1. Field of Invention
The present invention relates to a system for thin film deposition, and more particularly to a system for evaporating a film precursor and delivering the vapor to a deposition chamber.
2. Description of Related Art
The introduction of copper (Cu) metal into multilayer metallization schemes for manufacturing integrated circuits can necessitate the use of diffusion barriers/liners to promote adhesion and growth of the Cu layers and to prevent diffusion of Cu into the dielectric materials. Barriers/liners that are deposited onto dielectric materials can include refractive materials, such as tungsten (W), molybdenum (Mo), and tantalum (Ta), that are non-reactive and immiscible in Cu, and can offer low electrical resistivity. Current integration schemes that integrate Cu metallization and dielectric materials can require barrier/liner deposition processes at substrate temperatures between about 400° C. and about 500° C., or lower.
For example, Cu integration schemes for technology nodes less than or equal to 130 nm currently utilize a low dielectric constant (low-k) inter-level dielectric, followed by a physical vapor deposition (PVD) TaN layer and Ta barrier layer, followed by a PVD Cu seed layer, and an electrochemical deposition (ECD) Cu fill. Generally, Ta layers are chosen for their adhesion properties (i.e., their ability to adhere on low-k films), and Ta/TaN layers are generally chosen for their barrier properties (i.e., their ability to prevent Cu diffusion into the low-k film).
As described above, significant effort has been devoted to the study and implementation of thin transition metal layers as Cu diffusion barriers, these studies including such materials as chromium, tantalum, molybdenum and tungsten. Each of these materials exhibits low miscibility in Cu. More recently, other materials, such as ruthenium (Ru) and rhodium (Rh), have been identified as potential barrier layers since they are expected to behave similarly to conventional refractory metals.
The present invention provides a multi-tray film precursor evaporation system and a system for depositing a thin film from a film precursor vapor delivered from the multi-tray film precursor evaporation system. The film precursor may be a solid metal precursor. The present invention further provides a system for depositing a metal film from a solid metal precursor at a high rate. To this end, a film precursor evaporation system configured to be coupled to a thin film deposition system is provided that comprises a container having an outer wall and a bottom, and configured to be heated to an elevated temperature by a heater. A lid is configured to be sealably coupled to the container. The lid has an outlet configured to be sealably coupled to the thin film deposition system. A tray stack is positioned in the container and includes one or more trays including a first tray supported in the container and one or more optional additional trays configured to be positioned on one of the first tray or a preceding additional tray.
In certain embodiments of the invention, each of the one or more trays includes a first tray supported in said container and one or more optional additional trays configured to be positioned on a preceding additional tray. Each of the trays has an inner tray wall and an outer tray wall, one of which walls is a support wall having a support edge for supporting one of the optional additional trays. The inner and outer tray walls are configured to retain the film precursor between them. The inner tray walls define a central flow channel in the container, and the outer tray walls of the tray stack and the outer wall of the container have an annular space therebetween defining a peripheral flow channel in said container, one of said channels being a supply channel configured to be coupled to a carrier gas supply system to supply a carrier gas to the channel and the other of the channels is an exhaust channel configured to be coupled to the outlet in the lid. One or more openings are provided in the support walls of the tray stack and coupled to the supply channel, and configured to flow carrier gas from the supply channel, over the film precursor towards the exhaust channel, and to exhaust the carrier gas through the outlet in the lid with film precursor vapor.
In one embodiment, each of the one or more trays comprises an inner tray wall with a support edge for supporting one of the optional additional trays and an outer tray wall. The inner and outer tray walls are configured to retain the film precursor therebetween. Additionally, the inner tray walls define a central flow channel in the container configured to be coupled to a carrier gas supply system to supply a carrier gas to the central flow channel. An annular space is formed between the outer tray walls of the tray stack and the outer wall of the container, wherein the annular space defines a peripheral flow channel that is configured to be coupled to the outlet in the lid. One or more openings are positioned in the inner tray walls of the tray stack and coupled to the central flow channel. The one or more openings are configured to flow carrier gas from the central flow channel, over the film precursor towards the annular space, and to exhaust the carrier gas through the outlet in the lid with film precursor vapor. In one embodiment, the trays are separatable and stackable within the container, and in another embodiment, the trays are formed as an integral, unitary piece.
The present invention further provides a deposition system for forming a thin film on a substrate. The deposition system comprises a process chamber having a substrate holder configured to support the substrate and heat the substrate, a vapor distribution system configured to introduce a film precursor vapor above the substrate, and a pumping system configured to evacuate the process chamber. A film precursor evaporation system of the present invention configured to evaporate a film precursor is coupled to the vapor distribution system by a vapor delivery system having a first end coupled to the outlet of the film precursor evaporation system and a second end coupled to an inlet of the vapor distribution system of the process chamber. In one embodiment, a carrier gas supply system is coupled to the central flow channel in the container for providing carrier gas to the tray stack, which is then exhausted through the outlet with film precursor vapor and delivered to the process chamber via the vapor delivery system.
In the accompanying drawings:
In the following description, in order to facilitate a thorough understanding of the invention and for purposes of explanation and not limitation, specific details are set forth, such as a particular geometry of the deposition system and descriptions of various components. However, it should be understood that the invention may be practiced in other embodiments that depart from these specific details.
Referring now to the drawings, wherein like reference numerals designate identical or corresponding parts throughout the several views,
The process chamber 10 is further coupled to a vacuum pumping system 38 through a duct 36, wherein the pumping system 38 is configured to evacuate the process chamber 10, vapor precursor delivery system 40, and film precursor evaporation system 50 to a pressure suitable for forming the thin film on the Substrate 25, and suitable for evaporation of a film precursor (not shown) in the film precursor evaporation system 50.
Referring still to
In order to achieve the desired temperature for evaporating the film precursor (or subliming a solid metal precursor), the film precursor evaporation system 50 is coupled to an evaporation temperature control system 54 configured to control the evaporation temperature. For instance, the temperature of the film precursor is generally elevated to approximately 40 degrees C. or greater in conventional systems in order to sublime or evaporate the film precursor. As the film precursor is heated to cause evaporation (or sublimation), a carrier gas is passed over the film precursor or by the film precursor. The carrier gas can include, for example, an inert gas, such as a noble gas (i.e., He, Ne, Ar, Kr, Xe), or a monoxide, such as carbon monoxide (CO), for use with metal-carbonyls, or a mixture thereof. For example, a carrier gas supply system 60 is coupled to the film precursor evaporation system 50, and it is configured to, for instance, supply the carrier gas above the film precursor via feed line 61. In another example, carrier gas supply system 60 is coupled to the vapor precursor delivery system 40 and is configured to supply the carrier gas to the vapor of the film precursor via feed line 63 as or after it enters the vapor precursor delivery system 40. Although not shown, the carrier gas supply system 60 can comprise a gas source, one or more control valves, one or more filters, and a mass flow controller. For instance, the flow rate of carrier gas can range from approximately 5 sccm (standard cubic centimeters per minute) to approximately 1000 sccm. For example, the flow rate of carrier gas can range from about 10 sccm to about 200 sccm. By way of further example, the flow rate of carrier gas can range from about 20 sccm to about 100 sccm.
Downstream from the film precursor evaporation system 50, the film precursor vapor flows with the carrier gas through the vapor precursor delivery system 40 until it enters a vapor distribution system 30 coupled to the process chamber 10. The vapor precursor delivery system 40 can be coupled to a vapor line temperature control system 42 in order to control the vapor line temperature, and prevent decomposition of the film precursor vapor as well as condensation of the film precursor vapor. For example, the vapor line temperature can be set to a value approximately equal to or greater than the evaporation temperature. Additionally, for example, the vapor precursor delivery system 40 can be characterized by a high conductance in excess of about 50 liters/second.
Referring again to
Once film precursor vapor enters the processing zone 33, the film precursor vapor thermally decomposes upon adsorption at the substrate surface due to the elevated temperature of the substrate 25, and the thin film is formed on the substrate 25. The substrate holder 20 is configured to elevate the temperature of substrate 25, by virtue of the substrate holder 20 being coupled to a substrate temperature control system 22. For example, the substrate temperature control system 22 can be configured to elevate the temperature of substrate 25 up to approximately 500 degrees C. In one embodiment, the substrate temperature can range from about 100 degrees C. to about 500 degrees C. In another embodiment, the substrate temperature can range from about 300 degrees C. to about 400 degrees C. Additionally, the process chamber 10 can be coupled to a chamber temperature control system 12 configured to control the temperature of the chamber walls.
As described above, for example, conventional systems have contemplated operating the film precursor evaporation system 50, as well as the vapor precursor delivery system 40, at a temperature greater than or equal to approximately 40 degrees C. in order to limit metal vapor precursor decomposition, and metal vapor precursor condensation.
It may also be desirable to periodically clean deposition system 1 following processing of one or more substrates. For example, additional details on a cleaning method and system can be obtained from co-pending U.S. patent application Ser. No. 10/998,394, filed on Nov. 29, 2004 and entitled “Method and System for Performing In-situ Cleaning of a Deposition System”, which is herein incorporated by reference in its entirety.
As discussed above, the deposition rate is proportional to the amount of film precursor that is evaporated and transported to the substrate prior to decomposition, or condensation, or both. Therefore, in order to achieve a desired deposition rate, and to maintain consistent processing performance (i.e., deposition rate, film thickness, film uniformity, film morphology, etc.) from one substrate to the next, it is important to provide the ability to monitor, adjust, or control the flow rate of the film precursor vapor. In conventional systems, an operator may indirectly determine the flow rate of film precursor vapor by using the evaporation temperature, and a pre-determined relationship between the evaporation temperature and the flow rate. However, processes and their performance drift in time, and hence it is imperative that the flow rate is measured more accurately. For example, additional details can be obtained from co-pending U.S. patent application Ser. No. 10/998,393, filed on Nov. 29, 2004 and entitled “Method and System for Measuring a Flow Rate in a Solid Precursor Delivery System”, which is herein incorporated by reference in its entirety.
Still referring the
In yet another embodiment,
The process chamber 110 comprises an upper chamber section 111, a lower chamber section 112, and an exhaust chamber 113. An opening 114 is formed within lower chamber section 112, where bottom section 112 couples with exhaust chamber 113.
Referring still to
During processing, the heated substrate 125 can thermally decompose the vapor of film precursor vapor, such as a metal-containing film precursor, and enable deposition of a thin film, such as a metal layer, on the substrate 125. According to one embodiment, the film precursor includes a solid precursor. According to another embodiment, the film precursor includes a metal precursor. According to another embodiment, the film precursor includes a solid metal precursor. According to yet another embodiment, the film precursor includes a metal-carbonyl precursor. According to yet another embodiment, the film precursor can be a ruthenium-carbonyl precursor, for example Ru3(CO)12. According to yet another embodiment of the invention, the film precursor can be a rhenium carbonyl precursor, for example Re2(CO)10. As will be appreciated by those skilled in the art of thermal chemical vapor deposition, other ruthenium carbonyl precursors and rhenium carbonyl precursors can be used without departing from the scope of the invention. In yet another embodiment, the film precursor can be W(CO)6, Mo(CO)6, Co2(CO)8, Rh4(CO)12, Cr(CO)6, or Os3(CO)12. Additionally, for example, when depositing tantalum (Ta), the film precursor can include TaF5, TaCl5, TaBr5, TaI5, Ta(CO)5, Ta[N(C2H5CH3)]5 (PEMAT), Ta[N(CH3)2]5 (PDMAT), Ta[N(C2H5)2]5 (PDEAT), Ta(NC(CH3)3)(N(C2H5)2)3 (TBTDET), Ta(NC2H5)(N(C2H5)2)3, Ta(NC(CH3)2C2H5)(N(CH3)2)3, Ta(NC(CH3)3)(N(CH3)2)3, or Ta(EtCp)2(CO)H. Additionally, for example, when depositing titanium (Ti), the film precursor can include TiF4, TiCl4, TiBr4, TiI4, Ti[N(C2H5CH3)]4 (TEMAT), Ti[N(CH3)2]4 (TDMAT), or Ti[N(C2H5)2]4 (TDEAT). Additionally, for example, when depositing ruthenium (Ru), the film precursor can include Ru(C5H5)2, Ru(C2H5C5H4)2, Ru(C3H7C5H4)2, Ru(CH3C5H4)2, Ru3(CO)12, C5H4Ru(CO)3, RuCl3, Ru(C11H19O2)3, Ru(C8H13O2)3, or Ru(C5H7O)3.
The substrate holder 120 is heated to a pre-determined temperature that is suitable for depositing, for instance, a desired metal layer onto the substrate 125. Additionally, a heater (not shown), coupled to a chamber temperature control system 121, can be embedded in the walls of process chamber 110 to heat the chamber walls to a pre-determined temperature. The heater can maintain the temperature of the walls of the process chamber 110 from about 40 degrees C. to about 100 degrees C., for example from about 40 degrees C. to about 80 degrees C. A pressure gauge (not shown) is used to measure the process chamber pressure.
Also shown in
Furthermore, an opening 135 is provided in the upper chamber section 111 for introducing a vapor precursor from the vapor precursor delivery system 140 into vapor distribution plenum 132. Moreover, temperature control elements 136, such as concentric fluid channels configured to flow a cooled or heated fluid, are provided for controlling the temperature of the vapor distribution system 130, and thereby prevent the decomposition of the film precursor inside the vapor distribution system 130. For instance, a fluid, such as water, can be supplied to the fluid channels from a vapor distribution temperature control system 138. The vapor distribution temperature control system 138 can include a fluid source, a heat exchanger, one or more temperature sensors for measuring the fluid temperature or vapor distribution plate temperature or both, and a controller configured to control the temperature of the vapor distribution plate 131 from about 20 degrees C. to about 100 degrees C.
Film precursor evaporation system 150 is configured to hold a film precursor, and evaporate (or sublime) the film precursor by elevating the temperature of the film precursor. A precursor heater 154 is provided for heating the film precursor to maintain the film precursor at a temperature that produces a desired vapor pressure of film precursor. The precursor heater 154 is coupled to an evaporation temperature control system 156 configured to control the temperature of the film precursor. For example, the precursor heater 154 can be configured to adjust the temperature of the film precursor (or evaporation temperature) to be greater than or equal to approximately 40 degrees C. Alternatively, the evaporation temperature is elevated to be greater than or equal to approximately 50 degrees C. For example, the evaporation temperature is elevated to be greater than or equal to approximately 60 degrees C. In one embodiment, the evaporation temperature is elevated to range from approximately 60 to 100 degrees C., and in another embodiment, to range from approximately 60 to 90 degrees C. Additionally, precursor heaters may be provided in each of the trays. Such heaters can, for example, be of the resistance heating type.
As the film precursor is heated to cause evaporation (or sublimation), a carrier gas can be passed over the film precursor, or by the film precursor. The carrier gas can include, for example, an inert gas, such as a noble gas (i.e., He, Ne, Ar, Kr, Xe), or a monoxide, such as carbon monoxide (CO), for use with metal-carbonyls, or a mixture thereof. For example, a carrier gas supply system 160 is coupled to the film precursor evaporation system 150, and it is configured to, for instance, supply the carrier gas above the film precursor. Although not shown in
Additionally, a sensor 166 is provided for measuring the total gas flow from the film precursor evaporation system 150. The sensor 166 can, for example, comprise a mass flow controller, and the amount of film precursor delivered to the process chamber 110, can be determined using sensor 166 and mass flow controller 165. Alternately, the sensor 166 can comprise a light absorption sensor to measure the concentration of the film precursor in the gas flow to the process chamber 110.
A bypass line 167 can be located downstream from sensor 166, and it can connect the vapor delivery system 140 to an exhaust line 116. Bypass line 167 is provided for evacuating the vapor precursor delivery system 140, and for stabilizing the supply of the film precursor to the process chamber 110. In addition, a bypass valve 168, located downstream from the branching of the vapor precursor delivery system 140, is provided on bypass line 167.
Referring still to
Moreover, dilution gases can be supplied from a dilution gas supply system 190. The dilution gas can include, for example, an inert gas, such as a noble gas (i.e., He, Ne, Ar, Kr, Xe), or a monoxide, such as carbon monoxide (CO), for use with metal-carbonyls, or a mixture thereof. For example, the dilution gas supply system 190 is coupled to the vapor precursor delivery system 140, and it is configured to, for instance, supply the dilution gas to vapor film precursor. The dilution gas supply system 190 can comprise a gas source 191, one or more control valves 192, one or more filters 194, and a mass flow controller 195. For instance, the flow rate of carrier gas can range from approximately 5 sccm (standard cubic centimeters per minute) to approximately 1000 sccm.
Mass flow controllers 165 and 195, and valves 162, 192, 168, 141, and 142 are controlled by a controller 196, which controls the supply, shutoff, and the flow of the carrier gas, the film precursor vapor, and the dilution gas. The sensor 166 is also connected to the controller 196 and, based on output of the sensor 166, the controller 196 can control the carrier gas flow through mass flow controller 165 to obtain the desired film precursor flow to the process chamber 110.
As illustrated in
Referring back to the substrate holder 120 in the process chamber 110, as shown in
Referring again to
However, the controller 180 may be implemented as a general purpose computer system that performs a portion or all of the microprocessor based processing steps of the invention in response to a processor executing one or more sequences of one or more instructions contained in a memory. Such instructions may be read into the controller memory from another computer readable medium, such as a hard disk or a removable media drive. One or more processors in a multi-processing arrangement may also be employed as the controller microprocessor to execute the sequences of instructions contained in main memory. In alternative embodiments, hard-wired circuitry may be used in place of or in combination with software instructions. Thus, embodiments are not limited to any specific combination of hardware circuitry and software.
The controller 180 includes at least one computer readable medium or memory, such as the controller memory, for holding instructions programmed according to the teachings of the invention and for containing data structures, tables, records, or other data that may be necessary to implement the present invention. Examples of computer readable media are compact discs, hard disks, floppy disks, tape, magneto-optical disks, PROMs (EPROM, EEPROM, flash EPROM), DRAM, SRAM, SDRAM, or any other magnetic medium, compact discs (e.g., CD-ROM), or any other optical medium, punch cards, paper tape, or other physical medium with patterns of holes, a carrier wave (described below), or any other medium from which a computer can read.
Stored on any one or on a combination of computer readable media, the present invention includes software for controlling the controller 180, for driving a device or devices for implementing the invention, and/or for enabling the controller to interact with a human user. Such software may include, but is not limited to, device drivers, operating systems, development tools, and applications software. Such computer readable media further includes the computer program product of the present invention for performing all or a portion (if processing is distributed) of the processing performed in implementing the invention.
The computer code devices of the present invention may be any interpretable or executable code mechanism, including but not limited to scripts, interpretable programs, dynamic link libraries (DLLs), Java classes, and complete executable programs. Moreover, parts of the processing of the present invention may be distributed for better performance, reliability, and/or cost.
The term “computer readable medium” as used herein refers to any medium that participates in providing instructions to the processor of the controller 180 for execution. A computer readable medium may take many forms, including but not limited to, non-volatile media, volatile media, and transmission media. Non-volatile media includes, for example, optical, magnetic disks, and magneto-optical disks, such as the hard disk or the removable media drive. Volatile media includes dynamic memory, such as the main memory. Moreover, various forms of computer readable media may be involved in carrying out one or more sequences of one or more instructions to processor of controller for execution. For example, the instructions may initially be carried on a magnetic disk of a remote computer. The remote computer can load the instructions for implementing all or a portion of the present invention remotely into a dynamic memory and send the instructions over a network to the controller 180.
The controller 180 may be locally located relative to the deposition system 100, or it may be remotely located relative to the deposition system 100 via an internet or intranet. Thus, the controller 180 can exchange data with the deposition system 100 using at least one of a direct connection, an intranet, or the internet. Controller 180 may be coupled to an intranet at a customer site (i.e., a device maker, etc.), or coupled to an intranet at a vendor site (i.e., an equipment manufacturer). Furthermore, another computer (i.e., controller, server, etc.) can access the controller 180 to exchange data via at least one of a direct connection, an intranet, or the internet.
Referring now to
Furthermore, the container 310 is configured to be coupled to a heater (not shown) in order to elevate the evaporation temperature of the film precursor evaporation system 300, and to a temperature control system (not shown) in order to perform at least one of monitoring, adjusting, or controlling the evaporation temperature. When the evaporation temperature is elevated to an appropriate value as described earlier, film precursor evaporates (or sublimes) forming film precursor vapor to be transported through the vapor delivery system to the thin film deposition system. The container 310 is also sealably coupled to a carrier gas supply system (not shown), wherein the container 310 is configured to receive a carrier gas for transporting the film precursor vapor.
Referring still to
Referring still to
The base tray 330 and the stackable upper trays 340 are depicted to be cylindrical in shape. However, the shape can vary. For instance, the shape of the trays can be rectangular, square or oval. Similarly, the inner walls 344, and thus central upper flow channel 318, can be differently shaped.
When one or more stackable upper trays 340 are stacked upon the base tray 330, a stack 370 is formed, which provides for a carrier gas supply space in the form of a peripheral channel, such as an annular space 360, between the base outer wall 332 of the base tray 330 and the container outer wall 312, and between the upper outer walls 342 of the one or more stackable upper trays 340 and the container outer wall 312. The container 310 can further comprise one or more spacers (not shown) configured to space the base outer wall 332 of the base tray 330 and the upper outer walls 342 of the one or more stackable upper trays 340 from the container outer wall 312, and thereby ensure equal spacing within the annular space 360. To state it another way, in one embodiment, the container 310 is configured such that the base outer wall 332 and the upper outer walls 342 are in vertical alignment. Additionally, the container 310 can comprise one or more thermal contact members (not shown) configured to provide mechanical contact between the inner wall of the container 310 and the outer wall of each tray, thereby assisting the conduction of thermal energy from the wall of the container 310 to each respective tray.
A sealing device, such as an O-ring, may be located between each tray and the adjacent tray or trays in order to provide a vacuum seal between one tray and the next. For example, the sealing device can be retained in a receiving groove (not shown) formed in the upper support edge 343 of upper outer wall(s) 342 and the base support edge 333 of base outer wall 332. Therefore, once the trays are installed in container 310, the coupling of lid 320 to container 310 can facilitate compression of each sealing device. The sealing device can, for example, include an elastomer O-ring. Additionally, the sealing device can, for example, include a VITON O-ring.
The number of trays, including both the base tray and the stackable upper trays, can range from two (2) to twenty (20) and, for example in one embodiment, the number of trays can be five (5), as shown in
The base tray 330 and each of the upper trays 340, whether stackable or integral, are configured to support a film precursor 350. According to one embodiment, the film precursor 350 includes a solid precursor. According to another embodiment, the film precursor 350 includes a liquid precursor. According to another embodiment, the film precursor 350 includes a metal precursor. According to another embodiment, the film precursor 350 includes a solid metal precursor. According to yet another embodiment, the film precursor 350 includes a metal-carbonyl precursor. According to yet another embodiment, the film precursor 350 can be a ruthenium-carbonyl precursor, for example Ru3(CO)12. According to yet another embodiment of the invention, the film precursor 350 can be a rhenium carbonyl precursor, for example Re2(CO)10. In yet another embodiment, the film precursor 350 can be W(CO)6, Mo(CO)6, Co2(CO)8, Rh4(CO)12, Cr(CO)6, or Os3(CO)12. Additionally, according to yet another embodiment, when depositing tantalum (Ta), the film precursor 350 can include TaF5, TaCl5, TaBr5, TaI5, Ta(CO)5, Ta[N(C2H5CH3)]5 (PEMAT), Ta[N(CH3)2]5 (PDMAT), Ta[N(C2H5)2]5 (PDEAT), Ta(NC(CH3)3)(N(C2H5)2)3 (TBTDET), Ta(NC2H5)(N(C2H5)2)3, Ta(NC(CH3)2C2H5)(N(CH3)2)3, Ta(NC(CH3)3)(N(CH3)2)3, or Ta(EtCp)2(CO)H. Additionally, according to yet another embodiment, when depositing titanium (Ti), the film precursor 350 can include TiF4, TiCl4, TiBr4, TiI4, Ti[N(C2H5CH3)]4 (TEMAT), Ti[N(CH3)2]4 (TDMAT), or Ti[N(C2H5)2]4 (TDEAT). Additionally, according to yet another embodiment, when depositing ruthenium (Ru), the film precursor 350 can include Ru(C5H5)2, Ru(C2H5C5H4)2, Ru(C3H7C5H4)2, Ru(CH3C5H4)2, Ru3(CO)12, C5H4Ru(CO)3, RuCl3, Ru(C11H19O2)3, Ru(C8H13O2)3, or Ru(C5H7O)3.
As described above, the film precursor 350 can include a solid precursor. The solid precursor can take the form of a solid powder, or it may take the form of one or more solid tablets. For example, the one or more solid tablets can be prepared by a number of processes, including a sintering process, a stamping process, a dipping process, or a spin-on process, or any combination thereof. Additionally, the solid precursor in solid tablet form may or may not adhere to the base tray 330 or upper tray 340. For example, a refractory metal powder may be sintered in a sintering furnace configured for both vacuum and inert gas atmospheres, and temperature up to 2000° C. and 2500° C. Alternatively, for example, a refractory metal powder can be dispersed in a fluid medium, dispensed on a tray, and distributed evenly over the tray surfaces using a spin coating process. The refractory metal spin coat may then be thermally cured.
As described earlier, carrier gas is supplied to the container 310 from a carrier gas supply system (not shown). As shown in
Alternatively, as shown in
Referring again to
Referring yet again to
Additionally, the evaporation exhaust space, i.e., central flow channel 318, can be designed for high flow conductance. For example, the net flow conductance from the outlet of the one or more tray openings in each tray to the outlet 322 of container 310 can exceed approximately 50 liters per second, or the flow conductance can exceed approximately 100 liters per second, or the flow conductance can exceed approximately 500 liters per second.
Referring now to
Furthermore, the container 610 is configured to be coupled to a heater (not shown) in order to elevate the evaporation temperature of the film precursor evaporation system 600, and to a temperature control system (not shown) in order to perform at least one of monitoring, adjusting, or controlling the evaporation temperature. When the evaporation temperature is elevated to an appropriate value as described earlier, film precursor evaporates (or sublimes) forming film precursor vapor to be transported through the vapor delivery system to the thin film deposition system. The container 610 is also sealably coupled to a carrier gas supply system (not shown), wherein the container 610 is configured to receive a carrier gas for transporting the film precursor vapor.
Referring still to
The stackable trays 640 are depicted to be cylindrical in shape. However, the shape can vary. For instance, the shape of the trays can be rectangular, square or oval. Similarly, the inner walls 644, and thus central flow channel 618, can be differently shaped.
When one or more stackable trays 640 are stacked upon one another, a stack 670 is formed, which provides for the annular space 660 between the tray outer wall 642 of the one or more stackable trays 640 and the container outer wall 612. The container 610 can further comprise one or more spacers (not shown) configured to space the tray outer wall 642 of the one or more stackable trays 640 from the container outer wall 612, and thereby ensure equal spacing within the annular space 660. To state it another way, in one embodiment, the container 610 is configured such that the tray outer walls 642 are in vertical alignment. Additionally, the container 610 can comprise one or more thermal contact members (not shown) configured to provide mechanical contact between the inner wall of the container 610 and the outer wall of each tray, thereby assisting the conduction of thermal energy from the wall of the container 610 to each respective tray.
A sealing device, such as an O-ring, may be located between each tray and the adjacent tray or trays in order to provide a vacuum seal between one tray and the next. For example, the sealing device can be retained in a receiving groove (not shown) formed in the tray support edge 643 of inner walls 642. Therefore, once the trays are installed in the container 610, the coupling of lid 620 to container 610 can facilitate compression of each sealing device. The sealing device can, for example, include an elastomer O-ring. Additionally, the sealing device can, for example, include a Viton® O-ring.
The number of trays can range from two (2) to twenty (20) and, for example in one embodiment, the number of trays can be five (5), as shown in
The stackable trays 640, whether stackable or integral, are configured to support a film precursor 650. According to one embodiment, the film precursor 650 includes a solid precursor. According to another embodiment, the film precursor 650 includes a liquid precursor. According to another embodiment, the film precursor 650 includes a metal precursor. According to another embodiment, the film precursor 650 includes a solid metal precursor. According to yet another embodiment, the film precursor 650 includes a metal-carbonyl precursor. According to yet another embodiment, the film precursor 650 can be a ruthenium-carbonyl precursor, for example Ru3(CO)12. According to yet another embodiment of the invention, the film precursor 650 can be a rhenium carbonyl precursor, for example Re2(CO)10. In yet another embodiment, the film precursor 650 can be W(CO)6, Mo(CO)6, Co2(CO)8, Rh4(CO)12, Cr(CO)6, or Os3(CO)12. Additionally, according to yet another embodiment, when depositing tantalum (Ta), the film precursor 650 can include TaF5, TaCl5, TaBr5, TaI5, Ta(CO)5, Ta[N(C2H5CH3)]5 (PEMAT), Ta[N(CH3)2]5 (PDMAT), Ta[N(C2H5)2]5 (PDEAT), Ta(NC(CH3)3)(N(C2H5)2)3 (TBTDET), Ta(NC2H5)(N(C2H5)2)3, Ta(NC(CH3)2C2H5)(N(CH3)2)3, Ta(NC(CH3)3)(N(CH3)2)3, or Ta(EtCp)2(CO)H. Additionally, according to yet another embodiment, when depositing titanium (Ti), the film precursor 650 can include TiF4, TiCl4, TiBr4, TiI4, Ti[N(C2H5CH3)]4 (TEMAT), Ti[N(CH3)2]4 (TDMAT), or Ti[N(C2H5)2]4 (TDEAT). Additionally, according to yet another embodiment, when depositing ruthenium (Ru), the film precursor 650 can include Ru(C5H5)2, Ru(C2H5C5H4)2, Ru(C3H7C5H4)2, Ru(CH3C5H4)2, Ru3(CO)12, C5H4Ru(CO)3, RuCl3, Ru(C11H19O2)3, Ru(C8H13O2)3, or Ru(C5H7O)3.
As described above, the film precursor 650 can include a solid precursor. The solid precursor can take the form of a solid powder, or it may take the form of one or more solid tablets. For example, the one or more solid tablets can be prepared by a number of processes, including a sintering process, a stamping process, a dipping process, or a spin-on process, or any combination thereof. Additionally, the solid precursor in solid tablet form may or may not adhere to the stackable tray 640. For example, a refractory metal powder may be sintered in a sintering furnace configured for both vacuum and inert gas atmospheres, and temperature up to 2000° C. and 2500° C. Alternatively, for example, a refractory metal powder can be dispersed in a fluid medium, dispensed on a tray, and distributed evenly over the tray surfaces using a spin coating process. The refractory metal spin coat may then be thermally cured.
As described earlier, carrier gas is supplied to the container 610 from a carrier gas supply system (not shown). As shown in
Referring again to
Referring yet again to
Additionally, the evaporation exhaust space, i.e., annular space 660, can be designed for high flow conductance. For example, the net flow conductance from the outlet of the one or more tray openings in each tray to the outlet 680 of container 610 can exceed approximately 50 liters per second, or the flow conductance can exceed approximately 100 liters per second, or the flow conductance can exceed approximately 500 liters per second.
The film precursor evaporation systems 300 or 300′, or 400, 500 or 600 may be used as either the film precursor evaporation system 50 in
Referring now to
In 730, the film precursor is heated to form a film precursor vapor. The film precursor vapor can then be transported to the process chamber through the precursor vapor delivery system. In 740, the substrate is heated to a substrate temperature sufficient to decompose the film precursor vapor, and, in 750, the substrate is exposed to the film precursor vapor. Steps 710 to 750 may be repeated successively a desired number of times to deposit a metal film on a desired number of substrates.
Following the deposition of the thin film on one or more substrates, the stack of trays 370 or 370′, or 670, or one or more of the base or upper trays 330, 340, or one or more of the stackable trays 640, can be periodically replaced in 760 in order to replenish the level of film precursor 350, 650 in each tray.
Although only certain exemplary embodiments of this invention have been described in detail above, those skilled in the art will readily appreciate that many modifications are possible in the exemplary embodiments without materially departing from the novel teachings and advantages of this invention. Accordingly, all such modifications are intended to be included within the scope of this invention.
This application is a Continuation-In-Part of each of the following U.S. patent application Ser. No. 11/007,961, filed on Dec. 9, 2004; Ser. No. 11/007,962, filed on Dec. 9, 2004; and Ser. No. 10/998,420, filed on Nov. 29, 2004, all of which are hereby expressly incorporated by reference herein. U.S. patent application Ser. No. 11/007,961 is a Continuation-In-Part of U.S. patent application Ser. No. 10/998,420, filed on Nov. 29, 2004; and U.S. patent application Ser. No. 11/007,962 is also a Continuation-In-Part of U.S. patent application Ser. No. 10/998,420, filed on Nov. 29, 2004, all of which are hereby expressly incorporated by reference herein. This application is also related to U.S. patent application Ser. No. ______, filed as Express Mail No. EV724512017US, entitled “A Film Precursor Tray for Use in a Film Precursor Evaporation System and Method of Using”, filed on even date herewith, the entirety of which is incorporated by reference herein.
Number | Date | Country | |
---|---|---|---|
Parent | 11007961 | Dec 2004 | US |
Child | 11351539 | Feb 2006 | US |
Parent | 11007962 | Dec 2004 | US |
Child | 11351539 | Feb 2006 | US |
Parent | 10998420 | Nov 2004 | US |
Child | 11351539 | Feb 2006 | US |
Parent | 10998420 | Nov 2004 | US |
Child | 11007962 | US | |
Parent | 10998420 | Nov 2004 | US |
Child | 11007961 | US |