The present invention now will be described more fully hereinafter with reference to the accompanying drawings, in which a preferred embodiment of the invention is shown. This invention may, however, be embodied in many different forms and should not be construed as limited to the embodiment set forth herein; rather, this embodiment is provided so that this disclosure will be thorough and complete, and will fully convey the scope of the invention to those skilled in the art.
The present inventors have recognized that the breakdown voltage of a semiconductor junction diode device can be increased by reducing the overall impurity concentration in the starting substrate or wafer. Without being bound to any particular theory or model, the following analysis is presented to facilitate an understanding of the present invention.
As discussed, for example, in chapter 5 of Solid State Electronic Devices, 5th Edition, B. Streeman et al., Pearson Education, Inc., 2004, the contact potential Vo across a pn junction of width W0 can be expressed as:
where ε0 is the electric field across the junction.
The breakdown voltage VB that arises under a certain critical electrical field εC thus can be expressed as
where WB is the depletion width at device breakdown and WB>W0
As shown in Eq. (5-22) of Solid State Electronic Devices the equilibrium width W0 of the junction can be expressed as
where Na and Nd are the doping concentrations of acceptor ions and donor ions, respectively.
Accordingly, VB can be expressed as:
In the case of a one sided abrupt junction in which one side is more heavily doped (i.e., P+N) Na>>Nd then (1-3) and be approached by following Eq.
In the present invention the pn junction is defined by a more lightly doped substrate and a more heavily doped upper base region (described below). Accordingly, Nd represents the doping concentration of donor ions in the substrate, which may therefore be referred to as the bulk concentration of the substrate. The present invention reduces this bulk concentration in order to increase the breakdown voltage of the resulting semiconductor diode device.
The P-type dopants (e.g., boron) add positive charges to the semiconductor material, while the N-type dopants (e.g., phosphorus) add negative charges to the semiconductor materials. Preferably, the P+ or N++concentration approximately encompasses the range of 1×1019 to 1×1021 atoms/cm3 and the P+ and N+ concentration approximately encompasses the range of 1×1015 to 1×1020 atoms/cm3. The P− to P (or N− to N) range of dopant concentration approximately encompasses the range of 1×1014 to 1×1016 atoms/cm3. The concentration in the regions may vary depending on what depth of the region is examined. Thus, these concentrations are provided only in approximate ranges.
If the substrate 1 is initially doped so that it has a given impurity concentration of a given impurity type (the “background concentration” of the substrate), the present invention introduces into the substrate 1 a lower impurity concentration of the opposite impurity type. In this way the active bulk concentration NB discussed above is reduced, thereby increasing the breakdown voltage VB of the device. In contrast, in the conventional device of
The semiconductor junction diode device of the present invention may be fabricated in accordance with well-known techniques including a variety of different growth or deposition techniques, as well as different photolithographic and implantation techniques. That is, the pn junctions defined by the substrate 1 and the upper base 2 and the lower base 5 may be formed in a conventional manner after introducing an impurity into the substrate 1 that has a conductivity type that is opposite to the conductivity type initially present in the substrate 1.
By way of example, computer simulations have demonstrated that a diode device having a breakdown voltage of 130V can be fabricated from a substrate initially doped with arsenic and having a resistivity of 0.5 ohms/sq (corresponding to an impurity concentration of 1.14×1016/cc). This result can be achieved by introducing boron into the substrate by ion implantation at a dosage of 1×1013 ions/cc with an energy of 20 Kev and a drive-in for about 1400 minutes at 1265° C. Without the introduction of boron, the diode device would have a breakdown voltage of only about 58V.
The embodiment of the invention depicted in
Although various embodiments are specifically illustrated and described herein, it will be appreciated that modifications and variations of the present invention are covered by the above teachings and are within the purview of the appended claims without departing from the spirit and intended scope of the invention. For example, the method of the present invention may be used to form a semiconductor junction diode in which the conductivities of the various semiconductor regions are reversed from those described herein.