The present invention relates generally to the field of semiconductor equipment and processing. More specifically, the present invention relates to a gas distribution apparatus useful in semiconductor fabrication.
Wafer processing reactor systems and methods are widely used in the manufacture of semiconductors and integrated circuits. One particular type of wafer processing system utilizes chemical vapor deposition (CVD) to deposit films or layers on the surface of a substrate as a step in the manufacture of semiconductors and integrated circuits. In CVD processes that require multiple gases, the gases are generally combined within a mixing chamber. The gaseous mixture is then coupled through a conduit to a distribution plate or showerhead, which contains a plurality of holes such that the gaseous mixture is evenly distributed into a process region. As the gaseous mixture enters the process region and is infused with energy such as being heated, a chemical reaction occurs between the gases to form a film on a substrate proximate the processing region.
Although it is generally advantageous to mix gases prior to delivery into a process region to ensure that the gases are uniformly distributed into the process region, gases tend to begin reacting within the mixing chamber. Consequently, deposition or etching of the mixing chamber, conduits and other chamber components may occur prior to the gaseous mixture reaching the process region. Additionally, reaction by-products and deposits may accumulate in the chamber gas delivery components.
Some semiconductor processes require delivery of gases into a process region in a sequential manner without premixing. For example, in an atomic layer deposition (ALD) process, which increasingly becomes an alternative to CVD processes, each reactant gas is independently introduced into a reaction chamber through, for example, a showerhead, so that no gas phase intermixing occurs. A monolayer of a first reactant is physi- or chemi-sorbed onto a substrate surface. After the excess first reactant is evacuated from the reaction chamber, a second reactant is then introduced through the showerhead to the reaction chamber and reacts with the first reactant to form a monolayer of the desired film via a self-limiting surface reaction. A desired film thickness is obtained by repeating the deposition cycle as necessary. It is advantageous to introduce the first and second reactants independently and separately through the showerhead to avoid any reaction between the reactants in the showerhead.
Therefore, in either a CVD or an ALD process, it is desired to maintain gases in separate passageways within a showerhead until they exit the showerhead into a process region.
To distribute process gases from a single inlet port to a multitude of outlet holes, gas distribution networks created in a showerhead body may be used. For example, a plurality of parallel channels can be formed in a unitary showerhead body from which a multitude of perpendicular outlet channels deliver process chemicals into a process region. The parallel channels are intersected perpendicularly by a single transverse plenum connected to a central gas source inlet line. Process gas passes from the inlet to the outlets of the showerhead by following a “Cartesian” path by flowing laterally along the transverse plenum, transverse through the parallel channels, and the outlet channels into the process region.
A disadvantage of this design is that there is a large variation in total flow path to reach points of constant radius within the showerhead. As a result, there is typical a large variation in backpressure within the interior flow channels that result in an unacceptable azimuthal and radial variation in outlet gas flow velocity from the multitude of outlet holes. Furthermore, in showerhead designs with a single central gas inlet, there exists an unavoidable time lag between the gases that exist near the center of the showerhead and those existing at the outer perimeter. The large variation in total flow path at points of constant radius inherent with Cartesian-style flow networks creates a “phase error” that may lead to non-uniform chemical concentrations around the perimeter of the showerhead which may affect deposition in transient-flow processes.
To minimize the azimuthal variation in time-lag, radially oriented channels that converge at the center gas inlet may be employed instead of a multitude of parallel channels. However, this type of design leads to a decreasing outlet hole density (hole per square centimeter) due to the divergence of the radial passages. This may be compensated somewhat by additional radial passages at larger radii, however, these require cross-connection to the same source of gas which becomes difficult to do in a truly unit body block of material. Furthermore, it is not apparent that this will yield acceptable flow uniformity either.
Therefore, there is a need of a gas distribution system that provides improved uniform outlet velocity distribution and reduced variation in azimuthal time lag between the gases that exit near the center of the showerhead and those existing at the outer perimeter. Further developments in gas distribution apparatus useful in CVD and ALD processes are needed.
A gas distribution apparatus useful in semiconductor fabrication is provided. The gas distribution apparatus promotes uniformly delivery of gases into a process region and reduces azimuthal variation in time lag between gas that exits near the center and gas exiting at the outer perimeter of the apparatus.
In one embodiment, the present gas distribution apparatus comprises a member and a gas distribution network formed within the unitary member for uniformly delivering a gas into a process region. The member can be a unitary member. The gas distribution network is formed of an inlet passage extending upwardly through the upper surface of the unitary member for connecting to a gas source. A plurality of first passages converge at a junction and interconnect with the inlet passage at the junction. A plurality of second passages are connected with the plurality of first passages, and a plurality of outlet passages are connected with the plurality of second passages for delivering the gas into a processing region. The first passages extend radially and outwardly from the junction to the periphery surface of the unitary member. The second passages are non-perpendicular to the first passages and extend outwardly from the first passages to the periphery surface. The outlet passages extend downwardly through the lower surface of the unitary member for delivering the gas into the processing region.
In one embodiment, the first passages are comprised of four orthogonal coordinate passages dividing the gas distribution network into four regions or quadrants. The second passages in each of the quadrants are parallel with each other. In opposite two quadrants, the first and second passages are symmetrically arranged. In adjacent two quadrants, the second passages on both sides of a common first passage are staggeredly arranged. The first and second passages constitute an angle from about 30 to about 45. In one embodiment, the angle is about 45 degrees.
In another embodiment, the first passages are comprised of six passages, and adjacent two passages form an angle of about 60 degrees.
Generally, the first passages have a diameter larger than the diameter of the second passages. The second passages have a diameter larger than the diameter of the outlet passages. In one embodiment, the diameter of the first passages is in the range from about 5 to about 15 mm, the diameter of the second passages is in the range from about 3 to about 12 mm, and the outlet diameter is in the range from about 0.25 to about 2.5 mm.
In another embodiment, the outlet passages are substantially cylindrical and adapted to receive inserts to alter the size of and/or direction of gases exiting the outlets into a process region. In a further embodiment, the outlet passages are provided with threads for receiving the inserts.
In one embodiment, the present gas distribution system comprises a unitary cylindrical member and two independent gas distribution networks formed within the unitary member. Each of the gas distribution networks is formed of an inlet passage extending upwardly through the upper surface of the unitary member for connecting to a gas source, a plurality of co-planar first passages converged at a junction add interconnected with the inlet passage at the junction, a plurality of second passages connected with the plurality of first passages, and a plurality of outlet passages connected with the plurality of second passages and extending downwardly through the lower surface of the unitary member for delivering the gas into the processing region. The first passages extend radially and outwardly from the junction to the periphery surface of the unitary member. The second passages are co-planar with and non-perpendicular to the first passages and extend outwardly from the first passages to the periphery surface. The first and second passages of each of the gas distribution networks are formed at different elevations within the unitary member and the inlet passages of each of the gas distribution networks offset each other. The two independent gas distribution networks are not in fluid communication within the unitary member. In one embodiment, the first passages of each of the gas distribution networks are comprised of four orthogonal coordinate passages. In another embodiment, the outlet passages of each of the two gas distribution networks extend through the lower surface in an alternate and even configuration. In a further embodiment, the two gas distribution networks have substantially the same dimensions and configurations.
In one embedment, the present gas distribution system comprises a unitary cylindrical member having an upper surface, a lower surface and a periphery surface, and three independent gas distribution networks formed within the unitary member. Each of the gas distribution networks is formed of an inlet passage, a plurality of first passages, a plurality of second passages connected with the first passages, and a plurality of outlet passages connected with the second passages. The inlet passage extends upwardly through the upper surface for connecting to a gas source. The first passages converge at a junction and is interconnected with the inlet passage at the junction. The first passages extend radially and outwardly from the junction to the periphery surface. The second passages are co-planar with and non-perpendicular to the first passages and extend outwardly from the first passages to the periphery surface. The outlet passages are connected with the second passages and extend downwardly through the lower surface for delivering the gas into the processing region. The first and second passages of each of the three gas distribution networks are formed at different elevations within the unitary member and the inlet passages of each of the three gas distribution networks offset each other. The three independent gas distribution networks are not in fluid communication within the unitary member. In one embodiment, the first passages of each of the three gas distribution networks are comprised of six passages, and adjacent two passages form an angle of about 60 degrees. The three gas distribution networks may have substantially the same dimensions and configurations.
Other objects and advantages of the present invention become apparent upon reading of the detailed description of the invention provided below and upon reference to the drawings in which:
A gas distribution apparatus useful in semiconductor fabrication is provided. In general, the gas distribution apparatus of the present invention comprises a unitary member and one or more gas distribution networks formed within the unitary member for uniformly delivering gases into a process region.
Referring to the drawings where like components are designated by like reference numerals, the present gas distribution apparatus is described in more detail.
The showerhead 12 is preferably a unitary member 13, as shown in
Member 13 is preferably machined from a block of aluminum, stainless steel, nickel-based alloys, or any material that does not react with the particular gases being supplied into the showerhead 12. The unitary member 13 can be in a cylindrical shape or any shape suitable as a lid for the reactor 10. The unitary member 13 comprises an upper surface 23, a lower surface 24, and a peripheral surface 25. A plurality of channels, passages or holes are formed within the unitary member 13 to form a gas distribution network 21. Various manufacturing techniques known in the art can be used to form the channels, passages or holes, such as electric discharge drilling, mechanical drilling, pressurized reactant drilling, water jet cutting, and the like. In one embodiment, these channels or passages are formed by mechanical drilling and/or an electrode discharge machine (EDM).
As illustrated in
A plurality of horizontal passages or plenums 28a-d are formed within the unitary member 13. The horizontal plenums 28a-d are converged at a junction 30 and extend radially and outwardly to the peripheral surface 25 of the unitary member 13. The horizontal plenums 28a-d are closed at the peripheral surface 25. The horizontal plenums 28a-d can be formed by drilling from the peripheral surface 25. The openings on the peripheral surface 25 are closed by for example sealing plugs (not shown) after the plenums 28a-d are formed. The inlet passage 26 is connected with the plenums 28a-d via the junction 30. In
A plurality of branch passages or tributaries 32 are formed along the path of each of the horizontal plenums 28a-d. The tributaries 32 extend from the plenum 28 to the peripheral surface 25 of the unitary member 13. The tributaries 32 are closed at the peripheral surface 25. These branch passages or tributaries 32 are formed at a same elevation with the plenums 28. In one embodiment, such as shown in
In opposite two quadrants such as 34a and 34c, or 34b and 34d, the configuration of tributaries 32 are symmetrical. In adjacent two quadrants such as 34a and 34b, or 34a and 34c, the tributaries 32 formed along a common plenum such as 28a or 28b are staggered and angled from the plenum. In one embodiment, each tributary 32 forms an acute angle with the plenum 28 of about 45 degrees. This angle can be determined by the geometrical requirements imposed by the number of gas distribution networks and the desired outlet hole patterns.
Along the path of each of the tributaries 32, an array of passages or outlets 36 are formed for distributing gases into a process region 16. The outlets 36 extends downwardly and through the lower surface 24 of the unitary member 13 as shown in FIG. 4. The passages of the outlets 36 can be straight and cylindrical. Alternatively, the passages of the outlets 36 comprise a first portion proximate the tributary 32 and a second portion distant the tributary 32. The first portion of the outlet passage may have a larger or smaller diameter than that of the second portion to control the back pressure of the outlets 36 according to process requirements. The outlet passages may also be provided with threads for receiving inserts that are designed to alter the size of the outlet or direction of gases exiting the outlet into the process region. U.S. application Ser. No. 10/856,584 entitled “Adjustable Gas Distribution System” filed concurrently with this application discloses embodiments of inserts that can be used in the present gas distribution system, the disclosure of which is hereby incorporated by reference in its entirety.
The diameters of the plenums 28a-d, tributaries 32, and outlets 36 are selected to provide a desired outlet velocity. In one embodiment, the diameters of the plenums 28a-d are larger than those of the tributaries 32, and the diameters of the tributaries 32 are larger than those of the outlets 36. Small outlet diameters create resistance to gas flow so as to sustain smaller variation in back pressure among all of the outlets. Large plenum and tributary diameters assist in this effect which is desirable. Typically, if the backing pressure is uniform among all the outlets, the outlet velocities are also uniform. However, it is desirable not to make the outlets too small as this may lead to “jetting” of gases, which is undesirable in semiconductor processes. The diameters of the outlets 36 can be uniform throughout the entire distribution region. Alternatively, the diameters of the outlets 32 differ to provide an inner region with a larger diameters and an outer region with smaller diameters.
In one embodiment, the diameter of the plenums 28a-d is selected in the range from about 5 mm to about 15 mm, the diameter of the tributaries 32 in the range from about 3 mm to about 12 mm, and the diameter of the outlets 36 in the range from about 0.25 mm to about 2.5 mm. In another embodiment, the diameter of the plenums 28a-d is selected in the range from about 9 mm to about 12 mm, the diameter of the tributaries 32 in the range from about 6 mm to about 9 mm, and the diameter of the outlets 36 in the range from about 1 mm to about 1.5 mm.
For clarity and simplicity, only some tributaries, outlets and plenums are shown in
In Table 1, Max/Min refers to the ratio of maximum to minimum outlet velocity. Range/Average refers to the ratio of Max/Min value to the average gas flow velocity. The values of Max/Min and Range/Average are used to rank the performance of the gas distribution systems. Small values of Max/Min and Range/Average are desired for uniform distribution of gases into a process region.
Table 1 demonstrates a much better performance of the present gas distribution apparatus over prior art showerheads. In a prior art showerhead of the Cartesian style network type, the Max/Min ratio was tested and found to be 3.584, which means that the variation of the outlet velocity is as high as more than 350%, and the Range/Average was 150,or 150%. In comparison, the Max/Min ratios for the gas distribution system of the present invention range only from 1.220 to 1.364, and the Range/Average ratios range only from 0.131 to 0.337.
One advantage of the present gas distribution system is a smaller transit time variation in the polar directions over that of the prior art showerhead design.
In one embodiment, two internal gas distribution networks are formed at different elevations within a unitary member to independently and separately supply two gases into a process region. Each of the two internal gas distribution networks is described above with reference to
The two internal gas distribution networks are arranged at different elevations within the unitary member in such a manner so that the plenums, tributaries, inlet and outlet passages of one internal gas distribution network offset corresponding plenums, tributaries, inlet and outlet passages of another internal gas distribution network. In other words, the corresponding plenums, tributaries, and inlet and outlet passages are not overlapped when viewed from the top or bottom of the unitary member. When viewed from the bottom of the unitary member, the outlet passages of each of the internal gas distribution networks extend through the bottom surface in an alternative and even configuration.
In a further embodiment, three internal gas distribution networks are formed at different elevations within a unitary member to independently and separately supply three gases into a process region. Each of the three internal gas distribution networks is described above with reference to
The three internal gas distribution networks are arranged at different elevations within the unitary member in such a manner so that the inlet and outlet passages of one internal gas distribution network offset the inlet and outlet passages of the other two internal gas distribution network. In other words, the corresponding inlet and out passages are not overlapped when viewed from the top or bottom of the unitary member.
As described above, a gas distribution apparatus has been provided by the present invention. The foregoing description of specific embodiments of the invention have been presented for the purpose of illustration and description. They are not intended to be exhaustive or to limit the invention to the precise forms disclosed, and obviously many modification, embodiments, and variations are possible in light of the above teaching. It is intended that the scope of the invention be defined by the claims appended hereto and their equivalents.
This application claims the benefit of and priority to U.S. Provisional Application No. 60/475,079 filed May 30, 2003, the disclosure of which is hereby incorporated by reference in its entirety.
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Number | Date | Country | |
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60475079 | May 2003 | US |