14 that aerosolizes liquid that is drawn from the liquid supply region 22 through a wick 28. Upon completing the threaded connection 205, the battery 1 is connectable with the electrical heater 14 of the first section 70 upon actuation of the puff sensor. Air is drawn primarily into the first section 70 through one or more air inlets 44.


In the preferred embodiment, once the liquid of the cartridge is spent, only the first section 70 is replaced. An alternate arrangement includes a layout where the entire article 60 is disposed once the liquid supply is depleted. In such case the battery type and other features might be engineered for simplicity and cost-effectiveness, but generally embodies the same concepts as in the preferred embodiment in which the second section is reused and/or recharged.


In a preferred embodiment, the electronic cigarette 60 is about the same size as a conventional cigarette. In some embodiments, the electronic cigarette 60 can be about 80 mm to about 110 mm long, preferably about 80 mm to about 100 mm long and about 7 mm to about 8 mm in diameter. For example, in a preferred embodiment, the electronic cigarette is about 84 mm long and has a diameter of about 7.8 mm.


Preferably, at least one adhesive-backed label is applied to the outer tube 6. The label completely circumscribes the electronic cigarette 60 and can be colored and/or textured to provide the look and/or feel of a traditional cigarette. The label can include holes therein which are sized and positioned so as to prevent blocking of the air inlets 44.


The outer tube 6 and/or the inner tube 62 may be formed of any suitable material or combination of materials. Examples of suitable materials include metals, alloys, plastics or composite materials containing one or more of those materials, or thermoplastics that are suitable for food or pharmaceutical applications, for example polypropylene, polyetheretherketone (PEEK), ceramic, and polyethylene. Preferably, the material is light and non-brittle.


Cartridge Structure


Referring now to FIGS. 1, 2 and 3 the first section 70 includes an outer tube (or casing) 6 extending in a longitudinal direction and an inner tube (or chimney) 62 coaxially positioned within the outer tube 6. Preferably, a nose portion 61 (see FIG. 3a) of an upstream gasket (or seal) 15 is fitted into an upstream end portion 65 of the inner tube 62, while at the same time, an outer perimeter 67 of the gasket 15 provides a liquid-tight seal with an interior surface of the outer casing 6. The upstream gasket 15 also includes a central, longitudinal air passage 20, which opens into an interior of the inner tube 62 that defines a central channel 21. A transverse channel 33 at a backside potion of the gasket 15 intersects and communicates with the central channel 20 of the gasket 15. This channel 33 assures communication between the central channel 20 and a space 35 (see FIG. 2) defined between the gasket 15 and a cathode connector piece 37. In the preferred embodiment, the piece 37 includes a threaded section for effecting the threaded connection 205.


The cathode connector piece 37 includes opposing notches 38, 38′ about its perimeter 39, which, upon insertion of the cathode connector piece 37 into the casing 6, are aligned with the location of each of two RTD-controlling, air inlet ports 44 and 44′ in the outer casing 6. In an embodiment, such alignment may appear as shown in FIG. 3′(Detail). Such arrangement allows for placement of the ports 44, 44′ close to the threaded connection 205 without occlusion by the presence of the cathode connector piece 37. The arrangement also reinforces the area of ports 44, 44′ to facilitate precise drilling of the holes 44, 44′.


Air Inlets and Control of Resistance to Draw


In the preferred embodiment, at least one air inlet 44 is formed in the outer tube 6, preferably adjacent the threaded connection 205 to minimize the chance of a smoker' fingers occluding one of the ports and to control the resistance to draw (RTD) during smoking. Preferably, each of the RTD controlling, air inlets 44 and 44′ are machined into the casing 6 with precision tooling such that their diameters are closely controlled and replicated from one cigarette 60 to the next during their manufacture. Preferably, the air inlets 44 and 44′ are drilled with carbide drill bits or other high-precision tools and/or techniques. Also preferably, the outer tube 6 is formed of metal or metal alloys such that the size and shape of the air inlets 44, 44′ is not altered during manufacturing operations, packaging and smoking. Thus, the air inlets 44, 44′ provide consistent RTD. In the preferred embodiment, the air inlets 44, 44′ are sized and configured such that the electronic cigarette 60 has a RTD in the range of from about 60 mm H2O to about 150 mm H2O, more preferably about 90 mm H2O to about 110 mm H2O, most preferably about 100 mm H2O to about 130 mm H2O.


The RTD controlling, air inlets 44 and 44′ are the critical orifice (i.e. the smallest orifice along the pathway from the air inlets 44, 44′ and the inner passage 21 of the inner tube 62 (where the heater 14 aerosolizes liquid). Accordingly, the air inlets 44 and 44′ control the level of resistance to draw of the cigarette 60, which may be set at a level that contributes a drawing experience similar to that of drawing upon a conventional, lit-end cigarette.


Referring specifically to FIG. 1, another aspect of maintaining precise and reproducible resistance to draw is use of a metallic material in the casing 6 which is conducive to precision tooling and techniques. If another material is desired for the casing 6 (such as a plastic for presenting a softer feel), the air inlets 44, 44′ may be instead formed in a metallic plate fixture (or insert) 43 provided at the location of the air inlets 44, 44′ so as to maintain the precision of the air inlets 44, 44′.


It is envisioned that the metallic plate insert 43 may be included even in instances where the casing 6 is metallic, in that such arrangement allows the air inlets 44, 44′ to be produced and tested separately (off-line) on a collection of blank metallic plate inserts 43. Advantageously, should any finished metallic plate inserts 43 fail to meet standards or specifications for air inlet diameter (and RTD), the failed inserts may be disposed of instead of entire cartridge assemblies (first section) 70.


Referring back to FIG. 1, the metallic plate insert 43 may comprise a separate piece that becomes affixed to an outer surface of the casing 6 or wholly within the casing 6, in which case the outer casing 6 is preferably provided with an oversized hole, which can be superposed over the area of the air inlet 44. It is also envisioned that the insert might be shaped and fitted flush with the contour of the casing 6, using a snap fit and/or adhesive between the insert and the casing 6 or entirely within (internal of the outer casing 6). Preferably the shape and the location of the air inlet 44 of the insert 43 has a symmetry such that the air inlet 44 remains fully operative whether the insert 43 is positioned as shown in FIG. 1 or flipped 180 degrees. Moreover, the metallic plate insert 43 can be provided on an inside surface or on an outside surface of the outer casing 6. The metallic plate insert 43 can extend fully or partially about a circumference of the cigarette 60. When the metallic plate insert 43 extends partially about the circumference, multiple metallic plate inserts 43 can be used, each metallic plate insert 43 corresponding to a single air inlet 44, 44′.


In the preferred embodiment, the second section 72, includes an air inlet 45 at an upstream end 5 of the cigarette 60, which is sized just sufficient to assure proper operation of the puff sensor 16, located nearby. Drawing action upon the mouth end insert 8 is communicated to the air inlet port 45 through central channels provided in the anode post 47c of the first section 70 and the anode connection post 47b of the second section 72 and along space 13 between the battery 1 and the casing of the second section 72. These channels and the port 45 itself are sized such that the airflow rate there through are much smaller than through the air inlets 44, 44′, so that the impact on RTD is minimized and consistency in RTD is maintained. For example, each air inlet can be less than about 2.0 mm in width and less than about 1.5 mm in depth. For example, each air inlet can be about 0.7 mm to about 0.8 mm in width and about 0.7 mm to about 0.8 mm in depth. In a preferred embodiment, 95% of the air introduced in the cigarette 60 is through the air inlets 44, 44′, whereas only 5% of the total air flow enters through the inlet 45 at the upstream end 5 of the cigarette 60. Preferably, the ratio is determined by making a central channel 34 of the anode post 47b of the second section 72 small enough to impart a pressure drop far greater than that of the air inlets 44, 44′. For example, the central channel 34 of the anode post 47b may be sized to impart a pressure drop of approximately 2000 mm water (in contrast to a nominal pressure drop of 100 mm water from air inlets 44, 44′ combined).


Referring to FIG. 19, in order to maintain consistent RTD in the product, a removable protective covering 601 can be applied to the air inlets 44, 44′ to prevent degradation from dirt and dings during, manufacture, packaging shipping and handling at retail and beyond as shown in FIG. 19. To maintain consistent RTD until consumption, a circumferential wrapping or tape 601 may be wrapped about the outer casing 6 at the locations of the air inlets 44, 44′. In the alternative or in addition, the cigarette 60 may be accompanied with a reusable protective cover to provide the same or additional protections.


In addition, current manufacturing techniques for electronic cigarettes can be modified to include testing for consistent RTD. In other words, there is a need to couple an understanding of how to achieve consistent RTD in the product (as taught above) with an understanding of how to test for it in the course of manufacturing the product (as taught in the following). Achieving consistent RTD from one electronic cigarette to the next promotes consistent performance and delivery levels, and enhances smoking experiences by meeting smoker's expectations that a draw upon an electronic cigarette will be akin to drawing upon a lit end cigarette or cigar. The latter may include testing metallic plate inserts 43 prior to installation as previously described, or instead or in addition, testing completed first sections 70 by fastening a nominal, but inactivated second section 72 to a newly produced first section 70 to create a benign, inactive test configuration that accurately reproduces airflow event, but without risk of heater activation and applying a predetermined drawing action upon the configuration while measuring pressure drop. By way of non-limiting example, a fully assembled electronic cigarette may be drawn through the test configuration while pressure drop is measured using a PV10 pressure drop instrument manufactured by Borgwaldt KC of Chesterfield, Va. A suitable pressure drop testing method for electronic cigarettes can be adopted from standard method ISO 6565:2011 entitled “Tobacco and tobacco products—Draw Resistance of Cigarettes and Pressure Drop of Filter Rods—Standard Conditions and Measurement”, and applied with instrumentation capable of measure pressure drop in a working range of 50 mmWG (mm water gauge) to 1900 mmWG and a diameter range of 5.0 mm to 9.0 mm. The test can be completed in a matter of seconds and the instrumentation can be calibrated to a range of 50 mmWG to 300 mmWG.


Instead of using an inactivated second section 72, it is envisioned that a releasable test body might be employed to serve the same purpose in a benign (inactive) test configuration. The test body would be configured to reproduce nominal impact of a real reusable second portion 72 upon RTD, but could be optimized for machine handing and high speed automated coupling to and removal from newly produced first sections 70 that are undergoing testing.


The inclusion of a threaded connection 205 does not facilitate automated, high speed machine handling and execution of the RTD tests. Referring now to FIG. 12, an alternative coupling 205′ may include connections comprising pins 501 and releasable detents 503 and/or electrical bearing surfaces 505 with releasable detents, rotational locking devices or the like. In the illustrated embodiment, the detent 503 cooperates with a raised annulus 509. In the alternative, one or more biased balls may be used in lieu of or in addition to the raised annulus 509. Such arrangements facilitate automated machine handling, provide a greater capacity for speedy yet accurate testing of RTD, and facilitate machine automated execution of RTD testing. It is envisioned that quality control during the drilling of orifices could include a feedback loop such that the RTD test results are monitored to detect trends away from specifications so that corrective measures may be undertaken, such as replacement of a worn drill bit.


Referring now to FIGS. 3a and 3b, preferably, the cathode connector piece 37 includes opposing notches 38, 38′ about its perimeter 39, which, upon insertion of the cathode connector piece 37 into the outer casing 6, are aligned with the location of each of two or more RTD-controlling, air inlets 44 and 44′ in the outer casing 6. In some embodiments, more than two air inlets 44, 44′ may be included (e.g., three, four, five, six, seven, eight, nine, ten or more). Alternatively, a single air inlet 44 can be included. In an embodiment, such alignment may appear as shown in FIG. 3b. Such arrangement allows for placement of the air inlets 44, 44′ close to the threaded connection 205 without occlusion by the presence of the cathode connector piece 37. The arrangement also reinforces the area of air inlets 44, 44′, which can serve to facilitate precise drilling of the air inlets 44, 44′. Other arrangements can also be used as discussed below.


In another embodiment, as shown in FIG. 13, the cathode connector piece 37 can include one or more slits 300 formed in the perimeter 39 of the cathode connector piece 37. The outer casing 6 of the cartridge portion 70 is slid over the unthreaded end of the connector piece 37 until it reaches the stop (or edge) 307, leaving a predetermined portion of the slit 300 open to the exterior of the cartridge portion 70 for the admission of air. The admitted air can travel along the slit 300 and into the interior of the cartridge portion 70. The slit 300 may be used as the critical orifice and can be used in lieu of air inlets 44 and 44′. In another embodiment, the slit 300 may be used in addition to air inlets 44 and 44′.


In yet another embodiment, as shown in FIGS. 14A, 14B and 14C, the cathode connector piece 37 can include one or more angled holes 301 formed therein, which communicate with one or more slots 302 in a cathode connection fixture 49b. Preferably, the cathode connection fixture 49b can include an empty annular space 303 in an inner portion thereof which communicates with the one or more slots 302. Air is drawn in through slot 302 and travels into the annular space 303 and from there into the angled holes 307. Thus, there is no need to line up the slot 302 with the angled hole 301 because air will travel around the annular space 303 and into the angled holes 301 even if the holes 301 and slots 302 are not aligned. This arrangement provides advantages during manufacture since the angled holes 301 need not be aligned with the slots 302.


As shown in FIG. 15, in yet another embodiment, the anode post 47c can be shortened as compared to the anode post 47c of FIG. 2 so as to provide a larger air gap behind the cathode connector piece 37. Air enters via slot 302′ (not shown in FIG. 15 other than its relative position) and is drawn through an internal air inlet 44 via annular space 303 and then flows straight into the air gap, through the central channel 34 of the anode post 47c and into the central channel 20 leading to the heater 14.


Liquid Supply Region, Heater and Wick


Preferably, a nose portion 93 of an downstream gasket 10 is fitted into a downstream end portion 81 of the inner tube 62. An outer perimeter 82 of the gasket 10 provides a substantially liquid-tight seal with an interior surface 97 of the outer casing 6. The downstream gasket 10 includes a central channel 84 disposed between the central passage 21 of the inner tube 62 and the interior of the mouth end insert 8 and which communicates aerosol from the central passage 21 to the mouth end insert 8.


The space defined between the gaskets 10 and 15 and the outer tube 6 and the inner tube 62 establish the confines of a liquid supply region 22. The liquid supply region 22 comprises a liquid material and optionally a liquid storage medium 210 operable to store the liquid material therein. The liquid storage medium 210 may comprise a winding of cotton gauze or other fibrous material about the inner tube 62.


In the preferred embodiment, the liquid supply region 22 is contained in an outer annulus 620 between inner tube 62 and outer tube 6 and between the gaskets 10 and 15. Thus, the liquid supply region 22 at least partially surrounds the central air passage 21. The heater 14 extends transversely across the central channel 21 between opposing portions of the liquid supply region 22.


Preferably, the liquid storage medium 210 is a fibrous material comprising cotton, polyethylene, polyester, rayon and combinations thereof. Preferably, the fibers have a diameter ranging in size from about 6 microns to about 15 microns (e.g., about 8 microns to about 12 microns or about 9 microns to about 11 microns). The liquid storage medium 210 can be a sintered, porous or foamed material. Also preferably, the fibers are sized to be irrespirable and can have a cross-section which has a y shape, cross shape, clover shape or any other suitable shape. In the alternative, the liquid supply region 22 may comprise a filled tank lacking a fibrous storage medium 21 and containing only liquid material.


Also preferably, the liquid material has a boiling point suitable for use in the electronic cigarette 60. If the boiling point is too high, the heater 14 will not be able to vaporize liquid in the wick 28. However, if the boiling point is too low, the liquid may vaporize even when the heater 14 is not being activated.


Preferably, the liquid material includes a tobacco-containing material including volatile tobacco flavor compounds which are released from the liquid upon heating. The liquid may also be a tobacco flavor containing material or a nicotine-containing material. Alternatively, or in addition, the liquid may include a non-tobacco material. For example, the liquid may include water, solvents, ethanol, plant extracts and natural or artificial flavors. Preferably, the liquid further includes an aerosol former. Examples of suitable aerosol formers are glycerine and propylene glycol.


Referring now also to FIG. 8, in use, liquid material is transferred from the liquid supply region 22 and/or liquid storage medium 210 in proximity of the 14 heater by capillary action of the wick 28. In one embodiment, the wick 28 has a first end portion 29 and a second end portion 31 as shown in FIG. 8. The first end 29 and the second end 31 extend into opposite sides of the liquid storage medium 21 for contact with liquid material contained therein. Also preferably, the heater 14 at least partially surrounds a central portion 113 of the wick 28 such that when the heater 14 is activated, the liquid in the central portion 113 of the wick 28 is vaporized by the heater 14 to form an aerosol. The wick 28 preferably comprises filaments having a capacity to draw a liquid, more preferably a bundle of glass (or ceramic) filaments and most preferably a bundle comprising a group of windings of glass filaments, preferably three of such windings, all which arrangements are capable of drawing liquid via capillary action via interstitial spacings between the filaments. Preferably, the wick 28 is flexible and includes three strands, each strand including a plurality of filaments. Moreover, it is noted that the end portions of the 29 and 31 of the wick 28 are flexible and foldable into the confines of the liquid supply region 22.


Advantageously, the liquid material in the liquid supply region 22 is protected from oxygen (because oxygen cannot generally enter the liquid supply region 22 via the wick 28). In some embodiments, the liquid material is also protected from light so that the risk of degradation of the liquid material is significantly reduced. Thus, a high level of shelf-life and cleanliness can be maintained.


In the preferred embodiment, the liquid supply region 22 is sized and configured to hold enough liquid material such that the electronic cigarette 60 is operable for smoking for at least about 200 seconds, preferably at least about 250 seconds, more preferably at least 300 seconds and most preferably at least about 350 seconds. Thus, liquid supply region 22 is equivalent to about one pack of traditional cigarettes. Moreover, the electronic cigarette 60 can be configured to allow each puff to last a maximum of about 5 seconds.


Mouth End Insert


Referring to FIGS. 2, 3a, 4, 5, 6, 7 and 17, the first section 70 includes a mouth end insert 8 having at least two diverging outlet passages 24 (e.g., preferably 2 to 6 outlet passages 24, more preferably 4 outlet passages 24). Preferably, the outlet passages 24 are located off-axis and are angled outwardly in relation to the central channel 21 of the inner tube 62 (i.e., divergently). Also preferably, the mouth end insert (or flow guide) 8 includes outlets 24 uniformly distributed about the perimeter of mouth end insert 8 so as to substantially uniformly distribute aerosol in a smoker's mouth during use and create a greater perception of fullness in the mouth. Thus, as the aerosol passes into a smoker's mouth, the aerosol enters the mouth and moves in different directions so as to provide a full mouth feel. In contrast, electronic cigarettes having a single, on-axis orifice tend to direct its aerosol as single jet of greater velocity toward a more limited location within a smoker's mouth.


In addition, the diverging outlet passages 24 are arranged and include interior surfaces 83 such that droplets of unaerosolized liquid material, if any, that may be entrained in the aerosol impact the interior surfaces 83 of the mouth end insert 8 and/or impact portions of walls 305 which define the diverging outlet passages 24. As a result such droplets are substantially removed or broken apart, to the enhancement of the aerosol.


In the preferred embodiment, the diverging outlet passages 24 are angled at about 5° to about 60° with respect to the longitudinal axis of the outer tube 6 so as to more completely distribute aerosol throughout a mouth of a smoker during use and to remove droplets. In a preferred embodiment, there are four diverging outlet passages 24 each at an angle of about 40° to about 50° with respect to the longitudinal axis of the outer tube 6, more preferably about 40° to about 45° and most preferably about 42°.


Preferably, each of the diverging outlet passages 24 has a diameter ranging from about 0.015 inch to about 0.090 inch (e.g., about 0.020 inch to about 0.040 inch or about 0.028 inch to about 0.038 inch). The size of the diverging outlet passages 24 and the number of diverging outlet passages 24 can be selected to adjust the resistance to draw (RTD) of the electronic cigarette 60, if desired.


In one embodiment shown in FIG. 17, the mouth end insert 8 can include diverging outlet passages 24 and an on-axis outlet passage 26.


As shown in FIG. 2, an interior surface 83 of the mouth end insert 8 can comprise a generally domed surface 83. Alternatively, as shown in FIG. 7, the annular interior surface 83′ of the mouth end insert 8 can be generally cylindrical or frustoconical, with a planar end surface. Preferably, the interior surface 83 is substantially uniform over the surface thereof. Moreover, the interior surface 83 can be symmetrical about the longitudinal axis of the mouth end insert 8. However, in other embodiments, the interior surface 83 can be irregular and/or have other shapes.


In a preferred embodiment, a hollow 911 is disposed at the convergence of the diverging outlet passages 24 within the mouth end insert 8


The mouth end insert 8 may be integrally affixed within the tube 6 of the cartridge 70.


As mentioned previously, the multi-port mouth end insert 8 disperses and changes the direction of the aerosol as it is drawn from the electronic cigarette 60 so as to provide a fuller mouth feel. As aerosol is formed, it passes through the central channel 21 in the inner tube 62 and through the central channel 84 in the downstream gasket 10. In panel testing of early prototypes, some panelists reported a “hot” sensation on the lips from smoking an electronic cigarette constructed to include a mouth end insert including a plurality of diverging outlet passages 24 and a central channel 84 having a diameter of about 1.3 mm. However, in electronic cigarettes in which the inside diameter of the central channel 84 was increased to about 2.6 mm, reports of “hot” sensations essentially ceased.


Dynamic modeling of the area at and about the downstream gasket 10 and the mouth end insert 8 has indicated that a small 1 mm wide central channel 84 at the gasket 10 tends to create peak velocities of approximately 12 meters per second (m/sec) in aerosol exiting the mouth end insert. In contrast, modeling of a system including a 5 mm wide central channel 84 indicates peak velocities of only 2.5 m/s is achieved at the exits of the diverging outlet passages 24 of the mouth end insert 8, which is approximately a five-fold decrease in air velocity. From the aforementioned testing and modeling it is believed a further improvement in the organoleptic experience with an electronic cigarette is achieved by preventing acceleration of the aerosol flow stream by increasing the diameter of the central channel 84 before it is drawn through the exits of the diverging outlet passages 24 of the multi-port mouth end insert 8.


Accordingly, it is advantageous to provide an electronic cigarette having a downstream gasket 10 having a central channel 84, which has a diameter sufficient to prevent acceleration of the aerosol flow stream before reaching the mouth end insert 8. Preferably, the diameter of the central channel 84 is about 2.0 mm to about 3.0 mm, more preferably about 2.4 mm to about 2.8 mm. The mouth end insert 8 then divides output from the central channel 84 into multiple divergent streams of reduced speed so as to provide a full mouth feel and to avoid sensations of “hot”.


In that an appropriately sized central channel 84 of the gasket 10 serves to substantially prevent acceleration of the aerosol, such functionality can be further enhanced by providing the exit orifice with a beveled rim (not shown) at its exit plane to further reduce speed of the aerosol before it reaches the mouth end insert 8.


In an alternative embodiment, the mouth end insert 8 and the downstream gasket 10 can be integrally formed as a single piece so as to enhance consistent performance and to facilitate manufacture.


As shown in FIGS. 10 and 11, in an alternative embodiment, the electronic cigarette 60 of FIG. 1 can include a mouth end insert 8 having a stationary piece 27 and a rotatable piece 25. Outlets 24, 24′ are located in each of the stationary piece 27 and the rotatable piece 25. The outlets 24, 24′ match up as shown to allow aerosol to enter a smoker's mouth. However, the rotatable piece 25 can be rotated within the mouth end insert 8 so as to at least partially block one or more of the outlets 24 in the stationary mouth end insert 28. Thus, the consumer can adjust the amount of aerosol drawn with each puff. The outlets 24, 24′ can be formed in the mouth end insert mouth end insert 8 such that the outlets 24, 24′ diverge to provide a fuller mouth feel during inhalation of the aerosol.


Circuitry, Alloys Improving Consistent Heater Performance, Hot Spots and Carbonyl Abatement


In the preferred embodiment, the power supply 1 includes a battery arranged in the electronic cigarette 60 such that the anode 47a is downstream of the cathode 49a. A battery anode post 47b of the second section 72 preferably contacts the battery anode 47a.


More specifically, electrical connection between the anode 47a of the battery 1 and the heater coil 14 in the first section 70 is established through a battery anode connection post 47b in the second section 72 of the electronic cigarette 60, an anode post 47c of the cartridge 70 and an electrical lead 47d connecting a rim portion of the anode post 47c with an electrical lead 109 of the heater element 14 (see FIG. 8). Likewise, electrical connection between the cathode 49a of the battery 1 and the other lead 109′ of the heater coil 14 is established through the threaded connection 205 between a cathode connection fixture 49b of the second portion 72 and the cathode connector piece 37 of the first section 70 and from there through an electrical lead 49c which electrically connects the fixture 37 to the opposite lead 109′ of the heater coil 14.


Preferably, the electrical leads 47d, 49c and the heater leads 109, 109′ are highly conductive and temperature resistant while the coiled section 110 of the heater 14 is highly resistive so that heat generation occurs primarily along the coils 110 of the heater 14. Also preferably, the electrical lead 47d is connected to the heater lead 109 by crimping. Likewise, the electrical lead 49c is connected to the heater lead 109′ by crimping. In an alternative embodiment, the electrical leads 47d, 49c can be attached to the heater leads 109, 109′ via soldering. Crimping is preferred as it speeds manufacture.


The battery can be a Lithium-ion battery or one of its variants, for example a Lithium-ion polymer battery. Alternatively, the battery may be a Nickel-metal hydride battery, a Nickel cadmium battery, a Lithium-manganese battery, a Lithium-cobalt battery or a fuel cell. In that case, preferably, the electronic cigarette 60 is usable by a smoker until the energy in the power supply is depleted or in the case of lithium polymer battery, a minimum voltage cut-off level is achieved.


Alternatively, the power supply 1 may be rechargeable and include circuitry allowing the battery to be chargeable by an external charging device. In that case, preferably the circuitry, when charged, provides power for a pre-determined number of puffs, after which the circuitry must be re-connected to an external charging device. To recharge the electronic cigarette 60, an USB charger or other suitable charger assembly can be used.


Preferably, the electronic cigarette 60 also includes control circuitry including a puff sensor 16. The puff sensor 16 is operable to sense an air pressure drop and initiate application of voltage from the power supply 1 to the heater 14. As shown in FIG. 2, the control circuitry can also include a heater activation light 48 operable to glow when the heater 14 is activated. Preferably, the heater activation light 48 comprises an LED and is at an upstream end of the electronic cigarette 60 so that the heater activation light 48 takes on the appearance of a burning coal during a puff. Moreover, the heater activation light 48 can be arranged to be visible to the smoker. In addition, the heater activation light 48 can be utilized for cigarette system diagnostics or to indicate that recharging is in progress. The light 48 can also be configured such that the smoker can activate and/or deactivate the light 48 for privacy, such that the light 48 would not activate during smoking if desired.


Preferably, the at least one air inlet 45 (FIG. 1) is located adjacent the puff sensor 16, such that the puff sensor 16 senses air flow indicative of a smoker taking a puff and activates the power supply 1 and the heater activation light 48 to indicate that the heater 14 is working.


A control circuit is preferably integrated with the puff sensor 16 and supplies power to the heater 14 responsive to the puff sensor 16, preferably with a maximum, time-period limiter.


Alternatively, the control circuitry may include a manually operable switch for a smoker to initiate a puff. The time-period of the electric current supply to the heater may be pre-set depending on the amount of liquid desired to be vaporized. Alternatively, the circuitry may supply power to the heater 14 as long as the puff sensor 16 detects a pressure drop.


Preferably, when activated, the heater 14 heats a portion of the wick 28 surrounded by the heater for less than about 10 seconds, more preferably less than about 7 seconds. Thus, the power cycle (or maximum puff length) can range in period from about 2 seconds to about 10 seconds (e.g., about 3 seconds to about 9 seconds, about 4 seconds to about 8 seconds or about 5 seconds to about 7 seconds).


Preferably, the heater 14 is a wire coil that surrounds the wick 28. Examples of suitable electrically resistive materials include titanium, zirconium, tantalum and metals from the platinum group. Examples of suitable metal alloys include stainless steel, nickel-, cobalt-, chromium-, aluminium-titanium-zirconium-, hafnium-, niobium-, molybdenum-, tantalum-, tungsten-, tin-, gallium-, manganese- and iron-containing alloys, and super-alloys based on nickel, iron, cobalt, stainless steel. For example, the heater can be formed of nickel aluminide, a material with a layer of alumina on the surface, iron aluminide and other composite materials, the electrically resistive material may optionally be embedded in, encapsulated or coated with an insulating material or vice-versa, depending on the kinetics of energy transfer and the external physicochemical properties required. Preferably, the heater 14 comprises at least one material selected from the group consisting of stainless steel, copper, copper alloys, nickel-chromium alloys, super alloys and combinations thereof. In a preferred embodiment, the heater 14 is formed of nickel-chromium alloys or iron-chromium alloys, although the latter is not preferred for reasons which follow. In another embodiment, the heater 14 can be a ceramic heater having an electrically resistive layer on an outside surface thereof.


In another embodiment, the heater 14 may be constructed of an iron-aluminide (e.g., FeAl or Fe3Al), such as those described in commonly owned U.S. Pat. No. 5,595,706 to Sikka et al. filed Dec. 29, 1994, or nickel aluminide (e.g., Ni3Al). Use of iron-aluminide is advantageous in that iron-aluminide exhibits high resistivity. FeAl exhibits a resistivity of approximately 180 micro-ohms, whereas stainless steel exhibits approximately 50 to 91 micro-ohms. The higher resistivity lowers current draw or load on the power source (battery) 1.


In the preferred embodiment, the heater coil 14 is formed from a nickel-chromium alloy that is essentially free of iron content. Experience has indicated that heater coils constructed from an iron chromium alloy suffered oxidation of their iron content if the alloys were contacted with water during manufacturing operations, during shelf-life and/or operation of the device.


It is known that heating glycerin and/or propylene glycol beyond certain temperatures produces carbonyls (which include formaldehydes). Iron oxide tends to catalyze these reactions such that carbonyls are produced at lower temperatures. By using alloys essentially free of iron content, such catalyzation is avoided and the possibility of producing carbonyls and other constituents is minimized.


Moreover, in the manufacture and design of the preferred embodiment, certain aspects and measures are employed to avoid occurrence of unintended “hot spots” in the heater coil 14 during its heating cycle. Hot spots may contribute excessive peak temperatures that may produce undesired constituents that would otherwise be avoided in the absence of a hot spot.


While not wishing to be bound by theory, it is believed that if a winding of a coil heater 14 is altered such that spacing between loops of the coil 14 is locally reduced, the reduced spacing will create hotspots that are believed to drive peak temperatures beyond desirable levels. It is also believed that establishing uniform spacing along the coils of the heater 14 and taking steps to preserve the original, uniform spacing in the winding of the coil heater 14 will avoid the consequences of “hot spots”.


In particular and referring to FIG. 8, it is envisioned that production of consistent coil spacing 111 throughout the coiled section 110 of a given heater coil 14 may be achieved in ways including using automated winders to wind the coil about the wick 28 and using the wick 28 as an arbor for the winding step. In the preferred embodiment 3 to 8 windings are preferred, more preferably, 3 to 5 windings.


Once established, the uniformity of the coil spacing 111 is preserved in the course of manufacture and in the design of the preferred embodiment.


Referring also to FIG. 9A, in particular, the provision of opposing slots 63 in the inner tube 62 facilitates placement of the heater 14 and wick 28 into position within the inner tube 62 without impaction between edges of the slots 63 and the coiled section 110 (shown in FIG. 8) of the heater 14. Accordingly, edges of the slots 63 are not allowed to impact and alter the coil spacing 111 of the heater 14, which would otherwise create potential sources of hotspots.


Referring now to FIG. 9B, care is taken to position a closure ring 69 such that it is proximate to or touches but does not urge against the wick 28. Such positioning avoids imposing bending moments upon the heater coil 14 and avoids bowing of the coil 14 which might otherwise produce hotspots along one side of the coil 14 where the coil spacing 111 would become compressed and reduced. Thus, the upstream edge 114 of the closure ring 69 is brought into proximity of the wick 28, but is not positioned over the wick 28 so as to avoid the possibility of the aforementioned bowing effect. The closure ring 69, when placed as shown in FIG. 9B, closes off a remainder of open space provided between the heater coil assembly and the slot 63.


In the preferred embodiment, the inner tube 62 and the closure ring 69 are constructed from woven fiberglass.


In the preferred embodiment, the inner tube 62 has a diameter of about 4 mm and each of the opposing slots 63 has major and minor dimensions of about 2 mm by about 4 mm.


In one embodiment, the heater 14 comprises a wire coil which at least partially surrounds the wick 28. In that embodiment, preferably the wire is a metal wire and/or the heater coil may extend fully or partially along the length of the wick 28. The heater coil 14 may extend fully or partially around the circumference of the wick 28. In another embodiment, the heater coil is not in contact with the wick 28.


Preferably, the heater 14 heats liquid in the wick 28 by thermal conduction. Alternatively, heat from the heater 14 may be conducted to the liquid by means of a heat conductive element or the heater 14 may transfer heat to the incoming ambient air that is drawn through the electronic cigarette 60 during use, which in turn heats the liquid by convection.


In one embodiment, the wick 28 comprises a ceramic wick of ceramic filaments having a capacity to draw a liquid. As noted above, the wick 28 is at least partially surrounded by the heater 14. Moreover, in the preferred embodiment, the wick 28 extends through opposed slots 63 in the inner tube 62 such that each end of the wick 28 is in contact with the liquid supply region 22 (shown in FIG. 2).


In the preferred embodiment, the wick 28 comprises filaments and comprises a bundle of glass filaments. For example, the wick 28 may include a plurality of filaments. The filaments or threads may be generally aligned in a direction perpendicular (transverse) to the longitudinal direction of the electronic cigarette. Preferably, the wick 28 includes 1 to 8 filaments, more preferably 2 to 6 filaments. In the preferred embodiment, the wick 28 includes 3 stands, each strand comprising a plurality of glass filaments twisted together.


In the preferred embodiment, the structure of the wick 28 is formed of filaments through which the liquid can be transported to the heater 14 by capillary action. The wick 28 can include filaments having a cross-section which is generally cross-shaped, clover-shaped, Y-shaped or in any other suitable shape.


Preferably, the wick 28 includes any suitable material or combination of materials. Examples of suitable materials are glass, ceramic- or graphite-based materials. Moreover, the wick 28 may have any suitable capillarity drawing action to accommodate aerosol generating liquids having different liquid physical properties such as density, viscosity, surface tension and vapor pressure. The capillary properties of the wick 28, combined with the properties of the liquid, ensure that the wick 28 is always wet in the area of the heater 14 to avoid overheating of the heater 14.


Instead of using a wick 28, the heater 14 can be a porous material which incorporates a resistance heater formed of a material having a high electrical resistance capable of generating heat quickly.


Preferably, the wick 28 and the fibrous medium of the liquid supply region 22 are constructed from glass fiber.


Sleeve Assembly


As shown in FIG. 18, the electronic cigarette 60 can also include a sleeve assembly 87 removably and/or rotatably positioned about a first section 70 of the electronic cigarette 70. Moreover, the sleeve assembly 87 insulates at least a portion of the first section 70 so as to maintain the temperature of the aerosol prior to delivery to the smoker. In the preferred embodiment, the sleeve assembly 87 is rotatable about the electronic cigarette 60 and includes spaced apart slots 88 arranged transversely about the sleeve assembly such that the slots 88 line up with the air inlets 44, 44′ in the first section 70 to allow air to pass into the electronic cigarette 60 when a smoker draws a puff. Before or during smoking, the smoker can rotate the sleeve assembly 87 such that the air inlets 44, 44′ are at least partially blocked by the sleeve assembly 87 so as to adjust the resistance to draw and/or ventilation of the electronic cigarette 60 if desired.


Preferably, the sleeve assembly 87 is made of silicone or other pliable material so as to provide a soft mouthfeel to the smoker. However, the sleeve assembly 87 can be formed in one or more pieces and can be formed of a variety of materials including plastics, metals and combinations thereof. In a preferred embodiment, the sleeve assembly 87 is a single piece formed of silicone. The sleeve assembly 87 can be removed and reused with other electronic cigarettes or can be discarded along with the first section 70. The sleeve assembly 87 can be any suitable color and/or can include graphics or other indicia.


Aroma Delivery


As shown in FIG. 11, the electronic cigarette 60 can also include an aroma strip 89 located on an outer surface 91 of at least one of the first section 70 and the second section 72. Alternatively, the aroma strip 89 can be located on a portion of the sleeve assembly 87. Preferably, the aroma strip 89 is located between the battery of the device and the heater 14 such that the aroma strip 89 is adjacent a smoker's nose during smoking. The aroma strip 89 can include a flavor aroma gel, film or solution including a fragrance material that is released before and/or during smoking. In one embodiment, the flavor aroma of the gel, fluid and/or solution can be released by the action of a puff which may open a vent over the aroma strip when positioned inside the first section 70 (not shown). Alternatively, heat generated by the heater 14 can cause the release of the aroma.


In one embodiment, the aroma strip 89 can include tobacco flavor extracts. Such an extract can be obtained by grinding tobacco material to small pieces and extracting with an organic solvent for a few hours by shaking the mixture. The extract can then be filtered, dried (for example with sodium sulfate) and concentrated at controlled temperature and pressure. Alternatively, the extracts can be obtained using techniques known in the field of flavor chemistry, such as the Solvent Assisted Flavor Extraction (SAFE) distillation technique (Engel et al. 1999), which allows separation of the volatile fraction from the non-volatile fraction. Additionally, pH fractionation and chromatographic methods can be used for further separation and/or isolation of specific compounds. The intensity of the extract can be adjusted by diluting with an organic solvent or water.


The aroma strip 89 can be a polymeric or paper strip to which the extract can be applied, for example, using a paintbrush or by impregnation. Alternatively, the extract can be encapsulated in a paper ring and/or strip and released manually by the smoker, for example by squeezing during smoking the aroma strip.


In one embodiment, the electronic cigarette 60 of FIGS. 2, 5, 7 and 9 can also include a filter segment upstream of the heater 14 and operable to restrict flow of air through the electronic cigarette 60. The addition of a filter segment can also aid in adjusting the resistance to draw.


When the word “about” is used in this specification in connection with a numerical value, it is intended that the associated numerical value include a tolerance of ±10% around the stated numerical value. Moreover, when reference is made to percentages in this specification, it is intended that those percentages are based on weight, i.e., weight percentages.


Moreover, when the words “generally” and “substantially” are used in connection with geometric shapes, it is intended that precision of the geometric shape is not required but that latitude for the shape is within the scope of the disclosure. When used with geometric terms, the words “generally” and “substantially” are intended to encompass not only features which meet the strict definitions but also features which fairly approximate the strict definitions.


It will now be apparent that a new, improved, and nonobvious electronic cigarette has been described in this specification with sufficient particularity as to be understood by one of ordinary skill in the art. Moreover, it will be apparent to those skilled in the art that numerous modifications, variations, substitutions, and equivalents exist for features of the electronic cigarette which do not materially depart from the spirit and scope of the invention. Accordingly, it is expressly intended that all such modifications, variations, substitutions, and equivalents which fall within the spirit and scope of the invention as defined by the appended claims shall be embraced by the appended claims.

Claims
  • 1. A method of improving a plurality of electronic smoking articles, the method comprising: forming an air inlet in a metal plate insert prior to placement of the metal plate insert into an electronic smoking article, the air inlet being sized and configured to provide the electronic smoking article with a predetermined resistance to draw; andsubjecting the air inlet to a test of resistance-to-draw during manufacture of the electronic smoking article.
  • 2. The method of claim 1, further including affixing the metal plate insert to an inner surface or an outer surface of an outer tube of the electronic smoking article.
  • 3. The method of claim 1, wherein the subjecting includes establishing a benign test configuration.
  • 4. The method of claim 3, wherein the establishing includes using a release connection between components of the benign test configuration, the release connection conducive to automated machine handling.
  • 5. The method of claim 1, further comprising: protecting the air inlet with a removable tape prior after the subjecting.
  • 6. A method of achieving a consistent resistance to draw amongst a plurality of electronic cigarettes, said method comprising: determining a dimension of a critical orifice in an outer tube of an electronic cigarette that provides a desired resistance-to-draw;for each electronic cigarette, establishing the critical orifice by precision drilling the critical orifice in a wall of the outer tube of the electronic cigarette according to said determined dimensions and by selecting a material conducive to said precision drilling and having a capacity to retain said dimension; andtesting each established critical orifice for providing said desired resistance to draw and rejecting any established critical orifice failing said test.
  • 7. The method of claim 6, wherein the testing includes testing a critical orifice established on a piece separate of the electronic cigarette.
  • 8. The method of claim 6, wherein the desired resistance-to-draw is in a range of about 60 mm water to about 150 mm water.
  • 9. The method of claim 8, wherein the desired resistance-to-draw is in the range of about 60 mm water to about 150 mm water.
  • 10. The method of claim 9, wherein the desired resistance-to draw is in the range of about 90 mm water to about 110 mm water.
  • 11. The method of claim 6, wherein the testing includes monitoring the results of testing to detect trends away from said dimension of the critical orifice.
CROSS REFERENCE TO RELATED APPLICATION

This application is a divisional of U.S. patent application Ser. No. 13/741,267 filed on Jan. 14, 2013, and claims priority under 35 U.S.C. § 119(e) to U.S. Provisional Application No. 61/593,004, filed on Jan. 31, 2012, the entire content of each of which is incorporated herein by reference thereto.

US Referenced Citations (407)
Number Name Date Kind
539839 Voron May 1895 A
751923 Kelly Feb 1904 A
777948 Gable Dec 1904 A
900197 Osman Oct 1908 A
962617 Bucceri Jun 1910 A
1013157 Hadaway, Jr. Jan 1912 A
1185661 Hawley Jun 1916 A
1514682 Wilson Nov 1924 A
1557351 Fischer Oct 1925 A
1771366 Wyss et al. Jul 1930 A
1817546 Deinstein Aug 1931 A
1841952 Hughes Jan 1932 A
1865679 Colpe Jul 1932 A
1916799 Hughes Jul 1933 A
1968509 Tiffany Jul 1934 A
2057353 Whittlemore, Jr. Oct 1936 A
2104266 McCormick Jan 1938 A
2406275 Wejnarth Aug 1946 A
2442004 Hayward-Butt May 1948 A
2542612 Arneson Feb 1951 A
2558127 Downs Jun 1951 A
2599310 Abercrombie Jun 1952 A
2609817 Falcone Sep 1952 A
2670739 McNeill Mar 1954 A
2746890 Legler May 1956 A
2836183 Fay et al. May 1958 A
2907686 Siegel Oct 1959 A
2971039 Western Feb 1961 A
2972557 Toulmin, Jr. Feb 1961 A
2974669 Ellis Mar 1961 A
3062218 Temkovits Nov 1962 A
3150668 Lassiter et al. Sep 1964 A
3160946 Dickson, Jr. et al. Dec 1964 A
3200819 Gilbert Aug 1965 A
3255760 Selker Jun 1966 A
3258015 Ellis et al. Jun 1966 A
3294095 Ackerman Dec 1966 A
3347231 Chang Oct 1967 A
3356094 Ellis et al. Dec 1967 A
3363633 Weber Jan 1968 A
3396733 Allseits et al. Aug 1968 A
3402723 Hu Sep 1968 A
3425414 La Roche Feb 1969 A
3428050 Kandel Feb 1969 A
3439685 Allen Apr 1969 A
3482580 Hollabaugh Dec 1969 A
3521643 Toth Jul 1970 A
3559300 Fox Feb 1971 A
3581748 Cameron Jun 1971 A
3587573 Flack Jun 1971 A
3608560 Briskin et al. Sep 1971 A
3631856 Taylor Jan 1972 A
3681018 Knauff Aug 1972 A
3685527 Sherrill Aug 1972 A
3721240 Tamburri Mar 1973 A
3738374 Bennett Jun 1973 A
3744496 McCarty et al. Jul 1973 A
D229789 Berger Jan 1974 S
3789840 Rosenblatt Feb 1974 A
3804100 Fariello Apr 1974 A
3875476 Crandall et al. Apr 1975 A
3878041 Leitnaker et al. Apr 1975 A
3886954 Hannema et al. Jun 1975 A
3889690 Guarnieri Jun 1975 A
3895219 Richerson et al. Jul 1975 A
3943941 Boyd et al. Mar 1976 A
4016061 Wasa et al. Apr 1977 A
4068672 Guerra Jan 1978 A
4077784 Vayrynen Mar 1978 A
4083372 Boden Apr 1978 A
4098725 Yamamoto et al. Jul 1978 A
4110260 Yamamoto et al. Aug 1978 A
4131119 Blasutti Dec 1978 A
4141369 Burruss Feb 1979 A
4149548 Bradshaw Apr 1979 A
4164230 Pearlman Aug 1979 A
4193411 Faris et al. Mar 1980 A
4215708 Bron Aug 1980 A
4219032 Tabatznik et al. Aug 1980 A
4246913 Ogden et al. Jan 1981 A
4256945 Carter et al. Mar 1981 A
4259970 Green, Jr. Apr 1981 A
4275747 Miller Jun 1981 A
4284089 Ray Aug 1981 A
4331166 Hale May 1982 A
4413641 Dwyer, Jr. et al. Nov 1983 A
4419302 Nishino et al. Dec 1983 A
4429703 Haber Feb 1984 A
4430072 Kellogg et al. Feb 1984 A
4446878 Porenski, Jr. May 1984 A
4457319 Lamb et al. Jul 1984 A
4476882 Luke Oct 1984 A
4493331 Porenski, Jr. Jan 1985 A
4506683 Cantrell et al. Mar 1985 A
4515170 Cantrell et al. May 1985 A
4517996 Vester May 1985 A
4582072 Sanford Apr 1986 A
4620557 Cantrell et al. Nov 1986 A
4649944 Houck, Jr. et al. Mar 1987 A
4649945 Norman et al. Mar 1987 A
4681125 Johnson Jul 1987 A
4687008 Houck, Jr. et al. Aug 1987 A
4735217 Gerth et al. Apr 1988 A
4765347 Sensabaugh, Jr. et al. Aug 1988 A
4776353 Lilja et al. Oct 1988 A
4804002 Herron Feb 1989 A
4848376 Lilja et al. Jul 1989 A
4922901 Brooks et al. May 1990 A
4941486 Dube et al. Jul 1990 A
4945929 Egilmex Aug 1990 A
4945931 Gori Aug 1990 A
4947874 Brooks et al. Aug 1990 A
4947875 Brooks et al. Aug 1990 A
4966171 Serrano et al. Oct 1990 A
4981522 Nichols et al. Jan 1991 A
4991606 Serrano et al. Feb 1991 A
4993436 Bloom, Jr. Feb 1991 A
5000228 Manent et al. Mar 1991 A
5016656 McMurtrie May 1991 A
5040552 Schleich et al. Aug 1991 A
5042510 Curtiss et al. Aug 1991 A
5045237 Washburn Sep 1991 A
5060671 Counts et al. Oct 1991 A
5076296 Nystrom et al. Dec 1991 A
5085804 Washburn Feb 1992 A
5093894 Deevi et al. Mar 1992 A
5095921 Losee et al. Mar 1992 A
5116298 Bondanelli May 1992 A
5137578 Chan Aug 1992 A
5139594 Rabin Aug 1992 A
5144962 Counts et al. Sep 1992 A
5144964 Demain Sep 1992 A
5157242 Hetherington et al. Oct 1992 A
5159940 Hayward et al. Nov 1992 A
5179966 Losee et al. Jan 1993 A
5224498 Deevi et al. Jul 1993 A
5228460 Sprinkel et al. Jul 1993 A
5235157 Blackburn Aug 1993 A
5249586 Morgan et al. Oct 1993 A
5269327 Counts et al. Dec 1993 A
5274214 Blackburn Dec 1993 A
5285050 Blackburn Feb 1994 A
5322075 Deevi et al. Jun 1994 A
5353813 Deevi et al. Oct 1994 A
5369723 Counts et al. Nov 1994 A
5388594 Counts et al. Feb 1995 A
5396911 Casey, III et al. Mar 1995 A
5408574 Deevi et al. Apr 1995 A
5473251 Mori Dec 1995 A
5498855 Deevi et al. Mar 1996 A
5505214 Collins et al. Apr 1996 A
5514630 Willkens et al. May 1996 A
5591368 Fleischhauer et al. Jan 1997 A
5595706 Sikka et al. Jan 1997 A
5611360 Tang Mar 1997 A
5613504 Collins et al. Mar 1997 A
5613505 Campbell et al. Mar 1997 A
5665262 Hajaligol et al. Sep 1997 A
5666977 Higgins et al. Sep 1997 A
5666978 Counts et al. Sep 1997 A
5668978 Counts et al. Sep 1997 A
5692291 Deevi et al. Dec 1997 A
5724997 Smith et al. Mar 1998 A
5730158 Collins et al. Mar 1998 A
5743251 Howell et al. Apr 1998 A
5865185 Collins et al. Feb 1999 A
5865186 Volsey, II Feb 1999 A
5878752 Adams et al. Mar 1999 A
5894841 Voges Apr 1999 A
5924417 Braithwaite Jul 1999 A
5935975 Rose et al. Aug 1999 A
6006757 Lichtenberg Dec 1999 A
6016801 Philips Jan 2000 A
6026820 Baggett, Jr. et al. Feb 2000 A
6155268 Takeuchi Dec 2000 A
6164287 White Dec 2000 A
6196218 Voges Mar 2001 B1
6234167 Cox et al. May 2001 B1
6371127 Snaidr et al. Apr 2002 B1
6443146 Voges Sep 2002 B1
6516796 Cox et al. Feb 2003 B1
6598607 Adiga et al. Jul 2003 B2
6615840 Fournier et al. Sep 2003 B1
6715487 Nichols et al. Apr 2004 B2
6772756 Shayan Aug 2004 B2
6806682 Hsiao Oct 2004 B2
6810883 Felter et al. Nov 2004 B2
6854470 Pu Feb 2005 B1
6994096 Rostami et al. Feb 2006 B2
7073499 Reinhold et al. Jul 2006 B1
7117867 Cox et al. Oct 2006 B2
7131599 Katase Nov 2006 B2
7167641 Tam et al. Jan 2007 B2
7381277 Gonterman et al. Jun 2008 B2
7404405 Mehio Jul 2008 B1
7458374 Hale et al. Dec 2008 B2
D590988 Hon Apr 2009 S
D590989 Hon Apr 2009 S
D590990 Hon Apr 2009 S
D590991 Hon Apr 2009 S
7527059 Iannuzzi May 2009 B2
7614402 Gomes Nov 2009 B2
7726320 Robinson et al. Jun 2010 B2
7789089 Dube et al. Sep 2010 B2
7810508 Wyss-Peters et al. Oct 2010 B2
7832410 Hon Nov 2010 B2
7845359 Montaser Dec 2010 B2
7845369 Montaser Dec 2010 B2
7878962 Karles et al. Feb 2011 B2
7906936 Azancot et al. Mar 2011 B2
7913688 Cross et al. Mar 2011 B2
7920777 Rabin et al. Apr 2011 B2
7938121 Izumiya et al. May 2011 B2
7938124 Izumiya et al. May 2011 B2
7952322 Partovi et al. May 2011 B2
7997280 Rosenthal Aug 2011 B2
D646431 Awty et al. Oct 2011 S
D651338 Awty et al. Dec 2011 S
8079371 Robinson et al. Dec 2011 B2
D653390 Kaljura Jan 2012 S
D655036 Zhou Feb 2012 S
8113215 Rasouli et al. Feb 2012 B2
8118161 Guerrera et al. Feb 2012 B2
8127772 Montaser Mar 2012 B2
8156944 Han Apr 2012 B2
8157918 Becker et al. Apr 2012 B2
8196576 Kriksunov et al. Jun 2012 B2
8205622 Pan Jun 2012 B2
8258192 Wu et al. Sep 2012 B2
8314591 Terry et al. Nov 2012 B2
8365742 Hon Feb 2013 B2
8371310 Brenneise Feb 2013 B2
8375957 Hon Feb 2013 B2
8393331 Hon Mar 2013 B2
D684311 Liu Jun 2013 S
8459270 Coven et al. Jun 2013 B2
8459271 Inagaki Jun 2013 B2
8499766 Newton Aug 2013 B1
8511318 Hon Aug 2013 B2
8550068 Terry et al. Oct 2013 B2
8550069 Alelov Oct 2013 B2
8689805 Hon Apr 2014 B2
8833364 Buchberger Sep 2014 B2
8915254 Monsees et al. Dec 2014 B2
9078473 Worm et al. Jul 2015 B2
9078474 Thompson Jul 2015 B2
9204670 Liu Dec 2015 B2
9282772 Tucker et al. Mar 2016 B2
9326547 Tucker et al. May 2016 B2
9351522 Safari May 2016 B2
9408416 Monsees et al. Aug 2016 B2
9474306 Tucker et al. Oct 2016 B2
9510623 Tucker et al. Dec 2016 B2
20020005207 Wrenn et al. Jan 2002 A1
20020179101 Chavez Dec 2002 A1
20040020500 Wrenn et al. Feb 2004 A1
20040050396 Squeo Mar 2004 A1
20040099266 Cross et al. May 2004 A1
20040149296 Rostami et al. Aug 2004 A1
20050016550 Katase Jan 2005 A1
20050016553 Iannuzzi Jan 2005 A1
20050067503 Katase Mar 2005 A1
20050126651 Sherwin Jun 2005 A1
20050175331 Tam et al. Aug 2005 A1
20050279371 Billard et al. Dec 2005 A1
20060070633 Rostami et al. Apr 2006 A1
20060191546 Takano et al. Aug 2006 A1
20060196518 Hon Sep 2006 A1
20060254604 Martinez Fernandez Nov 2006 A1
20070074734 Braunshteyn et al. Apr 2007 A1
20070095357 Besso et al. May 2007 A1
20070102013 Adams et al. May 2007 A1
20070267031 Hon Nov 2007 A1
20070267032 Shan Nov 2007 A1
20070279002 Partovi Dec 2007 A1
20070280653 Viera Dec 2007 A1
20070295332 Ziegler et al. Dec 2007 A1
20080038363 Zaffaroni et al. Feb 2008 A1
20080047571 Braunshteyn et al. Feb 2008 A1
20080092912 Robinson et al. Apr 2008 A1
20080230052 Montaser Sep 2008 A1
20080276947 Martzel Nov 2008 A1
20090007925 Rasouli et al. Jan 2009 A1
20090012655 Kienman et al. Jan 2009 A1
20090044816 Rasouli et al. Feb 2009 A1
20090056729 Zawadzki et al. Mar 2009 A1
20090065011 Maeder et al. Mar 2009 A1
20090084391 Krupp Apr 2009 A1
20090095311 Han Apr 2009 A1
20090126745 Hon May 2009 A1
20090133704 Strickland et al. May 2009 A1
20090139533 Park et al. Jun 2009 A1
20090151717 Bowen et al. Jun 2009 A1
20090162294 Werner Jun 2009 A1
20090188490 Han Jul 2009 A1
20090230117 Fernando et al. Sep 2009 A1
20090272379 Thorens et al. Nov 2009 A1
20090283103 Nielsen et al. Nov 2009 A1
20090293892 Williams et al. Dec 2009 A1
20090301502 Mehio Dec 2009 A1
20100031968 Sheikh et al. Feb 2010 A1
20100083959 Siller Apr 2010 A1
20100126505 Rinker May 2010 A1
20100200006 Robinson et al. Aug 2010 A1
20100200008 Taieb Aug 2010 A1
20100206317 Albino et al. Aug 2010 A1
20100242975 Hearn Sep 2010 A1
20100242976 Katayama et al. Sep 2010 A1
20100275938 Roth et al. Nov 2010 A1
20100307518 Wang Dec 2010 A1
20110005535 Xiu Jan 2011 A1
20110011394 Edwards et al. Jan 2011 A1
20110011396 Fang Jan 2011 A1
20110036346 Cohen et al. Feb 2011 A1
20110036363 Urtsev et al. Feb 2011 A1
20110036367 Saito et al. Feb 2011 A1
20110088707 Hajaligol Apr 2011 A1
20110094523 Thorens et al. Apr 2011 A1
20110120455 Murphy May 2011 A1
20110120482 Brenneise May 2011 A1
20110126848 Zuber et al. Jun 2011 A1
20110147486 Greim et al. Jun 2011 A1
20110155153 Thorens et al. Jun 2011 A1
20110168194 Hon Jul 2011 A1
20110209717 Han Sep 2011 A1
20110220134 Duke et al. Sep 2011 A1
20110226236 Buchberger Sep 2011 A1
20110232654 Mass Sep 2011 A1
20110245493 Rabinowitz et al. Oct 2011 A1
20110253798 Tucker et al. Oct 2011 A1
20110265806 Alarcon et al. Nov 2011 A1
20110277756 Terry et al. Nov 2011 A1
20110277757 Terry et al. Nov 2011 A1
20110277760 Terry et al. Nov 2011 A1
20110277761 Terry et al. Nov 2011 A1
20110277764 Terry et al. Nov 2011 A1
20110277780 Terry et al. Nov 2011 A1
20110278189 Terry et al. Nov 2011 A1
20110290244 Schennum Dec 2011 A1
20110290268 Schennum Dec 2011 A1
20110303231 Li et al. Dec 2011 A1
20110304282 Li et al. Dec 2011 A1
20120006342 Rose et al. Jan 2012 A1
20120048266 Alelov Mar 2012 A1
20120090629 Turner et al. Apr 2012 A1
20120111347 Hon May 2012 A1
20120118301 Montaser May 2012 A1
20120145169 Wu Jun 2012 A1
20120167906 Gysland Jul 2012 A1
20120174914 Pirshafiey et al. Jul 2012 A1
20120186594 Liu Jul 2012 A1
20120199146 Marangos Aug 2012 A1
20120199663 Qiu Aug 2012 A1
20120201522 Stauffer et al. Aug 2012 A1
20120211015 Li et al. Aug 2012 A1
20120227753 Newton Sep 2012 A1
20120230659 Goodman et al. Sep 2012 A1
20120260927 Liu Oct 2012 A1
20120285475 Liu Nov 2012 A1
20120285476 Hon Nov 2012 A1
20120312313 Frija Dec 2012 A1
20120318882 Abehasera Dec 2012 A1
20120325227 Robinson et al. Dec 2012 A1
20130014772 Liu Jan 2013 A1
20130019887 Liu Jan 2013 A1
20130025609 Liu Jan 2013 A1
20130026798 Meier Jan 2013 A1
20130032159 Capuano Feb 2013 A1
20130032161 Herholdt Feb 2013 A1
20130037041 Worm et al. Feb 2013 A1
20130061861 Hearn Mar 2013 A1
20130081642 Safari Apr 2013 A1
20130087160 Gherghe Apr 2013 A1
20130118509 Richardson May 2013 A1
20130125906 Hon May 2013 A1
20130139833 Hon Jun 2013 A1
20130168880 Duke Jul 2013 A1
20130192615 Tucker et al. Aug 2013 A1
20130192616 Tucker et al. Aug 2013 A1
20130192619 Tucker et al. Aug 2013 A1
20130192620 Tucker et al. Aug 2013 A1
20130192621 Li et al. Aug 2013 A1
20130192622 Tucker et al. Aug 2013 A1
20130192623 Tucker et al. Aug 2013 A1
20130206154 Fernando et al. Aug 2013 A1
20130213418 Tucker et al. Aug 2013 A1
20130213419 Tucker et al. Aug 2013 A1
20130213420 Hon Aug 2013 A1
20130220315 Conley et al. Aug 2013 A1
20130228191 Newton Sep 2013 A1
20130263869 Zhu Oct 2013 A1
20130276798 Hon Oct 2013 A1
20130298905 Levin et al. Nov 2013 A1
20130300350 Xiang Nov 2013 A1
20130319440 Capuano Dec 2013 A1
20140000638 Sebastian et al. Jan 2014 A1
20140007863 Chen Jan 2014 A1
20140034071 Levitz et al. Feb 2014 A1
20140196718 Li et al. Jul 2014 A1
20140209110 Hon Jul 2014 A1
20140262869 Fath et al. Sep 2014 A1
20140262871 Fath Sep 2014 A1
20140262931 Fath Sep 2014 A1
20140338680 Abramov et al. Nov 2014 A1
20150020831 Weigensberg et al. Jan 2015 A1
20150128974 Hon May 2015 A1
20150250232 Hon Sep 2015 A1
Foreign Referenced Citations (230)
Number Date Country
421623 Jun 1937 BE
421623 Jun 1937 BE
1202378 Mar 1986 CA
1202378 Mar 1986 CA
421786 Sep 1966 CH
698603 Sep 2009 CH
87104459 Feb 1988 CN
87104459 Feb 1988 CN
2243191 Dec 1996 CN
1191696 Sep 1998 CN
1196660 Oct 1998 CN
2293953 Oct 1998 CN
2293953 Oct 1998 CN
1229616 Sep 1999 CN
2719043 Aug 2005 CN
277799 May 2006 CN
2777995 May 2006 CN
2777995 May 2006 CN
1906096 Jan 2007 CN
2889333 Apr 2007 CN
101116542 Feb 2008 CN
201018927 Feb 2008 CN
201029436 Mar 2008 CN
100377672 Apr 2008 CN
201054977 May 2008 CN
201067079 Jun 2008 CN
201076006 Jun 2008 CN
201079011 Jul 2008 CN
201085044 Jul 2008 CN
201076006 Aug 2008 CN
201108031 Sep 2008 CN
201127293 Oct 2008 CN
201146824 Nov 2008 CN
10132257 Dec 2008 CN
101322579 Dec 2008 CN
101322579 Dec 2008 CN
201238610 May 2009 CN
101518361 Sep 2009 CN
101524187 Sep 2009 CN
101557728 Oct 2009 CN
201379072 Jan 2010 CN
101843368 Sep 2010 CN
20170939 Jan 2011 CN
201709398 Jan 2011 CN
201709398 Jan 2011 CN
101983018 Mar 2011 CN
201767027 Mar 2011 CN
20178992 Apr 2011 CN
20179799 Apr 2011 CN
101606758 Apr 2011 CN
102014996 Apr 2011 CN
201789924 Apr 2011 CN
201789924 Apr 2011 CN
201797997 Apr 2011 CN
201797997 Apr 2011 CN
201830900 May 2011 CN
102106611 Jun 2011 CN
201860753 Jun 2011 CN
201860753 Jun 2011 CN
201869778 Jun 2011 CN
10210661 Aug 2011 CN
10216604 Aug 2011 CN
102106611 Aug 2011 CN
102166044 Aug 2011 CN
102166044 Aug 2011 CN
201986689 Sep 2011 CN
202014571 Oct 2011 CN
202014571 Oct 2011 CN
202014572 Oct 2011 CN
202014572 Oct 2011 CN
202026802 Oct 2011 CN
102264423 Nov 2011 CN
202026804 Nov 2011 CN
202026804 Nov 2011 CN
102266125 Dec 2011 CN
202068930 Dec 2011 CN
202068932 Dec 2011 CN
202122097 Jan 2012 CN
202145881 Feb 2012 CN
202179125 Apr 2012 CN
202233005 May 2012 CN
202233005 May 2012 CN
202233007 May 2012 CN
202233007 May 2012 CN
202262413 Jun 2012 CN
202286307 Jul 2012 CN
102655773 Sep 2012 CN
102740716 Oct 2012 CN
202456410 Oct 2012 CN
202525085 Nov 2012 CN
202603603 Dec 2012 CN
202603608 Dec 2012 CN
102894485 Jan 2013 CN
3610917 Aug 1988 DE
3640917 Aug 1988 DE
3735704 May 1989 DE
3735704 May 1989 DE
19854009 May 2000 DE
19854009 May 2000 DE
19935706 Feb 2001 DE
69824982 Oct 2004 DE
69824982 Oct 2004 DE
202010011436 Nov 2010 DE
0893071 Jul 1908 EP
0117355 Sep 1984 EP
0277519 Aug 1988 EP
0277519 Aug 1988 EP
0295122 Dec 1988 EP
0295122 Dec 1988 EP
0358002 Mar 1990 EP
0358002 Mar 1990 EP
0358114 Mar 1990 EP
0358114 Mar 1990 EP
0430566 Jun 1991 EP
0438862 Jul 1991 EP
0488488 Jun 1992 EP
0488488 Aug 1992 EP
0503767 Sep 1992 EP
0503767 Sep 1992 EP
0608783 Aug 1994 EP
0845220 Jun 1998 EP
0845220 Jun 1998 EP
0857431 Aug 1998 EP
0857431 Aug 1998 EP
0893071 Jan 1999 EP
1618803 Jan 2006 EP
1736065 Dec 2006 EP
1989946 Nov 2008 EP
1989946 Nov 2008 EP
2022350 Feb 2009 EP
2110033 Oct 2009 EP
2110033 Oct 2009 EP
2113178 Nov 2009 EP
2260733 Dec 2010 EP
2481308 Aug 2012 EP
1070376 Nov 2009 ES
203964 Sep 1923 GB
2148079 May 1985 GB
2148079 May 1985 GB
2406780 Apr 2005 GB
61068061 Apr 1986 JP
61068061 Apr 1986 JP
H11164679 Jun 1999 JP
2003527127 Sep 2003 JP
2006320286 Nov 2006 JP
2006320286 Nov 2006 JP
2007511437 May 2007 JP
2009537120 Oct 2009 JP
2010-104310 May 2010 JP
2010213579 Sep 2010 JP
3164992 Dec 2010 JP
100636287 Oct 2006 KR
100636287 Oct 2006 KR
200454110 Jun 2011 KR
20110006928 Jul 2011 KR
101081481 Nov 2011 KR
20110010862 Nov 2011 KR
200457340 Dec 2011 KR
8201585 Nov 1982 NL
8201585 Nov 1982 NL
94815 Jun 2010 RU
WO8602528 May 1986 WO
WO-8602528 May 1986 WO
WO9003224 Apr 1990 WO
WO-9003224 Apr 1990 WO
WO-9502970 Feb 1995 WO
WO95102970 Feb 1995 WO
WO-9748293 Dec 1997 WO
WO-9843019 Oct 1998 WO
WO0028843 Mar 2000 WO
WO-0028843 May 2000 WO
WO-0170054 Sep 2001 WO
WO03037412 May 2003 WO
WO-03037412 May 2003 WO
WO-2004043175 May 2004 WO
WO2004080216 Sep 2004 WO
WO-2004080216 Sep 2004 WO
WO2004095955 Nov 2004 WO
WO-2004095955 Nov 2004 WO
WO-2005049449 Jun 2005 WO
WO2005099494 Oct 2005 WO
WO-2005099494 Oct 2005 WO
WO2005120614 Dec 2005 WO
WO-2005120614 Dec 2005 WO
WO2007024130 Mar 2007 WO
WO-2007024130 Mar 2007 WO
WO2007066374 Jun 2007 WO
WO-2007066374 Jun 2007 WO
WO2007078273 Jul 2007 WO
WO-2007078273 Jul 2007 WO
WO2007098337 Aug 2007 WO
WO-2007098337 Aug 2007 WO
WO2007131449 Nov 2007 WO
WO-2007131449 Nov 2007 WO
WO2007131450 Nov 2007 WO
WO-2007131450 Nov 2007 WO
WO2007141668 Dec 2007 WO
WO-2007141668 Dec 2007 WO
WO2008055423 May 2008 WO
WO-2008055423 May 2008 WO
WO-2009135729 Nov 2009 WO
WO-2009135729 Nov 2009 WO
WO2010091593 Aug 2010 WO
WO-2010091593 Aug 2010 WO
WO2010145468 Dec 2010 WO
WO-2010145468 Dec 2010 WO
WO-2011015825 Feb 2011 WO
WO-2011050943 May 2011 WO
WO2011121326 Oct 2011 WO
WO-2011121326 Oct 2011 WO
WO2011124033 Oct 2011 WO
WO-2011124033 Oct 2011 WO
WO2011125058 Oct 2011 WO
WO-2011125058 Oct 2011 WO
WO2011146372 Nov 2011 WO
WO-2011146372 Nov 2011 WO
WO-2011146174 Nov 2011 WO
WO-2011147714 Dec 2011 WO
WO2012088675 Jul 2012 WO
WO-2012088675 Jul 2012 WO
WO2012109371 Aug 2012 WO
WO-2012109371 Aug 2012 WO
WO2012129787 Oct 2012 WO
WO-2012129787 Oct 2012 WO
WO2012129812 Oct 2012 WO
WO-2012129812 Oct 2012 WO
WO2012142293 Oct 2012 WO
WO-2012142293 Oct 2012 WO
WO-2012152053 Nov 2012 WO
WO-2013116565 Aug 2013 WO
Non-Patent Literature Citations (154)
Entry
Office Action for corresponding U.S. Appl. No. 15/911,520 dated Jan. 30, 2019.
Indian Examination Report for corresponding Application No. 6434/CHENP/2014 dated Mar. 13, 2019, English translation thereof.
U.S. Office Action dated Dec. 18, 2018 for corresponding U.S. Appl. No. 15/590,387.
“What is Vaping”, Dr. Linda Richter, Center on Addiction, 2018 [online], retrieved from the Internet, [retrieved Dec. 10, 2018], <URL: https://www.centeronaddiction.org/e-cigarettes/recreational-vaping/what-vaping>. (Year: 2018).
Definition of aerosol, Merriam-Webster [online], retrieved Jun. 8, 2017, [retrieved from the Internet], <URL: https://www.merriam-webster.com/dictionary/aerosol>. (Year: 2017).
International Search Report and Written Opinion for PCT/US13/24228 dated Apr. 9, 2013.
International Search Report and Written Opinion for PCT/US13/24229 dated Apr. 22, 2013.
International Search Report and Written Opinion for PCT/US13/24215 dated Apr. 22, 2013.
International Search Report and Written Opinion for PCT/US13/24222 dated Apr. 24, 2013.
International Search Report and Written Opinion for PCT/US13/27424 dated Apr. 25, 2013.
International Search Report and Written Opinion for PCT/US13/24224 dated May 13, 2013.
U.S. Appl. No. 13/843,028, filed Mar. 15, 2013, to Fath et al.
U.S. Appl. No. 13/843,449, filed Mar. 15, 2013, to Fath et al.
International Search Report and Written Opinion for PCT/US13/24219 dated Apr. 22, 2013.
U.S. Appl. No. 13/843,314, filed Mar. 15, 2013, to Fath et al.
International Search Report and Written Opinion for PCT/US13/24211 dated Apr. 19, 2013.
DE 19935706 Translation; Feb. 2001, Kumar Zubide.
Moroccan Office Action dated Mar. 13, 2015 issued in corresponding Malaysian Application No. 37287.
European Search Report dated May 29, 2015 issued in corresponding European Patent Application No. 13744358.6.
European Search Report dated Jul. 9, 2015 issued in corresponding European Patent Application No. 13743475.9.
Office Action for corresponding Chinese application No. 201380007594.2 dated Nov. 23, 2015 and English Translation thereof.
Notice of Allowance for co-related U.S. Appl. No. 13/741,217 dated Nov. 9, 2015.
Office Action for corresponding Chinese application No. 201380018495.4 dated Jan. 4, 2016 and English Translation thereof.
Kazakhstan Office Action dated Mar. 11, 2016 for corresponding KZ Application No. 2014/1685.1.
USPTO non-final Office Action dated Apr. 5, 2016 in U.S. Appl. No. 13/756,127.
Russian Office Action dated Mar. 11, 2016 for Applicatioan No. 2014/1685.1 (PCT/US2013/024219) with English machine translation.
Intermational Search Report and Written Opinion for PCT/US13/27432 dated May 2, 2013.
International Preliminary Report on Patentability for PCT/US2013/024215 dated Aug. 14, 2014.
Russian Office Action dated Jul. 14, 2016 for corresponding Application No. 2014135386.
Office Action for corresponding Russian application No. 2014135380 dated Aug. 8, 2016 and English translation thereof.
U.S. Office Action U.S. Appl. No. 15/049,573 dated Aug. 26, 2016.
Office Action for corresponding Chinese application No. 201380018578.3 dated Aug. 23, 2016 and English translation thereof.
International Search Report and Written Opinion for PCT/US13/27432 dated May 2, 2013.
International Preliminary Report on Patentability for PCT/US2013/024229 dated Aug. 14, 2014.
European Search Report dated May 29, 2015 issued in corresponding European Application No. 13744145.7.
Office Action for corresponding Chinese application No. 201380018578.3 dated Dec. 25, 2015 and English Translation thereof.
New Zealand Office Action dated Jun. 20, 2016 for corresponding NZ Application No. 720667.
Office Action for corresponding Japanese application No. 2014-555720 dated Jan. 10, 2017 and English Translation thereof.
European Search Report dated Dec. 23, 2016 issued in corresponding European Application No. 16165056.9.
Austrailian Notice of Acceptance for Patent Application No. 2013214987 dated Jan. 24, 2017.
New Zealand First Examination Report for IP No. 627444 dated Feb. 24, 2015.
Australian Notice of Acceptance for Patent Application No. 2013214987 dated Jan. 24, 2017.
Australian Examination Report for Patent Application No. 2013214987 dated Oct. 14, 2016.
Australian Examination Report for Patent Application No. 2013214997 dated Sep. 6, 2016.
New Zealand Examination Report for IP No. 627444 dated Feb. 24, 2015.
New Zealand Examination Report for IP No. 627439 dated Feb. 24, 2015.
New Zealand First Examination Report for IP No. 720667 dated Jun. 20, 2016.
Australian Examination Report for Patent Application No. 2013214991 dated Oct. 20, 2016.
Australian Examination Report for Patent Application No. 2013214998 dated Sep. 27, 2016.
Office Action for corresponding Chinese application No. 201380017766.4 dated Feb. 17, 2017 with English translation thereof.
New Zealand First Examination Report for IP No. 714217 dated Dec. 4, 2015.
European Search Report for Application No. 16165066.8 dated Mar. 16, 2017.
Office Action for corresponding Chinese Application No. 201380007585.3 dated May 11, 2017 and English translation thereof.
European Search Report for corresponding application No. 16165071.8 dated Apr. 7, 2017.
Office Action for corresponding Chinese application No. 201380018495.4 dated Mar. 8, 2017 and English translation thereof.
Office Action for corresponding Ukranian Application No. a201409540 dated Jun. 2, 2017 and English translation thereof.
Office Action for corresponding Ukranian Application No. a201409539 dated Jun. 9, 2017 and English translation thereof.
Office Action for corresponding European Application No. 13744145.7-1664 dated Jun. 12, 2017.
Office Action for corresponding European Application No. 13744358.6-1664 dated Jun. 12, 2017.
Office Action for corresponding European Application No. 13742632.5-1664 dated Jun. 12, 2017.
Office Action for corresponding European Application No. 13744358.6 dated Jun. 12, 2017.
Office Action for corresponding European Application No. 13743475.9-1614 dated Jul. 4, 2017.
Office Action for corresponding Ukrainian Application No. a201409537 dated Jul. 25, 2017.
United States Office Action for corresponding U.S. Appl. No. 15/065,422 dated Sep. 5, 2017.
Office Action for corresponding Chinese Application No. 201380007585.3 dated Sep. 1, 2017, English translation thereof.
Office Action for corresponding Japanese Application No. 2014-555720 dated Oct. 6, 2017 and English translation thereof.
Office Action for corresponding Japanese Application No. 2014-555726 dated Oct. 5, 2017 and English translation thereof.
Office Action for corresponding European Application No. 16 165 056.9 and dated Aug. 9, 2017.
Office Action for corresponding Morrocan Application No. 37286 dated Oct. 3, 2017 and English translation thereof.
Office Action for corresponding Morrocan Application No. 37289 dated Oct. 4, 2017 and English translation thereof.
Office Action for corresponding Morroccan Application No. 37289 dated Oct. 4, 2017 and English translation thereof.
Office Action for corresponding U.S. Appl. No. 15/683,135 dated Nov. 9, 2017.
Office Action for corresponding European Application No. 13744145.7-1664 dated Nov. 8, 2017.
Office Action for corresponding U.S. Appl. No. 15/339,005 dated Sep. 28, 2017.
Office Action for corresponding Ukrainian Application No. a201409539 dated Nov. 29, 2017 and English translation thereof.
Office Action for Corresponding U.S. Appl. No. 13/741,267 dated Nov. 4, 2015.
Office Action for Corresponding U.S. Appl. No. 13/741,267 dated Mar. 9, 2016.
Office Action for Corresponding U.S. Appl. No. 13/741,267 dated Ocotber 6, 2016.
Office Action for Corresponding U.S. Appl. No. 13/741,267 dated Jan. 26, 2017.
Notice of Allowance for Corresponding U.S. Appl. No. 13/741,267 dated Jul. 25, 2017.
Office Action for corresponding Chinese Office Action Application No. 201380016495.4 dated Aug. 12, 2016 and English Translation thereof.
United States Office Action for corresponding U.S. Appl. No. 15/590,456 dated Jan. 18, 2019.
International Preliminary Report on Patentability dated Aug. 14, 2014 for PCT/US2013/024219.
Moroccan Office Action dated Mar. 13, 2015 issued in Moroccan Application No. 37287.
European Search Report dated Jul. 9, 2015 issued in European Patent Application No. 13743475.9.
Non-Final Office Action dated Nov. 4, 2015 issued in U.S. Appl. No. 13/741,267.
Final Office Action dated Mar. 9, 2016 issued in U.S. Appl. No. 13/741,267.
Non-Final Office Action dated Oct. 6, 2016 issued in U.S. Appl. No. 13/741,267.
Final Office Action dated Jan. 26, 2017 issued in U.S. Appl. No. 13/741,267.
Notice of Allowance dated Jul. 25, 2017 issued in U.S. Appl. No. 13/741,267.
International Preliminary Report on Patentability dated Aug. 14, 2014 for PCT/US2013/024215.
European Search Report dated May 29, 2015 issued in European Patent Application No. 13744358.6.
Office Action for Chinese application No. 201380007594.2 dated Nov. 23, 2015 and English Translation thereof.
Notice of Allowance for co-related U.S. Appl. No. 13/741,217 dated Nov. 6, 2015.
Office Action for Chinese Office Action application No. 201380018495.4 dated Aug. 12, 2016 and English translation thereof.
New Zealand Office Action dated Jun. 20, 2016 for NZ Application No. 720667.
Office Action for Japanese application No. 2014-555720 dated Jan. 10, 2017 and English Translation thereof.
European Search Report dated Dec. 23, 2016 issued in European Application No. 16165056.9.
Office Action for Chinese Application No. 201380018495.4 dated Mar. 8, 2017 and English translation thereof.
Office Action for Chinese Application No. 201380007585.3 dated May 11, 2017 and English translation thereof.
European Search Report for application No. 16165071.8 dated Apr. 7, 2017.
Office Action for European Application No. 13744358.6-1664 dated Jun. 12, 2017.
Office Action for European Application No. 13743475.9-1614 dated Jul. 4, 2017.
Office Action for Ukrainian Application No. a201409537 dated Jul. 25, 2017.
Office Action for Japanese Application No. 2014-555720 dated Oct. 3, 2017 and English translation thereof.
Office Action for Japanese Application No. 2014-555726 dated Oct. 3, 2017 and English translation thereof.
Non-Final Office Action dated Jun. 8, 2016 issued in U.S. Appl. No. 15/049,573.
Non-Final Office Action dated Aug. 26, 2016 issued in U.S. Appl. No. 15/049,573.
Final Office Action dated Jan. 6, 2017 issued in U.S. Appl. No. 15/049,573.
Office Action for Moroccan Application No. 37286 dated Oct. 3, 2017 and English translation thereof.
Office Action for Moroccan Application No. 37287 dated Oct. 4, 2017 and English translation thereof.
Kazakhstan Office Action dated Mar. 11, 2016 for KZ Application No. 2014/1685.1.
Russian Office Action dated Jul. 14, 2016 in application No. 2014135386.
Preinterview First Office Action dated Jun. 1, 20016 issued in U.S. Appl. No. 14/991,449.
First Action Interview Office Action dated Jul. 11, 20016 issued in U.S. Appl. No. 14/991,449.
Preinterview First Office Action dated Oct. 27, 2016 issued in U.S. Appl. No. 15/285,931.
First Action Interview Office Action dated Dec. 13, 2016 issued in U.S. Appl. No. 15/285,931.
Notice of Allowance dated Mar. 9, 2017 issued in U.S. Appl. No. 15/285,931.
Supplemental Notice of Allowance dated May 4, 2017 issued in U.S. Appl. No. 15/285,931.
Non-Final Office Action dated Feb. 7, 2018 issued for U.S. Appl. No. 15/843,096.
United States Office Action for U.S. Appl. No. 15/065,422 dated Sep. 5, 2017.
Pre-Interivew First Office Action dated Jan. 19, 2018 issued for U.S. Appl. No. 15/065,467.
Office Action for Russian application No. 2014135380 dated Aug. 8, 2016 and English translation thereof.
Office Action for Chinese application No. 201380018578.3 dated Aug. 23, 2016 and English translation thereof.
European Search Report dated May 29, 2015 issued in European Application No. 13744145.7.
Office Action for Chinese application No. 201380018578.3 dated Dec. 25, 2015 and English Translation thereof.
Office Action for Chinese application No. 201380017766.4 dated Feb. 17, 2017 with English translation thereof.
Office Action for Ukranian Application No. a201409540 dated Jun. 2, 2017 and English translation thereof.
Office Action for Ukranian Application No. a201409539 dated Jun. 9, 2017 and English translation thereof.
Office Action for European Application No. 13744145.7-1664 dated Jun. 12, 2017.
Office Action for European Application No. 13743632.5-1664 dated Jun. 12, 2017.
Office Action for Chinese Application No. 201380007585.3 dated Sep. 1, 2017, English translation thereof.
Office Action for European Application No. 16 165 056.9 and dated Sep. 8, 2017.
Office Action for Moroccan Application No. 37289 dated Oct. 4, 2017 and English translation thereof.
Office Action for European Application No. 13744145.7-1664 dated Nov. 8, 2017.
Office Action for Ukrainian Application No. a201409539 dated Nov. 29, 2017 and English translation thereof.
Notice of Allowance dated Sep. 9, 2016 issued in U.S. Appl. No. 14/991,449.
First Action Interview—Office Action dated Mar. 5, 2018 issued in U.S. Appl. No. 15/065,467.
Office Action dated Mar. 15, 2018 in Malaysian Application No. PI 2014002168.
Office Action dated Mar. 15, 2018 in Malaysian Application No. PI 2014002250.
Office Action dated Apr. 26, 2018 in U.S. Appl. No. 15/911,520.
Office Action for Malaysian Application No. PI 2014002169 dated Mar. 30, 2018.
Re-examination Notice for Chinese Application No. 201380007585.3 dated May 21, 2018.
Final Office Action for corresponding U.S. Appl. No. 15/911,520 dated Aug. 9, 2018.
United States Office Action for corresponding U.S. Appl. No. 15/683,135 dated Mar. 20, 2019.
European Office Action for corresponding Application No. 13744358.6-1122 dated Mar. 1, 2019.
European Office Action for corresponding Application No. 16165066.8-1122 dated Mar. 18, 2019.
United States Notice of Allowance for corresponding U.S. Appl. No. 15/590,456 dated May 8, 2019.
Final Office Action for corresponding U.S. Appl. No. 15/911,520 dated May 13, 2019.
European Office Action for corresponding Application No. 16165056.9-1122, dated May 14, 2019.
European Office Action for corresponding Application No. 13743632.5-1122, dated May 15, 2019.
United States Office Action for U.S. Appl. No. 15/911,520, dated Nov. 21, 2019.
United States Final Office Action for U.S. Appl. No. 15/911,520, dated Apr. 13, 2020.
United States Notice of Allowance for U.S. Appl. No. 15/911,520, dated Aug. 5, 2020.
Related Publications (1)
Number Date Country
20180116296 A1 May 2018 US
Provisional Applications (1)
Number Date Country
61593004 Jan 2012 US
Divisions (1)
Number Date Country
Parent 13741267 Jan 2013 US
Child 15857836 US