This application is based on Japanese Patent Application No. 2007-70672 filed on Mar. 19, 2007, the contents of which are hereby incorporated by reference.
1. Technical Field
The present invention relates to an electronic component and a method of manufacturing the electronic component.
2. Related Art
A method of barrel plating is generally applied to forming a plated layer such as solder plated layer on a surface of a terminal electrode of an electronic component. In the barrel plating method, many electronic components are put into a basket dipped into a plating solution with metal grains called as dummy balls and plated by oscillating or rotating the basket and applying electricity to it. Even if dummy balls contact an insulating protective layer included in an electronic component, they do not contribute to plating layer formation. Hence, it is difficult to form a plating layer in an area of a terminal electrode close to the interface between a protective layer and a terminal electrode. As a result, a plated layer becomes thinned or unfinished in such area. This means that the area is exposed to the atmosphere, corroding the terminal electrode (a part including Ag in particular) with sulfur in the atmosphere.
In order to restrain such corrosion, JP-A-2004-253467 discloses the technology in that an auxiliary electrode is placed at the interface between a protective layer and a terminal electrode of a resistor element as a chip resistor device on a surface of a substrate where the resistor element is formed. The auxiliary electrode is connected to the terminal electrode.
On the other hand, other members of the resistor element such as a resistor member, a glass film for protecting the resistor member and the like are also placed on the surface of the substrate where the resistor element is formed. Hence, there is difficulty in that many members must be accurately arranged in a extremely narrow area if the auxiliary electrode further is placed at the interface between the protective layer and the terminal electrode.
An advantage of the present invention is to provide an electronic component where positional accuracy for arranging components constituting a circuit element such as a resistor element is mitigated and corrosion of a terminal electrode caused by sulfur in the atmosphere is reduced.
As a first aspect of the invention, an electronic component comprises; an insulating substrate including a front surface, a back surface and a side surface connecting the front surface with the back surface, a pair of terminal electrodes that are placed in end regions opposed to each other within the insulating substrate and on the front and back surfaces and the side surface; a circuit element including a resistor member and/or a dielectric member connected to the pair of terminal electrodes, being placed on one of surfaces of the insulating substrate; a protective layer protecting the resistor member and/or the dielectric member; an auxiliary electrode being placed, covering the interface between the protective layer and the terminal electrode and connecting the terminal electrode; and an plated layer placed on the surface of the terminal electrode and the auxiliary electrode. The interface between the protective layer and the terminal electrode is placed on the side surface or the back surface of the insulating substrate.
According to the first aspect of the invention, the interface between the protective layer and the terminal electrode is placed on the side surface or the back surface of the insulating substrate. Main members constituting a circuit element are generally placed on one surface of the insulating substrate. Only minor members are placed on the other surface (a back surface) opposing the above one surface and the side surface. In other words, if the interface between the terminal electrode and the protective film is formed on the side surface or the back surface and the auxiliary electrode is placed on the interface, there is little limitation for arranging and placing members. Accordingly, the first aspect of the invention can mitigate positional accuracy for arranging components constituting a circuit element such as a resistor element. Further, the interface is placed in an area where it is uneasy to form the above plated layer, making the terminal electrode easily exposed to the atmosphere. However, the first aspect of the invention blocks the terminal electrode from the atmosphere by placing the auxiliary electrode in the interface. Accordingly, the first aspect of the invention can reduce corrosion of the terminal electrode caused by sulfur in the atmosphere.
In the first aspect of the invention, the thicknesses of the terminal electrode, the protective layer and the auxiliary electrode placed on the side surface may be thinner than the thicknesses of the terminal electrode and the protective layer placed on a front surface of the insulating substrate. The above structure can reduce the dimensional fluctuation of the outer configuration of electronic component at the side surface even if fluctuation of thicknesses of the terminal electrode, the protective electrode and the auxiliary electrode is accumulated when the terminal electrode is placed on the side surface.
In the first aspect of the invention, the auxiliary electrode may be made of a conductive material mainly composed of nickel or nickel alloy. The above structure further avoids corrosion of the auxiliary electrode caused by sulfur in the atmosphere.
In the first aspect of the invention, the auxiliary electrode may be integrally extended from the front surface of the insulating substrate to the side surface of it. This structure can maintain the high adhesiveness of an electronic component with a substrate for mounting the electronic component.
In the first aspect of the invention, the side surface may include a concave portion. This structure can reduce fluctuation of the outer dimension of an electronic component even if the protective layer and the auxiliary electrode are placed on the side surface since members formed within the concave portion do not affect the outer dimension of an electronic component.
According to a second aspect of the invention, a method of manufacturing an electronic component comprises: a) forming a terminal electrode on front and back surfaces of a large insulating substrate and an inner wall of a plurality of through holes, the plurality of through holes being placed on a linearly-partitioned regions, which are horizontally and vertically located and crossed each other on the large insulating substrate, and on lines of the linearly-partitioned regions; b) forming a terminal electrode and a circuit element composed of a resistor member and/or an dielectric member on one surface of a unit of the insulating substrate (called as a unit insulating substrate) that is surrounded by the linearly-partitioned region; c) forming a protective layer on a surface of the circuit element and a conductive member within the inner wall of the through holes so as to protect the circuit element; d) forming an conductive auxiliary electrode so as to cover the interface between the protective layer and the inner wall of the through holes or a part of the conductive member on the back surface of the large insulating substrate; e) partitioning the large insulating substrate into a piece of the unit insulating substrate along the linearly-partitioned region; and f) depositing a low melting point metal film on a surface of the exposed conductive member and a surface of the auxiliary electrode by a method of barrel plating.
According to the second aspect of the invention, the interface between the protective layer and the terminal electrode is placed on the side surface or the back surface of the insulating substrate. Main components constituting a circuit element are generally placed on one surface (a front surface) of the insulating substrate. Only minor components are placed on other surface (a back side surface) opposing the above one surface and the side surface. In other word, if the interface between the terminal electrode and the protective film is formed on the side surface or the back surface and the auxiliary electrode is placed on the interface, there is no limitation for arrangement and placement of components. Accordingly, the second aspect of the invention can mitigate positional accuracy for arranging components constituting a circuit element such as a resistor element. Further, the interface is placed in area where it is uneasy to form the above plated layer, making the terminal electrode easily exposed to the atmosphere. However, the second aspect of the invention blocks the terminal electrode from the atmosphere by placing the auxiliary electrode in the interface. Accordingly, the second aspect of the invention can reduce corrosion of the terminal electrode because of sulfur in the atmosphere. Further, the aspect of the invention can form many circuit elements using a large insulating substrate, efficiently manufacturing electronic components.
In the second aspect of the invention, the terminal electrode, the protective layer, or the auxiliary electrode may be formed by a screen printing method during steps a), c) and d), the terminal electrode, the protective layer, or the auxiliary electrode may be moved into the inner wall of the through holes by sucking air via the through holes from the surface of the large insulating substrate opposing to the printing surface during the screen printing. This method efficiently can form the terminal electrode, the protective layer, or the auxiliary electrode within the inner wall of the through holes in a simple manner.
An advantage of the present invention is to provide an electronic component where positional accuracy for arranging components constituting a circuit element such as a resistor element is mitigated and corrosion of a terminal electrode caused by sulfur in the atmosphere is reduced.
The invention will be described with reference to the accompanying drawings, wherein like numbers reference like elements.
Embodiments of the invention will be described.
A resistor device regarding an embodiment of the invention will be explained with referring to drawings.
The four chips connected resistor device 1 comprises an insulating substrate 2 including a front surface 2a, a back surface 2b and a side surface 2c connecting the front surface 2a with the back surface 2b. The four chips connected resistor device 1 further comprises four pairs of terminal electrodes 3 and four resistor elements 5. The pairs of terminal electrodes 3 are placed on end regions opposing each other in the insulating substrate 2 and across the front and back surfaces 2a and 2b and the side surface 2C. The resistor elements 5 include four resistor bodies 4 connected with the pairs of terminal electrodes 3. Further, the device 1 includes a glass film 6 and an overcoating film 7. The glass film is placed at each of four positions as protecting four resistor bodies 4 and the overcoating film 7 integrally covers all glass films 6. The auxiliary electrode 9 is placed as covering an interface region 8 of the overcoating film 7 with a front terminal electrode 3A. The auxiliary electrode 9 is connected to the front surface terminal electrode 3A. The four chips connected resistor device 1 comprises the terminal electrodes 3 including the front surface terminal electrode 3A and the back surface terminal electrodes 3B, a nickel plated layer 10 placed on the surface of the auxiliary electrode and a solder plated layer 11. Then, an interface 8 between the overcoating layer 7 and the front surface terminal electrode 3A is placed on the side surface of the insulating substrate 2.
The thickness of each of the front surface terminal electrode 3A, the overcoating film 7 and the auxiliary electrode 9, placed on the side surface 2c, is thinner than the thickness of each of the front surface terminal electrode 3A, and the overcoating film 7, placed on the front surface 2a of the insulating substrate 2.
The auxiliary electrode 9 is made of a conductive material mainly composed of nickel or nickel alloy. The auxiliary electrode 9 is integrally formed across the front surface 2a and the side surface 2c of the insulating substrate 2. The side surface 2c includes a concave portion 2d having the interface 8.
The detail structure of the four chips connected resistor device 1 will be explained hereafter. As shown in
The structure of the resistor element 5 is explained with referring to
The resistor member 4 is connected to the pair of front surface terminal electrodes 3A since either a part of the resistor member 4 is overlapped with parts of the front surface terminal electrodes 3A. Then, the resistor member 4, the front surface terminal electrodes 3A and the back surface terminal electrodes 3B constitute the resistor element 5. The overcoating film 7 is extended to the central area of the side surface 2c which is around a central region along a path from the front surface 2a of the insulating substrate 2 to the back surface 2b. The overcoating film 7 also exists in an inner area of the trimmed groove 12, which is omitted in the drawing.
The auxiliary electrode 9 is extended from the upper end portion of the overcoating film 7 placed on the front surface 2a of the insulating substrate 2 to the interface area 8 between the overcoating film 7 and the front surface terminal electrode 3A. The interface 8 is placed at the end of the overcoating film 7. The overcoating film 7 and the front surface terminal electrode 3A and the back surface terminal electrodes 3B, which are not covered by the overcoating film 7, are covered with the nickel plated layer 10 that is also covered with a solder plated layer 11 as a low melting point metal film.
The structure of the four chips connected resistor device 1 shown in
Further, the above structure of the four chips connected resistor device 1 shown in
The auxiliary electrode 9 used for the four chips connected resistor device 1 in the embodiment of the invention is preferably made of a conductive material mainly composed of nickel or nickel alloy. The reason is that nickel or nickel alloy is hardly sulfurized compared to silver and the like. The auxiliary electrode 9 used for the four chips connected resistor device 1 in the embodiment of the invention is integrally placed extending from the front surface 2a of the insulating substrate 2 to around the center of the side surface 2c. Such integrally placing the auxiliary electrode 9 from the front surface 2a of the insulating substrate 2 to around the center of the side surface 2c can enhance the adhesiveness of the four chips connected resistor device 1 with a substrate for mounting the four chips connected resistor device 1. The reason is that an area for soldering can be enlarged when the four chips connected resistor device 1 is connected to a substrate for mounting the four chips connected resistor device 1 with using a solder. Namely, a solder-attached area is increased by a surface area of the auxiliary electrode 9. Further, integrally placing the auxiliary electrode 9 from the front surface 2a of the insulating substrate 2 to around the center of the side surface 2c can easily attain bulky supply. In the bulky supply, many of the four chips connected resistor devices 1 are discretely packaged and supplied with making them be aligned toward a predetermined direction. The reason of such easy supply is that the surface flatness of the front surface of the four chips connected resistor device 1 can be improved by aligning the auxiliary electrode 9.
Further, in the four chips connected resistor device 1 shown in
A method of manufacturing the four chips connected resistor device 1 regarding the embodiment will be explained with referring to
(Forming Terminal Electrode)
(Forming Resistor Element)
(Forming Protective Layer and Trimming)
Then, as shown in
(Forming Auxiliary Electrode)
(Partitioning)
Then, as shown in
During these first and second partitioning methods, a stress is applied toward the direction of opening the partitioned groove 2A in order to partition the large insulating substrate 2C and the reed shaped substrate 2F. Otherwise, other partitioning such as dicing may be applied instead of the above method. One advantage of dicing is to favorably maintain the dimensional accuracy of partitioning. Other advantage is to give a relatively small impact to the cut area. Further, dicing may be applied to the first partitioning, which is generally difficult to obtain high accuracy of dimensions of the insulating substrate. Then, the method of applying a stress to the direction of opening the partitioned groove 2A, which has an advantage in a manufacturing cost, may be applied to the second partitioning. Further, the partitioned groove 2A may be on other surface of the large insulating substrate 2C opposing to the front surface, or on the both surfaces.
(Plating)
Then, the surfaces of the exposed terminal electrode 3 and the auxiliary electrode 9 are plated by the barrel plating described before. In this plating, first, the nickel plated layer 10 is deposited and, next, the solder plated layer 11 having a low melting metal is deposited. As the result, as shown in
The four chips connected resistor device 1 and the method of manufacturing the same regarding the embodiments of the invention have been explained in the above. But, various modifications of them can be available within the spirit of the invention. In the above embodiments, the four chips connected resistor device 1 is shown as an electronic component. But, the above embodiments can be applied to other resistor devices such as a chip resistor device having a single piece of the resistor element 5, a chip resistor device having double connected resistor elements, eight connected resistor elements, or sixteen connected resistor elements, or a chip network resistor elements and the like. Further, the above mentioned embodiments can be applied to a circuit element such as a capacitor and coil and a hybrid electronic component in which such circuit element is combined with other element. If an electronic component includes capacitor as a circuit element, the resistor element 4 is replaced with a dielectric member.
Further, in the four chips connected resistor device 1 of the embodiments, the interface 8 between the overcoating film 7 as a protective layer and the terminal electrode 3 is placed at the end portion 2c of the insulating substrate 2. But, the interface 8 may be placed on the back surface of the insulating substrate 2. For example, in a case when it is difficult to fine tune the air suction at the time of through-hole printing, or when it is difficult to place the interface 8 at the end portion 2c because of a thinner thickness of the substrate 2, it is better that the interface 8 is formed on the back surface 2b (on the surface of the back surface terminal electrodes 3B) of the insulating substrate 2.
Further, the four chips connected resistor device 1 of the embodiments includes the concave portion 2d and is manufactured using the large insulating substrate 2C including the through holes 2B. But, the concave portion 2d and the through holes 2B may be omitted. In such case, an electrode member placed on the end portion 2c, the overcoating film 7 and the auxiliary electrode 9 may be formed by a thin film technology such as sputtering or a thick film technology such as coating. Otherwise, in a case when there are the concave portion 2d and the through holes 2B, electrode member placed on the end portion 2c, the overcoating film 7 and the auxiliary electrode 9 may be formed by a thin film technology such as sputtering or a thick film technology such as coating. If a thick film technology such as coating is applied to the above case, the thicknesses of the terminal electrode 3 placed at the end portion 2c, the overcoating film 7 as a protective layer and the auxiliary electrode 9 become equal to or thicker than that of the terminal electrode 3 placed on the front surface 2a of the insulating substrate 2. But, such thicknesses do not yield any problems. Despite the above case, the through-hole printing may be further advantageous for forming the concave portion 2d and the through holes 2B since films are simply and efficiently formed onto the end portion 2c by the through-hole printing.
The auxiliary electrode 9 regarding the four chips connected resistor device 1 of the embodiments is integrally extended from the front surface 2a of the insulating substrate 2 to the end portion 2c. However, in a case when a thin film technology such as sputtering or a thick film technology such as coating is applied to forming the electrode, the auxiliary electrode 9 is not integrally extended from the front surface 2a of the insulating substrate 2 to the end portion 2c. But, such formation does not yield any problems. If the sputtering technology is applied, Ni—Cr alloy metal may be used as a material of the auxiliary electrode 9.
Further, the auxiliary electrode 9 is formed with covering a part of the front surface terminal electrodes 3A via the overcoating film 7 in the process of forming the auxiliary electrode regarding the four chips connected resistor device 1 of the embodiments. However, the auxiliary electrode 9 may be formed with covering the entire region of the front surface terminal electrodes 3A. Otherwise, the auxiliary electrode 9 may be formed with covering a part or an entire region of the back surface terminal electrodes 3B by a through-hole printing toward the back surface of the large insulating substrate 2C.
The overcoating film 7 regarding the four chips connected resistor device 1 of the embodiments is made of any of resin materials. But, it may be made of any of glass materials instead of a resin. If it is made of a glass material, selecting a material for the auxiliary electrode 9 can be widened. For example, a material such as a Ag—Pd alloy metal glaze used in forming the front surface terminal electrode 3A and the back surface terminal electrodes 3B can also be used. Such material can be burned at the temperature similar to that for the overcoating film 7. A material such as a metal glaze may include a material deposited by plating.
Further, an ink is moved to the half depth of the through holes 2B during through-hole printing regarding the four chips connected resistor device 1 of the embodiments. But, such depth may be appropriately changed. For example, an ink may be distributed into an entire region of the inner wall of the through holes 2B.
Further, the shape of the through holes 2B regarding the four chips connected resistor device 1 of the embodiments is a circle. But, it may be an eclipse, a rectangular, or changed to any other shapes. But, it is preferably a circle in considering easiness of molding alumina. A material of the insulating substrate 2 may be any other more than alumina such as aluminum nitride and the like.
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