The invention belongs to the technical field of heat exchangers. The invention relates more specifically to plate heat exchangers filled with a powder designed to initiate a physical/chemical reaction.
Brazed-plate heat exchangers are traditionally used in the cryogenic industry for gas separation and liquefaction, in the energy and petrochemical sectors.
As part of an energy transition with major CO2 emission reduction targets, many countries are showing increasing interest in new energy sources. In this context, brazed-plate heat exchangers are being adapted to new industrial-scale processes. This is the case for hydrogen liquefaction processes linked to the development of hydrogen mobility.
Hydrogen, for example, is more stable at low temperatures in the para hydrogen state than in the ortho hydrogen state. At low temperatures, particularly liquefaction temperatures, ortho hydrogen tends to spontaneously transform into para hydrogen, releasing unwanted heat.
To keep hydrogen in its liquid state, there are two options. A first option is to continuously extract the heat released by the conversion of ortho hydrogen into para hydrogen. In practice, this technique proves to be particularly energy-intensive, and uneconomical on an industrial scale.
A second option is to eliminate ortho hydrogen by converting it to para hydrogen. An exothermic catalytic reaction combined with cooling converts most of the ortho hydrogen into para hydrogen. Spontaneous conversions of ortho hydrogen to para hydrogen are then reduced.
This second option is one of the areas wherein the present invention can be applied.
Due to the use of a catalyst, often in powder form, inserted into the heat exchanger after the brazing operations, it is necessary to use hydrogen dispensing heads with large openings whose cross-section is substantially equal to that of said heat exchanger. This ensures even powder distribution in the exchanger compartments.
This means that the dispensing heads are particularly large, which has an impact on the heat exchanger.
Conventional heat exchangers typically comprise longitudinal and end bars defining compartments separated from each other by hermetic separating walls.
In the case of distributor heads whose cross-section is roughly equal to the cross-section of the heat exchanger, there are no end bars in catalyst-containing compartments, as they would impede the insertion of catalyst in powder form. However, the overall structure of the heat exchanger is weakened, as the end bars contribute to the mechanical strength of the heat exchanger and to the distribution of welding stresses.
During the assembly operation, the dispensing heads are welded to said heat exchanger. Weld cooling, material expansion, and material contraction cause mechanical stresses that can deform the main structure of the heat exchanger, reducing its efficiency. A further disadvantage is that these deformations make it more difficult to fill the heat exchanger with powdered catalyst, leading to maldistribution of the catalyst, which is detrimental to the unit's performance.
The invention aims to address these drawbacks.
For this purpose, a heat exchanger comprising:
Such a heat exchanger enables the exchanger structure to absorb the mechanical stresses inherent in cooling the weld. This makes it easier to fill with powder.
Various additional features can be provided alone or in combination:
For the purposes of this application, the length of the spacers is defined in the direction of fluid flow in the compartment, while the width is defined perpendicular to the direction of fluid flow in the compartment.
Further features and advantages of the invention will become apparent from the following detailed description, which can be understood with reference to the accompanying drawings, wherein:
The heat exchanger 1 comprises several longitudinal bars 2 together defining a body 3 provided with compartments 4 defining an internal volume wherein a fluid is able to circulate. Each compartment 4 is bordered laterally along the Y axis by a longitudinal bar 2. The compartments 4 are adjacent to each other. In other words, compartments 4 are juxtaposed one on top of the other along the Z axis.
Each compartment has openings 5 through which fluid can enter and exit the interior volume.
The heat exchanger 1 has separating walls 6. A separating wall 6 is located between each compartment 4. A separating wall 6 separates the compartments 4, and therefore the corresponding interior volumes, from each other along the Z axis.
On either side of the heat exchanger 1 along the Z axis, the heat exchanger comprises an end compartment 6 located at the lower and upper ends 7. A closing wall 9 is arranged on each end compartment 7, thus closing the internal end volume and, in so doing, the heat exchanger 1.
As shown in [
The fluid thus distributed by the dispensing head 10 is distributed into the accessible compartments 4 arranged along the Z axis.
The heat exchanger 1 further comprises a collection head, not shown in the drawings, arranged opposite the dispensing head 10. The collection head collects the fluid leaving the heat exchanger 1.
The dispensing head 10 is attached to the body 3 by welding. When the welding is complete, the cooling of the weld metal causes mechanical stresses on the body 3. These mechanical stresses are commonly referred to as “material shrinkage”.
Advantageously, the heat exchanger I comprises a plurality of spacers 12. As can be seen in [
The spacers 12 arranged in this way prevent deformation of the compartments 4 as a result of material shrinkage due to welding operations on the distribution or collection head 10. As the openings 5 are not deformed, operations to fill the compartments 4 with catalyst powder are possible and easy. In addition, the spacers 12 prevent the creation of compartments 4 through which the fluid cannot easily pass. This is because a deformed compartment is more difficult for the fluid to access. This would create preferential passages for the fluid and destroy the homogeneity of fluid distribution in the heat exchanger 1.
Advantageously, the spacers 12 are located in the vicinity of the dispensing head 10 and the collection head (not shown). It is in the vicinity of the dispensing head 10 and collection head that the mechanical stresses likely to deform the compartments 4 exist. The spacers 12 located there advantageously prevent deformation of the compartments 4.
Advantageously, the spacers 12 are arranged at a longitudinal end 13, along the X axis, of the body 3. The longitudinal end 13 is located at the boundary between the distribution or collection head 10 on the one hand and the body 3 on the other. It is at the longitudinal end 13 of the body that the risk of deformation is greatest. The spacers 12 thus located advantageously prevent deformation of the longitudinal ends 13 of body 3, through which the catalyst in powder form is inserted. This facilitates filling.
Advantageously, the spacers 12 are provided with perforations 14. The spacers 12 represent obstacles to the passage of fluid and/or catalyst powder. The perforations 14 are sized to allow fluid and/or catalyst powder to pass through. This reduces the impact of spacers 12 on fluid flow and/or catalyst powder filling.
Advantageously, the spacers 12 have a length L/width 1 ratio of between 0.5 and 5, preferably between 0.8 and 2. In particular, the higher the ratio, the more limited the impact of the spacers on the flow in the passage. It should also be noted that each spacer is defined by a length defined along the X axis, a width defined along the Y axis and a height defined along the Z axis (see [
According to one embodiment shown in [
In a given compartment, the spacers 12 are arranged side by side and spaced apart by a distance k measured along the Y axis, of between 5 and 30 centimeters.
Referring to [
Advantageously, the spacers 12 are arranged one below the other, that is aligned along the Z axis as shown in [
In an embodiment not shown in the drawings, the spacers are cylindrical. Each flat face of the spacers is in contact with a closing or separating wall, while the circular face is in contact with the fluid or catalyst powder. Spacers of this shape are advantageous because they facilitate the flow of powder or fluid.
In another embodiment not shown in the drawings, the spacers are elliptical. Each flat face of the spacers is in contact with a closing or separating wall, while the ellipsoid face is in contact with the fluid or catalyst powder. Spacers of this aircraft wing shape are advantageous because they facilitate the flow of powder or fluid.
| Number | Date | Country | Kind |
|---|---|---|---|
| FR2114698 | Dec 2021 | FR | national |
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/EP2022/087109 | 12/20/2022 | WO |