Flocked articles having noncompatible insert and porous film

Information

  • Patent Grant
  • 7799164
  • Patent Number
    7,799,164
  • Date Filed
    Thursday, July 27, 2006
    18 years ago
  • Date Issued
    Tuesday, September 21, 2010
    14 years ago
Abstract
The present invention is directed to flocked articles comprising a metallized film and methods of manufacturing such articles.
Description
FIELD

The invention relates generally to flocked articles and particularly to flocked graphics.


BACKGROUND

Flocked articles are used in a wide variety of applications. Flocked articles are being used for textile decoration as well as molded articles. Flock is a short precision cut or pulverized natural or synthetic fiber used to produce a velvet like coating on cloth, rubber, film, or paper. Flock generally has a length between about 0.010 to 0.250 inches (0.25 mm to 6.25 mm).


In these applications, it has been highly desired to have multi-media flocked articles including a material having a metallic sheen or luster. Metal noncompatible inserts have been used in the prior art but the metal inserts have rapidly faded due to ultraviolet light exposure, wear, and/or the effects of repeated washings. It is therefore desirable to have a multi-media flocked article having a noncompatible insert that resists fading.


SUMMARY

These and other needs are addressed by the various embodiments and configurations of the present invention. The present invention is directed to flocked articles and graphics comprising a compatible and/or noncompatible (or incompatible) material, such as a metallized film. As used herein, a “metallized film” refers to any material, whether metal or a nonmetal, having a metal-like appearance (e.g., metal-like sheen or luster).


In one embodiment of the present invention, a metallized film is used to provide a number of highly attractive colors, sheens and matte finishes. In one configuration, the metallized film is metallic in appearance. In one configuration, it contains a metal layer vapor deposited on a first polymeric film with a second polymeric film being located on the opposing side of the metal layer. The metal layer is sandwiched between the first and second polymeric layers by means of a laminate adhesive. The polymeric layers can be UV-resistant, water resistant, thermally stable, and otherwise designed to resist wear and deterioration. Preferably, the polymeric layers are a polycarbonate. Thus, unlike conventional metal-containing noncompatible inserts water discoloration of the insert is typically not a problem. This can obviate the need to apply additional protective layers to the insert to protect any metal from oxidation.


The metallized film can have a highly desirable mirror-like metallic look from the metallized layer, a high abrasion resistance of the sandwiching polymeric films to protect the metal and laminate adhesive from fading, discoloration, and/or corrosion, and a high ability to accept and adhere to a wide variety of hot melt thermoplastic or thermoset adhesives, whether in the form of a liquid, power, or preformed film.


The flocked article can include a porous film to act as a binder or tie material for the otherwise incompatible or weakly compatible materials, namely the flock and the metallized film. The porous film can bond well to a number of otherwise compatible and noncompatible materials on opposite sides, thus serving well as a so-called “tie coat” layer. For example, the film bonds to a variety of adhesives as noted above. The adhesives can be applied as a thermoplastic powder, a self-supporting heat-activated film, or as a liquid coating. In particular, the film may be readily laminated to pre-formed, self-supporting films of thermoset and/or thermoplastic adhesive(s)s, including hot melt adhesive(s).


The porous film, though having modest tensile strength when taken alone, can experience substantial improvements in tensile strength when combined with one or more other materials. For example, the film, by itself, lacks the strength of conventional paper carriers and therefore would at first blush appear to be a poor candidate for use in a machine (web) based-process and in products that need to be durable. However, when coated with water or solvent-based release adhesives the release adhesives not only provide an adhesive surface to capture and hold flock fibers but also provides a substantial improvement in film strength after the adhesive is dried and cured. While not wishing to be bound by any theory, it is believed that the release adhesive is carried into the film matrix by the combined effects of the film's porosity and permeability and, after drying, substantially fills the pores in the film to provide the desired strength enhancement. The synergistic effect of the release adhesive and the porosity/permeability of the film makes the porous film strong enough to withstand the forces applied during subsequent processing stages, such as web-type tensile forces, vacuum cleaning, mechanical brushing, baking, and heat transfer application processes (e.g., heat pressing, cooling, pulling the carrier, and releasing the fibers). Additional support film(s) may nonetheless be added to the side of the porous film opposite the side containing the flock to provide further support.


These and other advantages will be apparent from the disclosure of the invention(s) contained herein.


The above-described embodiments and configurations are neither complete nor exhaustive. As will be appreciated, other embodiments of the invention are possible utilizing, alone or in combination, one or more of the features set forth above or described in detail below.


As used herein, “at least one”, “one or more”, and “and/or” are open-ended expressions that are both conjunctive and disjunctive in operation. For example, each of the expressions “at least one of A, B and C”, “at least one of A, B, or C”, “one or more of A, B, and C”, “one or more of A, B, or C” and “A, B, and/or C” means A alone, B alone, C alone, A and B together, A and C together, B and C together, or A, B and C together.





BRIEF DESCRIPTION OF THE DRAWINGS


FIG. 1 is a cross section of a three dimensional design according to an embodiment of the present invention;



FIG. 2 is a block diagram of a process embodiment to make an intermediate flocked article for use in the three dimensional design;



FIG. 3 is a cross section of an intermediate flocked article;



FIG. 4 is a block diagram of a process embodiment to make an insert assembly for use in the three dimensional design;



FIG. 5 is a cross section of an insert assembly;



FIG. 6 is a block diagram of a process embodiment to make the three dimensional design;



FIG. 7 is a block diagram of a process embodiment to make a three dimensional design according to another embodiment;



FIG. 8 is a cross section of the three dimensional design;



FIG. 9 is an exemplary decorative media according to an embodiment of the present invention;



FIG. 10 is a cross section of another embodiment of a three dimensional design in accordance with the present invention;



FIG. 11 is a block diagram of a process to make the three dimensional design of FIG. 10;



FIG. 12 is a side view of a decorative media in a first step of a production process according to an embodiment of the present invention;



FIG. 13 is a side view of the decorative media in a second step of the production process;



FIG. 14 is a side view of the decorative media in a third step of the production process; and



FIG. 15 is a side view of the decorative media after application to a substrate.





DETAILED DESCRIPTION


FIGS. 1 and 9 show a three-dimensional design according to an embodiment of the present invention. The design 100 includes (multi-colored or sublimation printed) flocked areas 104 surrounding a plurality of compatible or noncompatible inserts 112. The inserts 112 are adhered to a porous film 116 by a first adhesive 120. Additionally, the porous film 116 is adhered to the flock areas 104 by a flock (second) adhesive 124. Finally, the design 100 is adhered to a desired substrate, such as a textile, by a permanent (third) adhesive 128.


The inserts 112 can be any design media, such as glass beads. In a preferred embodiment, the inserts 112 are formed from one or more polymeric light diffusing films, such as polycarbonate and/or polyester light diffusion films sold under the tradenames Makrofol™ and/or Bayfol™. The films are preferably metal-containing and have a first and/or second surface gloss (60° angle with black inked second surface) of at least about 50 gloss units, more preferably of at least about 75 gloss units, and even more preferably of at least about 75 gloss units, first and/or second surface roughnesses (R3Z) of no more than about 20 microns, more preferably of no more than about 3 microns, and even more preferably of no more than about 1 micron, and a luminous transmittance of no more than about 50%, more preferably no more than about 5%, and even more preferably no more than about 1%. The insert 112 preferably has a metallic or nonmetallic sheen and a gloss/fine matte and a thickness of no more than about 0.5 inches, more preferably of no more than about 0.25 inches, and even more preferably of no more than about 0.20 inches. A particularly preferred insert is Makrofol™ DPF 5072™.


The porous film 116 is preferably a microporous material that includes a matrix of substantially water insoluble thermoplastic organic polymer, finely divided substantially water-insoluble filler particles and a network of interconnected pores communicating substantially throughout the microporous material. The filler particles are distributed throughout the matrix and constitute from about 40 to about 90 percent by weight of the microporous material. The filler particles are a metal oxide, such as alumina, silica, and titania with silica being preferred. Preferably, at least 50 percent by weight of the particles are amorphous precipitated silica particles. The particles have a preferred maximum dimension of less than about 5 micrometers, more preferably no more than about 1 micrometer, even more preferably no more than about 0.1 micrometers, and even more preferably no more than about 0.05 micrometers and a preferred average pore size of less than 1 micrometer and more preferably of no more than about 0.1 micrometer. The pores preferably constitute from about 35 to about 95 percent by volume of the microporous material. The matrix of the microporous material includes a water-insoluble thermoplastic organic polymer. Examples of suitable polymers include polyolefins, poly(halo-substituted olefins), polyesters, polyethylenes, polyamides, polyurethanes, polyureas, poly(vinyl halides), poly(vinylidene halides), polystyrenes, poly(vinyl esters), polycarbonates, polyethers, polysulfides, polyimides, polysilanes, polysiloxanes, polycaprolactones, polyacrylates, and polymethylacrylates, with poly(vinyl chloride), copolymers of vinyl chloride, and mixtures thereof being preferred. The material may further include plasticizers, lubricants, and antioxidants.


The microporous material is preferably coated with a substantially nonporous coating composition including a volatile liquid medium (e.g., water and/or a nonaqueous solvent) and binder dissolved or dispersed in the medium. The binder includes a film-forming organic polymer, preferably including (a) water-soluble poly(ethylene oxide) having a preferred weight average molecular weight in the range of from about 100,000 to 3,000,000 and (b) water-soluble or water-dispersible crosslinkable urethane-acrylate hybrid polymer. In addition to or in lieu of poly (ethylene oxide), the organic polymer may further include additional organic polymers such as water-soluble cellulosic organic polymers, water-soluble noncellulosic organic polymers, and/or water dispersible polymers such as poly(ethylene-co-acrylic acid), poly(ethylene),and poly(ethylene oxide). The poly(ethylene oxide) includes copolymers of ethylene oxide with lower alkylene oxide and homopolymers of ethylene oxide. Preferably, the organic polymer component of the coating includes from about 20 to about 80% by weight of the urethane-acrylate hybrid polymer. The coating may further include surfactants and adjuvant materials. After drying and crosslinking, the peel strength between the coating and microporous material substrate is high.


The film has a preferred puncture strength of greater than about 300 g/25.4 μm, a preferred tensile strength of less than about 2% at 1000 psi, and a preferred thermal ability of less than about 5% shrinkage after 160 minutes at 90° C.


A preferred porous film is further discussed in U.S. Pat. No. 6,025,068, which is incorporated herein by this reference. A particularly preferred porous film is sold by PPG Industries Inc. under the tradename Teslin™. Battery separator membranes can also be used. Examples include Daramic Industrial CL™ sold by Daramic, Inc., and the battery separator membranes sold by Celgard, or by Daramic, Inc. under the tradename Artisyn™. Artisyn™ is an uncoated, mono-layer, highly filled polyolefin sheet.


The flock fibers in the flock layer 1104 can be any desirable material, whether natural or synthetic. Preferably, the flock is composed of polyester (such as poly(ethylene terephthalate) and poly(cyclohexylene-dimethylene terephthalate)), vinyl, nylon, rayon, and the like.


The various permanent adhesives 1108, 1116, and 1120 can be any suitable adhesive, with water- and solvent-based adhesives and preformed film adhesives being preferred. Preferred permanent adhesives include thermoset and hot melt thermoplastic adhesives, whether as a liquid, powder, or (pre-formed) self-supporting film. As will be appreciated, thermoset adhesives solidify, activate and/or set irreversibly when heated above a certain temperature. This property is usually associated with a cross-linking reaction of the molecular constituents induced by heat or radiation. Thermoset adhesives can include curing agents such as organic peroxides, isocyanates, or sulfur. Examples of thermoplastic and thermosetting adhesives include polyethylene, phenolics, alkyds, acrylics, amino resins, polyesters, epoxides, polyurethanes, polyamides, and silicones.


The adhesives 1108, 1116, and 1200 may contain additives, such as fillers, catalysts, colorants (dyes or pigments) and optical blocking/reflective/absorbtive materials. The preferred porous film, namely Teslin™ and Artisyn™, can be highly sensitive to Ultraviolet (UV) radiation and can degrade rapidly when exposed to direct sunlight. Accordingly, the adhesives may contain light blocking, absorbing, and/or reflecting materials to decrease substantially the optical transmissivity of the adhesive. Preferably, the adhesive, when on the light contacting side of the porous film, blocks at least about 75%, more preferably at least about 85%, and even more preferably at least about 95% of the UV radiation spectrum. Such optical blocking/reflecting/absorbing materials are known to those of skill in the art.


Referring to FIGS. 1-6 and 9, a first process embodiment to manufacture the three dimensional design 100 will now be described. It is to be appreciated that those of ordinary skill in the art will envision other methods of manufacturing the design 100. Such other methods are considered to be a part of the present invention.


With reference to FIG. 2, the steps to produce an intermediate flocked article 300 will now be described.


In step 200 a carrier sheet 204 is flocked with flock fibers 208 in the reverse order of the desired pattern. The carrier sheet can be any substrate that is dimensionally stable under the conditions of temperature and pressure encountered during the process. The carrier sheet 204 is preferably a porous film, such as the porous film 116 described above, coated with a release adhesive 212, which is preferably water-based. Typically (but not always), the carrier is a discontinuous sheet as opposed to a continuous sheet on a running web line.


The release adhesive 212 can be any adhesive that adheres more strongly to the carrier sheet than the flock fibers but adheres to both enough to hold them together. For example, the release adhesive 212 can be any temporary adhesive, such as a resin or a copolymer, e.g., a polyvinyl acetate, polyvinyl alcohol, polyvinyl chloride, polyvinyl butyral, acrylic resin, polyurethane, polyester, polyamides, cellulose derivatives, rubber derivatives, starch, casein, dextrin, gum arabic, carboxymethyl cellulose, rosin, silicone, or compositions containing two or more of these ingredients.


It is desired that, when the flock fibers are removed from the release adhesive, the fibers are substantially free of release adhesive. The release adhesive may be applied in the form of a solution or emulsion. The release adhesive may be applied on the carrier in the perimeter shape of the desired design or without regard to the overall design desired. The release adhesive may be applied by any suitable technique such as, for example, by applying the release adhesive with rollers or spraying the release adhesive.


In optional step 216, the exposed ends 224 of the flocked surface are sublimation printed to provide the desired design on the flock. Sublimation printing is described in copending U.S. applications Ser. Nos. 10/614,340, filed Jul. 3, 2003; Ser. No. 11/139,439, filed May 26, 2005; and Ser. No. 11/036,887, filed Jan. 14, 2005, to Abrams, each of which is incorporated herein by this reference. As will be appreciated, common ways of performing sublimation ink direct printing include inkjet or screen sublimation ink printing and sublimation transfer printing using devices such as an inkjet dye sub printer, a ribbon-based dye sub printer, a hybrid sublimation printer, and a small dye sub ribbon-based printer. In inkjet (direct) sublimation ink printing, a special heat sensitive dye is used in a computer-controlled printer, such as an HP 550™, or Mimaki JV4™ to sublimation print the ink onto the flock fibers through vapor phase transportation of the ink from the printer to the flock fibers. The transferred dye is then heat and pressure thermofixed and thereby enters the amorphous areas of the fiber matrix. As noted, vacuuming of the flock can be conducted preferably before or after sublimation ink printing. Commonly, the color must go all the way down the fiber.


In optional step 220, the free ends 224 of the flock are coated with a binder adhesive 228. This process is discussed in U.S. Pat. Nos. 4,810,549; 5,207,851; 5,597,637; 5,858,156; 6,010,764; 6,083,332; and 6,110,560, which are incorporated herein by this reference. A suitable binder adhesive is a water based acrylic which binds the flock together as a unit. The binder adhesive 228 adhesive may contain a hot melt adhesive.


In step 232, the permanent (second) adhesive 124 is contacted with the free ends 224 of the flock 208 (or with the binder adhesive 228 depending on the process configuration employed). In one configuration, the second adhesive 124 is a thermoplastic or thermoset adhesive and is heated to a temperature sufficient to adhere the adhesive 124 to the flock 208. For a thermoset adhesive, the temperature is below the temperature at which the adhesive cross-links and is no longer reversible.


In step 236, areas of the assembly are removed to form voids 240 to receive the inserts 112 will be appreciated, the sizes of the areas removed are approximately the same size as the size of the corresponding insert 112. The void 240 passes completely through the assembly. In other words, the void 240 is free of adhesives 120, 224, and 212, the carrier sheet 204, and flock 208.


The process yields the intermediate flocked article 300 shown in FIG. 3.


With reference to FIG. 4, the steps to produce the insert 112 will now be described.


In step 400, the first permanent adhesive 120 is contacted with the noncompatible insert 112.


In step 404, the upper surface of the porous film 116 (of which the lower surface has previously been contacted with the third permanent adhesive 128) is contacted with the first permanent adhesive 120.


In step 408, the insert 112 and first permanent adhesive 120 are cut to the size and shape of the void 240 in the intermediate flocked article 300. Cutting may be made by known techniques, such as a laser or a mechanical cutting device.


In step 412, the first (and third) permanent adhesives 120 and 128 are heat sealed. Heat sealing preferably occurs at a temperature within the thermoplastic behavior regime. Thus, when the permanent adhesive is a thermoset adhesive, the adhesive following step 412 is not thermoset


As will be appreciated, steps 404, 408, and 412 may be performed in any order. For example, step 408 may be performed before step 404. Steps 400, 404, and 412 can be performed simultaneously, such as by lamination.


In step 416, the porous film, which was not cut in step 408, is cut to a size slightly larger than the void 240. This oversize relative to the void size is shown in FIG. 1. The overlapping edge of the porous film is used to secure the insert to the intermediate flocked article.


In step 420, a tack adhesive 504 is applied to the overlapping edge of the porous film to provide the insert assembly 500 depicted in FIG. 5.



FIG. 6 depicts the final steps of the process to form the three dimensional design 100.


In step 600, the insert 112 is positioned in the void 240 as shown in FIG. 1. The tack adhesive 504 temporarily holds the insert assembly 500 in position.


In step 604, the consolidated assembly formed from the insert assembly 500 and intermediate flocked article 300 is heat sealed to thermoplastically (and reversibly) set the second adhesive 124 and permanently adhere the porous film 116 to the flocked article 300.


The final three dimensional design 100 is shown in FIG. 1.


Another process embodiment to form a three dimensional design is depicted in FIGS. 7 and 8. The design 800 includes the flock 208, insert 112, porous film 116, and first and third adhesives 120 and 128.


In step 700, the porous film 116 is contacted with the first (and optionally third) permanent adhesives 120 and 128.


In step 704, the incompatible insert 112 is positioned on the first permanent adhesive 120.


In step 708, the exposed portions of the first permanent adhesive 120 are direct flocked by known techniques. Preferably, direct flocking is performed electrostatically by imparting a charge to the flock fibers and using an electric field to deposit the flock fibers on the oppositely charged substrate. The insert 112 acts as a mask and prevents flock fibers from being deposited in the area(s) to be occupied by inserts 112.


In optional step 712, the third permanent adhesive 128, if not already applied to the reverse side of the porous film 116, is now contacted with that side.


In step 716, the assembly is heated sealed to thermoplastically set the first and third adhesives. Following heat sealing or curing of the adhesive layers, which is typically performed using radiation (e.g., heat or light), the flocked surface can be vacuumed to remove loose flock fibers.


The final three dimensional design 800 is depicted in FIG. 8.


Another process embodiment to form a three dimensional design is depicted in FIGS. 10 and 11. The design 1300 includes the flock 208, insert 112, and first and second permanent adhesives 124 and 128. The first permanent adhesive 124 is preferably a thermoset adhesive, and the second permanent adhesive 128 is a thermoplastic hot melt adhesive.


The insert 112 components are also shown in FIG. 10. The insert 112 comprises first and second polymer films 1304 and 1308 (which are preferably polycarbonate films) sandwiching a metal film 1312 and laminate adhesive 1316. The insert 112 is formed by depositing the metal film 1312, such as by vapor deposition techniques, on the first polymer film 1304, followed by contacting the metal film or second polymer film 1308 with the laminate adhesive 1316, and finally laminating the first and second polymer films, metal film, and laminate adhesive together. To created desired metal appearances, the first or second polymer film can be colored, using suitable dyes or pigments or other colorants. Metal shades can be thus produced, such as brass, copper, and the like.


As a result of the properties of the adhesive, the insert is able to withstand exposure to temperature extremes and water, including washing and heat pressing. Other metallized films and/or laminates will let the metal layer begin to corrode (e.g., from the combined effects of water and detergent) from the outside edges where it is exposed and the corrosion progresses into the laminate, which delaminates the two films at the metal layer.


In other configurations, the first permanent adhesive is a composite of a thermoset adhesive contacting the flock and a thermoplastic adhesive contacting the insert. The thermoplastic adhesive is preferably a hot melt adhesive



FIG. 11 shows the process to manufacture the product of FIG. 10.


In step 1400, a flocked transfer, comprising a porous film, water-based release adhesive, and flock, is formed by electrostatic flocking techniques.


In step 1404, the free ends of the flock in the flock transfer are contacted with the first permanent adhesive and insert. The first permanent adhesive is heated to adhere to the flock. Preferably, the first permanent adhesive is thermoset in this step. This step may be performed by any technique, with lamination techniques being preferred. A preferred technique is discussed in copending U.S. application Ser. Nos. 09/621,830, filed Jul. 24, 2000; Ser. No. 10/455,541, filed Jun. 4, 2003; and Ser. No. 10/670,091, filed Sep. 23, 2003.


In step 1408, the flock transfer/first permanent adhesive/insert assembly is contacted with the second permanent adhesive to form the three dimensional design 1412. This step may be performed using any technique, with lamination techniques being preferred. A preferred technique is discussed in copending U.S. application Ser. No. 09/735,721, filed Dec. 13, 2000, and Ser. No. 10/455,575, filed Jun. 4, 2003.


Yet another embodiment of the composite media will be described with reference to FIGS. 12-15. The media is based on the processes described in U.S. Pat. Nos. 6,010,764 and 6,110,560, each of which is incorporated herein by this reference.


With reference to FIG. 12, the process to produce the media commences by bringing together, such as by lamination techniques, a flocked release sheet, pressure sensitive adhesive 1500, and the insert 112. The flocked release sheet includes flocked areas 104 embedded in the release adhesive 212, which is applied to the carrier sheet 204. The pressure sensitive adhesive 1500 is backed by a paper backing 1504. The flocked areas 104 are discontinuous being separated by a space 1508 sized to receive the insert 112. The pressure sensitive adhesive 1500 is applied to a surface of the insert 112. The paper backing 1504 is then removed and the pressure sensitive adhesive 1500 adhered to the release adhesive 212. For better adhesion, the release adhesive 212 may be omitted from the space 1508, which is to be free of flock. The omission of the release adhesive from this area may be done using screen printing techniques. In another configuration, the tack adhesive 1500 is omitted and the release adhesive 212 included in the space 1508 to adhere the insert temporarily to the carrier sheet 204.


With reference to FIG. 13, a layer of a hot melt adhesive 1600, whether applied as a preformed self-supporting layer, powder, or liquid, is applied to the free surfaces of the flock and the insert 112. Preferably, the hot melt adhesive 1600 is applied as a compatible hot melt powder having a grind size of preferably no more than about 250 microns, even more preferably of no more than about 225 microns and even more preferably ranging from about 40 to about 200 microns. The hot melt powder is preferably in the form of a polyester. In one configuration, the free surfaces of the flock and insert 112 are screen printed with a permanent latex fiber adhesive, which is coated with the hot melt powder. The coated hot melt powder is then dried, vacuum brushed, and cured to prepare it for application to a substrate, such as a textile.



FIG. 14 shows the assembly being applied to a substrate 1700. The adhesive layer 1600 is applied to the substrate in the presence of heat, such as applied by an iron, to soften the hot melt adhesive and cause it to adhere to the substrate. The hot melt adhesive readily adheres the flock and insert 112 to the substrate 1700.


Referring to FIG. 14, after adherence to the substrate 1700 the carrier sheet 204, release adhesive 112, and pressure sensitive adhesive 1500 are peeled away from the media. Thus, only the flocked areas 104 and insert 112 remain permanently affixed to the substrate 1700.


A number of variations and modifications of the invention can be used. It would be possible to provide for some features of the invention without providing others.


For example, the insert can include other design media in addition to or in lieu of the metal film. The design media include, for example, glass particles (e.g., sequins), ceramic particles, textiles, and the like.


By way of further illustration, the insert 112 can be bonded directly to the porous film 116 in the absence of an intervening adhesive. The porous film 116 can be formulated to have adhesive properties.


The present invention, in various embodiments, includes components, methods, processes, systems and/or apparatus substantially as depicted and described herein, including various embodiments, subcombinations, and subsets thereof. Those of skill in the art will understand how to make and use the present invention after understanding the present disclosure. The present invention, in various embodiments, includes providing devices and processes in the absence of items not depicted and/or described herein or in various embodiments hereof, including in the absence of such items as may have been used in previous devices or processes, e.g., for improving performance, achieving ease and or reducing cost of implementation.


The foregoing discussion of the invention has been presented for purposes of illustration and description. The foregoing is not intended to limit the invention to the form or forms disclosed herein. In the foregoing Detailed Description for example, various features of the invention are grouped together in one or more embodiments for the purpose of streamlining the disclosure. This method of disclosure is not to be interpreted as reflecting an intention that the claimed invention requires more features than are expressly recited in each claim. Rather, as the following claims reflect, inventive aspects lie in less than all features of a single foregoing disclosed embodiment. Thus, the following claims are hereby incorporated into this Detailed Description, with each claim standing on its own as a separate preferred embodiment of the invention.


Moreover, though the description of the invention has included description of one or more embodiments and certain variations and modifications, other variations and modifications are within the scope of the invention, e.g., as may be within the skill and knowledge of those in the art, after understanding the present disclosure. It is intended to obtain rights which include alternative embodiments to the extent permitted, including alternate, interchangeable and/or equivalent structures, functions, ranges or steps to those claimed, whether or not such alternate, interchangeable and/or equivalent structures, functions, ranges or steps are disclosed herein, and without intending to publicly dedicate any patentable subject matter.

Claims
  • 1. A method, comprising: (a) providing a flock transfer, the flock transfer comprising a carrier sheet, a release adhesive, and a flock layer, a first surface of the flock layer being adhered to the carrier sheet by the release adhesive;(b) applying a first permanent adhesive to a second surface of the flock layer to form a transfer assembly, the first and second surfaces being in an opposing relationship with one another;(c) thereafter, removing a selected portion of the flock layer from at least one of the flock transfer and transfer assembly to form a void;(d) positioning an insert substantially in the void of the transfer assembly, wherein the insert and the transfer assembly are positioned on a first substrate surface of a common substrate; and(e) adhering the transfer assembly and insert to the first substrate surface.
  • 2. The method of claim 1, wherein the insert comprises a design and a lamination adhesive positioned between first and second polymeric films.
  • 3. The method of claim 1, wherein the insert is adhered to the common substrate before the transfer assembly is adhered to the common substrate and wherein the insert and transfer assembly are not adhered to one another before step (e).
  • 4. The method of claim 1, wherein the common substrate is larger than the insert, the common substrate provides an overlapping edge and wherein step (d) comprises the sub-step of applying a tack adhesive to the overlapping edge, and wherein the overlapping edge contacts the second surface of the flock.
  • 5. The method of claim 1, wherein a second permanent adhesive is positioned between the insert an a first surface of the common substrate, and further comprising: (f) applying a third permanent adhesive to a second surface of the common substrate, the first and second surfaces of the common substrate being in an opposing relationship.
  • 6. The method of claim 4, wherein the tack adhesive applied is a thermosetting adhesive.
  • 7. A method, comprising: (a) providing a flock transfer, the flock transfer comprising a carrier sheet, a release adhesive, and a flock layer, a first surface of the flock layer being adhered to the carrier sheet by the release adhesive;(b) applying a first permanent adhesive to a second surface of the flock layer to form a transfer assembly, the first and second surfaces being in an opposing relationship with one another;(c) thereafter, removing a selected portion of the flock layer from at least one of the flock transfer and transfer assembly to form a void;(d) positioning an insert substantially in the void of the transfer assembly, wherein the insert and the transfer assembly are positioned on a first surface of a common porous film substrate; and(e) adhering the transfer assembly and insert to the first porous film common substrate surface.
  • 8. The method of claim 7, wherein the insert comprises a design and a lamination adhesive positioned between first and second polymeric films.
  • 9. The method of claim 7, wherein the insert is adhered to the porous film common substrate before the transfer assembly is adhered to the porous film common substrate and wherein the insert and transfer assembly are not adhered to one another before step (e).
  • 10. The method of claim 7, wherein the porous film common substrate is larger than the insert, the porous film common substrate provides an overlapping edge and wherein step (d) comprises the sub-step of applying a tack adhesive to the overlapping edge, and wherein the overlapping edge contacts the second surface of the flock.
  • 11. The method of claim 7, wherein a second permanent adhesive is positioned between the insert an a first surface of the porous film common substrate, and further comprising: (f) applying a third permanent adhesive to a second surface of the porous film common substrate, the first and second surfaces of the porous film common substrate being in an opposing relationship.
  • 12. The method of claim 10, wherein the tack adhesive applied is a thermosetting adhesive.
CROSS REFERENCE TO RELATED APPLICATION

The present application claims the benefits, under 35 U.S.C.§119(e), of U.S. Provisional Application Ser. Nos. 60/703,925, filed Jul. 28, 2005, entitled “Flocked Design with Three Dimensional Metallic Insert”; 60/704,681, filed Aug. 1, 2005, of the same title; 60/707,577, filed Aug. 11, 2005, of the same title; 60/710,368, filed Aug. 22, 2005, of the same title; 60/716,869, filed Sep. 13, 2005, of the same title; 60/719,469, filed Sep. 21, 2005, of the same title; 60/779,317, filed Mar. 3, 2006, of the same title; and 60/786,528, filed Mar. 27, 2006, of the same title; each of which is incorporated herein by this reference.

US Referenced Citations (198)
Number Name Date Kind
1580717 Flick Apr 1926 A
1905989 Safir et al. Apr 1933 A
1975542 Forsdale Oct 1934 A
1992676 Schwarz Feb 1935 A
2047978 Maclaurin Jul 1936 A
2275617 Duerr et al. Mar 1942 A
2278227 Thackeray et al. Mar 1942 A
2477912 Vallandigham Aug 1949 A
2592602 Saks Apr 1952 A
2636837 Summers Apr 1953 A
2835576 Ensink May 1958 A
2981588 Hyman Apr 1961 A
2999763 Sommer Sep 1961 A
3099514 Haber Jul 1963 A
3215584 McConnell et al. Nov 1965 A
3314845 Perri Apr 1967 A
3351479 Fairchild Nov 1967 A
3377232 Mencock et al. Apr 1968 A
3432446 Coppeta Mar 1969 A
3459579 Newman Aug 1969 A
3496054 Baigas Feb 1970 A
3529986 Kappas et al. Sep 1970 A
3565742 Stephens et al. Feb 1971 A
3591401 Snyder et al. Jul 1971 A
3630990 Neal Dec 1971 A
3639149 Spalding Feb 1972 A
3657060 Haigh Apr 1972 A
3660200 Anderson et al. May 1972 A
3674611 Petry et al. Jul 1972 A
3772132 Dulin, Jr. Nov 1973 A
3793050 Mumpower, Jr. Feb 1974 A
3803453 Hull Apr 1974 A
3837946 Gribbin Sep 1974 A
3887737 Baxter et al. Jun 1975 A
3900676 Alderson Aug 1975 A
3903331 Klein Sep 1975 A
3917883 Jepson Nov 1975 A
3918895 Mizuno Nov 1975 A
3928706 Gibbons Dec 1975 A
3936554 Squier Feb 1976 A
3956552 Geary May 1976 A
3961116 Klein Jun 1976 A
3969559 Boe Jul 1976 A
3979538 Gilman et al. Sep 1976 A
4018956 Casey Apr 1977 A
4025678 Frank May 1977 A
4034134 Gregorian et al. Jul 1977 A
4035532 Gregorian et al. Jul 1977 A
4062992 Power et al. Dec 1977 A
4098946 Fuzek Jul 1978 A
4142929 Otomine et al. Mar 1979 A
4201810 Higashiguchi May 1980 A
4216281 O'Rell et al. Aug 1980 A
4218501 Kameya et al. Aug 1980 A
4228225 O'Rell et al. Oct 1980 A
4238190 Rejto Dec 1980 A
4263373 McCaskey et al. Apr 1981 A
4264691 O'Rell et al. Apr 1981 A
4265985 O'Rell et al. May 1981 A
4269885 Mahn May 1981 A
4273817 Matsuo et al. Jun 1981 A
4282278 Higashiguchi Aug 1981 A
4292100 Higashiguchi Sep 1981 A
4294577 Bernard Oct 1981 A
4294641 Reed et al. Oct 1981 A
4308296 Chitouras Dec 1981 A
4314813 Masaki Feb 1982 A
4319942 Brenner Mar 1982 A
4330602 O'Rell et al. May 1982 A
4340632 Wells et al. Jul 1982 A
4362773 Shikinami Dec 1982 A
4368231 Egert et al. Jan 1983 A
4368243 O'Rell et al. Jan 1983 A
4369236 O'Rell et al. Jan 1983 A
4390387 Mahn Jun 1983 A
4396662 Higashiguchi Aug 1983 A
4413019 Brenner Nov 1983 A
4418106 Landler et al. Nov 1983 A
4430372 Knoke et al. Feb 1984 A
4438533 Hefele Mar 1984 A
4465723 Knoke et al. Aug 1984 A
4588629 Taylor May 1986 A
4599262 Schulte et al. Jul 1986 A
4610904 Mahn, Sr. et al. Sep 1986 A
4650533 Parker et al. Mar 1987 A
4652478 Maii Mar 1987 A
4687527 Higashiguchi Aug 1987 A
4741791 Howard et al. May 1988 A
4810549 Abrams et al. Mar 1989 A
4812357 O'Rell et al. Mar 1989 A
4861644 Young et al. Aug 1989 A
4895748 Squires Jan 1990 A
4923848 Akada et al. May 1990 A
4931125 Volkmann et al. Jun 1990 A
4980216 Rompp Dec 1990 A
4981750 Murphy et al. Jan 1991 A
5008130 Lenards Apr 1991 A
5047103 Abrams et al. Sep 1991 A
5059452 Squires Oct 1991 A
5066537 O'Rell et al. Nov 1991 A
5077116 Lefkowitz Dec 1991 A
5112423 Liebe, Jr. May 1992 A
5115104 Bunyan May 1992 A
5126182 Lumb et al. Jun 1992 A
5155163 Abeywardena et al. Oct 1992 A
5196262 Schwarz et al. Mar 1993 A
5198277 Hamilton et al. Mar 1993 A
5207851 Abrams May 1993 A
5238737 Burkhardt et al. Aug 1993 A
5298031 Gabay et al. Mar 1994 A
5326391 Anderson et al. Jul 1994 A
5338603 Mahn et al. Aug 1994 A
5346746 Abrams Sep 1994 A
5347927 Berna et al. Sep 1994 A
5352507 Bresson et al. Oct 1994 A
5383996 Dressler Jan 1995 A
5403884 Perlinski Apr 1995 A
5480506 Mahn, Sr. et al. Jan 1996 A
5529650 Bowers et al. Jun 1996 A
5543195 Squires et al. Aug 1996 A
5597633 Mecke et al. Jan 1997 A
5597637 Abrams et al. Jan 1997 A
5681420 Yamane Oct 1997 A
5685223 Vermuelen et al. Nov 1997 A
5756180 Squires et al. May 1998 A
5766397 Jones Jun 1998 A
5771796 Morrison et al. Jun 1998 A
5804007 Asano Sep 1998 A
5858156 Abrams et al. Jan 1999 A
5863633 Squires et al. Jan 1999 A
6010764 Abrams Jan 2000 A
6025068 Pekala Feb 2000 A
6083332 Abrams Jul 2000 A
6110560 Abrams Aug 2000 A
6114023 Schwarz et al. Sep 2000 A
6178680 Sloot Jan 2001 B1
6224707 Lion May 2001 B1
6247215 Van Alboom et al. Jun 2001 B1
6249297 Lion Jun 2001 B1
6350504 Alboom et al. Feb 2002 B1
6361855 Mahn, Jr. et al. Mar 2002 B2
6376041 Morrison et al. Apr 2002 B1
6436506 Pinter et al. Aug 2002 B1
6489038 Sperlich et al. Dec 2002 B1
6544634 Abrams et al. Apr 2003 B1
6676796 Pinter et al. Jan 2004 B2
6774067 Demott et al. Aug 2004 B2
6841240 Gorny et al. Jan 2005 B2
6913714 Liu et al. Jul 2005 B2
6924000 Tallmadge Aug 2005 B2
6929771 Abrams Aug 2005 B1
6977023 Abrams Dec 2005 B2
7021549 O'Rell et al. Apr 2006 B2
7135518 Bandou et al. Nov 2006 B2
7229680 Crompton Jun 2007 B1
7393516 Seo et al. Jul 2008 B2
7461444 Deaett et al. Dec 2008 B2
20010008039 Alboom et al. Jul 2001 A1
20010008672 Norvell et al. Jul 2001 A1
20020009571 Abrams Jan 2002 A1
20020098329 Abrams Jul 2002 A1
20030129353 Abrams Jul 2003 A1
20030186019 Abrams Oct 2003 A1
20030207072 Abrams Nov 2003 A1
20030211279 Abrams Nov 2003 A1
20040010093 Wefringhaus et al. Jan 2004 A1
20040033334 Merovitz Feb 2004 A1
20040050482 Abrams Mar 2004 A1
20040053001 Abrams Mar 2004 A1
20040055692 Abrams Mar 2004 A1
20040058120 Abrams Mar 2004 A1
20040081791 Abrams Apr 2004 A1
20040170799 Carr et al. Sep 2004 A1
20050081985 Abrams Apr 2005 A1
20050124734 Hucks et al. Jun 2005 A1
20050158508 Abrams Jul 2005 A1
20050159575 Rische et al. Jul 2005 A1
20050196594 O'Rell et al. Sep 2005 A1
20050260378 Bernabeu Nov 2005 A1
20050266204 Abrams Dec 2005 A1
20050268407 Abrams Dec 2005 A1
20060026778 Lion Feb 2006 A1
20060029767 Lion Feb 2006 A1
20060142405 Kijima Jun 2006 A1
20060150300 Hassan et al. Jul 2006 A1
20060160943 Weir Jul 2006 A1
20060251852 Abrams Nov 2006 A1
20060257618 Bernabeu Nov 2006 A1
20070003761 Miyazono et al. Jan 2007 A1
20070289688 Abrams Dec 2007 A1
20080003399 Abrams Jan 2008 A1
20080006968 Abrams Jan 2008 A1
20080050548 Abrams Feb 2008 A1
20080095973 Abrams Apr 2008 A1
20080111047 Abrams May 2008 A1
20080113144 Abrams May 2008 A1
20080124503 Abrams May 2008 A1
20080187706 Lion et al. Aug 2008 A1
Foreign Referenced Citations (73)
Number Date Country
606651 Feb 1991 AU
653994 Oct 1994 AU
757595 Apr 1967 CA
2010076 Aug 1990 CA
1306411 Aug 1992 CA
2064300 Sep 1992 CA
202835 Oct 1983 DD
3004560 Aug 1981 DE
19707381 Aug 1998 DE
19734316 Feb 1999 DE
0122656 Oct 1984 EP
0210304 Feb 1987 EP
0280296 Aug 1988 EP
0351079 Jan 1990 EP
0506601 Sep 1992 EP
0685014 Dec 1995 EP
0913271 Oct 1998 EP
0989227 Mar 2000 EP
1072712 Jan 2001 EP
1598463 Nov 2005 EP
2543984 Oct 1984 FR
2659094 Sep 1991 FR
2784619 Apr 2000 FR
2846202 Apr 2004 FR
2881149 Jul 2006 FR
1171296 Nov 1969 GB
1466271 Mar 1977 GB
2065031 Jun 1981 GB
2101932 Jan 1983 GB
2126951 Apr 1984 GB
2214869 Sep 1989 GB
0506601 Sep 1992 GB
71007184 Jun 1965 JP
55079143 Jun 1980 JP
55-147171 Nov 1980 JP
56058824 May 1981 JP
56107080 Aug 1981 JP
56108565 Aug 1981 JP
56141877 Nov 1981 JP
58062027 Apr 1983 JP
S61-146368 Jul 1986 JP
62-033576 Feb 1987 JP
63118544 May 1988 JP
64-014021 Jan 1989 JP
S64-068582 Mar 1989 JP
01192538 Aug 1989 JP
01-266284 Oct 1989 JP
01-310947 Dec 1989 JP
02048076 Feb 1990 JP
04-126221 Apr 1992 JP
04-169297 Jun 1992 JP
5-201196 Aug 1993 JP
08-267625 Oct 1996 JP
11256484 Sep 1999 JP
2000263673 Sep 2000 JP
2001270019 Oct 2001 JP
20030063833 Jul 2003 KR
WO 8901829 Mar 1989 WO
WO 9009289 Aug 1990 WO
WO 9204502 Mar 1992 WO
WO 9312283 Jun 1993 WO
WO 9419530 Sep 1994 WO
WO 9734507 Sep 1997 WO
WO 0207959 Jan 2002 WO
WO 0209925 Feb 2002 WO
WO 02058854 Aug 2002 WO
WO 03031083 Apr 2003 WO
WO 2004005023 Jan 2004 WO
WO 2004005600 Jan 2004 WO
WO 2005035235 Apr 2005 WO
WO 2005118948 Dec 2005 WO
886259 Apr 1990 ZA
922154 Feb 1993 ZA
Related Publications (1)
Number Date Country
20070026189 A1 Feb 2007 US
Provisional Applications (8)
Number Date Country
60703925 Jul 2005 US
60704681 Aug 2005 US
60707577 Aug 2005 US
60710368 Aug 2005 US
60716869 Sep 2005 US
60719469 Sep 2005 US
60779317 Mar 2006 US
60786528 Mar 2006 US