The invention relates to a flowmeter for measuring the flow of a medium.
An effective instrument for measuring flows is the Coriolis flowmeter.
Another category is formed by flowmeters of the thermal type. The invention has for its object to provide a flowmeter and a technology for its manufacture which render possible the measurement of very small flow rates, below 1 g/h, in combination with a universal manufacturing technology that renders it possible to manufacture different types of measuring devices and to integrate them with the additional sensor equipment referred to above.
The flowmeter according to the invention is for this purpose characterized in that it has a system chip which comprises a flow sensor, the system chip including a silicon substrate in an opening whereof a silicon nitride flow tube is provided for transporting a medium whose flow rate is to be measured, said flow tube having an inlet end and an outlet end, which ends each merge via a wall of the opening into a silicon nitride coated channel in the silicon substrate.
The invention also relates to a method of manufacturing a system chip for a flowmeter as described above. This method is characterized by the following steps:
providing a monocrystalline silicon substrate in which a SiN tube is realized by means of SiN deposition steps and partially etching away and partially exposing through etching so as to realize a tube structure that is fixed at at least one side and is otherwise free, by means of micro system technology (MST).
The invention will be explained in more detail below, by way of example, with reference to the drawing, in which:
a is a diagrammatic elevation of an embodiment of a flowmeter according to the invention with a system chip and a Coriolis flow sensor;
b is a front elevation of the flowmeter of
c is a cross-sectional view of the flowmeter of
a presents a clarification of the operation of a Coriolis flow sensor in an arrangement with a U-shaped Coriolis tube (with a diagrammatically indicated actuation and sensing of the vibrating Coriolis tube);
b shows a Lorentz actuation (torsion) and capacitive sensing (flapping) of the tube;
c shows a thermal actuation (torsion) and capacitive sensing (flapping) of the tube;
d shows a thermal actuation (flapping, no magnets) and capacitive sensing (torsion);
a shows a detail of the system chip of
b is a cross-sectional view of the system chip with fluidic coupling of connection tubes;
a-j are cross-sections through a system chip during manufacture;
a shows details of the manufacture of a round bend in a tube shape;
b shows parallel connections to one tube;
a and b show details of the capacitive detection means of a system chip;
a is an elevation of a system chip with Coriolis tube with thermal excitation means;
b diagrammatically shows a system chip with Coriolis tube with alternative capacitive sensing means;
a shows a first embodiment of a system chip with a flow sensor of the thermal type;
b shows a second embodiment of a system chip with a flow sensor of the thermal type; and
Corresponding components have been given the same reference numerals as much as possible in the Figures.
a shows a system chip 17 comprising a monocrystalline silicon substrate 1 in which an opening 4 has been etched. The system chip 17 in this example has a Coriolis flow sensor with a Coriolis tube 3 of silicon nitride which is freely suspended in the opening 4. In another example the flow sensor may be a thermal flow sensor. In either case an absolute pressure sensor 2, such as a Pirani pressure sensor, may be integrated in or on the substrate 1. The Coriolis tube has a loop shape, in this case a rectangular loop shape. Other loop shapes, such as triangular, trapezoidal, or U-shaped, are also possible.
The system chip 17 is (monolithically) assembled with two mutually opposed permanent magnets 9, 9′ which are arranged on a carrier 5, for example a PCB (printed circuit board) of ceramic or synthetic resin material with conductive, e.g. copper or silver, tracks thereon. The substrate is manufactured from a <1,0,0> Si wafer mounted on the carrier 5. The electrical connections between the system chip 17 and the carrier 5 are provided by so-termed bonding wires arranged in groups 6, 7, and 8. The bonding wires 6 (from and to the sensor chip) serve for conditioning the chip temperature/c.q. temperature control. A local temperature sensor and an (ambient) pressure sensor 2 may be present, if so desired.
The pressure sensor 2, if present, measures the absolute pressure. This is important because the quality factor of the tube's vibration depends inter alia on the air pressure.
The bonding wires 7 serve for bringing the freely suspended tube 3 into vibration. The bonding wires 8 serve for controlling the read-out elements for the freely suspended tube.
The freely suspended tube 3 together with the rod magnets 9, 9′, a current conductor (wire) 10 on the tube 3, and capacitive sensor elements 11 on the tube and 12 on the system chip 17 forms a so-termed Coriolis flowmeter, which is further clarified in
The hydraulic coupling of the system chip 17 to the external world is provided by pressure blocks 13 and 14. (see
b shows the same device as
c shows the same device as
(In a prototype sensor, Kelvin contacts are used for a temperature measurement of the tube and probe pins for the connections.)
A housing may be provided around the assembly for protection; this is not shown. The housing can be in the form of a cap which defines a hermetically sealed evacuated enclosure containing the free-hanging tube.
A pressure measurement of the medium flowing through the tube may also optionally be integrated. A thermal flow measurement of the medium may also be integrated, if so desired.
Furthermore, an absolute pressure measurement by means of a relative pressure measurement (membrane somewhere in the tube) with respect to the measured absolute ambient pressure is also possible. A complete multi-parameter measuring system is thus obtained.
a shows a U-shaped Coriolis tube 3 that was made by MST technology, that is freely suspended, and that is partly embedded in the silicon substrate where it merges into inlet and outlet channels present in the substrate and issuing at the side of the substrate 1 opposite to the freely suspended portion 3. The applied magnetic field 31 is indicated by arrows B, and the current passed through the conductor 10 on the tube 3 for generating the Lorentz forces is referenced 32.
During operation, a medium enters at 21 and exits at 21′. The mass flow of a medium is the mass that passes through a cross-section of the tube per second. If the mass is a self-contained quantity, the mass flow through the U-tube of
Therefore, the mass flow Q has the same (constant) modulus (or vector ‘length’) everywhere in the tube 3. However, Q points in the positive x-direction in tube portion 22 and in the negative x-direction in tube portion 26.
There are various methods for realizing and applying a Coriolis mass flowmeter with the tube 3 of
the tube is vibrated by means of a Lorentz actuator in a flapping mode or in a torque mode (cf.
heat is generated in the conductor pattern 10 through thermal excitation, which leads to a flapping mode (cf.
Generally spoken, a Lorentz actuator can comprise a magnet means which at a portion of the tube produces a magnetic field. This field can be a static field or a dynamic field. If an electric current is conveyed through the conductor 10, (AC current in the case of a static magnetic field, DC current in the case of a dynamic magnetic field) a Lorentz force is exerted on the tube and the tube vibrates in a flapping mode. By producing two magnetic fields a torque can be exerted on the tube (so-called torque excitation) and the tube vibrates in a torque mode. The magnetic field producing means can be in the form of one or more magnets, or in the form of one or more electric coils, or a magnetic (magnetically conducting) yoke equipped with a permanent magnet or an electric coil.
The tube is actuated (vibrated) about an axis of rotation 29 (= the x-axis), which in the case of a mass flow leads to a Coriolis force in that location where the distance to the axis of rotation changes, which is at tube portion 24. This Coriolis force on tube portion 24 causes the U-tube 3 to rotate about an axis of rotation 30 (= the y-axis), leading to a translatory movement of the tube portion 24. This (vibratory) actuation movement is referenced 34 in
The tube is flapped, or actuated (vibrated) about the axis of rotation 30 (= y-axis); this in the case of a mass flow again leads to a Coriolis force in that location where the distance to the axis of rotation changes, which is at tube portion 22 (upward) and tube portion 26 (downward) this time, causing a rotation of the tube portion 24. The (vibratory) actuation movement of the tube portion 24 in the z-direction is referenced 36 in
Reference numeral 11 (11′, 11″) in the previous Figures indicates means (projections or tags of SiN) at or on the connecting part between the legs of the U-shaped tube 3. These form capacitances together with their counterpart means (projections or tags) 12 (12′, 12″) at the substrate side. This renders it possible to detect the movements of the tube in a capacitive manner. One, two, or three such pairs of tags, for example, may be used. Alternatives will be described below with reference to
d diagrammatically shows a system chip with the same U-tube 3 as in
a shows a detail of the system chip of
b is a cross-sectional view taken in the plane IV-j in
The system chip described above is to be regarded as a fluidic PCB (printed circuit board), for which a tube structure having the desired functions is realized in one process in the cleanroom in one substrate. The tube structure according to the invention may be manufactured by means of the so-termed micro system technology (MST).
An example of this is the following method:
a thin, for example 500 nm thick, first silicon nitride layer (SixNy) which is rich in silicon is provided on both sides of a <100> oriented p-type silicon substrate (wafer). Then a 50 nm thick chromium layer is sputtered onto the upper side. This chromium layer is patterned with a photoresist mask having rows of elongate holes (with dimensions of, for example, 6×2 μm), with small interspacings between the holes (for example 2 μm). The pattern in the chromium layer is transferred by means of reactive ion etching (RIE) to the subjacent nitride layer.
The channel shape is defined by isotropic plasma etching through the holes in the silicon nitride layer. After the resist mask has been stripped, the chromium mask is removed and a thicker, second SixNy layer is grown to a thickness of approximately 1.4 μm. This will form the channel wall (tube wall) and at the same time seals off the etching holes in the first nitride layer.
Subsequently, a 10/100 nm layer of chromium/platinum is provided by sputtering and patterned by means of lift-off lithography so as to form the metal track (the electrode) which is necessary for making actuation of the structure possible (for example Lorentz actuation).
Furthermore, release windows are provided at the lower side of the wafer and fluidic access holes to the tube at the upper side of the wafer by means of RIE etching, and the structure is separated by means of (KOH) wafer through etching.
A preferred embodiment of the method according to the invention will now be elucidated with reference to
a relates to a silicon wafer on which the first SiN layer is grown and is patterned on both sides, which yields a cross-section as shown in
a: 45 denoting the SiN layer-1 at the upper side, 46 denoting the SiN layer-1 at the lower side, 47 denoting patterned openings in the layer 45 for the SiN tubes 3, 21, and 48 denoting patterned openings in the layer 46 for the fluid coupling to the external world.
b: after the substrate (side 46) has been etched, a cavity 49 is anisotropically etched via openings 48. Note: steps 4b and 4c may be interchanged!
c: after the substrate (side 45) has been etched, cavities 50 are isotropically etched via openings 47. Note again: 4b and 4c may be interchanged!
d shows the situation after the thicker, second SiN layer has been grown: 51 denoting the SiN layer-2. Everything is covered with the same thickness, also in the various holes. This is also called ‘conform deposition’. The deposition of the SiN layer creates a cavity 52.
e: deposition of a metal layer and patterning of this layer 10. This will form the current conductor 10 (cf.
f: patterning of the (by now dual, 45+51) SiN layer at the upper side. If this is omitted, the entire tube 3 will be suspended from a SiN membrane 45+51 at the upper side after the final etching step (4j)! Reference numeral 54 denotes openings in the upper double SiN layer.
g: providing and patterning of a photoresist layer at the areas of the components of the sensing capacitors, 55 denoting the resist layer that is to serve as a spacer layer.
h: providing and patterning of a second, thicker metal layer. The pattern will form the future crossing electrodes at the area of the sensing capacitor, with 56 denoting the patterned electrode, and 42 denoting a layer at the area of the fluid openings for protecting the embedded channels 21.
i: patterning of the lower double SiN layer at side 46, with 57 denoting an opening in the 46+51 SiN layer for etching the opening 4.
j is a cross-sectional view taken on the plane IV-j in
Summarizing, the steps are as follows:
A) Provision of a first SiN layer on both sides of the silicon wafer. The upper side is patterned with the tube structure, the lower side with the holes to be etched.
B) Etching of a hole into the lower side of the wafer to a depth greater than the wafer thickness minus the desired tube thickness.
C) Isotropic etching through the free holes at the upper side: the tube is defined. The longer the etching, the thicker the tube will be.
D) Deposition of the second, thicker SiN layer in an LPCVD tubular oven. All wetted materials thus become SiN.
E) Deposition and patterning of the first metal layer (conductor pattern).
F) Exposing the upper side of the Coriolis tube (at two or three sides).
G) Applying a photoresist layer that is to serve as a spacer for the capacitive read-out.
H) Providing and patterning the second, thicker metal layer. This layer also serves as an intermediate layer for the pressure blocks 13 (cf.
I) Providing the etching mask for exposing the Coriolis tube through etching.
J) Separating the chip from the wafer by sawing or breaking off. This is facilitated in that the holes are covered by sawing foil at the lower side.
a is a plan view showing details of the round bends in the possible tube shapes of a system chip with a Coriolis flow sensor or thermal flow sensor. The method according to the invention utilizes a mask for making round bends during the manufacture of the flow tube, the elongate mask openings having a small pitch and extending substantially tangentially.
Visible are: detail of tube 21 and tube 3 with rounded corner 23 (cf.
b shows an embodiment in which a number of parallel tubes are joined together into one tube. This is a method of obtaining a lower hydraulic resistance. The tubes may be embedded in the substrate, for example, or the same tube structure may be made free in its entirety without a transition 20, i.e. all being of tube type 3 (freely suspended). This may be achieved in that the mask defining the openings of type 54 (
a and b show two embodiments of the means for capacitive detection of the tube vibrations integrated in a single crystal in more detail. Detail of tube 3, front side 24, with electrodes for capacitive read out, showing: substrate 1; front 2 of free tube; current conductor 10 for Lorentz or thermal excitation; tag 11 at tube 3; tag 12 at opposite side of substrate 1; tube electrode 53 of sensing capacitors; electrodes 60 made in second metal layer; bond pad 61; finger electrode 62 at the substrate side; finger electrode 63 at the tube side.
The tags are at two levels in the embodiment of
a shows part of a system chip with a U-shaped Coriolis tube and means for thermal excitation of the tube vibrations, representing a general view of thermal excitation. Two independent heater resistors 65, 65′ arranged on the legs 22 and 26 of the U-shaped Coriolis tube 3 do and do not heat the legs in alternation. This causes the tube 3 to perform a torsional movement about the axis 29 (so this is unlike the situation of
When electric power is dissipated in the heater resistor 65′, the same happens there. Accordingly, the tube will perform a twisting movement about the axis 29 owing to the alternating dissipation of power in the legs.
b shows part of a system chip with a U-shaped Coriolis tube 3 suspended at one side of the opening 4 and provided with electrodes 68, 69 for the capacitive read out. An additional U-tube 66 suspended at the opposite side of the opening 4 is located straight opposite the U-tube 3 so as to position the finger-shaped electrodes on the tags 68 and 69 exactly at the same z-level. The excitation in the case of
Visible are: laser 80; light beam 81 from laser; mirror 82 oriented at an angle of 45° so as to direct the beam to the tube 3; position sensitive detector 83; beam 84 incident on the PSD after three reflections.
a shows part of a flowmeter with a system chip and a thermal flow sensor manufactured by means of the technology discussed above. The substrate 1 has an opening 4 in which a loop-shaped tube 3 having a U-shape is freely suspended. The tube 3 is connected to embedded channels in the substrate 1. A heater resistor 91 is arranged in the center of the connecting limb of the free tube 3. A thermopile 90 is arranged between the two legs of the free tube 3 for measuring a temperature difference between the legs, which temperature difference is a measure for the flow. The U-shaped tube may optionally be fixed by the connecting limb of the U to the wall of the opening 4 opposite thereto.
All this is arranged such that the flowmeter operates in accordance with the thermal flow sensor principle disclosed in EP 774 649.
b shows an alternative to the embodiment of
A thermal flow sensor based on the so-termed TBA (Temperature-Balance-Anemometry) principle is also suitable for being manufactured by the above technology.
The Lorentz excitation may be achieved in an alternative manner by means of a magnet yoke instead of the two permanent magnets.
a and 10b show a system chip 106 with a Coriolis tube 101 and a magnet yoke 100 for Lorentz excitation of the Coriolis tube.
The magnet yoke 100 for Lorentz excitation, in which a permanent magnet is accommodated, is to provide a loop of a soft magnetic material, such as soft iron, that is as fully closed as possible, with air gaps only in those locations where the Coriolis flow tube 101 crosses the path of the loop. A minimum resistance for the magnetic field lines crossing between the poles 102, 102′ is realized thereby. The preferred embodiment of the magnet yoke 100 is that which comprises not only the C- or U-shaped portion at the outer side of the tube 101, but also a smaller, beam-type part 103 within the loop of the tube 101. Said part shortens the path to be crossed by the field lines and thus reduces the magnetic resistance, so that a smaller magnet and/or a weaker current through a conducting layer on the tube 101 can suffice for realizing a given Lorentz force. In addition, the beam-type part 103 acts as a flux guide: it draws the fields lines towards itself so that there is no interfering magnetic field acting on locations of the tube outside the air gaps 105, 105′. The C- or U-shaped portion is built up from two symmetrical halves between which the permanent magnet 104 is placed. (It is noted that the C-shaped portion is in fact a U-shaped portion provided with pole shoes.)
The system chip 106 with the Coriolis tube 101 is manufactured from a thin silicon wafer in a number of etching and deposition steps in the ‘microchannel’ process. This results in a tube that is freely suspended from its inlet and outlet tubes 107, 108 in a silicon frame 109. This frame 109 is open at two sides. A closed, comparatively flat box is created in that a bottom and lid are glued to the frame 109 in a next manufacturing step. This box may be evacuated because a tube vibrating in a vacuum can be kept moving with less energy supplied. In the case of an optical measurement of the displacement of the tube 101, with a light source and detector located outside the box, the lid and/or bottom of the box may be manufactured from a transparent material, such as glass.
Before the box is closed, the magnet yoke 100 is placed: the ends of the C-shaped portion of the yoke 100 are glued into recesses of the frame 109 that were etched away during manufacture. The beam-type part 103 of the yoke, which lies within the loop of the tube 101, is glued to the bottom of the box before or after this bottom is glued to the frame 109.
a shows the stage in the manufacture in which the complete magnet yoke 100 has been put in place, but the lid has not yet been glued over the box. The inlet and outlet tubes 107, 108 are shown as issuing into the plane of the frame adjoining the Coriolis tube 101, but they may alternatively lie in the plane of the frame remote from the Coriolis tube 101. The Figure shows the preferred embodiment with a flux-guiding soft magnetic body 103 within the loop of the tube 103.
b shows an embodiment of a system chip 111 with a Coriolis tube 112 wherein a magnet yoke 110 for Lorentz force excitation lies in a plane parallel to the plane of the Coriolis tube 112. In both cases it is necessary for the generation of the Lorentz forces that the Coriolis tube 101, 112 is provided with a conductor pattern or conducting layer (not shown) that is connected to a current source (not shown) so as to pass an alternating current through the tube.
It is noted that in
It is noted that the embodiments of Lorentz actuation and thermal actuation, with optical or capacitive sensing as described above may also be used in other embodiments of flowmeters with flow tubes manufactured by means of MST, for example the Coriolis flowmeter described in U.S. Pat. No. 6,477,901.
Summarizing, the invention relates to a fluid and flow measuring system comprising a monocrystalline silicon chip in which a SiN tube has been (partly) etched out and a (freely suspended/standing) SiN tube has been (partly) exposed by etching, with (fluid) bottom connections and to a method of manufacturing thereof.
Number | Date | Country | Kind |
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1034905 | Jan 2008 | NL | national |