Patent Application
20110296996
The invention relates to the technical field of waste gas treatment, and in particular, to a free radical injection ionizer for flue gas treatment with corona discharge.
The technique for simultaneously removing flue gas pollutants by the non-thermal equilibrium plasma is one of the most promising comprehensive flue gas treatment techniques currently, which uses particles with high reactivity produced from gas discharge to react with various organic and inorganic pollutant molecules which are thereby decomposed and oxidized into harmless substances or easily treatable compounds. This technique has the characteristic of effectively, conveniently and non-selectively decomposing various pollutants by using simple equipment and small space, therefore it is adaptive to various working environments, and as a result, the application of non-thermal equilibrium plasma technique for simultaneously controlling pollutants in flue gas has drawn the universal concern at home and abroad, and the related techniques have been at the stage of commercial application based on a plenty of basic principle researches and technical popularization. At present, the most used plasma flue gas treatments are electron beam process, pulse corona process and direct current corona process.
During the removal of pollutants by using the electron beam process, N2, O2, CO2, vapor and the like absorb most electron beam energy after the irradiation of the electron beam to produce various free radicals including OH, O, HO2 and other particles with high reactivity. The free radicals are capable of oxidizing SO2 and NOx in the flue gas to produce sulfuric acid and nitric acid which would then be neutralized by the pre-introduced ammonia to produce ammonium sulfate and ammonium nitrate. The Ebara Corporation in Japan started the research on the technique of irradiating flue gas by electron beam for desulfuration and denitration in 1970, cooperated with the Japan Atomic Energy Research Institute in 1972, treated heavy oil combustion waste gas and performed experiments on the scale of 1000 Nm3/h with the radiation effect of the addition of ammonia detected, the conditions for desulfuration and denitration stabilized and the byproducts, ammonium sulfate and ammonium nitrate, entrapped successfully in 1974, and cooperated with the Research Institute for Controlling NOx of Steel Industry, and performed experiments on the scale of 10000 Nm3/h of sintering waste gas furnaces in 1977, so that the dry technique was affirmed. However, the main gas molecules in the high-energy electron pair flue gas produced from the electron beam process can break down the chemical bonds thereof, and decompose and ionize gas molecules with high content, such as N2 and CO2, in the flue gas, causing energy waste and large energy consumption in the process. Furthermore, the problems of expensive electron gun, shot longevities of electron gun and target window, complex equipment structure, large space, ammonia escape, shielding and protection of X-ray and the like are existing.
The pulse corona process may fast accelerate electrons within nanosecond-scale time, so that the electrons obtain larger energy, while less energy can accelerate the more massive ions, so as to greatly reduce the energy waste caused by the ion acceleration; meanwhile, the pulse corona process may reach a higher voltage peak to form a higher discharge intensity, making the high-energy electron energy reach 5-20 eV. The pulse corona process has been being widely researched since 1980s. In 1986, Masuda proposed a pulse corona discharge process of replacing electron accelerator with pulse high-voltage power supply above tens of thousands of volts to produce plasma, and performed a plenty of fundamental researches which showed that NO and SO2 were capable of effectively being oxidized into NO2 and SO3 by the pulse corona plasma chemical process. The Research Institute of Dalian University of Technology for Electrostatic and Special Power Supplies created a desulfuration device of 3000 Nm3/h, in 1996; Lee et al. created a large reaction device for simultaneous desulfuration and denitration by using pulse plasma technique, with the capacity of 42000 Nm3/h, and the desulfuration and denitration rates respectively of 99% and 70% by using ammonia free radical and propylene free radical under the energy consumption condition of 1.4 Wh/m3, in 2003. The energy consumption of the pulse corona process was only 50% of that of the electron beam process, but the pulse corona process still took effect and apply to ionize gas molecules, such as N2 and CO2, in the flue gas, resulting in energy waste. In addition, during the actual application of the electron beam process or pulse corona process, ammonia gas is usually added as absorbent and incapable of complete reaction, resulting in leakage and pollution to the surroundings after being discharged into the air.
The direct current corona discharge is a discharge form produced by the non-uniform electric field distribution between electrodes under the action of direct current and high voltage. The direct current corona discharge shares the similar working principle as the pulse corona discharge's, and has the advantages of simple discharge power supply, wide application of high-power direct current power supply in the electrostatic precipitation field, and mature and reliable technique. Chang et al. constructed a flue gas purification demonstration project of 1000-1500 Nm3/h for desulfuration and denitration of flue gas with direct current corona ammonia injection free radical shower with the removal rates of NO and SO2 of 75% and 99% respectively, and the energy consumptions of 125 g NO/kWh and 9 g SO2/kWh respectively.
In the pulse and direct current corona discharge pollutants removal systems, if the conventional discharge electrode structures are used, such as wire-cylinder structure and wire-plate structure, the corona zone of flue gas direct current corona discharge is smaller and only limited to the proximity of wire electrodes, and the discharge current is weaker, so that the pollutants removal effect is poor. If multi-pin and one-plate discharge structure is used, although the corona discharge zone and discharge current are increased, the energy consumption is larger.
For the deficiencies above, someone proposed to use the nozzle-type discharge electrode. China patent, Public Number CN1600468A filed on Mar. 30, 2005, discloses a discharge nozzle electrode for the direct current flue gas treatment with corona discharge, including a main pipe open at one end and sealed at the other end, and multiple nozzles symmetrically arranged on the main pipe. The additive gases introduced in the discharge nozzle electrode are ionized in the corona zone to produce a plenty of active substances capable of reacting with the pollutants, so as to remove the contaminations. In addition, the different additive gases are capable of being decomposed in the corona zone to produce different free radicals so as to be selected correspondingly according to the objects to be treated in the flue gas. With the electrode design, the air velocity in the nozzles is faster than the flue gas velocity in a reactor, so that the free radicals produced can be better transferred and contact with and oxidize the contaminations. The electrode is advantaged in that the additive gases are ionized to a great extent in the corona zone nearby the nozzles, and the flow of the gases at the nozzle mouths can make the corona discharge more stable, so as to produce stable streamer corona cross the whole discharge air gap. However, the additive gases are sprayed out from the ends of the nozzles, and the experimental result of the flow ionization zones is shown in
The invention incorporating good flue gas treatment effect, low energy consumption and small equipment investment provides a free radical injection ionizer for flue gas treatment with corona discharge to solve the problems of poor flue gas treatment effect, high energy consumption and large equipment investment of the current devices for flue gas treatment with non-thermal equilibrium plasma techniques.
To achieve the technical purpose above, the invention adopts the specific technical scheme: a free radical injection ionizer for flue gas treatment with corona discharge arranged in a flue gas channel and comprising an injection device for releasing free radical source substances and a separately arranged electrode device for producing corona. The electrode device comprises a conductive pole, and discharge tips arranged on the upper and lower sides of the conductive pole at equal intervals. The injection device comprises nozzles symmetrically arranged on two sides of the electrode device, and two lines of holes axially arranged on the wall of the nozzles nearby the electrode device. The holes are arranged at equal intervals with each other and with the discharge tips, and the axial lines of the holes direct the discharge tips nearest the holes. The injection device and electrode device are separately arranged and the axial lines of the holes direct the discharge tips nearest the holes, so that the free radial source substances sprayed out from the insulated nozzles on two sides of the electrodes are crosswise mixed with larger distribution zones. The experimental result of the free radical source substance discharge zone is shown in
As a preferred embodiment, the setting of discharge tips on the upper and lower sides of the conductive pole are symmetric or staggered. The settings of holes on the nozzles are symmetric or staggered, and are adapted to the discharge tips on the conductive pole. The holes on the nozzles correspond to the electrodes in quantity and position, i.e., one hole injects free radical source substances to one electrode tip to ensure the best ionization effect of the free radical source substances.
As a preferred embodiment, the holes are provided with flexible guiding hoses whose outlets are provided with well-distributed radial apertures. The holes are provided with flexible guiding hoses in the injection directions thereof, so that the flexible guiding hoses will irregularly wave or shake under the action of the flow injected from the holes. The flexible guiding hoses are provided with well-distributed radial apertures at the outlets thereof, so that the irregular waving or shaking may be further enhanced, upon which, the free radical source substances injected from the flexible guiding hoses have a larger range, and also the free radicals produced after the ionization of the free radical source substances have a larger distribution range to contact with more flue gas and improve the flue gas treatment effect.
As a preferred embodiment, the discharge tips are conical, cylindrical or serrated sharp, the ratio of the intervals of the discharge tips to the length of the discharge tips has a range of 3 to 1 to 5 to 1, and the number of each line of discharge tips on the conductive pole is 812.
As a preferred embodiment, the discharge tips are serrated sharp and are symmetrical settled on the upper and lower sides of the conductive pole which is structured like a plate, and integrally formed with the conductive pole. The vertex angle of the serrated structure is 40-50 degrees. The serrated electrode is one of the common electrodes in electrostatic precipitators, so that the invention may further reduce cost, and implement the integral dust precipitation and purification by combining with electrostatic precipitators.
As a preferred embodiment, the diameter of the nozzles is less than the total height of the electrode device, and the included angle between the axial lines of holes on each side of the nozzles is 110-140 degrees. The diameter of the nozzles and the angle between the axial lines of holes on each side of the nozzles are corresponding to the relative positions of the nozzles and electrodes. Usually, too close or too far from the nozzles to the electrodes will influence the ionization effect of the free radical source substances, so it would be more rational that the diameter of the nozzles is less than the total height of the electrode device and the included angle between the axial lines of holes on each side of the nozzles is 110-140 degrees.
As a preferred embodiment, one end of one nozzle is a sealed end connected with a vibrator through a connecting rod, and the other end of the nozzle is connected with a free radical air source through a hose. The action of connecting one end of the nozzle with the vibrator is similar as that of arranging the flexible guiding hose on the holes of the nozzles, but the vibrator may change the injection direction or range of the free radical source substances by controlling the vibration amplitude, direction or frequency of the nozzles to make the whole flue gas treatment device reach the optimum treatment effect.
The invention has the advantages of effectively solving the problems of poor flue gas treatment effect, high energy consumption and large equipment investment existing in the current devices for the flue gas treatment with non-thermal equilibrium plasma techniques. It has simple structure, good flue gas treatment effect, low energy consumption, and capability of combining with electrostatic precipitators to implement the integral dust precipitation and purification.
The specific implementation of the technical solution of the invention is described below in detail by referring to the following embodiments in conjunction with the figures attached.
In Embodiment 1 shown as
The discharge tips of Embodiment 2 are cylindrical (see
The discharge tips on the upper and lower sides of the conductive pole of Embodiment 3 are staggered (see
In Embodiment 4, the discharge tips are serrated and symmetric on the upper and lower sides of the conductive pole which is structured like a plate, and integrally formed with the conductive pole; and the vertex angle of the serrated structure is 45 degrees (see
When the free radical injection ionizer for flue gas treatment with corona discharge is operating, the flue gas passes through the flue gas channel 12. The electrode device in the flue gas channel and the electrode plates on the upper and lower sides of the flue gas channel exert direct current or pulse high voltage on the flue gas so as to produce corona discharge between the electrodes and the electrode plates. The nozzles on two sides of the electrode device spray out free radical source substances to the electrodes through the holes, and the free radical source substances produce highly active free radicals under the action of the corona to react with various organic and inorganic contamination molecules in the flue gas to have the contamination molecules decomposed and oxidized into harmless substances or easily treatable compounds, thus to reach the objective of flue gas treatment. Flexible guiding hoses are arranged in the injection directions of the holes, so that they will irregularly wave or shake under the action of the flow injected from the holes. Well-distributed radial apertures are arranged at the outlets of the flexible guiding hoses, so that the irregular waving or shaking may be further enhanced, upon which, the free radical source substances injected from the flexible guiding hoses have a larger range, and the free radicals produced after the ionization of the free radical source substances have a larger distribution range to contact with more flue gas, thus to improve the flue gas treatment effect. Additionally, connecting the nozzles with the vibrator to vibrate with it can also achieve the objective above. Compared with the flexible guiding hoses on the nozzles, the vibrator may change the injection direction or range of the free radical source substances by controlling the vibration amplitude, direction or frequency of the nozzles to make the whole flue gas treatment device reach the optimum treatment effect.
| Number | Date | Country | Kind |
|---|---|---|---|
| 200910153851.9 | Nov 2009 | CN | national |
| Filing Document | Filing Date | Country | Kind | 371c Date |
|---|---|---|---|---|
| PCT/CN2010/072503 | 5/7/2010 | WO | 00 | 4/12/2011 |
