Patent Application
20080008949
Any suitable multilayer photoreceptor may be employed in present imaging member. The various layers may be applied in any suitable order to produce either positive or negative charging photoreceptors. For example, the charge generation layer may be applied prior to the charge transport layer, as illustrated in U.S. Pat. No. 4,265,990, which is hereby incorporated by reference herein in its entirety, or the charge transport layer may be applied prior to the charge generation layer, as illustrated in U.S. Pat. No. 4,346,158, which is hereby incorporated by reference herein in its entirety. In selected embodiments, the first pass charge transport layer is formed upon a charge generation layer and the second pass charge transport layer is formed upon the first pass charge transport layer.
The supporting substrate can be selected to include a conductive metal substrate or a metallized substrate. While a metal substrate is substantially or completely metal, the substrate of a metallized substrate is made of a different material that has at least one layer of metal applied to at least one surface of the substrate. The material of the substrate of the metallized substrate can be any material for which a metal layer is capable of being applied. For instance, the substrate can be a synthetic material, such as a polymer. In various exemplary embodiments, a conductive substrate is, for example, at least one member selected from the group consisting of aluminum, aluminized or titanized polyethylene terephthalate belt (Mylar®).
Any metal or metal alloy can be selected for the metal or metallized substrate. Typical metals employed for this purpose include aluminum, zirconium, niobium, tantalum, vanadium, hafnium, titanium, nickel, stainless steel, chromium, tungsten, molybdenum, mixtures and combinations thereof, and the like. Useful metal alloys may contain two or more metals such as zirconium, niobium, tantalum, vanadium, hafnium, titanium, nickel, stainless steel, chromium, tungsten, molybdenum, mixtures and combinations thereof, and the like. Aluminum, such as mirror-finish aluminum, is selected in embodiments for both the metal substrate and the metal in the metallized substrate. All types of substrates may be used, including honed substrates, anodized substrates, bohmite-coated substrates and mirror substrates.
A metal substrate or metallized substrate can be selected. Examples of substrate layers selected for the present imaging members include opaque or substantially transparent materials, and may comprise any suitable material having the requisite mechanical properties. Thus, for example, the substrate can comprise a layer of insulating material including inorganic or organic polymeric materials, such as Mylar®, a commercially available polymer, Mylar® containing titanium, a layer of an organic or inorganic material having a semiconductive surface layer, such as indium tin oxide or aluminum arrange thereon, or a conductive material such as aluminum, chromium, nickel, brass or the like. The substrate may be flexible, seamless, or rigid, and may have a number of different configurations. For example, the substrate may comprise a plate, a cylindrical drum, a scroll, and endless flexible belt, or other configuration. In some situations, it may be desirable to provide an anticurl layer to the back of the substrate, such as when the substrate is a flexible organic polymeric material, such as for example polycarbonate materials, for example Makrolon® a commercially available material.
Optionally, a hole blocking layer is applied, in embodiments, to the substrate. Generally, electron blocking layers for positively charged photoreceptors allow the photogenerated holes in the charge generation layer at the top of the photoreceptor to migrate toward the charge (hole) transport layer below and reach the bottom conductive layer during the electrophotographic imaging process. Thus, an electron blocking layer is normally not expected to block holes in positively charged photoreceptors such as photoreceptors coated with a charge generation layer over a charge (hole) transport layer. For negatively charged photoreceptors, any suitable hole blocking layer capable of forming an electronic barrier to holes between the adjacent photoconductive layer and the underlying substrate layer may be utilized. A hole blocking layer may comprise any suitable material. Typical hole blocking layers utilized for the negatively charged photoreceptors may include, for example, polyamides such as Luckamide® (a nylon-6 type material derived from methoxymethyl-substituted polyamide), hydroxyl alkyl methacrylates, nylons, gelatin, hydroxyl alkyl cellulose, organopolyphosphazenes, organosilanes, organotitanates, organozirconates, silicon oxides, zirconium oxides, zinc oxides, titanium oxides, and the like. In embodiments, the hole blocking layer comprises nitrogen containing silanes.
The blocking layer, as with all layers herein, may be applied by any suitable technique such as, but not limited to, spraying dip coating, draw bar coating, gravure coating, silk screening, air knife coating, reverse roll coating, vacuum deposition, chemical treatment, and the like.
An adhesive layer may optionally be applied such as to the hole blocking layer. The adhesive layer may comprise any suitable material, for example, any suitable film forming polymer. Typical adhesive layer materials include, but are not limited to, for example, copolyester resins, polyarylates, polyurethanes, blends of resins, and the like. Any suitable solvent may be selected in embodiments to form an adhesive layer coating solution. Typical solvents include, but are not limited to, for example, tetrahydrofuran, toluene, hexane, cyclohexane, cyclohexanone, methylene chloride, 1,1,2-trichloroethane, monochlorobenzene, and mixtures thereof, and the like.
The photogenerating or charge-generating component converts light input into electron hole pairs. Examples of compounds suitable for use as the photogenerating component include rylenes. In embodiments, the rylene pigment is a rylene having a backbone consisting of peri-linked naphthalene units of the following structure:
benzimidazole terrylene (BZT) having the formula
benzimidazole quaterrylene (BZQ) having the formula of
piperidine-modified benzimidazole terrylene (PBZT) having the formula
piperidine-modified benzimidazole perylene (PBZP) having the formula
and piperidine-modified benzimidazole quaterrylene (PBZQ) having the formula
and the like, and mixtures and combinations thereof.
Photogenerating rylene is most responsive at a range of, for example, from about 500 nanometers to about 1,500 nanometers and is generally unresponsive to the light spectrum below about 500 nanometers. Typical wavelengths for photogeneration may be from about 600 nanometers to about 1,200 nanometers and may include a broadband between the two wavelengths. Single wavelength exposure may be from about 650 nanometers to about 1,000 nanometers. Photogenerating benzimidazole perylene absorbs most light at a range of from about 650 to about 700.
In general, rylene absorption spectra can be red-shifted via changing the chemical structures: (1) increasing number of rylene units; (2) aryl amination; (2) introduction of piperidine substitutents in the bay positions, etc. Photogenerating benzimidazole terrylene and benzimidazole quaterrylene absorb most light at longer wavelength than photogenerating benzimidazole perylene due to the presence of more peri-linked naphthalene units in their molecules. Furthermore, photogenerating piperidine-modified benzimidazole perylene, piperidine-modified benzimidazole terrylene and piperidine-modified benzimidazole quaterrylene absorb most light at longer wavelength than photogenerating benzimidazole perylene due to either the presence of more peri-linked naphthalene units in their molecules or/and piperidine substitutents in the bay positions.
The charge generation layer may comprise in embodiments single or multiple layers comprising inorganic or organic compositions and the like. Suitable polymeric film-forming binder materials for the charge generation layer and/or charge generating pigment include, but are not limited to, thermoplastic and thermosetting resins, such as polycarbonates, polyesters, polyamides, polyurethanes, polystyrenes, polyarylethers, polyarylsulfones, polybutadienes, polysulfones, polyethersulfones, polyethylenes, polypropylenes, polyimides, polymethylpentenes, polyphenylene sulfides, polyvinyl acetate, polysiloxanes, polyacrylates, polyvinyl acetals, amino resins, phenylene oxide resins, terephthalic acid resins, phenoxy resins, epoxy resins, phenolic resins, polystyrene and acrylonitrile copolymers, polyvinyl chloride, vinylchloride and vinyl acetate copolymers, acrylate copolymers, alkyd resins, cellulosic film formers, poly(amideimide), styrene-butadiene copolymers, vinylidinechloride-vinylchloride copolymers, vinylacetate-vinylidenechloride copolymers, carboxyl-modified vinyl acetate-vinylchloride copolymers, styrene-alkyd resins, polyvinylcarbazole, and mixtures thereof.
The photogenerating component, e.g., photogenerating composition or pigment, may be present in the resinous binder composition in various amounts, ranging from about 5% by volume to about 90% by volume (the photogenerating pigment is dispersed in about 10% by volume to about 95% by volume of the resinous binder); or from about 20% by volume to about 75% by volume (the photogenerating pigment is dispersed in about 25% by volume to about 80% by volume of the resinous binder composition). In embodiments, the rylene pigment is present in an amount of from about 20 to about 80 weight percent of the charge generation layer. When the photogenerating component contains photoconductive compositions and/or pigments in the resinous binder material, the thickness of the layer typically ranges from about 0.01 μm to about 10.0 μm, or from about 0.1 μm to about 3 μm. The charge generation layer thickness is often related to binder content, for example, higher binder content compositions typically require thicker layers for photogeneration. Thicknesses outside these ranges may also be selected.
In embodiments, the charge generation layer includes a rylene photoconductive pigment and a pigment sensitizing dopant having an electron acceptor molecule.
In embodiments, photogenerating rylene is selected from a group consisting of benzimidazole perylene, benzimidazole terrylene, benzimidazole quaterrylene, piperidine-modified benzimidazole perylene, piperidine-modified benzimidazole terrylene, piperidine-modified benzimidazole quaterrylene, and the like and mixtures and combinations thereof.
The dopant selected herein may comprise any suitable material having a suitable electron acceptor molecule. For example, in embodiments, the dopant is selected from the group consisting of 2,3-dichloro-5,6-dicyano-1,4-benzoquinone, tetracyanoethylene, 2,3,4,5-tetrabromobenzoquinone, 7,7,8,8-tetracyanoquinodimethane, chloranil, bromanil, 9-fluorenylidene, dinitroanthraquinone, p-nitrobenzonitrile, and mixtures and combinations thereof.
In embodiments, an imaging member is provided wherein the photoconductive pigment is benzimidazole perylene and the dopant is tetracyanoethylene.
In embodiments, an imaging member is provided wherein the photoconductive pigment is benzimidazole terrylene and the dopant is 2,3-dichloro-5,6-dicyano-1,4-benzoquinone.
In embodiments, an imaging member is provided wherein the photoconductive pigment is benzimidazole quaterrylene and the dopant is 2,3,4,5-tetrabromobenzoquinone.
In embodiments, an imaging member is provided wherein the photoconductive pigment is piperidine-modified benzimidazole perylene and the dopant is 9-fluorenylidene.
In embodiments, an imaging member is provided wherein the photoconductive pigment is piperidine-modified benzimidazole terrylene and the dopant is 7,7,8,8-tetracyanoquinodimethane.
In embodiments, an imaging member is provided wherein the photoconductive pigment is piperidine-modified benzimidazole quaterrylene and the dopant is dinitroanthraquinone.
The dopant material may be provided in any suitable amount. In embodiments, the dopant is present in an amount selected from about 0.1 weight percent to about 40 weight percent based upon the total weight of charge generation layer, or from about 1 weight percent to about 20 weight percent based upon the total weight of charge generation layer.
In embodiments, the dopant is incorporated in the charge generation layer by (1) adding it into an already prepared charge generation layer dispersion; or (2) milling it together with polymeric binder and photoconductive pigment in solvents. For example, in embodiments, the charge generation layer is coated from a charge generation layer dispersion that is prepared by adding the pigment sensitizing dopant having an electron acceptor molecule into the dispersion of a photoconductive pigment, for example a benzimidazole perylene photoconductive pigment, and a polymeric binder component, for example a polymeric resin, or by ball milling the pigment sensitizing dopant having an electron acceptor molecule, a photoconductive pigment, and a polymeric resin together.
In embodiments, the dopant is substantially completely soluble in a charge generation layer solvent.
Typical charge generation layer solvents comprising, for example, ketones, alcohols, aromatic hydrocarbons, halogenated aliphatic hydrocarbons, ethers, amines, amides, esters, and the like. Specific examples are cyclohexanone, acetone, methyl ethyl ketone, methanol, ethanol, butanol, amyl alcohol, toluene, xylene, chlorobenzene, carbon tetrachloride, chloroform, 1,2-dichloroethane, methylene chloride, trichloroethylene, tetrahydrofuran, dioxane, diethyl ether, dimethyl formamide, dimethyl acetamide, butyl acetate, ethyl acetate, methoxyethyl acetate, among others.
As with the various other layers described herein, the charge generation layer can be applied to underlying layers by any desired or suitable method. Any suitable technique may be employed to mix and thereafter apply the charge generation layer coating mixture with typical application techniques including, but not being limited to, spraying, dip coating, roll coating, wire wound rod coating, die coating, slot coating, slide coating, and the like. Drying, as with the other layers herein, can be effected by any suitable technique, such as, but not limited to, oven drying, infrared radiation drying, air drying, and the like.
The thickness of the imaging device typically ranges from about 2 μm to about 100 μm; from about 5 μm to about 50 μm, or from about 10 μm to about 30 μm. The thickness of each layer will depend on how many components are contained in that layer, how much of each component is desired in the layer, and other factors familiar to those in the art. In general, the ratio of the thickness of the charge transport layer to the charge generation layer can be maintained from about 2:1 to 200:1 and in some instances as great as 400:1. The charge transport layer, is substantially non-absorbing to visible light or radiation in the region of intended use but is electrically “active” in that it allows the injection of photogenerated holes from the photoconductive layer, i.e., charge generation layer, and allows these holes to be transported through itself to selectively discharge a surface charge on the surface of the active layer.
In embodiments, the at least one charge transport layer comprises from about 1 to about 7 layers. For example, in embodiments, the at last one charge transport layer comprises a top charge transport layer and a bottom charge transport layer, wherein the bottom layer is situated between the charge generation layer and the top layer.
Aryl amines selected for the charge, especially hole transport layers, which generally are of a thickness of from about 5 microns to about 75 microns, and more specifically, of a thickness of from about 10 microns to about 40 microns, include molecules of the following formula
wherein X is selected from the group consisting of alkyl, alkoxy, aryl and halogen, and in embodiments said alkyl contains from about 1 to about 10 carbon atoms, and in further embodiments those substitutents selected from the group consisting of Cl and CH3; and molecules of the following formula
wherein X and Y are independently alkyl, alkoxy, aryl, a halogen, or mixtures thereof, alkyl and alkoxy contain for example from 1 to about 25 carbon atoms, and more specifically from 1 to about 10 carbon atoms, such as methyl, ethyl, propyl, butyl, pentyl, and the corresponding alkoxides, aryl can contain from 6 to about 36 carbon atoms, such as phenyl, and the like, halogen includes chloride, bromide, iodide and fluoride. Substituted alkyls, alkoxys, and aryls can also be selected in embodiments.
Examples of specific aryl amines include N,N′-diphenyl-N,N′-bis(alkylphenyl)-1,1-biphenyl-4,4′-diamine wherein alkyl is selected from the group consisting of methyl, ethyl, propyl, butyl, hexyl, and the like; N,N′-diphenyl-N,N′-bis(halophenyl)-1,1′-biphenyl-4,4′-diamine wherein the halo substitutent is a chloro substitutent; N,N′-bis(4-butylphenyl)-N,N′-di-p-tolyl-[p-terphenyl]-4,4″-diamine, N,N′-bis(4-butylphenyl)-N,N′-di-m-tolyl-[p-terphenyl]-4,4″-diamine, N,N′-bis(4-butylphenyl)-N,N′-di-o-tolyl-[p-terphenyl]-4,4″-diamine, N,N′-bis(4-butylphenyl)-N,N′-bis-(4-isopropylphenyl)-[p-terphenyl]-4,4″-diamine, N,N′-bis(4-butylphenyl)-N,N′-bis-(2-ethyl-6-methylphenyl)-[p-terphenyl]-4,4″-diamine, N,N′-bis(4-butylphenyl)-N,N′-bis-(2,5-dimethylphenyl)[p-terphenyl]-4,4″-diamine, N,N′-diphenyl-N,N′-bis(3-chlorophenyl)-[p-terphenyl]-4,4″-diamine, and optionally mixtures thereof, and the like. Other known charge transport layer molecules can be selected, reference for example, U.S. Pat. Nos. 4,921,773 and 4,464,450, the disclosures of each of which are totally incorporated herein by reference. In embodiments, the charge transport layer comprises aryl amine mixtures.
In embodiments, the charge transport layer contains an antioxidant optionally comprised of, for example, a hindered phenol or a hindered amine.
Examples of components or materials optionally incorporated into the charge transport layers or at least one charge transport layer to, for example, enable improved lateral charge migration (LCM) resistance include hindered phenolic antioxidants, such as tetrakis methylene(3,5-di-tert-butyl-4-hydroxy hydrocinnamate) methane (IRGANOX™ 1010, available from Ciba Specialty Chemical), butylated hydroxytoluene (BHT), and other hindered phenolic antioxidants including SUMILIZER™ BHT-R, MDP-S, BBM-S, WX-R, NW, BP-76, BP-101, GA-80, GM and GS (available from Sumitomo Chemical Co., Ltd.), IRGANOX™ 1035, 1076, 1098, 1135, 1141, 1222, 1330, 1425WL, 1520L, 245, 259, 3114, 3790, 5057 and 565 (available from Ciba Specialties Chemicals), and ADEKA STAB™ AO-20, AO-30, AO40, AO-50, AO-60, AO-70, AO-80 and AO-330 (available from Asahi Denka Co., Ltd.); hindered amine antioxidants such as SANOL™ LS-2626, LS-765, LS-770 and LS-744 (available from SNKYO CO., Ltd.), TINUVIN™ 144 and 622LD (available from Ciba Specialties Chemicals), MARK™ LA57, LA67, LA62, LA68 and LA63 (available from Asahi Denka Co., Ltd.), and SUMILIZER™ TPS (available from Sumitomo Chemical Co., Ltd.); thioether antioxidants such as SUMILIZER™ TP-D (available from Sumitomo Chemical Co., Ltd); phosphite antioxidants such as MARK™ 2112, PEP-8, PEP-24G, PEP-36, 329K and HP-10 (available from Asahi Denka Co., Ltd.); other molecules such as bis(4-diethylamino-2-methylphenyl)phenylmethane (BDETPM), bis-[2-methyl-4-(N-2-hydroxyethyl-N-ethyl-aminophenyl)]-phenylmethane (DHTPM), and the like. The weight percent of the antioxidant in at least one of the charge transport layers is from about 0 to about 20, from about 1 to about 10, or from about 3 to about 8 weight percent.
Optionally, an overcoat layer can be employed to improve resistance of the photoreceptor to abrasion. An optional anticurl back coating may further be applied to the surface of the substrate opposite to that bearing the photoconductive layer to provide flatness and/or abrasion resistance where a web configuration photoreceptor is desired. These overcoating and anticurl back coating layers are well known in the art, and can comprise for example thermoplastic organic polymers or inorganic polymers that are electrically insulating or slightly semiconductive. In embodiments, overcoatings are continuous and have a thickness of less than about 10 microns, although the thickness can be outside this range. The thickness of anticurl backing layers is selected in embodiments sufficient to balance substantially the total forces of the layer or layers on the opposite side of the substrate layer.
Various exemplary embodiments encompassed herein include a method of imaging which includes generating an electrostatic latent image on an imaging member, developing a latent image, and transferring the developed electrostatic image to a suitable substrate.
Further embodiments encompassed within the present disclosure include methods of imaging and printing with the photoresponsive devices illustrated herein. Various exemplary embodiments include methods including forming an electrostatic latent image on an imaging member; developing the image with a toner composition including, for example, at least one thermoplastic resin, at least one colorant, such as pigment, at least one charge additive, and at least one surface additive; transferring the image to a necessary member, such as, for example any suitable substrate, such as, for example, paper; and permanently affixing the image thereto. In various exemplary embodiments in which the embodiment is used in a printing mode, various exemplary imaging methods include forming an electrostatic latent image on an imaging member by use of a laser device or image bar; developing the image with a toner composition including, for example, at least one thermoplastic resin, at least one colorant, such as pigment, at least one charge additive, and at least one surface additive; transferring the image to a necessary member, such as, for example any suitable substrate, such as, for example, paper; and permanently affixing the image thereto.
In a selected embodiment, an image forming apparatus for forming images on a recording medium comprises a) a photoreceptor member having a charge retentive surface to receive an electrostatic latent image thereon, wherein said photoreceptor member comprises a metal or metallized substrate, a charge generating layer comprising a rylene photoconductive pigment and a pigment sensitizing dopant having an electron acceptor molecule, and a charge transport layer comprising charge transport materials dispersed therein; b) a development component to apply a developer material to said charge-retentive surface to develop said electrostatic latent image to form a developed image on said charge-retentive surface; c) a transfer component for transferring said developed image from said charge-retentive surface to another member or a copy substrate; and d) a fusing member to fuse said developed image to said copy substrate.
In embodiments, imaging members are provided wherein the charge generation layer is more sensitive than an imaging member having a comparable charge generation layer that is free of the dopant. For example, in embodiments, an imaging member herein provides a charge generation layer that is about 5% to about 25% more sensitive than charge generation layer of a comparable device not comprising the present sensitized charge generation layer.
In embodiments, an imaging member having a charge generation layer comprising a dopant exhibits low imaging ghosting than an imaging member having a comparable charge generation layer that is free of the dopant.
The following Examples are being submitted to further define various species of the present disclosure. These Examples are intended to be illustrative only and are not intended to limit the scope of the present disclosure. Also, parts and percentages are by weight unless otherwise indicated.
Multilayered photoreceptors of the rigid drum design (Example 1, 2 and Comparative Example 1, 2) were fabricated by conventional coating technology with an aluminum drum of 34 millimeters in diameter as the substrate. The four drum photoreceptors contained the same undercoat layer and charge transport layer. The only difference is that Comparative Example 1 contained a charge generation layer (CGL) comprising a film forming polymer binder and a photoconductive component, benzimidazole perylene; Comparative Example 2 contains a charge generation layer (CGL) comprising a film forming polymer binder and a photoconductive component, benzimidazole terrylene; Example 1 contained the same layers as Comparative Example 1 except that tetracyanoethylene was incorporated into the charge generation layer; Example 2 contains the same layers as Comparative Example 2 except that 2,3-dichloro-5,6-dicyano-1,4-benzoquinone is incorporated into the charge generation layer.
The undercoat layer is a three-component undercoat which coating solution was prepared as follows: zirconium acetylacetonate tributoxide (ORGATICS™ ZC-540, available from Matsumoto Kosho Co., Japan, 35.5 grams), γ-aminopropyltriethoxysilane (4.8 grams) and polyvinyl butyral S-LEC™ BM-S (degree of polymerization=850, mole percent of vinyl butyral>=70, mole percent of vinyl acetate=4 to 6, mole percent of vinyl alcohol=25, available from Sekisui Chemical Co., Ltd., Tokyo, Japan, 2.5 grams) was dissolved in n-butanol (52.2 grams). The coating solution was coated via a ring coater, and the layer was pre-heated at 59° C. for 13 minutes, humidified at 58° C. (dew point=54° C.) for 17 minutes, and dried at 135° C. for 8 minutes. The thickness of the undercoat layer was approximately 1.3 μm.
1.7 grams of benzimidazole perylene pigment was mixed with about 0.8 grams of polyvinyl butyral, Butvar B-79 (MW=50,000-80,000, available from Solutia, St. Louis, Mo.), and 47.5 grams of n-butyl acetate. The mixture was milled in an ATTRITOR mill with about 200 grams of 1 mm Hi-Bea borosilicate glass beads for about 3 hours. The dispersion was filtered through a 20-μm nylon cloth filter. The benzimidazole perylene charge generation layer dispersion was applied on top of the above undercoat layer. The thickness of the charge generation layer was approximately 0.4 μm.
To the above CGL dispersion (Comparative Example 1) was added 0.125 grams of tetracyanoethylene, and the resulting dispersion was allowed to mix for at least 2 hours. The resulting benzimidazole perylene charge generation layer dispersion was applied on top of the above undercoat layer. The thickness of the charge generation layer was approximately 0.4 μm.
1.7 grams of benzimidazole terrylene pigment is mixed with about 0.8 grams of polyvinyl butyral, Butvar B-79 (Mw=50,000-80,000, available from Solutia, St. Louis, Mo.), and 47.5 grams of n-butyl acetate. The mixture is milled in an ATTRITOR mill with about 200 grams of 1 mm Hi-Bea borosilicate glass beads for about 3 hours. The dispersion is filtered through a 20-μm nylon cloth filter. The benzimidazole terrylene charge generation layer dispersion is applied on top of the above undercoat layer. The thickness of the charge generation layer is approximately 0.4 μm.
To the above CGL dispersion (Comparative Example 2) is added 0.25 grams of 2,3-dichloro-5,6-dicyano-1,4-benzoquinone, and the resulting dispersion is allowed to mix for at least 2 hours. The resulting benzimidazole terrylene charge generation layer dispersion is applied on top of the above undercoat layer. The thickness of the charge generation layer is approximately 0.4 μm.
Subsequently, a 26-μm charge transport layer was coated on top of the charge generation layer, respectively, which coating dispersion was prepared as follows: N,N′-diphenyl-N,N-bis(3-methylphenyl)-1,1′-biphenyl-4,4′-diamine (5.38 grams), a film forming polymer binder PCZ 400 [poly(4,4′-dihydroxy-diphenyl-1-1-cyclohexane, Mw=40,000)] available from Mitsubishi Gas Chemical Company, Ltd. (7.13 grams), and PTFE POLYFLON L-2 microparticle (1 gram) available from Daikin Industries were dissolved/dispersed in a solvent mixture of 20 grams of tetrahydrofuran (THF) and 6.7 grams of toluene via CAVIPRO 300 nanomizer (Five Star technology, Cleveland, Ohio). The charge transport layer was dried at about 120° C. for about 40 minutes.
The above prepared photoreceptor devices (Comparative Example 1 and Example 1) were tested in a scanner set to obtain photo-induced discharge cycles, sequenced at one charge-erase cycle followed by one charge-expose-erase cycle, wherein the light intensity was incrementally increased with cycling to produce a series of photo-induced discharge characteristic curves from which the photosensitivity and surface potentials at various exposure intensities were measured. Additional electrical characteristics were obtained by a series of charge-erase cycles with incrementing surface potential to generate several voltages versus charge density curves. The scanner was equipped with a scorotron set to a constant voltage charging at various surface potentials. The devices were tested at surface potentials of 700 volts with the exposure light intensity incrementally increased by means of regulating a series of neutral density filters; the exposure light source was a 780-nanometer light emitting diode. The aluminum drum was rotated at a speed of 55 revolutions per minute to produce a surface speed of 277 millimeters per second or a cycle time of 1.09 seconds. The xerographic simulation was completed in an environmentally controlled light tight chamber at ambient conditions (40 percent relative humidity and 22° C.). Two photo-induced discharge characteristic (PIDC) curves were generated. The photosensitivity (initial slope of the PIDC) of Example 1 was −130 Vcm2/erg; as comparison, the photosensitivity of Comparative Example 1 was −110 Vcm2/erg Incorporation of tetracyanoethylene into charge generation layer increased benzimidazole perylene photosensitivity by about 20%.
Multilayered photoreceptors of the flexible belt design are fabricated by conventional coating technology with a biaxially oriented polyethylene naphthalate substrate (KALEDEX™ 2000) having a thickness of 3.5 mils as the substrate. All the photoreceptors contain the same blocking layer, adhesive layer, and charge transport layers. The difference is that Comparative Example 3 contains no pigment sensitizing dopant having an electron acceptor molecule in the charge generation layer. Comparative Example 3 is prepared comprising a charge generation layer (CGL) comprising a film forming polymer binder and a photoconductive component, piperidine-modified benzimidazole perylene. Example 3 contains the same layers as Comparative Example 3 except that 7,7,8,8-tetracyanoquinodimethane is incorporated into the CGL.
The lower layers were prepared by providing a 0.02 micrometer thick titanium layer coated (the coater device) on a biaxially oriented polyethylene naphthalate substrate (KALEDEX™ 2000) having a thickness of 3.5 mils, and applying thereon, with a gravure applicator, a blocking layer solution containing 50 grams of 3-amino-propyltriethoxysilane, 41.2 grams of water, 15 grams of acetic acid, 684.8 grams of denatured alcohol, and 200 grams of heptane. This layer was then dried for about 1 minute at 120° C. in the forced air dryer of the coater. The resulting blocking layer had a dry thickness of 500 Angstroms. An adhesive layer was then prepared by applying a wet coating over the blocking layer, using a gravure applicator, and which adhesive contains 0.2 percent by weight based on the total weight of the solution of copolyester adhesive (ARDEL D100™ available from Toyota Hsutsu Inc.) in a 60:30:10 volume ratio mixture of tetrahydrofuran/monochlorobenzene/methylene chloride. The adhesive layer was then dried for about 5 minutes at 135° C. in the forced air dryer of the coater. The resulting adhesive layer had a dry thickness of 200 Angstroms.
0.45 grams of the known polycarbonate LUPILON 200™ (PCZ-200) or POLYCARBONATE Z™, weight average molecular weight of 20,000, available from Mitsubishi Gas Chemical Corporation, is mixed with 50 milliliters of tetrahydrofuran (THF) into a 4 ounce glass bottle. To this solution are added 2.4 grams of piperidine-modified benzimidazole perylene and 300 grams of ⅛-inch (3.2 millimeters) diameter stainless steel shot. This mixture is then placed on a ball mill for 8 hours. Subsequently, 2.25 grams of PCZ-200 are dissolved in 46.1 grams of tetrahydrofuran, and added to the piperidine-modified benzimidazole perylene dispersion. This slurry is then placed on a shaker for 10 minutes. The resulting dispersion is, thereafter, applied to the above adhesive interface with a Bird applicator to form a charge generation layer having a wet thickness of 0.50 mil. A strip about 10 millimeters wide along one edge of the substrate web bearing the blocking layer and the adhesive layer is deliberately left uncoated by any of the charge generation layer material to facilitate adequate electrical contact by the ground strip layer that was applied later. The charge generation layer is dried at 120° C. for 1 minute in a forced air oven to form a dry charge generation layer having a thickness of 1.0 micrometer.
To the above CGL dispersion (Comparative Example 3) is added 0.50 grams of 7,7,8,8-tetracyanoquinodimethane, and the resulting dispersion is allowed to mix for at least 2 hours. The resulting piperidine-modified benzimidazole perylene charge generation layer dispersion is applied on top of the above blocking layer. The thickness of the charge generation layer is approximately 1.0 μm.
The resulting imaging member web was then overcoated with a two-layer charge transport layer. Specifically, the charge generation layer was overcoated with a charge transport layer (the bottom layer) in contact with the charge generation layer. The bottom layer of the charge transport layer was prepared by introducing into an amber glass bottle in a weight ratio of 1:1 N,N′-diphenyl-N,N-bis(3-methylphenyl)-1,1′-biphenyl-4,4′-diamine, and MAKROLON 5705®, a known polycarbonate resin having a molecular weight average of from about 50,000 to 100,000, commercially available from Farbenfabriken Bayer A.G. The resulting mixture was then dissolved in methylene chloride to form a solution containing 15 percent by weight solids. This solution was applied on the charge generation layer to form the bottom layer coating that upon drying (120° C. for 1 minute) had a thickness of 14.5 microns. During this coating process, the humidity was equal to or less than 15 percent.
The bottom layer of the charge transport layer was then overcoated with a top layer. The charge transport layer solution of the top layer was prepared as described above for the bottom layer. This solution was applied on the bottom layer of the charge transport layer to form a coating that upon drying (120° C. for 1 minute) had a thickness of 14.5 microns. During this coating process the humidity was equal to or less than 15 percent.
It will be appreciated that various of the above-disclosed and other features and functions, or alternatives thereof, may be desirably combined into many other different systems or applications. Also that various presently unforeseen or unanticipated alternatives, modifications, variations or improvements therein may be subsequently made by those skilled in the art which are also intended to be encompassed by the following claims. Unless specifically recited in a claim, steps or components of claims should not be implied or imported from the specification or any other claims as to any particular order, number, position, size, shape, angle, color, or material.
Illustrated in U.S. Ser. No. ______ (Attorney Docket Number 20052105-US-NP), of Jin Wu et al., filed ______, entitled ‘Imaging Members and Method for Sensitizing a Charge Generation Layer of an Imaging Member,’ the disclosure of which is totally incorporated herein by reference, is, in embodiments, an imaging member comprising a substrate; an optional undercoat layer; a charge generation layer comprising photoconductive pigment and a pigment sensitizing dopant comprising in embodiments zinc dialkyldithiophosphate; and a charge transport layer. Illustrated in U.S. Ser. No. ______ (Attorney Docket Number 20052046-US-NP), of Jin Wu et al., filed ______, entitled ‘Imaging Members and Method for Sensitizing a Charge Generation Layer of an Imaging Member,’ the disclosure of which is totally incorporated herein by reference, is in embodiments, an imaging member comprising a substrate; an optional undercoat layer; a charge generation layer comprising photoconductive pigment, in embodiments, phthalocyanine, and a pigment sensitizing dopant comprising in embodiments an electron acceptor molecule, in embodiments, tetracyanoethylene; and a charge transport layer.
