Electrophotographic photoreceptor, and image forming method, image forming apparatus and process cartridge for image forming apparatus using the electrophotographic photoreceptor

BACKGROUND OF THE INVENTION

[0001] 1. Field of the Invention

[0002] The present invention relates to an electrophotographic photoreceptor, and an image forming method, an image forming apparatus and process cartridge for image forming apparatus using the electrophotographic photoreceptor.

[0003] 2. Discussion of the Background

[0004] Recently, information-processing systems using an electrophotographic method are making a remarkable progress. In particular, laser printers and digital copiers which record data with light by changing the data into digital signals make remarkable improvements in their printing qualities and reliabilities. Further, technologies used in these printers and copiers are applied to laser printers and digital copiers capable of printing full-color images with high-speed printing technologies. Because of these reasons, photoreceptors are required both to produce high-quality images and to have high durability.

[0005] Photoreceptors using organic photosensitive materials are widely used for these laser printers and digital copiers due to their cost, productivity and non-polluting properties. The organic photoreceptors are generally classified to a single-layered type and a functionally-separated type. The first practical organic photoreceptor, i.e., PVK-TNF charge transfer complex photoreceptor was the former single-layered type. In 1968, Mr. Hayashi and Mr. Regensburger independently invented PVK/a-Se multi-layered photoreceptor. In 1977, Mr. Melz, and in 1978, Mr. Schlosser disclosed a multi-layered photoreceptor whose photosensitive layers are all formed from organic materials, i.e. , an organic-pigment dispersed layer and an organic low-molecular-weight material dispersed polymer layer. These are called as functionally-separated photoreceptors because of having a charge generation layer (CGL) generating a charge by absorbing light and a charge transport layer (CTL) transporting the charge and neutralizing the charge on a surface of the photoreceptor. The multi-layered photoreceptor has much more improved sensitivity and durability than the single-layered photoreceptor. In addition, since materials can be separately selected for a charge generation material (CGM) and a charge transport material (CTM), a choice range of the materials is largely expanded. Because of these reasons, the multi-layered photoreceptor is now prevailing in the market.

[0006] A mechanism to form an electrostatic latent image in the multi-layered photoreceptor is as follows:

[0007] the photoreceptor is charged and irradiated with light; the light passes through the CTL and is absorbed by the CGM in the CGL to generate a charge; the charge is injected into the CTL at an interface of the CGL and the CTL; and the charge moves in the CTL by an electric field and neutralizes the charge on the surface of the photoreceptor to form an electrostatic latent image.

[0008] However, the photosensitive layers of the organic photoreceptor are easily abraded due to repeated use, and therefore potential and photosensitivity of the photoreceptor tend to deteriorate, resulting in background fouling due to a scratch on the surface thereof and deterioration of density and quality of the resultant images. Therefore, abrasion resistance of the organic photoreceptor has been an important subject. Further, recently, in accordance with speeding up of the printing speed and downsizing of an image forming apparatus, the photoreceptor has to have a smaller diameter, and durability thereof becomes a more important subject.

[0009] As a method of improving the abrasion resistance of the photoreceptor, methods of imparting lubricity to the photosensitive layer, hardening the photosensitive layer, including a filler therein and using a high-molecular-weight CTM instead of a low-molecular-weight CTM are widely known. However, another problem occurs when these methods are used to prevent the abrasion of the photoreceptor. Namely, an oxidized gas such as ozone and NOx arising due to use conditions or environment, adheres to the surface of the photosensitive layer and decreases the surface resistance thereof, resulting in a problem such as blurring of the resultant images. So far, such a problem has been avoided to some extent because the material causing the blurred images are gradually scraped off in accordance with the abrasion of the photosensitive layer. However, in order to comply with the above-mentioned recent demand for higher sensitivity and durability of the photoreceptor, a new technique has to be imparted thereto. In order to decrease an influence of the material causing the blurred images, there is a method of equipping the photoreceptor with a heater, which is a large drawback for downsizing the apparatus and decreasing the electric power consumption. In addition, a method of including an additive such as an antioxidant in the photosensitive layer is effective, but since a simple additive does not have photoconductivity, including much amount thereof in the photosensitive layer causes problems such as deterioration of the sensitivity and increase of residual potential of the resultant photoreceptor.

[0010] As mentioned above, the electrophotographic photoreceptor having less abrasion by being imparted with abrasion resistance or a process design around thereof inevitably produces blurred and low-resolution images, and it is difficult to have both of high durability and high quality of the resultant images. This is because high surface resistance of the photosensitive layer is preferable to prevent the blurred images and low surface resistance thereof is preferable to prevent the increase of residual potential.

[0011] Japanese Laid-Open Patent Publication No. 2000-231204 or 2002-313111 discloses a method of including at least a compound having a dialkylamino group in a photosensitive layer to solve the above-mentioned problem such as blurring of the resultant images due to a blur generating material such as an oxidizing gas. The reason why the compound is effective for maintaining quality of the resultant images after repeated use is not clarified at this time. However, it is supposed that the dialkylamino group having a strong basic neutralizes the oxidizing gas which is considered to cause the blurred images. However, the compound has an effect on image quality after the repeated use, but the resultant photoreceptor does not have high sensitivity and cannot comply with high speed printing because of having a low charge transportability. Therefore, an addition amount thereof has a limit, and a method of combining the compound with a CTM to increase sensitivity and repeated use stability of the resultant photoreceptor is disclosed therein.

[0012] On the other hand, it is described that a stilbene compound having a dialkylamino group disclosed in Japanese Laid-Open Patent Publication No. 60-196768 and Japanese Patent No. 2884353 has an effect on the blurred images due to the oxidizing gas on page 37 of Konica Technical Report Vol. 13 written by Itami, etc. and published in 2000. However, since the compound has a substituted dialkylamino group having a strong mesomeric effect (+M effect) at a resonance portion in its triarylamine structure, which is a charge transport site, total ionization potential is extremely small. Therefore, the compound has a critical defect of being quite difficult to practically use because charge retainability of a photosensitive layer in which the compound is used alone as a CTM largely deteriorates from the beginning or after repeated use. In addition, even when the above-mentioned stilbene compound is used together with other CTMs as it is in the present invention, the compound has a considerably smaller ionization potential than the other CTMs and becomes a trap site against a charge transport, and therefore, the resultant photoreceptor has quite a low sensitivity and a large residual potential.

[0013] Because of these reasons, a need exists for an electrophotographic photoreceptor having high durability against repeated use for a long time, preventing deterioration of image density and blurred images and stably producing quality images.

SUMMARY OF THE INVENTION

[0014] Accordingly, an object of the present invention is to provide an electrophotographic photoreceptor having high durability against repeated use for a long time, preventing deterioration of image density and blurred images and stably producing high-quality images.

[0015] Another object of the present invention is to provide an image forming method, an image forming apparatus and a process cartridge using the photoreceptor, in which the photoreceptor need not be exchanged, which enables downsizing the apparatus in accordance with the high-speed printing or smaller diameter of the photoreceptor, and which stably produce high-quality images even after repeated use for a long time.

[0016] Briefly these objects and other objects of the present invention as hereinafter will become more readily apparent can be attained by an electrophotographic photoreceptor including an electroconductive substrate and a photosensitive layer on the electroconductive substrate, wherein the photosensitive layer includes at least a compound having a substituted or unsubstituted alkylamino group and a charge transport material, and wherein an oxidation potential (Eox1) of the substituted or unsubstituted alkylamino group and an oxidation potential (Eox2) of the charge transport material satisfy the following relationship (I):

Eox1−Eox2≧−0.2 (I)

[0017] The charge transport material is preferably a stilbene compound having the following formula (1):

[0018] wherein n is 0 or 1; R1 represents a hydrogen atom, an alkyl group or a substituted or unsubstituted phenyl group; Ar1 represents a substituted or unsubstituted aryl group; R5 represents an alkyl group having 1 to 4 carbon atoms or a substituted or unsubstituted aryl group; and A represents a 9-anthryl group, a substituted or unsubstituted carbazolyl group or a group having the following formula (4) or (5):

[0019] wherein R2 represents a hydrogen atom, an alkyl group, an alkoxy group, a halogen atom or a group having the following formula (6); and m is an integer of from 1 to 3;

[0020] wherein R3 and R4 independently represent a substituted or unsubstituted aromatic ring group, and may form a ring, and wherein R2 may be the same or different from each other when m is not less than 2, and A and R1 may form a ring together when n is 0.

[0021] Further, the charge transport material is preferably a hydrazone compound having the following formula (2):

[0022] wherein the R11 represents an alkyl group, a benzyl group, a phenyl group or a naphtyl group; R22 represents a hydrogen atom, an alkyl group having 1 to 3 carbon atoms, an alkoxy group having 1 to 3 carbon atoms, a dialkylamino group, a diaralkylamino group or a substituted or unsubstituted diarylamino group; n represents integers of from 1 to 4 and R22 is optionally the same or different from each other when n is not less than 2; and R33 represents a hydrogen atom or a methoxy group.

[0023] Furthermore, the charge transport polymer material is preferably a charge transport polymer material having the following formula (3):

[0024] wherein R7 and R8 independently represent a substituted or unsubstituted aromatic ring group; Ar1, Ar2 and Ar3 independently represent an aromatic ring group; k is a number of from 0.1 to 1.0 and j is a number of from 0 to 0.9; n represents a repeating number and is an integer of from 5 to 5,000; and X represents a divalent aliphatic group, a divalent alicyclic group or a divalent group having the following formula (7):

[0025] wherein, R101 and R102 independently represent a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, or a halogen atom; t and m independently represent 0 or an integer of from 1 to 4; d is 0 or 1; and Y represents a linear alkylene group, a branched alkylene group, a cyclic alkylene group, —O—, —S—, —SO—, —SO2—, —CO—, —CO—O—Z—O—CO— (Z represents a divalent aliphatic group), or a group having the following formula (8):

[0026] wherein, a is an integer of from 1 to 20; b is an integer of from 1 to 2,000; and R103 and R104 independently represent a substituted or unsubstituted alkyl group, or a substituted or unsubstituted aryl group, and wherein R101, R102, R103 and R104 may be the same or different from the others.

[0027] These and other objects, features and advantages of the present invention will become apparent upon consideration of the following description of the preferred embodiments of the present invention taken in conjunction with the accompanying drawings.

BRIEF DESCRIPTION OF THE DRAWINGS

[0028] Various other objects, features and attendant advantages of the present invention will be more fully appreciated as the same becomes better understood from the detailed description when considered in connection with the accompanying drawings in which like reference characters designate like corresponding parts throughout and wherein:

[0029]
FIG. 1 is a cross-sectional view of an embodiment of the photosensitive layer of the electrophotographic photoreceptor of the present invention;

[0030]
FIG. 2 is a cross-sectional view of another embodiment of the photosensitive layer of the electrophotographic photoreceptor of the present invention;

[0031]
FIG. 3 is a cross-sectional view of a third embodiment of the photosensitive layer of the electrophotographic photoreceptor of the present invention;

[0032]
FIG. 4 is a cross-sectional view of a fourth embodiment of the photosensitive layer of the electrophotographic photoreceptor of the present invention;

[0033]
FIG. 5 is a cross-sectional view of a fifth embodiment of the photosensitive layer of the electrophotographic photoreceptor of the present invention;

[0034]
FIG. 6 is a schematic view illustrating a partial cross-section of an embodiment of the electrophotographic image forming apparatus of the present invention;

[0035]
FIG. 7 is a schematic view for explaining an embodiment of the electrophotographic image forming process of the present invention;

[0036]
FIG. 8 is a schematic view illustrating a cross-section of an embodiment of the process cartridge of the present invention;

[0037]
FIG. 9 is a chart showing a relationship between a difference (ΔE) between the oxidation potential of the compound having an alkylamino group and that of a CTM, and a bright section potential (VL) in the electrophotographic photoreceptor of the present invention;

[0038]
FIG. 10 is a chart showing a relationship between a difference (ΔE) between the oxidation potential of the compound having an alkylamino group and that of another CTM, and a bright section potential (VL) in the electrophotographic photoreceptor of the present invention;

[0039]
FIG. 11 is a chart showing a XD spectrum of an oxotitaniumphthalocyanine powder of the present invention;

[0040]
FIG. 12 is a chart showing a relationship between a difference (ΔE) between the oxidation potential of the compound having an alkylamino group and that of a third CTM, and a bright section potential (VL) in the electrophotographic photoreceptor of the present invention;

[0041]
FIG. 13 is a chart showing a XD spectrum of another oxotitaniumphthalocyanine powder of the present invention; and

[0042]
FIG. 14 is a chart showing a relationship between a difference (ΔE) between the oxidation potential of the compound having an alkylamino group and that of a fourth CTM, and a bright section potential (VL) in the electrophotographic photoreceptor of the present invention.

DETAILED DESCRIPTION OF THE INVENTION

[0043] Generally, the present invention provides an electrophotographic photoreceptor having high durability against repeated use for a long time, preventing deterioration of image density and blurred images and stably producing quality images.

[0044] The electrophotographic photoreceptor of the present invention includes an electroconductive substrate and a photosensitive layer on the electroconductive substrate, wherein the photosensitive layer includes at least a compound having a substituted or unsubstituted alkylamino group and a charge transport material, and wherein an oxidation potential (Eox1) of the substituted or unsubstituted alkylamino group and an oxidation potential (Eox2) of the charge transport material satisfy the following relationship (I):

Eox1−Eox2≧−0.2 (I)

[0045] The electrophotographic photoreceptor including a compound having an alkylamino group which is mixed with a CTM of the present invention has a high sensitivity and a high durability, and stably produces high-quality images even after repeated use when the compound having an alkylamino group has an ionization potential not less than that of CTM by a certain level. Namely, as mentioned above, as the alkylamino group is a substituent having a strong mesomeric effect (+M effect), a total ionization potential of the compound becomes extremely small when the substituent is substituted at a resonance portion thereof. When the compound having an alkylamino group has considerably a smaller ionization potential than that of the CTM, it becomes a hole trap site against the charge transport, and therefore the resultant electrophotographic photoreceptor has quite a low sensitivity and a large residual potential. When the compound having an alkylamino group has an ionization potential not less than that of CTM by a certain level, the resultant electrophotographic photoreceptor has a high sensitivity and a high durability, and stably produces high-quality images even after repeated use.

[0046] Specific examples of the compound having an alkylamino group include compounds having the following formulae (9) to (35):

[0047] wherein R1 and R2 independently represent an alkyl group having 1 to 4 carbon atoms, which is substituted with an aromatic ring group or an unsubstituted alkyl group having 1 to 4 carbon atoms and may be combined with each other to form a heterocyclic group including a nitrogen atom; n represents an integer of from 1 to 4; and Ar represents a substituted or unsubstituted aromatic ring group;

[0048] wherein R1 and R2 independently represent an alkyl group having 1 to 4 carbon atoms, which is substituted with an aromatic ring group or an unsubstituted alkyl group having 1 to 4 carbon atoms and may be combined with each other to form a heterocyclic group including a nitrogen atom; 1, m and n independently represent 0 or an integer of from 1 to 3, and are not 0 at the same time; Ar1, Ar2 and Ar3 independently represent a substituted or unsubstituted aromatic ring group; and Ar1 and Ar2, Ar2 and Ar3 or Ar3 and Ar1 may independently form a heterocyclic group including a nitrogen atom together;

[0049] wherein R1 and R2 independently represent an alkyl group having 1 to 4 carbon atoms, which is substituted with an aromatic ring group or an unsubstituted alkyl group having 1 to 4 carbon atoms and may be combined with each other to form a heterocyclic group including a nitrogen atom; k, l, m and n independently represent 0 or an integer of from 1 to 3, and are not 0 at the same time; Ar1, Ar2, Ar3 and Ar4 independently represent a substituted or unsubstituted aromatic ring group; and Ar1 and Ar2, Ar1 and Ar4 or Ar3 and Ar4 may independently form a ring together;

[0050] wherein R1 and R2 independently represent an alkyl group having 1 to 4 carbon atoms, which is substituted with an aromatic ring group or an unsubstituted alkyl group having 1 to 4 carbon atoms and may be combined with each other to form a heterocyclic group including a nitrogen atom; k, l, m and n independently represent 0 or an integer of from 1 to 3, and are not 0 at the same time; Ar1, Ar2, Ar3 and Ar4 independently represent a substituted or unsubstituted aromatic ring group; and Ar1 and Ar2, Ar1 and Ar3 or Ar3 and Ar4 may independently form a ring together;

[0051] wherein R1 and R2 independently represent an alkyl group having 1 to 4 carbon atoms, which is substituted with an aromatic ring group or an unsubstituted alkyl group having 1 to 4 carbon atoms and may be combined with each other to form a heterocyclic group including a nitrogen atom; k, l, m and n independently represent 0 or an integer of from 1 to 3, and are not 0 at the same time; Ar1, Ar2, Ar3 and Ar4 independently represent a substituted or unsubstituted aromatic ring group; Ar1 and Ar2, Ar1 and Ar3 or Ar1 and Ar4 may independently form a ring together; and X represents a methylene group, a cyclohexylidine group, an oxy atom or a sulfur atom;

[0052] wherein R1 and R2 independently represent an alkyl group having 1 to 4 carbon atoms, which is substituted with an aromatic ring group or an unsubstituted alkyl group having 1 to 4 carbon atoms and may be combined with each other to form a heterocyclic group including a nitrogen atom; 1 and m independently represent 0 or an integer of from 1 to 3, and are not 0 at the same time; Ar1, Ar2 and Ar3 independently represent a substituted or unsubstituted aromatic ring group; Ar1 and Ar2 or Ar1 and Ar3 may independently form a ring together; and n represents an integer of from 1 to 4;

[0053] wherein R1 and R2 independently represent an alkyl group having 1 to 4 carbon atoms, which is substituted with an aromatic ring group or an unsubstituted alkyl group having 1 to 4 carbon atoms and may be combined with each other to form a heterocyclic group including a nitrogen atom; m and n independently represent 0 or an integer of from 1 to 3, and are not 0 at the same time; R3 and R4 independently represent a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 11 carbon atoms and a substituted or unsubstituted aromatic ring group; and Ar1 and Ar2 independently represent a substituted or unsubstituted aromatic ring group, and one of Ar1, Ar2, R3 and R4 is an aromatic heterocyclic group;

[0054] wherein R1 and R2 independently represent an alkyl group having 1 to 4 carbon atoms, which is substituted with an aromatic ring group or an unsubstituted alkyl group having 1 to 4 carbon atoms and may be combined with each other to form a heterocyclic group including a nitrogen atom; m and n independently represent 0 or an integer of from 1 to 3, and are not 0 at the same time; R3 represents a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 11 carbon atoms and a substituted or unsubstituted aromatic ring group; Ar1, Ar2, Ar3, Ar4 and Ar5 independently represent a substituted or unsubstituted aromatic ring group; and Ar1 and Ar2 or Ar1 and Ar3 may form a heterocyclic group including a nitrogen atom together;

[0055] wherein R1 and R2 independently represent an alkyl group having 1 to 4 carbon atoms, which is substituted with an aromatic ring group or an unsubstituted alkyl group having 1 to 4 carbon atoms and may be combined with each other to form a heterocyclic group including a nitrogen atom; m and n independently represent 0 or an integer of from 1 to 3, and are not 0 at the same time; Ar1, Ar2, Ar3, Ar4 and Ar5 independently represent a substituted or unsubstituted aromatic ring group; and Ar1 and Ar2 or Ar1 and Ar3 may form a heterocyclic group including a nitrogen atom together;

[0056] wherein R1 and R2 independently represent an alkyl group having 1 to 4 carbon atoms, which is substituted with an aromatic ring group or an unsubstituted alkyl group having 1 to 4 carbon atoms and may be combined with each other to form a heterocyclic group including a nitrogen atom; n represents an integer of from 1 to 3; Ar1, Ar2, Ar3 and Ar4 independently represent a substituted or unsubstituted aromatic ring group; and Ar1 and Ar2 or Ar1 and Ar3 may form a heterocyclic group including a nitrogen atom together;

[0057] wherein R1 and R2 independently represent an alkyl group having 1 to 4 carbon atoms, which is substituted with an aromatic ring group or an unsubstituted alkyl group having 1 to 4 carbon atoms and may be combined with each other to form a heterocyclic group including a nitrogen atom; 1 represents an integer of from 1 to 3; Ar1 and Ar2 independently represent a substituted or unsubstituted aromatic ring group; R3 and R4 independently represent a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 4 carbon atoms, a substituted or unsubstituted aromatic ring group or a group having the following formula (20):

[0058] wherein R1 and R2 independently represent an alkyl group having 1 to 4 carbon atoms, which is substituted with an aromatic ring group or an unsubstituted alkyl group having 1 to 4 carbon atoms and maybe combined with each other to form a heterocyclic group including a nitrogen atom; m and n independently represent 0 or an integer of from 1 to 3; and R5 and R6 independently represent a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 4 carbon atoms or a substituted or unsubstituted aromatic ring group, and wherein R3 and R4, R5 and R6 or Ar1 and Ar2 may independently form a ring together;

[0059] wherein R1 and R2 independently represent an alkyl group having 1 to 4 carbon atoms, which is substituted with an aromatic ring group or an unsubstituted alkyl group having 1 to 4 carbon atoms and may be combined with each other to form a heterocyclic group including a nitrogen atom; n represents an integer of from 1 to 3; Ar1 and Ar2 independently represent a substituted or unsubstituted aromatic ring group; R3 and R4 independently represent a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 4 carbon atoms, a substituted or unsubstituted aromatic ring group or a group having the following formula (22), and R3 and R4 are not hydrogen atoms at the same time:

[0060] wherein R1 and R2 independently represent an alkyl group having 1 to 4 carbon atoms, which is substituted with an aromatic ring group or an unsubstituted alkyl group having 1 to 4 carbon atoms and may be combined with each other to form a heterocyclic group including a nitrogen atom; m and n independently represent 0 or an integer of from 1 to 3; and R5 and R6 independently represent a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 4 carbon atoms or a substituted or unsubstituted aromatic ring group, and wherein R3 and R4, R5 and R6 or Ar1 and Ar2 may independently form a ring together;

[0061] wherein R1 and R2 independently represent an alkyl group having 1 to 4 carbon atoms, which is substituted with an aromatic ring group or an unsubstituted alkyl group having 1 to 4 carbon atoms and may be combined with each other to form a heterocyclic group including a nitrogen atom; R3 and R4 independently represent a substituted or unsubstituted alkyl group having 1 to 4 carbon atoms or a substituted or unsubstituted aromatic ring group; R5, R6 and R7 independently represent a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 4 carbon atoms or a substituted or unsubstituted aromatic ring group; Ar1 and Ar2 independently represent a substituted or unsubstituted aromatic ring group; R3 and R4 or Ar2 and R4 may form a heterocyclic group including a nitrogen atom together; Ar1 and R5 may form a ring together; 1 represents an integer of from 1 to 3; m represents 0 or an integer of from 1 to 3; and n represents 0 or 1;

[0062] wherein R1 and R2 independently represent an alkyl group having 1 to 4 carbon atoms, which is substituted with an aromatic ring group or an unsubstituted alkyl group having 1 to 4 carbon atoms and may be combined with each other to form a heterocyclic group including a nitrogen atom; R3 and R4 independently represent a substituted or unsubstituted alkyl group having 1 to 4 carbon atoms or a substituted or unsubstituted aromatic ring group; R5, R6 and R7 independently represent a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 4 carbon atoms or a substituted or unsubstituted aromatic ring group; Ar1 and Ar2 independently represent a substituted or unsubstituted aromatic ring group; R3 and R4 or Ar2 and R4 may form a heterocyclic group including a nitrogen atom together; Ar1 and R5 may form a ring together; 1 represents an integer of from 1 to 3; m represents 0 or an integer of from 1 to 3; and n represents 0 or 1;

[0063] wherein R1 and R2 independently represent an alkyl group having 1 to 4 carbon atoms, which is substituted with an aromatic ring group or an unsubstituted alkyl group having 1 to 4 carbon atoms and may be combined with each other to form a heterocyclic group including a nitrogen atom; 1 and m independently represent 0 or an integer of from 1 to 3, and are not 0 at the same time; R3represents a substituted or unsubstituted alkyl group having 1 to 4 carbon atoms or a substituted or unsubstituted aromatic ring group; R4 represents a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 4 carbon atoms or a substituted or unsubstituted aromatic ring group; Ar1 and Ar2 represent a substituted or unsubstituted aromatic ring group; Ar1 and R4, Ar2 and R3 or Ar2 and another Ar2 may form a ring together; and n represents 0 or 1;

[0064] wherein R1 and R2 independently represent an alkyl group having 1 to 4 carbon atoms, which is substituted with an aromatic ring group or an unsubstituted alkyl group having 1 to 4 carbon atoms and may be combined with each other to form a heterocyclic group including a nitrogen atom; 1 and m independently represent 0 or an integer of from 1 to 3, and are not 0 at the same time; R3 represents a substituted or unsubstituted alkyl group having 1 to 4 carbon atoms or a substituted or unsubstituted aromatic ring group; R4 represents a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 4 carbon atoms or a substituted or unsubstituted aromatic ring group; Ar1 and Ar2 represent a substituted or unsubstituted aromatic ring group; Ar1 and R4, Ar2 and R3 or Ar2 and another Ar2 may form a ring together; and n represents 0 or 1;

[0065] wherein R1 and R2 independently represent an alkyl group having 1 to 4 carbon atoms, which is substituted with an aromatic ring group or an unsubstituted alkyl group having 1 to 4 carbon atoms and may be combined with each other to form a heterocyclic group including a nitrogen atom; k, l and m independently represent 0 or an integer of from 1 to 3, and are not 0 at the same time; R3 represents a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 4 carbon atoms or a substituted or unsubstituted aromatic ring group; Ar1 and Ar2 represent a substituted or unsubstituted aromatic ring group; Ar1 and R4, Ar2 and R3 or Ar2 and another Ar2 may form a ring together; and n represents 0 or 1;

[0066] wherein R1 and R2 independently represent an alkyl group having 1 to 4 carbon atoms, which is substituted with an aromatic ring group or an unsubstituted alkyl group having 1 to 4 carbon atoms and may be combined with each other to form a heterocyclic group including a nitrogen atom; k, l and m independently represent 0 or an integer of from 1 to 3, and are not 0 at the same time; R3 represents a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 4 carbon atoms or a substituted or unsubstituted aromatic ring group; Ar1 and Ar2 represent a substituted or unsubstituted aromatic ring group; Ar1 and R4, Ar2 and R3 or Ar2 and another Ar2 may form a ring together; and n represents 0 or 1;

[0067] wherein R1 and R2 independently represent an alkyl group having 1 to 4 carbon atoms, which is substituted with an aromatic ring group or an unsubstituted alkyl group having 1 to 4 carbon atoms and may be combined with each other to form a heterocyclic group including a nitrogen atom; R3 and R4 independently represent a substituted or unsubstituted alkyl group having 1 to 4 carbon atoms or a substituted or unsubstituted aromatic ring group; R5 represents a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 4 carbon atoms or a substituted or unsubstituted aromatic ring group; Ar1 and Ar2 represent a substituted or unsubstituted aromatic ring group; R3 and R4 or Ar1 and R4 may form a heterocyclic group including a nitrogen atom together; k, l and m independently represent 0 or an integer of from 1 to 3; n represents 1 or 2; and R3 and R4 independently represent an alkyl group having 1 to 4 carbon atoms and may be combined with each other to form a heterocyclic group including a nitrogen atom when k, l and m are 0 at the same time;

[0068] wherein R1 and R2 independently represent an alkyl group having 1 to 4 carbon atoms, which is substituted with an aromatic ring group or an unsubstituted alkyl group having 1 to 4 carbon atoms and may be combined with each other to form a heterocyclic group including a nitrogen atom; R3 and R4 independently represent a substituted or unsubstituted alkyl group having 1 to 4 carbon atoms or a substituted or unsubstituted aromatic ring group; R5 represents a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 4 carbon atoms or a substituted or unsubstituted aromatic ring group; Ar1 and Ar2 represent a substituted or unsubstituted aromatic ring group; R3 and R4 or Ar1 and R4 may form a heterocyclic group including a nitrogen atom together; m represents 0 or an integer of from 1 to 4; n represents 1 or 2; and R3 and R4 independently represent an alkyl group having 1 to 4 carbon atoms and may be combined with each other to form a heterocyclic group including a nitrogen atom when m is 0;

[0069] wherein R1 and R2 independently represent an alkyl group having 1 to 4 carbon atoms, which is substituted with an aromatic ring group or an unsubstituted alkyl group having 1 to 4 carbon atoms and may be combined with each other to form a heterocyclic group including a nitrogen atom; Ar represents a substituted or unsubstituted aromatic ring group; R3 and R4represent a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 4 carbon atoms or a substituted or unsubstituted aromatic ring group; and l, m and n independently represent 0 or an integer of from 1 to 3, and are not 0 at the same time;

[0070] wherein R1 and R2 independently represent an alkyl group having 1 to 4 carbon atoms, which is substituted with an aromatic ring group or an unsubstituted alkyl group having 1 to 4 carbon atoms and may be combined with each other to form a heterocyclic group including a nitrogen atom; Ar1, Ar2 and Ar3 represent a substituted or unsubstituted aromatic ring group; R3 represents a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 4 carbon atoms or a substituted or unsubstituted aromatic ring group; l and m independently represent 0 or an integer of from 1 to 3, and are not 0 at the same time; and n represents an integer of from 1 to 3;

[0071] wherein R1 and R2 independently represent an alkyl group substituted with an aromatic hydrocarbon group or an unsubstituted alkyl group and may be combined with each other to form a heterocyclic group including a nitrogen atom; Ar1 and Ar2 represent a substituted or unsubstituted aromatic ring group; l and m independently represent 0 or an integer of from 1 to 3, and are not 0 at the same time; and n represents 1 or 2;

[0072] wherein R1 and R2 independently represent an alkyl group substituted with an aromatic hydrocarbon group or an unsubstituted alkyl group and may be combined with each other to form a heterocyclic group including a nitrogen atom; Ar1 and Ar2 represent a substituted or unsubstituted aromatic ring group; l and m independently represent 0 or an integer of from 1 to 3, and are not 0 at the same time; and n represents 1 or 2; and

[0073] wherein R1 and R2 independently represent substituted or unsubstituted alkyl group and a substituted or unsubstituted aromatic hydrocarbon group, and one of R1 and R2 is a substituted or unsubstituted aromatic hydrocarbon group, and may be combined with each other to form a heterocyclic group including a nitrogen atom; and Ar represents a substituted or unsubstituted aromatic hydrocarbon group.

[0074] Specific examples of the alkyl group mentioned in the explanations of these formulae (9) to (35) include a methyl group, an ethyl group, a propyl group, a butyl group, a hexyl group, an undecanyl group, etc. Specific examples of the aromatic hydrocarbon group include aromatic ring groups such as benzene, biphenyl, naphthalene, anthracene, fluorene and pyrene; and aromatic heterocyclic groups such as pyridine, quinoline, thiophene, furan, oxazole, oxadiazole and carbazole. Specific examples of their substituents include the above-mentioned specific examples of the alkyl group; an alkoxy group such as a methoxy group, an ethoxy group, a propoxy group and a butoxy group; a halogen atoms such as a fluorine atom, a chlorine atom, a bromine atom and an iodine atom; the above-mentioned aromatic hydrocarbon groups; and heterocyclic ring groups such as pyrrolidine, piperidine and piperazine. When R1 and R2 are combined with each other to form a heterocyclic group including a nitrogen atom, specific examples thereof include a condensed heterocyclic group such as pyrrolidino groups, piperidino groups and piperazino groups condensed with aromatic hydrocarbon groups.

[0075] A method of measuring the oxidation potential (Eox1) of the compound having an alkylamino group and that (Eox2) of the CTM, i.e., a primary oxidation half-wave potential. A predetermined amount of acetonitrile and that of an unrelated salt (a supporting electrolyte) such as tetrabutylammonium perchlorate and tetraethylammonium perchlorate are added to a material to be measured to prepare a test liquid. The oxidation potential of the material can be measured by analyzing the test liquid with an electrochemical analysis methods such as polarographic methods and cyclic voltammetric methods. The electrochemical analysis methods are disclosed in “Electrochemical Methods” written by A. J. Bard and L. R. Faulkner and published by Wiley in 1980 in detail, wherein a potential scanning method using a potentiostat is used, and wherein a dropping mercury electrode is used as a working electrode, a noble metal such as platinum or gold (platinum in “Electrochemical Methods”) as a counter electrode and a saturated calomel electrode (SCE) as a reference electrode.

[0076] Specific examples of the compound having an alkylamino group and oxidation potential (Eox1) thereof are shown as follows:

1EoxCom-(Vpoundvs.No.FormulaSCE)1

0.5202

0.6053

0.5004

0.4405

0.6556

0.5207

0.5508

0.6509

0.64010

0.66011

0.66012

0.62513

0.87514

0.66015

0.78016

0.75017

0.60018

0.62519

0.39520

0.66021

0.62022

0.54523

0.76024

0.46025

0.78526

0.74027

0.75028

0.60029

0.85530

0.68031

0.62032

0.75033

0.78034

0.770

[0077] Hereinafter, the CTM will be explained. The CTM is classified to a low-molecular-weight CTM and a charge transport polymer material.

[0078] Specific examples of the low-molecular-weight CTM include compounds having the following formulae (1), (2), (4) to (6), and (36) to (54).

[0079] wherein R1 represents a methyl group, an ethyl group, a 2-hydroxyethyl group or a 2-chlorethyl group; and R2 represents a methyl group, an ethyl group, a benzyl group or a phenyl group; and R3 represents a hydrogen atom, a chlorine atom, a bromine atom, an alkyl group having 1 to 4 carbon atoms, an alkoxy group having 1 to 4 carbon atoms, a dialkylamino group or a nitro group.

[0080] Specific examples of the compound having formula (36) include 9-ethylcalbazole-3-aldehyde-1-methyl-1-phenylhydrazone, 9-ethylcalbazole-3-aldehyde-1-benzyl-1-phenylhydrazone, 9-ethylcalbazole-3-aldehyde-1-diphenylhydrazone, etc.

[0081] wherein Ar represents a naphthalene ring, an anthracene ring, a pyrene ring and their substituents, a pyridine ring, a furan ring or thiophene ring; and R represents an alkyl group, a phenyl group or a benzyl group.

[0082] Specific examples of the compound having formula (37) include 4-diethylaminostyryl-β-aldehhyde-1-methyl-1-phenylhydrazone, 4-methoxynaphthalene-1-aldehyde-1-benzyl-1-phenylhydrazone, etc.

[0083] wherein R1 represents an alkyl group, a benzyl group, a phenyl group or a naphtyl group; R2 represents a hydrogen atom, an alkyl group having 1 to 3 carbon atoms, an alkoxy group having 1 to 3 carbon atoms, a dialkylamino group, diaralkylamino group or a diarylamino group; n represents an integer of from 1 to 4 and R2 may be the same or different from each other when n is not less than 2; and R3 represents a hydrogen atom or a methoxy group.

[0084] Specific examples of the compound having formula (2) include 4-methoxybenzaldehyde-1-methyl-1-phenylhydrazone, 2,4-dimethoxybenzaldehyde-1-benzyl-1-phenylhydrazone, 4-diethylaminobenzaldehyde-1,1-diphenylhydrazone, 4-methoxybenzaldehyde-1-(4-methoxy)phenylhydrazone, 4-diphenylaminobenzaldehyde-1-benzyl-1-phenylhydrazone, 4-dibenzylaminobenzaldehyde-1,1-diphenylhydrazone, etc.

[0085] wherein R1 represents an alkyl group having 1 to 11 carbon atoms, a substituted or unsubstituted phenyl group or a heterocyclic ring group; R2 and R3 independently represent a hydrogen atom, an alkyl group having 1 to 4 carbon atoms, a hydroxyalkyl group, a chloralkyl group or a substituted or unsubstituted aralkyl group, and may be combined each other to form a heterocyclic ring group including a nitrogen atom; and R4 independently represent a hydrogen atom, an alkyl group having 1 to 4 carbon atoms, an alkoxy group or a halogen atom.

[0086] Specific examples of the compound having the formula (38) include 1,1-bis(4-dibenzylaminophenyl)propane, tris(4-diethylaminophenyl)methane, 1,1-bis(4-dibenzylaminophenyl)propane, 2,2′-dimethyl-4,4′-bis(diethylamino)-triphenylmethane, etc.

[0087] wherein R represents a hydrogen atom or a halogen atom; and Ar represents a substituted or unsubstituted phenyl group, a naphtyl group, an anthryl group or a carbazolyl group.

[0088] Specific examples of the compound having the formula (39) include 9-(4-diethylaminostyryl)anthracene, 9-bromo-10-(4-diethylaminostyryl)anthracene, etc.

[0089] wherein R1 represents a hydrogen atom, a cyano group, an alkoxy group having 1 to 4 carbon atoms or a alkyl group having 1 to 4 carbon atoms; and Ar represents a group having the following formulae (41) and (42):

[0090] wherein R2 represents an alkyl group having 1 to 4 carbon atoms; R3 represents a hydrogen atom, a halogen atom, an alkyl group having 1 to 4 carbon atoms, an alkoxy group having 1 to 4 carbon atoms or a dialkylamino group; n is 1 or 2, and R3 may be the same or different from each other when n is 2; and R4 and R5 represent a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 4 carbon atoms or a substituted or unsubstituted benzyl group.

[0091] Specific examples of the compound having the formula (40) include 9-(4-dimethylaminobenzylidene)fluorene, 3-(9-fluorenylidene)-9-ethylcarbazole, etc.

[0092] wherein R represents a carbazolyl group, a pyridyl group, a thienyl group, an indolyl group, a furyl group, a substituted or unsubstituted phenyl, styryl, naphtyl group or an anthryl group, and their substituents are selected from the group consisting of a dialkylamino group, an alkyl group, an alkoxy group, a carboxyl group or its ester, a halogen atom, a cyano group, an aralkylamino group, N-alkyl-N-aralkylamino group, an amino group, a nitro group and an acethylamino group.

[0093] Specific examples of the compound having the formula (43) include 1,2-bis-(4-diethylaminostyryl)benzene, 1,2-bis(2-,4-dimethoxystyryl)benzene, etc.

[0094] wherein R1 represents a lower alkyl group, a substituted or unsubstituted phenyl group or a benzyl group; R2 and R3 represent a hydrogen atom, a lower alkyl group, a lower alkoxy group, a halogen atom, a nitro group, an amino group or an amino group substituted by a lower alkyl group or a benzyl group; and n is 1 or 2.

[0095] Specific examples of the compound having the formula (44) include 3-styryl-9-ethylcarbazole, 3-(4-methoxystyryl)-9-ethylcarbazole, etc.

[0096] wherein R1 represents a hydrogen atom, an alkyl group, an alkoxy group or a halogen atom; R2 and R3 represent a substituted or unsubstituted aryl group; R4 represents a hydrogen atom, a lower alkyl group or a substituted or unsubstituted phenyl group; and Ar represents a substituted or unsubstituted phenyl group or a naphtyl group.

[0097] Specific examples of the compound having the formula (31) include 4-diphenylaminostilbene, 4-dibenzylaminostilbene, 4-ditolylaminostilbene, 1-(4-iphenylaminostyryl)naphthalene, 1-(4-diethylaminostyryl)naphthalene, etc.

[0098] wherein n is 0 or 1; R1 represents a hydrogen atom, an alkyl group or a substituted or unsubstituted phenyl group; Ar1 represents a substituted or unsubstituted aryl group; R5 represents an alkyl group having 1 to 4 carbon atoms or a substituted or unsubstituted aryl group; and A represents a 9-anthryl group, a substituted or unsubstituted carbazolyl group or a group having the following formula (4) or (5):

[0099] wherein R2 represents a hydrogen atom, an alkyl group, an alkoxy group, a halogen atom or a group having the following formula; and m is an integer of from 1 to 3;

[0100] wherein R3 and R4 independently represent a substituted or unsubstituted aryl group, and R4 may form a ring, and wherein R2 may be the same or different from each other when m is not less than 2, and A and R1 may form a ring together when n is 0.

[0101] Specific examples of the compound having the formula (1) include 4′-diphenylamino-α-phenylstilbene, 4′-bis (4-methylphenyl)amino-α-phenylstilbene, etc.

[0102] wherein R1, R2 and R3 represent a hydrogen atom, a lower alkyl group, a lower alkoxy group, a halogen atom or a dialkylamino group; and n is 0 or 1.

[0103] Specific examples of the compound having the formula (46) include 1-phenyl-3-(4-diethylaminostyryl)-5-(4-diethylaminophenyl)pyrazoline, etc.

[0104] wherein R1 and R2 represent an alkyl group including a substituted alkyl group or a substituted or unsubstituted aryl group; and A represents a substituted amino group, a substituted or unsubstituted aryl group or an aryl group.

[0105] Specific examples of the compound having the formula (47) include 2,5-bis(4-diethylaminophenyl)-1,3,4-oxadiazole, 2-N,N-diphenylamino-5-(4-diethylaminophenyl)-1,3,4-oxadiazole, 2-(4-dimethylaminophenyl)-5-(4-diethylaminophenyl)-1,3,4-oxadiazole, etc.

[0106] wherein X represents a hydrogen atom, a lower alkyl group or a halogen atom; R represents an alkyl group including a substituted alkyl group or a substituted or unsubstituted aryl group; and A represents a substituted amino group, a substituted or unsubstituted aryl group or an aryl group.

[0107] Specific examples of the compound having the formula (48) include 2-N,N-diphenylamino-5-(N-ethylcarbazole-3-yl)-1,3,4-oxadiazole, 2-(4-diethylaminophenyl)-5-(N-ethylcarbazole-3-yl)-1,3,4-oxadiazole, etc.

[0108] wherein R1 represents a lower alkyl group, a lower alkoxy group or a halogen atom; R2 and R3 independently represent a hydrogen atom, a lower alkyl group, a lower alkoxy group or a halogen atom; and l, m and n independently represent 0 or an integer of from 1 to 4.

[0109] Specific examples of the benzidine compound having the formula (49) include N,N′-diphenyl-N,N′-bis(3-methylphenyl)-[1,1′-biphenyl]-4,4′-diamine, 3,3′-dimethyl-N,N,N′,N′-tetrakis(4-methylphenyl)-[1,1′-biphenyl]-4,4′-diamine, etc.

[0110] wherein R1 R3 and R4 represent a hydrogen atom, an amino group, an alkoxy group, a thioalkoxy group, an aryloxy group, a methylenedioxy group, a substituted or unsubstituted alkyl group, a halogen atom or a substituted or unsubstituted aryl group; R2 represents a hydrogen atom, an alkoxy group, a substituted or unsubstituted alkyl group or a halogen atom, but a case in which R1, R2, R3 and R4 are all hydrogen atoms is excluded; and k, l, m, and n are independently an integer of from 1 to 4, and R1, R2, R3 and R4 may be the same or different from the others when k, l, m, and n are an integer of from 2 to 4.

[0111] Specific examples of the biphenylamine compound having the formula (50) include 4′-methoxy-N,N-diphenyl-[1,1′-biphenyl]-4-amine, 4′-methyl-N,N-bis (4-methylphenyl)-[1,1′-biphenyl]-4-amine, 4′-methoxy-N,N-bis(4-methylphenyl)-[1,1′-biphenyl]-4-amine, N,N-bis(3,4-dimethylphenyl)-[1,1′-biphenyl]-4-amine, etc.

[0112] wherein Ar represents a condensation polycyclic hydrocarbon group having 18 or less carbon atoms which can have a substituent; and R1 and R2 independently represent a hydrogen atom, a halogen atom, a substituted or unsubstituted alkyl group, an alkoxy group, or a substituted or unsubstituted phenyl group and n is 1 or 2.

[0113] Specific examples of the triarylamine compound having the formula (51) include N,N-diphenyl-pyrene-1-amine, N,N-di-p-tolyl-pyrne-1-amine, N,N-di-p-tolyl-1-naphthylamine, N,N-di(p-tolyl)-1-phenanthorylamine, 9,9-dimethyl-2-(di-p-tolylamino)fluorene, N,N,N′,N′-tetrakis(4-methylphenyl)-phenanthrene-9,10-diamine, N,N,N′,N′-tetrakis(3-methylphenyl)-m-phenylenediamine, etc.

A—CH═CH—Ar—CH═CH—A (52)

[0114] wherein Ar represents a substituted or unsubstituted aromatic hydrocarbon group; and A represents the following formula (53):

[0115] wherein Ar′ represents a substituted or unsubstituted aromatic hydrocarbon group; and R1 and R2 represent substituted or unsubstituted alkyl group or a substituted or unsubstituted aryl group.

[0116] Specific examples of the diolefin aromatic compound having the formula (52) include 1,4-bis (4-diphenylaminostyryl)benzene, 1,4-bis[4-di(p-tolyl)aminostyryl]benzene, etc.

[0117] wherein Ar represents a substituted or unsubstituted aromatic hydrocarbon group; R represents a hydrogen atom, a substituted or unsubstituted alkyl group or a substituted or unsubstituted aryl group; n is 0 or 1; m is 1 or 2; and Ar and R may form a ring when n is 0 and m is 1.

[0118] Specific examples of the styrylpyrene compound having the formula (54) include 1-(4-diphenylaminostyryl)pyrene, 1-[4-di(p-tolyl) aminostyryl]pyrene, etc.

[0119] Specific examples of an electron transport materials include chloranil, bromoanil, tetracyanoethylene, tetracyanoquinodimethane, 2,4,7-trinitro-9-fluorenone, 2,4,5,7-tetranitro-9-fluorenone, 2,4,5,7-tetranitroxanthone, 2,4,8-trinitrothioxanthone, 2,6,8-trinitro-indeno[1,2-b]thiophene-4-one, and 1,3,7-trinitrodibenzothiophene-5,5-dioxide, etc. In addition, electron transport materials having the following formulae (55), (56) and (57) are preferably used.

[0120] wherein R1, R2 and R3 independently represent a hydrogen atom, a halogen atom, a substituted or unsubstituted alkyl group, an alkoxy group or a substituted or unsubstituted phenyl group;

[0121] wherein R1 and R2 independently represent a hydrogen atom, a substituted or unsubstituted alkyl group, or a substituted or unsubstituted phenyl group;

[0122] wherein R1, R2 and R3 independently represent a hydrogen atom, a halogen atom, a substituted or unsubstituted alkyl group, an alkoxy group or a substituted or unsubstituted phenyl group.

[0123] These CTMs can be used alone or in combination.

[0124] In the present invention, among the above-mentioned low-molecular-weight CTMs, the low-molecular-weight CTMs having formulae (1) and (2) are preferably used because of particularly having good transportability and good properties of receiving charges from CGMs. Therefore, an electrophotographic photoreceptor including the low-molecular-weight CTMs having formulae (1) and (2) in its photosensitive layer has high sensitivity.

[0125] Specific examples of the charge transport polymer material include compounds having the following formulae (3), (7), (8) and (58) to (69):

[0126] wherein R7 and R8 independently represent a substituted or unsubstituted aromatic ring group; Ar1, Ar2 and Ar3 independently represent an aromatic ring group; k is a number of from 0.1 to 1.0 and j is a number of from 0 to 0.9; n represents a repeating number and is an integer of from 5 to 5,000; and X represents a divalent aliphatic group, a divalent alicyclic group or a divalent group having the following formula (7):

[0127] wherein, R101 and R102 independently represent a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, or a halogen atom; t and m independently represent 0 or an integer of from 1 to 4; d is 0 or 1; and Y represents a linear alkylene group, a branched alkylene group, a cyclic alkylene group, —O—, —S—, —SO—, —SO2—, —CO—, —CO—O—Z—O—CO— (Z represents a divalent aliphatic group), or a group having the following formula (8):

[0128] wherein, a is an integer of from 1 to 20; b is an integer of from 1 to 2,000; and R103 and R104 independently represent a substituted or unsubstituted alkyl group, or a substituted or unsubstituted aryl group, and wherein R101, R102, R103 and R104 may be the same or different from the others.

[0129] wherein, R1, R2 and R3 independently represent a substituted or unsubstituted alkyl group, or a halogen atom; R4 represents a hydrogen atom, or a substituted or unsubstituted alkyl group; R5, and R6 independently represent a substituted or unsubstituted aryl group; o, p and q independently represent 0 or an integer of from 1 to 4; and X, k, j and n are same in formula (3);

[0130] wherein, R9 and R10 represent a substituted or unsubstituted aryl group; Ar4, Ar5 and Ar6 independently represent an arylene group; and X, k, j and n are same in formula (3);

[0131] wherein, R11 and R12 represent a substituted or unsubstituted aryl group; Ar7, Ar8 and Ar9 independently represent an arylene group; p is an integer of from 1 to 5; and X, k, j and n are same in formula (3);

[0132] wherein, R13 and R14 represent a substituted or unsubstituted aryl group; Ar10, Ar11 and Ar12 independently represent an arylene group; X1 and X2 represent a substituted or unsubstituted ethylene group, or a substituted or unsubstituted vinylene group; and X, k, j and n are same in formula (3);

100

[0133] wherein, R15, R16, R17 and R18 represent a substituted or unsubstituted aryl group; Ar13, Ar14, Ar15 and Ar16 independently represent an arylene group; Y1, Y2 and Y3 independently represent a direct bonding, a substituted or unsubstituted alkylene group, a substituted or unsubstituted cycloalkylene group, a substituted or unsubstituted alkylene ether group, an oxygen atom, a sulfur atom, or a vinylene group; and X, k, j and n are same in formula (3);

101

[0134] wherein, R19 and R20 represent a hydrogen atom, or substituted or unsubstituted aryl group, and R19 and R20 may form a ring; Ar17, Ar18 and Ar19 independently represent an arylene group; and X, k, j and n are same in formula (3);

102

[0135] wherein, R21 represents a substituted or unsubstituted aryl group; Ar20, Ar21, Ar22 and Ar23 independently represent an arylene group; and X, k, j and n are same in formula (3);

103

[0136] wherein, R22, R23, R24 and R25 represent a substituted or unsubstituted aryl group; Ar24, Ar25, Ar26, Ar27 and Ar28 independently represent an arylene group; and X, k, j and n are same in formula (3);

104

[0137] wherein, R26 and R27 independently represent a substituted or unsubstituted aryl group; Ar29, Ar30 and Ar31 independently represent an arylene group; and X, k, j and n are same in formula (3);

105

[0138] wherein Ar1, Ar2 Ar3, Ar4 and Ar5 represent a substituted or unsubstituted aromatic ring group; Z represents an aromatic ring group or —Ar6-Za-Ar6—; Ar6 represents a substituted or unsubstituted aromatic ring group; Za represents O,S or an alkylene group; R and R′ represent a linear alkylene group or a branched alkylene group; m is 0 or 1; and X, k, j and n are same in formula (3).

[0139] In the present invention, among the above-mentioned charge transport polymer materials, the charge transport polymer material having formula (3) is preferably used because of particularly having good abrasion resistance and good transportability. Therefore, an electrophotographic photoreceptor including the charge transport polymer material having formula (3) in its photosensitive layer has high durability and sensitivity.

[0140] Next, layer compositions of the electrophotographic photoreceptor of the present invention will be explained, referring to FIGS. 1 to 5.

[0141]
FIG. 1 is a schematic view illustrating a cross section of a surface of an embodiment of the photoreceptor of the present invention, in which a photosensitive layer 33 including a CGM the main components is formed on an electroconductive substrate 31.

[0142] In FIG. 2, a CGL 35 including a CGM as the main component overlies a CTL 37 including a CTM as the main component on an electroconductive substrate 31.

[0143] In FIG. 3, a photosensitive layer 33 including a CGM and a CTM as the main components is formed on an electroconductive substrate 31, and further a protection layer 39 is formed on a surface of the photosensitive layer. In this case, the protection layer 39 may include an amine compound of the present invention.

[0144] In FIG. 4, a CGL 35 including a CGM as the main component, a CTL 37 including a CTM as the main component overlying the CGL, and further a protection layer 39 overlying the CTL are formed on an electroconductive substrate 31. In this case, the protection layer 39 may include an amine compound of the present invention.

[0145] In FIG. 5, a CTL 37 including a CTM as the main component, a CGL 35 including a CGM as the main component overlying the CTL, and further a protection layer 39 overlying the CGL are formed on an electroconductive substrate 31. In this case, the protection layer 39 may include an amine compound of the present invention.

[0146] Suitable materials for use as the electroconductive substrate 31 include materials having a volume resistance not greater than 1010 Ω·cm. Specific examples of such materials include plastic cylinders, plastic films or paper sheets, on the surface of which a metal such as aluminum, nickel, chromium, nichrome, copper, gold, silver, platinum and the like, or a metal oxide such as tin oxides, indium oxides and the like, is deposited or sputtered. In addition, a plate of a metal such as aluminum, aluminum alloys, nickel and stainless steel and a metal cylinder, which is prepared by tubing a metal such as the metals mentioned above by a method such as impact ironing or direct ironing, and then treating the surface of the tube by cutting, super finishing, polishing and the like treatments, can be also used as the substrate. Further, endless belts of a metal such as nickel and stainless steel, which have been disclosed in Japanese Laid-Open Patent Publication No. 52-36016, can be also used as the electroconductive substrate 31.

[0147] Furthermore, substrates, in which a coating liquid including a binder resin and an electroconductive powder is coated on the supporters mentioned above, can be used as the substrate 31. Specific examples of such an electroconductive powder include carbon black, acetylene black, powders of metals such as aluminum, nickel, iron, Nichrome, copper, zinc, silver and the like, and metal oxides such as electroconductive tin oxides, ITO and the like. Specific examples of the binder resin include known thermoplastic resins, thermosetting resins and photo-crosslinking resins, such as polystyrene, styrene-acrylonitrile copolymers, styrene-butadiene copolymers, styrene-maleic anhydride copolymers, polyesters, polyvinyl chloride, vinyl chloride-vinyl acetate copolymers, polyvinyl acetate, polyvinylidene chloride, polyarylates, phenoxy resins, polycarbonates, cellulose acetate resins, ethyl cellulose resins, polyvinyl butyral resins, polyvinyl formal resins, polyvinyl toluene, poly-N-vinyl carbazole, acrylic resins, silicone resins, epoxy resins, melamine resins, urethane resins, phenolic resins, alkyd resins and the like resins. Such an electroconductive layer can be formed by coating a coating liquid in which an electroconductive powder and a binder resin are dispersed in a solvent such as tetrahydrofuran, dichloromethane, methyl ethyl ketone, toluene and the like solvent, and then drying the coated liquid.

[0148] In addition, substrates, in which an electroconductive resin film is formed on a surface of a cylindrical substrate using a heat-shrinkable resin tube which is made of a combination of a resin such as polyvinyl chloride, polypropylene, polyesters, polyvinylidene chloride, polyethylene, chlorinated rubber and fluorine-containing resins, with an electroconductive material, can be also used as the substrate 31.

[0149] Next, the photosensitive layer of the present invention will be explained. In the present invention, the photosensitive layer may be single-layered or a multi-layered. At first, the multi-layered photosensitive layer including the CGL 35 and the CTL 37 will be explained for explanation convenience.

[0150] The CGL 35 is a layer including a CGM as the main component. Known CGMs can be used in the CGL 35. Specific examples of the CGM include azo pigments such as CI Pigment Blue 25 (color index CI 21180), CI Pigment Red 41 (CI 21200), CI Acid Red 52 (CI 45100), CI Basic Red 3 (CI 45210), an azo pigment having a carbazole skeleton disclosed in Japanese Laid-Open Patent Publication (JLPP) No. 53-95033, an azo pigment having a distyrylbenzene skeleton disclosed in JLPP No. 53-133445, an azo pigment having a triphenylamine skeleton disclosed in JLPP No. 53-132347, an azo pigment having a dibenzothiophene skeleton disclosed in JLPP No. 54-21728, an azo pigment having an oxadiazole skeleton disclosed in JLPP No. 54-12742, an azo pigment having a fluorenone skeleton disclosed in JLPP No. 54-22834, an azo pigment having a bisstilbene skeleton disclosed in JLPP No. 54-17733, an azo pigment having a distyryloxadiazole skeleton disclosed in JLPP No. 54-2129, an azo pigment having a distyrylcarbazole skeleton disclosed in JLPP No. 54-14967 and an azo pigment having a benzanthrone skeleton; phthalocyanine pigments such as CI Pigment Blue 16 (CI 74100), Y-type oxotitaniumphthalocyanine disclosed in JLPP No. 64-17066, A(β)-type oxotitaniumphthalocyanine, B(α)-type -type oxotitaniumphthalocyanine, I-type oxotitaniumphthalocyanine disclosed in JLPP No. 11-21466, II-type chlorogalliumphthalocyanine disclosed by Mr. Iijima and others in the 67th spring edition 1B4, 04 published by Chemical Society of Japan in 1994, V-type hydroxygalliumphthalocyanine disclosed Mr. Daimon and others in the 67th spring edition 1B4, 05 published by Chemical Society of Japan in 1994 and X-type metal-free phthalocyanine disclosed in U.S. Pat. No. 3,816,118; indigo pigments such as CI Vat Brown 5 (CI 73410) and CI Vat Dye (CI 73030); and perylene pigments such as Algo Scarlet B from Bayer AG and Indanthrene Scarlet R from Bayer AG. These materials can be used alone or in combination.

[0151] The CGL 35 can be prepared by dispersing a CGM in a proper solvent optionally together with a binder resin using a ball mill, an attritor, a sandmill or a supersonic dispersing machine, coating the coating liquid on an electroconductive substrate and then drying the coated liquid.

[0152] Specific example of the binder resins optionally used in the CGL 35, include polyamides, polyurethanes, epoxy resins, polyketones, polycarbonates, silicone resins, acrylic resins, polyvinyl butyral, polyvinyl formal, polyvinyl ketones, polystyrene, polysulfone, poly-N-vinylcarbazole, polyacrylamide, polyvinyl benzal, polyesters, phenoxy resins, vinyl chloride-vinyl acetate copolymers, polyvinyl acetate, polyphenylene oxide, polyamides, polyvinyl pyridine, cellulose resins, casein, polyvinyl alcohol, polyvinyl pyrrolidone, and the like resins. The content of the binder resin in the CGL 35 is preferably from 0 to 500 parts by weight, and preferably from 10 to 300 parts by weight, per 100 parts by weight of the CGM. The binder resin can be included either before or after dispersion of the CGM in the solvent.

[0153] Specific examples of the solvent include isopropanol, acetone, methyl ethyl ketone, cyclohexanone, tetrahydrofuran, dioxane, ethyl cellosolve, ethyl acetate, methyl acetate, dichloromethane, dichloroethane, monochlorobenzene, cyclohexane, toluene, xylene, ligroin, and the like solvents. In particular, ketone type solvents, ester type solvents and ether type solvents are preferably used. These can be used alone or in combination.

[0154] The CGL 35 includes a CGM, a solvent and a binder rein as the main components. Any additives such as a sensitizer, a disperser, a detergent and a silicone oil can be included therein.

[0155] The coating liquid can be coated by a coating method such as dip coating, spray coating, bead coating, nozzle coating, spinner coating and ring coating. The CGL 35 preferably has a thickness of from 0.01 to 5 μm, and more preferably from 0.1 to 2 μm.

[0156] The CTL 37 is a layer including a CTM as the main component and a compound having an alkylamino group. The CTMs having the above-mentioned formulae (1) to (8) and (36) to (67) are preferably used, and the compound having an alkylamino group CTMs having the above-mentioned formulae (9) to (35) (specifically the above-mentioned compounds Nos. 1 to 34) are preferably used. The CTL 37 is formed by dissolving the CTM, compound having an alkylamino group and optionally a binder resin in a proper solvent to prepare a coating liquid, coating the coating liquid on the CGL 35 and drying the coating liquid.

[0157] Specific examples of the binder resin include thermoplastic resins, thermosetting resins such as polystyrene, styrene-acrylonitrile copolymers, styrene-butadiene copolymers, styrene-maleic anhydride copolymers, polyesters, polyvinyl chloride, vinyl chloride-vinyl acetate copolymers, polyvinyl acetate, polyvinylidene chloride, polyarylates, phenoxy resins, polycarbonates, cellulose acetate resins, ethyl cellulose resins, polyvinyl butyral resins, polyvinyl formal resins, polyvinyl toluene, poly-N-vinyl carbazole, acrylic resins, silicone resins, epoxy resins, melamine resins, urethane resins, phenolic resins, alkyd resins and the like.

[0158] When a photosensitive layer is formed of the CGL 35 and CTL 37, and the CTM and compound having an alkylamino group are included in the CTL 37, a total content of the CTM and compound having an alkylamino group is preferably from 20 to 300 parts by weight, and more preferably from 40 to 150 parts by weight per 100 parts by weight of the binder resin. The CTL preferably has a thickness not greater than 25 μm in view of resolution of the resultant images and response. The lower limit of the thickness is preferably not less than 5 μm, although it depends on the image forming system (particularly on a charged potential of the electrophotographic photoreceptor).

[0159] In addition, the content of the compound having an alkylamino group is preferably from 0.01 to 150% by weight based on total weight of the CTM. When less than 0.01% by weight, the durability against the oxidizing gas of the resultant photoreceptor deteriorates. When greater than 150% by weight, the residual potential thereof increases.

[0160] In the present invention, an oxidation potential (Eox1) of the compound having an alkylamino group and that (Eox2) of the CTM satisfy the following relationship (I):

Eox1−Eox2≧−0.2 (I)

[0161] To satisfy the relationship, a compound having an alkylamino group and an oxidation potential (Eox1) which is not far from a fixed oxidation potential (Eox2) of the main CTM is preferably selected. When a threshold, i.e. Eox1−Eox2, is less than −0.2, the compound having an alkylamino group noticeably becomes a trap against the charge transport (hole) and a bright section potential of the resultant electrophotographic photoreceptor becomes large, and therefore the resultant images do not have a contrast.

[0162] Specific examples of a solvent for use in forming the CTL 37 include tetrahydrofuran, dioxane, toluene, dichloromethane, monochlorobenzene, dichloroethane, cyclohexanone, methyl ethyl ketone, acetone and the like solvents. The CTM can be used alone or in combination in the solvent.

[0163] As an antioxidant is preferably included in the CTL 37 and conventional antioxidants mentioned later can be used, and (c) hydroquinone compounds and (f) hindered amine compounds are effectively used in particular.

[0164] However, the antioxidant for use in the CTL has a different purpose from the after-mentioned purpose, and are used to prevent quality alteration of the amine compound of the present invention. Therefore, the antioxidant is preferably included in a CTL coating liquid before the amine compound of the present invention is included therein. The content of the antioxidant is from 0.1 to 200% by weight based on total weight of the amine compound.

[0165] The CTL 37 preferably includes a polymer CTM, which has both a binder resin function and a charge transport function, because the resultant CTL 37 has good abrasion resistance. Suitable charge transport polymer materials include known materials. Among these materials, polycarbonate resins having a triarylamine structure in their main chain and/or side chain are preferably used.

[0166] The CTL 37 can be formed by coating a coating liquid in which the CTM alone or the CTM and a binder resin are dissolved or dispersed in a proper solvent on the CGL, and drying the liquid. In addition, the CTL may optionally include two or more of additives such as plasticizers, leveling agents and antioxidants.

[0167] As a method of coating the thus prepared coating liquid, a conventional coating method such as a dip coating method, a spray coating method, a bead coating method, a nozzle coating method, a spinner coating method and a ring coating method can be used.

[0168] Next, a single-layered photosensitive layer will be explained. A photoreceptor in which the above-mentioned CGM is dispersed in the binder resin can be used. The photosensitive layer can be formed by coating a coating liquid in which a CGM, a CTM and a binder resin are dissolved or dispersed in a proper solvent, and then drying the coated liquid. In addition, the photosensitive layer may optionally include additives such as plasticizers, leveling agents and antioxidants.

[0169] Suitable binder resins include the resins mentioned above in the CTL 37. The resins mentioned above in the CGL 35 can be added as a binder resin. In addition, the polymer CTLs mentioned above can be also used as a binder resin preferably. A content of the CGM is preferably from 5 to 40 parts by weight per 100 parts by weight of the binder resin. A total content of the CGM and the compound having an alkylamino group is preferably from 10 to 45 parts by weight, and more preferably from 20 to 30 parts by weight. Further, the compound having an alkylamino group preferably has a content of from 5 to 100% by weight per 100% by weight of the CTM. When less than 5% by weight, the resultant electrophotographic photoreceptor does not have sufficient resistance against the oxidizing gas. When greater than 100% by weight, the residual potential of the resultant electrophotographic photoreceptor due to repeated use increases.

[0170] A method of satisfying the above-mentioned relationship (I) between an oxidation potential (Eox1)of the compound having an alkylamino group and that (Eox2) of the CTM when the photosensitive layer is single-layered is the same as that for the above-mentioned photosensitive layer formed of the CGL 35 and CTL 37.

[0171] The single-layered photosensitive layer can be formed by coating a coating liquid in which a CGM, a binder resin and a CTM are dissolved or dispersed in a solvent such as tetrahydrofuran, dioxane, dichloroethane, cyclohexane, etc. by a coating method such as a dip coating method, spray coating method, a bead coating method and a ring coating method. The thickness of the photosensitive layer is preferably from 5 to 25 μm.

[0172] In the photoreceptor of the present invention, an under coat layer may be formed between the substrate 31 and the photosensitive layer. The undercoat layer includes a resin as a main component. Since a photosensitive layer is typically formed on the undercoat layer by coating a liquid including an organic solvent, the resin in the undercoat layer preferably has good resistance against general organic solvents. Specific examples of such resins include water-soluble resins such as polyvinyl alcohol resins, casein and polyacrylic acid sodium salts; alcohol soluble resins such as nylon copolymers and methoxymethylated nylon resins; and thermosetting resins capable of forming a three-dimensional network such as polyurethane resins, melamine resins, alkyd-melamine resins, epoxy resins and the like. The undercoat layer may include a fine powder of metal oxides such as titanium oxide, silica, alumina, zirconium oxide, tin oxide and indium oxide to prevent occurrence of moiré in the recorded images and to decrease residual potential of the photoreceptor.

[0173] The undercoat layer can be formed by coating a coating liquid using a proper solvent and a proper coating method similarly to those for use in formation of the photosensitive layer mentioned above. The undercoat layer may be formed using a silane coupling agent, titanium coupling agent or a chromium coupling agent. In addition, a layer of aluminum oxide which is formed by an anodic oxidation method and a layer of an organic compound such as polyparaxylylene (parylene) or an inorganic compound such as SiO, SnO2, TiO2, ITO or CeO2 which is formed by a vacuum evaporation method is also preferably used as the undercoat layer. The thickness of the undercoat layer is preferably 0 to 5 μm.

[0174] In the photoreceptor of the present invention, the protection layer 39 is optionally formed overlying the photosensitive layer. Suitable materials for use in the protection layer 39 include organic compounds having an acid value of from 10 to 400 mgKOH/g such as ABS resins, ACS resins, olefin-vinyl monomer copolymers, chlorinated polyethers, aryl resins, phenolic resins, polyacetal, polyamides, polyester resins, polyamideimide, polyacrylates, polyarylsulfone, polybutylene, polybutylene terephthalate, polycarbonate, polyethersulfone, polyethylene, polyethylene terephthalate, polyimides, acrylic resins, polymethylpentene, polypropylene, polyphenyleneoxide, polysulfone, polystyrene, AS resins, butadiene-styrene copolymers, polyurethane, polyvinyl chloride, polyvinylidene chloride, epoxy resins and the like, because of preventing an increase of residual potential of the resultant photoreceptor. Among these materials, the polycarbonate resin and the polyarylate resin are preferably and effectively used in terms of dispersibility of a filler, decrease of residual potential and coating defect of the resultant photoreceptor.

[0175] The protection layer 39 preferably includes a filler for the purpose of improving abrasion resistance thereof. Suitable fillers include highly-insulative fillers having a pH not less than 5 and a dielectric constant not less than 5 such as titanium oxide, alumina, zinc oxide and zirconium oxide.

[0176] The protection layer 39 can be formed by dispersing a binder resin, a filler material, etc. in a proper solvent with a ball mill, an attritor, a sand mill or an ultrasonic to prepare a dispersion liquid; coating the dispersion liquid on a photosensitive layer; and drying the dispersion liquid.

[0177] As a solvent for use in forming the protection layer, tetrahydrofuran, dioxane, toluene, dichloromethane, monochlorobenzene, dichloroethane, cyclohexanone, methyl ethyl ketone, acetone and the like solvents which are all used in the CTL 37 can be used. However, a high-viscosity solvent is preferably used in dispersion, and a high-volatile solvent is preferably used in coating. When such a solvent as satisfies the conditions is not available, a mixture of two or more of solvents having each property can be used, which occasionally improves dispersibility of the filler and decreases residual potential of the resultant photoreceptor.

[0178] Further, the protection layer 39 may include the compound having an alkylamino group of the present invention. A CTM and the compound having an alkylamino group are preferably and effectively included therein to decrease residual potential of the resultant photoreceptor and to improve quality of the resultant images.

[0179] As a method of forming the protection layer, a conventional coating method such as a dip coating method, a spray coating method, a bead coating method, a nozzle coating method, a spinner coating method and ring coating method can be used. In particular, the spray coating method is preferably used in terms of coated film uniformity.

[0180] In the photoreceptor of the present invention, an intermediate layer may be formed between the photosensitive layer and the protection layer. The intermediate layer includes a resin as a main component. Specific examples of the resin include polyamides, alcohol soluble nylons, water-soluble polyvinyl butyral, polyvinyl butyral, polyvinyl alcohol, and the like. The intermediate layer can be formed by one of the above-mentioned known coating methods. The thickness of the intermediate layer is preferably from 0.05 to 2 μm.

[0181] In the photoreceptor of the present invention, antioxidants, plasticizers, lubricants, ultraviolet absorbents and leveling agents can be included in each layer such as the CGL, CTL, undercoat layer, protection layer and intermediate layer for environmental improvement, above all for the purpose of preventing decrease of photosensitivity and increase of residual potential. Such compounds will be shown as follows.

[0182] Suitable antioxidants for use in the layers of the photoreceptor include the following compounds but are not limited thereto.

[0183] (a) Phenolic Compounds

[0184] 2,6-di-t-butyl-p-cresol, butylated hydroxyanisole, 2,6-di-t-butyl-4-ethylphenol, n-octadecyl-3-(4′-hydroxy-3′,5′-di-t-butylphenol), 2,2′-methylene-bis-(4-methyl-6-t-butylphenol), 2,2′-methylene-bis-(4-ethyl-6-t-butylphenol), 4,4′-thiobis-(3-methyl-6-t-butylphenol), 4,4′-butylidene bis-(3-methyl-6-t-butylphenol), 1,1,3-tris-(2-methyl-4-hydroxy-5-t-butylphenyl)butane, 1,3,5-trimethyl-2,4,6-tris(3,5-di-t-butyl-4-hydroxybenzyl)benzene, tetrakis-[methylene-3-(3′,5′-di-t-butyl-4′-hydroxyphenyl)propionate]methane, bis[3,3′-bis(4′-hydroxy-3′-t-butylphenyl)butyric acid]glycol ester, tocophenol compounds, and the like.

[0185] (b) Paraphenylenediamine Compounds

[0186] N-phenyl-N′-isopropyl-p-phenylenediamine, N,N′-di-sec-butyl-p-phenylenediamine, N-phenyl-N-sec-butyl-p-phenylenediamine, N,N′-di-isopropyl-p-phenylenediamine, N,N′-dimethyl-N,N′-di-t-butyl-p-phenylenediamine, and the like.

[0187] (c) Hydroquinone Compounds

[0188] 2,5-di-t-octylhydroquinone, 2,6-didodecylhydroquinone, 2-dodecylhydroquinone, 2-dodecyl-5-chlorohydroquinone, 2-t-octyl-5-methylhydroquinone, 2-(2-octadecenyl)-5-methylhydroquinone and the like.

[0189] (d) Organic Sulfur-Containing Compounds

[0190] Dilauryl-3,3′-thiodipropionate, distearyl-3,3′-thiodipropionate, ditetradecyl-3,3′-thiodipropionate, and the like.

[0191] (e) Organic Phosphorus-Containing Compounds

[0192] Triphenylphosphine, tri(nonylphenyl)phosphine, tri(dinonylphenyl)phosphine, tricresylphosphine, tri(2,4-dibutylphenoxy)phosphine and the like.

[0193] Suitable plasticizers for use in the layers of the photoreceptor include the following compounds but are not limited thereto:

[0194] (a) Phosphoric Acid Esters Plasticizers

[0195] Triphenyl phosphate, tricresyl phosphate, trioctyl phosphate, octyldiphenyl phosphate, trichloroethyl phosphate, cresyldiphenyl phosphate, tributyl phosphate, tri-2-ethylhexyl phosphate, triphenyl phosphate, and the like.

[0196] (b) Phthalic Acid Esters Plasticizers

[0197] Dimethyl phthalate, diethyl phthalate, diisobutyl phthalate, dibutyl phthalate, diheptyl phthalate, di-2-ethylhexyl phthalate, diisooctyl phthalate, di-n-octyl phthalate, dinonyl phthalate, diisononyl phthalate, diisodecyl phthalate, diundecyl phthalate, ditridecyl phthalate, dicyclohexyl phthalate, butylbenzyl phthalate, butyllauryl phthalate, methyloleyl phthalate, octyldecyl phthalate, dibutyl fumarate, dioctyl fumarate, and the like.

[0198] (c) Aromatic Carboxylic Acid Esters Plasticizers

[0199] Trioctyl trimellitate, tri-n-octyl trimellitate, octyl oxybenzoate, and the like.

[0200] (d) Dibasic Fatty Acid Esters Plasticizers

[0201] Dibutyl adipate, di-n-hexyl adipate, di-2-ethylhexyl adipate, di-n-octyl adipate, n-octyl-n-decyl adipate, diisodecyl adipate, dialkyl adipate, dicapryl adipate, di-2-etylhexyl azelate, dimethyl sebacate, diethyl sebacate, dibutyl sebacate, di-n-octyl sebacate, di-2-ethylhexyl sebacate, di-2-ethoxyethyl sebacate, dioctyl succinate, diisodecyl succinate, dioctyl tetrahydrophthalate, di-n-octyl tetrahydrophthalate, and the like.

[0202] (e) Fatty Acid Ester Derivatives

[0203] Butyl oleate, glycerin monooleate, methyl acetylricinolate, pentaerythritol esters, dipentaerythritol hexaesters, triacetin, tributyrin, and the like.

[0204] (f) Oxyacid Esters Plasticizers

[0205] Methyl acetylricinolate, butyl acetylricinolate, butylphthalylbutyl glycolate, tributyl acetylcitrate, and the like.

[0206] (g) Epoxy Plasticizers

[0207] Epoxydized soybean oil, epoxydized linseed oil, butyl epoxystearate, decyl epoxystearate, octyl epoxystearate, benzyl epoxystearate, dioctyl epoxyhexahydrophthalate, didecyl epoxyhexahydrophthalate, and the like.

[0208] (h) Dihydric Alcohol Esters Plasticizers

[0209] Diethylene glycol dibenzoate, triethylene glycol di-2-ethylbutyrate, and the like.

[0210] (i) Chlorine-Containing Plasticizers

[0211] Chlorinated paraffin, chlorinated diphenyl, methyl esters of chlorinated fatty acids, methyl esters of methoxychlorinated fatty acids, and the like.

[0212] (j) Polyester Plasticizers

[0213] Polypropylene adipate, polypropylene sebacate, acetylated polyesters, and the like.

[0214] (k) Sulfonic Acid Derivatives

[0215] P-toluene sulfonamide, o-toluene sulfonamide, p-toluene sulfoneethylamide, o-toluene sulfoneethylamide, toluene sulfone-N-ethylamide, p-toluene sulfone-N-cyclohexylamide, and the like.

[0216] (l) Citric Acid Derivatives

[0217] Triethyl citrate, triethyl acetylcitrate, tributyl citrate, tributyl acetylcitrate, tri-2-ethylhexyl acetylcitrate, n-octyldecyl acetylcitrate, and the like.

[0218] (m) Other Compounds

[0219] Terphenyl, partially hydrated terphenyl, camphor, 2-nitro diphenyl, dinonyl naphthalene, methyl abietate, and the like.

[0220] Suitable lubricants for use in the layers of the photoreceptor include the following compounds but are not limited thereto.

[0221] (a) Hydrocarbon Compounds

[0222] Liquid paraffins, paraffin waxes, micro waxes, low molecular weight polyethylenes, and the like.

[0223] (b) Fatty Acid Compounds

[0224] Lauric acid, myristic acid, palmitic acid, stearic acid, arachidic acid, behenic acid, and the like.

[0225] (c) Fatty Acid Amide Compounds

[0226] Stearic acid amide, palmitic acid amide, oleic acid amide, methylenebisstearamide, ethylenebisstearamide, and the like.

[0227] (d) Ester Compounds

[0228] Lower alcohol esters of fatty acids, polyhydric alcohol esters of fatty acids, polyglycol esters of fatty acids, and the like.

[0229] (e) Alcohol Compounds

[0230] Cetyl alcohol, stearyl alcohol, ethylene glycol, polyethylene glycol, polyglycerol, and the like.

[0231] (f) Metallic Soaps

[0232] Lead stearate, cadmium stearate, barium stearate, calcium stearate, zinc stearate, magnesium stearate, and the like.

[0233] (g) Natural Waxes

[0234] Carnauba wax, candelilla wax, beeswax, spermaceti, insect wax, montan wax, and the like.

[0235] (h) Other Compounds

[0236] Silicone compounds, fluorine compounds, and the like.

[0237] Suitable ultraviolet absorbing agents for use in the layers of the photoreceptor include the following compounds but are not limited thereto.

[0238] (a) Benzophenone Compounds

[0239] 2-hydroxybenzophenone, 2,4-dihydroxybenzophenone, 2,2′,4-trihydroxybenzophenone, 2,2′,4,4′-tetrahydroxybenzophenone, 2,2′-dihydroxy-4-methoxybenzophenone, and the like.

[0240] (b) Salicylate Compounds

[0241] Phenyl salicylate, 2,4-di-t-butylphenyl-3,5-di-t-butyl-4-hydroxybenzoate, and the like.

[0242] (c) Benzotriazole Compounds

[0243] (2′-hydroxyphenyl)benzotriazole, (2′-hydroxy-5′-methylphenyl)benzotriazole and (2′-hydroxy-3′-t-butyl-5′-methylphenyl)-5-chlorobenzotriazole.

[0244] (d) Cyano Acrylate Compounds

[0245] Ethyl-2-cyano-3,3-diphenyl acrylate, methyl-2-carbomethoxy-3-(paramethoxy) acrylate, and the like.

[0246] (e) Quenchers (Metal Complexes)

[0247] Nickel(2,2′-thiobis(4-t-octyl)phenolate)-n-butylamine, nickeldibutyldithiocarbamate, cobaltdicyclohexyldithiophosphate, and the like.

[0248] (f) HALS (Hindered Amines)

[0249] Bis(2,2,6,6-tetramethyl-4-piperidyl)sebacate, bis(1,2,2,6,6-pentamethyl-4-piperidyl)sebacate, 1-[2-{3-(3,5-di-t-butyl-4-hydroxyphenyl)propionyloxy}ethyl]-4-{3-(3,5-di-t-butyl-4-hydroxyphenyl)propionyloxy}-2,2,6,6-tetrametylpyridine, 8-benzyl-7,7,9,9-tetramethyl-3-octyl-1,3,8-triazaspiro[4,5]undecane-2,4-dione, 4-benzoyloxy-2,2,6,6-tetramethylpiperidine, and the like.

[0250] Next, the image forming method and apparatus of the present invention will be explained, referring to drawings. Specifically, the image forming method typified by an electrophotographic image forming method and the image forming apparatus typified by an electrophotographic image forming apparatus will be explained.

[0251]
FIG. 6 is a schematic view for explaining the electrophotographic method and apparatus of the present invention, and a modified embodiment as mentioned below belongs to the present invention.

[0252] In FIG. 6, a photoreceptor 1 includes at least a photosensitive layer and the most surface layer includes a filler. The photoreceptor 1 is drum-shaped, and may be sheet-shaped or endless-belt shaped. Any known chargers such as a corotron, a scorotron, a solid state charger and a charging roller can be used for a charger 3, a pre-transfer charger 7, a transfer charge 10, a separation charger 11 and a pre-cleaning charger 13.

[0253] The above-mentioned chargers can be used as transfer means, and typically a combination of the transfer charger and the separation charger is effectively used.

[0254] Suitable light sources for use in the imagewise light irradiating device 5 and the discharging lamp 2 include fluorescent lamps, tungsten lamps, halogen lamps, mercury lamps, sodium lamps, light emitting diodes (LEDs), laser diodes (LDs), light sources using electroluminescence (EL) and the like. In addition, in order to obtain light having a desired wave length range, filters such as sharp-cut filters, band pass filters, near-infrared cutting filters, dichroic filters, interference filters, color temperature converting filters and the like can be used.

[0255] The above-mentioned light sources can be used for not only the processes mentioned above and illustrated in FIG. 6, but also other processes, such as a transfer process, a discharging process, a cleaning process, a pre-exposure process, which include light irradiation to the photoreceptor.

[0256] When the toner image formed on the photoreceptor 1 by a developing unit 6 is transferred onto a transfer sheet 9, all of the toner image are not transferred thereon, and residual toner particles remain on the surface of the photoreceptor 1. The residual toner is removed from the photoreceptor by a fur brush 14 and a blade 15. The residual toner remaining on the photo receptor 1 can be removed by only a cleaning brush. Suitable cleaning brushes include known cleaning brushes such as fur brushes and mag-fur brushes.

[0257] When the photoreceptor which is previously charged positively is exposed to imagewise light, an electrostatic latent image having a positive or negative charge is formed on the photoreceptor. When the latent image having a positive charge is developed with a toner having a negative charge, a positive image can be obtained. In contrast, when the latent image having a positive charge is developed with a toner-having a positive charge, a negative image (i.e., a reversal image) can be obtained.

[0258] As the developing method, known developing methods can be used. In addition, as the discharging methods, known discharging methods can be also used.

[0259]
FIG. 7 is a schematic view for explaining another embodiment of the electrophotographic apparatus and method of the present invention. A photoreceptor 21 includes at least a photosensitive layer and the most surface layer includes a filler. The photoreceptor is rotated by rollers 22a and 22b. Charging using a charger 23, imagewise exposure using an imagewise light irradiating device 24, developing using a developing unit (not shown), transferring using a transfer charger 25, pre-cleaning using a light source 26, cleaning using a cleaning brush 27 and discharging using a discharging light source 28 are repeatedly performed. In FIG. 7, the pre-cleaning light irradiating is performed from the side of the substrate of the photoreceptor 21. In this case, the substrate has to be light-transmissive.

[0260] The image forming apparatus of the present invention is not limited to the image forming units as shown in FIGS. 6 and 7. For example, although the pre-cleaning light irradiation is performed from the substrate side in FIG. 7, the pre-cleaning light irradiating operation can be performed from the photosensitive layer side of the photoreceptor. In addition, the light irradiation in the light image irradiating process and the discharging process may be performed from the substrate side of the photoreceptor

[0261] As light irradiation processes, the imagewise irradiation process, pre-cleaning irradiation process, and discharging light irradiation are illustrated. In addition, a pre-transfer light irradiation and a preliminary light irradiation before the imagewise light irradiation, and other known light irradiation processes may also be performed on the photoreceptor.

[0262] The above-mentioned image forming unit may be fixedly set in a copier, a facsimile or a printer. However, the image forming unit may be set therein as a process cartridge. The process cartridge means an image forming unit (or device) which includes a photoreceptor, a charger, an imagewise light irradiator, an image developer, an image transferer, a cleaner, and a discharger. Various process cartridges can be used in the present invention. FIG. 8 illustrates an embodiment of the process cartridge.

[0263] Having generally described this invention, further understanding can be obtained by reference to certain specific examples which are provided herein for the purpose of illustration only and are not intended to be limiting. In the descriptions in the following examples, the numbers represent weight ratios in parts, unless otherwise specified.

EXAMPLES

Examples 1 to 26 and Comparative Examples 1 to 8

[0264] An undercoat coating liquid, a charge generation coating liquid and charge transport coating liquid, which have the following formulations, were coated in this order on an aluminium cylinder by a dip coating method and dried to prepare photoreceptors 1 to 34 having an undercoat layer of 3.5 μm thick, a CGL of 0.2 μm thick, a CTL of 23 μm thick.

2Undercoat layer coating liquidTitanium dioxide powder400Melamine resin65Alkyd resin1202-butanone400

[0265]

3

CGL coating liquid

Fluorenone bisazo pigment
12

having the following formula (68)

(68)

106

Polyvinyl butyral
5

2-butanone
200

Cyclohexanone
400

[0266]

4

CTL coating liquid

Polycarbonate resin
10

(Z polyca from Teijin Chemicals Ltd.)

The compounds having an alkylamino group
1

No. 1 to 34

CTM having the following formula (69)
9

and an oxidation potential of 0.76

(V vs. SCE)

(69)

107

Tetrahydrofuran
100

[0267] After the thus prepared each photoreceptor 1 to 34 was installed in a process cartridge for electrophotography and the cartridge was installed in a modified copier imagio MF2200 from Ricoh Company, ltd. having a scorotron type corona charger an imagewise light source of a LD having a wavelength of 655 nm, in which the photoreceptor had a dark portion potential of 800 (−V) and an image surface illuminance of 0.45 (μj/cm2), a bright portion potential was measured. Further, 100,000 images were continuosly produced, and the initial image and the image after 100,000 images were produced were evaluated. The results are shown in Table 1. In addition, a graph in which a difference (ΔE) between an oxidation potential of the compound having an alkylamino group and that of the CTM and the initial bright portion potential (VL) of the photoreceptor are plotted is shown in FIG. 9.

5TABLE 1AfterΔEInitial100,000No. of(V vs.VLImageImagecompoundSCE)(−V)qualityqualityCom. Ex. 11−0.240479Low imageLow imagedensitydensityEx. 12−0.155133GoodGoodCom. Ex. 23−0.260709Image was not—producedCom. Ex. 34−0.320769Image was not—producedEx. 25−0.105117GoodGoodCom. Ex. 46−0.240571Image was not—producedCom. Ex. 57−0.210385Low imageLow imagedensitydensityEx. 38−0.110124GoodGoodEx. 49−0.120115GoodGoodEx. 510−0.100113GoodGoodEx. 611−0.100130GoodGoodEx. 712−0.135112GoodGoodEx. 8130.115120GoodGoodEx. 914−0.100102GoodGoodEx. 10150.020105GoodGoodEx. 1116−0.010115GoodGoodEx. 1217−0.160150GoodGoodEx. 1318−0.135131GoodGoodCom. Ex. 619−0.365780Image was not—producedEx. 1420−0.100105GoodGoodEx. 1521−0.140113GoodGoodCom. Ex. 722−0.215318GoodLow imagedensityEx. 16230.000122GoodGoodCom. Ex. 824−0.300785Image was not—producedEx. 17250.025101GoodGoodEx. 1826−0.020101GoodGoodEx. 1927−0.01096GoodGoodEx. 2028−0.160109GoodGoodEx. 21290.09576GoodGoodEx. 2230−0.08078GoodGoodEx. 2331−0.14083GoodGoodEx. 2432−0.010102GoodGoodEx. 25330.02095GoodGoodEx. 26340.010105GoodGood

Examples 27 to 52 and Comparative Examples 9 to 16

[0268] The procedures for preparation and evaluation of the photoreceptor in Example 1 were repeated to prepare and evaluate photoreceptors 35 to 68 except for changing 9 parts of the CTM and 10 parts of the polycarbonate resin included in the CTL binder resin to 19 parts of a charge transport polymer material having the following formula (70) and an oxidation potential of 0.780 (V. vs. SCE). The results are shown in Table 2 and FIG. 10.

6TABLE 2(70)

108

InitialNo. of compoundΔE (V vs. SCE)VL (−V)Image qualityAfter 100,000 Image qualityCom. Ex. 91−0.260519Low image densityImage was notproducedEx. 272−0.175168GoodGoodCom. Ex. 103−0.260719Image was not produced—Com. Ex. 114−0.280779Image was not produced—Ex. 285−0.340137GoodGoodCom. Ex. 126−0.125611Image was not produced—Com. Ex. 137−0.260285GoodLow imagedensityEx. 298−0.230134GoodGoodEx. 309−0.130147GoodGoodEx. 3110−0.140143GoodGoodEx. 3211−0.120160GoodGoodEx. 3312−0.120147GoodGoodEx. 3413−0.155160GoodGoodEx. 3514−0.120102GoodGoodEx. 36150.000125GoodGoodEx. 3716−0.030130GoodGoodEx. 3817−0.180180GoodGoodEx. 3918−0.155161GoodGoodCom. Ex. 1419−0.385800Image was not produced—Ex. 4020−0.120123GoodGoodEx. 4121−0.160137GoodGoodCom. Ex. 1522−0.235349GoodLow imagedensityEx. 4223−0.020152GoodGoodCom. Ex. 1624−0.320772Image was not produced—Ex. 43250.005131GoodGoodEx. 4426−0.040131GoodGoodEx. 4527−0.030122GoodGoodEx. 4628−0.180129GoodGoodEx. 47290.075128GoodGoodEx. 4830−0.100106GoodGoodEx. 4931−0.160113GoodGoodEx. 5032−0.030113GoodGoodEx. 51330.000121GoodGoodEx. 5234−0.010135GoodGood

Examples 53 to 83 and Comparative Examples 17 to 19

[0269] The procedures for preparation and evaluation of the photoreceptor in Example 1 were repeated to prepare and evaluate photoreceptors 69 to 102 except for changing the CGL coating liquid and CTL coating liquid to a CGL coating liquid and a CTL coating liquid having the following formulations respectively. The results are shown in Table 3 and FIG. 12.

7CGL coating liquidOxotitaniumphthalocyanine8having the powder XD spectrum in FIG. 11Polyvinylbutyral52-butanone400

[0270]

8

TABLE 3

CGL coating liquid

Oxotitaniumphthalocyanine
8

having the powder XD spectrum in FIG. 11

Polyvinylbutyral
5

2-butanone
400

CTL coating liquid

Polycarbonate resin
10

(Z polyca from Teijin Chemicals Ltd.)

The compounds having an alkylamino group
1

No. 1 to 34

CTM having the following formula (71)
7

and an oxidation potential of 0.675

(V vs. SCE)

(71)

109

Toluene
70

ΔE
Initial
After

No. of
(V vs.
VL

100,000

compound
SCE)
(−V)
Image quality
Image quality

Ex. 53
1
−0.155
94
Good
Good

Ex. 54
2
−0.070
82
Good
Good

Ex. 55
3
−0.175
112
Good
Good

Com. Ex.
4
−0.235
423
Low image
Low image

17

density
density

Ex. 56
5
−0.020
108
Good
Good

Ex. 57
6
−0.155
129
Good
Good

Ex. 58
7
−0.125
123
Good
Good

Ex. 59
8
−0.025
956
Good
Good

Ex. 60
9
−0.035
116
Good
Good

Ex. 61
10
−0.015
94
Good
Good

Ex. 62
11
−0.015
78
Good
Good

Ex. 63
12
−0.050
65
Good
Good

Ex. 64
13
0.200
105
Good
Good

Ex. 65
14
−0.015
83
Good
Good

Ex. 66
15
0.105
64
Good
Good

Ex. 67
16
0.075
58
Good
Good

Ex. 68
17
−0.075
101
Good
Good

Ex. 69
18
−0.050
73
Good
Good

Com. Ex.
19
−0.280
633
Image was not
—

18

produced

Ex. 70
20
−0.015
58
Good
Good

Ex. 71
21
−0.055
87
Good
Good

Ex. 72
22
−0.130
97
Good
Low image

density

Ex. 73
23
0.085
81
Good
Good

Com. Ex.
24
−0.215
382
Low image
Low image

19

density
density

Ex. 74
25
0.110
68
Good
Good

Ex. 75
26
0.065
60
Good
Good

Ex. 76
27
0.075
100
Good
Good

Ex. 77
28
−0.075
95
Good
Good

Ex. 78
29
0.180
110
Good
Good

Ex. 79
30
0.005
97
Good
Good

Ex. 80
31
−0.055
73
Good
Good

Ex. 81
32
0.075
85
Good
Good

Ex. 82
33
0.105
55
Good
Good

Ex. 83
34
0.095
102
Good
Good

Examples 84 to 109 and Comparative Examples 20 to 27

[0271] An undercoat coating liquid, a charge generation coating liquid and charge transport coating liquid, which have the following formulations, were coated in this order on an aluminium cylinder by a dip coating method and dried form an undercoat layer of 3.5 μm thick, a CGL of 0.2 μm thick, a CTL of 23 μm thick on the aluminium cylinder.

9Undercoat layer coating liquidTitanium dioxide powder400Melamine resin65Alkyd resin1202-butanone400

[0272]

10

CGL coating liquid

Oxotitaniumphthalocyanine
8

having the powder XD spectrum in FIG. 13

Polyvinylbutyral
5

2-butanone
400

[0273]

11

CTL coating liquid

Polycarbonate resin
10

(Z polyca from Teijin Chemicals Ltd.)

CTM having the following formula (72)
9

(72)

110

Tetrahydrofuran
100

[0274] Further, a protection layer having a thickness of about 4 μm is formed on the CTL by spraying a protection layer coating liquid having the following formulation onto the CTL to prepare photoreceptors 103 to 136. The evaluation results of the photoreceptors are shown in Table 4 and FIG. 14.

12Protection layer coating liquidAlumina having an average primary2particle diameter of 0.3 μm fromSumitomo Chemical Co., Ltd.The compounds having an alkylamino group0.5No. 1 to 34Unsaturated polycarbonate polymer solution0.02having an acid value of 180 mg KOH/g fromBYK Chemie GmbHCTM having the following formula (73)3.5and an oxidation potential of 0.76(V vs. SCE)(73)

111

Polycarbonate resin6(Z polyca from Teijin Chemicals Ltd.)Tetrahydrofuran220Cyclohexanone80

[0275]

13

TABLE 4

ΔE
Initial
After

No. of
(V vs.
VL

100,000

compound
SCE)
(−V)
Image quality
Image quality

Com. Ex.
1
−0.240
600
Image was not
—

20

produced

Com. Ex.
2
−0.155
237
Good
Good

21

Com. Ex.
3
−0.260
720
Image was not
—

22

produced

Com. Ex.
4
−0.320
787
Image was not
—

23

produced

Ex. 84
5
−0.105
221
Good
Good

Com. Ex.
6
−0.240
682
Image was not
—

24

produced

Ex. 85
7
−0.210
496
Low image
Low image

density
density

Ex. 86
8
−0.110
220
Good
Good

Ex. 87
9
−0.120
221
Good
Good

Ex. 88
10
−0.100
221
Good
Good

Ex. 89
11
−0.100
222
Good
Good

Ex. 90
12
−0.135
262
Good
Good

Ex. 91
13
0.115
202
Good
Good

Ex. 92
14
−0.100
252
Good
Good

Ex. 93
15
0.020
211
Good
Good

Ex. 94
16
−0.010
218
Good
Good

Ex. 95
17
−0.160
248
Good
Good

Ex. 96
18
−0.135
235
Good
Good

Com. Ex.
19
−0.365
765
Image was not
—

25

produced

Ex. 97
20
−0.100
255
Good
Good

Ex. 98
21
−0.140
265
Good
Good

Com. Ex.
22
−0.215
448
Good
Low image

26

density

Ex. 99
23
0.000
227
Good
Good

Com. Ex.
24
−0.300
789
Image was not
—

27

produced

Ex. 100
25
0.025
216
Good
Good

Ex. 101
26
−0.020
203
Good
Good

Ex. 102
27
−0.010
199
Good
Good

Ex. 103
28
−0.160
216
Good
Good

Ex. 104
29
0.095
184
Good
Good

Ex. 105
30
−0.080
184
Good
Good

Ex. 106
31
−0.140
198
Good
Good

Ex. 107
32
−0.010
204
Good
Good

Ex. 108
33
0.020
174
Good
Good

Ex. 109
34
0.010
187
Good
Good

Comparative Example 28

[0276] The procedures for preparation and evaluation of the photoreceptor in Example 1 were repeated to prepare and evaluate a comparative photoreceptors 1 except for not adding the compound having an alkylamino group into the CTL coating liquid. The results are shown in Table 5.

Comparative Example 29

[0277] The procedures for preparation and evaluation of the photoreceptor in Example 1 were repeated to prepare and evaluate a comparative photoreceptors 2 except for changing the compound having an alkylamino group into a hindered phenol antioxidant having the following formula (74). The results are shown in Table 5.

14TABLE 5(74)

112

Compara-tivePhoto-InitialAfterreceptorVL100,000No.(-V)Image qualityImage qualityCom. Ex.1100GoodImage resolution28lowered (moderate)Com. Ex.2545Low imageImage density lowered29density(large) and illegible

[0278] The results show that an electrophotographic photoreceptor including an electroconductive substrate and a photosensitive layer on the electroconductive substrate, wherein the photosensitive layer includes at least a compound having a substituted or unsubstituted alkylamino group and a charge transport material, and wherein an oxidation potential (Eox1) of the substituted or unsubstituted alkylamino group and an oxidation potential (Eox2) of the charge transport material satisfy the following relationship (I) has a high sensitivity and stably produces high-quality images even after 100,000 images are produced.

Eox1−Eox2≧−0.2 (I)

[0279] On the other hand, when out of the above-mentioned relationship, the bright portion of the resultant photoreceptor is extremely high from the beginning. Therefore, the image density deteriorates and no image can be produced.

[0280] The deterioration of image resolution of the images produced by the comparative photoreceptor 1 in Comparative Example 28 due to repeated use is worse than that of the images produced by the photoreceptor of the present invention because of not including the compound having an alkylamino group effective for oxidizing gases causing blurred images.

[0281] Further, the comparative photoreceptor 2 in Comparative Example 29 including only a typical antioxidant in its CTL has a high bright portion potential from the beginning and does not produce good images.

[0282] This document claims priority and contains subject matter related to Japanese Patent Application No. 2003-049975 filed on Feb. 26, 2003 incorporated herein by reference.

[0283] Having now fully described the invention, it will be apparent to one of ordinary skill in the art that many changes and modifications can be made thereto without departing from the spirit and scope of the invention as set forth therein.

Electrophotographic photoreceptor, and image forming method, image forming apparatus and process cartridge for image forming apparatus using the electrophotographic photoreceptor

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