This application claims priority under 35 U.S.C. § 119(a) on Patent Application No(s). 112100588 filed in Taiwan, R.O.C. on Jan. 6, 2023, the entire contents of which are hereby incorporated by reference.
The present disclosure is related to a heat transfer fluid for thermal management, a thermal management device and a battery thermal management system.
With the development of clean energy, new energy vehicles (NEVs) will gradually replace traditional fuel vehicles. Lithium batteries, as a widely known power source for NEVs, are affected by temperature in terms of charging and discharging efficiency, capacity, safety and service life. If the battery temperature is overly high or low, it will lead to the degradation of battery performance, making the system fail prematurely or even cause fire and explosion accidents. Therefore, an effective thermal management for lithium batteries is an important issue to be solved in this technical field.
At present, the thermal management for a battery pack consisting of multiple lithium cells includes, but not limited to, air thermal management, liquid thermal management, and phase change material thermal management. Since the liquid thermal management features high thermal conductivity and high heat exchange rate, it is helpful to achieve uniform temperature distribution of the battery pack.
Recently, due to the increasing demand for heat exchange efficiency, a thermal management configuration including additional heat pipe(s) in a liquid cooling system has attracted extensive attention.
According to one embodiment of the present disclosure, a heat transfer fluid for thermal management includes a liquid carrier and a gas generation substance. The gas generation substance is distributed in the liquid carrier. The gas generation substance includes at least one of two-dimensional nanomaterial and three-dimensional nanomaterial.
According to another embodiment of the present disclosure, a thermal management device includes a pulsating heat pipe and a heat transfer fluid. The heat transfer fluid is provided in the pulsating heat pipe, and the heat transfer fluid includes a liquid carrier and a gas generation substance. The gas generation substance is distributed in the liquid carrier. The gas generation substance includes at least one of two-dimensional nanomaterial and three-dimensional nanomaterial.
According to still another embodiment of the present disclosure, a battery thermal management system includes a battery container, a pulsating heat pipe and a heat transfer fluid. The pulsating heat pipe is disposed in the battery container. The heat transfer fluid is provided in the pulsating heat pipe, and the heat transfer fluid includes a liquid carrier and a gas generation substance. The gas generation substance is distributed in the liquid carrier and includes nanomaterial.
In the following detailed description, for purposes of explanation, numerous specific details are set forth in order to provide a thorough understanding of the disclosed embodiments. According to the description, claims and the drawings disclosed in the specification, one skilled in the art may easily understand the concepts and features of the present disclosure. The following embodiments further illustrate various aspects of the present disclosure, but are not meant to limit the scope of the present disclosure.
According to one embodiment of the present disclosure, a battery thermal management system may include a battery container, a pulsating heat pipe and a heat transfer fluid. Please refer to
According to one embodiment of the present disclosure, the pulsating heat pipe may be submerged in a coolant in the battery container. As shown in
The heat generated by the battery cells 12 can be transferred to the pulsating heat pipe 21 through the coolant 11. The heat transfer fluid 22 in the pulsating heat pipe 21 absorbs heat and vaporizes to form multiple bubbles 23 (or vapor plugs) so as to increase the pressure in the evaporation section 210, thereby pushing the heat transfer fluid 22 to move toward the condensation section 220. The vaporized heat transfer fluid 22 at the condensation section 220 condenses into liquid state and forms one or more liquid slugs, thus creating a capillary phenomenon in the pulsating heat pipe 21 and causing the condensed heat transfer fluid 22 to flow back to the evaporation section 210. By back and forth of the heat transfer fluid 22 between the evaporation section 210 and the condensation section 220, the heat exchange can be achieved to dissipate heat from the battery cells 12.
According to one embodiment of the present disclosure, the pulsating heat pipe may include a plurality of bends at the evaporation section. As shown in
According to one embodiment of the present disclosure, the pulsating heat pipe may include a plurality of bends at the condensation section. As shown in
The present disclosure is not limited by the number of the bends 211 and 221 shown in
According to one embodiment of the present disclosure, the battery thermal management system may further include a heat sink. Please refer to
According to one embodiment of the present disclosure, the heat transfer fluid may include a gas generation substance. Specifically, the heat transfer fluid 22 in
The gas generation substance may include a first nanomaterial, and the first nanomaterial includes at least one of two-dimensional nanomaterial and three-dimensional nanomaterial. Specifically, a suitable two-dimensional nanomaterial meets the requirements of single atomic layer thickness and planar shape, such as graphene. Also, a suitable three-dimensional nanomaterial meets the requirement that the dimensions of length, width and height are all in nanometer scale.
The gas generation substance may include at least one of graphene and carbon black. Specifically, said graphene refers to graphene nanowires, graphene nanorods, graphene nanotubes, or graphene nanoribbons. Said carbon black refers to graphite nano-sheets having a thickness of more than two carbon atomic layers. The selection of graphene or carbon black is helpful to simultaneously meet the requirements of high production rate of bubbles or vapor plugs and high thermal conductivity.
A mass percentage concentration of the gas generation substance in the heat transfer fluid 22 may range from 0.001 wt % to 5.0 wt %. In one embodiment, the mass percentage concentration of the gas generation substance in the heat transfer fluid 22 may range from 0.05 wt % to 1.2 wt %. In another embodiment, the mass percentage concentration of the gas generation substance in the heat transfer fluid 22 may range from 0.4 wt % to 1.0 wt %. Herein, the mass percentage concentration of the gas generation substance in the heat transfer fluid 22 may be, for example, 0.05 wt %, 0.1 wt %, 0.3 wt %, 0.4 wt %, 0.45 wt %, 0.5 wt %, 0.75 wt % or 1.0 wt %.
A mass percentage concentration of the first nanomaterial in the heat transfer fluid 22 may range from 0.001 wt % to 5.0 wt %. In one embodiment, the mass percentage concentration of the first nanomaterial in the heat transfer fluid 22 may range from 0.05 wt % to 1.2 wt %. In another embodiment, the mass percentage concentration of the first nanomaterial in the heat transfer fluid 22 may range from 0.4 wt % to 1.0 wt %. Herein, the mass percentage concentration of the first nanomaterial in the heat transfer fluid 22 may be, for example, 0.05 wt %, 0.1 wt %, 0.3 wt %, 0.4 wt %, 0.45 wt %, 0.5 wt %, 0.75 wt % or 1.0 wt %.
A mass percentage concentration of graphene or carbon black in the heat transfer fluid 22 may range from 0.001 wt % to 5.0 wt %. In one embodiment, the mass percentage concentration of graphene or carbon black in the heat transfer fluid 22 may range from 0.05 wt % to 1.2 wt %. In another embodiment, the mass percentage concentration of graphene or carbon black in the heat transfer fluid 22 may range from 0.4 wt % to 1.0 wt %. Herein, the mass percentage concentration of graphene or carbon black in the heat transfer fluid 22 may be, for example, 0.05 wt %, 0.1 wt %, 0.3 wt %, 0.4 wt %, 0.45 wt %, 0.5 wt %, 0.75 wt % or 1.0 wt %.
When the mass percentage concentration of the gas generation substance in the heat transfer fluid 22 is no less than 0.05 wt % or no less than 0.4 wt %, the amount of bubbles or vapor plugs is sufficient for accelerating the flow of the heat transfer fluid 22. When the mass percentage concentration of the gas generation substance in the heat transfer fluid 22 is no more than 1.2 wt % or no more than 1.0 wt %, it is favorable for preventing viscous heat transfer fluid 22 due to excessive gas generation substance, and thus easy to flow.
In addition to the aforementioned two-dimensional nanomaterial and/or three-dimensional nanomaterial, the gas generation substance may further include a second nanomaterial for the auxiliary of heat transfer. The second nanomaterial may be metal oxide nanomaterial or silicon nanomaterial. Herein, the second nanomaterial may be aluminum oxide nanoparticles, copper oxide nanoparticles, iron oxide nanoparticles or silicon nanoparticles.
The mass percentage concentration of the first nanomaterial in the heat transfer fluid 22 may be greater than a mass percentage concentration of the second nanomaterial in the heat transfer fluid 22. In one embodiment, the mass percentage concentration of the second nanomaterial in the heat transfer fluid 22 may range from 0.001 wt % to 0.5 wt %. Herein, the mass percentage concentration of the second nanomaterial in the heat transfer fluid 22 may be, for example, 0.05 wt %, 0.1 wt %, 0.2 wt % or 0.5 wt %.
According to one embodiment of the present disclosure, the heat transfer fluid 22 includes the first nanomaterial and the second nanomaterial, but the present disclosure is not limited thereto. In some other embodiments, the heat transfer fluid 22 may include only the first nanomaterial, which means that only graphene or carbon black is presented in the liquid carrier.
The technical effects of the heat transfer fluid disclosed in the present disclosure will be illustrated by specific embodiments hereafter.
A heat transfer fluid 22 in a pulsating heat pipe 21 according to any embodiment of the present disclosure is provided. The heat transfer fluid 22 includes pure water as a liquid carrier, graphene as a first nanomaterial, and aluminum oxide as a second nanomaterial. The mass percentage concentration of graphene in the heat transfer fluid 22 is 0.5 wt %. The mass percentage concentration of aluminum oxide in the heat transfer fluid 22 is 0.1 wt %.
A heat transfer fluid 22 in a pulsating heat pipe 21 according to any embodiment of the present disclosure is provided. The heat transfer fluid 22 includes pure water as a liquid carrier, graphene as a first nanomaterial, and copper oxide as a second nanomaterial. The mass percentage concentration of graphene in the heat transfer fluid 22 is 0.5 wt %. The mass percentage concentration of copper oxide in the heat transfer fluid 22 is 0.05 wt %.
A heat transfer fluid 22 in a pulsating heat pipe 21 according to any embodiment of the present disclosure is provided. The heat transfer fluid 22 includes pure water as a liquid carrier, and graphene as well as carbon black as a first nanomaterial. The mass percentage concentration of graphene in the heat transfer fluid 22 is 0.45 wt %. The mass percentage concentration of carbon black in the heat transfer fluid 22 is 0.05 wt %.
A heat transfer fluid 22 in a pulsating heat pipe 21 according to any embodiment of the present disclosure is provided. The heat transfer fluid 22 includes pure water as a liquid carrier, and graphene as a first nanomaterial. The mass percentage concentration of graphene in the heat transfer fluid 22 is 0.5 wt %.
A heat transfer fluid 22 in a pulsating heat pipe 21 according to any embodiment of the present disclosure is provided. The heat transfer fluid 22 includes pure water as a liquid carrier, and graphene as a first nanomaterial. The mass percentage concentration of graphene in the heat transfer fluid 22 is 0.75 wt %.
A heat transfer fluid 22 in a pulsating heat pipe 21 according to any embodiment of the present disclosure is provided. The heat transfer fluid 22 includes pure water as a liquid carrier, and graphene as a first nanomaterial. The mass percentage concentration of graphene in the heat transfer fluid 22 is 1.0 wt %.
A heat transfer fluid 22 in a pulsating heat pipe 21 according to any embodiment of the present disclosure is provided. The heat transfer fluid 22 includes pure water as a liquid carrier, graphene as a first nanomaterial, and silicon as a second nanomaterial. The mass percentage concentration of graphene in the heat transfer fluid 22 is 0.5 wt %. The mass percentage concentration of silicon in the heat transfer fluid 22 is 0.05 wt %.
A heat transfer fluid 22 in a pulsating heat pipe 21 according to any embodiment of the present disclosure is provided. The heat transfer fluid 22 includes pure water as a liquid carrier, graphene as well as carbon black as a first nanomaterial, and aluminum oxide as a second nanomaterial. The mass percentage concentration of graphene in the heat transfer fluid 22 is 0.4 wt %. The mass percentage concentration of carbon black in the heat transfer fluid 22 is 0.1 wt %. The mass percentage concentration of aluminum oxide in the heat transfer fluid 22 is 0.1 wt %.
A heat transfer fluid 22 in a pulsating heat pipe 21 according to any embodiment of the present disclosure is provided. The heat transfer fluid 22 includes pure water as a liquid carrier, carbon black as a first nanomaterial, and aluminum oxide as well as iron oxide as a second nanomaterial. The mass percentage concentration of carbon black in the heat transfer fluid 22 is 0.3 wt %. The mass percentage concentration of aluminum oxide in the heat transfer fluid 22 is 0.1 wt %. The mass percentage concentration of iron oxide in the heat transfer fluid 22 is 0.1 wt %.
A heat transfer fluid 22 in a pulsating heat pipe 21 according to any embodiment of the present disclosure is provided. The heat transfer fluid 22 includes pure water as a liquid carrier, carbon black as a first nanomaterial, and iron oxide as well as silicon as a second nanomaterial. The mass percentage concentration of carbon black in the heat transfer fluid 22 is 0.3 wt %. The mass percentage concentration of iron oxide in the heat transfer fluid 22 is 0.1 wt %. The mass percentage concentration of silicon in the heat transfer fluid 22 is 0.1 wt %.
Pure water in a pulsating heat pipe 21 according to any embodiment of the present disclosure is provided. There is no nanomaterial in the water.
The mass percentage concentration of nanomaterial in the heat transfer fluid, the maximum heat flux of the heat transfer fluid, and the heat transfer coefficient of the heat transfer fluid in each embodiment (EM) and comparative example can be referred to TABLE 1 below.
According to the present disclosure, by adding the gas generation substance, a large amount of bubbles or vapor plugs can be generated in the heat transfer fluid in a short period of time to facilitate the movement of the liquid carrier, allowing the heat transfer fluid to flow quickly from the evaporation section to the condensation section, thereby enhancing heat exchange efficiency. Please refer to
According to the present disclosure, the gas generation substance is helpful to enhance the heat exchange efficiency of the thermal management device, which in turn facilitates a uniform temperature distribution in the battery thermal management system.
It will be apparent to those skilled in the art that various modifications and variations can be made to the present disclosure. It is intended that the specification and examples be considered as exemplary embodiments only, with a scope of the disclosure being indicated by the following claims and their equivalents.
Number | Date | Country | Kind |
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112100588 | Jan 2023 | TW | national |