Claims
- 1. A composition providing dye protection benefits to fabric comprising:A) from 0.05% by weight, of a polymer, copolymer, or mixtures thereof, said polymer or copolymer comprising one or more units selected from the group consisting of: I) linear polymer units having the formula: wherein each R1 is independently a) hydrogen; b) C1-C4 alkyl; c) substituted or unsubstituted phenyl; d) substituted or unsubstituted benzyl; e) carbocyclic; f) heterocyclic; g) and mixtures thereof; each R2 is independently a) hydrogen; b) halogen c) C1-C4 alkyl; d) C1-C4 alkoxy; e) substituted or unsubstituted phenyl; f) substituted or unsubstituted benzyl; g) carbocyclic; h) heterocyclic; i) and mixtures thereof; each Z is independently a) hydrogen; b) hydroxyl; c) halogen; d) —(CH2)mR; wherein R is: i) hydrogen; ii) hydroxyl iii) halogen; iv) nitrilo; v) —OR3; vi) —O(CH2)nN(R3)2; vii) —O(CH2)n+(R3)3X−; viii) —OCO(CH2)nN(R3)2; ix) —OCO(CH2)nN+(R3)3X−; x) —NHCO(CH2)nN(R3)2; xi) —NHCO(CH2)nN+(R3)3X−; xii) —(CH2)nN(R3)2; xiii) —(CH2)nN+(R3)3X−; xiv) carbocyclic; xv) heterocyclic; xvi) nitrogen heterocycle quaternary ammonium; xvii) nitrogen heterocycle N-oxide; xviii) aromatic N-heterocyclic quaternary ammonium; xix) aromatic N-heterocyclic N-oxide; xx) —NHCHO; xxi) or mixtures thereof; each R3 is independently hydrogen, C1-C8 alkyl, C2-C8 hydroxyalkyl, and mixtures thereof; X is a water soluble anion; the index n is from 0 to 6 e) —(CH2)mCOR′ wherein R′ is i) —OR3; ii) —O(CH2)nN(R3)2; iii) —O(CH2)nN+(R3)3X−; iv) —NR3(CH2)nN(R3)2; v) —NR3(CH2)nN+(R3)3X−; vi) —(CH2)nN(R3)2; vii) —(CH2)nN+(R3)3X−; viii) or mixtures thereof; each R3 is independently hydrogen, C1-C8 alkyl, C2-C8 hydroxyalkyl, and mixtures thereof; X is a water soluble anion; the index n is from 0 to 6; f) and mixtures thereof; the index m is from 0 to 6; II) cyclic units derived from cyclically polymerizing monomers having the formula: wherein each R4 is independently an olefin comprising unit which is capable of propagating polymerization in addition to forming a cyclic residue with an adjacent R4 unit; R5 is C1-C12 linear or branched alkyl, benzyl, substituted benzyl, and mixtures thereof; X is a water soluble anion; and III) mixtures thereof; provided said polymer or co-polymer has a net cationic charge; B) a polyamine selected from the group consisting of N,N′-bis(aminopropyl)-1,3-propylenediamine, N,N′-bis(hydroxyethyl)-N,N′-bis[3-N,N-bis(hydroxyethyl)aminopropyl]-1,3-propylenediamine, N,N′-bis(2-hydroxypropyl)-N,N′-bis[3-N,N-bis(2-hydroxypropyl)aminopropyl]-1,3-propylenediamine, N,N′-bis(2-hydroxybutyl)-N,N′-bis[3-N,N-bis(2-hydroxybutyl)aminopropyl]-1,3-propylenediamine, 5-N-methyl dipropylenetriamine, 1,1-N-dimethyl-5-N′-methyl-9,9-N″-dimethyl dipropylenetriamine, 1,1-N-dimethyl-9,9-N″-dimethyl dipropylenetriamine, and mixtures thereof; and C) the balance carriers and adjunct ingredients.
- 2. A composition according to claim 1 comprising a co-polymer wherein each R1 is hydrogen, C1-C4 alkyl, phenyl and mixtures thereof and R2 is hydrogen, C1-C4 alkyl, and mixtures thereof.
- 3. A composition according to claim 2 comprising a co-polymer wherein Z has the formula:—(CH2)mCOR′wherein each R′ is independently —O(CH2)nN(R3)2; —O(CH2)nN+(R3)3X−; —(CH2)nN(R3)2; —(CH2)nN+(R3)3X−; and mixtures thereof, m is 0, n is from 2 to 4.
- 4. A composition according to claim 1 comprising a co-polymer wherein Z has the formula —CONH2, —CO2(CH2)2N+(CH3)3Cl−, and mixtures thereof, wherein the ratio of —CONH2 units to —CO2(CH2)2N+(CH3)3Cl−units is from 9:1 to 1:9.
- 5. A composition according to claim 2 wherein said composition further comprises from 1% to 80% by weight, of a fabric softening active, said fabric softener active comprises a quaternary ammonium compound having the formula: an amine having the formula: and mixtures thereof; wherein each R is independently C1-C6 alkyl, C1-C6 hydroxyalkyl, benzyl, and mixtures thereof; R1 is C1-C22 alkyl, C3-C22 alkenyl, and mixtures thereof; Q is a carbonyl moiety having the formula: wherein R2 is hydrogen, C1-C4 alkyl, C1-C4 hydroxyalkyl, and mixtures thereof; R3 is hydrogen, C1-C4 alkyl, and mixtures thereof; X is a softener compatible anion; m is from 1 to 3; n is from 1 to 4.
- 6. A composition according to claim 5, further comprising a crystal growth inhibitor comprising 2-phosphonobutane-1,2,4-tricarboxylic acid and a dye fixing agent comprising dodecyl trimethylammonium chloride.
- 7. A composition for providing enhanced fabric protection to fabric, said composition comprising:a) from 0.05% by weight, of a polymer, copolymer, or mixtures thereof, said polymer or copolymer comprising one or more units selected from the group consisting of: I) linear polymer units having the formula: wherein each R1 is independently a) hydrogen; b) C1-C4 alkyl; c) substituted or unsubstituted phenyl; d) substituted or unsubstituted benzyl; e) carbocyclic; f) heterocyclic; g) and mixtures thereof; each R2 is independently a) hydrogen; b) halogen c) C1-C4 alkyl; d) C1-C4 alkoxy; e) substituted or unsubstituted phenyl; f) substituted or unsubstituted benzyl; g) carbocyclic; h) heterocyclic; i) and mixtures thereof; each Z is independently a) hydrogen; b) hydroxyl; c) halogen; d) —(CH2)mR; wherein R is: i) hydrogen; ii) hydroxyl iii) halogen; iv) nitrilo; v) —OR3; vi) —O(CH2)nN(R3)2; vii) —O(CH2)n+(R3)3X−; viii) —OCO(CH2)nN(R3)2; ix) —OCO(CH2)nN+(R3)3X−; x) —NHCO(CH2)nN(R3)2; xi) —NHCO(CH2)nN+(R3)3X−; xii) —(CH2)nN(R3)2; xiii) —(CH2)nN+(R3)3X−; xiv) carbocyclic; xv) heterocyclic; xvi) nitrogen heterocycle quaternary ammonium; xvii) nitrogen heterocycle N-oxide; xviii) aromatic N-heterocyclic quaternary ammonium; xix) aromatic N-heterocyclic N-oxide; xx) —NHCHO; xxi) or mixtures thereof; each R3 is independently hydrogen, C1-C8 alkyl, C2-C8 hydroxyalkyl, and mixtures thereof; X is a water soluble anion; the index n is from 0 to 6 e) —(CH2)mCOR′ wherein R′ is i) —OR3; ii) —O(CH2)nN(R3)2; iii) —O(CH2)nN+(R3)3X−; iv) —NR3(CH2)nN(R3)2; v) —NR3(CH2)nN+(R3)3X−; vi) —(CH2)nN(R3)2; vii) —(CH2)nN+(R3)3X−; viii) or mixtures thereof; each R3 is independently hydrogen, C1-C8 alkyl, C2-C8 hydroxyalkyl, and mixtures thereof; X is a water soluble anion; the index n is from 0 to 6; f) and mixtures thereof; the index m is from 0 to 6; II) cyclic units derived from cyclically polymerizing monomers having the formula: wherein each R4 is independently an olefin comprising unit which is capable of propagating polymerization in addition to forming a cyclic residue with an adjacent R4 unit; R5 is C1-C12 linear or branched alkyl, benzyl, substituted benzyl, and mixtures thereof; X is a water soluble anion; and III) mixtures thereof; provided said polymer or co-polymer has a net cationic charge; b) from 0.01% to 50% by weight, of a polyamine, said polyamine is selected from the group consisting of N,N′-bis(aminopropyl)-1,3-propylenediamine; N,N′-bis(hydroxyethyl)-N,N′-bis[3-N,N-bis(hydroxyethyl)aminopropyl]-1,3-propylenediamine; N,N′-bis(2-hydroxypropyl)-N,N′-bis[3-N,N-bis(2-hydroxypropyl)aminopropyl]-1,3-propylenediamine; N,N′-bis(2-hydroxybutyl)-N,N′-bis[3-N,N-bis(2-hydroxybutyl)aminopropyl]-1,3-propylenediamine; 5-N-methyl dipropylenetriamine; 1,1-N-dimethyl-5-N′-methyl-9,9-N″-dimethyl dipropylenetriamine; 1,1-N-dimethyl-9,9-N″-dimethyl dipropylenetriamine; and mixtures thereof; c) from 0.005% to 1% by weight, of one or more crystal growth inhibitors; d) from 0.001% to 90% by weight, of one or more dye fixing agents; and e) the balance carriers and adjunct ingredients.
- 8. A composition providing dye protection benefits to fabric comprising:a) from 0.05% by weight, of a copolymer having the formula: wherein Z1 has the formula: Z2 has the formula: x has the value of from 10 to 100,000; y has the value of from 10 to 100,000; the ratio of x to y is from 9:1 to 1:9; B) a polyamine selected from the group consisting of N,N′-bis(aminopropyl)-1,3-propylenediamine, N,N′-bis(hydroxyethyl)-N,N′-bis[3-N,N-bis(hydroxyethyl)aminopropyl]-1,3-propylenediamine, N,N′-bis(2-hydroxypropyl)-N,N′-bis[3-N,N-bis(2-hydroxypropyl)aminopropyl]-1,3-propylenediamine, N,N′-bis(2-hydroxybutyl)-N,N′-bis[3-N,N-bis(2-hydroxybutyl)aminopropyl]-1,3-propylenediamine, 5-N-methyl dipropylenetriamine, 1,1-N-dimethyl-5-N′-methyl-9,9-N″-dimethyl dipropylenetriamine, 1,1-N-dimethyl-9,9-N″-dimethyl dipropylenetriamine, and mixtures thereof; and C) the balance carriers and adjunct ingredients.
- 9. A composition providing dye protection benefits to fabric comprising:A) from 0.05% by weight, of a polymer, copolymer, or mixtures thereof, said polymer or copolymer comprising one or more units selected from the group consisting of: I) linear polymer units having the formula: wherein each R1 is independently a) hydrogen; b) C1-C4 alkyl; c) substituted or unsubstituted phenyl; d) substituted or unsubstituted benzyl; e) carbocyclic; f) heterocyclic; g) and mixtures thereof; each R2 is independently a) hydrogen; b) halogen c) C1-C4 alkyl; d) C1-C4 alkoxy; e) substituted or unsubstituted phenyl; f) substituted or unsubstituted benzyl; g) carbocyclic; h) heterocyclic; i) and mixtures thereof; each Z is independently a) hydrogen; b) hydroxyl; c) halogen; d) —(CH2)mR; wherein R is: i) hydrogen; ii) hydroxyl iii) halogen; iv) nitrilo; v) —OR3; vi) —O(CH2)nN(R3)2; vii) —O(CH2)nN+(R3)3X−; viii) —OCO(CH2)nN(R3)2; ix) —OCO(CH2)nN+(R3)3X−; x) —NHCO(CH2)nN(R3)2; xi) —NHCO(CH2)nN+(R3)3X−; xii) —(CH2)nN(R3)2; xiii) —(CH2)nN+(R3)3X−; xiv) carbocyclic; xv) heterocyclic; xvi) nitrogen heterocycle quaternary ammonium; xvii) nitrogen heterocycle N-oxide; xviii) aromatic N-heterocyclic quaternary ammonium; xix) aromatic N-heterocyclic N-oxide; xx) —NHCHO; xxi) or mixtures thereof; each R3 is independently hydrogen, C1-C8 alkyl, C2-C8 hydroxyalkyl, and mixtures thereof; X is a water soluble anion; the index n is from 0 to 6 e) —(CH2)mCOR′ wherein R′ is i) —OR3; ii) —O(CH2)nN(R3)2; iii) —O(CH2)nN+(R3)3X−; iv) —NR3(CH2)nN(R3)2; v) —NR3(CH2)nN+(R3)3X−; vi) —(CH2)nN(R3)2; vii) —(CH2)nN+(R3)3X−; viii) or mixtures thereof; each R3 is independently hydrogen, C1-C8 alkyl, C2-C8 hydroxyalkyl, and mixtures thereof; X is a water soluble anion; the index n is from 0 to 6; f) and mixtures thereof; the index m is from 0 to 6; II) cyclic units derived from cyclically polymerizing monomers having the formula: wherein each R4 is independently an olefin comprising unit which is capable of propagating polymerization in addition to forming a cyclic residue with an adjacent R4 unit; R5 is C1-C12 linear or branched alkyl, benzyl, substituted benzyl, and mixtures thereof; X is a water soluble anion; and E) mixtures thereof; provided said polymer or co-polymer has a net cationic charge; B) from 0.01% by weight, of a fabric abrasion reducing polymer, said fabric abrasion polymer comprising: i) at least one monomeric unit comprising an amide moiety; ii) at least one monomeric unit comprising an N-oxide moiety; iii) and mixtures thereof; C) optionally from 1% by weight, of a fabric softening active; D) optionally less than 15% by weight, of a principal solvent, said principal solvent has a ClogP of from 0.15 to 1; E) optionally from 0.001% to 90% by weight, of one or more dye fixing agents; F) optionally from 0.01% to 50% by weight, of one or more cellulose reactive dye fixing agents; G) optionally from 0.01% to 15% by weight, of a chlorine scavenger; H) 0.005% to 1% by weight, of one or more crystal growth inhibitors; I) optionally from 1% to 12% by weight, of one or more liquid carriers; J) optionally from 0.001% to 1% by weight, of an enzyme; K) optionally from 0.01% to 8% by weight, of a polyolefin emulsion or suspension; L) optionally from 0.01% to 0.2% by weight, of a stabilizer; M) optionally from 1% to 80% by weight, of a cationic surfactant; N) from 0.01% by weight, of one or more linear or cyclic polyamines which provide bleach protection; and O) the balance carriers and adjunct ingredients.
Parent Case Info
This application claims the benefit of U.S. Provisional Application Ser. No. 60/126,072 filed Mar. 25, 1999.
PCT Information
| Filing Document |
Filing Date |
Country |
Kind |
| PCT/US00/08030 |
|
WO |
00 |
| Publishing Document |
Publishing Date |
Country |
Kind |
| WO00/56848 |
9/28/2000 |
WO |
A |
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Provisional Applications (1)
|
Number |
Date |
Country |
|
60/126072 |
Mar 1999 |
US |
Patent Grant
6642200
