The present application is related to the following patent applications, each of which is assigned to the assignee of the present patent application: (1) U.S. patent application Ser. No. 12/181,436, entitled “A Magnetic Electrical Device” and filed on Jul. 29, 2008 and (2) U.S. Provisional Patent Application Ser. No. 61/080,115, entitled “High Performance High Current Power Inductor” and filed on Jul. 11, 2008. Each of the above related applications are incorporated by reference herein.
The invention relates generally to electronic components and methods of manufacturing these components and, more particularly, to inductors, transformers, and the methods of manufacturing such items.
Typical inductors may include toroidal cores and shaped-cores, including a shield core and drum core, U core and I core, E core and I core, and other matching shapes. The typical core materials for these inductors are ferrite or normal powder core materials, which include iron (Fe), Sendust (Al—Si—Fe), MPP (Mo—Ni—Fe), and HighFlux (Ni—Fe). The inductors typically have a conductive winding wrapped around the core, which may include, but is not limited to a magnet wire coil that may be flat or rounded, a stamped copper foil, or a clip. The coil may be wound on the drum core or other bobbin core directly. Each end of the winding may be referred to as a lead and is used for coupling the inductor to an electrical circuit. The winding may be preformed, semi-preformed, or non-preformed depending upon the application requirements. Discrete cores may be bound together through an adhesive.
With the trend of power inductors going toward higher current, a need exists for providing inductors having more flexible form factors, more robust configurations, higher power and energy densities, higher efficiencies, and tighter inductance and Direct Current Resistance (“DCR”) tolerance. DC to DC converters and Voltage Regulator Modules (“VRM”) applications often require inductors having tighter DCR tolerances, which is currently difficult to provide due to the finished goods manufacturing process. Existing solutions for providing higher saturation current and tighter tolerance DCR in typical inductors have become very difficult and costly and do not provide the best performance from these typical inductors. Accordingly, the current inductors are in need for such improvements.
To improve certain inductor characteristics, toroidal cores have recently been manufactured using an amorphous powder material for the core material. Toroidal cores require a coil, or winding, to be wound onto the core directly. During this winding process, the cores may crack very easily, thereby causing the manufacturing process to be difficult and more costly for its use in surface-mount technology. Additionally, due to the uneven coil winding and coil tension variations in toroidal cores, the DCR is not very consistent, which is typically required in DC to DC converters and VRM. Due to the high pressures involved during the pressing process, it has not been possible to manufacture shaped-cores using amorphous powder materials.
Due to advancements in electronic packaging, the trend has been to manufacture power inductors having miniature structures. Thus, the core structure must have lower and lower profiles so that they may be accommodated by the modern electronic devices, some of which may be slim or have a very thin profile. Manufacturing inductors having a low profile has caused manufactures to encounter many difficulties, thereby making the manufacturing process expensive.
For example, as the components become smaller and smaller, difficulty has arisen due to the nature of the components being hand wound. These hand wound components provide for inconsistencies in the product themselves. Another encountered difficulty includes the shape-cores being very fragile and prone to core cracking throughout the manufacturing process. An additional difficulty is that the inductance is not consistent due to the gap deviation between the two discrete cores, including but not limited to drum cores and shielded cores, ER cores and I cores, and U cores and I cores, during assembly. A further difficulty is that the DCR is not consistent due to uneven winding and tension during the winding process. These difficulties represent examples of just a few of the many difficulties encountered while attempting to manufacture inductors having a miniature structure.
Manufacturing processes for inductors, like other components, have been scrutinized as a way to reduce costs in the highly competitive electronics manufacturing business. Reduction of manufacturing costs is particularly desirable when the components being manufactured are low cost, high volume components. In a high volume component, any reduction in manufacturing cost is, of course, significant. It may be possible that one material used in manufacturing may have a higher cost than another material. However, the overall manufacturing cost may be less by using the more costly material because the reliability and consistency of the product in the manufacturing process is greater than the reliability and consistency of the same product manufactured with the less costly material. Thus, a greater number of actual manufactured products may be sold, rather than being discarded. Additionally, it also is possible that one material used in manufacturing a component may have a higher cost than another material, but the labor savings more than compensates for the increase in material costs. These examples are just a few of the many ways for reducing manufacturing costs.
It has become desirable to provide a magnetic component having a core and winding configuration that can allow one or more of the following improvements, a more flexible form factor, a more robust configuration, a higher power and energy density, a higher efficiency, a wider operating frequency range, a wider operating temperature range, a higher saturation flux density, a higher effective permeability, and a tighter inductance and DCR tolerance, without substantially increasing the size of the components and occupying an undue amount of space, especially when used on circuit board applications. It also has become desirable to provide a magnetic component having a core and winding configuration that can allow low cost manufacturing and achieves more consistent electrical and mechanical properties. Furthermore, it is desirable to provide a magnetic component that tightly controls the DCR over large production lot sizes.
A magnetic component and a method of manufacturing such a component is described. The magnetic component may include, but is not limited to, an inductor or a transformer. The method comprises the steps of providing at least one shaped-core fabricated from an amorphous powder material, coupling at least a portion of at least one winding to the at least one shaped-core, and pressing the at least one shaped-core with at least a portion of the at least one winding. The magnetic component comprises at least one shaped-core fabricated from an amorphous powder material and at least a portion of at least one winding coupled to the at least one shaped-core, wherein the at least one shaped-core is pressed to at least a portion of the at least one winding. The winding may be preformed, semi-preformed, or non-preformed and may include, but is not limited to, a clip or a coil. The amorphous powder material may be an iron-based amorphous powder material or a nanoamorphous powder material.
According to some aspects, two shaped-cores are coupled together with a winding positioned therebetween. In these aspects, one of the shaped-cores is pressed, and the winding is coupled to the pressed shaped-core. The other shaped-core is coupled to the winding and the pressed shaped-core and pressed again to form the magnetic component. The shaped-core may be fabricated from an amorphous powder material or a nanoamorphous powder material.
According to other exemplary aspects, the amorphous powder material is coupled around at least one winding. In these aspects, the amorphous powder material and the at least one winding are pressed together to form the magnetic component, wherein the magnetic component has a shaped-core. According to these aspects, the magnetic component may have a single shaped-core and a single winding, or it may comprise a plurality of shaped-cores within a single structure, wherein each of the shaped-cores has a corresponding winding. Alternatively, the shaped-core may be fabricated from a nanoamorphous powder material.
These and other aspects, objects, features, and advantages of the invention will become apparent to a person having ordinary skill in the art upon consideration of the following detailed description of illustrated exemplary embodiments, which include the best mode of carrying out the invention as presently perceived.
The foregoing and other features and aspects of the invention will be best understood with reference to the following description of certain exemplary embodiments of the invention, when read in conjunction with the accompanying drawings, wherein:
Referring to
The ER core 110 is generally square or rectangular in shape and has a base 112, two side walls 114, 115, two end walls 120, 121, a receptacle 124, and a centering projection or post 126. The two side walls 114, 115 extend the entire longitudinal length of the base 112 and have an exterior surface 116 and an interior surface 117, wherein the interior surface 117 is proximate to the centering projection 126. The exterior surface 116 of the two side walls 114, 115 are substantially planar, while the interior surface 117 of the two side walls are concave. The two end walls 120, 121 extend a portion of the width of the base 112 from the ends of each side wall 114, 115 of the base 112, such that a gap 122, 123 is formed in each of the two end walls 120, 121, respectively. This gap 122, 123 may be formed substantially in the center of each of the two end walls 120, 121 such that the two side walls 114, 115 are mirror images of one another. The receptacle 124 is defined by the two side walls 114, 115 and the two end walls 120, 121. The centering projection 126 may be centrally located in the receptacle 124 of the ER core 110 and may extend upwardly from the base 112 of the ER core 110. The centering projection 126 may extend to a height that is substantially the same as the height of the two side walls 114, 115 and the two end walls 120, 121, or the height may extend less than the height of the two side walls 114, 115 and the two end walls 120, 121. As such, the centering projection 126 extends into an inner periphery 132 of the preformed coil 130 to maintain the preformed coil 130 in a fixed, predetermined, and centered position with respect to the ER core 110. Although the ER core is described as having a symmetrical core structure in this embodiment, the ER core may have an asymmetrical core structure without departing from the scope and spirit of the exemplary embodiment.
The preformed coil 130 has a coil having one or more turns, and two terminals 134, 136, or leads, that extend from the preformed coil 130 at 180° from one another. The two terminals 134, 136 extend in an outwardly direction from the preformed coil 130, then in an upward direction, and then back in an inward direction towards the preformed coil 130; thereby each forming a U-shaped configuration. The preformed coil 130 defines the inner periphery 132 of the preformed coil 130. The configuration of the preformed coil 130 is designed to couple the preformed coil 130 to the ER core 110 via the centering projection 126, such that the centering projection 126 extends into the inner periphery 132 of the preformed coil 130. The preformed coil 130 is fabricated from copper and is plated with nickel and tin. Although the preformed coil 130 is made from copper and has nickel and tin plating, other suitable conductive materials, including but not limited to gold plating and soldering, may be utilized in fabricating the preformed coil 130 and/or the two terminals 134, 136 without departing from the scope and spirit of the invention. Additionally, although a preformed coil 130 has been depicted as one type of winding that may be used within this embodiment, other types of windings may be utilized without departing from the scope and spirit of the invention. Additionally, although this embodiment utilizes a preformed coil 130, semi-preformed windings, and non-preformed windings may also be used without departing from the scope and spirit of the invention. Further, although the terminals 134, 136 have been described in a particular configuration, alternative configurations may be used for the terminals without departing from the scope and spirit of the invention. Moreover, the geometry of the preformed coil 130 may be circular, square, rectangular, or any other geometric shape without departing from the scope and spirit of the invention. The interior surface of the two side walls 114, 115 and the two end walls 120, 121 may be reconfigured accordingly to correspond to the geometry of the preformed coil 130, or winding. In the event the coil 130 has multiple turns, insulation between the turns may be required. The insulation may be a coating or other type of insulator that may be placed between the turns.
The I core 150 is generally square or rectangular in shape and substantially corresponds to the footprint of the ER core 110. The I core 150 has two opposing ends 152, 154, wherein each end 152, 154 has a recessed portion 153, 155, respectively, to accommodate an end portion of the terminals 134, 136. The recessed portions 153, 155 are substantially the same width, or slightly larger in width, when compared to the width of the end portion of the terminals 134, 136.
In an exemplary embodiment, the ER core 110 and the I core 150 are both fabricated from an amorphous powder core material. According to some embodiments, the amorphous powder core material can be an iron-based amorphous powder core material. One example of the iron-based amorphous powder core material comprises approximately 80% iron and 20% other elements. According to alternative embodiments, the amorphous powder core material can be a cobalt-based amorphous powder core material. One example of the cobalt-based amorphous powder core material comprises approximately 75% cobalt and 25% other elements. Still, according to some other alternative embodiments, the amorphous powder core material can be a nanoamorphous powder core material.
This material provides for a distributed gap structure, wherein the binder material behaves as gaps within the fabricated iron-based amorphous powder material. An exemplary material is manufactured by Amosense in Seoul, Korea and sold under product number APHxx (Advanced Powder Core), where xx represents the effective permeability of the material. For example, if the effective permeability for the material is 60, the part number is APH60. This material is capable of being used for high current power inductor applications. Additionally, this material may be used with higher operating frequencies, typically in the range of about 1 MHz to about 2 MHz, without producing abnormal heating of the inductor 100. Although the material may be used in the higher frequency range, the material may be used in lower and higher frequency ranges without departing from the scope and spirit of the invention. The amorphous powder core material can provide a higher saturation flux density, a lower hysteresis core loss, a wider operating frequency range, a wider operating temperature range, better heat dissipation and a higher effective permeability. Additionally, this material can provide for a lower loss distributed gap material, which thereby can maximize the power and energy density. Typically, the effective permeability of shaped-cores is not very high due to pressing density concerns. However, use of this material for the shaped-cores can allow a much higher effective permeability than previously available. Alternatively, the nanoamorphous powder material can allow up to three times higher permeability when compared to the permeability of an iron-based amorphous powder material.
As illustrated in
The preformed clip 230 has two terminals 234, 236, or leads, that may be coupled around the mistake proof I core 250 by positioning the preformed clip 230 at the removed portions 257, 261 and sliding the preformed clip 230 towards the non-removed portions 258, 262 until the preformed clip 230 may not be moved further. The preformed clip 230 can allow better DCR control, when compared to a non-preformed clip, because bending and cracking of platings is greatly reduced in the manufacturing process. The mistake proof I core 250 enables the preformed clip 230 to be properly positioned so that the U core 210 may be quickly, easily, and correctly coupled to the mistake proof I core 250. As shown in
The preformed clip 230 is fabricated from copper and is plated with nickel and tin. Although the preformed clip 230 is made from copper and has nickel and tin plating, other suitable conductive materials, including but not limited to gold plating and soldering, may be utilized in fabricating the preformed clip 230 and/or the two terminals 234, 236 without departing from the scope and spirit of the invention. Additionally, although a preformed clip 230 is used in this embodiment, the clip 230 may be partially preformed or not preformed without departing from the scope and spirit of the invention. Furthermore, although a preformed clip 230 is depicted in this embodiment, any form of winding may be used without departing from the scope and spirit of the invention.
The removed portions 257, 261 from the mistake proof I core 250 may be dimensioned such that a symmetrical U core or an asymmetrical U core, which are described with respect to
In an exemplary embodiment, the U core 210 and the I core 250 are both fabricated from an amorphous powder core material, which is the same material as described above in reference to the ER core 110 and the I core 150. According to some embodiments, the amorphous powder core material can be an iron-based amorphous powder core material. Additionally, a nanoamorphous powder material may also be used for these core materials. As illustrated in
In an exemplary embodiment, the bead core 410 is fabricated from an amorphous powder core material, which is the same material as described above in reference to the ER core 110 and the I core 150. According to some embodiments, the amorphous powder core material can be an iron-based amorphous powder core material. Additionally, a nanoamorphous powder material may also be used for these core materials.
The semi-preformed clip 430 comprises two terminals, or leads, 434, 436 at opposing two ends 416, 418 and may be coupled to the bead core 410 by having a portion of the semi-preformed clip 430 pass centrally within the bead core 410 and having the two terminals 434, 436 wrap around the two ends 416, 418 of the bead core 410. The semi-preformed clip 430 can allow better DCR control, when compared to a non-preformed clip, because bending and cracking of platings is greatly reduced in the manufacturing process.
The semi-preformed clip 430 is fabricated from copper and is plated with nickel and tin. Although the semi-preformed clip 430 is made from copper and has nickel and tin plating, other suitable conductive materials, including but not limited to gold plating and soldering, may be utilized in fabricating the semi-preformed clip 430 without departing from the scope and spirit of the invention. Additionally, although a semi-preformed clip 430 is used in this embodiment, the clip 430 may be not preformed without departing from the scope and spirit of the invention. Furthermore, although a semi-preformed clip 430 is depicted in this embodiment, any form of winding may be used without departing from the scope and spirit of the invention.
As illustrated in
According to an exemplary embodiment, the amorphous powder core material may be initially formed into a sheet and then wrapped or rolled around the semi-preformed clip 430. Upon rolling the amorphous powder core material around the semi-preformed clip 430, the amorphous powder core material and the semi-preformed clip 430 can then be pressed at high pressures, thereby forming the power inductor 400. The press molding removes the physical gap that is generally located between the semi-preformed clip 430 and the bead core 410 by having the bead core 410 form molded around the semi-preformed clip 430.
According to another exemplary embodiment, the amorphous powder core material and the semi-preformed clip 430 may be positioned within a mold (not shown), such that the amorphous powder core material surrounds at least a portion of the semi-preformed clip 430. The amorphous powder core material and the semi-preformed clip 430 can then be pressed at high pressures, thereby forming the power inductor 400. The press molding removes the physical gap that is generally located between the semi-preformed clip 430 and the bead core 410 by having the bead core 410 form molded around the semi-preformed clip 430.
Additionally, other methods may be used to form the inductor described above. In a first alternative method, a bead core may be formed by pressing the amorphous powder core material at high pressures, followed by coupling the winding to the bead core, and then followed by adding additional amorphous powder core material to the bead core so that the winding is disposed between the bead core and at least a portion of the additional amorphous powder core material. The bead core, the winding and the additional amorphous powder core material are then pressed together at high pressures to form the power inductor described in this embodiment. In a second alternative method, two discrete shaped cores may be formed by pressing the amorphous powder core material at high pressures, followed by positioning the winding between the two discrete shaped cores, and then followed by adding additional amorphous powder core material. The two discrete shaped cores, the winding, and the additional amorphous powder core material are then pressed together at high pressures to form the power inductor described in this embodiment. In a third alternative method, injection molding can be used to mold the amorphous powder core material and the winding together. Although a bead core is described in this embodiment, other shaped cores may be utilized without departing from the scope and spirit of the exemplary embodiment.
In an exemplary embodiment, the core material is fabricated from an iron-based amorphous powder core material, which is the same material as described above in reference to the ER core 110 and the I core 150. Additionally, a nanoamorphous powder material may also be used for these core materials.
Each clip 530, 532, 534, 536 has two terminals, or leads, 540 (not shown), 542 at opposing ends and may be coupled to each of the U shaped-cores 510, 515, 520, 525 by having a portion of the clip 530, 532, 534, 536 pass centrally within each of the U shaped-cores 510, 515, 520, 525 and having the two terminals 540 (not shown), 542 of each clip 530, 532, 534, 536 wrap around the two ends 506, 508 of the inductor 500.
The clips 530, 532, 534, 536 are fabricated from copper and are plated with nickel and tin. Although the clips 530, 532, 534, 536 are made from copper and has nickel and tin plating, other suitable conductive materials, including but not limited to gold plating and soldering, may be utilized in fabricating the clips without departing from the scope and spirit of the invention. Additionally, although the clips 530, 532, 534, 536 are depicted in this embodiment, any form of windings may be used without departing from the scope and spirit of the invention.
As illustrated in
According to an exemplary embodiment, the amorphous powder core material may be initially formed into a sheet and then wrapped around the clips 530, 532, 534, 536. Upon wrapping the amorphous powder core material around the clips 530, 532, 534, 536, the amorphous powder core material and the clips 530, 532, 534, 536 can then be pressed at high pressures, thereby forming the U-shaped inductor 500 having a plurality of U shaped-cores 510, 515, 520, 525 formed as a single structure 505. The press molding removes the physical gap that is generally located between the clips 530, 532, 534, 536 and the cores 510, 515, 520, 525 by having the cores 510, 515, 520, 525 form molded around the clips 530, 532, 534, 536.
According to another exemplary embodiment, the amorphous powder core material and the clips 530, 532, 534, 536 may be positioned within a mold (not shown), such that the amorphous powder core material surrounds at least a portion of the clips 530, 532, 534, 536. The amorphous powder core material and the clips 530, 532, 534, 536 can then be pressed at high pressures, thereby forming the U-shaped inductor 500 having a plurality of U shaped-cores 510, 515, 520, 525 formed as a single structure 505. The press molding removes the physical gap that is generally located between the clips 530, 532, 534, 536 and the cores 510, 515, 520, 525 by having the cores 510, 515, 520, 525 form molded around the clips 530, 532, 534, 536.
Additionally, other methods may be used to form the inductor described above. In a first alternative method, a plurality of U-shaped cores may be formed together by pressing the amorphous powder core material at high pressures, followed by coupling the plurality of windings to each of the plurality of U-shaped cores, and then followed by adding additional amorphous powder core material to the plurality of U-shaped cores so that the plurality of windings are disposed between the plurality of U-shaped cores and at least a portion of the additional amorphous powder core material. The plurality of U-shaped cores, the plurality of windings, and the additional amorphous powder core material are then pressed together at high pressures to form the inductor described in this embodiment. In a second alternative method, two discrete shaped cores, wherein each discrete shaped core has a plurality of shaped cores coupled together, may be formed by pressing the amorphous powder core material at high pressures, followed by positioning the plurality of windings between the two discrete shaped cores, and then followed by adding additional amorphous powder core material. The two discrete shaped cores, the plurality of windings, and the additional amorphous powder core material are then pressed together at high pressures to form the inductor described in this embodiment. In a third alternative method, injection molding can be used to mold the amorphous powder core material and the plurality of windings together. Although a plurality of U-shaped cores are described in this embodiment, other shaped cores may be utilized without departing from the scope and spirit of the exemplary embodiment.
Additionally, the plurality of clips 530, 532, 534, 536 may be connected in parallel to each other or in series based upon circuit connections on a substrate (not shown) and depending upon application requirements. Furthermore, these clips 530, 532, 534, 536 may be designed to accommodate multi-phase current, for example, three-phase and four-phase.
Although several embodiments have been disclosed above, it is contemplated that the invention includes modifications made to one embodiment based upon the teachings of the remaining embodiments.
Although the invention has been described with reference to specific embodiments, these descriptions are not meant to be construed in a limiting sense. Various modifications of the disclosed embodiments, as well as alternative embodiments of the invention, will become apparent to persons having ordinary skill in the art upon reference to the description of the invention. It should be appreciated by those having ordinary skill in the art that the conception and the specific embodiments disclosed may be readily utilized as a basis for modifying or designing other structures for carrying out the same purposes of the invention. It should also be realized by those having ordinary skill in the art that such equivalent constructions do not depart from the spirit and scope of the invention as set forth in the appended claims. It is therefore contemplated that the claims will cover any such modifications or embodiments that fall within the scope of the invention.
Number | Name | Date | Kind |
---|---|---|---|
2391563 | Goldberg | Dec 1945 | A |
3255512 | Lochner et al. | Jun 1966 | A |
4072780 | Zillman | Feb 1978 | A |
4313152 | Vranken | Jan 1982 | A |
4543553 | Mandai et al. | Sep 1985 | A |
4689594 | Kawabata et al. | Aug 1987 | A |
4750077 | Amagasa | Jun 1988 | A |
4758808 | Sasaki et al. | Jul 1988 | A |
4803425 | Swanberg | Feb 1989 | A |
4873757 | Williams | Oct 1989 | A |
5032815 | Kobayashi et al. | Jul 1991 | A |
5045380 | Kobayashi et al. | Sep 1991 | A |
5250923 | Ushiro et al. | Oct 1993 | A |
5257000 | Billings et al. | Oct 1993 | A |
5300911 | Walters | Apr 1994 | A |
5463717 | Takatori et al. | Oct 1995 | A |
5500629 | Meyer | Mar 1996 | A |
5515022 | Tashiro et al. | May 1996 | A |
5532667 | Haertling et al. | Jul 1996 | A |
5572180 | Huang et al. | Nov 1996 | A |
5664069 | Takatori et al. | Sep 1997 | A |
5761791 | Bando | Jun 1998 | A |
5821638 | Boys et al. | Oct 1998 | A |
5849355 | McHenry | Dec 1998 | A |
5875541 | Kumeji et al. | Mar 1999 | A |
5945902 | Lipkes et al. | Aug 1999 | A |
6038134 | Belter | Mar 2000 | A |
6054914 | Abel et al. | Apr 2000 | A |
6114939 | Wittenbreder | Sep 2000 | A |
6169801 | Levasseur et al. | Jan 2001 | B1 |
6198374 | Abel | Mar 2001 | B1 |
6198375 | Shafer | Mar 2001 | B1 |
6204744 | Shafer et al. | Mar 2001 | B1 |
6287931 | Chen | Sep 2001 | B1 |
6293001 | Uriu et al. | Sep 2001 | B1 |
6366192 | Person et al. | Apr 2002 | B2 |
6379579 | Harada | Apr 2002 | B1 |
6392525 | Kato et al. | May 2002 | B1 |
6420953 | Dadafshar | Jul 2002 | B1 |
6449829 | Shafer | Sep 2002 | B1 |
6460244 | Shafer et al. | Oct 2002 | B1 |
6566731 | Ahn et al. | May 2003 | B2 |
6628531 | Dadafshar | Sep 2003 | B2 |
6631545 | Uriu et al. | Oct 2003 | B1 |
6653196 | Ahn et al. | Nov 2003 | B2 |
6658724 | Nakano et al. | Dec 2003 | B2 |
6713162 | Takaya et al. | Mar 2004 | B2 |
6720074 | Zhang et al. | Apr 2004 | B2 |
6749827 | Smalley et al. | Jun 2004 | B2 |
6750723 | Yoshida et al. | Jun 2004 | B2 |
6791445 | Shibata et al. | Sep 2004 | B2 |
6794052 | Schultz et al. | Sep 2004 | B2 |
6797336 | Garvey et al. | Sep 2004 | B2 |
6808642 | Takaya et al. | Oct 2004 | B2 |
6817085 | Uchikoba et al. | Nov 2004 | B2 |
6835889 | Hiraoka et al. | Dec 2004 | B2 |
6864201 | Schultz et al. | Mar 2005 | B2 |
6879238 | Liu et al. | Apr 2005 | B2 |
6882261 | Moro et al. | Apr 2005 | B2 |
6885276 | Iha et al. | Apr 2005 | B2 |
6897718 | Yoshida et al. | May 2005 | B2 |
6908960 | Takaya et al. | Jun 2005 | B2 |
6927738 | Senba et al. | Aug 2005 | B2 |
6936233 | Smalley et al. | Aug 2005 | B2 |
6946944 | Shafer et al. | Sep 2005 | B2 |
6949237 | Smalley et al. | Sep 2005 | B2 |
6952355 | Riggio et al. | Oct 2005 | B2 |
6971391 | Wang et al. | Dec 2005 | B1 |
6979709 | Smalley et al. | Dec 2005 | B2 |
6986876 | Smalley et al. | Jan 2006 | B2 |
7008604 | Smalley et al. | Mar 2006 | B2 |
7019391 | Tran | Mar 2006 | B2 |
7034091 | Schultz et al. | Apr 2006 | B2 |
7034645 | Shafer et al. | Apr 2006 | B2 |
7041620 | Smalley et al. | May 2006 | B2 |
7048999 | Smalley et al. | May 2006 | B2 |
7069639 | Choi et al. | Jul 2006 | B2 |
7071406 | Smalley et al. | Jul 2006 | B2 |
7078999 | Uriu et al. | Jul 2006 | B2 |
7081803 | Takaya et al. | Jul 2006 | B2 |
7087207 | Smalley et al. | Aug 2006 | B2 |
7091412 | Wang et al. | Aug 2006 | B2 |
7091575 | Ahn et al. | Aug 2006 | B2 |
7105596 | Smalley et al. | Sep 2006 | B2 |
7108841 | Smalley et al. | Sep 2006 | B2 |
7127294 | Wang et al. | Oct 2006 | B1 |
7142066 | Hannah et al. | Nov 2006 | B1 |
7162302 | Wang et al. | Jan 2007 | B2 |
7205069 | Smalley et al. | Apr 2007 | B2 |
7213915 | Tsutsumi et al. | May 2007 | B2 |
7221249 | Shafer et al. | May 2007 | B2 |
7262482 | Ahn et al. | Aug 2007 | B2 |
7263761 | Shafer et al. | Sep 2007 | B1 |
7294366 | Renn et al. | Nov 2007 | B2 |
7319599 | Hirano et al. | Jan 2008 | B2 |
7330369 | Tran | Feb 2008 | B2 |
7339451 | Liu et al. | Mar 2008 | B2 |
7345562 | Shafer et al. | Mar 2008 | B2 |
7354563 | Smalley et al. | Apr 2008 | B2 |
7375417 | Tran | May 2008 | B2 |
7380328 | Ahn et al. | Jun 2008 | B2 |
7390477 | Smalley et al. | Jun 2008 | B2 |
7390767 | Smalley et al. | Jun 2008 | B2 |
7393699 | Tran | Jul 2008 | B2 |
7400512 | Hirano et al. | Jul 2008 | B2 |
7419624 | Smalley et al. | Sep 2008 | B1 |
7419651 | Smalley et al. | Sep 2008 | B2 |
7442665 | Schultz et al. | Oct 2008 | B2 |
7445852 | Maruko et al. | Nov 2008 | B2 |
7449984 | Kawarai | Nov 2008 | B2 |
7481989 | Smalley et al. | Jan 2009 | B2 |
7485366 | Ma et al. | Feb 2009 | B2 |
7489537 | Tran | Feb 2009 | B2 |
7525406 | Cheng | Apr 2009 | B1 |
7567163 | Dadafshar et al. | Jul 2009 | B2 |
20010016977 | Moro et al. | Aug 2001 | A1 |
20010043135 | Yamada et al. | Nov 2001 | A1 |
20030029830 | Takaya et al. | Feb 2003 | A1 |
20030184423 | Holdahl et al. | Oct 2003 | A1 |
20040017276 | Chen et al. | Jan 2004 | A1 |
20040174239 | Shibata et al. | Sep 2004 | A1 |
20040210289 | Wang et al. | Oct 2004 | A1 |
20050151614 | Dadafshar | Jul 2005 | A1 |
20050174207 | Young et al. | Aug 2005 | A1 |
20060038651 | Mizushima et al. | Feb 2006 | A1 |
20060049906 | Liu et al. | Mar 2006 | A1 |
20060145800 | Dadafshar et al. | Jul 2006 | A1 |
20060158299 | Sutardja | Jul 2006 | A1 |
20060186983 | Ding et al. | Aug 2006 | A1 |
20060197644 | Lin | Sep 2006 | A1 |
20060279395 | Lee et al. | Dec 2006 | A1 |
20070132533 | Shiu et al. | Jun 2007 | A1 |
20070175545 | Urata et al. | Aug 2007 | A1 |
20070252669 | Hansen et al. | Nov 2007 | A1 |
20080001702 | Brunner | Jan 2008 | A1 |
20080012674 | Sano et al. | Jan 2008 | A1 |
20080061917 | Manoukian et al. | Mar 2008 | A1 |
20080110014 | Shafer et al. | May 2008 | A1 |
20080231401 | Lee et al. | Sep 2008 | A1 |
20080310051 | Yan et al. | Dec 2008 | A1 |
20090058588 | Suzuki et al. | Mar 2009 | A1 |
20090066454 | Hansen | Mar 2009 | A1 |
20090096565 | Lanni | Apr 2009 | A1 |
20090179723 | Ikriannikov et al. | Jul 2009 | A1 |
20100007453 | Yan et al. | Jan 2010 | A1 |
20100026443 | Yan et al. | Feb 2010 | A1 |
Number | Date | Country |
---|---|---|
0655754 | May 1995 | EP |
1150312 | Oct 2001 | EP |
1486991 | Dec 2004 | EP |
1526556 | Apr 2005 | EP |
1564761 | Aug 2005 | EP |
6423121 | Feb 1989 | JP |
07272932 | Oct 1995 | JP |
2700713 | Jan 1998 | JP |
10106839 | Apr 1998 | JP |
3108931 | Nov 2000 | JP |
3160685 | Apr 2001 | JP |
20010014533 | Feb 2001 | KR |
20020071285 | Sep 2002 | KR |
20030081738 | Oct 2003 | KR |
9205568 | Apr 1992 | WO |
2005008692 | Jan 2005 | WO |
2006063081 | Jun 2006 | WO |
2008008538 | Jan 2008 | WO |
2009113775 | Sep 2009 | WO |
Number | Date | Country | |
---|---|---|---|
20100085139 A1 | Apr 2010 | US |