Claims
- 1. An electrophotographic photoreceptor which has an electrophotographic photoreceptive layer containing a charge generating material and a charge transporting material, said charge generating material being a compound of the following general formula (I) or (II): ##STR11## wherein: (i) m is 0, and n is 0, 1, or 2,
- (ii) R.sup.1 to R.sup.5 may be the same or different, and each is a hydrogen atom, an alkyl group, an aralkyl group, an aryl group or a monovalent group produced by removing one hydrogen atom from a heterocyclic ring,
- (iii) A.sup.1 is substituted phenyl group, a monovalent group produced by removing one hydrogen atom from a monocyclic 5-membered hetero-ring, a condensed 5-membered hetero-ring or a condensed 6-membered hetero-ring, which have the following structural formulae, respectively; ##STR12## wherein R.sup.6 is an alkoxy group, an aralkyloxy group or a substituted amino group of the formula ##STR13## R.sup.12 and R.sup.13 each is a substituted or non-substituted alkyl group or a substituted or non-substituted phenyl group, or they may combine with each other and form a nitrogen-containing hetero-ring, and they may be the same or different; R.sup.7 and R.sup.8 may be the same or different, and each is a hydrogen atom, a halogen atom, an alkyl group or a lower alkoxy group; Y and Z are S, O or N--R.sup.14, wherein R.sup.14 is an alkyl group having 1 to 4 carbon atoms, and they may be the same or different; R.sup.9 and R.sup.10 may be the same or different, and each is a hydrogen atom, an alkyl group or an alkoxy group, or they may combine with each other and form a benzene ring or a naphthalene ring; and R.sup.11 is a hydrogen atom, an alkyl group, an alkoxy group, an aryloxy group, an acyl group, an alkoxycarcarbonyl group, an aryloxycarbonyl group, a halogen atom, a monoalkylamino group, a dialkylamino group, an amido group or a nitro group, which groups each may be substituted;
- (iv) A.sup.2 is a divalent group produced by removing two hydrogen atoms attached to the same carbon from a heterocyclic ring selected from a group consisting of imidazoles, 3H-indoles, thiazoles, benzothiazoles, naphthothiazoles, thianaphtheno-7',6',4,5-thiazoles, oxazoles, benzoxazoles, naphthooxazoles, selenazoles, benzoselenazoles, naphthoselenazoles, thiazolines, quinolines, isoquinolines, benzimidazoles and pyridines, and
- (v) B.sup.1 is a divalent group selected from substituents of the following structural formulae; ##STR14## wherein R.sup.15 and R.sup.16 each is an alkyl group or an aryl group; X is an oxygen atom or a sulfur atom; and B.sup.2 is a cyano group, a carboxyl group, an alkoxycarbonyl group, an aryloxycarbonyl group, an alkylsulfonyl group, an alkylcarbonyl group, an arylcarbonyl group, a nitro group, a nitro-substituted aryl group, a sulfo group, a trifluoromethylsulfonyl group, a carbamoyl group, an alkylcarbamoyl group, an arylcarbamoyl group or an acyl group whose carbonyl group is attached to a monovalent group produced by removing one hydrogen atom from a heterocyclic ring, and said charge transporting material is at least one compound selected from the group consisting of triphenylamine derivatives, polyarylalkane derivatives, pyrazoline derivatives and hydrazone derivatives.
- 2. The electrophotographic photoreceptor described in claim 1, wherein said electrophotographic photoreceptive layer is a single layer containing both said charge generating material and said charge transporting material.
- 3. The electrophotographic photoreceptor described in claim 1, wherein said electrophotographic photoreceptive layer is comprised of two layers, a first layer being a charge generating layer containing said charge generating material, and a second layer being a charge transporting layer containing said charge transporting material.
- 4. An electrophotographic photoreceptor as claimed in claim 2, wherein the electrophotographic photoreceptive layer has a thickness of from 3 .mu.m to 50 .mu.m.
- 5. An electrophotographic photoreceptor as claimed in claim 4, wherein the thickness of the electrophotographic photoreceptive layer is 5 .mu.m to 20 .mu.m.
- 6. An electrophotographic photoreceptor as claimed in claim 3, wherein the charge-generating layer has a thickness of 5 .mu.m or less.
- 7. An electrophotographic photoreceptor as claimed in claim 6, wherein the charge-generating layer has a thickness of 2 .mu.m or less.
- 8. An electrophotographic photoreceptor as claimed in claim 3, wherein the charge transporting layer has a thickness of 3 .mu.m to 50 .mu.m.
- 9. An electrophotographic photoreceptor as claimed in claim 8, wherein the thickness of the charge transporting layer is from 5 .mu.m to 20 .mu.m.
- 10. An electrophotographic photoreceptor as claimed in claim 2, wherein the charge generating material is dispersed homogeneously or heterogeneously in a charge transporting medium comprising a charge transporting material and a binder and wherein the charge transporting material is from 10 to 150 weight percent with respect to the binder and further wherein the compound represented by the general formula (I) or (II) is contained in an amount of 1 to 150 weight percent with respect to the binder.
- 11. An electrophotographic photoreceptor as claimed in claim 10, wherein the charge transporting material is contained in an amount of 30 to 100 weight percent with respect to the weight of the binder and the compound represented by the general formula (I) or (II) is contained in an amount of 5 to 50 weight percent with respect to the binder.
- 12. An electrophotographic photoreceptor as claimed in claim 3, wherein the charge transporting material is contained in a binder and said charge transporting material is present in an amount of 10 to 150 weight percent based on the weight of the binder.
- 13. An electrophotographic photoreceptor as claimed in claim 12, wherein the charge transporting material is contained in an amount of 30 to 100 weight percent based on the weight of the binder.
- 14. An electrophotographic photoreceptor as claimed in claim 3, wherein the charge generating layer comprises the charge generating material dispersed in the binder present in an amount of 10 parts by weight or less per 1 part by weight of the compound represented by the general formula (I) or (II).
- 15. An electrophotographic photoreceptor as claimed in any of claims 1, 2, or 3, wherein a plurality of compounds represented by the general formula (I) or (II) are present.
- 16. An electrophotographic photoreceptor as claimed in any of claims 1, 2, or 3, further comprising sensitizer dyes.
- 17. An electrophotographic photoreceptor as claimed in claim 1, further comprising an adhesive layer or barrier layer positioned between the photoreceptive layer and the conductive surface.
- 18. An electrophotographic photoreceptor as claimed in claim 17, wherein the adhesive layer or the barrier layer has a thickness of 1 .mu.m or less.
- 19. An electrophotographic photoreceptor as claimed in claim 1, wherein said charge transporting material is the triphenylamine derivatives.
- 20. An electrophotographic photoreceptor as claimed in claim 1, wherein said charge transporting material is the polyarylalkane derivatives.
- 21. An electrophotographic photoreceptor as claimed in claim 1, wherein said charge transporting material is the pyrazoline derivatives.
- 22. An electrophotographic photoreceptor as claimed in claim 1, wherein said charge transporting material is the hydrazone derivatives.
Priority Claims (1)
Number |
Date |
Country |
Kind |
56-110423 |
Jul 1981 |
JPX |
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Parent Case Info
This is a continuation of application Ser. No. 628,135, filed July 11, 1984, now abandoned, which is a continuation of U.S. Ser. No. 398,488, filed July 15, 1982, now abandoned.
US Referenced Citations (4)
Foreign Referenced Citations (3)
Number |
Date |
Country |
3117701 |
Jan 1982 |
DEX |
7503582 |
Jul 1975 |
NLX |
1337228 |
Nov 1973 |
GBX |
Continuations (2)
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Number |
Date |
Country |
Parent |
628135 |
Jul 1984 |
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Parent |
398488 |
Jul 1982 |
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