Floor panel

Information

  • Patent Grant
  • 10815676
  • Patent Number
    10,815,676
  • Date Filed
    Thursday, February 20, 2020
    4 years ago
  • Date Issued
    Tuesday, October 27, 2020
    4 years ago
Abstract
A floor may include a substrate having a top side and a bottom side. A top layer may be provided on the substrate. The top layer may consist of a printed thermoplastic film and a thermoplastic transparent or translucent layer provided on the printed thermoplastic film. The top layer may be directly adhered to the substrate by heat welding the printed thermoplastic film and the top side of the substrate, in the absence of a glue layer. The substrate may be a synthetic material board including a filler. The substrate at least at two opposite edges may include coupling means provided in the synthetic material board. The thermoplastic transparent or translucent layer may be provided with a structure.
Description
BACKGROUND
1. Field

This invention relates to floor panels and methods for manufacturing floor panels.


More particularly, the invention relates to floor panels of the type which is at least composed of a substrate and a top layer provided on this substrate, wherein said top layer comprises a motif. As known, above said motif a transparent or translucent synthetic material layer can be provided, which layer then forms part of said top layer.


In particular, the present invention relates to floor panels of the type which, at two or more opposite edges, comprises coupling means or coupling parts, with which two of such floor panels can be coupled at the respective edges, such that they are locked together in a horizontal direction perpendicular to the respective edge the floor panels, as well as in a vertical direction perpendicular to the plane of the floor panels. Such floor panels can be applied for composing a so-called floating floor covering, wherein the floor panels are interconnected at their edges, however, are lying freely on the underlying floor.


2. Related Art

From WO 97/47834, laminate floor panels are known for forming a floating floor covering. However, laminate floor panels show the disadvantage that they mostly are provided with a moisture-sensitive substrate, namely MDF or HDF (Medium Density Fiberboard or High Density Fiberboard), and that the top layer provided on said substrate, when the floor covering is in use, leads to the development of ticking noises. Mostly, laminate floor panels have a thickness situated between 6 and 12 millimeters, wherein the thickness of the top layer mostly is less than 0.5 millimeters. Moreover, the high density of the substrate material leads to high impact sensitivity.


From EP 1 290 290, it is known to provide laminate floor panels with a structured surface, for example, with a structure imitating wood pores. According to EP 1 290 290, such structure can be provided by means of a press device of the short-cycle type and an associated structured press element or press platen. Herein, the structure can be provided in such a manner that it corresponds to the pattern of the laminate floor panels.


From EP 1 938 963, vinyl-based floor panels are known for forming such floating floor covering. Such vinyl-based floor panels mostly have a thickness of 3 to 5 millimeters and have a high material density. Inherent to these floor panels is their limited bending stiffness and their high deformability. These features lead to problems when the floor panels are applied on an uneven underlying surface. Namely, after a certain period of time the unevennesses of the underlying surface may migrate to the surface of the floor covering. With a local load, for example, underneath the legs of tables or chairs, permanent impressions will occur, which are undesired as well. Such floor panels also lead to problems with the propagation of sound towards underlying rooms.


SUMMARY

The present invention relates to an alternative panel, which in particular is intended as a floor panel for forming a floating floor covering. According to various preferred embodiments of the invention, also a solution is offered for one or more problems with the floor panels of the state of the art.


To this aim, the invention, according to its first independent aspect, relates to a floor panel of the type which comprises at least a substrate and a top layer provided thereon, wherein said top layer comprises a motif, with the characteristic that said substrate substantially consists of a foamed synthetic material layer, which preferably has an average density of more than 300 kilograms per cubic meter. In that a foamed synthetic material layer is applied, a less moisture-sensitive floor panel is obtained than in the case of an MDF or HDF substrate. By foaming, with a comparable amount of synthetic material as with the floor panels of EP 1 938 963, a thicker and stiffer substrate is obtained, such that the risk of the occurrence of migration effects from the underlying layer to the surface of the floor covering can be minimized. This is in particular the case when an average density is applied of more than 300 kilograms per cubic meter. Said substrate preferably has a thickness of more than five millimeters. With such thickness of the substrate, the risk of the occurrence of said migration effects is minimized even further. The minimum thickness of five millimeters also allows that sturdy mechanical coupling means can be formed in one piece with the synthetic material board, for example, in that those can be provided at least partially directly in the synthetic material board as milled profiles.


The preferred minimum average density of the foamed synthetic material board is also advantageous when providing, more particularly milling, the profiles and can result in coupling means offering a strong vertical and/or horizontal locking. With said minimum density, it is avoided that the edges of the synthetic material board are deformed too much. Boards of a lower density namely have a higher risk of pushing up the edges, wherein such pushed-up edges will protrude above the actual board surface. Such effect is undesired. Another advantage of said minimum density is that it results in a better resistance against local loads.


Preferably, said synthetic material board has an average density of 450 to 900 kilograms


per cubic meter, preferably 500 to 600 kilograms per cubic meter. It is clear that the above-mentioned advantages of the preferred minimum density are more pronounced with a higher density of the foamed board material. However, too high a density will lead to disadvantageous effects, such as high impact sensitivity and increased sensitivity for possible unevennesses in the underlying surface, whereby sound boxes can be created, which effect an amplification of possible sound developed during the use of the floor covering.


Preferably, said synthetic material board has a local density on one or both flat sides which is higher than in a central layer of the foamed synthetic material board. With such construction, an optimal combination of an average low density and sufficient dimensional stiffness can be obtained. The locally higher density, preferably at least 5 or 10 percent higher than the average density, of course can be situated on the surface itself, as well as at a certain distance underneath the surface of the respective side, however, at a distance from a central layer of the substrate. In the cases where the locally higher density substantially is realized on one of both flat sides only, this preferably relates to the side of the substrate which is situated closest to said top layer. By means of such embodiment, the risk of the occurrence of permanent impressions can be minimized, while the floor panel as a whole has a low weight.


Preferably, said foamed synthetic material board relates to a foamed PVC (polyvinyl chloride) board, or a foamed synthetic material board which substantially consists of another vinyl compound, such as polyvinyl dichloride, polyvinyl butyrate, polyvinyl acetate and the like. As an alternative, as a basis material for the substrate use can also be made of melamine foam, polyurethane or polyisocyanurate.


According to a particular embodiment, said foamed synthetic material board is of the closed cell type, still better it relates to a closed cell foamed PVC board. It is known as such that with foamed synthetic material of the closed cell type the chambers of the foam practically are not interconnected, or at least to a much lesser extent than this is the case with foamed synthetic materials of the open cell type. A foamed synthetic material board of the closed cell type offers a very high stiffness, dimensional stability and water-resistance, with a limited density of, for example, 600 kilograms per cubic meter or less. The limited density offers interesting advantages in logistics, such as in transport. Also, the limited density offers a more ergonomic whole, when 5 to 10 of such floor panels are offered together in a packaging unit. It is clear that the present invention also relates to such packaging unit. The package applied therewith as such preferably consists at least of a cardboard box or open-top box, and shrink film. For example, the packaging materials can be applied which are known as such from WO 2006/103565.


As also mentioned above, an average density of the synthetic material board situated between 500 and 600 kilograms per cubic meter leads to an optimum result of all advantageous and disadvantageous effects. Such density can be realized by means of synthetic materials of the closed cell type, such contrary to the usual hard foams of the open cell type, for example, polyester hard foams or the hard foams known from U.S. Pat. No. 3,853,685, which have a density of 150 kilograms per cubic meter or less and typically are applied for cushions or mattresses.


According to another embodiment, said synthetic material board comprises separate layers which increase the bending stiffness thereof. Such layers preferably are situated at a distance of the center of said synthetic material board, preferably at both sides of this center. Such layers can consist, for example, of a glass fiber cloth or glass fiber fabric. Preferably, this particular embodiment is combined with a locally higher density on one or both flat sides, as also mentioned above.


Preferably, said top layer substantially consists of synthetic material. For example, said top layer can consist substantially of a vinyl compound or of a polyurethane compound. Preferably, said motif herein is formed by a printed synthetic material film, for example, a printed PVC film or a printed PUR (polyurethane) film. However, the invention does not exclude that the pattern can be formed in another manner, for example, by means of a print performed directly on said substrate, or on a primer layer provided on this substrate. The top layer preferably also includes a transparent or translucent layer based on synthetic material and situated above the motif, which layer is provided as a film, whether or not together with said printed film, or is provided in liquid form and subsequently is hardened on the substrate.


Preferably, the adherence between the top layer and the substrate is obtained in that these two are hardened against each other. For example, a top layer of synthetic material can be hardened on an already foamed synthetic material board or vice versa, or a top layer of synthetic material can be hardened while said synthetic material board is foamed against this hardening top layer or vice versa, or the synthetic material board and at least a portion of the top layer can be extruded together, namely, coextruded. According to a variant, said top layer can also be glued to the substrate, for example, with contact glue. According to another variant, the top layer and the substrate can be welded to each other, for example, in that they both are heated and pressed against each other. Herein, the heating preferably is performed at least on the sides of the top layer and the substrate which have to be adhered to each other. To this aim, for example, heating with infrared radiation can be chosen.


It is clear that the entire layer composition of the floor panel can be obtained by a combination of the possibilities or variants therefor mentioned herein. Namely, the top layer as such can consist of different layers, which each as such are provided on the substrate or another adjoining layer according to any of these possibilities.


Preferably, said top layer has a higher density than said substrate, or at least a density of more than 500 kilograms per cubic meter. By using a top layer of high density, nevertheless a substrate consisting of a foamed synthetic material layer of lower density can obtain a good impact resistance. The density of said top layer can be adapted, for example, by the use of filler materials, such as chalk.


It is noted that within the scope of the invention the foamed synthetic material substrate can be provided with filler materials, such as chalk, wood fiber, sand and the like. In such embodiment, savings on the amount of synthetic material can be obtained.


According to a particular preferred embodiment, said top at layer as such of at least a back layer, a motif or pattern provided thereon, and a transparent or translucent wear layer. Said back layer preferably has a thickness which is 45 percent or more of the overall thickness of the top layer. Such back layer preferably consists of a vinyl compound or polyurethane compound, wherein preferably use is made of fillers, such as chalk. The synthetic material applied therewith preferably comprises recycled synthetic material or substantially consists thereof. Preferably, the back layer is made with a higher density than the wear layer. Amongst others, to this aim the application of filler materials in the back layer is of interest. As aforementioned, for the motif or the pattern, use can be made of a printed material sheet, such as a synthetic material film or a print performed directly on the substrate. For said translucent or transparent wear layer, preferably use is made of a vinyl layer or polyurethane layer having a thickness of at least 0.2 millimeters and still better having a thickness of at least 0.3 millimeters.


Preferably, this translucent or transparent layer is made not thicker than 1 millimeter. By means of a transparent layer of 0.25 to 0.7 millimeters, a wear resistance can be obtained which is comparable to that of laminate floor panels. The transparent or translucent layer can either be applied as a film, whether or not together with the aforementioned printed film, or can be applied in liquid form and subsequently be hardened on the substrate. Preferably, the transparent or translucent layer has a thickness which corresponds to at least 25 percent of the overall thickness of the top layer. Optionally, the top layer can include a surface layer on the basis of a UV-hardened substance.


It is noted that according to the above particular embodiment, the back layer, the motif and the wear layer can be manufactured according to various possibilities. According to a first possibility, originally they all are made as a synthetic material layer, which, for example, are bonded to each other at least with the use of heat. This bond can be obtained, for example, in a heated press device, such as in a short-cycle press. Subsequently, such composed layer can be adhered to the substrate, for example, by means of an adhesive connection or by means of a welding connection, wherein the substrate and the top layer are melted together. According to a second possibility, at least the back layer and/or the wear layer are provided in liquid or paste-like form on a carrier material, such as glass fiber non-wovens, where they harden. According to this second possibility, the motif then either can be provided by means of a separate printed film, or can be printed directly on the back layer or on the bottom side of the wear layer, for example, by means of offset printing or inkjet printing, preferably by means of UV-based inks or solvent inks.


Preferably, said floor panel has a thickness of 5 to 10 millimeters, wherein said top layer as such has a thickness of 0.5 to 3 millimeters.


As aforementioned, the floor panel of the invention is intended in particular for composing floating floor coverings. To this aim, the floor panel of the invention comprises preferably at least at two opposite edges coupling means, with which two of such floor panels can be locked to each other in horizontal direction as well as in vertical direction. Preferably, herein this relates to coupling means of the type known as such from WO 97/47834. Preferably, said coupling means substantially are made as a tongue-in-groove coupling, which is provided with locking means or locking parts, wherein said tongue-in-groove coupling realizes said vertical locking, whereas said locking means or parts are provided for realizing said locking in horizontal direction.


Preferably, said coupling means substantially are realized in said foamed synthetic material board. Preferably, said coupling means are provided by means of a milling treatment with rotating milling tools. Preferably, the floor panel of the invention relates to a rectangular, either oblong or square, panel, which, at both pairs of opposite sides, is provided with mechanical coupling means.


According to a particular embodiment, the floor panel, at least at two opposite edges, for example, at the long edges of an oblong floor panel, and preferably at all opposite edges, is provided with a recessed edge having, for example, the shape of a chamfer. Such chamfer preferably is limited in depth to the thickness of said transparent or translucent layer. In the case that a deeper recessed edge is intended, the surface of the recessed edge can be provided with a separate decorative covering, or the color and/or the appearance of a possible back layer and/or the substrate can be adapted to the desired effect to be obtained. Said recessed edge preferably is realized by removing a material portion on the respective edges. As an alternative, they can also be realized by means of a deformation exerted at the location of the edge material.


According to an alternative for the above particular embodiment, said recessed edge also be provided respectively on one edge of a pair opposite edges.


According to a second independent aspect, the present invention relates to a method for manufacturing panels, wherein these panels comprise at least a substrate and a top layer provided on said substrate, wherein said top layer comprises a thermoplastic, translucent or transparent layer, with the characteristic that said method comprises at least the following steps:


the step of providing said top layer, including said thermoplastic layer, on the substrate; the step of heating at least said thermoplastic layer; and


the step of structuring said thermoplastic layer at least by means of a mechanical press element.


It is clear that according to the second aspect of the invention, said thermoplastic layer as such, before being heated, already is layer-shaped. Preferably, said heating relates to heating from a temperature of less than 100° C. to a temperature of more than 100° C. Preferably, a temperature of minimum 120° C. and still better minimum 130° C. is obtained. Preferably, the temperature does not rise above 175° C. Preferably, said thermoplastic layer, before being heated, has a temperature of less than 60° C. and still better of less than 40° C. and/or is it not in a paste-like form.


For heating said thermoplastic layer, use can be made of a radiation source, preferably infrared light. As an alternative, also one or more hot-air ovens or hot-air pistols can be applied.


It is clear that the method of the second aspect preferably is applied for realizing the floor panels of the first aspect. Generally, it can also be applied, independently from the substrate material, for floor panels where such top layer, or at least said thermoplastic layer, substantially consists of a vinyl compound or a polyurethane compound. For examples of such top layers, also reference is made to the preferred first aspect, wherein then again not necessarily use is made of a foamed synthetic material board. Instead, use can be made of other synthetic material boards or of wood-based substrates, such as MDF or HDF, or of mineral boards, such as plasterboards. In any case, according to the second aspect, use preferably is made of a substrate having an average density of more than 450 kilograms per cubic meter, with a thickness situated between 5 and 12 millimeters, such that a sufficient dimensional stability is obtained.


Preferably, for the step of structuring, use is made of a press device of the cyclic type, more particular the short-cycle type; in German better known as a Kurztaktpresse. It is not excluded that the press device is applied for the step of heating the thermoplastic layer. Preferably, however, said heating of the thermoplastic layer is performed at least partially and preferably substantially or entirely prior to the press treatment. Instead of a Kurztaktpresse, use can also be made of a multiple-opening press, wherein then a plurality of thermoplastic layers are structured during the same press cycle.


Preferably, said press device is not heated. In other words, the press device preferably is applied at ambient temperature, wherein it is not excluded that the press element, by the contact with the surface of the thermoplastic layer to be structured, increases its temperature. The inventors have found that such method reduces the risk of deformations of the product. Moreover, such method results in a lower risk of the springing-back of the thermoplastic layer, such that sharp structural details can be realized.


When a heated press device is applied, such heated press cycle preferably is followed by a cold press cycle, whether or not performed in the same press device. If it is not performed in the same press device, preferably at least the same structured press element is applied. In this manner, problems with registering between two press elements can be avoided. For example, the thermoplastic layer with the press element provided thereon can be brought from one to the other press device as one stack, without interrupting the contact between the press element and the thermoplastic layer. It is noted that with a heated press cycle, preferably a temperature of more than 100° C. is reached at the surface of the thermoplastic layer, whereas with a cold press cycle preferably a temperature of less than 60° C. is reached at the surface of the thermoplastic layer.


According to a variant, the press element can be provided on the thermoplastic layer before the whole unit of at least the press element and the thermoplastic layer is fed into the press device. In such method, the thermoplastic layer, prior to the press treatment, can be at least partially heated in that the press element is heated. The heating or warming up of the press element can be performed, for example, by applying magnetic induction. In such method, it is possible to exclude a separate heating of the thermoplastic layer. As aforementioned, said press device preferably as such is not or almost not heated, such that a cooling down of the thermoplastic layer is obtained and the risk of springing back of the layer is minimized.


Preferably, a pressure of the press between 20 and 65 bar is applied, wherein a pressure of approximately 40 bar is a good value.


Preferably, pressing is performed during 12 to 60 seconds, still better during 15 to 30 seconds, and such preferably in the case of a press device of the short-cycle type.


Preferably, as the press element a flat press element or a so-called press platen is applied, which is provided with a structure. Such press element can be manufactured, for example, of metal, namely, a steel alloy, a copper alloy or an aluminum alloy, wherein the structure then can be obtained, for example, by means of etching, laser and/or milling treatments. As an alternative, use can also be made of press elements on the basis of synthetic material, for example, on the basis of melamine or Perspex (PMMA).


It is noted that a method wherein a press element on the basis of melamine or another thermo-hardening synthetic material is applied for structuring a thermoplastic layer, as such forms an independent inventive idea of the present patent application. Such press element as such can consist, for example, of one or more material sheets provided with such thermo-hardening synthetic material, such as paper layers, which are consolidated in a press device. The structure of such press element can be realized in any manner, for example, in that this press element as such is consolidated by means of a structured press element of metal, which, by means of etching, laser, and/or milling treatments, is provided with a relief. The advantage of such method is that the metal press element shows almost no wear, whereas the actual press element on the basis of a thermo-hardening synthetic material is cheap and can be considered a disposable tool. It is clear that the press element of this inventive idea preferably relates to a flat press element, or example, a press element for use in a press device of the cyclic type, in a Kurztaktpresse or in a multiple-opening press. The press element of the invention can be applied in an ideal manner in press treatments in which the press device does not have to be heated. In those applications, the reduced heat transfer of the thermo-harder is of no importance. In applications where heat transfer indeed is of importance, possibly additives in the thermo-harder can be used, which improve the heat conduction thereof, such as, for example, the addition of metal particles, carbon particles and the like. The inventors have found that a thermo-harder shows ideal detachment properties when providing a thermoplastic layer with a structure. Moreover, a thermo-harder can be provided with a sharp structure, such that the freedom of design does not have to be restricted.


Preferably, during the step of warming up, at least a pattern or motif, for example, a printed decor film, is situated on the lower side of said thermoplastic layer. Such method allows that in a smooth manner a structure can be obtained, which corresponds to the pattern or the motif. To this aim, a relative positioning between at least the pattern and the press element can be performed. Still better, the step of applying said top layer on the substrate is performed prior to or possibly at the same time with the step of heating up the thermoplastic layer. In such case, said press treatment preferably is performed a stack comprising at least the substrate and the top layer, including said thermoplastic layer. In the case of a multiple-opening press, then a plurality of such stacks are present in the same press, respectively separated by one or more structured press elements.


It is also noted that said top layer further can also comprise an UV surface coating. Such coating can be intended, for example, for obtaining a resistance against stains, in particular resulting from shoe soles, on the surface of the floor panel. Preferably, such surface coating is applied after said pressing step. Namely, the inventors have found that such surface coating results in an inferior pressing process.


It is clear that the structure, which according to the second aspect is provided in the surface of the thermoplastic layer, relates to a decorative relief, such as, for example, a relief imitating wood. Such relief can consist, for example, of separate impressions, which imitate wood pores and which together form a structure with the appearance of a wood nerve. Preferably, a plurality of such wood pores follow a wood nerve depicted in the motif. Of course, other structures can be realized, too, such as stone structures.


According to a third independent aspect, the present invention also relates to a method for manufacturing the floor panels of the first aspect and/or the preferred embodiments thereof, with the characteristic that this method comprises at least the steps of manufacturing said synthetic material board and of providing said top layer on this synthetic material board, wherein these two steps are performed continuously on the same production line. Preferably, herein said synthetic material board is extruded. The third aspect of the invention provides for an extremely smooth production process for such floor panels.


Preferably, the top layer is at least partially obtained from polyvinyl chloride (PVC) or other vinyl compounds. According to a first possibility for this, it can be started from extruded PVC, which, via heated rollers, is placed as a layer-shaped substance on a carrier material and hardens there. Herein, the carrier material either can comprise said synthetic material board, or can comprise a separate carrier material, such as a glass fiber cloth. Preferably, the carrier material is heated. Possibly, in said vinyl compounds use can be made of plasticizers, such as phthalate plasticizers isosorbide plasticizers, and/or of waxes, for obtaining a smoother process. According to a second possibility hereof, it can be started from one or more vinyl-containing synthetic material films, which are adhered to the synthetic material board, preferably after supplying heat.


Preferably, on the production line of the third aspect, larger boards consisting of foamed synthetic material layers with top layers are formed, from which afterwards, by means of at least a dividing operation, such as a sawing operation, a plurality of floor panels can be obtained.


Of course, the method of the third aspect can be combined with a method having the characteristics of the second aspect.


According to all aspects, the present invention relates to floor panels or other panels, which as such are rigid and thus as such can not be wound up. Preferably, the final panel shows a thickness of more than 5 millimeters, however, preferably less of than 15 millimeters. A good value for the thickness is 7 to 10 millimeters. Such panels are very suitable for providing mechanical coupling means thereon, which allow to couple two or more such panels at their edges to each other. Preferably, herein use is made of mechanical coupling means, such as of the type known from WO 97/47834. It is clear that also the possible larger boards, from which a plurality of such floor panels are formed, and the substrates as such are rigid. Preferably, the floor panels, boards and substrates are so rigid that they will bend less than 10 centimeters per meter under their own weight.





BRIEF DESCRIPTION OF THE DRAWINGS

With the intention of better showing the characteristics of the invention, hereafter, as an example without any limitative character, some preferred embodiments are described, with reference to the accompanying drawings.



FIG. 1 in perspective represents a floor panel according to a non-limiting embodiment of the invention.



FIG. 2, at a larger scale, represents a cross-section according to the line II-II represented in FIG. 1.



FIG. 3 schematically represents a method for manufacturing floor panels.



FIG. 4, at a larger scale, represents a cross-section according to the line IV-IV represented in FIG. 3.



FIGS. 5 to 7, in a view similar to that of FIG. 3, represent variants of a method for manufacturing floor panels.





DESCRIPTION OF NON-LIMITING EMBODIMENTS


FIG. 1 represents a floor panel 1 for forming a floating floor covering.



FIG. 2 clearly shows that the floor panel 1 is of the type which comprises at least a substrate 2 and a top layer 3 provided on this substrate 2, wherein the top layer 3 comprises a motif 4, in this case a wood motif.


In the example of FIGS. 1 and 2, this relates to a rectangular floor panel 1, which, at the first pair 5-6 as well as at the second pair 7-8 of opposite edges, is provided with mechanical coupling means 9.



FIG. 2 represents that the coupling means 9 at the first pair 5-6 of opposite edges, namely, the long edges of the floor panel 1, substantially are performed as a tongue 10, a groove 11, respectively. Herein, the groove 11 is flanked by an upper lip 12 and a lower lip 13. When two of such floor panels 1 are coupled to each other at these edges 5-6, the cooperation of the tongue 10 and the groove 11 as such leads to a locking in a vertical direction V1 perpendicular to the plane of the floor panels 1. The cooperation between the tongue 10 and the groove 11 preferably comprises forming one or more pairs 14-15-16-17 of vertically active locking surfaces. In this case, a pair of locking surfaces 14-15 is formed between the upper surface of the tongue 10 and the lower side of the upper lip 12 and a pair 16-17 between the lower side of the tongue 10 and the upper side of the lower lip 13. At least one of said pairs 14-15, and in this case both pairs 14-15-16-17 of vertically active locking surfaces are formed in the example of the particular substrate 2 of the invention. In this manner, a strong locking in vertical direction V1 is obtained.


The coupling means 9 represented here also comprise locking means or locking parts 18-19, which result in a locking in a horizontal direction H1 perpendicular to the coupled edges 5-6 and in the plane of the coupled floor panels 1. In the example, the locking parts 18-19 are formed as an upstanding part 19 on the lower lip 13 and a recess 18 on the lower side of the tongue 10. These locking parts 18-19 are provided in each other when coupling two or more of such floor panels 1. Herein, one or more, preferably two, pairs 20-21-22-23 of horizontally active locking surfaces are created. In the example, one pair of horizontally active locking surfaces 20-21 is situated on said upstanding part 19 and cooperating therewith surface 20 of said recess 18. This pair of horizontal locking surfaces 20-21 is formed from the material of the particular substrate 2 of the invention. The respective locking surfaces 20-21 are oriented at an angle A with the surface of the floor panels 1. This angle A preferably is more than 30 degrees, and still better more than 45 degrees. Angles A of 90 degrees or more are not excluded. The second pair of horizontal locking surfaces 22-23 of the example is situated next to the floor surface, at the height of the location where the top layers 3 of two floor panels, which are coupled to each other, are flanking each other. In this case, this second pair of locking surfaces 22-23 is made substantially vertical. Moreover, this pair of horizontally active locking surfaces 22-23 is substantially and here even exclusively formed of the material of the top layer 3.


Many of the characteristics listed up above and represented in FIGS. 1 and 2 can be applied, within the scope of the invention, broader than in combination with the other characteristics of the example. The following characteristics, each individually or in any combination, can offer interesting advantages:

    • the characteristic that the coupling means 9 offer a locking in horizontal direction H1 as well as in vertical direction V1, independently from the fact whether the coupling means 9 are mechanical and/or are performed, whether or not substantially, in the form of a tongue 10 and groove 11;
    • the characteristic that at least one pair of horizontally active locking surfaces 20-21 of the coupling means 9 is realized in the substrate 2 of the invention and/or the characteristic that at least one pair of horizontally active locking surfaces 22-23 of the coupling means 9 is at least partially and preferably entirely realized in the top layer 3;
    • the characteristic that one or more pairs 14-15-16-17 of the vertically active locking surfaces are formed at least partially and preferably entirely from the substrate 2;
    • the characteristic that the mechanical coupling means 9 consist of milled profiles, which, for at least 70 percent of their circumference, are provided in the substrate 2 of the invention;
    • the characteristic that the first pair of opposite edges 5-6 as well as the second pair of opposite edges 7-8 is provided with coupling means;
    • the characteristic that the mechanical coupling means 9 allow a coupling by means of a turning movement W along the respective edges 5-6 and/or a horizontal shifting movement S of the edges towards each other and/or a downwardly directed movement of a male coupling part having for example, a tongue 10, into a female coupling part having, for example, a groove 11;
    • the characteristic that the lower lip 13 extends in horizontal direction beyond the upper lip 12;
    • the characteristic that in a coupled condition of two of such floor panels 1 a tension force is obtained between the top layers 3 of the respective floor panels 1; herein, the lower lip 13 preferably is in a bent condition;
    • the characteristic that the lower lip 13, in a coupled condition, is bent.


The particularity of the present invention, at least according to its first aspect, consists in that said substrate 2 substantially consists of a foamed synthetic material board. In the example, the substrate 2 relates to a foamed PVC board of the closed cell type. The board 2 concerned has an average density of 450 kilograms per cubic meter, however, also has a local density on both flat sides 24-25, namely, a density of 500 kilograms per cubic meter or more, which is higher than the density of a central layer 26 of the synthetic material board 2. Moreover, the substrate 2 comprises separate layers 27, in this case layers of glass fiber, which increase the bending stiffness thereof. In the example, these separate layers 27 are situated on both flat sides 24-25 of the substrate 2.


The top layer 3 of the floor panel 1 of the example is a top layer 3 which substantially consists of synthetic material, namely, of a vinyl compound such as PVC (polyvinyl chloride). This top layer 3 has a higher density than the average density of the substrate 2. The represented top layer 3 as such consists of a back layer 28, a provided thereon motif 4 and a transparent wear layer 29. The back layer 28 is the thickest and densest layer of the top layer 3. It consists of recycled synthetic material, here PVC, which comprises filler material, preferably chalk. For said motif 4, use is made of a printed synthetic material film 30. For example, use can be made of a synthetic material film 30 which is printed by means of solvent inks. Such inks may result in a high-resolution print quality. The synthetic material film 30 as such can consist of PVC or another vinyl compound. For the transparent layer or wear layer 29, use is made of vinyl, such as PVC.


Preferably, said transparent layer 29 is free from filler materials or hard particles, such as aluminum oxide. The inventors have found that a transparent or translucent layer 29 of 0.2 millimeters of vinyl as such is sufficient for obtaining an acceptable wear resistance. Of course, it is not excluded that use should be made of a wear layer 29 which comprises hard particles. However, these have a negative influence on the transparency of such wear layer and lead to accelerated wear of machines which are applied when manufacturing such floor panels 1. When hard particles are applied, preferably a wear layer 29 is used having a thickness of less than 0.3 millimeters, or even less than 0.2 millimeters. Preferably, in such case use is made of hard particles in a concentration of 5 to 20 grams per square meter, wherein 10 grams per square meter represent a good value. Preferably, the applied hard particles have an average grain size between 30 and 120 micrometers, and still better between 50 and 90 micrometers.


As is mentioned in the introduction, however, not represented here, the floor panel 1 can be provided with a surface layer at its surface, for example, on the basis of a UV-hardened substance. Such layer preferably has a thickness of less than 0.1 millimeter, or still better of less than 50 micrometers. It is not excluded that such surface layer includes hard particles, such as aluminum oxide particles, wherein these hard particles preferably have an average grain size of less than 50 micrometers. Possibly, flat particles may be used here.


In dashed line 31, it is represented on FIG. 2 that a backing layer 32 can be provided on the lower side of the floor panel 1. Such backing layer 32 preferably consists of a similar material as the top layer 3, for example, of vinyl, which possibly is provided with filler material. Preferably, the density of said backing layer 32 is lower than the density of said top layer 3, or anyhow at least lower than the back layer 28, which in the example is included in said top layer 3. Preferably, the backing layer 32 consists of open cell foamed PVC or so-called cushion vinyl (cushion vinyl). Such backing layer 32 can be connected to the substrate by similar methods as the top layer 3, namely, either by gluing, by foaming it against the substrate or vice versa, by melting or by extruding or otherwise forming this backing layer 32 together with said synthetic material board 2.



FIG. 3 represents a method for manufacturing floor panels 1 in accordance with the embodiment of FIGS. 1 and 2. Herein, larger boards are formed, which show the composition of such floor panel 1 and which, in a step not represented here, are divided into panels showing approximately the final dimensions of such floor panel 1. After this step of dividing, still further operations can be performed on these panels 1, such as forming coupling means or coupling parts 9 at the edges thereof.


The method comprises a step S1 where in the top layer 3 is provided on the substrate 2, and a step S2 wherein a thermoplastic translucent or transparent layer 29, which forms part of the top layer 3, is structured by means of a mechanical press element 33. In the example of FIG. 3, these two steps S1-S2 are performed simultaneously in a press device 34, for example, as represented here, in a press device 34 of the short-cycle type. As press element 33, a press platen is applied.



FIG. 4 clearly shows that this press platen 33 is provided with a structure 35 which is copied by means of the press treatment at least into thermoplastic transparent or translucent layer 29. In this case, the underlying motif 4 and the back layer 28 are deformed as well. However, it is also possible that the motif 4 and/or the back layer 28 are left undisturbed during the press treatment, or that, in other words, the impressions 36 which are formed in the thermoplastic layer 29 are limited in depth, such that at least the motif 4, or the printed synthetic material film 30, is free from local deformations.


Preferably, by means of the step S2 of structuring, impressions 36 are obtained which in location and/or size correspond to the motif 4.


Prior to the press treatment, a step S0 is performed, wherein two thermoplastic layers 29-30 are adhered to each other. Namely, the synthetic material film 30 and the transparent thermoplastic layer 29 are welded or melted to each other by means of a calender device 37. To this aim, use is made of infrared heating 38 and one or more rollers 39. The obtained whole is cut to sheets 41 by means of the cutting tool 40 and, together with the back layer 28, the substrate 2 and a backing layer 32, is brought into the press device 34.


During said press treatment, a third step S3 is performed, too. Herein, the thermoplastic translucent or transparent layer 29 is heated again, by which providing a structure by means of the press element 33 becomes possible. Moreover, by means of this heat an adherence of the thermoplastic layer 29, the synthetic material film 30, the back layer 28, the substrate 2 and the backing layer 32 is obtained. Preferably, the hot press cycle is followed by a cold or cooled press cycle, whether or not taking place in the same press device 34. Such cool cycle prevents an excessive springing back of the realized structure of impressions 36.


According to a not represented variant of FIG. 3, the thermoplastic layer 29 can be sufficiently heated prior to the press treatment, for example, by means of the represented infrared heating 38, such that it can be fed into the press device 37 in warm condition. In such case, a cold press cycle may suffice for structuring the thermoplastic layer 29. The adherence between this thermoplastic layer 29, the back layer 28, the substrate 2 and the possible backing layer 32 then preferably is obtained in another manner than by means of the cold press treatment.



FIG. 5 represents a variant, wherein the thermoplastic layer 29 is provided on the substrate 2 prior to the step S2 of providing a structure. Schematically, a calender device 37 is represented by which the thermoplastic layer 29 and the possible backing layer 32 are adhered to the substrate 2. It is clear that also a possible printed synthetic material film 30 and/or back layer 28, for example, also by means of such device 37, can be provided on the substrate 2 prior to the step S2 of providing a structure. In this case, the complete layer composition 2-3-32 of the floor panel 1 is obtained prior to the step S2 of providing a structure.


In accordance with the second aspect of the invention, in FIG. 5 the thermoplastic layer 29 is heated, in this case prior to the step S2 of providing a structure, by means of one or more infrared heating units 38. The thermoplastic layer 29, while it already forms part of the connected whole of substrate 2, top layer 3 and possible backing layer 32, is fed in its hot condition into the press device 34, where it is provided with impressions 36 by means of a press element 33. Preferably, here a cold press cycle is used. A similar result can be achieved as represented in FIG. 4.



FIG. 6 represents another variant, wherein the thermoplastic transparent or translucent layer 29 is formed in line with the step S1 of providing at least this thermoplastic layer 29 on the substrate 2. To this aim, an extruding machine 42 is installed above a pair of heated rollers 43. By means of the extruding machine 42, amounts of vinyl are provided between said heated rollers 43 and applied in paste-like form on a web-shaped carrier material 44, where it hardens. The carrier material 44 as such can be heated, for example, by means of one or more infrared heating units 38. The carrier material 44 preferably comprises a printed synthetic material film 30, which shows the motif 4 of the final floor panel 1. The extruded vinyl forms a thermoplastic transparent or translucent layer 29 above the motif 4. It is clear that in a similar manner also the back layer 28 and/or the backing layer 32 can be formed against the substrate 2. The step S1 of applying the thermoplastic layer 29 on the substrate 2, the step S3 of heating the thermoplastic layer and the step S2 of providing a structure in this example are performed in a similar manner as in the embodiment of FIG. 5.


It is possible that the thermoplastic layer 29 is provided with a structure at least partially prior to the step S1 of applying this layer 29 on the substrate 2. To this aim, for example, a structured roller 45 can be applied.


In the example of FIG. 6, use is made of a method having the characteristics of the third aspect of the invention. To this aim, the step of manufacturing the synthetic material board 2 and the step S1 of providing the top layer 3 on this synthetic material board 2, or at least providing at least a portion or a partial layer 28-29-30 thereof, for example, the transparent or translucent synthetic material layer 29, are performed continuously and on the same production line. In this case, the synthetic material board 2 is manufactured by means of an extrusion process, which makes use of an extruding machine 46.



FIG. 7, too, represents an embodiment having, amongst others, the characteristics of the second and the third aspect of the invention. In this case, the vinyl originating from the extruding machine 42 is provided in past-like form directly on the substrate 2, namely, without the intermediary of a carrier material. Of course, in such example already one or more other partial layers 28-29-30 of the top layer 3 can be provided on the substrate 2, such as, for example, a back layer 28 and/or a motif 4, for example, in the form of a printed synthetic material film 30. For the rest, the process represented here is similar to that represented in FIGS. 6, 7 and 8.


According to an alternative, which is not represented here, the substrate 2 and one or more partial layers 28-29-30 of the top layer 3 and/or the backing layer 32 are extruded together via so-called coextrusion. Preferably, in such case at least the back layer 28 and/or the backing layer 32 are extruded together with a synthetic material board 2, preferably a foamed synthetic material layer, such as described by means of the first aspect of the invention.


It is clear that the method illustrated in FIGS. 3 to 7 shows examples of a method having the characteristics of the second aspect of the invention. FIGS. 6 and 7 also are examples of the third aspect of the invention.


According to the embodiments of FIGS. 5, 6 and 7, the substrate 2 is supplied as an endless board material, which is divided prior to the step S2 of providing a structure. However, it is not excluded that in these embodiments, too, boards of limited length are applied, for example, a length approximately corresponding to the length of an integer of the final floor panels, for example, corresponding to one to four times this length. It is also possible that the board material from FIGS. 3, 5, 6 and 7, in endless form, is at least subjected to step S2 of providing a structure. In such embodiment, preferably a press device is applied of the continuous type. Of course, in such case the cutting device 40 preferably is arranged after the press device.


It is clear that the infrared heating units 38, as mentioned and/or represented in connection with the figures, can be replaced by any other heating apparatus. According to a particular variant, the press element 33 is provided on the thermoplastic layer 29 prior to the step S2 of providing a structure and this press element 33 is heated, wherein the heating of the thermoplastic layer 29 then occurs at least partially by the contact with the press element 33. In the case of a metallic press element 33, the warming up of the press element 33 can be performed by means of magnetic induction.


The present invention is in no way limited to the embodiments described herein above, on the contrary, such methods and floor panels can be realized according to various variants, without leaving the scope of the present invention. Moreover, the panels, instead as floor panels 1, may also be realized as wall panels or ceiling panels or even as furniture panels. Of course, the methods of the invention, mutatis mutandis, can be applied for manufacturing wall panels, ceiling panels, furniture panels or the like.

Claims
  • 1. A floor panel comprising: a substrate; anda top layer located above and glued to the substrate;wherein the substrate includes a foamed PVC board with fillers;wherein the foamed PVC board has an average density of more than 300 kilograms per cubic meter;wherein the top layer includes a back layer, a printed synthetic material film located above the back layer and a transparent or translucent synthetic material wear layer located above the printed synthetic material film;wherein the back layer includes a vinyl compound with fillers;wherein the back layer has a thickness of at least 45 percent of the thickness of the top layer;wherein the floor panel includes a first pair of edges and a second pair of edges;wherein the floor panel includes first mechanical coupling parts at the first pair of edges and second mechanical coupling parts at the second pair of edges;wherein the first mechanical coupling parts allow a horizontal and vertical locking of two of such floor panels using a turning movement along the respective edges;wherein the first mechanical coupling parts include a tongue and a groove;wherein the groove is flanked by an upper lip and a lower lip;wherein the first mechanical coupling parts include a vertical locking mechanism having a vertically active locking surface at the upper side of the tongue and a vertically active locking surface at the lower side of the upper lip;wherein the first mechanical coupling parts include a horizontal locking mechanism having a horizontally active locking surface at the lower side of the tongue and a horizontally active locking surface at the upper side of the lower lip; andwherein both said horizontally active locking surfaces and both said vertically active locking surfaces are formed completely in the material of the foamed PVC board.
  • 2. The floor panel of claim 1, wherein at least 70 percent of the circumference of the first mechanical coupling parts is formed in the material of the foamed PVC board.
  • 3. The floor panel of claim 1, wherein the first mechanical coupling parts comprise additional horizontally active locking surfaces situated at the height of the location where the top layers of two of such floor panels in coupled condition are flanking each other; and wherein the additional horizontally active locking surfaces are formed substantially in the material of the top layer.
  • 4. The floor panel of claim 1, wherein the first mechanical coupling parts comprise additional vertically active locking surfaces at the lower side of the tongue and the upper side of the lower lip, respectively; and wherein the additional vertically active locking surfaces are formed completely in the material of the foamed PVC board.
  • 5. The floor panel of claim 1, wherein the substrate has a thickness of at least 5 millimeters.
  • 6. The floor panel of claim 1, wherein the foamed PVC board has a top flat side and a bottom flat side; and wherein the foamed PVC board has a local density on the top flat side which is higher than in a central layer of the foamed PVC board.
  • 7. The floor panel of claim 6, wherein the foamed PVC board has a local density on the top flat side and the bottom flat side which is higher than in a central layer of the foamed PVC board.
  • 8. The floor panel of claim 1, wherein the transparent or translucent synthetic material wear layer comprises a vinyl layer.
  • 9. The floor panel of claim 1, wherein the back layer is the thickest and densest layer of the top layer.
  • 10. The floor panel of claim 1, wherein the top layer has a thickness of 0.5 to 3 millimeters.
  • 11. The floor panel of claim 1, wherein the top layer has a density of more than 500 kilograms per cubic meter.
  • 12. The floor panel of claim 1, wherein the top layer has a higher density than the substrate.
  • 13. The floor panel of claim 1, wherein the floor panel comprises a backing layer below the substrate.
  • 14. The floor panel of claim 13, wherein the backing layer has a lower density than the back layer.
  • 15. The floor panel of claim 1, wherein the floor panel has a thickness of 5 to 10 millimeters.
  • 16. The floor panel of claim 1, wherein the floor panel is rectangular and oblong and includes a pair of long edges and a pair of short edges; wherein the pair of long edges is formed by the first pair of edges; andwherein the pair of short edges is formed by the second pair of edges.
  • 17. The floor panel of claim 1, wherein the floor panel will bend less than 10 centimeters per meter under its own weight.
  • 18. The floor panel of claim 1, wherein the foam of said foamed PVC board comprises chambers which are practically not interconnected.
  • 19. A floor panel comprising: a substrate;a top layer located above and glued to the substrate; anda backing layer located below the substrate;wherein the substrate includes a foamed PVC board with fillers;wherein the foamed PVC board has an average density of more than 300 kilograms per cubic meter;wherein the foamed PVC board has a top flat side and a bottom flat side;wherein the foamed PVC board has a local density on the top flat side and the bottom flat side which is higher than in a central layer of the foamed PVC board;wherein the top layer includes a back layer, a printed synthetic material film located above the back layer, a transparent or translucent synthetic material wear layer located above the printed synthetic material film and a surface layer located above the transparent or translucent synthetic material wear layer;wherein the back layer comprises a vinyl compound with fillers;wherein the back layer has a thickness of at least 45 percent of the thickness of the top layer;wherein the transparent or translucent synthetic material wear layer includes a vinyl layer;wherein the surface layer includes a UV hardened substance;wherein the floor panel includes a first pair of edges and a second pair of edges;wherein the floor panel includes first mechanical coupling parts at the first pair of edges and second mechanical coupling parts at the second pair of edges;wherein the first mechanical coupling parts allow a horizontal and vertical locking of two of such floor panels using a turning movement along the respective edges;wherein the first mechanical coupling parts include a tongue and a groove;wherein the groove is flanked by an upper lip and a lower lip;wherein the first mechanical coupling parts include a vertical locking mechanism having a vertically active locking surface at the upper side of the tongue and a vertically active locking surface at the lower side of the upper lip;wherein the first mechanical coupling parts include a horizontal locking mechanism having a horizontally active locking surface at the lower side of the tongue and a horizontally active locking surface at the upper side of the lower lip; andwherein both said horizontally active locking surfaces and both said vertically active locking surfaces are formed completely in the material of the foamed PVC board.
  • 20. The floor panel of claim 19, wherein the substrate has a thickness of at least 5 millimeters.
  • 21. The floor panel of claim 19, wherein the back layer is the thickest and densest layer of the top layer.
  • 22. The floor panel of claim 19, wherein the top layer has a thickness of 0.5 to 3 millimeters.
  • 23. The floor panel of claim 19, wherein the top layer has a higher density than the substrate.
  • 24. The floor panel of claim 19, wherein the top layer has a density of more than 500 kilograms per cubic meter.
  • 25. The floor panel of claim 19, wherein the backing layer has a lower density than the back layer.
  • 26. The floor panel of claim 19, wherein the floor panel has a thickness of 5 to 10 millimeters.
  • 27. The floor panel of claim 19, wherein the floor panel is rectangular and oblong and includes a pair of long edges and a pair of short edges; wherein the pair of long edges is formed by the first pair of edges; andwherein the pair of short edges is formed by the second pair of edges.
  • 28. The floor panel of claim 19, wherein the floor panel will bend less than 10 centimeters per meter under its own weight.
  • 29. The floor panel of claim 19, wherein the foam of said foamed PVC board comprises chambers which are practically not interconnected.
  • 30. A floor panel comprising: a substrate; anda top layer located above and welded to the substrate;wherein the substrate includes a foamed PVC board with fillers;wherein the foamed PVC board has an average density of more than 300 kilograms per cubic meter;wherein the top layer includes a back layer, a printed synthetic material film located above the back layer and a transparent or translucent synthetic material wear layer located above the printed synthetic material film;wherein the top layer has a thickness of 0.5 to 3 millimeters;wherein the top layer has a density of more than 500 kilograms per cubic meter;wherein the back layer comprises a vinyl compound with fillers;wherein the back layer has a thickness of at least 45 percent of the thickness of the top layer;wherein the back layer has a higher density than the transparent or translucent synthetic material wear layer;wherein the transparent or translucent synthetic material wear layer has a thickness of 1 millimeter or less;wherein the floor panel is rectangular and oblong and includes a pair of long edges and a pair of short edges;wherein the floor panel includes first mechanical coupling parts at the pair of long edges and second mechanical coupling parts at the pair of short edges;wherein the first mechanical coupling parts allow a horizontal and vertical locking of two of such floor panels using a turning movement along the respective long edges;wherein the first mechanical coupling parts include a tongue and a groove;wherein the groove is flanked by an upper lip and a lower lip;wherein the first mechanical coupling parts include a vertical locking mechanism having a vertically active locking surface at the upper side of the tongue and a vertically active locking surface at the lower side of the upper lip;wherein the first mechanical coupling parts include a horizontal locking mechanism having a horizontally active locking surface at the lower side of the tongue and a horizontally active locking surface at the upper side of the lower lip; andwherein both said horizontally active locking surfaces are formed completely in the material of the foamed PVC board.
  • 31. The floor panel of claim 30, wherein the foamed PVC board has a top flat side and a bottom flat side; and wherein the foamed PVC board comprises a first glass fiber layer situated on the top flat side and a second glass fiber layer situated on the bottom flat side.
  • 32. The floor panel of claim 30, wherein the floor panel will bend less than 10 centimeters per meter under its own weight.
  • 33. The floor panel of claim 30, wherein the foam of said foamed PVC board comprises chambers which are practically not interconnected.
Priority Claims (1)
Number Date Country Kind
2010/0283 May 2010 BE national
Parent Case Info

This application is a continuation application of U.S. patent application Ser. No. 15/695,163, filed Sep. 5, 2017, which is a continuation of U.S. patent application Ser. No. 15/045,389 filed Feb. 17, 2016, now U.S. Pat. No. 9,783,995 issued Oct. 10, 2017, which is a continuation application of U.S. patent application Ser. No. 14/015,307 filed Aug. 30, 2013, now U.S. Pat. No. 9,322,184 issued Apr. 26, 2016, which is a divisional application of U.S. patent application Ser. No. 13/696,769 filed Nov. 7, 2012, now U.S. Pat. No. 8,549,807 issued Oct. 8, 2013, which is a US National Phase Application of International Application No. PCT/IB2011/051884 filed Apr. 28, 2011, the entire content of all which are incorporated herein by reference. This application claims priority under 35 USC § 119(a)-(d) to Belgian Patent Application No. 2010/0283 filed May 10, 2010, the entire content of which is incorporated herein by reference.

US Referenced Citations (469)
Number Name Date Kind
1387011 Ratcliff Aug 1921 A
1448180 Atwood et al. Mar 1923 A
1887011 Carr et al. Sep 1930 A
1921164 Lewis Aug 1933 A
1971067 Fess Aug 1934 A
2143220 Cheney Jan 1939 A
3038363 Miessner Jun 1962 A
3173804 Standfuss Mar 1965 A
3282010 King, Jr. Nov 1966 A
3383262 Ettore et al. May 1968 A
3434861 Luc Mar 1969 A
3498870 Fritchey Mar 1970 A
3554827 Yamagishi Jan 1971 A
3740914 Diez Jun 1973 A
3741851 Erb et al. Jun 1973 A
3810774 Pittman May 1974 A
3811915 Burrell et al. May 1974 A
3853685 Friedrich et al. Dec 1974 A
3905849 Bomboire Sep 1975 A
4050409 Duchenaud et al. Sep 1977 A
4097635 Sanz Hernández et al. Jun 1978 A
4225374 Kaufmann Sep 1980 A
4233343 Barker et al. Nov 1980 A
4242390 Nemeth Dec 1980 A
4312686 Smith et al. Jan 1982 A
4379198 Jaeschke et al. Apr 1983 A
4396566 Brinkmann et al. Aug 1983 A
4397896 Moran Aug 1983 A
4400862 Ignell Aug 1983 A
4426820 Terbrack et al. Jan 1984 A
4471012 Maxwell Sep 1984 A
4614680 Fry et al. Sep 1986 A
4654099 Sandman Mar 1987 A
4690434 Schmidt Sep 1987 A
4778547 Becker et al. Oct 1988 A
4833855 Winter, IV May 1989 A
4844763 Robbins Jul 1989 A
4913858 Miekka et al. Apr 1990 A
4948653 Dinter et al. Aug 1990 A
4975008 Wagner Dec 1990 A
5034084 Schäfer et al. Jul 1991 A
5077112 Hensel et al. Dec 1991 A
5082495 Iijima Jan 1992 A
5112671 Diamond et al. May 1992 A
5261508 Kikuchi Nov 1993 A
5275862 Ramadan et al. Jan 1994 A
5344704 O'Dell et al. Sep 1994 A
5394672 Seem Mar 1995 A
5437964 Witt et al. Aug 1995 A
5516472 Laver May 1996 A
5560797 Burt et al. Oct 1996 A
5728476 Harwood et al. Mar 1998 A
5755068 Ormiston May 1998 A
5787675 Futagi Aug 1998 A
5836128 Groh et al. Nov 1998 A
5863632 Bisker Jan 1999 A
5899038 Stroppiana May 1999 A
5916662 Schmidt Jun 1999 A
5928772 Shiraishi et al. Jul 1999 A
5952076 Foster Sep 1999 A
5961903 Eby et al. Oct 1999 A
5976288 Ekendahl Nov 1999 A
5988503 Kuo Nov 1999 A
6006486 Moriau et al. Dec 1999 A
6098357 Franklin et al. Aug 2000 A
6216409 Roy et al. Apr 2001 B1
6256959 Palmersten Jul 2001 B1
6282859 Van Der Heijden Sep 2001 B1
6287678 Spengler Sep 2001 B1
6306318 Ricciardelli et al. Oct 2001 B1
6333094 Schneider et al. Dec 2001 B1
6345481 Nelson Feb 2002 B1
6385936 Schneider May 2002 B1
6444075 Schneider et al. Sep 2002 B1
6467224 Bertolini Oct 2002 B1
6477948 Nissing et al. Nov 2002 B1
6490836 Moriau et al. Dec 2002 B1
6536178 Pålsson et al. Mar 2003 B1
6588166 Martensson et al. Jul 2003 B2
6591568 Pålsson Jul 2003 B1
6617009 Chen et al. Sep 2003 B1
6647690 Martensson Nov 2003 B1
6764741 Kawasumi et al. Jul 2004 B2
6769219 Schwitte et al. Aug 2004 B2
6769835 Stridsman Aug 2004 B2
6772568 Thiers et al. Aug 2004 B2
6804926 Eisermann Oct 2004 B1
6874282 Moriau et al. Apr 2005 B1
6880307 Schwitte et al. Apr 2005 B2
6918221 Williams Jul 2005 B2
6928779 Moriau et al. Aug 2005 B2
6931811 Thiers Aug 2005 B2
6933043 Son et al. Aug 2005 B1
6955020 Moriau et al. Oct 2005 B2
6979487 Scarbrough et al. Dec 2005 B2
6991830 Hansson et al. Jan 2006 B1
6993877 Moriau et al. Feb 2006 B2
7040068 Moriau et al. May 2006 B2
7063768 Tsujimoto et al. Jun 2006 B2
7093399 Thiers et al. Aug 2006 B2
7169460 Chen et al. Jan 2007 B1
7243469 Miller Jul 2007 B2
7328536 Moriau et al. Feb 2008 B2
7357959 Bauer Apr 2008 B2
7377081 Ruhdorfer May 2008 B2
7451578 Hannig Nov 2008 B2
7452440 Tsujimoto et al. Nov 2008 B1
7467499 Moriau et al. Dec 2008 B2
7484337 Hecht Feb 2009 B2
7516588 Pervan Apr 2009 B2
7584583 Bergelin et al. Sep 2009 B2
7596920 Konstanczak Oct 2009 B2
7600354 Knauseder Oct 2009 B2
7603826 Moebus Oct 2009 B1
7617645 Moriau et al. Nov 2009 B2
7621092 Groeke et al. Nov 2009 B2
7621094 Moriau et al. Nov 2009 B2
7634886 Moriau et al. Dec 2009 B2
7634887 Moriau et al. Dec 2009 B2
7637066 Moriau et al. Dec 2009 B2
7637067 Moriau et al. Dec 2009 B2
7640708 Moriau et al. Jan 2010 B2
7644554 Moriau et al. Jan 2010 B2
7644555 Moriau et al. Jan 2010 B2
7644557 Moriau et al. Jan 2010 B2
7647741 Moriau et al. Jan 2010 B2
7647743 Moriau et al. Jan 2010 B2
7650727 Moriau et al. Jan 2010 B2
7650728 Moriau et al. Jan 2010 B2
7654054 Moriau et al. Feb 2010 B2
7658048 Moriau et al. Feb 2010 B2
7661238 Moriau et al. Feb 2010 B2
7665265 Moriau et al. Feb 2010 B2
7665266 Moriau et al. Feb 2010 B2
7665267 Moriau et al. Feb 2010 B2
7665268 Moriau et al. Feb 2010 B2
7669376 Moriau et al. Mar 2010 B2
7669377 Moriau et al. Mar 2010 B2
7673431 Moriau et al. Mar 2010 B2
7677008 Moriau et al. Mar 2010 B2
7681371 Moriau et al. Mar 2010 B2
7698868 Moriau et al. Apr 2010 B2
7698869 Moriau et al. Apr 2010 B2
7707793 Moriau et al. May 2010 B2
7712280 Moriau et al. May 2010 B2
7726088 Muehlebach Jun 2010 B2
7726089 Moriau et al. Jun 2010 B2
7735288 Moriau et al. Jun 2010 B2
7757453 Moriau et al. Jul 2010 B2
7762035 Cappelle Jul 2010 B2
7770350 Moriau et al. Aug 2010 B2
7810297 Moriau et al. Oct 2010 B2
7827754 Moriau et al. Nov 2010 B2
7827755 Moriau et al. Nov 2010 B2
7836648 Garcia et al. Nov 2010 B2
7841145 Pervan et al. Nov 2010 B2
7861483 Dammers Jan 2011 B2
7930862 Bergelin et al. Apr 2011 B2
7980039 Groeke et al. Jul 2011 B2
7984600 Alford et al. Jul 2011 B2
8038363 Hannig et al. Oct 2011 B2
8056236 Brouckaert et al. Nov 2011 B2
8071193 Windmöller Dec 2011 B2
8099924 Braun Jan 2012 B2
8112891 Pervan Feb 2012 B2
8132384 Hannig Mar 2012 B2
8153234 Nollet Apr 2012 B2
8156705 Alford et al. Apr 2012 B2
8166723 Moriau et al. May 2012 B2
8191333 Braun Jun 2012 B2
8204904 Bonchi et al. Jun 2012 B2
8209928 Garcia et al. Jul 2012 B2
8245477 Pervan Aug 2012 B2
8245478 Bergelin et al. Aug 2012 B2
8261508 Thiers Sep 2012 B2
8272187 Meersseman et al. Sep 2012 B2
8302361 Braun et al. Nov 2012 B2
8302367 Schulte Nov 2012 B2
8303743 Youn et al. Nov 2012 B2
8335212 Hovey et al. Dec 2012 B2
8336272 Prager et al. Dec 2012 B2
8341915 Pervan et al. Jan 2013 B2
8365494 Moriau et al. Feb 2013 B2
8375672 Hannig Feb 2013 B2
8381476 Hannig Feb 2013 B2
8381477 Pervan et al. Feb 2013 B2
8407963 Schulte Apr 2013 B2
8465804 Provoost et al. Jun 2013 B2
8475871 Oldorff Jul 2013 B2
8511031 Bergelin et al. Aug 2013 B2
8511040 Braun et al. Aug 2013 B2
8516767 Engstrom Aug 2013 B2
8584423 Pervan et al. Nov 2013 B2
8621814 Cappelle Jan 2014 B2
8631621 Hannig Jan 2014 B2
8726513 Braun et al. May 2014 B2
8789334 Moriau et al. Jul 2014 B2
8806830 Schacht et al. Aug 2014 B2
8820014 Durnberger Sep 2014 B2
8839584 Sokol Sep 2014 B2
8966852 Cappelle Mar 2015 B2
8966853 Hannig Mar 2015 B2
8991055 Cappelle Mar 2015 B2
8997429 Moriau et al. Apr 2015 B2
9109366 Schulte Aug 2015 B2
9145691 Cappelle Sep 2015 B2
9169658 Hecht Oct 2015 B2
9194133 Thiers Nov 2015 B2
9200460 Cappelle Dec 2015 B2
9222267 Bergelin et al. Dec 2015 B2
9290040 Verhaeghe Mar 2016 B2
9290948 Cappelle et al. Mar 2016 B2
9290951 Moriau et al. Mar 2016 B2
9366037 Cappelle Jun 2016 B2
9371654 Cappelle Jun 2016 B2
9487957 Cappelle Nov 2016 B2
9506256 Thiers Nov 2016 B2
9534400 Schacht et al. Jan 2017 B2
9695599 Cappelle Jul 2017 B2
9745756 Hannig Aug 2017 B2
9765530 Bergelin et al. Sep 2017 B2
9890542 Cappelle Feb 2018 B2
9932741 Cappelle et al. Apr 2018 B2
10094123 Meersseman Oct 2018 B2
10100532 Schacht et al. Oct 2018 B2
10100533 Meersseman Oct 2018 B2
10125499 Cappelle Nov 2018 B2
10240348 Pervan et al. Mar 2019 B2
10358831 Cappelle Jul 2019 B2
10450760 Bergelin et al. Oct 2019 B2
10519674 Cappelle Dec 2019 B2
20010034991 Martensson et al. Nov 2001 A1
20020009598 Lafave et al. Jan 2002 A1
20020020127 Thiers et al. Feb 2002 A1
20020046528 Pervan et al. Apr 2002 A1
20020056245 Thiers May 2002 A1
20020092252 Kettler et al. Jul 2002 A1
20020092263 Schulte Jul 2002 A1
20020136862 Dong et al. Sep 2002 A1
20020142106 Bethune et al. Oct 2002 A1
20020160680 Laurence Oct 2002 A1
20020170258 Schwitte et al. Nov 2002 A1
20020189183 Ricciardelli Dec 2002 A1
20030024199 Pervan Feb 2003 A1
20030024200 Moriau et al. Feb 2003 A1
20030024201 Moriau et al. Feb 2003 A1
20030029115 Moriau et al. Feb 2003 A1
20030029116 Moriau et al. Feb 2003 A1
20030029117 Moriau et al. Feb 2003 A1
20030029119 Coleman Feb 2003 A1
20030033777 Thiers et al. Feb 2003 A1
20030033779 Downey Feb 2003 A1
20030037504 Schwitte et al. Feb 2003 A1
20030097808 Sabatini May 2003 A1
20030101674 Pervan et al. Jun 2003 A1
20030159385 Thiers Aug 2003 A1
20030159777 Tsujimoto et al. Aug 2003 A1
20040016197 Ruhdorfer Jan 2004 A1
20040020145 Matsufuji Feb 2004 A1
20040026017 Taylor et al. Feb 2004 A1
20040028830 Bauer Feb 2004 A1
20040068954 Martensson Apr 2004 A1
20040071978 Hallenbeck et al. Apr 2004 A1
20040102120 Plusquellec et al. May 2004 A1
20040103602 Geraud Jun 2004 A1
20040128934 Hecht Jul 2004 A1
20040137248 Elsasser Jul 2004 A1
20040139678 Pervan Jul 2004 A1
20040139679 Della Pepa Jul 2004 A1
20040146695 Hardwick Jul 2004 A1
20040161588 Mauk et al. Aug 2004 A1
20040168392 Konzelmann et al. Sep 2004 A1
20040182036 Sjoberg et al. Sep 2004 A1
20040191547 Oldorff Sep 2004 A1
20040211143 Hannig Oct 2004 A1
20040250914 Olofsson Dec 2004 A1
20040255538 Ruhdorfer Dec 2004 A1
20050016107 Rosenthal et al. Jan 2005 A1
20050025934 Thiers Feb 2005 A1
20050050827 Schitter Mar 2005 A1
20050153243 Rundle et al. Jul 2005 A1
20050186393 Wilson Aug 2005 A1
20050208255 Pervan Sep 2005 A1
20050221056 Schwonke et al. Oct 2005 A1
20050224174 Tsujimoto et al. Oct 2005 A1
20050281986 Nam Dec 2005 A1
20050284075 Moriau et al. Dec 2005 A1
20050284076 Moriau et al. Dec 2005 A1
20060005499 Moriau et al. Jan 2006 A1
20060008630 Thiers et al. Jan 2006 A1
20060032175 Chen et al. Feb 2006 A1
20060032177 Moriau Feb 2006 A1
20060062966 Kang et al. Mar 2006 A1
20060064940 Cappelle Mar 2006 A1
20060075713 Pervan et al. Apr 2006 A1
20060156670 Knauseder Jul 2006 A1
20060174578 Konstanczak Aug 2006 A1
20060179773 Pervan Aug 2006 A1
20060196138 Moriau et al. Sep 2006 A1
20060201095 Moriau et al. Sep 2006 A1
20060204773 Kwon et al. Sep 2006 A1
20060225370 Moriau et al. Oct 2006 A1
20060225377 Moriau et al. Oct 2006 A1
20060236630 Moriau et al. Oct 2006 A1
20060236631 Moriau et al. Oct 2006 A1
20060236632 Moriau et al. Oct 2006 A1
20060236633 Moriau et al. Oct 2006 A1
20060236634 Moriau et al. Oct 2006 A1
20060236635 Moriau et al. Oct 2006 A1
20060236636 Moriau et al. Oct 2006 A1
20060236637 Moriau et al. Oct 2006 A1
20060236638 Moriau et al. Oct 2006 A1
20060236643 Moriau et al. Oct 2006 A1
20060248829 Moriau et al. Nov 2006 A1
20060248830 Moriau et al. Nov 2006 A1
20060248831 Moriau et al. Nov 2006 A1
20060254183 Moriau et al. Nov 2006 A1
20060254184 Moriau et al. Nov 2006 A1
20060254185 Moriau et al. Nov 2006 A1
20060260249 Moriau et al. Nov 2006 A1
20060272263 Moriau et al. Dec 2006 A1
20060280870 Halot et al. Dec 2006 A1
20070006543 Engstrom Jan 2007 A1
20070051064 Thiers Mar 2007 A1
20070094978 Svanholm et al. May 2007 A1
20070094986 Moriau et al. May 2007 A1
20070094987 Moriau et al. May 2007 A1
20070107360 Moriau et al. May 2007 A1
20070107363 Moriau et al. May 2007 A1
20070141316 McGrath et al. Jun 2007 A1
20070151189 Yang Jul 2007 A1
20070175148 Bergelin et al. Aug 2007 A1
20070175160 Groeke et al. Aug 2007 A1
20070193178 Groeke et al. Aug 2007 A1
20070202314 Youn et al. Aug 2007 A1
20070251188 Moriau et al. Nov 2007 A1
20070254175 Song Nov 2007 A1
20070266666 Dammers Nov 2007 A1
20070294968 Braun Dec 2007 A1
20080000183 Bergelin et al. Jan 2008 A1
20080000186 Pervan et al. Jan 2008 A1
20080005999 Pervan Jan 2008 A1
20080010928 Moriau et al. Jan 2008 A1
20080010929 Moriau et al. Jan 2008 A1
20080010931 Pervan et al. Jan 2008 A1
20080010938 Hannig Jan 2008 A1
20080029926 Steinwender et al. Feb 2008 A1
20080034701 Pervan Feb 2008 A1
20080053027 Moriau et al. Mar 2008 A1
20080053028 Moriau et al. Mar 2008 A1
20080060308 Pervan et al. Mar 2008 A1
20080060309 Moriau et al. Mar 2008 A1
20080060310 Moriau et al. Mar 2008 A1
20080060311 Moriau et al. Mar 2008 A1
20080066416 Moriau et al. Mar 2008 A1
20080078181 Mueller et al. Apr 2008 A1
20080118713 Bordener May 2008 A1
20080134607 Pervan et al. Jun 2008 A1
20080134613 Pervan Jun 2008 A1
20080134614 Pervan et al. Jun 2008 A1
20080138560 Windmoller Jun 2008 A1
20080152825 Mukai et al. Jun 2008 A1
20080168737 Pervan Jul 2008 A1
20080172856 Brouckaert et al. Jul 2008 A1
20080295432 Pervan et al. Dec 2008 A1
20080295438 Knauseder Dec 2008 A1
20080295958 Tsujimoto et al. Dec 2008 A1
20080305312 Kim et al. Dec 2008 A1
20080311355 Chen et al. Dec 2008 A1
20090019801 Coghlan et al. Jan 2009 A1
20090019806 Muehlebach Jan 2009 A1
20090019808 Palsson et al. Jan 2009 A1
20090031662 Chen et al. Feb 2009 A1
20090042010 Stanhope Feb 2009 A1
20090047465 Zafiroglu Feb 2009 A1
20090061168 Kim Mar 2009 A1
20090064624 Sokol Mar 2009 A1
20090100782 Groeke et al. Apr 2009 A1
20090133353 Pervan et al. May 2009 A1
20090133358 Hecht May 2009 A1
20090139170 Thiers Jun 2009 A1
20090151290 Liu Jun 2009 A1
20090155612 Pervan Jun 2009 A1
20090173032 Prager et al. Jul 2009 A1
20090193741 Cappelle Aug 2009 A1
20090217615 Engstrom Sep 2009 A1
20090223162 Chen Sep 2009 A1
20090226662 Dyczko-Riglin et al. Sep 2009 A1
20090260307 Thiers Oct 2009 A1
20090260313 Segaert Oct 2009 A1
20090269522 Liu Oct 2009 A1
20090320402 Schacht et al. Dec 2009 A1
20100015420 Riebel Jan 2010 A1
20100018149 Thiers Jan 2010 A1
20100037550 Braun Feb 2010 A1
20100043333 Hannig Feb 2010 A1
20100055420 Vermeulen Mar 2010 A1
20100058590 Braun et al. Mar 2010 A1
20100083603 Goodwin Apr 2010 A1
20100115874 Nilsson May 2010 A1
20100192793 Verhaeghe Aug 2010 A1
20100218450 Braun et al. Sep 2010 A1
20100281803 Cappelle Nov 2010 A1
20100300029 Braun et al. Dec 2010 A1
20100319292 Moriau et al. Dec 2010 A1
20110023405 Moriau et al. Feb 2011 A1
20110056167 Nilsson Mar 2011 A1
20110088346 Hannig Apr 2011 A1
20110138722 Hannig Jun 2011 A1
20110154763 Bergelin et al. Jun 2011 A1
20110162312 Schulte Jul 2011 A1
20110162777 Youn et al. Jul 2011 A1
20110225921 Schulte Sep 2011 A1
20110225922 Pervan et al. Sep 2011 A1
20110268937 Schacht et al. Nov 2011 A1
20110271632 Cappelle et al. Nov 2011 A1
20110300392 Vermeulen Dec 2011 A1
20110308182 Downey Dec 2011 A1
20120011796 Hannig Jan 2012 A1
20120015107 Schacht et al. Jan 2012 A1
20120055112 Engstrom Mar 2012 A1
20120067461 Braun Mar 2012 A1
20120124932 Cappelle et al. May 2012 A1
20120174519 Schulte Jul 2012 A1
20120174521 Schulte Jul 2012 A1
20120213973 Clement Aug 2012 A1
20120266555 Cappelle Oct 2012 A1
20120279154 Bergelin et al. Nov 2012 A1
20130008118 Baert et al. Jan 2013 A1
20130008127 Braun et al. Jan 2013 A1
20130036695 Durnberger Feb 2013 A1
20130042558 Cordeiro Feb 2013 A1
20130062006 Meersseman et al. Mar 2013 A1
20130067842 Meersseman et al. Mar 2013 A1
20130081349 Pervan et al. Apr 2013 A1
20130104487 Moriau et al. May 2013 A1
20130295352 Thiers et al. Nov 2013 A1
20130298487 Bergelin et al. Nov 2013 A1
20130305649 Thiers Nov 2013 A1
20140020820 Meersseman et al. Jan 2014 A1
20140033635 Pervan et al. Feb 2014 A1
20140033636 Cappelle Feb 2014 A1
20140053497 Pervan et al. Feb 2014 A1
20140130437 Cappelle May 2014 A1
20140150369 Hannig Jun 2014 A1
20140255659 Windmöller Sep 2014 A1
20140290174 Moriau et al. Oct 2014 A1
20140318070 Schacht et al. Oct 2014 A1
20150167317 Cappelle Jun 2015 A1
20150204080 Cappelle Jul 2015 A1
20150204081 Cappelle Jul 2015 A1
20150211238 Moriau et al. Jul 2015 A1
20160046144 Thiers Feb 2016 A1
20160069089 Bergelin et al. Mar 2016 A1
20160193857 De Mondt et al. Jul 2016 A1
20160215505 Cappelle et al. Jul 2016 A1
20160251861 Cappelle Sep 2016 A1
20160265233 Cappelle Sep 2016 A1
20170051514 Cappelle Feb 2017 A1
20170089078 Schacht et al. Mar 2017 A1
20170284106 Cappelle Oct 2017 A1
20170335571 Hannig Nov 2017 A1
20170350140 Bergelin et al. Dec 2017 A1
20180127985 Cappelle May 2018 A1
20180223540 Cappelle Aug 2018 A1
20190048595 Cappelle Feb 2019 A1
20190093370 Pervan et al. Mar 2019 A1
20190330858 Cappelle Oct 2019 A1
20200063444 Cappelle Feb 2020 A1
Foreign Referenced Citations (245)
Number Date Country
1011466 Oct 1999 BE
1017703 Apr 2009 BE
1237344 May 1988 CA
2226286 Dec 1997 CA
2734801 Mar 2010 CA
2110047 Jul 1992 CN
1119152 Mar 1996 CN
2301491 Dec 1998 CN
1239174 Dec 1999 CN
2364121 Feb 2000 CN
2415082 Jan 2001 CN
1361844 Jul 2002 CN
1399051 Feb 2003 CN
2536701 Feb 2003 CN
2536704 Feb 2003 CN
2654757 Nov 2004 CN
2688807 Mar 2005 CN
2705574 Jun 2005 CN
2880971 Mar 2007 CN
101023230 Aug 2007 CN
101042014 Sep 2007 CN
101072691 Nov 2007 CN
100354492 Dec 2007 CN
101158226 Apr 2008 CN
101168610 Apr 2008 CN
201071580 Jun 2008 CN
101300142 Nov 2008 CN
101368440 Feb 2009 CN
101376277 Mar 2009 CN
101397840 Apr 2009 CN
101460688 Jun 2009 CN
201268019 Jul 2009 CN
100523404 Aug 2009 CN
101529032 Sep 2009 CN
101544005 Sep 2009 CN
101544082 Sep 2009 CN
101545314 Sep 2009 CN
101563511 Oct 2009 CN
101629446 Jan 2010 CN
201381624 Jan 2010 CN
201679203 Dec 2010 CN
202483139 Oct 2012 CN
254920 Dec 1912 DE
1534802 Apr 1970 DE
2545854 Oct 1976 DE
2721292 Nov 1978 DE
2856391 Jul 1980 DE
254920 Mar 1988 DE
19532819 Mar 1997 DE
19725829 Aug 1998 DE
20002744 Aug 2000 DE
19944399 Apr 2001 DE
20206751 Aug 2002 DE
10138285 Mar 2003 DE
20300306 Apr 2003 DE
10154767 May 2003 DE
20300291 Nov 2003 DE
10237397 Feb 2004 DE
10230818 Mar 2004 DE
102004055951 Jul 2005 DE
102005002297 Aug 2005 DE
102004009160 Sep 2005 DE
102004023157 Nov 2005 DE
202005019427 Apr 2006 DE
202007000310 Apr 2007 DE
102006054023 Dec 2007 DE
102007018309 Aug 2008 DE
202008008597 Aug 2008 DE
102007015907 Oct 2008 DE
202008011589 Nov 2008 DE
102007026342 Jan 2009 DE
102007032885 Jan 2009 DE
102007035648 Jan 2009 DE
102007042250 Mar 2009 DE
102007043308 Mar 2009 DE
2009004530 Jun 2009 DE
102007062430 Jul 2009 DE
102008003550 Jul 2009 DE
102008022511 Oct 2009 DE
102008021970 Nov 2009 DE
102008003117 Dec 2009 DE
102009038750 Mar 2011 DE
102010022290 Dec 2011 DE
102010023922 Dec 2011 DE
0007230 Jan 1980 EP
0130559 Jan 1985 EP
0270291 Jun 1988 EP
0562402 Sep 1993 EP
0843763 May 1998 EP
0864712 Sep 1998 EP
0903451 Mar 1999 EP
0974713 Jan 2000 EP
1026341 Aug 2000 EP
1138467 Oct 2001 EP
1154090 Nov 2001 EP
1229182 Aug 2002 EP
1247641 Oct 2002 EP
1262607 Dec 2002 EP
1262609 Dec 2002 EP
1420125 May 2004 EP
1454763 Sep 2004 EP
1469140 Oct 2004 EP
1493879 Jan 2005 EP
1593796 Nov 2005 EP
1624130 Feb 2006 EP
1650375 Apr 2006 EP
1705309 Sep 2006 EP
1707705 Oct 2006 EP
1808546 Jul 2007 EP
1818478 Aug 2007 EP
1872959 Jan 2008 EP
1892352 Feb 2008 EP
1938963 Jul 2008 EP
2063044 May 2009 EP
2130991 Dec 2009 EP
1290290 Jan 2010 EP
2333195 Jun 2011 EP
2390437 Nov 2011 EP
2149112 Mar 1973 FR
2271365 Dec 1975 FR
2609664 Jul 1988 FR
2827529 Jan 2003 FR
900958 Jul 1962 GB
1015701 Jan 1966 GB
1364685 Aug 1974 GB
1467899 Mar 1977 GB
1520964 Aug 1978 GB
2020998 Nov 1979 GB
2145371 Mar 1985 GB
2202184 Sep 1988 GB
2376916 Dec 2002 GB
S60255843 Dec 1985 JP
S62127225 Jun 1987 JP
H03110258 May 1991 JP
H03169967 Jul 1991 JP
H05018028 Jan 1993 JP
H05214803 Aug 1993 JP
H0664108 Mar 1994 JP
H07180333 Jul 1995 JP
2000170361 Jun 2000 JP
2001096706 Apr 2001 JP
960005785 Jul 1996 KR
19990036219 May 1999 KR
19990036219 May 1999 KR
20030050167 Jun 2003 KR
20040000297 Jan 2004 KR
20060004828 Jan 2006 KR
20060045871 May 2006 KR
20080069896 Jul 2008 KR
8000083 Aug 1981 NL
9511333 Apr 1995 WO
9627721 Sep 1996 WO
9718949 May 1997 WO
9747824 Dec 1997 WO
9747834 Dec 1997 WO
9917930 Apr 1999 WO
9945060 Sep 1999 WO
0020705 Apr 2000 WO
0020706 Apr 2000 WO
0047841 Aug 2000 WO
0109461 Feb 2001 WO
0147724 Jul 2001 WO
0147725 Jul 2001 WO
0148333 Jul 2001 WO
0151732 Jul 2001 WO
0166877 Sep 2001 WO
0175247 Oct 2001 WO
0183488 Nov 2001 WO
0196689 Dec 2001 WO
0198604 Dec 2001 WO
0200449 Jan 2002 WO
0204206 Jan 2002 WO
02060702 Aug 2002 WO
03012224 Feb 2003 WO
03016654 Feb 2003 WO
03084746 Oct 2003 WO
03087497 Oct 2003 WO
03089736 Oct 2003 WO
2004003314 Jan 2004 WO
2004015221 Feb 2004 WO
2004042168 May 2004 WO
2004048716 Jun 2004 WO
2004050359 Jun 2004 WO
2004081316 Sep 2004 WO
2005003489 Jan 2005 WO
2005018833 Mar 2005 WO
2005033204 Apr 2005 WO
2005054599 Jun 2005 WO
2006032378 Mar 2006 WO
2006033706 Mar 2006 WO
2006043893 Apr 2006 WO
2006066776 Jun 2006 WO
2006090287 Aug 2006 WO
2006103565 Oct 2006 WO
2006104436 Oct 2006 WO
2007015669 Feb 2007 WO
2007047834 Apr 2007 WO
2007059967 May 2007 WO
2007078181 Jul 2007 WO
2007079845 Jul 2007 WO
2007081267 Jul 2007 WO
2007113676 Oct 2007 WO
2007141605 Dec 2007 WO
2008004960 Jan 2008 WO
2008017281 Feb 2008 WO
2008060232 May 2008 WO
2008068245 Jun 2008 WO
2008078181 Jul 2008 WO
2008083662 Jul 2008 WO
2008091045 Jul 2008 WO
2008116623 Oct 2008 WO
2008119339 Oct 2008 WO
2009021487 Feb 2009 WO
2009033623 Mar 2009 WO
2009061279 May 2009 WO
2009065769 May 2009 WO
2009066153 May 2009 WO
2009116926 Sep 2009 WO
2009118709 Oct 2009 WO
2009139687 Nov 2009 WO
2010023042 Mar 2010 WO
2010028621 Mar 2010 WO
2010042182 Apr 2010 WO
2010075839 Jul 2010 WO
2010082171 Jul 2010 WO
2010087752 Aug 2010 WO
2010088769 Aug 2010 WO
2010102735 Sep 2010 WO
2010108980 Sep 2010 WO
2010142671 Dec 2010 WO
2011001326 Jan 2011 WO
2011012104 Feb 2011 WO
2011012105 Feb 2011 WO
2011028171 Mar 2011 WO
2011061659 May 2011 WO
2011085306 Jul 2011 WO
2011085788 Jul 2011 WO
2011085825 Jul 2011 WO
2011087425 Jul 2011 WO
2011096879 Aug 2011 WO
2011127981 Oct 2011 WO
2011141043 Nov 2011 WO
2012001091 Jan 2012 WO
2012001109 Jan 2012 WO
2012004700 Jan 2012 WO
Non-Patent Literature Citations (72)
Entry
Search Report and Written Opinion from corresponding EP Application No. EP09015885, dated May 25, 2010.
Search Report from corresponding BE Application No. BE201000420, dated Feb. 15, 2011.
Search Report from corresponding BE Application No. BE201000705, dated May 23, 2011.
Search Report from corresponding BE Application No. BE201000713, dated Jun. 14, 2011.
Search Report from corresponding PCT Application No. PCT/IB2010/055693, dated Jun. 24, 2011.
Search Report from corresponding BE Application No. BE201000719, dated Sep. 27, 2011.
Search Report from corresponding BE Application No. BE201100247, dated Sep. 28, 2011.
Search Report from corresponding PCT Application No. PCT/IB2011/051884, dated Nov. 22, 2011.
Search Report from corresponding PCT Application No. PCT/IB2011/051886, dated Feb. 21, 2012.
Search Report from corresponding BE Application No. BE201100128, dated Jun. 19, 2012.
International Preliminary Report on Patentability from corresponding PCT Application No. PCT/IB2010/055693, dated Jun. 26, 2012.
Search Report from corresponding PCT Application No. PCT/IB2011/052715, dated Aug. 21, 2012.
Search Report from corresponding CN Application No. 201080063498, dated Jan. 6, 2014.
Search Report from corresponding CN Application No. 2015101886353, dated Aug. 1, 2016.
Search Report from corresponding CN Application No. 2015101885153, dated Aug. 19, 2016.
Search Report from corresponding CN Application No. 20151018855562, dated Aug. 19, 2016.
Search Report from corresponding CN Application No. 2015101878249, dated Aug. 22, 2016.
Search Report from corresponding CN Application No. 2015101885346, dated Sep. 1, 2016.
Search Report from corresponding CN Application No. 2015101876968, dated Oct. 17, 2016.
Search Report from corresponding CN Application No. 2015101882070, dated Oct. 18, 2016.
Supplementary Search Report from corresponding CN Application No. 2015101885562, dated Mar. 29, 2017.
Supplementary Search Report from corresponding CN Application No. 2015101882070, dated May 26, 2017.
Supplementary Search Report from corresponding CN Application No. 2015101885153, dated May 31, 2017.
Supplementary Search Report from corresponding CN Application No. 2015101882070, dated Aug. 2, 2017.
Supplementary Search Report from corresponding CN Application No. 2015101876968, dated Jan. 2, 2018.
Supplementary Search Report from corresponding CN Application No. 2015101878249, dated Feb. 7, 2018.
Supplementary Search Report from corresponding CN Application No. 2015101876968, dated Apr. 15, 2018.
Search Report and Written Opinion from corresponding EP Application No. EP19175669, dated Sep. 26, 2019.
Chang et al., Product Review: “Advances in Polyurethane Coatings (1969 to Early 1972)”, Industrial & Engineering Chemistry Product Research & Development, vol. 12, No. 4, pp. 278-288, Sep. 7, 1973.
An et al., “Building and Ornament Materials,” China Architecture & Buildingpress, Feb. 2005, pp. 111-114.
Zhong, “Building Plastic,” China Petrochemical Press, Jan. 2007, 6 Pages.
WPI Database week 199338 Thomson Scientific, Lodon, GB; an 1993-300138 XP002621436, 1 page, Feb. 16, 2011 08:59:55.
Search Report from corresponding EP Application No. EP09015855, dated May 25, 2010.
Search Report from corresponding BE Application No. BE201000749, dated Mar. 25, 2011.
Search Report from corresponding BE Application No. BE20110719, dated Sep. 27, 2011.
Search Report from corresponding BE Application No. BE20110247, dated Sep. 28, 2011.
Search Report from corresponding PCT Application No. PCT/IB2011/054223, dated May 23, 2012.
Search Report from corresponding BE Application No. 201100418, dated Jun. 11, 2012.
Search Report from corresponding PCT Application No. PCT/IB2011/052714, dated Jun. 11, 2012.
Search Report from corresponding PCT Application No. PCT/IB2011/052713, dated Jun. 22, 2012.
Search Report from corresponding PCT Application No. PCT/IB2011/051523, dated Sep. 24, 2012.
Search Report from corresponding BE Application No. BE201000602, dated Nov. 9, 2012.
International Preliminary Report on Patentability from PCT Application No. PCT/IB2011/051885, dated Nov. 13, 2012.
International Preliminary Report on Patentability from PCT Application No. PCT/IB2011/051884, dated Nov. 13, 2012.
International Preliminary Report on Patentability from PCT Application No. PCT/IB2011/051886, dated Nov. 13, 2012.
International Preliminary Report on Patentability from PCT Application No. PCT/IB2011/051523, dated Jan. 15, 2013.
International Preliminary Report on Patentability from PCT Application No. PCT/IB2011/052713, dated Jan. 15, 2013.
International Preliminary Report on Patentability from PCT Application No. PCT/IB2011/052714, dated Jan. 15, 2013.
International Preliminary Report on Patentability from PCT Application No. PCT/IB2011/052715, dated Jan. 15, 2013.
International Preliminary Report on Patentability from PCT Application No. PCT/IB2011/054223, dated Apr. 16, 2013.
Search Report from corresponding CN Application No. 2011800231833, dated Feb. 19, 2014.
Search Report from corresponding CN Application No. 2011800237219, dated Mar. 10, 2014.
Search Report from corresponding CN Application No. 2011800341072, dated Jul. 23, 2014.
Supplementary Search Report from corresponding CN Application No. 2011800231833, dated Aug. 6, 2014.
Supplementary Search Report from corresponding CN Application No. 2011800237219, dated Oct. 15, 2014.
Supplementary Search Report from corresponding CN Application No. 2011800237219, dated Jan. 9, 2015.
Supplementary Search Report from corresponding CN Application No. 2011800237219, dated May 28, 2015.
Search Report and Written Opinion from corresponding EP Application No. 16184900, dated Nov. 1, 2016.
Search Report from corresponding CN Application No. 201505878943, dated Jan. 16, 2017.
Search Report from corresponding CN Application No. 2015106053134, dated Mar. 24, 2017.
Search Report from corresponding CN Application No. 201510618221, dated Mar. 22, 2017.
Search Report and Written Opinion from corresponding EP Application No. EP17192481, dated Jan. 23, 2018.
Search Report from corresponding EP Application No. EP18152924, dated Apr. 20, 2018.
Search Report from corresponding PCT Application No. PCT/IB2011/051885, dated Feb. 9, 2020.
Search Report from corresponding Belgian Application No. BE201000441, dated Feb. 25, 2011.
Search Report and Written Opinion from corresponding EP Application No. EP16186084, dated Nov. 23, 2016.
Search Report from corresponding CN Application No. 201510587784, dated Jan. 17, 2017.
Search Report and Written Opinion from corresponding EP Application No. EP17192468, dated Feb. 5, 2018.
Search Report and Written Opinion from corresponding EP Application No. EP17192992, dated Feb. 26, 2018.
Search Report and Written Opinion from corresponding EP Application No. EP17193145, dated Feb. 26, 2018.
Search Report and Written Opinion from corresponding EP Application No. EP17192967, dated Mar. 2, 2018.
Search Report and Written Opinion from corresponding EP Application No. EP18195393, dated Jan. 23, 2019.
Related Publications (1)
Number Date Country
20200190818 A1 Jun 2020 US
Divisions (1)
Number Date Country
Parent 13696769 US
Child 14015307 US
Continuations (3)
Number Date Country
Parent 15695163 Sep 2017 US
Child 16796202 US
Parent 15045389 Feb 2016 US
Child 15695163 US
Parent 14015307 Aug 2013 US
Child 15045389 US