Patent Application
20080291389
The present invention relates to an elliptically polarizing plate and to an image display apparatus using the elliptically polarizing plate. More specifically, the present invention relates to a very thin elliptically polarizing plate having broadband and wide viewing angle and to an image display apparatus using the elliptically polarizing plate.
Various optical films each having a polarizing film and a retardation plate in combination are generally used for various image display apparatuses such as a liquid crystal display apparatus and an electroluminescence (EL) display, to thereby obtain optical compensation.
In general, a circularly polarizing plate which is one type of the optical films can be produced by combining a polarizing film and λ/4 plate. However, the λ4 plate has characteristics providing larger retardation values with shorter wavelengths, so-called “positive wavelength dispersion characteristics”, and the λ/4 plate generally has high positive wavelength dispersion characteristics. Thus, the λ/4 plate has a problem in that it cannot exhibit desired optical characteristics (such as functions of the λ/4 plate) over a wide wavelength range. In order to avoid the problem, there has been recently proposed a retardation plate having wavelength dispersion characteristics providing larger retardation values with longer wavelengths, so-called “reverse dispersion characteristics” such as a norbornene-based film or a modified polycarbonate-based film. However, such a film has problems in cost.
At present, a λ/4 plate having positive wavelength dispersion characteristics is combined with, for example, a retardation plate providing larger retardation values with longer wavelengths or a plate, to thereby correct the wavelength dispersion characteristics of the λ/4 plate (see JP 3174367 B, for example).
In a case where a polarizing film, a λ/4 plate, and a λ/2 plate are combined as described above, angles of respective optical axes, that is, angles between an absorption axis of the polarizing film and slow axes of the respective retardation plates must be adjusted. However, the optical axes of the polarizing film and the retardation plates each formed of a stretched film generally vary depending on stretching directions. The respective films must be cut out in accordance with directions of the respective optical axes and laminated, to thereby laminate the films such that the absorption axis and the slow axes are at desired angles. To be specific, an absorption axis of a polarizing film is generally in parallel with its stretching direction, and a slow axis of a retardation plate is also in parallel with its stretching direction. Thus, for lamination of the polarizing film and the retardation plate at an angle between the absorption axis and the slow axis of 45°, for example, one of the films must be cut out in a direction of 45° with respect to a longitudinal direction (stretching direction) of the film. In the case where a film is cut out and then attached as described above, angles between optical axes may vary by cut-out film, for example. The variation may result in problems of variation in quality by product and production requiring high cost and long time. Further problems include increased waste by cutting out of the films, and difficulties in production of large films.
As a countermeasure to the problems, there is proposed a method of adjusting a stretching direction by stretching a polarizing film or a retardation plate in an oblique direction or the like (see JP 2003-195037 A, for example). However, the method has a problem in that the adjustment involves difficulties.
Further, a demand for reduction in thickness of an image display apparatus has increased recently. With the increasing demand, a demand for reduction in thickness of an optical film such as a circularly polarizing plate has also increased.
The present invention has been made in view of solving the conventional problems described above, and an object of the present invention is therefore to provide a very thin elliptically polarizing plate having broadband and wide viewing angle and an image display apparatus using the elliptically polarizing plate.
The inventors of the present invention have conducted intensive studies on properties of the elliptically polarizing plate, and have found that the above-mentioned object can be attained by applying a liquid crystal composition containing a liquid crystal material and a chiral agent to a specific substrate, transferring a formed birefringent layer, and forming a very thin λ/4 plate having excellent optical properties. Thus, the inventors have completed the present invention.
An elliptically polarizing plate of the present invention includes a polarizer, a protective layer formed on one side of the polarizer, a first birefringent layer serving as a λ/2 plate, and a second birefringent layer serving as a λ/4 plate in the stated order. In the plate, an absorption axis of the polarizer and a slow axis of the first birefringent layer form an angle α of 10° to 20° or −10° to −20°, and the absorption axis of the polarizer and a slow axis of the second birefringent layer form an angle β of 65° to 85° or 5° to 25°. According to a preferred embodiment of the elliptically polarizing plate, the first birefringent layer has a thickness of 0.5 to 5 μm, and the second birefringent layer has a thickness of 0.3 to 3 μm.
According to another preferred embodiment of the elliptically polarizing plate, the first birefringent layer is formed by using a liquid crystal material, and the second birefringent layer is formed by using a liquid crystal composition containing a liquid crystal material and a chiral agent. According to still another preferred embodiment of the elliptically polarizing plate, the liquid crystal material used for forming the second birefringent layer is at least one of the compounds represented by the following formulae (4) to (19), and the chiral agent is at least one of the compounds represented by the following formulae (24) to (44). According to a particularly preferred embodiment of the elliptically polarizing plate, the liquid crystal material used for forming the second birefringent layer is a compound represented by the formula (10), and the chiral agent is a compound represented by the formula (32).
Another aspect of the present invention provides a method of producing an elliptically polarizing plate. The method includes the steps of: subjecting a surface of a transparent protective film (T) to alignment treatment; forming a first birefringent layer on the surface of the transparent protective film (T) subjected to the alignment treatment; laminating a polarizer on a surface of the transparent protective film (T); and laminating a second birefringent layer on the surface of the first birefringent layer. In the method, the polarizer and the first birefringent layer are arranged on opposite sides of the transparent protective film (T). According to a preferred embodiment, the transparent protective film (T), the first birefringent layer, the polarizer, and the second birefringent layer are continuous films, and long sides of the transparent protective film (T), the first birefringent layer, the polarizer, and the second birefringent layer are attached together for lamination.
According to a preferred embodiment, the step of forming a first birefringent layer includes the steps of: applying an application liquid containing a liquid crystal material; and aligning the applied liquid crystal material through treatment at a temperature at which the liquid crystal material exhibits a liquid crystal phase. According to another preferred embodiment, the liquid crystal material includes at least one of a polymerizable monomer and a crosslinking monomer, and the step of aligning the liquid crystal material further includes the step of performing at least one of polymerization treatment and crosslinking treatment. According to still another preferred embodiment, at least one of the polymerization treatment and the crosslinking treatment is performed by one of heating and photoirradiation.
According to a preferred embodiment, the step of laminating a second birefringent layer includes the steps of: applying an application liquid containing a liquid crystal material and a chiral agent to a substrate; forming a second birefringent layer on the substrate by subjecting the application liquid to treatment at a temperature at which the liquid crystal material exhibits a liquid crystal phase; and transferring the second birefringent layer formed on the substrate to the surface of the first birefringent layer. According to a preferred embodiment, the application liquid contains the chiral agent in a ratio of 0.03 to 0.11 part by weight with respect to 100 parts by weight of the liquid crystal material. According to another preferred embodiment, the substrate is a polyethylene terephthalate film obtained through stretching treatment and recrystallization treatment. According to still another preferred embodiment, the substrate is used for the step of applying an application liquid without being subjected to alignment treatment on its surface.
Another aspect of the present invention provides an image display apparatus. This image display apparatus includes the above-mentioned elliptically polarizing plate.
As described above, according to the present invention, the first birefringent layer and the second birefringent layer are each formed of a liquid crystal material, to thereby remarkably increase a difference between nx and ny compared with that in the case where the first birefringent layer and the second birefringent layer are each formed of a stretched polymer film. As a result, a thickness of the first birefringent layer for providing a desired in-plane retardation for the first birefringent layer to serve as a λ/2 plate may be reduced remarkably as compared to the conventional one, and a thickness of the second birefringent layer for providing a desired in-plane retardation for the second birefringent layer to serve as a λ/4 plate may be reduced remarkably as compared to the conventional one. Thus, the elliptically polarizing plate of the present invention may have a remarkably reduced thickness compared with that of a conventional elliptically polarizing plate, and may greatly contribute to reduction in thickness of an image display apparatus. Further, in the elliptically polarizing plate of the present invention, alignment of the liquid crystal material of each of the first birefringent layer and the second birefringent layer is fixed through polymerization or crosslinking, and thus the elliptically polarizing plate of the present invention has remarkably excellent heat resistance compared with that of the conventional elliptically polarizing plate. As a result, the elliptically polarizing plate of the present invention has a particular effect in that its optical properties do not degrade even in a high temperature environment (such as in vehicle use).
In addition, according to the present invention, formation of the second birefringent layer by using a predetermined (trace) amount of the chiral agent with respect to the amount of the liquid crystal material allows shift in direction of a slow axis of the second birefringent layer without formation of a negative C plate (nx=ny>nz). That is, the direction of the slow axis may be shifted without disappearance of the slow axis. As a result, the direction of the slow axis of the second birefringent layer may be set in a direction different from a direction parallel or perpendicular to the absorption axis of the polarizer. Conventionally, experiments have suggested that light leak may be prevented by shifting a direction of a slow axis of a λ/4 plate from a direction parallel or perpendicular to an absorption axis of a polarizer in an elliptically polarizing plate. However, lamination of such a λ/4 plate for practical use is substantially impossible (the λ/4 plate must be punched out in an oblique direction or must be attached with its axis being shifted, to thereby provide non-allowable production efficiency for practical use). According to the present invention, a continuous polarizer and a continuous λ/4 plate having a slow axis in a direction different from a direction parallel or perpendicular to the absorption axis of the polarizer may be continuously attached together with respective longitudinal directions in the same direction (by so-called roll to roll). Thus, the continuous λ/4 plate having a slow axis in a direction different from a direction parallel or perpendicular to the absorption axis of the polarizer can be laminated at very high production efficiency. As a result, an elliptically polarizing plate capable of significantly preventing light leak (which conventionally and substantially could not be produced) can be obtained. Conventionally, use of the chiral agent caused formation of a negative C plate and disappearance of the slow axis. However, the use of the chiral agent in a trace amount has been found to allow shift in slow axis without disappearance of the slow axis. Control in direction of the slow axis by optimization of the amount of the chiral agent used is one significant result of the present invention.
In the accompanying drawings:
The first birefringent layer 13 may serve as a so-called λ/2 plate. In the specification of the present invention, the λ/2 plate refers to a plate having a function of converting linearly polarized light having a specific vibration direction into linearly polarized light having a vibration direction perpendicular thereto, or converting right-handed circularly polarized light into left-handed circularly polarized light (or converting left-handed circularly polarized light into right-handed circularly polarized light). The second birefringent layer 14 may serve as a so-called λ/4 plate. In the specification of the present invention, the λ/4 plate refers to a plate having a function of converting linearly polarized light having a specific wavelength into circularly polarized light (or converting circularly polarized light into linearly polarized light).
The elliptically polarizing plate of the present invention has a total thickness of preferably 80 to 200 μm, more preferably 90 to 130 μm, and most preferably 100 to 120 μm. According to the present invention, the first birefringent layer and the second birefringent layer are each formed of a liquid crystal material (described below). Thus, a thickness of the first birefringent layer for causing the first birefringent layer to serve as a λ/2 plate may be reduced remarkably as compared to the conventional one, and a thickness of the second birefringent layer for causing the second birefringent layer to serve as a λ/4 plate may be reduced remarkably as compared to the conventional one. As a result, the elliptically polarizing plate of the present invention may have a remarkably reduced thickness of a minimum of about ¼ of a total thickness of the conventional elliptically polarizing plate, and may greatly contribute to reduction in thickness of a liquid crystal display apparatus. Hereinafter, details of the respective layers forming the elliptically polarizing plate of the present invention will be described.
As described above, the first birefringent layer 13 may serve as a so-called λ/2 plate. The first birefringent layer serves as a λ/2 plate, to thereby appropriately adjust retardation of wavelength dispersion properties (in particular, a wavelength range in which the retardation departs from λ/4) of the second birefringent layer serving as a λ/4 plate. An in-plane retardation (Δnd) of the first birefringent layer at a wavelength of 590 nm is preferably 210 to 330 nm, more preferably 230 to 310 nm, and most preferably 245 to 295 nm. The in-plane retardation (Δnd) may be determined by an expression Δnd=(nx−ny)×d. In the expression, nx represents a refractive index in a direction providing a maximum in-plane refractive index (that is, a slow axis direction), and ny represents an in-plane refractive index in a direction perpendicular to the slow axis. d represents a thickness of the first birefringent layer. The first birefringent layer 13 preferably has a refractive index profile of nx>ny=nz. In the specification of the present invention, the expression “ny=nz” refers to not only a case where ny and nz are exactly equal but also a case where ny and nz are substantially equal. In the specification of the present invention, the phrase “substantially equal” includes a case where nx and ny differ without providing effects on overall polarization properties of an elliptically polarizing plate in practical use.
A thickness of the first birefringent layer is set such that it serves as a λ/2 plate most appropriately. That is, the thickness thereof is set to provide a desired in-plane retardation. To be specific, the thickness is preferably 0.5 to 5 μm, more preferably to 4 μm, and most preferably 1.5 to 3 μm.
An arbitrary and appropriate material may be used as a material forming the first birefringent layer as long as the above characteristics are provided. A liquid crystal material is preferable, and a liquid crystal material (nematic liquid crystal) having a nematic phase as a liquid crystal phase is more preferable. Examples of the liquid crystal material which can be used include a liquid crystal polymer and a liquid crystal monomer. Liquid crystallinity of the liquid crystal material may develop through a lyotropic mechanism or a thermotropic mechanism. Further, an alignment state of the liquid crystal is preferably homogeneous alignment.
A liquid crystal monomer used as the liquid crystal material is preferably a polymerizable monomer or a crosslinking monomer, for example. As described below, this is because the alignment state of the liquid crystal material can be fixed by polymerizing or crosslinking the polymerizable monomer or the crosslinking monomer. The alignment state of the liquid crystal material can be fixed by aligning the liquid crystal monomer, and then polymerizing or crosslinking the liquid crystal monomers (polymerizable monomers or crosslinking monomers), for example. A polymer is formed through polymerization, and a three-dimensional network structure is formed through crosslinking. However, the polymer and the three-dimensional network structure are not crystalline. Thus, the formed first birefringent layer will not undergo phase transition into a liquid crystal phase, a glass phase, or a crystal phase by change in temperature, which is specific to a liquid crystal compound. As a result, the first birefringent layer is a birefringent layer which has excellent stability and is not affected by change in temperature.
Any suitable liquid crystal monomers may be employed as the liquid crystal monomer. For example, there are used polymerizable mesogenic compounds and the like described in JP 2002-533742 A (WO 00/37585), EP358208 (U.S. Pat. No. 5,211,877), EP 66137 (U.S. Pat. No. 4,388,453), WO 93/22397, EP 0261712, DE 19504224, DE 4408171, GB 2280445, and the like. Specific examples of the polymerizable mesogenic compounds include: LC242 (trade name) available from BASF Aktiengesellschaft; E7 (trade name) available from Merck & Co., Inc.; and LC-Silicone-CC3767 (trade name) available from Wacker-Chemie GmbH.
For example, a nematic liquid crystal monomer is preferred as the liquid crystal monomer, and a specific example thereof includes a monomer represented by the below-indicated formula (1). The liquid crystal monomer may be used alone or in combination of two or more thereof.
In the above formula (1), A1 and A2 each represent a polymerizable group, and may be the same or different from each other. One of A1 and A2 may represent hydrogen. Each X independently represents a single bond, —O—, —S—, —C═N—, —O—CO—, —CO—O—, —O—CO—O—, —CO—NR—, —NR—CO—, —NR—, —O—CO—NR—, —NR—CO—O—, —CH2—O—, or —NR—CO—NR—. R represents H or an alkyl group having 1 to 4 carbon atoms. M represents a mesogen group.
In the above formula (1), Xs may be the same or different from each other, but are preferably the same.
Of monomers represented by the above formula (1), each A2 is preferably arranged in an ortho position with respect to A1.
A1 and A2 are preferably each independently represented by the below-indicated formula (2), and A1 and A2 preferably represent the same group.
Z-X-(Sp)n (2)
In the above formula (2), Z represents a crosslinkable group, and X is the same as that defined in the above formula (1). Sp represents a spacer consisting of a substituted or unsubstituted linear or branched alkyl group having 1 to 30 carbon atoms. n represents 0 or 1. A carbon chain in Sp may be interrupted by oxygen in an ether functional group, sulfur in a thioether functional group, a non-adjacent imino group, an alkylimino group having 1 to 4 carbon atoms, or the like.
In the above formula (2), Z preferably represents any one of functional groups represented by the below-indicated formulae. In the below-indicated formulae, examples of R include a methyl group, an ethyl group, an n-propyl group, an i-propyl group, an n-butyl group, an i-butyl group, and a t-butyl group.
In the above formula (2), Sp preferably represents any one of structural units represented by the below-indicated formulae. In the below-indicated formulae, m preferably represents 1 to 3, and p preferably represents 1 to 12.
In the above formula (1), M is preferably represented by the below-indicated formula (3). In the below-indicated formula (3), X is the same as that defined in the above formula (1). Q represents a substituted or unsubstituted linear or branched alkylene group, or an aromatic hydrocarbon group, for example. Q may represent a substituted or unsubstituted linear or branched alkylene group having 1 to 12 carbon atoms, for example.
In the case where Q represents an aromatic hydrocarbon group, Q preferably represents any one of aromatic hydrocarbon groups represented by the below-indicated formulae or substituted analogues thereof.
The substituted analogues of the aromatic hydrocarbon groups represented by the above formulae may each have 1 to 4 substituents per aromatic ring, or 1 to 2 substituents per aromatic ring or group. The substituents may be the same or different from each other. Examples of the substituents include: an alkyl group having 1 to 4 carbon atoms; a nitro group; a halogen group such as F, Cl, Br, or I; a phenyl group; and an alkoxy group having 1 to 4 carbon atoms.
Specific examples of the liquid crystal monomer include monomers represented by the following formulae (4) to (19).
A temperature range in which the liquid crystal monomer exhibits liquid-crystallinity varies depending on the type of liquid crystal monomer. More specifically, the temperature range is preferably 40 to 120° C., more preferably 50 to 100° C., and most preferably 60 to 90° C.
As described above, the second birefringent layer 14 may serve as a so-called λ/4 plate. According to the present invention, the wavelength dispersion characteristics of the second birefringent layer serving as a λ/4 plate are corrected by optical characteristics of the first birefringent layer serving as a λ/2 plate, to thereby exhibit circularly polarizing function over a wide wavelength range. An in-plane retardation (Δnd) of the second birefringent layer at a wavelength of 590 nm is preferably 80 to 200 nm, more preferably to 180 nm, and most preferably 120 to 160 nm. An Nz coefficient (=(nx−nz) (nx−ny)) of the second birefringent layer is preferably to 1.5 and more preferably 1.2 to 1.3. Further, the second birefringent layer 14 preferably has a refractive index profile of nx>ny>nz.
The thickness of the second birefringent layer may be set such that the second birefringent layer may serve as a λ/4 plate most appropriately. That is, the thickness thereof may be set to provide a desired in-plane retardation. To be specific, the thickness thereof is preferably 0.3 to 3 μm, more preferably 0.5 to 2.5 μm, and most preferably 0.8 to 2 μm. Realization of such a very thin second birefringent layer (λ/4 plate) is one feature of the present invention. For example, the elliptically polarizing plate of the present invention may realize a λ/4 plate (second birefringent layer) having a thickness of about 1/20 to 1/200 of that of a λ/4 plate formed of a conventional stretched film having a thickness of about 60 μm.
Any appropriate material may be employed as a material used for forming the second birefringent layer as long as the above-described properties are obtained. The second birefringent layer is preferably formed of a liquid crystal composition containing a liquid crystal material and a chiral agent. The use of a liquid crystal material may remarkably increase a difference between nx and ny compared with that of a conventional stretched polymer film (such as a norbornene-based resin or a polycarbonate-based resin), to thereby remarkably reduce a thickness of the second birefringent layer for providing an in-plane retardation desired for a λ/4 plate. Further, the use of a predetermined amount of the chiral agent in combination allows change in direction of the slow axis of the second birefringent layer to be obtained into a desired direction. One type of liquid crystal material or chiral agent may be used alone, or two or more types thereof may be used in combination.
The same material as that used for the first birefringent layer may be used as the liquid crystal material. The details of the liquid crystal material are as described in the above section A-2.
The chiral agent may employ any appropriate material capable of aligning the liquid crystal material in a desired direction to form the slow axis of the second birefringent layer in a desired direction. For example, such a chiral agent has a torsional force of preferably 1×10−6 nm−1·(wt %)−1 or more, more preferably 1×10−5 nm−1·(wt %)−1 to 1×10−2 nm−1·(wt %)−1, and most preferably 1×10−4 nm−1·(wt %)−1 to 1×10−3 nm−1·(wt %)−1. A chiral agent having such a torsional force may be used in a predetermined amount, to thereby allow the second birefringent layer to exhibit its slow axis in a desired direction. Note that in the specification of the present invention, the term “torsional force” refers to ability of the chiral agent to provide torsion to the liquid crystal material and to shift the slow axis of the second birefringent layer.
The chiral agent is preferably a polymerizable chiral agent. Specific examples of the polymerizable chiral agent include chiral compounds represented by the following general formulae (20) to (23).
(Z-X5)nCh (20)
(Z-X2-Sp-X5)nCh (21)
(P1—X5)nCh (22)
(Z-X2-Sp-X3-M-X4)nCh (23)
In the formulae (20) to (23), Z and Sp are the same as those defined for the above formula (2). X2, X3, and X4 each independently represent a chemical single bond, —O—, —S—, —O—CO—, —CO—O—, —O—CO—O—, —CO—NR—, —NR—CO—, —O—CO—NR—, —NR—CO—O—, or —NR—CO—NR—. R represents H or an alkyl group having 1 to 4 carbon atoms. X5 represents a chemical single bond, —O—, —S—, O—CO—, —CO—O—, —O—CO—O—, —CO—NR—, —NR—CO—, —O—CO—NR—, —NR—CO—O—, —NR—CO—NR—, —CH2O—, —O—CH2—, —CH═N—, —N═CH—, or —N≡N—. R represents H or an alkyl group having 1 to 4 carbon atoms as described above. M represents a mesogenic group as described above. P1 represents hydrogen, an alkyl group having 1 to 30 carbon atoms, an acyl group having 1 to 30 carbon atoms, or a cycloalkyl group having 3 to 8 carbon atoms which is substituted by 1 to 3 alkyl groups having 1 to 6 carbon atoms. n represents an integer of 1 to 6. Ch represents a chiral group with a valence of n. In the formula (23), at least one of X3 and X4 preferably represents —O—CO—O—, —O—CO—NR—, —NR—CO—O—, or —NR—CO—NR—. In the formula (22), in the case where P1 represents an alkyl group, an acyl group, or a cycloalkyl group, its carbon chain may be interrupted by oxygen of an ether functional group, sulfur of a thioether functional group, a non-adjacent imino group, or an alkyl imino group having 1 to 4 carbon atoms.
Examples of the chiral group represented by Ch include atomic groups represented by the following formulae.
In the atomic groups described above, L represents an alkyl group having 1 to 4 carbon atoms, an alkoxy group having 1 to 4 carbon atoms, a halogen, COOR, OCOR, CONHR, or NHCOR. R represents an alkyl group having 1 to 4 carbon atoms. Note that terminals of the atomic groups represented in the above formulae each represent a bonding hand to an adjacent group.
Of the atomic groups, atomic groups represented by the following formulae are particularly preferred.
In a preferred example of the chiral compound represented by the above formula (21) or (23): n represents 2; Z represents H2C═CH—; and Ch represents atomic groups represented by the following formulae.
Specific examples of the chiral compound include compounds represented by the following formulae (24) to (44). Note that those chiral compounds each have a torsional force of 1×10−6 nm−1·(wt %)−1 or more.
In addition to the chiral compounds represented above, further examples of the chiral compound include chiral compounds described in RE-A4342280, DE 19520660.6, and DE 19520704.1.
Note that any appropriate combination of the liquid crystal material and the chiral agent may be employed in accordance with the purpose. Particularly typical examples of the combination include: a combination of the liquid crystal monomer represented by the above formula (10)/the chiral agent represented by the above formula (32); a combination of the liquid crystal monomer represented by the above formula (10)/the chiral agent represented by the above formula (38); and a combination of the liquid crystal monomer represented by the above formula (11)/the chiral agent represented by the above formula (39).
The chiral agent may be used in a ratio of 0.03 to 0.11 part by weight, more preferably 0.045 to 0.105 part by weight, and most preferably 0.05 to 0.09 part by weight with respect to 100 parts by weight of the liquid crystal material. In the case where the use amount of the chiral agent is less than 0.03 part by weight, torsion may not be sufficiently provided to the liquid crystal material and thus the slow axis of the second birefringent layer may not be sufficiently shifted. In the case where the use amount of the chiral agent is more than 0.11 part by weight, the liquid crystal material may form into cholesteric alignment to form a negative C plate (nx=ny>nz). As a result, the slow axis may not be formed in the second birefringent layer. Realization of shift in slow axis of the second birefringent layer without formation of a negative C plate by adjusting the use amount of the chiral agent within the above ranges is one feature of the present invention.
The liquid crystal composition contains at least one of a polymerization initiator and a crosslinking agent (curing agent) as required. The polymerization initiator and/or the crosslinking agent (curing agent) are/is used, to thereby fix the shift formed in the liquid crystal material in a liquid crystal state. As a result, a slow axis shifted in a desired direction may be stably formed in the second birefringent layer. Any appropriate substance may be used for the polymerization initiator or the crosslinking agent as long as the effect of the present invention can be obtained. Examples of the polymerization initiator include benzoylperoxide (BPO) and azobisisobutyronitrile (AIBN). Examples of the crosslinking agent (curing agent) include a UV-curing agent, a photo-curing agent, and a heat-curing agent. Specific examples thereof include an isocyanate-based crosslinking agent, an epoxy-based crosslinking agent, and a metal chelate crosslinking agent. One type of polymerization initiator or crosslinking agent may be used, or two or more types thereof may be used in combination. A content of the polymerization initiator or the crosslinking agent in the liquid crystal composition is preferably 0.1 to 10 wt %, more preferably 0.5 to 8 wt %, and most preferably 1 to 5 wt %. In the case where the content of the polymerization initiator or the crosslinking agent is less than 0.1 wt %, the shift in the liquid crystal material may be fixed insufficiently. In the case where the content of the polymerization initiator or the crosslinking agent is more than 10 wt %, the liquid crystal material exhibits a liquid crystal state in a very narrow temperature range and temperature control during formation of the second birefringent layer may involve difficulties.
The liquid crystal composition may contain another appropriate additive as required. Examples of the additive include an antioxidant, a modifier, a surfactant, a dye, a pigment, a color protection agent, and a UV absorber. One type of additive may be used alone, or two or more types thereof may be used in combination. Specific examples of the antioxidant include a phenol-based compound, an amine-based compound, an organic sulfur-based compound, and a phosphine-based compound. Examples of the modifier include glycols, silicones, and alcohols. The surfactant is added for smoothing a surface of a birefringent layer. Examples the surfactant that can be used include a silicone-based surfactant, an acrylic surfactant, and a fluorine-based surfactant, and a particularly preferred example thereof is a silicon-based surfactant.
Any suitable polarizers may be employed as the polarizer 11 in accordance with the purpose. Examples thereof include: a film prepared by adsorbing a dichromatic substance such as iodine or a dichromatic dye on a hydrophilic polymer film such as a polyvinyl alcohol-based film, a partially formalized polyvinyl alcohol-based film, or a partially saponified ethylene/vinyl acetate copolymer-based film and uniaxially stretching the film; and a polyene-based orientation film such as a dehydrated product of a polyvinyl alcohol-based film or a dechlorinated product of a polyvinyl chloride-based film. Of those, a polarizer prepared by adsorbing a dichromatic substance such as iodine on a polyvinyl alcohol-based film and uniaxially stretching the film is particularly preferred because of high polarized dichromaticity. A thickness of the polarizer is not particularly limited, but is generally about 1 to 80 μm.
The polarizer prepared by adsorbing iodine on a polyvinyl alcohol-based film and uniaxially stretching the film may be produced by, for example: immersing a polyvinyl alcohol-based film in an aqueous solution of iodine for coloring; and stretching the film to a 3 to 7 times length of the original length. The aqueous solution may contain boric acid, zinc sulfate, zinc chloride, or the like as required, or the polyvinyl alcohol-based film may be immersed in an aqueous solution of potassium iodide or the like. Further, the polyvinyl alcohol-based film may be immersed and washed in water before coloring as required.
Washing the polyvinyl alcohol-based film with water not only allows removal of contamination or an antiblocking agent on a film surface, but also provides an effect of preventing nonuniformity such as uneven coloring by swelling of the polyvinyl alcohol-based film. The stretching of the film may be performed after coloring of the film with iodine, performed during coloring of the film, or performed followed by coloring of the film with iodine. The stretching may be performed in an aqueous solution of boric acid or potassium iodide, or in a water bath.
The protective layer 12 and the second protective layer 15 are each formed of an arbitrary and appropriate film which can be used as a protective layer for a polarizing plate. The film is preferably a transparent protective film. Specific examples of a material used as a main component of the film include transparent resins such as a cellulose-based resin (such as triacetylcellulose (TAC)), a polyester-based resin, a polyvinyl alcohol-based resin, a polycarbonate-based resin, a polyamide-based resin, a polyimide-based resin, a polyether sulfone-based resin, a polysulfone-based resin, a polystyrene-based resin, a polynorbornene-based resin, a polyolefin-based resin, an acrylic resin, and an acetate-based resin. Another example thereof includes an acrylic, urethane-based, acrylic urethane-based, epoxy-based, or silicone-based thermosetting resin or UV-curing resin. Still another example thereof includes a glassy polymer such as a siloxane-based polymer. Further, a polymer film described in JP 2001-343529 A (WO 01/37007) may also be used. To be specific, the film is formed of a resin composition containing a thermoplastic resin having a substituted or unsubstituted imide group on a side chain, and a thermoplastic resin having a substituted or unsubstituted phenyl group and a nitrile group on a side chain. A specific example thereof includes a resin composition containing an alternate copolymer of isobutene and N-methylmaleimide, and an acrylonitrile/styrene copolymer. The polymer film may be an extruded product of the above-mentioned resin composition, for example. Of those, TAC, a polyimide-based resin, a polyvinyl alcohol-based resin, and a glassy polymer are preferable, and TAC is most preferable.
The protective layer is preferably transparent and colorless. To be specific, the protective layer has a thickness direction retardation Rth of preferably −90 nm to +90 nm, more preferably −80 nm to +80 nm, and most preferably −70 nm to +70 nm. The thickness direction retardation Rth may be determined by an expression Rth={(nx+ny)/2−nz}×d.
The protective layer has an arbitrary and appropriate thickness as long as the preferable thickness direction retardation can be obtained. To be specific, the thickness of the protective layer is preferably 5 mm or less, more preferably 1 mm or less, even more preferably 1 to 500 μm, and most preferably 5 to 150 μm.
The surface of the second protective layer 15 opposite to that of the polarizer (that is, the outermost part of the elliptically polarizing plate) may be subjected to hard coat treatment, antireflection treatment, anti-sticking treatment, anti-glare treatment, or the like as required.
A method of producing an elliptically polarizing plate according to a preferred embodiment of the present invention includes the steps of: subjecting a surface of a transparent protective film (T) (eventually, the protective layer 12) to alignment treatment; forming a first birefringent layer on the surface of the transparent protective film (T) subjected to the alignment treatment; laminating a polarizer on a surface of the transparent protective film (T); and laminating a second birefringent layer on the surface of the first birefringent layer. In the method, the polarizer and the first birefringent layer are arranged on opposite sides of the transparent protective film (T). Such a production method provides an elliptically polarizing plate shown in
A surface of a transparent protective film (T) (eventually, the protective layer 12) is subjected to alignment treatment, and an application liquid containing a predetermined liquid crystal material is applied onto the surface, to thereby form the first birefringent layer 13 having a slow axis B at an angle α with respect to the absorption axis of the polarizer 11 as shown in
Arbitrary and appropriate alignment treatment may be employed as the alignment treatment for the transparent protective film (T). Specific examples of the alignment treatment include rubbing treatment, an oblique deposition method, stretching treatment, photoalignment treatment, magnetic field alignment treatment, and electrical field alignment treatment. The rubbing treatment is preferable. Arbitrary and appropriate conditions may be employed as conditions for various alignment treatments in accordance with the purpose.
The alignment direction of the alignment treatment refers to a direction at a predetermined angle with respect to the absorption axis of the polarizer when the transparent protective film (T) and the polarizer are laminated. The alignment direction is substantially the same as the direction of the slow axis B of the first birefringent layer 13 to be formed as described below. Thus, the predetermined angle is preferably +10° to +20° or −10° to −20°, more preferably +13° to +19° or −13° to −19°, particularly preferably +14° to +18° or −14° to −18°.
The alignment treatment at such a predetermined angle as described above with respect to a continuous transparent protective film (T) involves treatment in a longitudinal direction of the continuous transparent protective film (T) and treatment in an oblique direction (to be specific, direction at such a predetermined angle as described above) with respect to the longitudinal direction or direction perpendicular thereto (width direction) of the continuous protective film (T). The polarizer is produced by stretching the polymer film colored with a dichromatic substance as described above, and has an absorption axis in the stretching direction. For mass production of the polarizer, a continuous polymer film is prepared and is continuously stretched in a longitudinal direction. In a case where a continuous polarizer and a continues transparent protective film (T) are attached together, longitudinal directions thereof are in the direction of the absorption axis of the polarizer. Thus, in order to align the transparent protective film (T) in a direction at a predetermined angle with respect to the absorption axis of the polarizer, the transparent protective film is desirably subjected to the alignment treatment in an oblique direction. The direction of the absorption axis of the polarizer and the longitudinal directions of the continuous films (polarizer and transparent protective film (T)) are substantially the same, and thus the direction of the alignment treatment may be at the above predetermined angle with respect to the longitudinal directions. Meanwhile, in a case where the treatment is performed in a longitudinal direction or width direction of the transparent protective film, the transparent protective film must be cut out in an oblique direction and then laminated. As a result, angles between optical axes may vary by cut-out film. The variation may result in variation in quality by product, production requiring high cost and long time, increased waste, and difficulties in production of large films.
The surface of the transparent protective film (T) may be directly subjected to the alignment treatment. Alternatively, an arbitrary and appropriate aligned film (typified by a polyimide layer or a polyvinyl alcohol layer) may be formed, and the aligned film may be subjected to the alignment treatment.
Next, an application liquid (liquid crystal composition) containing a liquid crystal material as described in the section A-2 is applied onto the surface of the transparent protective film (T) which has been subjected to the alignment treatment. Then, the liquid crystal material in the application liquid is aligned to form the first birefringent layer. More specifically, an application liquid having a liquid crystal material dissolved or dispersed in an appropriate solvent may be prepared, and the application liquid may be applied onto the surface of the transparent protective film (T) which has been subjected to the alignment treatment. The step of aligning the liquid crystal material is described in the section B-3 below.
Any suitable solvents which may dissolve or disperse the liquid crystal material may be employed as the solvent. The type of solvent to be used may be appropriately selected in accordance with the type of liquid crystal material or the like. Specific examples of the solvent include: halogenated hydrocarbons such as chloroform, dichloromethane, carbon tetrachloride, dichloroethane, tetrachloroethane, methylene chloride, trichloroethylene, tetrachloroethylene, chlorobenzene, and orthodichlorobenzene; phenols such as phenol, p-chlorophenol, o-chlorophenol, m-cresol, o-cresol, and p-cresol; aromatic hydrocarbons such as benzene, toluene, xylene, mesitylene, methoxybenzene, and 1,2-dimethoxybenzene; ketone-based solvents such as acetone, methyl ethyl ketone (MEK), methyl isobutyl ketone, cyclohexanone, cyclopentanone, 2-pyrrolidone, and N-methyl-2-pyrrolidone; ester-based solvents such as ethyl acetate, butyl acetate, and propyl acetate; alcohol-based solvents such as t-butyl alcohol, glycerin, ethylene glycol, triethylene glycol, ethylene glycol monomethyl ether, diethylene glycol dimethyl ether, propylene glycol, dipropylene glycol, and 2-methyl-2,4-pentanediol; amide-based solvents such as dimethylformamide and dimethylacetamide; nitrile-based solvents such as acetonitrile and butyronitrile; ether-based solvents such as diethyl ether, dibutyl ether, tetrahydrofuran, and dioxane; and carbondisulfide, ethylcellosolve, butyl cellosolve, and ethyl cellosolve acetate. Of those, toluene, xylene, mesitylene, MEK, methyl isobutyl ketone, cyclohexanone, ethyl cellosolve, butyl cellosolve, ethyl acetate, butyl acetate, propyl acetate, and ethyl cellosolve acetate are preferred. The solvent may be used alone or in combination of two or more types thereof.
A content of the liquid crystal material in the application liquid may be appropriately determined in accordance with the type of liquid crystal material, the thickness of the target layer, and the like. More specifically, the content of the liquid crystal material is preferably 5 to 50 wt %, more preferably 10 to 40 wt %, and most preferably 15 to 30 wt %.
The application liquid may further contain any suitable additives as required. Specific examples of the additive include a polymerization initiator and a crosslinking agent. The additive is particularly preferably used when a liquid crystal monomer (polymerizable monomer or crosslinking monomer) is used as the liquid crystal material. The details of the polymerization initiator and the crosslinking agent are as described in the above section A-3.
An application amount of the application liquid may be appropriately determined in accordance with a concentration of the application liquid, the thickness of the target layer, and the like. In a case where the concentration of the liquid crystal material is 20 wt % in the application liquid, the application amount is preferably 0.03 to 0.17 ml, more preferably 0.05 to 0.15 ml, and most preferably 0.08 to 0.12 ml per 100 cm2 of the transparent protective film (T).
Any suitable application methods may be employed, and specific examples thereof include roll coating, spin coating, wire bar coating, dip coating, extrusion, curtain coating, and spray coating.
Next, the liquid crystal material forming the first birefringent layer is aligned in accordance with the alignment direction of the surface of the transparent protective film (T). The liquid crystal material is aligned through treatment at a temperature at which the liquid crystal material exhibits a liquid crystal phase in accordance with the type of liquid crystal material used. The treatment at such a temperature allows the liquid crystal material to be in a liquid crystal state, and the liquid crystal material is aligned in accordance with the alignment direction of the surface of the transparent protective film (T). Thus, birefringence is caused in the layer formed through application, to thereby form the first birefringent layer.
As described above, a treatment temperature may be arbitrarily determined in accordance with the type of liquid crystal material. To be specific, the treatment temperature is preferably 40 to 120° C., more preferably 50 to 100° C., and most preferably 60 to 90° C. A treatment time is preferably 30 seconds or more, more preferably 1 minute or more, particularly preferably 2 minutes or more, and most preferably 4 minutes or more. A treatment time of less than 30 seconds may provide an insufficient liquid crystal state of the liquid crystal material. Meanwhile, the treatment time is preferably 10 minutes or less, more preferably 8 minutes or less, and most preferably 7 minutes or less. A treatment time exceeding 10 minutes may cause sublimation of additives.
In a case where the liquid crystal monomer (polymerizable monomer or crosslinking monomer) as described in the section A-2 is used as the liquid crystal material, the layer formed through the application is preferably subjected to polymerization treatment or crosslinking treatment. The polymerization treatment allows the liquid crystal monomer to polymerize and to be fixed as a repeating unit of a polymer molecule. The crosslinking treatment allows the liquid crystal monomer to form a three-dimensional structure and to be fixed as a part of a crosslinked structure. As a result, the alignment state of the liquid crystal material is fixed. The polymer or three-dimensional structure formed through polymerization or crosslinking of the liquid crystal monomer is “non-liquid crystal”. Thus, the formed first birefringent layer will not undergo phase transition into a liquid crystal phase, a glass phase, or a crystal phase by change in temperature, which is specific to a liquid crystal molecule. As a result, the first birefringent layer which is not affected by change in temperature and has excellent stability can be obtained.
A specific procedure for the polymerization treatment or crosslinking treatment may be arbitrarily selected in accordance with the type of polymerization initiator or crosslinking agent to be used. For example, in a case where a photopolymerization initiator or a photocrosslinking agent is used, photoirradiation may be performed. In a case where a UV polymerization initiator or a UV crosslinking agent is used, UV irradiation may be performed. In a case where a polymerization initiator or crosslinking agent based on heat is used, heating may be performed. The irradiation time, irradiation intensity, total amount of irradiation, and the like of light or UV light may be arbitrarily set in accordance with the type of liquid crystal material, the type of transparent protective film (T), the type of alignment treatment, desired characteristics for the first birefringent layer, and the like. A heating temperature, a heating time, and the like may be arbitrarily set in the same manner.
Such alignment treatment is performed to align the liquid crystal material in the alignment direction of the transparent protective film (T). Thus, the direction of the slow axis B of the first birefringent layer formed is substantially the same as the alignment direction of the transparent protective film (T). The direction of the slow axis B of the first birefringent layer is 10° to 20° or −10° to −20°, preferably 13° to 19° or −13° to −19°, and more preferably 14° to 18° or −14° to −18° with respect to the longitudinal direction of the transparent protective film (T).
The polarizer is laminated on the surface of the transparent protective film (T). As described above, the polarizer is laminated at an arbitrary and appropriate point in time in the production method of the present invention. For example, the polarizer may be laminated on the transparent protective film (T) in advance, may be laminated after the first birefringent layer is formed, or may be laminated after the second birefringent layer is formed.
An arbitrary and appropriate lamination method (such as adhesion) may be employed as a method of laminating the transparent protective film (T) and the polarizer. The adhesion may be performed by using an arbitrary and appropriate adhesive or pressure sensitive adhesive. The type of adhesive or pressure sensitive adhesive may be arbitrarily selected in accordance with the type of adherend (that is, transparent protective film (T) and polarizer). Specific examples of the adhesive include: acrylic, vinyl alcohol-based, silicone-based, polyester-based, polyurethane-based, and polyether-based polymer adhesives; isocyanate-based adhesives; and rubber-based adhesives. Specific examples of the pressure sensitive adhesive include acrylic, vinyl alcohol-based, silicone-based, polyester-based, polyurethane-based, polyether-based, isocyanate-based, and rubber-based pressure sensitive adhesives.
A thickness of the adhesive or pressure sensitive adhesive is not particularly limited, but is preferably 10 to 200 nm, more preferably 30 to 180 nm, and most preferably 50 to 150 nm.
According to the production method of the present invention, the slow axis of the first birefringent layer may be set in the alignment treatment for the transparent protective film (T). Thus, a continuous polarizing film (polarizer) stretched in a longitudinal direction (that is, film having an absorption axis in the longitudinal direction) can be used. In other words, a continuous transparent protective film (T) subjected to the alignment treatment at a predetermined angle with respect to its longitudinal direction and a continuous polarizing film (polarizer) may be continuously attached together with the respective longitudinal directions in the same direction (so-called roll-to-roll). Thus, an elliptically polarizing plate can be obtained at very high production efficiency. According to the method of the present invention, the film need not be cut out obliquely with respect to its longitudinal direction (stretching direction) for lamination. As a result, angles of optical axes do not vary by cut-out film, resulting in an elliptically polarizing film without variation in quality by product. Further, no wastes are produced by cutting of the film, and the elliptically polarizing plate can be obtained at low cost and production of a large polarizing plate is facilitated.
Note that the direction of the absorption axis of the polarizer is substantially parallel to the longitudinal direction of the continuous film. In the specification of the present invention, the phrase “substantially parallel” includes a case where the longitudinal direction and the direction of the absorption axis form an angle of 0°±10°, preferably 0°±5°, and more preferably 0°±3°.
The second birefringent layer is laminated on the surface of the first birefringent layer. A detailed procedure for the step of laminating a second birefringent layer is described below. First, an application liquid containing a liquid crystal composition (containing a liquid crystal material and a chiral agent) used for forming the second birefringent layer is applied to a substrate, and the liquid crystal material in the liquid crystal composition is aligned on the substrate. The alignment of the liquid crystal material is performed through treatment at a temperature at which the liquid crystal material exhibits a liquid crystal phase in accordance with the type of liquid crystal material used. Through such temperature treatment, the liquid crystal material converts into a liquid crystal state, and the liquid crystal material aligns in accordance with the alignment direction of the surface of the substrate. In this way, birefringence generates in a layer formed through application, to thereby form the second birefringent layer. In addition, the chiral agent in the liquid crystal composition exerts an appropriate torsion effect on the liquid crystal material, so the second birefringent layer to be obtained has a slow axis shifted in a desired direction. The details of the application of the application liquid and the alignment treatment of the liquid crystal material are as described in the above sections B-2 and B-3. However, the thickness of the second birefringent layer is about half the thickness of the first birefringent layer, and thus the application amount is also reduced to about half. To be specific, the application amount is preferably 0.02 to 0.08 ml, more preferably 0.03 to 0.07 ml, and most preferably 0.04 to 0.06 ml per area (100 cm2) of the substrate.
Any appropriate substrate may be used for the substrate as long as an appropriate second birefringent layer of the present invention can be obtained. The substrate is preferably a polyethylene terephthalate (PET) film obtained through stretching treatment and recrystallization treatment. To be specific, a PET resin is formed into an extruded film, stretched, and recrystallized, to thereby obtain a substrate. The stretching method is preferably transverse uniaxial stretching or longitudinal and transverse biaxial stretching. In the longitudinal and transverse biaxial stretching, a stretch ratio in a transverse direction is preferably larger than a stretch ratio in a longitudinal direction. Such a method provides a substrate having an alignment axis in a width direction. The substrate may be stretched after a polyimide layer or a polyvinyl alcohol layer is formed thereon. A stretching temperature is preferably 120 to 160° C., and the stretch ratio is preferably 2 to 7 times. A stretching direction may be set in accordance with a desired direction of the slow axis of the second birefringent layer. In the present invention, the slow axis of the second birefringent layer is preferably shifted in a direction different from a direction parallel or perpendicular to the absorption axis (longitudinal direction of the continuous film) of the polarizer. Here, as described above, the direction of the slow axis of the second birefringent layer can be controlled by changing the use amount of the chiral agent in a predetermined range. Thus, the stretching of the substrate only needs to be performed in a transverse direction (direction perpendicular to the longitudinal direction: direction perpendicular to the absorption axis of the polarizer). As a result, in the present invention, the second birefringent layer needs not be punched out for aligning the direction of the slow axis of the second birefringent layer, and may be attached by roll-to-roll, to thereby further improve the production efficiency. A recrystallization temperature is preferably 150 to 250° C. The recrystallization is performed within such a temperature range, to thereby set directions of PET molecules in the same direction and provide a substrate having a very small variation in alignment axis. The substrate has a thickness of preferably 20 to 100 μm, more preferably 30 to 90 μm, and most preferably 30 to 80 μm. The substrate has a thickness within the above ranges, and thus provides strength for favorably supporting the very thin second birefringent layer in the lamination step and provides appropriately maintained operability such as sliding property or roll traveling property.
As described above, the specific stretching treatment and recrystallization treatment may be performed in combination, to thereby provide a substrate having a very small variation in alignment axis. To be specific, the variation in alignment axis of the substrate to be obtained is ±1° or less, and more preferably ±0.5° or less with respect to an average direction of the alignment axes. Such a substrate may be used, to thereby omit the alignment treatment for the surface of the substrate (such as rubbing treatment, oblique evaporation method, stretching treatment, photoalignment treatment, magnetic field alignment treatment, or electrical field alignment treatment) upon application of a liquid crystal composition. As a result, a very thin elliptically polarizing plate may be produced at very excellent production efficiency. Formation of the second birefringent layer by using a substrate which may omit the alignment treatment is one significant feature of the present invention. Such a substrate is available from Toray Industries, Inc. and Mitsubishi Polyester Film Corporation.
Next, the second birefringent layer formed on the substrate is transferred to the surface of the first birefringent layer. A transfer method is not particularly limited, and the second birefringent layer supported on the substrate is attached to the first birefringent layer through an adhesive, for example. A typical example of the adhesive is a curable adhesive. Typical examples of the curable adhesive include: a photo-curable adhesive such as a UV-curable adhesive; a moisture-curable adhesive; and a heat-curable adhesive. A specific example of the heat-curable adhesive is a heat-curable resin-based adhesive formed of an epoxy resin, an isocyanate resin, a polyimide resin, or the like. A specific example of the moisture-curable adhesive is an isocyanate resin-based moisture-curable adhesive. The moisture-curable adhesive (in particular, an isocyanate resin-based moisture-curable adhesive) is preferred. The moisture-curable adhesive cures through a reaction with moisture in air, water adsorbed on a surface of an adherend, an active hydrogen group of a hydroxyl group, a carboxyl group or the like, etc. Thus, the adhesive may be applied and then cured naturally by leaving at stand, and has excellent operability. Further, the moisture-curable adhesive requires no heating for curing, and thus the first and second birefringent layers are not heated during attaching (bonding). As a result, no heat shrinkage occurs, and thus formation of cracks during lamination or the like may significantly be prevented even in the case where the first and second birefringent layers each have a very small thickness as in the present invention. Note that the isocyanate resin-based adhesive is a general term for a polyisocyanate-based adhesive and a polyurethane resin adhesive.
For example, a commercially available adhesive may be used as the curable adhesive, or various curable resins may be dissolved or dispersed in a solvent to prepare a curable resin adhesive solution (or dispersion). In the case where the solution (or dispersion) is prepared, a ratio of the curable resin in the solution is preferably 10 to 80 wt %, more preferably 20 to 65 wt %, especially preferably 25 to 65 wt %, and most preferably 30 to 50 wt % in solid content. Any appropriate solvent may be used as the solvent to be used in accordance with the type of curable resin, and specific examples thereof include ethyl acetate, methyl ethyl ketone, methyl isobutyl ketone, toluene, and xylene. One type of solvent may be used alone, or two or more types thereof may be used in combination.
An application amount of the adhesive may appropriately be set in accordance with the purpose. For example, the application amount is preferably 0.3 to 3 ml, more preferably 0.5 to 2 ml, and most preferably 1 to 2 ml per area (cm2) of the first or second birefringent layer. After the application, the solvent in the adhesive is evaporated through natural drying or heat drying as required. A thickness of the adhesive layer to be obtained is preferably 0.1 to 20 μm, more preferably 0.5 to 15 μm, and most preferably 1 to 10 μm. Microhardness of the adhesive layer is preferably 0.1 to 0.5 GPa, more preferably 0.2 to 0.5 GPa, and most preferably 0.3 to 0.4 GPa. Correlation between Microhardness and Vickers hardness is known, and thus the Microhardness may be converted into Vickers hardness. Microhardness may be calculated from indentation depth and indentation load by using a thin-film hardness meter (trade name, MH4000 or MHA-400, for example) manufactured by NEC Corporation.
Finally, the substrate is peeled off from the second birefringent layer, to thereby complete the lamination of the first birefringent layer and the second birefringent layer. In this way, the elliptically polarizing plate of the present invention can be obtained.
An example of a specific procedure for the production method of the present invention will be described with reference to
First, a continuous polymer film is prepared as a raw material for a polarizer, and is colored, stretched, and the like as described in the section A-4. The continuous polymer film is stretched continuously in a longitudinal direction. In this way, as shown in a perspective view of
Meanwhile, as shown in a perspective view of
Next, as shown in a schematic diagram of
As shown in a schematic diagram of
Finally, as shown in
Another example of the specific procedure for the production method of the present invention will be described.
As described above and shown in a perspective view of
Meanwhile, as shown in a perspective view of
Next, as shown in a schematic diagram of
Then, the first birefringent layer 13 is formed (not shown) on the surface of the protective layer (transparent protective film) 12 subjected to the rubbing treatment as described in the above sections B-2 and B-3. The first birefringent layer 13 has a liquid crystal material aligned along the rubbing direction, and the direction of its slow axis is in substantially the same direction as the rubbing direction of the protective layer (transparent protective film) 12. As a result, a laminate 123 of second protective layer (transparent protective film) 15/polarizer 11/protective layer (transparent protective film) 12/first birefringent layer 13 can be obtained.
As shown in a schematic diagram of
Finally, as shown in
Another further example of the specific procedure for the production method of the present invention will be described.
As described above and shown in the perspective view of
Next, as shown in the schematic diagram of
Next, as described above, a surface (side opposite to the polarizer 11) of the transparent protective film 12 is subjected to rubbing treatment by using a rubbing roll (now shown). At this time, the rubbing direction is in a direction different from the longitudinal direction of the transparent protective film 12 such as +23° to +24° or −23° to −24°.
Then, the first birefringent layer 13 is formed (not shown) on the surface of the protective layer (transparent protective film) subjected to the rubbing treatment as described in the above sections B-2 and B-3. The first birefringent layer 13 has a liquid crystal material aligned along the rubbing direction, and the direction of its slow axis is in substantially the same direction as the rubbing direction of the protective layer (transparent protective film) 12. As a result, a laminate 123 of second protective layer (transparent protective film) 15/polarizer 11/protective layer (transparent protective film) 12/first birefringent layer 13 can be obtained.
As shown in the schematic diagram of
Finally, as shown in
The elliptically polarizing plate of the present invention may further include another optical layer. Any suitable optical layers may be employed as the other optical layer in accordance with the purpose or the type of image display apparatus. Specific examples of the other optical layer include a birefringent layer (retardation film), a liquid crystal film, a light scattering film, and a diffraction film.
The elliptically polarizing plate of the present invention may further include a sticking layer as an outermost layer on at least one side. Inclusion of the sticking layer as an outermost layer facilitates lamination of the elliptically polarizing plate with other members (such as liquid crystal cell), to thereby prevent peeling off of the elliptically polarizing plate from other members. Any suitable materials may be employed as a material for the sticking layer. Specific examples of the material include those described in the section B-4. A material having excellent humidity resistance and thermal resistance is preferably used in view of preventing foaming or peeling due to moisture absorption, degradation of optical characteristics and warping of a liquid crystal cell due to difference in thermal expansion, and the like.
For practical purposes, the surface of the sticking layer is covered with an appropriate separator until the elliptically polarizing plate is actually used, to thereby prevent contamination. The separator may be formed by providing a release coating on any suitable film by using a silicone-based, long-chain alkyl-based, fluorine-based, or molybdenum sulfide release agent, for example.
Each layer of the elliptically polarizing plate of the present invention may be provided with UV absorbability through treatment or the like with a UV absorber such as a salicylate-based compound, a benzophenone-based compound, a benzotriazole-based compound, a cyanoacrylate-based compound, or a nickel complex salt-based compound.
The elliptically polarizing plate of the present invention may be suitably used for various image display apparatuses (such as liquid crystal display and selfluminous display). Specific examples of the image display apparatus for which the elliptically polarizing plate may be used include a liquid crystal display, an EL display, a plasma display (PD), and a field emission display (FED). The elliptically polarizing plate of the present invention used for a liquid crystal display is useful for viewing angle compensation, for example. The elliptically polarizing plate of the present invention is used for a liquid crystal display of a circularly polarization mode, and is particularly useful for a homogeneous alignment TN liquid crystal display, an in-plane switching (IPS) liquid crystal display, and a vertical alignment (VA) liquid crystal display. The elliptically polarizing plate of the present invention used for an EL display is useful for prevention of electrode reflection, for example.
A liquid crystal display apparatus will be described as an example of an image display apparatus of the present invention. Here, a liquid crystal panel used for the liquid crystal display apparatus will be described. Any suitable constitutions may be employed for a constitution of the liquid crystal display apparatus excluding the liquid crystal panel in accordance with the purpose.
For example, a display mechanism of VA mode will be described.
Hereinafter, the present invention will be more specifically described by way of examples. However, the present invention is not limited to the examples. Methods of measuring characteristics in the examples are as described below.
Refractive indices nx, ny, and nz of a sample film were measured with an automatic birefringence analyzer (Automatic birefringence analyzer KOBRA-31PR manufactured by Oji Scientific Instruments), and an in-plane retardation Δnd a thickness direction retardation Rth were calculated. A measurement temperature was 23° C., and a measurement wavelength was 590 nm.
The thickness of each of the first and second birefringent layers was measured through interference thickness measurement by using MCPD-2000, manufactured by Otsuka Electronics Co., Ltd. The thickness of each of other various films was measured with a dial gauge.
The same elliptically polarizing plates obtained in Example 1 were attached together. The transmittance of the attached sample was measured with DOT-3 (trade name, manufactured by Murakami Color Research Laboratory).
The same elliptically polarizing plates were superimposed, and were irradiated with backlight. A white image (absorption axes of polarizers are in parallel with each other) and a black image (absorption axes of polarizers are perpendicular to each other) were displayed, and were scanned from 45° to 135° with respect to the absorption axis of the polarizer on the visual side, and from −60° to 60° with respect to the normal by using “EZ Contrast 160D” (trade name, manufactured by ELDIM SA). A contrast ratio “YW/YB” in an oblique direction was calculated from a Y value (YW) of the white image and a Y value (YB) of the black image.
Transparent protective films (T) were subjected to alignment treatment, to thereby prepare aligned substrates (eventually, protective layers 12).
Substrates (1) to (8): A PVA film (thickness of 0.1 μm) was formed on a surface of a TAC film (thickness of 40 μm). Then, the surface of the PVA film was subjected to rubbing at a rubbing angle shown in the following table by using a rubbing cloth, to thereby form each of aligned substrates.
Substrates (9) and (10): A TAC film (thickness of 40 μm) was subjected to rubbing at a rubbing angle shown in the following table by using a rubbing cloth, to thereby form each of aligned substrates.
10 g of polymerizable liquid crystal (liquid crystal monomer) (Paliocolor LC242, trade name; available from BASF Aktiengesellschaft) exhibiting a nematic liquid crystal phase, and 3 g of a photopolymerization initiator (IRGACURE 907, trade name; available from Ciba Specialty Chemicals) for the polymerizable liquid crystal compound were dissolved in 40 g of toluene, to thereby prepare a liquid crystal application liquid. The liquid crystal application liquid was applied onto the aligned substrate prepared as described above by using a bar coater, and the whole was heated and dried at 90° C. for 2 minutes, to thereby align the liquid crystal. The thus-formed liquid crystal layer was irradiated with light of 1 mJ/cm2 by using a metal halide lamp, and the polymerizable liquid crystal of the liquid crystal was polymerized so that the alignment of the liquid crystal layer was fixed, to thereby form each of first birefringent layers (1) to (3). The thickness and retardation of each of the first birefringent layers were adjusted by changing an application amount of the liquid crystal application liquid. The following table shows the thickness and in-plane retardation value (nm) of each of the first birefringent layers formed.
III-a. Preparation of Substrate
A polyethylene terephthalate roll (width of 4 m) having an alignment axis in a width direction and having a variation in alignment axis of ±1° or less with respect to an average direction of alignment axes was prepared.
III-b. Formation of Second Birefringent Layer (Part 1)
First, 9.9964 g of polymerizable liquid crystal (liquid crystal monomer) exhibiting a nematic liquid crystal phase (Paliocolor LC242, trade name, available from BASF Aktiengesellschaft, represented by the formula (10)), 0.0036 g of a chiral agent (Paliocolor LC756, trade name, available from BASF Aktiengesellschaft, represented by the formula (32)), and 3 g of a photopolymerization initiator (IRGACURE 907, trade name, available from Ciba Specialty Chemicals) for the polymerizable liquid crystal compound were dissolved in 40 g of toluene, to thereby prepare a liquid crystal application liquid. Then, through the same procedure as that in the above section II, a second birefringent layer (21) was formed. The following table shows the thickness and in-plane retardation value (nm) of the second birefringent layer formed, and the direction of the slow axis of the second birefringent layer formed with respect to the absorption axis of the polarizer.
III-b. Formation of Second Birefringent Layer (Part 2)
First, 9.9930 g of polymerizable liquid crystal (liquid crystal monomer) exhibiting a nematic liquid crystal phase (Paliocolor LC242, trade name, available from BASF Aktiengesellschaft), 0.0070 g of a chiral agent (Paliocolor LC756, trade name, available from BASF Aktiengesellschaft), and 3 g of a photopolymerization initiator (IRGACURE 907, trade name, available from Ciba Specialty Chemicals) for the polymerizable liquid crystal compound were dissolved in 40 g of toluene, to thereby prepare a liquid crystal application liquid. Then, through the same procedure as that in the above section II, a second birefringent layer (22) was formed. The following table shows the thickness and in-plane retardation value (nm) of the second birefringent layer formed, and the direction of the slow axis of the second birefringent layer formed with respect to the absorption axis of the polarizer.
III-b. Formation of Second Birefringent Layer (Part 3)
First, 9.9899 g of polymerizable liquid crystal (liquid crystal monomer) exhibiting a nematic liquid crystal phase (Paliocolor LC242, trade name, available from BASF Aktiengesellschaft), 0.0101 g of a chiral agent (Paliocolor LC756, trade name, available from BASF Aktiengesellschaft), and 3 g of a photopolymerization initiator (IRGACURE 907, trade name, available from Ciba Specialty Chemicals) for the polymerizable liquid crystal compound were dissolved in 40 g of toluene, to thereby prepare a liquid crystal application liquid. Then, through the same procedure as that in the above section II, a second birefringent layer (23) was formed. The following table shows the thickness and in-plane retardation value (nm) of the second birefringent layer formed, and the direction of the slow axis of the second birefringent layer formed with respect to the absorption axis of the polarizer.
A polyvinyl alcohol film was colored in an aqueous solution containing iodine and was then uniaxially stretched to 6 times length between rolls of different speed ratios in an aqueous solution containing boric acid, to thereby obtain a polarizer. The protective layer, the first birefringent layer, and the second birefringent layer were used in the combination shown in the following table. The polarizer, the protective layer, the first birefringent layer, and the second birefringent layer were laminated through the production procedure shown in
The elliptically polarizing plates A09 were superimposed to measure a contrast ratio. The elliptically polarizing plate had the minimum angle of 40° and maximum angle of 50° for contrast 10 in all directions, and a difference between the maximum and minimum angles of 10°. The minimum angle of 40° for contrast 10 in all directions was at a preferable level in practical use. Further, the difference between the maximum and minimum angles was as small as 10° and was also at a very preferable level in practical use, and thus the elliptically polarizing plate had balanced visual characteristics.
The elliptically polarizing plates A01 were superimposed to measure a contrast ratio. The elliptically polarizing plate had the minimum angle of 40° and maximum angle of 60° for contrast 10 in all directions, and a difference between the maximum and minimum angles of 20°. The minimum angle of 40° for contrast 10 in all directions was at a preferable level in practical use.
The elliptically polarizing plate of the present invention may suitably be used for various image display apparatuses (such as a liquid crystal display apparatus and a self-luminous display apparatus).
| Number | Date | Country | Kind |
|---|---|---|---|
| 2004-370503 | Dec 2004 | JP | national |
| Filing Document | Filing Date | Country | Kind | 371c Date |
|---|---|---|---|---|
| PCT/JP2005/020348 | 11/7/2005 | WO | 00 | 7/14/2008 |
