1. Field of the Invention
The disclosure relates to a low pressure drop heat transfer unit for process fluids.
2. Description of the Related Art
Various catalytic conversion processes are known in the petrochemical industry. For example, the catalytic reforming of a hydrocarbon feedstream (e.g., a naphtha feedstream) to produce aromatics (e.g., benzene, toluene, and xylenes) is described in U.S. Patent Application Publication Nos. 2012/0277501, 2012/0277502, 2012/0277503, 2012/0277504, and 2012/0277505. The catalytic dehydrogenation of a paraffin stream to yield olefins is described in U.S. Pat. No. 8,282,887.
Catalytic reforming and catalytic dehydrogenation processes are endothermic and therefore, heat must be added to maintain the temperature of the reactions. U.S. Patent Application Publication No. 2012/0275974 describes the use of interbed heaters to maintain the temperature of reaction in the catalytic reactor of a reforming process. Example heaters for process fluids can also be found in U.S. Pat. Nos. 8,176,974 and 7,954,544.
Aromatics yield from a catalytic reforming unit and olefin yield from a catalytic dehydrogenation unit increase, while yield of undesirable products from competing cracking reactions decreases, with lessening operating pressure. Thus, it may be advantageous to minimize reaction zone operating pressure.
The hot residence time of a process stream before the product stream leaves a reactor (also known as hot volume) can also be critical to the catalytic selectivity to desired products for thermally sensitive processes such as catalytic reforming and catalytic dehydrogenation. Hot residence time reduction can be critical in reactor circuit non-catalyst volumes in order to prevent yield loss (aromatics or olefins) from competing thermal cracking reactions.
Thus, the design of heaters used in catalytic reforming and catalytic dehydrogenation processes to heat the feed upstream of each reactor can be guided by two criteria, pressure drop and hot residence time. While the overall low operating pressure benefits the yields from the processes, it is more beneficial to use the available pressure drop diligently in a reactor circuit. The use of the available pressure drop further upstream in the reactor circuit is least detrimental. The use of higher pressure drop further upstream in the reactor circuit reduces yields to a lesser extent. However, it reduces the hot residence time (thus thermal cracking) in the upstream heaters where the process streams are often more susceptible to thermal cracking than in the downstream heaters.
Thermal expansion and contraction in heater coils is yet another design consideration. Specifically, the heater coils must be able to withstand high process temperatures and metallurgical changes and mechanical stress.
Therefore, what is needed is an improved heat transfer unit for process fluids wherein the heat transfer unit provides low pressure drop but also the flexibility to withstand thermal expansion/contraction in the heater coils.
The foregoing needs are met by a heat transfer unit for process fluids. The heat transfer unit includes an inlet manifold; an outlet manifold spaced from the inlet manifold; and a plurality of conduits coupling the inlet manifold to the outlet manifold, wherein at least one of the conduits is coupled to the outlet manifold at an oblique angle.
In one version of the heat transfer unit, at least one of the conduits includes a L-Coil.
In another version of the heat transfer unit, at least one of the conduits includes a D-Coil.
In another version of the heat transfer unit, at least one of the conduits includes a coil having a plurality of generally C-shaped sections.
In another version of the heat transfer unit, at least one of the conduits is coupled to the outlet manifold at an angle between about five and eighty-five degrees.
In another version of the heat transfer unit, at least one of the conduits is coupled to the outlet manifold at an angle between about thirty and sixty degrees.
In another version of the heat transfer unit, each of the conduits is coupled to the outlet manifold at an oblique angle.
In another version of the heat transfer unit, each conduit includes a section arranged in an interior space of a heater box and wherein at least one heater is arranged in the interior space of the heater box.
In another aspect, the invention provides an L-Coil heat transfer unit for process fluids. The L-Coil heat transfer unit includes an inlet manifold; an outlet manifold spaced from the inlet manifold; and an L-Coil coupled between the inlet manifold and the outlet manifold. The L-Coil includes a horizontal leg and a vertical leg, wherein the horizontal leg is coupled to the outlet manifold at an oblique angle such that a flow aperture formed therebetween defines an oblong profile.
In one version of the L-Coil heat transfer unit, a plurality of L-Coils are coupled to the outlet manifold at an oblique angle.
In another version of the L-Coil heat transfer unit, the L-Coil is arranged at between about a thirty and sixty degree angle relative to the outlet manifold.
In another version of the L-Coil heat transfer unit, the L-Coil is arranged at between about a five and eighty-five degree angle relative to the outlet manifold.
The L-Coil heat transfer unit can further comprise a heater arranged substantially adjacent a bottom of the L-Coil heat transfer unit.
The L-Coil heat transfer unit can include a section arranged in an interior space of a heater box.
In another aspect, the invention provides a D-Coil heat transfer unit for process fluids. The D-Coil heat transfer unit includes an inlet manifold; an outlet manifold spaced from the inlet manifold; and a D-Coil coupled between the inlet manifold and the outlet manifold, The D-Coil includes an inlet section and an outlet section, and the inlet section is coupled to the inlet manifold at an oblique angle, and the outlet section is coupled to the outlet manifold at an oblique angle.
In one version of the D-Coil heat transfer unit, a flow aperture formed between the outlet section and the outlet manifold defines an oblong profile.
In another version of the D-Coil heat transfer unit, a plurality of D-Coils are coupled to the inlet manifold at an oblique angle and are coupled to the outlet manifold at an oblique angle.
In another version of the D-Coil heat transfer unit, the inlet section is arranged at between about a thirty and sixty degree angle relative to the inlet manifold, and the outlet section is arranged at between about a thirty and sixty degree angle relative to the outlet manifold.
In another version of the D-Coil heat transfer unit, the D-Coil includes a section arranged in an interior space of a heater box. At least one heater can be arranged in the interior space of the heater box.
In a low pressure drop heater design, the heater manifold may account for close to 50% of the total pressure heater pressure drop. The manifold pressure drop is mainly due to the entrance and exit frictional losses from heater tubes to the heater outlet and inlet.
The invention provides a heat transfer unit with an L-coil design that decreases pressure drop. In one non-limiting example of the heat transfer unit, an angled entrance to the heater outlet manifold is used with the L-coil design. An angled entrance results in an elliptical opening into the manifold. This lowers the inlet velocity and the velocity is in the same direction as the process fluid flow resulting in an additional decrease in a pressure drop. An angled inlet into the heater outlet manifold also provides a longer horizontal arm in an L-heater coil. This in turn gives more flexibility to the heater coil for vertical compression and tension. A longer horizontal arm of the L-Coil can provide better flexibility in vertical movements.
The invention also provides a heat transfer unit with a D-Coil to integrate the benefits for low pressure drop design with an improved flexibility. A D-coil achieves an added reduction in pressure drop by having an angled entry into and exit from, inlet and outlet manifolds, respectively. In addition, a D-Coil provides a better flexibility for vertical movements in a heater coil.
The invention demonstrates that an angled connection from heater conduits to the manifold is preferably used and more preferably, an angled connection is used at an outlet manifold connection. This provides pressure drop reduction due to a bigger opening at the connection (thus lower frictional loss) and less turbulence (via same flow direction) with more flexibility for vertical movements. The pressure drop reduction by angled connection may be more at the outlet manifold connection than the inlet connection due to higher designed velocity at the outlet. The pressure reduction benefit can be more prominent in the low pressure drop heater design. The design can also be used for higher pressure drop heater designs. However, yield benefits from reduced heater drop may be less.
It is therefore an advantage of the invention to provide a low pressure drop heat transfer unit for process fluids.
It is another advantage of the invention to provide a heat transfer unit for process fluids in a process where pressure drop affects product yields.
These and other features, aspects, and advantages of the present invention will become better understood upon consideration of the following detailed description, drawings, and appended claims.
Like reference numerals will be used to refer to like parts from Figure to Figure in the following description of the drawings.
Catalytic reactor systems may use U-Coil heaters for heating fresh feed and reheating feed between reactors. A U-Coil style heater may be desirable due to low process side pressure drop. An example U-Coil style heat transfer unit 10 is shown in
Alternatively, catalytic reactor systems may use L-Coil heaters for heating fresh feed and reheating feed between reactors. An example L-Coil style heat transfer unit 30 is shown in
The L-Coils 62 are preferably welded to the inlet manifold 54 and the outlet manifold 58 to provide a hermetic seal. As is clearly visible in
As shown in
Turning to
In one embodiment, the length of the inlet manifold 54 and outlet manifold 58 in the longitudinal direction is about fifteen meters (about 50 feet) or more. In other embodiments, the installation may be smaller or larger, as desired. The L-Coils 62 may be spaced apart by about fifty centimeters (about 10 feet). In other embodiments, more or less spacing may be desirable. The L-Coil heat transfer unit 50 may include up to about eighteen-hundred (1800) L-Coils 62. In other embodiments, the L-Coil heat transfer unit 50 may include more or less L-Coils 62, as desired.
An additional feature of the L-Coil heat transfer unit 50 is the ability to position a burner 78 in a variety of locations and arrangements. As shown in
The L-Coil heat transfer unit 50 provides an advantageous fluid flow pattern (shown in dash lines in
Turning now to
Turning now to
Turning to
The illustrated inlet section 116 is arranged at an oblique angle relative to a longitudinal axis of the inlet manifold 104. In the illustrated embodiment, the inlet section 116 is arranged at about a forty-five degree angle (45°) relative to the longitudinal axis of the inlet manifold 104. In other embodiments, the inlet section 116 is arranged at between about thirty and sixty degrees (30-60°) relative to the longitudinal axis of the inlet manifold 104. In still other embodiments, the inlet section 116 is arranged at between about twenty and seventy degrees (20-70°) relative to the longitudinal axis of the inlet manifold 104. In still other embodiments, the inlet section 116 is arranged at between about five and eighty-five degrees (5-85°) relative to the longitudinal axis of the inlet manifold 104.
The outlet section 122 is arranged at an oblique angle relative to a longitudinal axis of the outlet manifold 108. In the illustrated embodiment, the outlet section 122 is arranged at about a forty-five degree angle (45°) relative to the longitudinal axis of the outlet manifold 108. In other embodiments, the outlet section 122 is arranged at between about thirty and sixty degrees (30-60°) relative to the longitudinal axis of the outlet manifold 108. In other embodiments, the outlet section 122 is arranged at between about twenty and seventy degrees (20-70°) relative to the longitudinal axis of the outlet manifold 108. In still other embodiments, the outlet section 122 is arranged at between about five and eighty-five degrees (5-85°) relative to the longitudinal axis of the outlet manifold 108.
As a result of the oblique relation between the D-Coils 112 and the inlet and outlet manifolds 104, 108, the flow apertures formed at the junction between the D-Coils 112 and the inlet and outlet manifolds 104, 108 are oval or oblong or elliptical as described above with respect to apertures 74.
The D-Coil heat transfer unit 100 provides an advantageous fluid flow pattern (shown in dash lines in
Turning to
The illustrated inlet section 216 is arranged at an oblique angle relative to a longitudinal axis of the inlet manifold 204. In the illustrated embodiment, the junction of the inlet section 216 is arranged at about a forty-five degree angle (45°) relative to the longitudinal axis of the inlet manifold 204. See angle C in
The outlet section 222 is arranged at an oblique angle relative to a longitudinal axis of the outlet manifold 208. In the illustrated embodiment, the junction of the outlet section 222 is arranged at about a forty-five degree angle (45°) relative to the longitudinal axis of the outlet manifold 208. See angle D in
As a result of the oblique relation between the Triple C-Coils 210 and the inlet and outlet manifolds 204, 208, the flow apertures formed at the junction between the Triple C-Coils 210 and the inlet and outlet manifolds 204, 208 are oval or oblong or elliptical as described above with respect to apertures 74.
The Triple C-Coil heat transfer unit 200 provides an advantageous fluid flow pattern that reduces the fluid friction and therefore reduces the pressure drop through the Triple C-Coil heat transfer unit 200 compared to other heat transfer solutions. In other embodiments, other flow patterns are feasible.
In one aspect, the invention provides a catalytic dehydrogenation process that includes passing a hydrocarbon feed stream through any of heat transfer units 10, 30, 50, 50′, 50″, 100, 100′, 200, and then passing the heated hydrocarbon feed stream and a catalyst into a reactor thereby creating a product stream.
In another aspect, the invention provides, a catalytic reforming process that includes passing a hydrocarbon feed stream through any of heat transfer units 10, 30, 50, 50′, 50″, 100, 100′, 200, and then passing the heated hydrocarbon feed stream and a catalyst into a reactor thereby creating a product stream.
Thus, the invention provides a heat transfer unit for process fluids. While use of the heat transfer unit is not limited to any process, the heat transfer unit can be particularly beneficial in heating process fluids in: (i) the catalytic reforming of a hydrocarbon feedstream (e.g., a naphtha feedstream) to produce aromatics (e.g., benzene, toluene and xylenes) (see, e.g., U.S. Patent Application Publication Nos. 2012/0277501, 2012/0277502, 2012/0277503, 2012/0277504, and 2012/0277505); and (ii) the catalytic dehydrogenation of a paraffin stream to yield olefins (see, e.g., U.S. Pat. No. 8,282,887).
Although the invention has been described in considerable detail with reference to certain embodiments, one skilled in the art will appreciate that the present invention can be practiced by other than the described embodiments, which have been presented for purposes of illustration and not of limitation. Therefore, the scope of the appended claims should not be limited to the description of the embodiments contained herein.