Patent Application
20130015362
The present invention relates to an apparatus for the treatment of a fluid, such as for example air or water, and the detection of fluid contamination. In particular, the present invention relates to the use of a dual wavelength emitting laser in an apparatus for the treatment of air or water and the detection of airborne or waterborne contamination. The invention may be applied to a product which purifies air and confirms whether or not the air is safe to breathe. The invention also may be applied to a product which purifies drinking water and confirms whether or not the water is safe to drink.
There is an ever increasing need for clean and safe air to breathe and water to drink, particularly in heavily populated countries or regions throughout the world. A major, high-volume, application for compact solid-state deep ultraviolet (UV-C) light sources is for chemical-free sterilisation of air or water. UV-C light causes permanent physical damage to DNA which prevents bacteria, viruses and fungi from replicating. This means that UV-C treatment can be used to disinfect air or water at points-of-use for safe breathing or drinking. UV-C light is particularly effective at destroying the e-coli bacteria.
Compact solid-state UV-C light sources also have application in bio- and chemical-sensing because biological and chemical compounds strongly absorb UV-C light. Proteins and other organic chemicals can be identified from their fluorescence spectra. A fluorescence measurement requires illumination with light at a short wavelength at which the compounds are strongly absorbing, and detection of the resulting fluorescence at longer wavelengths. Wavelengths near about 280 nm are suitable, but shorter wavelengths of about 220 nm are preferred owing to the stronger absorbance at this wavelength.
Point-of-use products for the UV-C treatment of air and water are already available, and these products use mercury lamps as the UV light source. However, mercury lamps contain toxic material, tend to have short operating lifetimes and long warm-up times. An alternative UV light source currently under development is the UV semiconductor light emitting diode (LED). The current drawbacks to using UV LEDs are again lifetime issues, their poor performance below a wavelength of 260 nm and their inability to provide a collimated beam or tightly focused light spot. UV-C lasers, on the other hand, potentially provide a monochromatic, coherent, collimated and easily focusable beam which can be rapidly modulated for fluorescence measurements. UV-C lasers also emit at wavelengths down to 205 nm.
A UV-C laser can be realised by frequency doubling a blue-violet wavelength laser diode. Nishimura, JJAP 42, 5079 (2003) reported on making a UV-C laser in this way. An advantage of using a UV-C laser made by frequency doubling is that the device can be made to emit both the UV-C laser light (205-230 nm) and the blue-violet laser light (410-460 nm). The two wavelengths of light are particularly useful in a sensor system for distinguishing between micro-organisms of different species and size.
Several systems for the detection and treatment of micro-organisms in air using UV lasers are disclosed in the following:
Yoshinaga et al., U.S. Pat. No. 5,123,731, issued on Jun. 13, 1992, discloses a particle measuring device which uses two laser wavelengths through frequency doubling a first laser beam. The use of laser wavelengths down to 200 nm are specified; however, no mention of air treatment is made in this patent, and the system does not provide treatment of the particles.
Silcott et al., U.S. Pat. No. 7,106,442, issued on Sep. 12, 2006, discloses another particle measuring device which uses multiple laser beams of different wavelengths, including frequency doubled laser beams. Treatment of the particles is not mentioned in this patent.
Wilson et al., U.S. Pat. No. 7,242,009, issued on Jul. 10, 2007, discloses a method of using multiple wavelength laser induced fluorescence to distinguish between threat and background airborne particles. Again, no method of treating the threat particles is disclosed.
Berry et al., WO2004110504A2, published on Dec. 23, 2004, is an air sterilising system which uses a UV laser. The use of multiple laser wavelengths is specified, but only in a discrete narrow range. The system does not provide sensing.
Zamir, WO2005011753A1, published on Feb. 10, 2005, discloses another system for sterilising liquids and gases using a UV laser. Only UV light is used, and there is no sensing of micro-organisms.
Several systems for the treatment and detection of micro-organisms in water using UV lasers are disclosed in the following:
Baca et al., U.S. Pat. No. 6,919,019B2, issued on Jul. 19, 2005, discloses a laser water detection and treatment system for the military. However, this system has micro-organism sensing which is separate from the water treatment zone, and a laser is not used for the sensing of micro-organisms. Both of these issues will increase the size and cost of such a system.
Goudy, Jr., U.S. Pat. No. 4,816,145, issued on Mar. 28, 1989, discloses a system for the laser disinfection of fluids. The device disinfects water using a UV (gas) laser and sensors to adjust the laser power to compensate for scattering. Only one laser wavelength is used (UV), and the detectors do not distinguish between scattering, absorption and fluorescence. Again, the size and cost of such a system are likely to be problematic. Also, the sensitivity and range of the detector will be limited in this device.
Baca, U.S. Pat. No. 6,740,244B2, issued on May 25, 2004, discloses another laser water treatment system that disinfects water near point-of-use using a UV laser. Only a UV laser is used, and there is no sensing in this device.
Safta, U.S. Pat. No. 6,767,458B2, issued on Jul. 27, 2004, discloses another water purification system using only a UV laser. However, it does not have sensing.
Killinger et al., U.S. Pat. No. 7,812,946, issued on Oct. 12, 2010, discloses a water monitoring apparatus that includes a UV LED source to excite fluorescence from dissolved organic compounds. The use of a UV laser is mentioned but only as a performance comparison to the UV LED.
Aspects of the invention include a system for the disinfection of a flowing fluid, such as for example air or water, using ultraviolet laser light, and the determination of fluid (air or water) purity from detecting and comparing fluorescence, scattering and absorption of visible and ultraviolet laser light in the fluid (air or water) flow.
Exemplary embodiments of the invention include a laser light source simultaneously generating both visible and ultraviolet laser beams. Both laser beams are incident on a narrow stream of flowing fluid, such as for example air or water, containing micro-organism particulates. The micro-organisms mostly absorb the UV laser light, causing them to both fluoresce and be destroyed, and mostly transmit and scatter the visible blue-violet laser light. By detecting and comparing the fluorescence, absorption and scattering of the different laser beams, the air or water purity can be determined.
Advantages of the invention include:
Other exemplary embodiments of the present invention include a system with an apparatus having a conduit for directing a flow path of a fluid, such as air or water, containing biological particles at a constant velocity along a straight path, and a laser light source simultaneously emitting both an ultraviolet and a visible laser beam that is directed to be incident on the flow path of the air or water. The visible laser beam may be generated by a laser diode, and the ultraviolet laser beam may be generated by frequency doubling the visible laser beam using a non-linear optical crystal. The ultraviolet laser beam excites the biological particles to fluoresce and damage their DNA structure at the same time. The system may further include a sensor for measuring the scattered laser light from the biological particles in the directed flow path, a sensor for measuring the fluorescence from the biological particles in the flow path, and a sensor for measuring the transmission of laser light through the flow path to determine absorption of the laser light by the water or air. The system further may include a controller configured to determine whether contaminants are present in the fluid based upon the detections of the sensors.
Accordingly, an aspect of the invention is a system for purifying a fluid or determining fluid purity. An embodiment of the system includes a light source for generating a first laser light beam incident upon a flow path of the fluid, and a frequency doubler for doubling the frequency of at least a portion of the first laser light beam to generate a second laser light beam incident upon the flow path of the fluid, wherein the second laser light beam has a wavelength suitable for absorption by contaminants in the fluid. A plurality of light detectors detect at least one of the first laser light beam or the second laser light beam after the light beams exit the flow path. A controller is configured to determine whether contaminants are present in the fluid based upon the detections of the plurality of light detectors.
In another exemplary embodiment of the system, the first laser light beam is a visible laser light beam and the second laser light beam is an ultraviolet laser light beam.
In another exemplary embodiment of the system, the wavelength of the ultraviolet laser light beam is exactly half that of the visible laser light beam.
In another exemplary embodiment of the system, the ultraviolet laser beam has a wavelength of less than 270 nm.
In another exemplary embodiment of the system, the ultraviolet laser beam has a wavelength of less than 230 nm.
In another exemplary embodiment of the system, the ultraviolet laser beam has a wavelength of less than 210 nm.
In another exemplary embodiment of the system, the visible laser beam has a wavelength of less than 540 nm.
In another exemplary embodiment of the system, the visible laser beam has a wavelength of less than 460 nm.
In another exemplary embodiment of the system, the visible laser beam has a wavelength of less than 420 nm.
In another exemplary embodiment of the system, at least one of the light detectors is a scattering light detector that measures light scattered from the flow path.
In another exemplary embodiment of the system, at least one of the light detectors is a transmitted light detector that measures light transmitted through the flow path.
In another exemplary embodiment of the system, at least one of the light detectors is a fluorescence light detector that measures fluorescence from the flow path.
In another exemplary embodiment of the system, the first laser beam is a pulsating laser beam.
In another exemplary embodiment of the system, the system further includes a conduit defining the flow path of the fluid.
In another exemplary embodiment of the system, the conduit includes a plurality of optical window regions that are transparent to wavelengths of light corresponding to wavelengths of light of the first and second laser light beams.
In another exemplary embodiment of the system, the first and second laser light beams intersect the flow path at different points.
In another exemplary embodiment of the system, the fluid is contained in a vessel as a static volume flow path.
In another exemplary embodiment of the system, the light source includes a semiconductor laser diode for generating the first laser light beam.
In another exemplary embodiment of the system, the frequency doubler is a non-linear optical crystal.
In another exemplary embodiment of the system, the frequency doubler is a beta-Barium Borate non-linear optical crystal.
Another aspect of the invention is a method for purifying a fluid or determining fluid purity. An exemplary embodiment of the method may include the steps of generating a first laser light beam incident upon a flow path of the fluid; doubling the frequency of at least a portion of the first laser light beam to generate a second laser light beam incident upon the flow path of the fluid wherein the second laser light beam has a wavelength suitable for absorption by contaminants in the fluid; detecting at least one of the first laser light beam or the second laser light beam after the light beams exit the flow path; and determining whether contaminants are present in the fluid based upon the light detections.
In another exemplary embodiment of the method, the first laser light beam is a visible laser light beam and the second laser light beam is an ultraviolet laser light beam having half the wavelength of the first laser light beam.
In another exemplary embodiment of the method, the first and second laser light beams intersect the flow path at different points.
In another exemplary embodiment of the method, detecting at least one of the first laser light beam or the second laser light beam comprises at least one of detecting light that is scattered from the flow path, detecting light that is transmitted through flow path, or detecting light fluorescence from the flow path.
In another exemplary embodiment of the method, the fluid is at least one of air or water.
To the accomplishment of the foregoing and related ends, the invention, then, comprises the features hereinafter fully described and particularly pointed out in the claims. The following description and the annexed drawings set forth in detail certain illustrative embodiments of the invention. These embodiments are indicative, however, of but a few of the various ways in which the principles of the invention may be employed. Other objects, advantages and novel features of the invention will become apparent from the following detailed description of the invention when considered in conjunction with the drawings.
Referring to
The first blue-violet laser light beam may be generated by a blue-violet laser diode 1a and may have a wavelength in the range 410 to 460 nm. Green laser diodes with wavelengths as long as 540 nm are also suitable. The monochromatic blue-violet laser beam is shaped and focused into a frequency doubler, such as a non-linear optical FD crystal 1b that may be made of beta-Barium Borate (BaB2O4 or BBO) with a pre-determined crystal cut, orientation and geometric shape. The BBO FD crystal frequency doubles the input laser beam to produce the second ultraviolet output laser light beam with double the frequency (or half the wavelength). For example, an input laser beam of 460 nm will produce an output laser beam of 230 nm. As depicted in
In an exemplary embodiment, the BBO FD crystal may be placed inside a re-circulating optical cavity which allows multiple passes of the incident blue-violet laser beam through the BBO FD crystal, thereby increasing the total amount of blue-violet light converted into UV light. In addition, one may increase the total amount of blue-violet light converted into UV light by mechanically shaping the BBO FD crystal into a ridge waveguide structure with dimensions of several micrometers in directions orthogonal to the blue-violet laser beam and several millimeters in the same direction as the blue violet laser beam.
Examples of the operation of the present invention are described below. Although the invention is described principally in connection with the purification and detection of contaminants in air or water, it will be appreciated that the invention is not limited in such regard. Rather, the invention may be utilized in connection with any suitable fluid (the term fluid being understood to include both liquids and gases).
An exemplary preferred embodiment of the present invention is now described with reference to
The pair of laser beams provided by the dual wavelength laser component 1 are split and then directed onto the water flow via the optical window region. The UV laser beam typically will be absorbed by any biological particles or micro-organisms in the water causing them to fluoresce. The DNA structure of the biological particles typically will also be physically damaged or destroyed by the UV light. Some of the UV laser beam will also scatter off the particles or pass through the water (depending on its purity). Most of the blue-violet laser beam typically will either pass through the water or scatter off the particles. However, some particle fluorescence may also be induced by the blue-violet laser beam.
A plurality of light detectors 3 are positioned to receive light that exits the flow path from the optical window region 5 of the water conduit. For example, the light detectors 3 may include detectors to measure the light scattering (detector 3a), fluorescing (detector 3b) or light being transmitted (detector 3c) by any biological particles in the water (which in turn may be used to determine absorption). CCD sensors are preferred detectors due to their compact size. Optical filters may also be used to distinguish between signals. Pulsing the laser beams may be employed as the input light signals. The type, size, and number of biological particles in the water stream may be determined by detecting and comparing the corresponding scattering, fluorescence and transmission signals.
The conduit 2a may contain several optical window regions 5 for light to exit the water flow that are not adjacent to the entry window. This provides a means for the UV laser beam to experience multiple reflections inside the conduit before exiting, thereby increasing its germicidal effectiveness in destroying any micro-organisms.
A controller 7 receives and processes outputs from the plurality of light detectors 3. The controller 7 is configured to determine whether contaminants are present in the water based upon the detections of the plurality of light detectors 3. More specifically, the controller 7 may compare the outputs of the light detectors 3 against a library of stored reference signals produced by known contaminants. In this way, contaminant species can be identified and quantified. Optical filters may be employed in conjunction with the light detectors 3 so as to improve signal to noise ratio. The controller 7 may be provided in the form of a control circuit or processing device that may execute program code stored on a machine-readable medium. Such controller functionality could also be carried out via dedicated hardware, firmware, software, or combinations thereof, without departing from the scope of the invention.
Another exemplary preferred embodiment of the disclosed system is illustrated in
The pair of laser beams provided by the dual wavelength laser component 1 are split and then directed onto the air flow via the optical window region. The UV laser beam typically will be absorbed by any biological particles or micro-organisms in the air causing them to fluoresce. The DNA structure of the biological particles typically will also be physically damaged or destroyed by the UV light. Some of the UV laser beam will also scatter off the particles or pass through the air (depending on its purity). Most of the blue-violet laser beam typically will either pass through the air or scatter off the particles. However, some particle fluorescence may also be induced by the blue-violet laser beam.
A plurality of light detectors 3 are positioned to receive light that exits the flow path from the optical window region of the air conduit. For example, the light detectors 3 may include detectors to measure the light scattering (detector 3a), fluorescing (detector 3b) or being transmitted (detector 3c) by any biological particles in the air (which in turn may be used to determine absorption). CCD sensors are preferred detectors due to their compact size. Optical filters may also be used to distinguish between signals. Pulsing laser beams may be employed as the light input signal. The type, size and number of biological particles in the air stream may be determined by detecting and comparing the corresponding scattering, fluorescence and transmission signals.
The conduit 2b may contain several optical window regions 5 for light to exit the air flow that are not adjacent to the entry window. This provides a means for the UV laser beam to experience multiple reflections inside the conduit before exiting, thereby increasing its germicidal effectiveness in destroying any micro-organisms.
As in the previous example, a controller 7 receives and processes outputs from the plurality of light detectors 3. The controller 7 is configured to determine whether contaminants are present in the air based upon the detections of the plurality of light detectors 3.
Another exemplary preferred embodiment of the disclosed system is illustrated in
The pair of laser beams provided by the dual wavelength laser component 1 are split and then directed onto the air or water volume via the optical window region. The UV laser beam typically will be absorbed by any biological particles or micro-organisms in the air/water causing them to fluoresce. The DNA structure of the biological particles typically will also be physically damaged or destroyed by the UV light. Some of the UV laser beam will also scatter off the particles or pass through the air/water (depending on its purity). Most of the blue-violet laser beam typically will either pass through the air/water or scatter off the particles. However, some particle fluorescence may also be induced by the blue-violet laser beam.
A plurality of light detectors 3 are positioned to receive light that exits the vessel from the optical window region 6 of the air/water vessel. For example, the light detectors 3 may include detectors to measure the light scattering (detector 3a), fluorescing (detector 3b) or being transmitted (detector 3c) by any biological particles in the air or water (which in turn may be used to determine absorption). CCD sensors are preferred detectors due to their compact size. Optical filters may also be used to distinguish between signals. Pulsing laser beams may be employed as the input light signal. The type, size and number of biological particles in the air/water volume may be determined by detecting and comparing the corresponding scattering, fluorescence and transmission signals.
The vessel 4 may contain several optical window regions 6 for light to exit the air/water that are not adjacent to the entry window. This provides a means for the UV laser beam to experience multiple reflections inside the vessel before exiting, thereby increasing its germicidal effectiveness in destroying any micro-organisms.
As in the previous examples, a controller 7 receives and processes outputs from the plurality of light detectors 3. The controller 7 is configured to determine whether contaminants are present in the air or water based upon the detections of the plurality of light detectors 3.
Once germicidal treatment of the air/water volume is completed, the vessel 4 may be emptied into another vessel ready for safe use, and the first vessel 4 may then be refilled with a new volume of air/water for treatment and sensing.
Although the invention has been shown and described with respect to a certain embodiment or embodiments, equivalent alterations and modifications may occur to others skilled in the art upon the reading and understanding of this specification and the annexed drawings. In particular regard to the various functions performed by the above described elements (components, assemblies, devices, compositions, etc.), the terms (including a reference to a “means”) used to describe such elements are intended to correspond, unless otherwise indicated, to any element which performs the specified function of the described element (i.e., that is functionally equivalent), even though not structurally equivalent to the disclosed structure which performs the function in the herein exemplary embodiment or embodiments of the invention. In addition, while a particular feature of the invention may have been described above with respect to only one or more of several embodiments, such feature may be combined with one or more other features of the other embodiments, as may be desired and advantageous for any given or particular application.
