This invention is generally directed to a solid-state light source having an electromagnetic radiation density sufficient to perform a variety of functions in a variety of production applications.
High-intensity pressure arc lamps of various varieties (for example, metal halide, mercury, Xenon, Excimer, and halogen) and other high-intensity light sources are used in the majority of commercial and industrial applications involving, for example, projection, illumination and displays, inspection, initiation of chemical or biological processes, image reproduction, fluorescence, exposure, sterilization, photopolymer polymerization, irradiation, and cleaning. In each of the applications above, a high irradiation bulb generates a high-intensity broad spectral output of incoherent light that is filtered and spatially modified through the use of complicated optics to allow the emission of a narrow spectral band of light, such as, ultraviolet (UV) light with the proper intensity and spatial properties for the desired application. Unfortunately, conventional high-intensity light sources have a variety of disadvantages, as illustrated in the following examples.
UV light is an effective tool in many production applications in many industries. For example, UV light is used for photopolymer polymerization, a process used widely for various processes such as, printing, lithography, coatings, adhesives, processes used in semiconductor and circuit board manufacturing, publishing, and packaging. UV light, due to its high photon energy, is also useful for molecular excitation, chemical initiation and dissociation processes, including, fluorescence for inspection and measurement tasks, cleaning processes, and sterilization, and medical, chemical, and biological initiation processes, and used in a variety of industries such as, electronics, medicine, and chemical industries. The efficiency and duration of conventional light sources for these applications is extremely low. For instance, 8000 W ultraviolet lamp sources (after filtering) are used in exposure of polymer resists, but they provide only 70 W of power in the spectral range required by the process. Therefore, more efficient semiconductor light sources are needed.
Arrays of semiconductor light sources such as LEDs and laser diodes are more efficient than high pressure light sources and offer advantages over lamps and most other high-intensity light sources. For example, such arrays of semiconductor light sources are four to five times more efficient than that of high-intensity light sources. Other advantages of such semiconductor light source arrays are that they produce a far greater level of spectral purity than high-intensity light sources, they are more safe than high-intensity light sources since voltages and currents associated with such diodes are lower than those associated with high-intensity light sources, and they provide increased power densities since due to smaller packaging requirements. Furthermore, semiconductor light source arrays emit lower levels of electromagnetic interference, are significantly more reliable, and have more stable outputs over time requiring less maintenance, intervention, and replacement than with high-intensity light sources. Arrays of semiconductor light sources can be configured and controlled to allow individual addressability, produce a variety of wavelengths and intensities, and allow for rapid starting and control from pulsing to continuous operation.
None of the prior art discloses a semiconductor light source that can be adapted for a variety of applications and/or provide the high power densities required by a variety of applications.
The present invention overcomes the problems in the prior art by providing a solid-state light source adapted for a variety of applications requiring relatively high power density output. For example, the present invention may be used in material transformation, projection, and illumination applications. This is achieved by a unique array of solid-state light emitters that are arranged in a dense configuration capable of producing high-intensity power output that prior to this invention required inefficient high-intensity lamps and/or expensive and complex laser devices.
The device of this invention is capable of producing power densities greater than about 50 mW/cm2 for any application requiring such power density. The device of this invention may be used to produce power densities within the range of between about 50 mW/cm2 and 6,000 mW/cm2. The device may be configured differently for a variety of applications each of which may have different requirements such as, optical power output density, wavelength, optics, drive circuitry, and heat transfer. For example, the device may include a drive circuitry to supply power necessary to achieve the density of power output for a particular application. Additionally, the device may include various optics for applications in which a specific light wavelength is required such as, in fluorescent imaging or backside semiconductor wafer inspection.
In one preferred embodiment, the present invention provides a solid-state light module having a thermally conductive substrate with multiple chips of LEDs mounted in a spatially dense arrangement such that illumination is achieved at sufficient intensities to perform physical processes and/or to be utilized in projection and/or illumination applications. The solid-state light source of the present invention can be utilized to perform functions in a variety of applications in such areas of, for example, projection, exposure, curing, sterilization, cleaning, and material ablation. The solid-state light source achieves high efficiency, spectral purity, power densities, and spatial characteristics for each of the applications described above, as well as other applications that require efficient light production.
The present invention provides a solid-state light source that is self-contained, thus eliminating the need for intricate optical coupling mechanisms required by many prior art devices. Furthermore, the solid-state light source of the present invention optimizes light output and is advantageous in the design of small cost effective LED projector systems.
The foregoing embodiments and features are for illustrative purposes and are not intended to be limiting, persons skilled in the art being capable of appreciating other embodiments from the scope and spirit of the foregoing teachings.
The present invention provides a lighting module that serves as a solid-state light source capable of performing operations in a variety of applications requiring high density power output. The device of the present invention includes a dense chip-onboard array of solid-state light emitters that produce high-intensity power output and further includes heat transfer; drive circuitry, light intensity, spectral purity, spatial uniformity, and directionality required for a variety of applications. Such applications are typically those requiring a power density output of over about 50 mW/cm2. Most applications typically require between about 50 mW/cm2 and 6,000 mW/cm2 and the present invention can provide power output in this range. However, it is contemplated that the lighting module of the present invention may be utilized in applications requiring a power density output greater than about 6,000 mW/cm2′ Applications requiring power density output of between about 50 mW/cm2 and 6,000 mW/cm2 include the following:
The lighting module of the present invention includes an array of solid-state light emitters that may be configured to produce the required light intensity for each application of use. As used herein, the phrase “solid-state light emitter” means any device that converts electric energy into electro-magnetic radiation through the recombination of holes and electrons. Examples of solid-state light emitters include semiconductor light emitting diodes (LEDs), semiconductor laser diodes, vertical cavity surface emitting lasers (VCSELs), polymer light emitting diodes, and electroluminescent devices (i.e., devices that convert electric energy to light by a solid phosphor subjected to an alternating electric field). In the following description, LEDs are used to illustrate solid-state light emitters.
LEDs are arranged in a dense array on a substrate, as discussed below. The density of the chip array or, in other words, the spacing of the chips on the substrate, may vary according to the application of intended use. Each application of intended use may require a different power density output that may be achieved based on the spacing (or density) of the chips on the substrate, depending on the power of chip used. Additionally, each application may require different light wavelengths or a mixture of wavelengths for the application. Table 1 below shows examples of power density outputs that can be achieved by various chip array densities or spacing using 12 mW and 16 mW chips. For example, an array of 12 mW chips formed on a substrate in a density of 494 chips/cm2 (22 chips/cm) produces a power density output of 5037 mW/cm2. This power output density may be required for cleaning applications using light wavelengths of between 300-400 nm. For cleaning applications requiring a higher power density output, an array of 16 mW chips formed in the same density described above produces a power density output of 6716 mW/cm2. While individually packaged prior art semiconductors like LEDs, VCSELs, and laser diodes are typically arranged on 4 mm or larger center-to-center pitches, this invention achieves significant increases in power density by arranging the devices on center-to-center pitches below 3 mm, and more typically between 1 min and 2 mm center-to-center pitches. In view of the teachings herein, it should be apparent to one skilled in the art that other power densities, other wavelengths, and other device spacings are possible limited only by the future availability of devices. As defined herein, a dense array of solid state emitters is one a plurality of solid state emitters are arranged in an array of 3 mm or less center-to-center spacing to provide a power density output of at least 50 mW/cm2.
Wires 30 are connected to LED chips 22 and substrate 24 through circuitry patterns 28 by any wire bonding or electrical joining technique, including wire bonding, flip chip, surface mount, or other bonding technique. Circuitry patterns 28 may include connections to thick or thin film passive components 32. Thick film components 32 can be laser trimmed to achieve uniform light intensities across array 26. A power supply 34 is provided and is connected to circuitry patterns 28 to power LED chips 22. Power supply 34 may be connected to or controlled by a computer controller 36 so that LED chips 22 can be turned on, off, or pulsed for variable times or intensities. At least one temperature sensor 37 may be connected to circuitry patterns 28 in any known manner to monitor the temperature of substrate 24. Sensor 37 may be connected through control circuitry to power supply to prevent the module 20 from overheating. Thus, input from temperature sensors 37 may be used to provide real-time in-situ temperature control. Thermal stability and heat dissipation may be achieved, if desired, by mounting substrate 24 onto a heat sink 38. This heat sink can be comprised of heat conductive materials like copper or aluminum, heat pipes consisting of a metal cylinder containing a fluid for enhanced heat convection, or a water-cooled heat conducting material.
Optical properties of spatial directionality, uniformity and spectral filtering may be achieved, if desired, by an optical component 40, which might include a micro lens array of refractive or diffractive components or other optical redirection technology, as well as spectral filtering. Light output 42 from LED chips 22 can be focused, collimated, and/or made more uniform. Although not required, optical efficiency may be achieved by matching the index of refraction of a gas, liquid, or transparent polymer hermetically sealed in a gap or space 44 created between the substrate 24 and optical component 40 for maximum reliability. Suitable refracting gases are known to persons skilled in the art and may include helium, nitrogen, argon, or air. Suitable refracting liquid could include coolants or optical mineral oils. Suitable transparent polymers include optical gels of silicone and epoxy, and rigid polymers of acrylic, polycarbonate, epoxy and others known to persons skilled in the art. The gas, liquid or polymer may further improve thermal dissipation. Optical efficiency can also be improved by addition of reflective surface coatings on substrate 24 or by the addition of known thin film coatings on optical component 40 or component 22.
One possible example of a solid-state light device 46 is seen in
As seen in
To control the temperature of light bar 84, a fluid tube 114 introduces cooling fluid (coolant) in and carries heated fluid out. Light bar housing 96 includes upper and lower metal plates 116 and 118 such as, aluminum or copper, between which fluid tube 114 is positioned so that heat is transferred from light bar housing 96 to the fluid which is then carried out of light bar housing 96. Alternatively, light bar housing 96 may be provided with plural channels 120 (
Other material transformation processes may include, resist exposure for circuit boards that include at least one material that reacts to light wavelengths between about 350-425 nm with the optimal wavelength being 365 nm at a power density output of greater than 100 mW/cm2. The substrate may be ceramic such as alumina or Aluminum Nitride (AN) or any of the other thermally conductive substrates mentioned herein using a fluid cooled heat sink. A collimating optic micro array may be utilized to collimate light output. The LED chips such as those manufactured by Cree, Inc. as discussed above, may be either be pulsed or driven continuously to obtain a power output density of greater than 700 mW/cm2. For some cleaning operations, light wavelengths of between 300-400 nm may be used as some organic materials can be removed using such a range of wavelengths. For example, fingerprints may be removed from a semiconductor wafer using a wavelength of about 365 nm and pulsing the LED chips at less than 100 nsec pulses to obtain a power output density of greater than 5,000 mW/cm2.
Power supply 144, as well as other power supplies described above, can provide a variety of power waveforms, as seen in
For backside inspection of silicon wafers or for MEMs seal inspections, module 160 preferably includes 1050-2500 nm LED chips or laser diodes having a combined output power density greater than 50 mW/cm′. Second optical element 166 is preferably a 50% beam splitter at the same wavelength as the light output from module 160, which is typically between 1100-1300 nm. This arrangement is effective for work objects 164 that are transmissive at 1100-1300 nm so that the wavelengths transmitted from work object 164 are propagated through second optical element 166 to camera 168 that is sensitive in the near infrared at the source wavelength.
Light output may be further extended by stacking modules 160 as seen in
Grounds for a triad of LEDs or other multiple grouping can either be separate or one single common ground. A solid-state light module 170 is partially seen in
The lighting module of the present invention may be utilized in a variety of applications that require high-intensity ultraviolet light. For example, the lighting module may be used in fluorescence applications for mineral, polymer, and medical inspection and measurement by using a power output density of between 10-20 mW/cm2 of light of a wavelength of less than about 400 nm applied for at least a duration of about 40 msec. For water sterilization, a power output density of between 2-42 mW/cm2 of light of a wavelength of about 254 nm may be provided and for sterilization of blood a power output density of about 80 mW/cm2 of light of a wavelength of between 325-390 nm. In polymer curing of for example, adhesives, paints, inks, seals, conformal coatings, and masks, a power output density of between 30-300 mW/cm2 of light of a wavelength of between about 300-400 nm. For imaging exposure for, for example, circuits and printing, a power output density of between 25-300 mW/cm2 of light of wavelengths of about 246 nm, 365 nm, 405 nm, and 436 nm is provided for a duration of between about 6-30 seconds. In stereo lithography applications for rapid prototyping, a power output density of greater than 10 mJ/cm2 of light of wavelengths between about 325-355 nm is provided for a duration of about 20 nsec. For organic cleaning applications for debris removal of, for example, epoxy or fingerprints, a power density output of between 60-500 mJ/cm2 of light of wavelengths of 172 nm and 248 nm for a duration of 20 nsec. In photo ablation applications for material removal, a power output density of 1 E7 W/cm2 of light of a wavelength less than about 400 nm is utilized for a duration of about 20 nsec. The light might be pulsed by drive circuits and optical elements may provide an improvement of directionality and uniformity, perhaps with gradient index planar lens materials.
In applications in which the module is used for projection the module may be used to drive fluorescing material to generate the required R,G,B output. For example, three phosphors may be used as a target and one or more phosphors may be activated depending on the intensity of the light output. This application may be used to create visual interest or for small televisions. The present invention also contemplates embodiments of the invention for deformable mirror device (DMD) and LCD based projection devices, which would overcome the problem of light output balancing from R,G,B LEDs.
Additionally, a variety of other applications including water treatments including splitting, disinfecting, ionizing, and reduction of pollutants; polymerization of medical coatings, conductive inks, controlled release drugs, and furniture coating; sterilization of medical devices, blood products, medicines, and airborne particulates; diagnostic and therapeutic uses of light for dental, skin treatment for a variety of diseases, mental disorders, and identifying particular materials through spectrographic or chromatography methods; agricultural uses including stimulating plant growth or preparing plant transitions from artificial to natural sunlight; environmental applications including the degradation of materials to accelerate biodegration.
In exposure applications, higher coherence, spectral purity, and/or directionality of light could be achieved by including an anti-reflective coated side enclosures for each LED or diode to avoid side reflections and interference effect. This will effectively prevent creative and/or destructive interferences from up close. Alternatively, the modules can be enclosed in a series of reflectors to dramatically increase the distance to the work surface to ensure greater spectral purity. Alternatively, a micro lenses could be fabricated on the LED pitch spacing to improve collimation. Such lenses might be, for example, gradient index diffractive optics or Fresnel lenses. Furthermore, distributed Bragg Reflectors formed by dielectric coatings could form a resonant cavity, which would improve light directionality. Additionally, a planar collimator, such as an assembly of one or more stacked laminated transparent materials of varying index of refraction formed in any combination, or a gradient index modified glass, perhaps assembled on the LED pitch spacing.
In the embodiments herein described, a power source may be constructed and arranged as seen in
The power density output of the modules can be tested using a machine vision inspection technique, as seen in
Persons skilled in the art will recognize that many modifications and variations are possible in the details, materials, and arrangements of the parts and actions which have been described and illustrated in order to explain the nature of this invention and that such modifications and variations do not depart from the spirit and scope of the teachings and claims contained therein.
This application claims priority to, and is a continuation of U.S. patent application Ser. No. 13/466,337 filed May 8, 2012, which is a continuation of U.S. patent application Ser. No. 10/984,589 filed Nov. 8, 2004, which is a continuation-in-part application claiming the benefit of International Application No. PCT/US2003/014625 filed May 8, 2003, which claims priority of U.S. Provisional Patent Application No. 60/379,019 filed May 8, 2002, the contents of which are incorporated herein by reference in their entirety for all purposes.
Number | Name | Date | Kind |
---|---|---|---|
3586959 | Eccles et al. | Jun 1971 | A |
3609335 | Kelly | Sep 1971 | A |
3936686 | Moore | Feb 1976 | A |
4011575 | Groves | Mar 1977 | A |
4194814 | Fischer et al. | Mar 1980 | A |
4298869 | Okuno | Nov 1981 | A |
4321508 | Adler et al. | Mar 1982 | A |
4435732 | Hyatt | Mar 1984 | A |
4439910 | Vasudev | Apr 1984 | A |
4504776 | Haville | Mar 1985 | A |
4530040 | Petterson | Jul 1985 | A |
4535247 | Kurtz | Aug 1985 | A |
4544642 | Maeda et al. | Oct 1985 | A |
4595289 | Feldman et al. | Jun 1986 | A |
4680644 | Shirato et al. | Jul 1987 | A |
4684801 | Carroll et al. | Aug 1987 | A |
4685139 | Masuda et al. | Aug 1987 | A |
4734714 | Takasu et al. | Mar 1988 | A |
4913906 | Friedman | Apr 1990 | A |
5003357 | Kim et al. | Mar 1991 | A |
5006724 | Liu | Apr 1991 | A |
5018853 | Hechel et al. | May 1991 | A |
5067799 | Gold et al. | Nov 1991 | A |
5125153 | Frey | Jun 1992 | A |
5150623 | Woods | Sep 1992 | A |
5195102 | McLean et al. | Mar 1993 | A |
5285356 | Skene | Feb 1994 | A |
5296724 | Ogata et al. | Mar 1994 | A |
5321595 | Jacobi et al. | Jun 1994 | A |
5332894 | Fujimoto | Jul 1994 | A |
5365084 | Cochran et al. | Nov 1994 | A |
5390071 | Kersten | Feb 1995 | A |
5397867 | Demeo | Mar 1995 | A |
5418384 | Yamana et al. | May 1995 | A |
5424544 | Shelton et al. | Jun 1995 | A |
5436710 | Uchiyama | Jul 1995 | A |
5449926 | Holm et al. | Sep 1995 | A |
5479029 | Ikawa Katsuhiko et al. | Dec 1995 | A |
5487662 | Kipke et al. | Jan 1996 | A |
5490049 | Montalan et al. | Feb 1996 | A |
5522225 | Eskandari | Jun 1996 | A |
5554849 | Gates | Sep 1996 | A |
5555038 | Conway | Sep 1996 | A |
5564819 | Yamaguchi | Oct 1996 | A |
5568136 | Hochstein et al. | Oct 1996 | A |
5623510 | Hamilton et al. | Apr 1997 | A |
5632551 | Roney et al. | May 1997 | A |
5633629 | Hochstein | May 1997 | A |
5660461 | Ignatius et al. | Aug 1997 | A |
5661645 | Hochstein | Aug 1997 | A |
5670780 | Lewis | Sep 1997 | A |
5698866 | Doiron et al. | Dec 1997 | A |
5705788 | Beyer et al. | Jan 1998 | A |
5715270 | Zediker et al. | Feb 1998 | A |
5719589 | Norman et al. | Feb 1998 | A |
5724062 | Hunter | Mar 1998 | A |
5777729 | Aiyer et al. | Jul 1998 | A |
5782555 | Hochstein | Jul 1998 | A |
5783909 | Hochstein | Jul 1998 | A |
5784006 | Hochstein | Jul 1998 | A |
5785418 | Hochstein | Jul 1998 | A |
5806965 | Deese | Sep 1998 | A |
5857767 | Hochstein | Jan 1999 | A |
5877899 | Stern et al. | Mar 1999 | A |
5880828 | Nakamura et al. | Mar 1999 | A |
5886313 | Kraus et al. | Mar 1999 | A |
5892579 | Elyasaf et al. | Apr 1999 | A |
5910706 | Stevens et al. | Jun 1999 | A |
5936353 | Triner et al. | Aug 1999 | A |
5940683 | Holm et al. | Aug 1999 | A |
5949528 | Iwasaki | Sep 1999 | A |
6033087 | Shozo et al. | Mar 2000 | A |
6045240 | Hochstein | Apr 2000 | A |
6058012 | Cooper et al. | May 2000 | A |
6065854 | West et al. | May 2000 | A |
6077073 | Jacob | Jun 2000 | A |
6078148 | Hochstein | Jun 2000 | A |
6088185 | Ratliff et al. | Jul 2000 | A |
6095812 | Senn | Aug 2000 | A |
6115184 | Hubble, III et al. | Sep 2000 | A |
6118383 | Hegyi | Sep 2000 | A |
6141040 | Toh | Oct 2000 | A |
6155699 | Miller et al. | Dec 2000 | A |
6160354 | Ravinski et al. | Dec 2000 | A |
6163036 | Taninaka et al. | Dec 2000 | A |
6200134 | Kovac et al. | Mar 2001 | B1 |
6222207 | Carter-Coman et al. | Apr 2001 | B1 |
6224216 | Parker et al. | May 2001 | B1 |
6232659 | Clayton | May 2001 | B1 |
6252351 | Koizami et al. | Jun 2001 | B1 |
6258618 | Lester | Jul 2001 | B1 |
6273596 | Parkyn, Jr. | Aug 2001 | B1 |
6288497 | Chang et al. | Sep 2001 | B1 |
6290382 | Bourn et al. | Sep 2001 | B1 |
6291839 | Lester | Sep 2001 | B1 |
6299329 | Mui et al. | Oct 2001 | B1 |
6318886 | Stopa et al. | Nov 2001 | B1 |
6318996 | Melikechi et al. | Nov 2001 | B1 |
6319425 | Tasaki et al. | Nov 2001 | B1 |
6325524 | Weber et al. | Dec 2001 | B1 |
6328456 | Mize | Dec 2001 | B1 |
6329758 | Salem | Dec 2001 | B1 |
6330017 | Suzuki | Dec 2001 | B1 |
6331111 | Cao | Dec 2001 | B1 |
6340868 | Lys | Jan 2002 | B1 |
6342402 | Tajini et al. | Jan 2002 | B1 |
6346771 | Salem | Feb 2002 | B1 |
6351079 | Willis | Feb 2002 | B1 |
6357904 | Kawashimi | Mar 2002 | B1 |
6366017 | Antoniadis et al. | Apr 2002 | B1 |
6367950 | Yamada et al. | Apr 2002 | B1 |
6373188 | Johnson | Apr 2002 | B1 |
6373635 | Fujimoto et al. | Apr 2002 | B1 |
6375340 | Biebl et al. | Apr 2002 | B1 |
6419384 | Lewis et al. | Jul 2002 | B1 |
6420839 | Chiang et al. | Jul 2002 | B1 |
6424399 | Shimada et al. | Jul 2002 | B1 |
6420199 | Comen et al. | Aug 2002 | B1 |
6428189 | Hochstein | Aug 2002 | B1 |
6439888 | Boutoussov et al. | Aug 2002 | B1 |
6441873 | Young | Aug 2002 | B2 |
6445124 | Asai et al. | Sep 2002 | B1 |
6450664 | Kelly | Sep 2002 | B1 |
6455930 | Palanisamy et al. | Sep 2002 | B1 |
6457823 | Cleary et al. | Oct 2002 | B1 |
6459010 | Carpena | Oct 2002 | B1 |
6459919 | Lys et al. | Oct 2002 | B1 |
6461568 | Eckhardt | Oct 2002 | B1 |
6462669 | Pederson | Oct 2002 | B1 |
6480389 | Shie et al. | Nov 2002 | B1 |
6497840 | Palestro | Dec 2002 | B1 |
6498355 | Harrah et al. | Dec 2002 | B1 |
6498423 | Bell et al. | Dec 2002 | B1 |
6501084 | Sakai et al. | Dec 2002 | B1 |
6517218 | Hochstein | Feb 2003 | B2 |
6518502 | Hammond et al. | Feb 2003 | B2 |
6525335 | Krames et al. | Feb 2003 | B1 |
6533205 | Kles | Mar 2003 | B1 |
6534791 | Hayashi et al. | Mar 2003 | B1 |
6536923 | Merz | Mar 2003 | B1 |
6541800 | Barnett et al. | Apr 2003 | B2 |
6545808 | Ehbets et al. | Apr 2003 | B1 |
6547249 | Collins, III et al. | Apr 2003 | B2 |
6554217 | Rodriguez | Apr 2003 | B1 |
6554451 | Keuper | Apr 2003 | B1 |
6558021 | Wu | May 2003 | B2 |
6561640 | Young | May 2003 | B1 |
6561808 | Neuberger | May 2003 | B2 |
6573536 | Dry | Jun 2003 | B1 |
6577332 | Osawa et al. | Jun 2003 | B2 |
6578986 | Osumi et al. | Jun 2003 | B2 |
6578989 | Swaris et al. | Jun 2003 | B2 |
6607286 | West et al. | Aug 2003 | B2 |
6630689 | Bhat et al. | Oct 2003 | B2 |
6669129 | Shah | Dec 2003 | B1 |
6670856 | Mazzochette | Dec 2003 | B1 |
6683421 | Kennedy et al. | Jan 2004 | B1 |
6686581 | Verhoeckx et al. | Feb 2004 | B2 |
6692250 | Decaudin et al. | Feb 2004 | B1 |
6708501 | Ghoshal | Mar 2004 | B1 |
6709749 | Kumar | Mar 2004 | B1 |
6713862 | Palanisamy et al. | Mar 2004 | B2 |
6720859 | Mazzochette | Apr 2004 | B2 |
6724473 | Leong et al. | Apr 2004 | B2 |
6736321 | Tsikos et al. | May 2004 | B2 |
6739047 | Hammond et al. | May 2004 | B2 |
6739511 | Tsikos et al. | May 2004 | B2 |
6742707 | Tsikos et al. | Jun 2004 | B1 |
6742711 | Tsikos et al. | Jun 2004 | B2 |
6746295 | Sorg | Jun 2004 | B2 |
6755647 | Melikechi et al. | Jun 2004 | B2 |
6759664 | Thompson et al. | Jul 2004 | B2 |
6759803 | Sorg | Jul 2004 | B2 |
6759940 | Mazzochette | Jul 2004 | B2 |
6773608 | Hallett | Aug 2004 | B1 |
6794688 | Nakatsu et al. | Sep 2004 | B2 |
6796502 | Nogami et al. | Sep 2004 | B2 |
6796690 | Bohlander | Sep 2004 | B2 |
6796698 | Sommers et al. | Sep 2004 | B2 |
6796994 | Ignatius et al. | Sep 2004 | B2 |
6798932 | Kuhara et al. | Sep 2004 | B2 |
6815724 | Dry | Sep 2004 | B2 |
6799864 | Bohler et al. | Oct 2004 | B2 |
6799967 | Cao | Oct 2004 | B2 |
6800500 | Comen et al. | Oct 2004 | B2 |
6801237 | Gaudiana et al. | Oct 2004 | B2 |
6805466 | Ranish | Oct 2004 | B1 |
6806987 | Kwasnick et al. | Oct 2004 | B2 |
6822991 | Collins, III et al. | Nov 2004 | B2 |
6826059 | Bockle et al. | Nov 2004 | B2 |
6831303 | Dry | Dec 2004 | B2 |
6834963 | Kim et al. | Dec 2004 | B2 |
6836081 | Swanson et al. | Dec 2004 | B2 |
6850637 | Burnett | Feb 2005 | B1 |
6857767 | Matsui et al. | Feb 2005 | B2 |
6869635 | Kobayashi | Mar 2005 | B2 |
6882331 | Wu | Apr 2005 | B2 |
6882782 | Conzone et al. | Apr 2005 | B2 |
6930870 | Nobe et al. | Aug 2005 | B2 |
6937754 | Eguchi | Aug 2005 | B1 |
6992335 | Ohkawa | Jan 2006 | B2 |
6995348 | Bradley et al. | Feb 2006 | B2 |
6995405 | Braddell et al. | Feb 2006 | B2 |
7009165 | Hehemann et al. | Mar 2006 | B2 |
7071493 | Owen et al. | Jul 2006 | B2 |
7102172 | Lynch et al. | Sep 2006 | B2 |
7179670 | Shelton et al. | Feb 2007 | B2 |
7270748 | Lieggi | Sep 2007 | B1 |
7440147 | Kelsay | Oct 2008 | B2 |
8192053 | Owen et al. | Jun 2012 | B2 |
20010002120 | Bessendorf et al. | May 2001 | A1 |
20010048814 | Lenmann et al. | May 2001 | A1 |
20010007498 | Aral et al. | Jul 2001 | A1 |
20010030782 | Trezza | Oct 2001 | A1 |
20010046652 | Ostler et al. | Nov 2001 | A1 |
20010049893 | Maas et al. | Dec 2001 | A1 |
20020005826 | Pederson | Jan 2002 | A1 |
20020015662 | Hlavinka | Feb 2002 | A1 |
20020041499 | Pederson | Apr 2002 | A1 |
20020053589 | Owen et al. | May 2002 | A1 |
20020057567 | Chen | May 2002 | A1 |
20020090184 | Sayag | Jul 2002 | A1 |
20020151941 | Okawa et al. | Oct 2002 | A1 |
20020176250 | Bohler et al. | Nov 2002 | A1 |
20020187454 | Melikechi et al. | Dec 2002 | A1 |
20020191396 | Reiff et al. | Dec 2002 | A1 |
20020191430 | Meir | Dec 2002 | A1 |
20030001507 | Cao | Jan 2003 | A1 |
20030002282 | Swaris et al. | Jan 2003 | A1 |
20030021121 | Pederson | Jan 2003 | A1 |
20030031028 | Murray et al. | Feb 2003 | A1 |
20030031032 | Wu et al. | Feb 2003 | A1 |
20030038943 | Almarzouk et al. | Feb 2003 | A1 |
20030043582 | Chan et al. | Mar 2003 | A1 |
20030062185 | Hammond et al. | Apr 2003 | A1 |
20030081096 | Young | May 2003 | A1 |
20030112229 | Pong | Jun 2003 | A1 |
20030128552 | Takagi et al. | Jul 2003 | A1 |
20030159308 | Field et al. | Aug 2003 | A1 |
20030174947 | Sweetser et al. | Sep 2003 | A1 |
20030209714 | Taskar et al. | Nov 2003 | A1 |
20030218760 | Tomasai et al. | Nov 2003 | A1 |
20030218761 | Tomasai et al. | Nov 2003 | A1 |
20030230765 | Dry | Dec 2003 | A1 |
20040000677 | Dry | Jan 2004 | A1 |
20040011457 | Kobayashi et al. | Jan 2004 | A1 |
20040026721 | Dry | Feb 2004 | A1 |
20040057873 | Yerazunis et al. | Mar 2004 | A1 |
20040061079 | Thompson et al. | Apr 2004 | A1 |
20040090794 | Ollett et al. | May 2004 | A1 |
20040101802 | Scott | May 2004 | A1 |
20040113549 | Roberts et al. | Jun 2004 | A1 |
20040119084 | Hsieh et al. | Jun 2004 | A1 |
20040134603 | Kobayashi et al. | Jul 2004 | A1 |
20040135159 | Siegel | Jul 2004 | A1 |
20040141326 | Dry | Jul 2004 | A1 |
20040164325 | Siegel | Aug 2004 | A1 |
20040166249 | Siegel | Aug 2004 | A1 |
20040183078 | Wang | Sep 2004 | A1 |
20040196653 | Clark et al. | Oct 2004 | A1 |
20040201846 | Mullani | Oct 2004 | A1 |
20040201988 | Allen | Oct 2004 | A1 |
20040201995 | Galli | Oct 2004 | A1 |
20040203189 | Chen et al. | Oct 2004 | A1 |
20040206970 | Martin | Oct 2004 | A1 |
20040211926 | Alexander | Oct 2004 | A1 |
20040218390 | Holman et al. | Nov 2004 | A1 |
20040222433 | Mazochette et al. | Nov 2004 | A1 |
20040238111 | Siegel | Dec 2004 | A1 |
20050082480 | Wagner et al. | Apr 2005 | A1 |
20050086964 | Hackman et al. | Apr 2005 | A1 |
20050087750 | Braddell et al. | Apr 2005 | A1 |
20050088209 | Wessels | Apr 2005 | A1 |
20050088380 | Bulovic et al. | Apr 2005 | A1 |
20050098299 | Goodson et al. | May 2005 | A1 |
20050218468 | Owen | Oct 2005 | A1 |
20050230600 | Olson et al. | Oct 2005 | A1 |
20050231713 | Owen et al. | Oct 2005 | A1 |
20050253252 | Owen et al. | Nov 2005 | A1 |
20050285129 | Jackson et al. | Dec 2005 | A1 |
20060216865 | Owen et al. | Sep 2006 | A1 |
Number | Date | Country |
---|---|---|
8815418 | Feb 1989 | DE |
19619154 | Jun 1997 | DE |
10127171 | Dec 2001 | DE |
146998 | Jul 1985 | EP |
0560605 | Sep 1993 | EP |
0879582 | Nov 1998 | EP |
0935145 | Aug 1999 | EP |
1033229 | Sep 2000 | EP |
1158761 | Nov 2001 | EP |
1158761 | Nov 2001 | EP |
1462069 | Sep 2004 | EP |
1467416 | Oct 2004 | EP |
1469529 | Oct 2004 | EP |
1502752 | Feb 2005 | EP |
1526581 | Apr 2005 | EP |
1479270 | Jul 2006 | EP |
2224374 | May 1990 | GB |
2396331 | Jun 2004 | GB |
2399162 | Sep 2004 | GB |
59035492 | Feb 1984 | JP |
404204333 | Jul 1992 | JP |
2003268042 | Sep 2003 | JP |
9507731 | Mar 1995 | WO |
9716679 | May 1997 | WO |
9808051 | Feb 1998 | WO |
0037904 | Jun 2000 | WO |
0059671 | Oct 2000 | WO |
0067048 | Nov 2000 | WO |
0102846 | Jan 2001 | WO |
0206723 | Jan 2002 | WO |
0211640 | Feb 2002 | WO |
0213231 | Feb 2002 | WO |
0213231 | Feb 2002 | WO |
0226270 | Apr 2002 | WO |
02069839 | Sep 2002 | WO |
02086972 | Oct 2002 | WO |
02103411 | Dec 2002 | WO |
03023875 | Mar 2003 | WO |
03059025 | Jul 2003 | WO |
03060927 | Jul 2003 | WO |
03060928 | Jul 2003 | WO |
03096387 | Nov 2003 | WO |
2004009318 | Jan 2004 | WO |
04011848 | Feb 2004 | WO |
2004011848 | Feb 2004 | WO |
04038759 | May 2004 | WO |
2004038759 | May 2004 | WO |
2004049462 | Jun 2004 | WO |
2004056581 | Jul 2004 | WO |
04078477 | Sep 2004 | WO |
2004081475 | Sep 2004 | WO |
04088760 | Oct 2004 | WO |
069958 | Nov 2004 | WO |
05041632 | May 2005 | WO |
05043598 | May 2005 | WO |
05043954 | May 2005 | WO |
05091392 | Sep 2005 | WO |
05094390 | Oct 2005 | WO |
05100961 | Oct 2005 | WO |
05101535 | Oct 2005 | WO |
06072071 | Jul 2006 | WO |
Entry |
---|
Data Sheet for G*SiC Technology Super Blue LEDs No. C430-CB290-E1200, manufactured by Opto Semiconductors, May 1, 1999, 8 pages. |
Data Sheet for 5.0 mm Blue Series LEDs No. LNG992CFB, manufactured by the Panasonic Corporation, Mar. 2001, 1 page. |
Data Sheet for 3.0 mm Blue Series LEDs No. LNG997CKB, manufactured by the Panasonic Corporation, Mar. 2001, 1 page. |
Data Sheet for G*SiC Technology Ultraviolet LEDs No. C395-XB290-E0400, manfucatured by Cree, Inc., 2 pages. |
PCT International Search Report dated Nov. 19, 2003 and International Preliminary Examination Report dated Sep. 29, 2003 for International PCT Application No. PCT/US03/14625, filed May 8, 2003, 6 pages. |
PCT International Search Report and Written Opinion dated Jun. 3, 2005 for International PCT Application No. PCT/US04/36260, filed Oct. 28, 2004, 5 pages. |
PCT International Search Report and Written Opinion dated Jun. 17, 2005 for International PCT Application No. PCT/US04/36370, filed Nov. 1, 2004, 6 pages. |
PCT International Search Report and Written Opinion dated Aug. 26, 2005 for International PCT Application No. PCT/US05/09407, filed Mar. 18, 2005, 11 pages. |
Martin, S. et al, LED Applications for Phototonics Adhesive Curing, Proc. of SPIE, Jun. 2002, vol. 4833 pp. 296-303. |
“LIA Handbook of Laser Material Processing,” 2001, pp. 290, 548. |
“Electrically pumped vertical-cavity GaN-based LED shows directional emission,” Laser Focus World, Feb. 2002, p. 11. |
“Spacing of High-Brightness LEDs on Metal Substrate PCB's for Proper Thermal performance,” James Petroski, IEEE Inter Soc. Conference on Thermal Phenom, 2004. |
Supplemental European Search Report and Written Opinion for Corresponding EU Application No. EP03724539, dated Nov. 21, 2007, 8 pages total. |
PCT International Search Report and Written Opinion dated Jun. 7, 2006 for International Application No. PCT/US04/36046, filed Oct. 29, 2004, 6 pages. |
First Office Action dated Sep. 14, 2006 from related U.S. Appl. No. 11/109,903, filed Apr. 19, 2005, by Mark Owen, et al. 7 pages. |
First Office Action dated Nov. 14, 2007 issued after a Final Office Action and Request for Continued Examination for related U.S. Appl. No. 11/109,903, filed Apr. 19, 2005, by Mark Owen, et al. 6 pages. |
Applicant Response to First Office Action Filed with the United States Patent and Trademark Office dated Dec. 13, 2006 for related U.S. Appl. No. 11/109,903, filed Apr. 19, 2005, by Mark Owen, et al. 13 pages. |
Applicant Response to Final Office Action filed with the United States Patent and Trademark Office dated Aug. 17, 2007 for related U.S. Appl. No. 11/109,903, filed Apr. 19, 2005, by Mark Owen, et al., 14 pages. |
Final Office Action dated Apr. 17, 2007 from related U.S. Appl. No. 11/109,903, filed Apr. 19, 2005, by Mark Owen, et al. |
Taiwan Intellectual Property Office, translation of Examination Report for Corresponding Taiwan Patent Application No. 094112503, including Search Report, 4 pages. |
Not yet published related U.S. Appl. No. 11/614,753, filed Dec. 21, 2006, Specification and Figures, 58 pages. |
PCT International Search Report and PCT Written Opinion dated Oct. 13, 2006 for International PCT Application No. PCT/US05/13448, filed Apr. 19, 2005, 8 pages. |
PCT International Search Report and PCT Written Opinion dated Sep. 28, 2006 for International PCT Application No. PCT/US05/11216 filed Mar. 30, 2005, 9 pages. |
PCT International Search Report and PCT Written Opinion dated Oct. 16, 2006 for International PCT Application No. PCT/US05/09076 filed Mar. 18, 2005, 10 pages. |
Not yet published related U.S. Appl. No. 11/342,363, filed Jan. 26, 2006; Specification and Figures; 44 pages. |
Not yet published related U.S. Appl. No. 11/434,544, filed May 12, 2006; Specification and Figures; 28 pages. |
Electromagnetic Spectrum (http://brocku.ca/earthsciies/people/gfinn/optical/spectrum.gif). |
Number | Date | Country | |
---|---|---|---|
20130302209 A1 | Nov 2013 | US |
Number | Date | Country | |
---|---|---|---|
60379019 | May 2002 | US |
Number | Date | Country | |
---|---|---|---|
Parent | 13466337 | May 2012 | US |
Child | 13944223 | US | |
Parent | 10984589 | Nov 2004 | US |
Child | 13466337 | US |
Number | Date | Country | |
---|---|---|---|
Parent | PCT/US03/14625 | May 2003 | US |
Child | 10984589 | US |