1. Field of the Invention
The present invention relates to arc deposition systems and, in particular, to methods of filtering particles from such arc deposition systems.
2. Background Art
Over the last 20 years, cathodic arc deposition has become established as a reliable source of highly ionized plasma for deposition of reacted as well as un-reacted coatings from conductive target materials such as zirconium, titanium, chrome, aluminum, copper and alloys thereof. The highly ionized plasma and the associated electron beam generated in the arc evaporation process is also used in such surface processing techniques as ion sputtering, etching, implantation and diffusion processes.
An undesirable side effect of the arc evaporation process is the generation of macroscopically large particles (“macro-particles”) which tend to end up on substrates to be treated. These macro-particles potentially represent defects in the developing film, loosely adherent impurities, surface inhomogeneity and add roughness to the surface. The presence of macro-particles reduces the value and general applicability of the coating in demanding applications requiring superior properties such as corrosion performance, homogeneity, hardness, gloss or barrier performance.
Filters that can lower macro content reaching the substrate from arc evaporated plasmas are known. Such prior art filters typically rely on the following mechanisms. Some filters provide a physical barrier that intercepts macro-particles as they propagate in line of sight from an arc spot on the cathode towards the substrate. Such barriers may be associated with features that partially prevent bouncing macro-particles from reaching the substrate. Other prior art filters use a shaped magnetic field that steers the arc electron beam in a trajectory clear of the physical barrier and a strength at least partially magnetically insulating the physical barrier from being an anode for the electrons. Finally, some prior art filters use a positive potential of the physical barrier repelling ions present in the arc generated plasma. Filters relying on a combination of these three filter principles are described in the scientific and patent literature. For an overview see Anders, A., “Approaches to rid cathodic arc plasmas of macro- and nanoparticles—a review,” S
Cathodes for filtered arc sources are typically point source, i.e. circular cathodes, while a few elongate configurations such as linear aligned multiple point sources and linear sources have been described. The linear arrangement of the arc source allows for elongated coating zones and greatly increases the large volume production potential of the filtered arc technology. Yet, cylindrical target filtered arc plasma sources are even more desirable for coating or ion processing of large substrates, sheet material in roll form, and for quantities of smaller substrates on a linear conveyor or circular carousel.
Although the prior art methods for filtering macro-particles from arc deposition processes work reasonably well, these methods still suffer from a number of drawbacks. For example, deposition systems using the prior art filters tend to have a low net ion output current from the cathode target. The prior art methods also tend to have suboptimal utilization of the cathode surface. Finally, the coatings formed in such methods still tend to include an undesirable level of defects.
Accordingly, there is a need for improved cathode arc deposition systems with improved macro-particle filtering.
The present invention solves one or more problems of the prior art by providing, in at least one embodiment, a filter for an arc deposition system which includes an elongated cathode, an anode, and at least one substrate. The filter includes an even number of duct assemblies symmetrically positioned around the elongated cathode. The duct assemblies define a magnetic field for guiding a plasma and have a baffle component for blocking macro-particles.
In another embodiment, a filter assembly for use in an arc deposition system is provided. The filter assembly includes an even number of duct assemblies symmetrically positioned around the cathode target. The duct assemblies define paths through which positively charged ions are guided from a cathode target to a substrate. In order to accomplish such guidance, the duct assemblies are electrically biased such that positively charged ions are repelled. The duct assemblies also include components for generating a magnetic field that guide a plasma from the cathode target to the substrates. In particular, the magnetic field guides the movement of electrons which desirably results in ions (i.e., positively charged) moving in a manner to avoid collision with the filter. The duct assemblies also include baffles for blocking macro-particles from reaching substrates. Neutral and negatively charged particles are undesirable as they lead to imperfections and agglomerates in the coating. The neutral and negatively charged particles collide with the filter and are, therefore, removed and prevented from reaching the substrate.
In still another embodiment, an arc deposition system for removing material from a cathode target which is deposited on a substrate is provided. The arc deposition system includes an elongated cathode target which is placed within a vacuum chamber. One or more substrates are positioned within a substrate zone that is a predetermined distance from the cathode target in the vacuum chamber. The filter assembly is also placed within the vacuum chamber such that the filter assembly is interposed between the cathode target and the substrate zone. Characteristically, the filter assembly includes an even number of duct assemblies symmetrically positioned around the cathode target. The duct assemblies define paths through which positively charged ions are guided from the cathode target to the substrates. In order to accomplish such guidance, the duct assemblies are electrically biased such that positively charged ions are repelled. The duct assemblies also include components for generating a magnetic field that guides a plasma from the cathode target to the substrates. The magnetic field guides the movement of electrons which desirably results in ions (i.e., positively charged) moving in a manner to avoid collision with the filter. The duct assemblies also include baffles for blocking macro-particles from reaching substrates. Neutrals and negatively charged particles are undesirable as they lead to imperfections and agglomerates in the coating. The neutral and negatively charged particles collide with the filter and are, therefore, removed and prevented from reaching the substrate.
Exemplary embodiments of the present invention will become more fully understood from the detailed description and the accompanying drawings, wherein:
Reference will now be made in detail to presently preferred compositions, embodiments and methods of the present invention, which constitute the best modes of practicing the invention presently known to the inventors. The Figures are not necessarily to scale. However, it is to be understood that the disclosed embodiments are merely exemplary of the invention that may be embodied in various and alternative forms. Therefore, specific details disclosed herein are not to be interpreted as limiting, but merely as a representative basis for any aspect of the invention and/or as a representative basis for teaching one skilled in the art to variously employ the present invention.
Except in the examples, or where otherwise expressly indicated, all numerical quantities in this description indicating amounts of material or conditions of reaction and/or use are to be understood as modified by the word “about” in describing the broadest scope of the invention. Practice within the numerical limits stated is generally preferred. Also, unless expressly stated to the contrary: percent, “parts of,” and ratio values are by weight; the description of a group or class of materials as suitable or preferred for a given purpose in connection with the invention implies that mixtures of any two or more of the members of the group or class are equally suitable or preferred; description of constituents in chemical terms refers to the constituents at the time of addition to any combination specified in the description, and does not necessarily preclude chemical interactions among the constituents of a mixture once mixed; the first definition of an acronym or other abbreviation applies to all subsequent uses herein of the same abbreviation and applies mutatis mutandis to normal grammatical variations of the initially defined abbreviation; and, unless expressly stated to the contrary, measurement of a property is determined by the same technique as previously or later referenced for the same property.
It is also to be understood that this invention is not limited to the specific embodiments and methods described below, as specific components and/or conditions may, of course, vary. Furthermore, the terminology used herein is used only for the purpose of describing particular embodiments of the present invention and is not intended to be limiting in any way.
It must also be noted that, as used in the specification and the appended claims, the singular form “a,” “an,” and “the” comprise plural referents unless the context clearly indicates otherwise. For example, reference to a component in the singular is intended to comprise a plurality of components.
Throughout this application where publications are referenced, the disclosures of these publications in their entireties are hereby incorporated by reference into this application to more fully describe the state of the art to which this invention pertains.
With reference to
Although the present embodiment is not limited by the dimensions of cathode target 12, typically cathode 12 has a diameter from 1 to 10 inches and a length from 6 inches to 5 feet. Substrates 20 are positioned within substrate zone 22 that is a distance d1 from cathode target 12. Filter assembly 24 is also placed with vacuum chamber 16. In particular, filter assembly 24 is interposed between cathode target 12 and substrate zone 22. Filter assembly 24 includes an even number of duct assemblies 26, 28, 30, 32 symmetrically positioned around cathode target 12. Duct assemblies 26, 28, 30, 32 define ducts 34, 36, 38, 40 through which positively charged ions are guided from cathode target 12 to substrates 20. In order to accomplish such guidance, duct assemblies 26, 28, 30, 32 are electrically biased such that positively charged ions are repelled from the duct assemblies via filter power supply 42. A voltage of plus 10 volts or more effectively repels positively charged ions. Duct assemblies 24, 26, 28, 30 also include components for generating a magnetic field that guides a plasma (i.e., positively charged ions) from cathode target 12 to substrates 20. In a refinement, duct assemblies 24, 26, 28, 30 also include baffles for blocking macro-particles from reaching substrates 20.
In a refinement, system 10 includes helical electromagnet coil 48 which is coaxially mounted about cathode target 12. Helical electromagnet coil 48 is powered by a separate coil power supply 50. Electromagnet coil 48 may be electrically isolated or it may be connected to the vacuum chamber 16.
Control system 52 is provided to vary the current input to each end of the cathode target 12 while maintaining the total arc current substantially constant, such that the current to each end of cathode target 12 may be varied between 0 and 100 percent of the total arc current supplied. Arc current is directly correlated to deposition rate and can be controlled between 50 A and, for example, 2000 A, the upper limit determined by cooling efficiency of target. This may be accomplished by using separate arc power supplies 54, 56 connected at each end of cathode target 12 with a controller 58 to provide complementary set point signals for the separate arc power supplies 54, 56. In an alternative variation, a single arc power supply having two complementary current outputs may be employed.
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Electromagnet coil 48 may be connected in series with the arc power supply 54, 56, such that the arc current flows through electromagnet coil 48 to generate an axial magnetic field. Since the coil is connected between the positive output of arc power supply 54, 56 and the anode, and since the total arc current is constant, the current input to the electromagnet coil 48 is not affected by the variation in current to the two ends of cathode target 12. This arrangement eliminates the necessity of a separate power supply for powering electromagnet coil 48, but sacrifices independent adjustability of the strength of the applied magnetic field except through selection of the pitch of electromagnet coil 48.
With reference to
With reference to
It should be appreciated that dimensions and orientation of duct assemblies depicted above as well as characteristics of magnetic field elements the transmission and filter efficiency can be altered without departing from the underlying teaching of this invention. Filters allowing a tailoring of the amount of macro-particle content in the coatings are achievable.
With reference to
As set forth above, the filter of the present embodiment includes an even number of duct assemblies that are symmetrically placed around cathode target 12. In a refinement, the number of duct assemblies is an even number from 2 to 8. In another refinement, the number of duct assemblies is an even number from 4 to 8. The inclusion of four duct assemblies is found to be particularly useful. Moreover, as depicted in
With reference to
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It should further be apparent that alternative cathode configurations can be operated in the filter configuration of this invention. One such cathode configuration well known in the art, is the rotary cylindrical cathode described, for example, in U.S. Pat. No. 6,262,539 (the entire disclosure of which is incorporated herein by reference) which can be operated in present filter invention without departing from the scope and teachings of this invention. Another cathode configuration well known in the art, is the planar magnetron as described, for example, in U.S. Pat. No. 4,892,633 (the entire disclosure of which is incorporated herein by reference) which can be operated in present filter invention without departing from the scope and teachings of this invention.
The following examples illustrate the various embodiments of the present invention. Those skilled in the art will recognize many variations that are within the spirit of the present invention and scope of the claims.
A filtered arc as disclosed with four duct elements was furnished with a chromium cylindrical cathode. The chamber was pumped down to 1 mTorr and maintained at pressure using argon as background gas. An arc was stricken and maintained at 900 A while passing 8000 A through duct elements biased at plus 30 volts, passing 100 A through steering coil and biasing the substrate at minus 50 volts. A current of 40 A was collected at the substrate and a Cr film deposited. The deposited film was documented for macros showing a reduction in macro content from 1% volume to less than 0.01% volume as compared to an unfiltered arc. The cross sectioned Cr film showed generally amorphous and isotropic properties without signs of defects.
A filtered arc as disclosed with four duct elements was furnished with a chromium cylindrical cathode. The chamber was pumped down to 1 mTorr and maintained at pressure using argon and nitrogen in 1:1 ratio as background gas. An arc was stricken and maintained at 900 A while passing 8000 A through duct elements biased at plus 30 volts, passing 100 A through steering coil and biasing the substrate at minus 50 volts. A current of 40 A was collected at the substrate and a Cr film deposited. The deposited film was documented for macros showing a reduction in macro content from 1% volume to less than 0.01% volume as compared to an unfiltered arc. The cross sectioned CrN film showed generally amorphous and isotropic properties without signs of defects.
While embodiments of the invention have been illustrated and described, it is not intended that these embodiments illustrate and describe all possible forms of the invention. Rather, the words used in the specification are words of description rather than limitation, and it is understood that various changes may be made without departing from the spirit and scope of the invention.