Electronic smoking article

Information

  • Patent Grant
  • 8997753
  • Patent Number
    8,997,753
  • Date Filed
    Thursday, January 31, 2013
    11 years ago
  • Date Issued
    Tuesday, April 7, 2015
    9 years ago
Abstract
An electronic smoking article comprising an aerosol generator and a mechanical aerosol converter insert having the capacity to improve characteristics of aerosol produced by the aerosol generator, including sensory attributes.
Description
SUMMARY OF SELECTED FEATURES

An electronic cigarette or cigar (collectively “electronic smoking article”) is provided which includes a heater element which vaporizes liquid material to produce an aerosol or “vapor”. In an embodiment, the heater element comprises a resistive heater coil, with a wick extending therethrough. Aerosol generated by the heater coil and wick assembly is drawn down a central channel toward the mouth end portion of the smoking article.


The electronic article preferably includes a mechanical aerosol converter (MAC) insert having a face and one or more outlets. The face and outlets of the MAC insert are mutually arranged and the face is aligned with the central channel so as to cause the aerosol to strike the face prior to it being drawn out from the article. As a result, the aerosol particle size distribution is shifted to a distribution comprising a range of smaller particles, and both the vapor phase components of the aerosol and the temperature of the aerosol are reduced. These effects and possibly others are believed to contribute to sensory attributes of reduced throat irritation, even at higher levels of nicotine content in the liquid formulation, and to improved mouth feel over aerosols of electronic smoking articles lacking a MAC insert as taught herein.





BRIEF DESCRIPTION OF THE DRAWINGS


FIGS. 1A and 1B are cross sectional side views of an electronic smoking article according to a first embodiment;



FIG. 2 is a perspective view of a mechanical aerosol converter (MAC) insert of the electronic smoking article shown in FIG. 1A, the perspective being viewed in the general direction of arrow A in FIG. 1A;



FIGS. 3A and 3B are perspective views of MAC inserts of FIGS. 1A and 1B, the perspective being viewed in the general direction of arrow B in FIGS. 1A and 1B;



FIG. 4 is a side view of the MAC insert of FIGS. 1A, 2 and 3A, with interior features of the face shown in dashed lines;



FIG. 5A is a perspective view of an another embodiment of a MAC insert including a flange for use in the electronic smoking article shown in FIG. 1A, the perspective being viewed in the general direction of arrow B in FIG. 1A;



FIG. 5B is a perspective view of an another embodiment of a MAC insert excluding a flange for use in the electronic smoking article shown in FIG. 1B, the perspective being viewed in the general direction of arrow B in FIG. 1B;



FIG. 6 is an abbreviated sectional side view of an electronic smoking article in accordance with another embodiment including a flow-centralizer disc interposed between a first MAC insert, shown in FIG. 5A, and a second MAC insert, shown in FIG. 5B;



FIG. 7 is a perspective view of the flow-centralizing disc of FIG. 6;



FIG. 8 is a stylized representation of a possible effect of aerosol striking a MAC insert prior to exiting an electronic smoking;



FIG. 9 is an abbreviated sectional side view of an electronic smoking article having a mouth end insert constructed in accordance with another embodiment, and including a flow-centralizer disc interposed between an upstream MAC insert, as shown in FIG. 5B, and a downstream, multi-ported mouthpiece insert;



FIGS. 10A and 10B are perspective views of a multi-ported mouth end insert for use in the electronic smoking article of FIG. 9;



FIG. 11 is an abbreviated sectional side view of an electronic smoking article having a MAC insert constructed in accordance with another embodiment; wherein the MAC insert is in the form of a disc.



FIG. 12 is a planar view of the MAC insert as shown in FIG. 11;



FIG. 13 is sectional side view of a detail of a gasket having a convergent outlet for inclusion in any of the foregoing embodiments;



FIG. 14 is a cross sectional view of a MAC insert including a plurality of partitions therein; and



FIG. 15 is an abbreviated cross sectional side view of an electronic smoking article including another embodiment of a MAC insert.





DETAILED DESCRIPTION

Electronic Smoking Article Layout


Referring to FIGS. 1A and 1B, an electronic smoking article (cigarette) 60 comprises a replaceable cartridge (or first section) 70 and a reusable fixture (or second section) 72, which in the preferred embodiment, are coupled together at a threaded connection 205 or by other convenience such as a snug-fit, detent, snap-fit, clamp and/or clasp. Generally, the second section 72 includes a puff sensor 16 responsive to air drawn into the second section 72 via an air inlet port 45 adjacent the free end or tip of the electronic smoking article 60, a battery 1 and control circuitry. The disposable first section 70 includes a liquid supply region 22 of liquid and a heater 14 that aerosolizes liquid that is drawn from the liquid supply region 22 through a wick 28. Upon completing the threaded connection 205, the battery 1 is connectable with the electrical heater 14 of the first section 70 upon actuation of the puff sensor. Air is drawn primarily into the first section 70 through one or more air inlets 44 located in the outer tube (casing) 6.


In a preferred embodiment, once the liquid of the cartridge is spent, only the first section 70 is replaced. An alternate arrangement includes a layout where the entire electronic smoking article 60 is disposed once the liquid supply is depleted. In such case the battery type and other features might be engineered for simplicity and cost-effectiveness, but generally embodies the same concepts as in the preferred embodiment in which the second section is reused and/or recharged.


In a preferred embodiment, the electronic smoking article 60 is about the same size as a conventional cigarette. In some embodiments, the electronic smoking article 60 can be about 80 mm to about 110 mm long, preferably about 80 mm to about 100 mm long and about 7 mm to about 8 mm in diameter. For example, in a preferred embodiment, the electronic smoking article is about 84 mm long and has a diameter of about 7.8 mm.


Preferably, at least one adhesive-backed label is applied to the outer tube 6, preferably about the first section 70. The label preferably completely circumscribes the electronic smoking article 60 and can be colored and/or textured to provide the look and/or feel of a traditional cigarette. The label can include holes therein which are sized and positioned so as to prevent blocking of the air inlets 44 in the outer tube 6 (or casing).


The outer tube 6 and/or the inner tube 62 may be formed of any suitable material or combination of materials. Examples of suitable materials include metals, alloys, plastics or composite materials containing one or more of those materials, or thermoplastics that are suitable for food or pharmaceutical applications, for example polypropylene, polyetheretherketone (PEEK), ceramic, and polyethylene. Preferably, the material is light and non-brittle. The inner tube 62 can also include a substantially water impermeable coating.


Referring now to FIGS. 1A, 1B, 6 and 9, the first section 70 includes the outer tube (or casing) 6 extending in a longitudinal direction and the inner tube (or chimney) 62 coaxially positioned within the outer tube 6. Preferably, a nose portion 61 of an upstream gasket (or seal) 15 is fitted into an upstream end portion 65 of the inner tube 62, while at the same time, an outer perimeter 67 of the upstream gasket 15 provides a liquid-tight seal with an interior surface of the outer tube 6. The upstream gasket 15 also includes a central, longitudinal air passage 20, which opens into an interior of the inner tube 62 that defines a central channel 21.


Referring to FIG. 1, a transverse channel 33 can be provided across a backside potion of the upstream gasket 15, which intersects and communicates with the central channel 20 of the gasket 15. This channel 33 assures communication between the central channel 20 and a space 35 defined within a cathode connector piece 37. In the preferred embodiment, the piece 37 includes a threaded section for effecting the threaded connection 205. The cathode connector piece 37 includes opposing notches about its perimeter, which, upon insertion of the cathode connector piece 37 into the outer tube 6, are aligned with the location of each of two RTD-controlling, air inlet ports 44 and 44′ in the outer tube 6. Preferably, the air inlet ports 44 and 44′ are precision drilled so as to provide the smoking article a predetermined, desired resistance to draw (RTD) ranging from about 60 mm H2O to about 150 mm H2O, more preferably about 90 mm H2O to about 110 mm H2O, most preferably about 100 mm H2O to about 130 mm H2O.


The space defined between the upstream gasket 15, a downstream gasket 10 and the outer tube 6 and the inner tube 62 establish the confines of the liquid supply region 22. The liquid supply region 22 comprises a liquid material and optionally a liquid storage medium 210 operable to store the liquid material therein. The liquid storage medium 210 may comprise a winding of cotton gauze or other fibrous material about the inner tube 62.


In the preferred embodiment, the liquid supply region 22 is contained in an outer annulus 620 between inner tube 62 and outer tube 6 and between the gaskets 10 and 15. Thus, the liquid supply region 22 at least partially surrounds the central air passage 21. The heater 14 preferably extends transversely across the central channel 21 between opposing portions of the liquid supply region 22, although the teachings herein are applicable to arrangements wherein the heater 14 is oriented in the longitudinal direction instead of transversely.


Preferably, the liquid storage medium 210 is a fibrous material comprising cotton, polyethylene, polyester, rayon and combinations thereof. Preferably, the fibers have a diameter ranging in size from about 6 microns to about 15 microns (e.g., about 8 microns to about 12 microns or about 9 microns to about 11 microns). The liquid storage medium 210 can be a sintered, porous or foamed material. Also preferably, the fibers are sized to be irrespirable and can have a cross-section which has a y shape, cross shape, clover shape or any other suitable shape. In the alternative, the liquid supply region 22 may comprise a filled tank lacking a fibrous storage medium 21 and containing only liquid material.


Also preferably, the liquid material has a boiling point suitable for use in the electronic smoking article 60. If the boiling point is too high, the heater 14 will not be able to vaporize liquid in the wick 28. However, if the boiling point is too low, the liquid may vaporize even when the heater 14 is not being activated.


Preferably, the liquid material includes a tobacco-containing material including volatile tobacco flavor compounds which are released from the liquid upon heating. The liquid may also be a tobacco flavor containing material or a nicotine-containing material. Alternatively, or in addition, the liquid may include a non-tobacco material. For example, the liquid may include water, solvents, ethanol, plant extracts and natural or artificial flavors. Preferably, the liquid further includes an aerosol former. Examples of suitable aerosol formers are glycerine and propylene glycol.


In use, liquid material is transferred from the liquid supply region 22 and/or liquid storage medium 210 by capillary action at each end portion of the wick 28. In an embodiment, the heater 14 can at least partially surround a central portion of the wick 28 such that when the heater 14 is activated, the liquid in that portion of the wick 28 is vaporized by the heater 14 to form an aerosol. In other embodiments, the heater 14 can be disposed adjacent a portion of the wick without being wound about the wick. The wick 28 preferably comprises filaments having a capacity to draw a liquid, more preferably a bundle of glass (or ceramic) filaments and most preferably a bundle comprising a group of windings of glass filaments, preferably three of such windings, all which arrangements are capable of drawing liquid via capillary action via spacings between the filaments. Preferably, the wick 28 is flexible and includes three strands, each strand including a plurality of filaments. Moreover, it is noted that the end portions of the wick 28 are preferably flexible and foldable into the confines of the liquid supply region 22.


Preferably, a nose portion 81 of a downstream gasket 10 is fitted into a downstream end portion 83 of the inner tube 62. An outer perimeter 82 of the gasket 10 provides a substantially liquid-tight seal with an interior surface of the outer tube 6. Aerosol generated by the heater 14 travels from the central channel 21 and through a central channel 63 in the downstream gasket 10 and into a remaining downstream end portion of a mouth piece portion 99 of the smoking article 60. From the central channel 63 of the gasket 10, the aerosol, in substantial part, is drawn into contact with a face 102 of a mechanical aerosol converter (MAC) insert 104.


Referring now to FIG. 2, in one embodiment, the MAC insert 104 comprises a cylindrical body portion 106 having an outer diameter that can be sized to provide a sliding fit with the interior surfaces of the outer tube 6 of the smoking article 60. As shown in FIG. 1B, an upstream end portion 108 of the cylindrical body portion 106 of the MAC insert 104 is preferably brought into contact with adjacent portions of the gasket 10 so that the spatial relationship and orientation between the MAC insert 104 and the gasket 10 are essentially the same from one article 60 to the next. Thus, the body portion 106 is provided with a length such that a face portion 110 of the MAC insert 104 is flush with or at some other desired relation with the downstream end of the outer tube 6. The MAC insert 104 can be formed of any suitable substantially air impermeable material, such as plastic or metal foil.


The transverse, annular face portion 110 of the MAC insert 104 is provided with a plurality of orifices 112, which in an embodiment comprise six circular orifices 112, each orifice having a diameter ranging from about 0.015 inch to about 0.090 inch (e.g., about 0.020 inch to about 0.040 inch or about 0.028 inch to about 0.038 inch). After contacting the face 102 of the MAC insert 104, aerosol is then drawn through the orifices 112 in the MAC insert 104, which are disposed radially about the face 102.


Although the orifices 112 are shown as extending in a longitudinal direction, all or some of them may be directed divergently so as to impart a radially outward component to the velocity to the aerosol streams as they are drawn through the MAC insert 104. The number, size and shape of the orifices can be varied in the practice of the teachings herein.


Referring now to FIGS. 2 and 4, the face 102 of the MAC insert 104 is disposed within the confines of the cylindrical body portion 106 by a predetermined spacing “L” from the edge portion 108 of the cylindrical body portion 106 such that upon placement of the MAC insert 104 against the gasket 10, the face 102 is positioned a predetermined distance apart from the discharge orifice 63 of the gasket 10. In a preferred embodiment, that distance is in the range of about 1 mm to about 3 mm, more preferably in the range of about 1.5 mm to about 2.5 mm, but could be established at other values through analytic testing and/or modeling to find which distance is preferred for any particular design of the electronic smoking article 60.


Referring to FIGS. 3A, 3B, and 4, the MAC insert 104 can include a central recess 114 to facilitate molding operations during the manufacture of the MAC insert 104. It is envisioned that the MAC insert 104 could be formed without the recess 114 such that an external face portion 110 of the insert is generally circular and planar instead of being annular as shown in FIGS. 3A and 3B. In addition, the MAC insert 104 may be provided with a flange 116 (as shown in FIG. 3A) which could act as a stop against the downstream edge of the outer tube 6 so as to register placement within the smoking article 60 with the flange 116 instead of abutment against the insert 10 as shown in FIG. 1A. Such arrangement is advantageous when it is desired to locate the MAC insert 104 in spaced apart relation from the gasket 10. It is also envisioned that the MAC insert 104 and the gasket 10 can be integrally formed so as to simplify manufacture and assembly of the electronic smoking article 60.


Referring now to FIGS. 1 and 8, as aerosol is drawn through the central channel 63 of the gasket 10, it is directed against the face 102 of the MAC insert 104, whereupon heat is exchanged such that the temperature of the aerosol is reduced. In some cases, the temperature can be reduced by 30° C. or more. When the aerosol strikes the face 102, larger aerosol particles, as represented in region X of FIG. 8, tend to break up to form several smaller particles, as represented in region Y.


In particular and in reference to region X of FIG. 8, it is believed for that upon exiting the central channel 63 of the gasket 10, the aerosol comprises large particles of propylene glycol and water 510 and relatively large, separate particles of nicotine droplets 515. The relatively large, nicotine droplets 515 comprise a vapor phase component of the aerosol and are known to contribute undesirable sensory responses such as throat irritation and/or harshness when inhaled.


Not wishing to be bound by theory, upon striking the face 102 of the MAC insert 104, it is believed that the aerosol undergoes a transformation such as shown in region Y of FIG. 8, whereby larger particles 510 and 515 of the aerosol as previously described become smaller particulate phase constituents 600 comprising smaller, particulate phase nicotine 615 surrounded by propylene glycol 610.


As a result of drawing the aerosol through the MAC insert 104, it has been found that the aerosol of the electronic smoking article 60 tends to be lower in temperature, to have a particle size distribution that has shifted toward a range of smaller particle sizes and that the vapor phase components as previously described are reduced. It is also believed that the MAC insert 104 increases production of core-shell particles comprising a nicotine particle surrounded by a shell of propylene glycol. These attributes and others are believed to contribute to a finding that the aerosol has acceptable sensory attributes including less throat irritation and improved sensory experience, even at higher nicotine levels in the liquid formulation. The reduced aerosol temperature is believed to improve mouth feel.


As noted, use of the MAC insert 104 tends to avoid perceived sensory deficits when elevated levels of nicotine are added to the liquid formulation of an electronic smoking article. For example, an electronic smoking article of the prior art tends to produce perceived sensations of harshness and/or irritation if the liquid formulation is modified to include nicotine at levels greater than 2% by weight. It has been found that with inclusion of a MAC insert in accordance with the teachings herein, nicotine levels in the liquid formulation can be increased up to 6% nicotine with acceptable sensory attributes. Such provides opportunity to produce an electronic smoking article 60 having high impact with little to no irritation. With inclusion of the MAC insert 104, an electronic smoking article can be constructed which provides 0.18 mg of nicotine per puff on a 10 puff basis, which provides comparable levels of nicotine when compared to traditional cigarettes, with acceptable sensory attributes.


With regard to particle size distribution, it has been found that particles size distribution of an aerosol from a smoking article lacking a MAC insert as taught herein has a bell-shaped distribution of sizes in the range of about 0.1 nanometer (nm) to about 0.7 nm. In contrast, the particles size distribution of an aerosol from an electronic smoking article including the MAC insert as described herein has a bell-shaped distribution of sizes in the range of about 0.1 nm to about 0.6 nm, a significant decrease in particle size distribution.


It has also been found that some electronic smoking articles not including a MAC insert tend to produce aerosols having temperatures at or above 110° Celsius. In contrast, an electronic smoking article 60 as described in FIGS. 1A and 1B, which include the MAC insert 104, produce an aerosol having a temperature, when measured at the exit of the mouth end of the electronic smoking article 60, of about 60° C. to about 100° C.


Referring now to FIG. 5A, according to another embodiment, the MAC insert 104a, 104b includes three exit orifices 112a, 112b that are elongated, generally kidney shaped and extend circumferentially about the perimeter of the face 102a, 102b of the MAC insert 104a, 104b. Being larger, the orifices 112a, 112b are less subject to risk of accumulation of material and blockage. In a preferred embodiment, each orifice 112a, 112b has a length of about 2 mm to about 5 mm, preferably about 3 mm to about 4 mm, and a width of about 0.5 mm to about 1 mm in width. The face 102a, 102b can have a diameter of about 3 mm to about 5 mm. The size, circumferential extent and the number of the orifices 112a, 112b may be varied in the practice of these teachings with respect to any particular article.


Referring now to FIG. 6, another embodiment of an electronic smoking article 60 comprises many of the same components as described with reference to FIGS. 1A and 1B, but with the battery section 1 and the puff sensors/control circuitry 16 shown in block diagram. In this embodiment, a first MAC insert 104b is disposed immediately downstream of the gasket 10 as previously described with reference to FIG. 1. A disk 120 having a central orifice 122 is positioned downstream of the first MAC insert 104b and immediately upstream of a second MAC insert 104a.


The disc 122 with its central orifice 122 operates to centralize the discharge of the first MAC insert 104b before it is drawn through the second MAC insert 104a. In essence the flow-centralizing disc imparts additional compaction of the aerosol while also directing the flow against the face 102a of the second MAC insert 104a. With this arrangement, additional mechanical aerosol converting events are imparted on the aerosol so as to further enhance the beneficial aspects of reduction of aerosol particle size upon the aerosol generated by the electronic smoking article 60.


It is envisioned that the first MAC insert 104b may have orifices of the shape such as shown in FIG. 2, whereas the second MAC insert 104a might have the elongated orifices shown in FIG. 5A or 5B or vise-versa. Alternatively, both the first MAC insert 104b and the second MAC insert 104a can include the round orifices shown in FIGS. 2 and 3 or both can include the elongated orifices shown in FIGS. 5A and 5B. Moreover, the second MAC insert 104a can include a flange 103 as shown in FIG. 5A, while the first MAC insert 104b may exclude a flange.


Referring now to FIG. 9, another embodiment provides a smoking article as previously described including a downstream gasket 10 followed by (in the sense of direction of aerosol flow), a MAC insert 104, 104a, 104b, as shown in FIG. 2, 5A or 5B, which is in turn is followed by a disk 120, as previously described, which in turn is followed by a multiport mouth end insert 140 having a plurality of divergent passages 142. Referring now also to FIG. 10A, the multi-port mouth end insert 140 is constructed in accordance with the teachings of U.S. application Ser. No. 13/741,217 to Tucker et al. filed Jan. 14, 2013 and titled “Electronic Cigarette”, which is incorporated in its entirety by reference thereto.


In a preferred embodiment, the multi-port mouth end insert 140 includes at least two diverging outlet passages 142 (e.g., preferably 2 to 10 outlet passages 142, more preferably 4 outlet passages or 3, 4, 5, 6, or more passages 142). Preferably, the outlet passages 142 are located off-axis and are angled outwardly in relation to the central channel 21 of the inner tube 62 (i.e., divergently). Also preferably, the outlets 142 are uniformly distributed about a perimeter of the insert 140 so as to substantially uniformly distribute aerosol in a smoker's mouth during use and create a greater perception of fullness in the mouth. Thus, as the aerosol passes into a smoker's mouth, the aerosol enters the mouth and moves in divergent directions so as to provide a full mouth feel. In contrast, electronic smoking articles having a single, on-axis orifice tend to direct its aerosol as single jet of greater velocity toward a more limited location within a smoker's mouth.


In addition, the multi-ported mouthpiece insert 140 and its diverging outlet passages 142 are arranged and include interior surfaces 144 such that droplets of un-aerosolized liquid material, if any, that may be entrained in the aerosol strike the interior surfaces 144 of the mouth end insert 140 and/or strike portions of walls of the diverging outlet passages 142. As a result such droplets are substantially removed or broken apart so as to enhance o\the aerosol.


In the preferred embodiment, the diverging outlet passages 142 are angled at about 5° to about 60° with respect to the longitudinal axis of the outer tube 6 so as to more completely distribute aerosol throughout a mouth of a smoker during use and to remove droplets. In a preferred embodiment, there are four diverging outlet passages 142, each at an angle of about 40° to about 50° with respect to the longitudinal axis of the outer tube 6, more preferably about 40° to about 45° and most preferably about 42°.


Preferably, each of the diverging outlet passages 142 has a diameter ranging from about 0.015 inch to about 0.090 inch (e.g., about 0.020 inch to about 0.040 inch or about 0.028 inch to about 0.038 inch). The size of the diverging outlet passages 24 and the number of diverging outlet passages 24 can be selected to adjust the resistance to draw (RTD) of the electronic smoking article 60, if desired. Moreover, the mouth end insert 8 can be formed of a polymer selected from the group consisting of low density polyethylene, high density polyethylene, polypropylene, polyvinylchloride, polyetheretherketone (PEEK) and combinations thereof. The mouth end insert 8 may also be colored if desired.


In one embodiment, shown in FIG. 10B, the mouth end insert 140 can include an on-axis central outlet passage 143, together with the diverging outlet passages 142.


As shown in FIG. 9, an interior surface 144 of the mouth end insert 140 can comprise a generally domed surface 144. Alternatively, the interior surface 144 of the mouth end insert 140 can be generally cylindrical or frustoconical, with a planar end surface. Preferably, the interior surface 144 is substantially uniform over the surface thereof. Moreover, the interior surface 144 can be symmetrical about the longitudinal axis of the mouth end insert 140. However, in other embodiments, the interior surface 140 can be irregular and/or have other shapes.


In a preferred embodiment, the interior surfaces 144 of the insert 140 may include a void disposed at the convergence of the diverging outlet passages 144.


Referring now to FIG. 11, in another embodiment, the electronic smoking article 60 includes a gasket 10 having a central channel 63 as previously described with the other embodiments, together with a MAC insert 104c, which functions in a manner similar to that described with respect to the MAC insert 104 of the first embodiment with reference to FIGS. 1A and 1B. However, the MAC insert 104c of embodiment in FIG. 11 is in the form of a single disc having openings 112c radially spaced outwardly of a central face 102c. In this embodiment, the openings 112c and the face 102c are coplanar, whereas in the first embodiment shown in FIGS. 1A, 1B, 2 and 3, the face 102 is spaced upstream from the openings 112. Each opening 112c may have a diameter ranging from about 0.015 inch to about 0.090 inch (e.g., about 0.020 inch to about 0.040 inch or about 0.028 inch to about 0.038 inch).


Referring now to FIG. 13, in that higher velocities may enhance the benefits of impaction, expedients may be implemented to increase the speed of the aerosol as it approaches the face 102 of the MAC insert 104. For example, the gasket 10 can include a constricted central channel 63′ to produce greater velocities in the aerosol as it is drawn through the central channel 63′, and acts as an aerosol stream forming element.


Referring now to FIG. 14, in another embodiment, the MAC insert 104d comprises a cylindrical body 106 and a series of partitions 979 extending partially across the an interior of the cylindrical body 106 in alternating relationship. The partitions 979 are longitudinally spaced from one another and present multiple faces 102d, which aerosol may strike as aerosol passes through the MAC insert 104d. In this embodiment, the outlet orifices 112d are provided downstream of the partitions 979.


Optionally, the orifices 112, 112a, 112b, 112c, 112d, 112e in the embodiments of FIGS. 2, 3, 5A, 5B, 12, 14 and 15 may be sized to provide an RTD controlling aspect.


Optionally, as shown in FIG. 15, it is contemplated that the relative, radial positions of the face 102e and the exit orifices 112e can be reversed such that an aerosol may be directed instead to an outer peripheral region of the MAC insert 104e and drawn through a central orifice 112e.


Optionally, the face 102, 102a, 102b, 102c, 102d, 102e of the MAC insert 104, 104a, 104b, 104c, 104d, 104e may be porous such that it has the capacity to collect particles through adsorption and/or absorption and in lieu of or in addition, may be concave in the upstream direction or in the downstream direction to adjust its characteristics as a mechanical aerosol converter.


Although the above teachings are with reference to a particular layout of an electronic smoking article 60, the teachings are equally applicable to any electronic smoking article whatever the configuration.


When the word “about” is used in this specification in connection with a numerical value, it is intended that the associated numerical value include a tolerance of ±10% around the stated numerical value. Moreover, when reference is made to percentages in this specification, it is intended that those percentages are based on weight, i.e., weight percentages.


Moreover, when the words “generally” and “substantially” are used in connection with geometric shapes, it is intended that precision of the geometric shape is not required but that latitude for the shape is within the scope of the disclosure. When used with geometric terms, the words “generally” and “substantially” are intended to encompass not only features which meet the strict definitions but also features which fairly approximate the strict definitions.


It will now be apparent that a new, improved, and nonobvious electronic smoking article has been described in this specification with sufficient particularity as to be understood by one of ordinary skill in the art. Moreover, it will be apparent to those skilled in the art that numerous modifications, variations, substitutions, and equivalents exist for features of the electronic smoking article which do not materially depart from the spirit and scope of the invention. Accordingly, it is expressly intended that all such modifications, variations, substitutions, and equivalents which fall within the spirit and scope of the invention as defined by the appended claims shall be embraced by the appended claims.

Claims
  • 1. An electronic smoking article comprising: an outer tube extending in a longitudinal direction;an aerosol generator within the outer tube which produces a condensation aerosol within the outer tube; anda liquid supply within the outer tube delivering liquid material to the aerosol generator;an aerosol stream forming element within the outer tube operable to produce an aerosol stream wherein the aerosol stream forming element comprises a gasket arranged such that the aerosol is drawn through a central orifice of the gasket; anda mouth end insert comprising a mechanical aerosol converter (MAC) insert disposed downstream of said gasket, said MAC insert arranged to impart impaction upon said aerosol stream as said aerosol is being drawn from said electronic smoking article, the MAC insert including three elongated exit orifices extending circumferentially about a perimeter of an exposed end surface of the MAC insert, said MAC insert comprising a face disposed upstream of said exposed end surface, said face being spaced from said central orifice, said face and said central orifice being arranged such that at least some of said aerosol stream drawn through said central orifice strikes said face, whereby a characteristic of said aerosol is altered.
  • 2. The electronic smoking article of claim 1, wherein the three elongated exit orifices extending circumferentially about the perimeter of the exposed end surface are disposed radially outward of said face.
  • 3. The electronic smoking article of claim 2, wherein said face is disposed within a cylindrical body, said face is spaced from an upstream edge portion of said cylindrical body, said edge portion abutting said gasket, whereby spacing between said face and said central orifice is consistently established.
  • 4. The electronic smoking article of claim 1, wherein the characteristic of said aerosol is at least one of aerosol temperature and particle size distribution.
  • 5. The electronic smoking article of claim 1, further comprising: an inner tube within the outer tube, wherein the aerosol generator comprises a heater located in the inner tube; and a wick in communication with the liquid supply and surrounded by the heater such that the wick delivers liquid material to the heater and the heater heats the liquid material to a temperature sufficient to vaporize the liquid material and form an aerosol in the inner tube, wherein the liquid supply is contained in an outer annulus between the outer tube and the inner tube.
  • 6. The electronic smoking article of claim 1, wherein the face is porous and particles of a predetermined size are retained on the face.
  • 7. The electronic smoking article of claim 1, wherein the face is concave.
  • 8. The electronic smoking article of claim 5, wherein the electronic smoking article comprises a first section attachable to a second section and wherein the wick, the heater and the liquid supply are contained in the first section and a power supply is contained in the second section.
  • 9. The electronic smoking article of claim 5, wherein the outer tube is a single tube and the wick, the heater, the liquid supply and a power supply are contained in the outer tube.
  • 10. The electronic smoking article of claim 1, wherein the liquid supply has a nicotine content of greater than 2% by weight based on the weight of the liquid supply.
  • 11. The electronic smoking article of claim 1, wherein each of the three elongated exit orifices has a length ranging from about 2 mm to about 5 mm and a width ranging from about 0.5 mm to about 1 mm.
  • 12. The electronic smoking article of claim 1, wherein the MAC insert is formed of plastic or metal foil.
  • 13. The electronic smoking article of claim 1, wherein the MAC insert is in the form of a disk and the plurality of orifices are coplanar with the face of the MAC insert.
  • 14. An electronic smoking article comprising: an outer tube extending in a longitudinal direction; an aerosol generator within the outer tube which produces a condensation aerosol within the outer tube;a liquid supply within the outer tube delivering liquid material to the aerosol generator;an aerosol stream forming element within the outer tube operable to produce an aerosol stream through a central orifice; anda mechanical aerosol converter (MAC) insert comprising a monolithic cylindrical body portion having an outer diameter that is sized to provide a sliding fit with interior surfaces of the outer tube and a plurality of orifices disposed radially outward of a face, said face being aligned with and spaced from the central orifice of the aerosol stream forming element, wherein the face and inlets of the plurality of orifices are not coplanar, wherein the face of the MAC insert is arranged to impart impaction upon said aerosol stream and a characteristic of said aerosol is altered, as said aerosol is being drawn from said electronic smoking article.
  • 15. The electronic smoking article of claim 14, wherein the aerosol generator is operable to heat a liquid material to a temperature sufficient to vaporize the liquid material to form an aerosol and the face of the MAC insert is arranged such that the characteristic of the aerosol which is altered upon impaction thereof with the face of the MAC insert is the temperature of the aerosol, wherein the temperature of the aerosol is reduced.
  • 16. The electronic smoking article of claim 15, wherein the face of the MAC insert is arranged such that the temperature of the aerosol is reduced by 30° C. or more.
  • 17. The electronic smoking article of claim 14, wherein the aerosol stream forming element comprises a gasket.
  • 18. An electronic smoking article comprising: an outer tube extending in a longitudinal direction; an aerosol generator within the outer tube which produces a condensation aerosol within the outer tube;a liquid supply within the outer tube delivering liquid material to the aerosol generator;an aerosol stream forming element within the outer tube operable to produce an aerosol stream, wherein the aerosol stream forming element comprises a constricted central channel operable to increase the velocity of the aerosol as it is drawn therethrough; anda mechanical aerosol converter (MAC) insert comprising a monolithic cylindrical body portion having an outer diameter that is sized to provide a sliding fit with interior surfaces of the outer tube and a plurality of orifices disposed radially outward of a face, said face being aligned with and spaced from the constricted channel of the aerosol stream forming element, wherein the face and inlets of the plurality of orifices are not coplanar, wherein the face of the MAC insert is arranged to impart impaction upon said aerosol stream, and a characteristic of said aerosol is altered, as said aerosol is being drawn from said electronic smoking article.
  • 19. The electronic smoking article of claim 18, wherein the aerosol stream forming element comprises a gasket.
CROSS REFERENCE TO RELATED APPLICATION

This application claims priority under 35 U.S.C. §119(e) to U.S. Provisional Application No. 61/593,004, filed on Jan. 31, 2012, the entire content of which is incorporated herein by reference thereto.

US Referenced Citations (537)
Number Name Date Kind
393869 Warren Dec 1888 A
539839 Voron May 1895 A
567558 Wiseman Sep 1896 A
652987 Watson Jul 1900 A
962617 Bucceri Jun 1910 A
1013157 Hadaway, Jr. Jan 1912 A
1514682 Wilson Nov 1924 A
1771366 Wyss et al. Jul 1930 A
1775947 Robinson Sep 1930 A
1968509 Tiffany Jul 1934 A
2051030 Dalinda Aug 1936 A
2057353 Whittemore, Jr. Oct 1936 A
2104266 McCormick Jan 1938 A
2247869 Beers Jul 1940 A
2342853 Furstenberg Feb 1944 A
2406275 Wejnarth Aug 1946 A
2425624 Lardinois Aug 1947 A
2442004 Hayward-Butt May 1948 A
2445476 Folkman Jul 1948 A
2479002 Ceperly Aug 1949 A
2558127 Downs Jun 1951 A
2631219 Suchy Mar 1953 A
2701836 Pavenick Feb 1955 A
2702033 Pardeman Feb 1955 A
2721551 Lobl Oct 1955 A
2746890 Legler May 1956 A
2815028 Bernhard Dec 1957 A
2830597 Kummli Apr 1958 A
2836183 Fay et al. May 1958 A
2860638 Bartolomeo Nov 1958 A
2907686 Siegel Oct 1959 A
2971039 Western Feb 1961 A
2972557 Toulmin, Jr. Feb 1961 A
2974669 Ellis Mar 1961 A
3062218 Temkovits Nov 1962 A
3150668 Lassiter et al. Sep 1964 A
3200819 Gilbert Aug 1965 A
3234357 Seuthe Feb 1966 A
3255760 Selker Jun 1966 A
3258015 Ellis et al. Jun 1966 A
3280819 Weeks Oct 1966 A
3320953 Rindner May 1967 A
3324861 Gaisman Jun 1967 A
3347231 Ellis et al. Dec 1967 A
3356094 Ellis et al. Dec 1967 A
3363633 Weber Jan 1968 A
3402723 Hu Sep 1968 A
3404692 Lampert Oct 1968 A
3410273 Bolles Nov 1968 A
3425414 Roche Feb 1969 A
3482580 Hollabaugh Dec 1969 A
3516417 Moses Jun 1970 A
3521643 Toth Jul 1970 A
3559300 Fox Feb 1971 A
3587573 Flack Jun 1971 A
3608560 Briskin et al. Sep 1971 A
3631856 Taylor Jan 1972 A
3648929 Corbaz Mar 1972 A
3681018 Knauff Aug 1972 A
3683936 O'Neil, Jr. Aug 1972 A
3721240 Tamburri Mar 1973 A
3738374 Bennett Jun 1973 A
3744496 McCarty et al. Jul 1973 A
D229725 Berger Dec 1973 S
D229788 Berger Jan 1974 S
D229789 Berger Jan 1974 S
D229790 Berger Jan 1974 S
3789840 Rosenblatt Feb 1974 A
3804100 Fariello Apr 1974 A
3875476 Crandall et al. Apr 1975 A
3878041 Leitnaker et al. Apr 1975 A
3886954 Hannema et al. Jun 1975 A
3889690 Guarnieri Jun 1975 A
3895219 Richerson et al. Jul 1975 A
3943941 Boyd et al. Mar 1976 A
D240541 Rupert Jul 1976 S
4016061 Wasa et al. Apr 1977 A
4068672 Guerra Jan 1978 A
4077784 Vayrynen Mar 1978 A
4083372 Boden Apr 1978 A
4098725 Yamamoto et al. Jul 1978 A
4110260 Yamamoto et al. Aug 1978 A
4131119 Blasutti Dec 1978 A
4141369 Burruss Feb 1979 A
4149548 Bradshaw Apr 1979 A
4164230 Pearlman Aug 1979 A
4171000 Uhle Oct 1979 A
4184496 Adair Jan 1980 A
4193411 Faris et al. Mar 1980 A
4209026 Dock Jun 1980 A
4215708 Bron Aug 1980 A
4219032 Tabatznik et al. Aug 1980 A
4246913 Ogden et al. Jan 1981 A
4256945 Carter et al. Mar 1981 A
4259970 Green, Jr. Apr 1981 A
4267976 Chatwin May 1981 A
4275747 Miller Jun 1981 A
4284089 Ray Aug 1981 A
4303083 Burruss, Jr. Dec 1981 A
4319587 Moser Mar 1982 A
4319591 Keith et al. Mar 1982 A
4327186 Murata et al. Apr 1982 A
4331166 Hale May 1982 A
4340072 Bolt et al. Jul 1982 A
4393884 Jacobs Jul 1983 A
D270097 Minkevitch Aug 1983 S
4407971 Komatsu et al. Oct 1983 A
4413641 Dwyer et al. Nov 1983 A
4416840 Lee et al. Nov 1983 A
4418354 Perduijn Nov 1983 A
4419302 Nishino et al. Dec 1983 A
4429703 Haber Feb 1984 A
4431903 Riccio Feb 1984 A
4436100 Green, Jr. Mar 1984 A
4449039 Fukazawa et al. May 1984 A
4457319 Lamb et al. Jul 1984 A
4463247 Lawrence et al. Jul 1984 A
4475029 Yoshida et al. Oct 1984 A
4493331 Porenski, Jr. Jan 1985 A
4503319 Moritoki et al. Mar 1985 A
4505282 Cogbill et al. Mar 1985 A
4515763 Boudart et al. May 1985 A
4517996 Vester May 1985 A
4528121 Matsushita et al. Jul 1985 A
4549905 Yamaguchi et al. Oct 1985 A
4555358 Matsushita et al. Nov 1985 A
4562337 Lawrence Dec 1985 A
4570646 Herron Feb 1986 A
4580583 Green, Jr. Apr 1986 A
4621649 Osterrath Nov 1986 A
4623401 Derbyshire et al. Nov 1986 A
4624828 Alexander Nov 1986 A
4634837 Ito et al. Jan 1987 A
4637407 Bonanno et al. Jan 1987 A
4649944 Houck, Jr. et al. Mar 1987 A
4659912 Derbyshire Apr 1987 A
4676237 Wood et al. Jun 1987 A
4687008 Houck, Jr. et al. Aug 1987 A
4708151 Shelar Nov 1987 A
4714082 Banerjee et al. Dec 1987 A
4735217 Gerth et al. Apr 1988 A
4765347 Sensabaugh et al. Aug 1988 A
4771796 Myer Sep 1988 A
4776353 Lilja et al. Oct 1988 A
4780299 Kumagai et al. Oct 1988 A
4784978 Ogasawara et al. Nov 1988 A
4793365 Sensabaugh, Jr. et al. Dec 1988 A
4799979 Baldi Jan 1989 A
4800183 Quinby Jan 1989 A
4800903 Ray et al. Jan 1989 A
4804002 Herron Feb 1989 A
4837421 Luthy Jun 1989 A
4846199 Rose Jul 1989 A
4848376 Lilja et al. Jul 1989 A
4851206 Boudart et al. Jul 1989 A
4874924 Yamamoto et al. Oct 1989 A
4877989 Drews et al. Oct 1989 A
4922901 Brooks et al. May 1990 A
4941486 Dube et al. Jul 1990 A
4945929 Egilmex Aug 1990 A
4945931 Gori Aug 1990 A
4947874 Brooks et al. Aug 1990 A
4947875 Brooks Aug 1990 A
4953572 Rose et al. Sep 1990 A
4966171 Serrano et al. Oct 1990 A
4981522 Nichols et al. Jan 1991 A
4991606 Serrano et al. Feb 1991 A
4993436 Bloom, Jr. Feb 1991 A
5016656 McMurtrie May 1991 A
5038458 Wagoner et al. Aug 1991 A
5040552 Schleich et al. Aug 1991 A
5042470 Kanesaka Aug 1991 A
5042510 Curtiss et al. Aug 1991 A
5045237 Washburn Sep 1991 A
5060671 Counts et al. Oct 1991 A
5076296 Nystrom et al. Dec 1991 A
5085804 Washburn Feb 1992 A
5093894 Deevi et al. Mar 1992 A
5095921 Losee et al. Mar 1992 A
5116298 Bondanelli et al. May 1992 A
5137578 Chan Aug 1992 A
5139594 Rabin Aug 1992 A
5144962 Counts et al. Sep 1992 A
5144964 Demain Sep 1992 A
5157242 Hetherington et al. Oct 1992 A
5159940 Hayward et al. Nov 1992 A
5179966 Losee et al. Jan 1993 A
5188130 Hajaligol et al. Feb 1993 A
5224498 Deevi et al. Jul 1993 A
5228460 Sprinkel et al. Jul 1993 A
5235157 Blackburn Aug 1993 A
5249586 Morgan et al. Oct 1993 A
5269327 Counts et al. Dec 1993 A
5274214 Blackburn Dec 1993 A
5285050 Blackburn Feb 1994 A
5304125 Leith Apr 1994 A
5322075 Deevi et al. Jun 1994 A
5353813 Deevi et al. Oct 1994 A
5369723 Counts et al. Nov 1994 A
5372148 McCafferty et al. Dec 1994 A
5388574 Ingebrethsen Feb 1995 A
5388594 Counts et al. Feb 1995 A
5396911 Casey, III et al. Mar 1995 A
5408574 Deevi et al. Apr 1995 A
5479948 Counts et al. Jan 1996 A
5497791 Bowen et al. Mar 1996 A
5498855 Deevi et al. Mar 1996 A
5499636 Baggett, Jr. et al. Mar 1996 A
5505214 Collins et al. Apr 1996 A
5514630 Willkens et al. May 1996 A
5530225 Hajaligol Jun 1996 A
5591368 Fleischhauer et al. Jan 1997 A
5592955 Keritsis Jan 1997 A
5595706 Sikka et al. Jan 1997 A
5611360 Tang Mar 1997 A
5613504 Collins et al. Mar 1997 A
5613505 Campbell et al. Mar 1997 A
5665262 Hajaligol et al. Sep 1997 A
5666976 Adams et al. Sep 1997 A
5666977 Higgins et al. Sep 1997 A
5666978 Counts et al. Sep 1997 A
5692525 Counts et al. Dec 1997 A
5708258 Counts et al. Jan 1998 A
5724997 Smith et al. Mar 1998 A
5726421 Fleischhauer et al. Mar 1998 A
5730158 Collins et al. Mar 1998 A
5738087 King Apr 1998 A
5743251 Howell et al. Apr 1998 A
5750964 Counts et al. May 1998 A
5758637 Ivri et al. Jun 1998 A
5865185 Collins et al. Feb 1999 A
5865186 Volsey, II Feb 1999 A
5878752 Adams et al. Mar 1999 A
5894841 Voges Apr 1999 A
5909845 Greatbatch et al. Jun 1999 A
5915387 Baggett, Jr. et al. Jun 1999 A
5934289 Watkins et al. Aug 1999 A
5935975 Rose et al. Aug 1999 A
5954979 Counts et al. Sep 1999 A
5962526 Yu et al. Oct 1999 A
5988176 Baggett, Jr. et al. Nov 1999 A
6026820 Baggett, Jr. et al. Feb 2000 A
6040560 Fleischhauer et al. Mar 2000 A
6053176 Adams et al. Apr 2000 A
6085740 Ivri et al. Jul 2000 A
6116247 Banyasz et al. Sep 2000 A
6125866 Nichols et al. Oct 2000 A
6155268 Takeuchi Dec 2000 A
6156796 Sano et al. Dec 2000 A
6196218 Voges Mar 2001 B1
6214133 Deevi et al. Apr 2001 B1
6223745 Hammarlund et al. May 2001 B1
6234167 Cox et al. May 2001 B1
6280682 Sikka et al. Aug 2001 B1
D453854 Verhoeven-Koster et al. Feb 2002 S
6357671 Cewers Mar 2002 B1
6418938 Fleischhauer et al. Jul 2002 B1
6425964 Deevi et al. Jul 2002 B1
6427682 Klimowicz et al. Aug 2002 B1
6443146 Voges Sep 2002 B1
6446426 Sweeney et al. Sep 2002 B1
6491233 Nichols Dec 2002 B2
6501052 Cox et al. Dec 2002 B2
6506338 Gedevanishvili et al. Jan 2003 B1
6509553 Golan et al. Jan 2003 B2
6532965 Abhulimen et al. Mar 2003 B1
6557552 Cox et al. May 2003 B1
6568390 Nichols et al. May 2003 B2
6598607 Adiga et al. Jul 2003 B2
D478983 Whitehall et al. Aug 2003 S
6607576 Sikka et al. Aug 2003 B1
6640050 Nichols et al. Oct 2003 B2
6681998 Sharpe et al. Jan 2004 B2
6682716 Hodges et al. Jan 2004 B2
6688313 Wrenn et al. Feb 2004 B2
6701921 Sprinkel, Jr. et al. Mar 2004 B2
6701922 Hindle et al. Mar 2004 B2
6715487 Nichols et al. Apr 2004 B2
6766220 McRae et al. Jul 2004 B2
6772756 Shayan Aug 2004 B2
6799572 Nichols et al. Oct 2004 B2
6803545 Blake et al. Oct 2004 B2
6803550 Sharpe et al. Oct 2004 B2
6804458 Sherwood et al. Oct 2004 B2
6806682 Hsiao Oct 2004 B2
6810883 Felter et al. Nov 2004 B2
6854470 Pu Feb 2005 B1
6883516 Hindle et al. Apr 2005 B2
D512777 Beisner et al. Dec 2005 S
7077130 Nichols et al. Jul 2006 B2
7117867 Cox et al. Oct 2006 B2
7131599 Katase Nov 2006 B2
7167641 Tam et al. Jan 2007 B2
7167776 Maharajh et al. Jan 2007 B2
7173222 Cox et al. Feb 2007 B2
7293565 Griffin et al. Nov 2007 B2
7381277 Gonterman et al. Jun 2008 B2
7400940 McRae et al. Jul 2008 B2
7404405 Mehio Jul 2008 B1
7405555 Rao et al. Jul 2008 B2
7458374 Hale et al. Dec 2008 B2
D590988 Hon Apr 2009 S
D590989 Hon Apr 2009 S
D590990 Hon Apr 2009 S
D590991 Hon Apr 2009 S
7527059 Iannuzzi May 2009 B2
7614402 Gomes Nov 2009 B2
D613902 Kaljura Apr 2010 S
D613903 Wu et al. Apr 2010 S
D613904 Wu et al. Apr 2010 S
D614346 Lik Apr 2010 S
7726320 Robinson et al. Jun 2010 B2
7789089 Dube et al. Sep 2010 B2
7810505 Yang Oct 2010 B2
7810508 Wyss-Peters et al. Oct 2010 B2
7832397 Lipowicz Nov 2010 B2
7832410 Hon Nov 2010 B2
7845359 Montaser Dec 2010 B2
7878962 Karles et al. Feb 2011 B2
7906936 Azancot Mar 2011 B2
7913688 Cross et al. Mar 2011 B2
7920777 Rabin et al. Apr 2011 B2
7938124 Izumiya et al. May 2011 B2
7952322 Partovi et al. May 2011 B2
D644375 Zhou Aug 2011 S
7997280 Rosenthal Aug 2011 B2
D646431 Awty et al. Oct 2011 S
8052127 Nichols et al. Nov 2011 B2
D651338 Awty et al. Dec 2011 S
8079371 Robinson et al. Dec 2011 B2
D652987 Kaljura Jan 2012 S
D653390 Kaljura Jan 2012 S
D653802 Kaljura Feb 2012 S
D655036 Zhou Feb 2012 S
8113215 Rasouli et al. Feb 2012 B2
8118161 Guerrera et al. Feb 2012 B2
D656094 Wu Mar 2012 S
8127772 Montaser Mar 2012 B2
8156944 Han Apr 2012 B2
8157918 Becker et al. Apr 2012 B2
8205622 Pan Jun 2012 B2
8251055 Srinivasan Aug 2012 B2
8258192 Wu et al. Sep 2012 B2
D671677 Wu Nov 2012 S
D671678 Wu Nov 2012 S
8314591 Terry et al. Nov 2012 B2
D677000 Liu Feb 2013 S
D677001 Liu Feb 2013 S
8365742 Han Feb 2013 B2
8371310 Brenneise Feb 2013 B2
8375957 Hon Feb 2013 B2
8393331 Hon et al. Mar 2013 B2
D681268 Wu Apr 2013 S
D681269 Wu Apr 2013 S
D683898 Liu Jun 2013 S
D683899 Liu Jun 2013 S
D684311 Liu Jun 2013 S
8459270 Coven et al. Jun 2013 B2
D688418 Liu Aug 2013 S
8499766 Newton Aug 2013 B1
8511318 Hon et al. Aug 2013 B2
D690461 Chen Sep 2013 S
8528569 Newton Sep 2013 B1
D691765 Tucker et al. Oct 2013 S
D691766 Tucker et al. Oct 2013 S
8550068 Terry et al. Oct 2013 B2
8550069 Alelov Oct 2013 B2
8558147 Greim et al. Oct 2013 B2
8578942 Schennum Nov 2013 B2
D695449 Tucker et al. Dec 2013 S
8662479 Nichols et al. Mar 2014 B2
8689804 Fernando et al. Apr 2014 B2
8689805 Hon et al. Apr 2014 B2
8794231 Thorens et al. Aug 2014 B2
20030205228 Nichols et al. Nov 2003 A1
20040020500 Wrenn et al. Feb 2004 A1
20040035409 Harwig et al. Feb 2004 A1
20040050396 Squeo Mar 2004 A1
20040079368 Gupta et al. Apr 2004 A1
20040081624 Nguyen et al. Apr 2004 A1
20040099266 Cross et al. May 2004 A1
20040105818 Every et al. Jun 2004 A1
20040129793 Nguyen et al. Jul 2004 A1
20040170405 Sherwood et al. Sep 2004 A1
20040200493 Matsufuji et al. Oct 2004 A1
20040223917 Hindle et al. Nov 2004 A1
20040223918 Pham et al. Nov 2004 A1
20040255941 Nichols et al. Dec 2004 A1
20050016550 Katase Jan 2005 A1
20050016553 Iannuzzi Jan 2005 A1
20050045179 Faison et al. Mar 2005 A1
20050079137 Blondino et al. Apr 2005 A1
20050081639 Gourlay Apr 2005 A1
20050126624 Pellizzari Jun 2005 A1
20050132879 Grollimund et al. Jun 2005 A1
20050133029 Nichols et al. Jun 2005 A1
20050143866 McRae et al. Jun 2005 A1
20050175331 Tam et al. Aug 2005 A1
20050205084 Gupta et al. Sep 2005 A1
20050268911 Cross et al. Dec 2005 A1
20050279371 Billard et al. Dec 2005 A1
20060016453 Kim Jan 2006 A1
20060047368 Maharajh et al. Mar 2006 A1
20060191546 Tokano et al. Aug 2006 A1
20060196518 Hon Sep 2006 A1
20060254604 Martinez Fernandez Nov 2006 A1
20070074734 Braunshteyn et al. Apr 2007 A1
20070095357 Besso et al. May 2007 A1
20070102013 Adams et al. May 2007 A1
20070175476 Lipowicz Aug 2007 A1
20070267031 Hon Nov 2007 A1
20070267032 Shan Nov 2007 A1
20070279002 Partovi Dec 2007 A1
20080047571 Braunshteyn et al. Feb 2008 A1
20080092912 Robinson et al. Apr 2008 A1
20080110458 Srinivasan et al. May 2008 A1
20080230052 Montaser Sep 2008 A1
20080276947 Martzel Nov 2008 A1
20090007925 Rasouli et al. Jan 2009 A1
20090044816 Rasouli et al. Feb 2009 A1
20090056729 Zawadzki et al. Mar 2009 A1
20090084391 Krupp Apr 2009 A1
20090095311 Han Apr 2009 A1
20090107503 Baran Apr 2009 A1
20090126745 Hon May 2009 A1
20090133704 Strickland et al. May 2009 A1
20090151717 Bowen et al. Jun 2009 A1
20090162294 Werner Jun 2009 A1
20090188490 Han Jul 2009 A1
20090230117 Fernando et al. Sep 2009 A1
20090272379 Thorens et al. Nov 2009 A1
20090283103 Nielsen et al. Nov 2009 A1
20090301502 Mehio Dec 2009 A1
20090320863 Fernando et al. Dec 2009 A1
20100031967 Inagaki Feb 2010 A1
20100031968 Sheikh et al. Feb 2010 A1
20100083959 Siller Apr 2010 A1
20100126505 Rinker May 2010 A1
20100163063 Fernando et al. Jul 2010 A1
20100200008 Taieb Aug 2010 A1
20100206317 Albino et al. Aug 2010 A1
20100242975 Hearn Sep 2010 A1
20100242976 Katayama et al. Sep 2010 A1
20100307518 Wang Dec 2010 A1
20110005535 Xiu Jan 2011 A1
20110011396 Fang Jan 2011 A1
20110036346 Cohen et al. Feb 2011 A1
20110036363 Urtsev et al. Feb 2011 A1
20110088707 Hajaligol Apr 2011 A1
20110094523 Thorens et al. Apr 2011 A1
20110108025 Fink et al. May 2011 A1
20110120455 Murphy May 2011 A1
20110120482 Brenneise May 2011 A1
20110126848 Zuber et al. Jun 2011 A1
20110147486 Greim et al. Jun 2011 A1
20110150936 Villalba Gonzales et al. Jun 2011 A1
20110155153 Thorens et al. Jun 2011 A1
20110155718 Greim et al. Jun 2011 A1
20110209717 Han Sep 2011 A1
20110220134 Duke et al. Sep 2011 A1
20110226236 Buchberger Sep 2011 A1
20110232654 Mass Sep 2011 A1
20110245493 Rabinowitz et al. Oct 2011 A1
20110253798 Tucker et al. Oct 2011 A1
20110265806 Alarcon et al. Nov 2011 A1
20110277756 Terry et al. Nov 2011 A1
20110277757 Terry et al. Nov 2011 A1
20110277760 Terry et al. Nov 2011 A1
20110277761 Terry et al. Nov 2011 A1
20110277764 Terry et al. Nov 2011 A1
20110277780 Terry et al. Nov 2011 A1
20110290244 Schennum Dec 2011 A1
20110303231 Li et al. Dec 2011 A1
20110304282 Li et al. Dec 2011 A1
20120006342 Rose et al. Jan 2012 A1
20120006343 Renaud et al. Jan 2012 A1
20120048266 Alelov Mar 2012 A1
20120062041 Nelson et al. Mar 2012 A1
20120090629 Turner et al. Apr 2012 A1
20120090630 Hon Apr 2012 A1
20120111347 Hon May 2012 A1
20120118301 Montaser May 2012 A1
20120145169 Wu Jun 2012 A1
20120167906 Gysland Jul 2012 A1
20120174914 Pirshafiey et al. Jul 2012 A1
20120186593 Grano et al. Jul 2012 A1
20120186594 Liu Jul 2012 A1
20120199146 Marangos Aug 2012 A1
20120199663 Qiu Aug 2012 A1
20120211015 Li et al. Aug 2012 A1
20120227753 Newton Sep 2012 A1
20120230659 Goodman et al. Sep 2012 A1
20120260927 Liu Oct 2012 A1
20120285475 Liu Nov 2012 A1
20120312313 Frija Dec 2012 A1
20120318283 Watanabe et al. Dec 2012 A1
20120318882 Abehasera Dec 2012 A1
20130014772 Liu Jan 2013 A1
20130019887 Liu Jan 2013 A1
20130025609 Liu Jan 2013 A1
20130032159 Capuano Feb 2013 A1
20130037041 Worm et al. Feb 2013 A1
20130042865 Monsees et al. Feb 2013 A1
20130056013 Terry et al. Mar 2013 A1
20130081642 Safari Apr 2013 A1
20130118509 Richardson May 2013 A1
20130183852 Rostami Jul 2013 A1
20130192615 Tucker et al. Aug 2013 A1
20130192616 Tucker et al. Aug 2013 A1
20130192619 Tucker et al. Aug 2013 A1
20130192620 Tucker et al. Aug 2013 A1
20130192621 Li et al. Aug 2013 A1
20130192622 Tucker et al. Aug 2013 A1
20130192623 Tucker et al. Aug 2013 A1
20130206154 Fernando et al. Aug 2013 A1
20130213418 Tucker et al. Aug 2013 A1
20130213419 Tucker et al. Aug 2013 A1
20130220315 Conley et al. Aug 2013 A1
20130228191 Newton Sep 2013 A1
20130284192 Peleg et al. Oct 2013 A1
20130298905 Levin et al. Nov 2013 A1
20130300350 Xiang Nov 2013 A1
20130306064 Thorens et al. Nov 2013 A1
20130306065 Thorens et al. Nov 2013 A1
20130319407 Liu Dec 2013 A1
20130319435 Flick Dec 2013 A1
20130319439 Gorelick et al. Dec 2013 A1
20130319440 Capuano Dec 2013 A1
20130340750 Thorens et al. Dec 2013 A1
20130340775 Juster et al. Dec 2013 A1
20140014126 Peleg et al. Jan 2014 A1
20140034071 Levitz et al. Feb 2014 A1
20140064715 Greim et al. Mar 2014 A1
20140202472 Levitz et al. Jul 2014 A1
20140261489 Cadieux et al. Sep 2014 A1
20140261492 Kane et al. Sep 2014 A1
20140318559 Thorens et al. Oct 2014 A1
Foreign Referenced Citations (112)
Number Date Country
421623 Jun 1937 BE
1202378 Mar 1986 CA
421786 Sep 1966 CH
87104459 Feb 1988 CN
1040914 Apr 1990 CN
2719043 Aug 2005 CN
2777995 May 2006 CN
2887086 Apr 2007 CN
200983833 Dec 2007 CN
101116542 Feb 2008 CN
201018927 Feb 2008 CN
201029436 Mar 2008 CN
201051762 Apr 2008 CN
201054977 May 2008 CN
201067079 Jun 2008 CN
201076006 Jun 2008 CN
201085044 Jul 2008 CN
101322579 Dec 2008 CN
101371721 Feb 2009 CN
101518361 Sep 2009 CN
201379072 Jan 2010 CN
201571500 Sep 2010 CN
201709398 Jan 2011 CN
201789924 Apr 2011 CN
201797997 Apr 2011 CN
102106611 Jun 2011 CN
201860753 Jun 2011 CN
102166044 Aug 2011 CN
201986689 Sep 2011 CN
202014571 Oct 2011 CN
202014572 Oct 2011 CN
202026802 Nov 2011 CN
202026804 Nov 2011 CN
202233005 May 2012 CN
202233007 May 2012 CN
1632249 Dec 1970 DE
2547941 Apr 1977 DE
3006553 Apr 1977 DE
3640917 Aug 1988 DE
3735704 May 1989 DE
19854009 May 2000 DE
69824982 Oct 2004 DE
0057243 Aug 1982 EP
0086180 Aug 1983 EP
0117355 Sep 1984 EP
0236992 Sep 1987 EP
0277519 Aug 1988 EP
0295122 Dec 1988 EP
0358 002 Mar 1990 EP
0358114 Mar 1990 EP
0430566 May 1990 EP
0438862 Jul 1991 EP
0488488 Jun 1992 EP
0503767 Sep 1992 EP
0608783 Mar 1994 EP
0845220 Jun 1998 EP
0857431 Aug 1998 EP
0893071 Jan 1999 EP
1298808 Apr 2003 EP
1618803 Jan 2006 EP
1736065 Dec 2006 EP
2113178 Apr 2008 EP
1989946 Nov 2008 EP
2022350 Feb 2009 EP
2110033 Oct 2009 EP
2481308 Aug 2012 EP
1397351 Jun 1975 GB
1528391 Oct 1978 GB
2089188 Jun 1982 GB
2115676 Sep 1983 GB
2132539 Jul 1984 GB
2148079 May 1985 GB
2148676 May 1985 GB
61068061 Apr 1986 JP
2006320286 Nov 2006 JP
2010-213579 Sep 2010 JP
100636287 Oct 2006 KR
8201585 Nov 1982 NL
WO8602528 May 1986 WO
WO9003224 Apr 1990 WO
WO9502970 Feb 1995 WO
WO9843019 Oct 1998 WO
WO0028843 Mar 2000 WO
WO0028843 May 2000 WO
WO03037412 May 2003 WO
W 03095688 Nov 2003 WO
WO2004043175 May 2004 WO
WO2004080216 Sep 2004 WO
WO2004095955 Nov 2004 WO
WO2005099494 Oct 2005 WO
WO2005120614 Dec 2005 WO
WO2007024130 Mar 2007 WO
WO2007066374 Jun 2007 WO
WO2007078273 Jul 2007 WO
WO2007098337 Aug 2007 WO
WO2007131449 Nov 2007 WO
WO2007131450 Nov 2007 WO
WO2007141668 Dec 2007 WO
WO2008055423 May 2008 WO
WO2010091593 Aug 2010 WO
WO2010145468 Dec 2010 WO
WO2011121326 Oct 2011 WO
WO2011124033 Oct 2011 WO
WO2011125058 Oct 2011 WO
WO2011146372 Nov 2011 WO
WO2012088675 Jul 2012 WO
WO2012109371 Aug 2012 WO
WO2012129787 Oct 2012 WO
WO2012129812 Oct 2012 WO
WO2012142293 Oct 2012 WO
WO2013093695 Jun 2013 WO
WO2013116558 Aug 2013 WO
Non-Patent Literature Citations (49)
Entry
International Search Report and Written Opinion for PCT/US13/24228 dated Apr. 9, 2013.
International Search Report and Written Opinion for PCT/US13/24211 dated Apr. 19, 2013.
International Search Report and Written Opinion for PCT/US13/24219 dated Apr. 22, 2013.
International Search Report and Written Opinion for PCT/US13/24229 dated Apr. 22, 2013.
International Search Report and Written Opinion for PCT/US13/24215 dated Apr. 22, 2013.
International Search Report and Written Opinion for PCT/US13/24222 dated Apr. 24, 2013.
International Search Report and Written Opinion for PCT/US13/27424 dated Apr. 25, 2013.
International Search Report and Written Opinion for PCT/US13/27432 dated May 2, 2013.
International Search Report and Written Opinion for PCT/US13/24224 dated May 13, 2013.
U.S. Appl. No. 13/843,028, filed Mar. 15, 2013, to Fath et al.
U.S. Appl. No. 13/843,314, filed Mar. 15, 2013, to Fath et al.
U.S. Appl. No. 13/843,449, filed Mar. 15, 2013, to Fath et al.
Excerpt from “NASA Tech Briefs”, Jul./Aug. 1988, p. 31.
RjG, Comment to Exactly What Material Is the Wick?, E-Cigarette Forum (Jan. 2, 2010, 9:27 PM), http://www.e-cigarette-forum.com/forum/atomizer-mods/58918-exactly-what-material-wick.html.
International Search Report and Written Opinion for PCT/US2012/033329 dated Oct. 4, 2012.
International Preliminary Report on Patentability for PCT/US2012/033329 dated Oct. 15, 2013.
International Preliminary Report on Patentability for PCT/US2013/024215 dated Aug. 14, 2014.
International Preliminary Report on Patentability for PCT/US2013/024219 dated Aug. 14, 2014.
International Preliminary Report on Patentability for PCT/US2013/024229 dated Aug. 14, 2014.
European Search Report for EP 08251579.2 dated Nov. 7, 2008.
European Search Report for EP 09252490 dated Mar. 11, 2010.
International Search Report and Written Opinion for PCT/EP2010/006534 dated Apr. 5, 2011.
International Preliminary Report on Patentability for PCT/EP2010/006534 dated May 10, 2012.
U.S. Appl. No. 14/332,785, filed Jul. 16, 2014, to Janardhan et al.
U.S. Appl. No. 14/337,872, filed Jul. 22, 2014, to Janardhan et al.
U.S. Appl. No. 14/337,353, filed Jul. 22, 2014, to Janardhan et al.
U.S. Appl. No. 29/456,109, filed May 29, 2013, to Weigensberg.
U.S. Appl. No. 29/469,749, filed Oct. 14, 2013, to Tucker et al.
U.S. Appl. No. 29/473,662, filed Nov. 25, 2013, to Tucker et al.
U.S. Appl. No. 29/469,741, filed Oct. 14, 2013, to Tucker et al.
U.S. Appl. No. 29/469,750, filed Oct. 14, 2013, to Tucker et al.
U.S. Appl. No. 29/471,338, filed Oct. 30, 2013, to Bramley et al.
U.S. Appl. No. 29/471,454, filed Oct. 31, 2013, to Bramley et al.
U.S. Appl. No. 29/503,697, filed Sep. 29, 2014, to Bramley et al.
“Joining of Ceramics” by R.E. Loehman et al., published in Ceramic Bulletin, 67(d); 375-380 (1988).
Oxidation Behavior of Silver—and Copper-Based Brazing Filler Metals for Silicon Nitride/Metal Joints by R.R. Kapoor et al., published in J. Am. Ceram. Soc., 72(3):448-454 (1989).
“Brazing Ceramic Oxides to Metals at Low Temperatures” by J.P. Hammond et al., published in Welding Research Supplement, 227-232-s, (1988).
“Brazing of Titanium-Vapor-Coated Silicon Nitride” by M. L. Santella, published in Advanced Ceramic Materials, 3(5):457-465 (1988).
“High Temperature Structural Silicides” by A.K. Vasudevan et al., Elsevier Science Publishers B.V. (1992).
John A. Dean, Lange's handbook of Chemistry, 12th Edition, 1978 pp. 4-16, 4-123.
Fen et al., “Cyclic oxidation of Haynes 230 alloy”, Chapman & Hall, pp. 1514-1520 (1992).
Reinshagen and Sikka, “Thermal Spraying of Selected Aluminides”, Proceedings of the Fourth National Thermal Spray Conference, Pittsburgh, PA USA, pp. 307-313 (May 4-10, 1991).
Kutner, “Thermal spray by design”, Reprint from Advanced Materials & Processes Incorporating Metal Progress, Oct. 1988.
“Characterizing Thermal Spray Coatings”, Article based on presentation made at the Fourth National Thermal Spray Conference, May 4-10, 1991 and appearing in Advanced Materials and Processes, May 1992, pp. 23-27.
Howes, Jr., “Computerized Plasma Control for Applying Medical-Quality Coatings”, Industrial Healing, pp. 22-25, Aug. 1993.
V. Sikka, “Processing of Aluminides”, Intermetallic Metallurgy and Processing Intermetallic Compounds, ed Stoloff et al., Van Mestrand Reinhold, N.Y., 1994.
K.H. Jack, “The Iron-Nitrogen System: The Crystal Structures of ∈-Phase Iron Nitrides”, Aceta Crystallographica, 5. pp. 404-411 (1952).
K.H. Jack, “Binary and ternary interstitial alloys 1. The iron-nitrogen system: the structures of Fe4N and Fe2N”, Proceedings of the Royal Society, A. 195, pp. 34-40 (1948).
K.H. Jack, “The iron-nitrogen system: the preparation and the crystal structures of nitrogen-austenite (Y) and nitrogen-martensite (a)”, Proceedings of the Royal Society, A. 208, pp. 200-215 (1952).
Related Publications (1)
Number Date Country
20130192621 A1 Aug 2013 US
Provisional Applications (1)
Number Date Country
61593004 Jan 2012 US