Claims
- 1. A heat sensitive recording sheet prepared by coating a developer, coupler which develops a color by a heat fusion reaction with said developer and binder, on a sheet substrate, or by impregnating such therein, characterized in that said developer is one or more than one of the compounds represented by formula (I): ##STR2## wherein each R is hydrogen, an alkyl radical of 1 to 12 carbon atoms, a cycloalkyl radical of 3 to 10 carbon atoms, an aralkyl radical of 7 to 10 carbon atoms or a phenyl radical, and can be identical to or different from each other, M is a polyvalent metal, except for Group IA of the Periodic Table, and n is zero or an integer of 1 or 2 and said sheet is substantially colorless at room temperature.
- 2. The heat sensitive recording sheet claimed in claim 1, wherein M in formula (I) is magnesium, calcium, aluminium, zinc, tin, nickel, cobalt, barium, strontium, cadmium, manganese, or chromium.
- 3. The heat sensitive recording sheet claimed in claim 2, wherein M in formula (I) is nickel, zinc, cobalt, magnesium, or calcium.
- 4. The heat sensitive recording sheet claimed in claim 1, wherein R in formula (I) is a tert-butyl, amyl, tert-octyl, nonyl, dodecyl, or cumyl radical.
- 5. A heat sensitive recording sheet prepared by coating a developer, coupler which develops a color by a heat fusion reaction with said developer and binder, on a sheet substrate, or by impregnating such therein, characterized in that said developer is one or more than one of the compounds represented by formula (I): ##STR3## wherein each R is hydrogen, an alkyl radical of 1 to 12 carbon atoms, a cycloalkyl radical of 7 to 10 carbon atoms or a phenyl radical, and can be identical to or different from each other, M is a polyvalent metal, except for Group IA of the Periodic Table, and n is zero or an integer of 1 to 2, and said sheet further contains a heat fusible material which has a melting point of 50.degree.to 190.degree. C. and is substantially colorless at room temperature.
- 6. The heat sensitive recording sheet claimed in claim 5, wherein said heat fusible material is acetanilide, urea, diphenylamine, biphenyl, naphthalene, .alpha.-naphthol, .beta.-naphthol, bisphenol A, 4,4'-cyclohexilidenediphenol, phthalic anhydride, benzoic acid, phthalic acid, methyl p-hydroxybenzoate, stearic acid, zinc stearate, ethyleneglycol ester stearate, a triphenylphosphate, a 2,2'-bisphenol sulfide, a 2,2'-bisphenolsulfoxide or a 2,2'-bisphenolsulfone.
Priority Claims (1)
Number |
Date |
Country |
Kind |
54-75623 |
Jun 1979 |
JPX |
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Parent Case Info
This is a continuation of application Ser. No. 229,562, filed on Feb. 18, 1981, abandoned.
US Referenced Citations (7)
Foreign Referenced Citations (3)
Number |
Date |
Country |
2342758 |
Oct 1975 |
DEX |
46-409309 |
Aug 1961 |
JPX |
54-106313 |
Aug 1979 |
JPX |
Non-Patent Literature Citations (1)
Entry |
Chem. Abstracts, vol. 92, No. 155910v, (1980). |
Continuations (1)
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Number |
Date |
Country |
Parent |
229562 |
Feb 1981 |
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