Claims
- 1. An electrophotographic photosensitive member comprising a conductive support, a photosensitive layer and a protective layer, said protective layer containing resin formed by photosetting a photoinitiator type acrylic monomer, and said photosensitive layer containing at least one compound selected from the group consisting of (A), (B) and (C) below:
- (A) styryl compounds having a structure expressed by the following formula (1) and a melting point not higher than 135.degree. C.; ##STR191## wherein Ar.sup.1 and Ar.sup.2 are aromatic ring groups, Ar.sup.3 is a bivalent aromatic ring group or a bivalent heterocyclic group, R.sup.1 is an alkyl group or an aromatic ring group, R.sup.2 is a hydrogen atom, an alkyl group or an aromatic ring group, and n.sub.1 is 1 or 2, and R.sup.1 and R.sup.2 may be joined to form a ring when n.sub.1 =1:
- (B) triarylamine compounds having a structure expressed by the following formula (2) and a melting point not higher than 150.degree. C.; ##STR192## wherein Ar.sup.4, Ar.sup.5 and Ar.sup.6 are each an aromatic ring group or a heterocyclic group:
- (c) hydrazone compounds having a structure expressed by the following formula (3) and a melting point not higher than 155.degree. C.; ##STR193## wherein R.sup.3 Is a hydrogen atom or an alkyl group, R.sup.4 and R.sup.5 are alkyl groups, aralkyl groups or aromatic ring groups, n.sub.2 is 1 or 2, A is an aromatic ring group, a heterocyclic group or --CH.dbd.C(R.sup.6)R.sup.7 (R.sup.6 and R.sup.7 are hydrogen atoms, aromatic ring groups or heterocyclic groups provided that R.sup.6 and R.sup.7 are not both hydrogen atoms at the same time).
- 2. An electrophotographic photosensitive member according to claim 1, wherein said compound is (A).
- 3. An electrophotographic photosensitive member according to claim 1, wherein said compound is (B).
- 4. An electrophotographic photosensitive member according to claim 1, wherein said compound is (C).
- 5. An electrophotographic photosensitive member according to claim 1, wherein said photoinitial type acrylic monomer has three or more functional groups per molecule.
- 6. An electrophotographic photosensitive member according to claim 1, wherein said photoinitial type acrylic monomer has functional groups not less than 0.004 mol/g.
- 7. An electrophotographic photosensitive member according to claim 1, wherein said protective layer contains conductive particles.
- 8. An electrophotographic photosensitive member according to claim 7, wherein said conductive particles are metal oxide particles.
- 9. An electrophotographic photosensitive member according to claim 1, wherein said protective layer contains a coupling agent and/or an anti-oxidizing agent.
- 10. An electrophotographic photosensitive member according to claim 1, wherein said photosensitive layer comprises a charge generating layer and a charge transporting layer.
- 11. An electrophotographic photosensitive member according to claim 10, wherein said electrophotographic photosensitive member comprises a conductive support, a charge generating layer and a charge transporting layer in this order.
- 12. An electrophotographic photosensitive member according to claim 10, wherein said electrophotographic photosensitive member comprises a conductive support, a charge transporting layer and a charge generating layer in this order.
- 13. An electrophotographic photosensitive member according to claim 1, wherein said photosensitive layer is a single layer.
- 14. An electrophotographic photosensitive member according to claim 1, wherein said electrophotographic photosensitive member has an underlying layer between said conductive support and said photosensitive layer.
- 15. An electrophotographic apparatus comprising an electrophotographic photosensitive member, an electrostatic latent image forming means, a means for developing an electrostatic latent image formed by said electrostatic latent image forming means, and a means for transferring a developed image to a transfer material,
- said electrophotographic photosensitive member comprising a conductive support, a photosensitive layer and a protective layer, said protective layer containing resin formed by photosetting a photoinitial type acrylic monomer, and said photosensitive layer containing at least one compound selected from the group consisting of (A), (B) and (C) below:
- (A) styryl compounds having a structure expressed by the following formula (1) and a melting point not higher than 135.degree. C.; ##STR194## wherein Ar.sup.1 and Ar.sup.2 are aromatic ring groups, Ar.sup.3 is a bivalent aromatic ring group or a bivalent heterocyclic group, R.sup.1 is an alkyl group or an aromatic ring group, R.sup.2 is a hydrogen atom, an alkyl group or an aromatic ring group, and n.sub.1 is 1 or 2, R.sup.1 and R.sup.2 may be joined to form a ring when n.sub.1 =1:
- (B) triarylamine compounds having a structure expressed by the following formula (2) and a melting point not higher than 150.degree. C.; ##STR195## wherein Ar.sup.4, Ar.sup.5 and Ar.sup.6 are each an aromatic ring group or a heterocyclic group:
- (c) hydrazone compounds having a structure expressed by the following formula (3) and a melting point not higher than 155.degree. C.; ##STR196## wherein R.sup.3 is a hydrogen atom or an alkyl group, R.sup.4 and R.sup.5 are alkyl groups, aralkyl groups or aromatic ring groups, n.sub.2 is 1 or 2, A is an aromatic ring group, a heterocyclic group or --CH.dbd.C(R.sup.6)R.sup.7 (R.sup.6 and R.sup.7 are hydrogen atoms, aromatic ring groups or heterocyclic groups, provided that R.sup.6 and R.sup.7 are not both hydrogen atoms at the same time).
- 16. An electrophotographic apparatus according to claim 15, wherein said compound is (A).
- 17. An electrophotographic apparatus according to claim 15, wherein said compound is (B).
- 18. An electrophotographic apparatus according to claim 15, wherein said compound is (C).
- 19. A device unit comprising an electrophotographic photosensitive member, and at least one means selected from the group consisting of charging means, developing means and cleaning means,
- said electrophotographic photosensitive member comprising a conductive support, a photosensitive layer and a protective layer, said protective layer containing resin formed by photosetting a photoinitial type acrylic monomer, and said photosensitive layer containing at least one compound selected from the group consisting of (A), (B) and (C) below;
- (A) styryl compounds having a structure expressed by the following formula (1) and a melting point not higher than 135.degree. C.; ##STR197## wherein Ar.sup.1 and Ar.sup.2 are aromatic ring groups, Ar.sup.3 is a bivalent aromatic ring group or a bivalent heterocyclic group, R.sup.1 is an alkyl group or an aromatic ring group, R.sup.2 is a hydrogen atom, an alkyl group or an aromatic ring group, and n.sub.1 is 1 or 2, R.sup.1 and R.sup.2 may be joined to form a ring when n.sub.1 =1:
- (B) triarylamine compounds having a structure expressed by the following formula (2) and a melting point not higher than 150.degree. C.; ##STR198## wherein Ar.sup.4, Ar.sup.5 and Ar.sup.6 are each an aromatic ring group or a heterocyclic group:
- (C) hydrazone compounds having a structure expressed by the following formula (3) and a melting point not higher than 155.degree. C.; ##STR199## wherein R.sup.3 is a hydrogen atom or an alkyl group, R.sup.4 and R.sup.5 are alkyl groups, aralkyl groups or aromatic ring groups, n.sub.2 is 1 or 2, A is an aromatic ring group, a heterocyclic group or --CH.dbd.C(R.sup.6)R.sup.7 (R.sup.6 and R.sup.7 are hydrogen atoms, aromatic ring groups or heterocyclic groups, provided that R.sup.6 and R.sup.7 are not both hydrogen atoms at the same time),
- said unit supporting said electrophotographic photosensitive member and said at least one means selected from the group consisting of charging means, developing means and cleaning means together, and being attached to an apparatus body in a detachable manner.
- 20. A device unit according to claim 19, wherein said compound is (A).
- 21. A device unit according to claim 19, wherein said compound is (B).
- 22. A device unit according to claim 19, wherein said compound is (C).
- 23. A facsimile machine comprising an electrophotographic apparatus and means for receiving image information from a remote terminal,
- said electrophotographic apparatus having an electrophotographic photosensitive member,
- said electrophotographic photosensitive member comprising a conductive support, a photosensitive layer and a protective layer, said protective layer containing resin formed by photosetting a photoinitiator type acrylic monomer, and said photosensitive layer containing at least one compound selected from the group consisting of (A), (B) and (C) below;
- (A) styryl compounds having a structure expressed by the following formula (1) and a melting point not higher than 135.degree. C.; ##STR200## wherein Ar.sup.1 and Ar.sup.2 are aromatic ring groups, Ar.sup.3 is a bivalent aromatic ring group or a bivalent heterocyclic group, R.sup.1 is an alkyl group or an aromatic ring group, R.sup.2 is a hydrogen atom, an alkyl group or an aromatic ring group, and n.sub.1 is 1 or 2, R.sup.1 and R.sup.2 may be joined to form a ring when n.sub.1 =1:
- (B) triarylamine compounds having a structure expressed by the following formula (2) and a melting point not higher than 150.degree. C.; ##STR201## wherein Ar.sup.4, Ar.sup.5 and Ar.sup.6 are each an aromatic ring group or a heterocyclic group:
- (C) hydrazone compounds having a structure expressed by the following formula (3) and a melting point not higher than 155.degree. C.; ##STR202## wherein R.sup.3 is a hydrogen atom or an alkyl group, R.sup.4 and R.sup.5 are alkyl groups, aralkyl groups or aromatic ring groups, n.sub.2 is 1 or 2, A is an aromatic ring group, a heterocyclic group or --CH.dbd.C(R.sup.6)R.sup.7 (R.sup.6 and R.sup.7 are hydrogen atoms, aromatic ring groups or heterocyclic groups, provided that R.sup.6 and R.sup.7 are not simultaneously both hydrogen atoms.
- 24. A facsimile unit according to claim 23, wherein said compound is (A).
- 25. A facsimile unit according to claim 23, wherein said compound is (B).
- 26. A facsimile unit according to claim 23, wherein said compound is (C).
Priority Claims (4)
Number |
Date |
Country |
Kind |
4-062306 |
Mar 1991 |
JPX |
|
3-077290 |
Mar 1991 |
JPX |
|
3-077291 |
Mar 1991 |
JPX |
|
3-077292 |
Mar 1991 |
JPX |
|
Parent Case Info
This application is a continuation-in-part of application Ser. No. 07/852,720 filed Mar. 17, 1992, now abandoned.
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Continuation in Parts (1)
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Number |
Date |
Country |
Parent |
852720 |
Mar 1992 |
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