Heat-dissipating device with interfacial enhancements

Information

  • Patent Grant
  • 11181323
  • Patent Number
    11,181,323
  • Date Filed
    Thursday, February 21, 2019
    5 years ago
  • Date Issued
    Tuesday, November 23, 2021
    3 years ago
Abstract
An example heat-dissipating device with enhanced interfacial properties generally includes a first heat spreader configured to be thermally coupled to a region configured to generate heat, a second heat spreader, an interposer thermally coupled to at least one of the first heat spreader or the second heat spreader, at least one interfacial layer including a graphene material disposed on at least one surface of the interposer, and a phase change material disposed between the at least one interfacial layer and at least one of the first heat spreader or the second heat spreader and thermally coupled to at least one of the first heat spreader or the second heat spreader.
Description
BACKGROUND
Field of the Disclosure

The teachings of the present disclosure relate generally to a heat-dissipating device, and more particularly, to a heat-dissipating device with interfacial enhancements for an electronic device.


Description of Related Art

Electronic devices include internal components that generate heat. Some of these internal components (e.g., a central processing unit (CPU), a graphics processing unit (GPU), and/or memory) can generate a lot of heat, especially when performing data intensive operations (e.g., processing video and/or music). To counter or dissipate the heat generated by the CPU and/or GPU, an electronic device may include a heat-dissipating device, such as a heat spreader. As an example, a mobile device may include a heat spreader for dissipating heat generated by an integrated circuit (IC). The heat spreader may be coupled between the IC and a back side of the mobile device enabling heat generated by the IC to be dissipated through the heat spreader and the back side of the mobile device. However, the heat spreader has limitations, including its limited heat-dissipating capabilities. For example, the heat spreader implemented in a mobile device may be limited to dissipate about 3 W of heat.


SUMMARY

The following presents a simplified summary of one or more aspects of the present disclosure, in order to provide a basic understanding of such aspects. This summary is not an extensive overview of all contemplated features of the disclosure, and is intended neither to identify key or critical elements of all aspects of the disclosure nor to delineate the scope of any or all aspects of the disclosure. Its sole purpose is to present some concepts of one or more aspects of the disclosure in a simplified form as a prelude to the more detailed description that is presented later.


Certain aspects of the present disclosure provide a heat-dissipating device. The heat-dissipating device generally includes a first heat spreader configured to be thermally coupled to a region configured to generate heat, a second heat spreader, an interposer thermally coupled to at least one of the first heat spreader or the second heat spreader, at least one interfacial layer comprising a graphene material disposed on at least one surface of the interposer, and a phase change material disposed between the at least one interfacial layer and at least one of the first heat spreader or the second heat spreader and thermally coupled to at least one of the first heat spreader or the second heat spreader.


Certain aspects of the present disclosure provide a heat-dissipating device. The heat-dissipating device generally includes a first heat spreader configured to be thermally coupled to a region configured to generate heat, a second heat spreader, an interposer comprising at least one functionalize surface and thermally coupled to at least one of the first heat spreader or the second heat spreader, and a phase change material disposed between the interposer and at least one of the first heat spreader or the second heat spreader and thermally coupled to at least one of the first heat spreader or the second heat spreader. The at least one functionalize surface of the interposer is configured to increase a contacting area between the interposer and the phase change material.


Certain aspects of the present disclosure provide an apparatus. The apparatus generally includes first means for spreading heat configured to be thermally coupled to means for generating heat, second means for spreading heat, means for separating the first means for spreading heat from the second means for spreading heat, means for storing heat disposed between the means for separating and at least one of the first means for spreading heat or the second means for spreading heat and thermally coupled to at least one of the first means for spreading heat or the second means for spreading heat, and means for reducing a thermal resistivity between the means for separating and the means for storing heat. The means for separating is thermally coupled to at least one of the first means for spreading heat or the second means for spreading heat.





BRIEF DESCRIPTION OF THE DRAWINGS

So that the manner in which the above-recited features of the present disclosure can be understood in detail, a more particular description, briefly summarized above, may be had by reference to aspects, some of which are illustrated in the appended drawings. It is to be noted, however, that the appended drawings illustrate only certain typical aspects of this disclosure and are therefore not to be considered limiting of its scope, for the description may admit to other equally effective aspects.



FIG. 1 illustrates a front view of an example mobile device.



FIG. 2 illustrates a back view of the example mobile device of FIG. 1.



FIG. 3 illustrates a cross-sectional view of the example mobile device of FIG. 1.



FIG. 4A illustrates a cross-sectional view of an example heat-dissipating device with an interfacial layer, in accordance with certain aspects of the present disclosure.



FIG. 4B illustrates a perspective view of the traversal of an interposer, in accordance with certain aspects of the present disclosure.



FIG. 4C illustrates an example operation of depositing the interfacial layer on the interposer, in accordance with certain aspects of the present disclosure.



FIG. 5A illustrates a cross-sectional view of an example heat-dissipating device with a functionalized surface, in accordance with certain aspects of the present disclosure.



FIG. 5B illustrates an example operation of forming a functionalized surface of an interposer, in accordance with certain aspects of the present disclosure.



FIG. 5C illustrates an example interposer having a phosphorous-based functionalized surface, in accordance with certain aspects of the present disclosure.



FIG. 6 illustrates a cross-sectional view of an example heat-dissipating device with a functionalized surface and an interfacial layer, in accordance with certain aspects of the present disclosure.



FIG. 7 illustrates an example graph of transient heat storage for a heat-dissipating device without interfacial modifications.



FIG. 8 illustrates an example graph of transient heat storage for an example heat-dissipating device with interfacial modifications, in accordance with certain aspects of the present disclosure.



FIG. 9 illustrates an example graph of junction temperatures of various heat-dissipating devices versus thermal resistivity, in accordance with certain aspects of the present disclosure.





DETAILED DESCRIPTION

The detailed description set forth below in connection with the appended drawings is intended as a description of various configurations and is not intended to represent the only configurations in which the concepts described herein may be practiced. The detailed description includes specific details for the purpose of providing a thorough understanding of various concepts. However, it will be apparent to those skilled in the art that these concepts may be practiced without these specific details. In some instances, well-known structures and components are shown in block diagram form in order to avoid obscuring such concepts.


The various aspects will be described in detail with reference to the accompanying drawings. Wherever possible, the same reference numbers will be used throughout the drawings to refer to the same or like parts. References made to particular examples and implementations are for illustrative purposes, and are not intended to limit the scope of the disclosure or the claims.


The terms “computing device” and “mobile device” are used interchangeably herein to refer to any one or all of servers, personal computers, smartphones, cellular telephones, tablet computers, laptop computers, netbooks, ultrabooks, palm-top computers, personal data assistants (PDAs), wireless electronic mail receivers, multimedia Internet-enabled cellular telephones, Global Positioning System (GPS) receivers, wireless gaming controllers, and similar personal electronic devices which include a programmable processor. While the various aspects are particularly useful in mobile devices (e.g., smartphones, laptop computers, etc.), which have limited resources (e.g., processing power, battery, size, etc.), the aspects are generally useful in any computing device that may benefit from improved processor performance and reduced energy consumption.



FIGS. 1-3 illustrate an example of a mobile device that includes a heat-dissipating device for dissipating heat generated by an integrated circuit (IC) (also referred to as a chip). As shown in FIGS. 1 and 2, the mobile device 100 includes a display 102, a back side surface 200, a die 202, and a heat-dissipating device 204. The die 202 and the heat-dissipating device 204, which are both shown with dotted lines, are located inside the mobile device 100. The die 202 may be coupled to a first surface of the heat-dissipating device 204. A second surface of the heat-dissipating device 204 may be coupled to an inner surface of the back side surface 200.



FIG. 3 illustrates a profile view of the mobile device 100 that includes the heat-dissipating device 204. As shown in FIG. 3, the mobile device 100 includes the display 102, the back side surface 200, a front side surface 300, a bottom side surface 302, and a top side surface 304. FIG. 3 also illustrates a printed circuit board (PCB) 306, the die 202, and the heat-dissipating device 204 inside the mobile device 100.


As further shown in FIG. 3, a first side of the die 202 is coupled to a first surface of the PCB 306. A second side of the die 202 is coupled to a first surface of the heat-dissipating device 204. A second surface of the heat-dissipating device 204 is coupled to a first surface (e.g., inner surface) of the back side surface 200. In this configuration, heat that is generated by the die 202 is dissipated through the heat-dissipating device 204 and the back side surface 200 of the mobile device as well as through the PCB 306 and display 102.


Example Heat-Dissipating Device

With rising power demands and shrinking device sizes, integrated circuits (ICs) rely on heat-storage solutions to control junction and skin temperatures for reliable and safe operation. Heat-storage solutions, including integration of phase change materials (PCMs) (e.g., paraffin) with heat spreaders (e.g., graphite heat spreader), may facilitate dissipating heat generated by the ICs. Overall thermal performance and mechanical robustness of conventional heat-storage solutions are limited by interfacial properties of materials contacting the PCMs. For example, current heat-storage solutions may have incomplete contact areas with the PCM, resulting in air gaps that increase the interfacial thermal resistance. Conventional heat-storage solutions may also have intrinsic boundary resistivities between the PCM and a metallic material that affect the interfacial thermal resistance.


Certain aspects of the present disclosure provide a heat-dissipating device that increases effectiveness and robustness of heat dissipation via interfacial enhancements, such as increasing the contact area between an interposer and PCM integrated with heat spreaders, as further described herein. For example, an interfacial layer may be disposed on the interposer to increase the contact area with the PCM. As another example, the interposer may have a functionalized surface, as further described herein, to increase the contact area with the PCM. In certain aspects, the interposer may have the functionalized surface in combination with the interfacial layer to enhance the contact area with the PCM.



FIG. 4A illustrates a cross-sectional view of an example heat-dissipating device 204 that may be thermally coupled to a region (e.g., of an electronic device) configured to generate heat (e.g., die 202 of FIGS. 2 and 3) during operation, in accordance with certain aspects of the present disclosure. As shown, the heat-dissipating device 204 includes a first heat spreader 402, a second heat spreader 404, an interposer 406, an interfacial layer 408, and at least one PCM 410.


The first heat spreader 402 may be thermally coupled to the region configured to generate heat, such as the die 202 depicted in FIGS. 2 and 3. The second heat spreader 404 may be thermally coupled to another surface of an electronic device, such as the inner surface of the back side surface 200 as depicted in FIGS. 2 and 3. The first and second heat spreaders 402, 404 may include at least one of metal, carbon, graphite, and/or aluminum. In certain aspects, at least one of the heat spreaders 402, 404 has a thermal conductivity value of about 300 W/m-K or higher. In other aspects, at least one of the heat spreaders 402, 404 has a thermal conductivity value of about 500 W/m-K or higher (e.g., graphite).


The interposer 406 may be thermally coupled to at least one of the first heat spreader 402 or the second heat spreader 404. The interposer may include a thermally conductive metallic material including but not limited to copper, gold, and/or silver. The interposer 406 may periodically traverse the PCM 410, alternating between contacting the first heat spreader 402 and the second heat spreader 404, as portrayed in the two-dimensional cross-sectional view of FIG. 4A. In three dimensions, the interposer 406 may form a cross-hatched (checker board) pattern as shown in the example perspective view of FIG. 4B, in accordance with certain aspects of the present disclosure. Referring to FIG. 4B, the PCM may be disposed in the trenches 412 of the patterned interposer 406.


Referring to FIG. 4A, to enhance the contact area between the interposer 406 and PCM 410, at least one interfacial layer 408 may be disposed on at least one surface of the interposer 406. The interfacial layer(s) 408 may be composed of any of various suitable thermally conductive materials capable of filling small volumes, such as a graphene material. The graphene material may be applied in any of various suitable forms, such as carbon nanotubes (CNTs). The interfacial layer(s) 408 may include a first graphene layer 408A disposed on a lower surface of an upper portion of the interposer 406 and a second graphene layer 408B disposed on an upper surface of a lower portion of the interposer 406, as illustrated in the example of FIG. 4A. In certain aspects, the interfacial layer 408 may reduce a thermal resistivity between the interposer 406 and the PCM 410. For instance, the interfacial layer 408 may provide an improved wettability between the interposer 406 and PCM 410. In certain aspects, the interfacial layer 408 may enable the interposer 406 to match fidelity of phases of the PCM 410.


The PCM 410 may include a plurality of PCMs having similar and/or different melting temperatures. The PCM 410 may include, for example, a paraffin wax, a high performance wax, and/or gallium. The high performance wax may have a heat of fusion of about 200,000 J/kg and a melting point/melting temperature of about 35° C. The gallium-based material may have a heat of fusion of about 80,000 J/kg and a melting point/melting temperature of about 29-31° C.



FIG. 4C illustrates an example operation of depositing the interfacial layer 408 on the interposer 406, in accordance with certain aspects of the present disclosure. As shown, the interfacial layer 408 may be disposed on a surface of the interposer 406 via a deposition technique, such as a chemical vapor deposition (CVD) process.


In certain aspects, the interposer 406 may have a functionalized surface that increases the contact area with the PCM. For example, FIG. 5A illustrates a cross-sectional view of the example heat-dissipating device 204 with a functionalized surface 502 of the interposer 406, in accordance with certain aspects of the present disclosure. The functionalized surface 502 may be formed through a solution- or vapor-phase functionalization. As an example, the surface of the interposer 406 may be modified via vapor-phase reactions with an R-group material (e.g., a long-chain alkane molecule) as illustrated in FIG. 5B. The R-group material may be any suitable material that facilitates a reduced thermal resistance and enhanced wettability with the PCM 410. As an example, the R-group material may include a phosphorous material, such as R-PO3, as depicted in FIG. 5C. As shown in FIG. 5C, the R-group material of the functionalized surface 502 may bond with an oxide surface of the metallic interposer 406. The R-group material may be selected to form a polymer structure on the surface of the interposer 406 such that the functionalized surface 502 increases the contact area between the PCM 410 and interposer 406.


In certain aspects, the interposer 406 may have a functionalized surface and an interfacial layer 408. For example, FIG. 6 illustrates a cross-sectional view of the example heat-dissipating device 204 with a functionalized surface 502 and an interfacial layer 408, in accordance with certain aspects of the present disclosure. As shown, the interfacial layer 408 may be disposed on the functionalized surface 502 of the interposer 406.



FIGS. 7 and 8 illustrate example graphs of transient heat storage for heat-dissipating devices. As shown, curves 702 and 704 represent the maximum temperatures over time in seconds for the bottom and top surfaces, respectively, of a heat-dissipating device without any interfacial modifications. Curves 802 and 804 represent the maximum temperatures in seconds for the bottom and top surfaces, respectively, of an example heat-dissipating device with interfacial modifications, such as the functionalized surface 502 and/or the interfacial layer 408. FIG. 8 demonstrates that the example heat-dissipating device described herein provides enhanced thermal resistivity resulting in a reduced peak temperature (130° C.) and reduced steady state temperature (32.5° C.). In contrast, the heat-dissipating device without interfacial modifications exhibits a peak temperature of 160° C. and a steady state temperature of 36.3° C.



FIG. 9 illustrates an example graph of junction temperatures of various heat-dissipating devices, in accordance with certain aspects of the present disclosure. As shown, various maximum junction temperatures (Celsius) as a function of thermal resistivities are plotted. The junction temperatures within a first region 902 represent the temperatures exhibited by a heat-dissipating device without interfacial modifications, whereas the junction temperatures within the second region 904 represent the temperatures exhibited by the example heat-dissipating device with interfacial modifications as described herein. FIG. 9 demonstrates that the example heat-dissipating device described herein with interfacial modifications provides improved thermal resistivity and reduced peak temperatures.


Means for spreading heat may include a heat spreader, such as the heat spreaders 402, 404 depicted in FIGS. 4A, 5A, and 6. Means for separating the heat spreaders may include an interposer, such as the interposer 406 depicted in FIGS. 4A, 5A, and 6. Means for storing heat may include a phase change material, such as the PCM 410 illustrated in FIGS. 4A, 5A, and 6. Means for reducing a thermal resistivity may include an interfacial layer, such as the interfacial layer 408 depicted in FIGS. 4A and 6, and/or a functionalized surface of an interposer, such as the functionalized surface 502 shown in FIGS. 5A and 6.


Within the present disclosure, the word “exemplary” is used to mean “serving as an example, instance, or illustration.” Any implementation or aspect described herein as “exemplary” is not necessarily to be construed as preferred or advantageous over other aspects of the disclosure. Likewise, the term “aspects” does not require that all aspects of the disclosure include the discussed feature, advantage, or mode of operation. The term “coupled” is used herein to refer to the direct or indirect coupling between two objects. For example, if object A physically touches object B and object B touches object C, then objects A and C may still be considered coupled to one another—even if objects A and C do not directly physically touch each other. For instance, a first object may be coupled to a second object even though the first object is never directly physically in contact with the second object. The terms “circuit” and “circuitry” are used broadly and intended to include both hardware implementations of electrical devices and conductors that, when connected and configured, enable the performance of the functions described in the present disclosure, without limitation as to the type of electronic circuits.


The apparatus and methods described in the detailed description are illustrated in the accompanying drawings by various blocks, modules, components, circuits, steps, processes, algorithms, etc. (collectively referred to as “elements”). These elements may be implemented using hardware, for example.


One or more of the components, steps, features, and/or functions illustrated herein may be rearranged and/or combined into a single component, step, feature, or function or embodied in several components, steps, or functions. Additional elements, components, steps, and/or functions may also be added without departing from features disclosed herein. The apparatus, devices, and/or components illustrated herein may be configured to perform one or more of the methods, features, or steps described herein. The algorithms described herein may also be efficiently implemented in software and/or embedded in hardware.


It is to be understood that the specific order or hierarchy of steps in the methods disclosed is an illustration of exemplary processes. Based upon design preferences, it is understood that the specific order or hierarchy of steps in the methods may be rearranged. The accompanying method claims present elements of the various steps in a sample order, and are not meant to be limited to the specific order or hierarchy presented unless specifically recited therein.


The previous description is provided to enable any person skilled in the art to practice the various aspects described herein. Various modifications to these aspects will be readily apparent to those skilled in the art, and the generic principles defined herein may be applied to other aspects. Thus, the claims are not intended to be limited to the aspects shown herein, but are to be accorded the full scope consistent with the language of the claims, wherein reference to an element in the singular is not intended to mean “one and only one” unless specifically so stated, but rather “one or more.” Unless specifically stated otherwise, the term “some” refers to one or more. A phrase referring to “at least one of” a list of items refers to any combination of those items, including single members. As an example, “at least one of: a, b, or c” is intended to cover at least: a, b, c, a-b, a-c, b-c, and a-b-c, as well as any combination with multiples of the same element (e.g., a-a, a-a-a, a-a-b, a-a-c, a-b-b, a-c-c, b-b, b-b-b, b-b-c, c-c, and c-c-c or any other ordering of a, b, and c). All structural and functional equivalents to the elements of the various aspects described throughout this disclosure that are known or later come to be known to those of ordinary skill in the art are expressly incorporated herein by reference and are intended to be encompassed by the claims. Moreover, nothing disclosed herein is intended to be dedicated to the public regardless of whether such disclosure is explicitly recited in the claims. No claim element is to be construed under the provisions of 35 U.S.C. § 112(f) unless the element is expressly recited using the phrase “means for” or, in the case of a method claim, the element is recited using the phrase “step for.”

Claims
  • 1. A heat-dissipating device, comprising: a first heat spreader configured to be thermally coupled to a region configured to generate heat;a second heat spreader;an interposer thermally coupled to at least one of the first heat spreader or the second heat spreader, wherein the interposer has a functionalized surface comprising alkane molecules;at least one interfacial layer comprising a graphene material disposed on at least one surface of the interposer, wherein the at least one surface of the interposer comprises the functionalized surface; anda phase change material disposed between the at least one interfacial layer and at least one of the first heat spreader or the second heat spreader and thermally coupled to at least one of the first heat spreader or the second heat spreader.
  • 2. The heat-dissipating device of claim 1, wherein the at least one interfacial layer comprises a first graphene layer disposed on an upper surface of the interposer and a second graphene layer disposed on a lower surface of the interposer.
  • 3. The heat-dissipating device of claim 1, wherein the interfacial layer is configured to reduce a thermal resistivity between the interposer and the phase change material.
  • 4. The heat-dissipating device of claim 1, wherein the interposer periodically traverses the phase change material, alternating between contacting the first heat spreader and the second heat spreader.
  • 5. The heat-dissipating device of claim 1, wherein the interposer comprises a thermally conductive metallic material.
  • 6. The heat-dissipating device of claim 1, wherein the interposer comprises at least one of copper, gold, or silver.
  • 7. The heat-dissipating device of claim 1, wherein the functionalized surface is configured to increase a contacting area between the at least one interfacial layer and the phase change material.
  • 8. The heat-dissipating device of claim 1, wherein the functionalized surface comprises a phosphorous material.
  • 9. A heat-dissipating device, comprising: a first heat spreader configured to be thermally coupled to a region configured to generate heat;a second heat spreader;an interposer comprising at least one functionalized surface and thermally coupled to at least one of the first heat spreader or the second heat spreader, wherein the functionalized surface comprises alkane molecules; anda phase change material disposed between the interposer and at least one of the first heat spreader or the second heat spreader and thermally coupled to at least one of the first heat spreader or the second heat spreader, wherein the at least one functionalized surface of the interposer is configured to increase a contacting area between the interposer and the phase change material.
  • 10. The heat-dissipating device of claim 9, wherein the functionalized surface comprises a phosphorous material.
  • 11. The heat-dissipating device of claim 9, wherein the functionalized surface is configured to reduce a thermal resistivity between the interposer and the phase change material.
  • 12. The heat-dissipating device of claim 9, wherein the interposer periodically traverses the phase change material, alternating between contacting the first heat spreader and the second heat spreader.
  • 13. The heat-dissipating device of claim 9, wherein the interposer comprises a thermally conductive metallic material.
  • 14. The heat-dissipating device of claim 9, wherein the interposer comprises at least one of copper, gold, or silver.
  • 15. The heat-dissipating device of claim 9, further comprising at least one interfacial layer comprising a graphene material disposed on a surface of the interposer.
  • 16. The heat-dissipating device of claim 15, wherein the at least one interfacial layer comprises a first graphene layer disposed on an upper surface of the interposer and a second graphene layer disposed on a lower surface of the interposer.
  • 17. An apparatus, comprising: first means for spreading heat configured to be thermally coupled to means for generating heat;second means for spreading heat;means for separating the first means for spreading heat from the second means for spreading heat, the means for separating being thermally coupled to at least one of the first means for spreading heat or the second means for spreading heat, wherein the means for separating has a functionalized surface comprising alkane molecules;means for storing heat disposed between the means for separating and at least one of the first means for spreading heat or the second means for spreading heat and thermally coupled to at least one of the first means for spreading heat or the second means for spreading heat; andmeans for reducing a thermal resistivity between the means for separating and the means for storing heat.
  • 18. The apparatus of claim 17, wherein the means for separating periodically traverses the means for storing heat, alternating between contacting the first means for spreading heat and the second means for spreading heat.
  • 19. The apparatus of claim 17, wherein the means for separating comprises a thermally conductive metallic material.
  • 20. The apparatus of claim 17, wherein the functionalized surface comprises a phosphorous material.
US Referenced Citations (91)
Number Name Date Kind
4775588 Ishii Oct 1988 A
5691062 Shalaby Nov 1997 A
6226178 Broder et al. May 2001 B1
6503564 Fleming Jan 2003 B1
6674642 Chu et al. Jan 2004 B1
6938678 Bortolini et al. Sep 2005 B1
7184265 Kim et al. Feb 2007 B2
7188484 Kim Mar 2007 B2
7249627 Choi et al. Jul 2007 B2
7420807 Mikubo et al. Sep 2008 B2
7486517 Aapro et al. Feb 2009 B2
7552759 Liu et al. Jun 2009 B2
8058724 Refai-Ahmed Nov 2011 B2
8443874 Mikami May 2013 B2
8587945 Hartmann Nov 2013 B1
8716689 Chen et al. May 2014 B2
8763681 Agostini et al. Jul 2014 B2
9007769 Cheng et al. Apr 2015 B2
9048188 Maldonado Jun 2015 B2
9097467 Gradinger et al. Aug 2015 B2
9261309 Wang Feb 2016 B2
9546826 Carter Jan 2017 B1
9918407 Rosales et al. Mar 2018 B2
9930808 Li Mar 2018 B2
9999157 Chiriac et al. Jun 2018 B2
20010003308 Li Jun 2001 A1
20010017762 Ueda et al. Aug 2001 A1
20020015288 Dibene, II Feb 2002 A1
20020036890 Furuya Mar 2002 A1
20020056542 Yamamoto May 2002 A1
20020104641 Searls Aug 2002 A1
20020144804 Liang Oct 2002 A1
20020170705 Cho et al. Nov 2002 A1
20030079865 Son et al. May 2003 A1
20030205364 Sauciuc et al. Nov 2003 A1
20040040696 Cho Mar 2004 A1
20040093889 Bureau May 2004 A1
20040190253 Prasher et al. Sep 2004 A1
20050051304 Makino et al. Mar 2005 A1
20050087327 Wang Apr 2005 A1
20050099776 Xue et al. May 2005 A1
20050116336 Chopra Jun 2005 A1
20050129928 Lee Jun 2005 A1
20050141195 Pokharna Jun 2005 A1
20050207120 Tseng Sep 2005 A1
20060005950 Wang Jan 2006 A1
20060157227 Choi et al. Jul 2006 A1
20060243425 Dussinger Nov 2006 A1
20070012427 Liu et al. Jan 2007 A1
20070025081 Berlin et al. Feb 2007 A1
20070029070 Yamamoto et al. Feb 2007 A1
20070068654 Chang Mar 2007 A1
20070151275 Chiriac Jul 2007 A1
20070158052 Lin Jul 2007 A1
20070284090 Wu et al. Dec 2007 A1
20080047684 Noel Feb 2008 A1
20080142195 Erturk et al. Jun 2008 A1
20090232991 Wang Sep 2009 A1
20100044014 Ho et al. Feb 2010 A1
20110003143 Sugimoto Jan 2011 A1
20110051071 Nakamichi et al. Mar 2011 A1
20110108978 Kim May 2011 A1
20110198059 Gavillet Aug 2011 A1
20110232874 Xu et al. Sep 2011 A1
20110279978 Yoshikawa et al. Nov 2011 A1
20120111553 Tsoi et al. May 2012 A1
20120199322 Frigiere et al. Aug 2012 A1
20130141866 Refai-Ahmed Jun 2013 A1
20130270721 Chiriac et al. Oct 2013 A1
20140138052 Hsieh et al. May 2014 A1
20140238645 Enright Aug 2014 A1
20140246176 Yang Sep 2014 A1
20140352926 Sun et al. Dec 2014 A1
20140377145 Govyadinov et al. Dec 2014 A1
20150000866 Lin et al. Jan 2015 A1
20150198380 Haj-Hariri Jul 2015 A1
20150257308 Li Sep 2015 A1
20150268704 Chiriac Sep 2015 A1
20150315449 Kim Nov 2015 A1
20160037681 Lee et al. Feb 2016 A1
20160076819 Espersen et al. Mar 2016 A1
20160102109 Maeda Apr 2016 A1
20160369936 Hwang Dec 2016 A1
20170202104 Lin Jul 2017 A1
20170293329 Chiriac et al. Oct 2017 A1
20170295671 Chiriac et al. Oct 2017 A1
20170303433 Delano Oct 2017 A1
20170333941 Park Nov 2017 A1
20180015460 Sells et al. Jan 2018 A1
20180157297 Delano Jun 2018 A1
20190257589 Rosales et al. Aug 2019 A1
Foreign Referenced Citations (21)
Number Date Country
102440086 May 2012 CN
103000595 Mar 2013 CN
102589197 Apr 2014 CN
2348271 Jul 2011 EP
2000252671 Sep 2000 JP
2001024372 Jan 2001 JP
2004349652 Dec 2004 JP
2005142513 Jun 2005 JP
2006191123 Jul 2006 JP
2006242176 Sep 2006 JP
2007113864 May 2007 JP
2010203694 Sep 2010 JP
2010236792 Oct 2010 JP
2015032776 Feb 2015 JP
20130093596 Aug 2013 KR
2007130668 Nov 2007 WO
2012161002 Nov 2012 WO
2015142669 Sep 2015 WO
2015154044 Oct 2015 WO
2017180524 Oct 2017 WO
2018031218 Feb 2018 WO
Non-Patent Literature Citations (2)
Entry
Hong Y., et al., “Tuning Thermal Contact Conductance at Graphene—Copper Interface via Surface Nanoengineering”, Nanoscale, The Royal Society of Chemistry, 2015, pp. 6286-6294.
Himran S., et al., “Characterization of Alkanes and Paraffin Waxes for Application as Phase Change Energy Storage Medium”, Energy Sources Journal, vol. 16, 1994, pp. 117-128.
Related Publications (1)
Number Date Country
20200271388 A1 Aug 2020 US