The present invention relates to an inductance element including a magnetic core and a coil embedded in the magnetic core.
Japanese Unexamined Patent Application Publication No. 2002-324714 discloses a coil-embedded dust core including: a compact formed from ferromagnetic metal particles coated with an insulating material; and a coil embedded in the compact and formed from a flat, insulation-coated conductor wound into a coil shape. It is stated that the coil-embedded dust core is produced by subjecting the coil and a powder mixture of a lubricant and an insulation-treated ferromagnetic powder for the dust core to compression molding (FIGS. 9 to 11 in Japanese Unexamined Patent Application Publication No. 2002-324714).
Inductance elements including the coil-embedded dust core disclosed in Japanese Unexamined Patent Application Publication No. 2002-324714 are widely used as components for driving displays of portable communication terminals such as smartphones. There is a continuous need for thinner and smaller portable communication terminals, and there is also a continuous need for display units having improved performance such as improved maximum display brightness. In view of the foregoing needs, inductance elements are required to be reduced in size (including height) and improved in withstand voltage (to address increased driving voltage) while appropriate basic characteristics (such as L/DCR) of the elements are maintained, but these requirements are in a trade-off relation.
In view of the foregoing circumstances, the present invention provides an inductance element that can maintain an appropriate withstand voltage and appropriate element functions even when the inductance element is reduced in size. The present invention also provides a method for producing the inductance element.
One aspect of the present invention provided to solve the foregoing problem provides an inductance element including: a magnetic core that is a compact containing a magnetic powder; and a coil having a portion embedded in the magnetic core, wherein the portion of the coil that is embedded in the magnetic core includes a wound portion formed by winging a wire-shaped coil material including a wire-shaped conductive material and an insulating coating that covers a surface of the conductive material, wherein the insulating coating on the wound portion has a portion located in a region capable of being in contact with the magnetic powder, the portion of the insulating coating including a thin-walled portion reduced in thickness due to contact with the magnetic powder, and wherein a biting ratio R defined by formula (I) below is from 0.4 to 0.85 inclusive:
R=ds/B (I)
where B is the average thickness (unit: μm) of inter-coil insulating coatings, the inter-coil insulating coatings being portions of the insulating coating that are located between two adjacent portions of the conductive material in the wound portion, the average thickness being the arithmetic mean of measurement results obtained by measuring the thicknesses of the inter-coil insulating coatings at at least 100 points, and ds is an upper biting limit (unit: μm) obtained by measuring a biting depth d (unit: μm) at at least 15 points in the inductance element, approximating a frequency distribution of the results of the measurement by a normal distribution, and computing, as the upper biting limit, the sum (da+3.99σ) of the mean da of the normal distribution and the product of 3.99 and the standard deviation σ of the normal distribution, the biting depth being a value obtained by subtracting, from the average thickness B of the inter-coil insulating coatings, the thickness of the thin-walled portion that is smaller than the average thickness B of the inter-coil insulating coatings.
In this inductance element, an appropriate reduction in thickness of part of the insulating coating on the wound portion of the coil is achieved (i.e., the insulating coating has thin-walled portions having an appropriate thickness). With this structure, even when the inductance element is reduced in thickness and height, a reduction in the basic characteristics of the inductance element, particularly a reduction in L/DCR, can be prevented while the insulating coating included in the coil used has a thickness enough to prevent an excessive reduction in withstand voltage.
In the above inductance element, the average thickness B of the inter-coil insulating coatings may be from 1 μm to 5 μm inclusive. When the average thickness B of the inter-coil insulating coatings is within the above range, the formation of pinholes in the insulating coating is prevented suitably, and the shape of the inductance element can be reduced in size and height.
In the above inductance element, at least part of the magnetic powder may be composed of an amorphous alloy material. Generally, the magnetic powder composed of the amorphous alloy material is hard and resists deformation caused by pressure applied from the outside or pressure due to thermal expansion during production of the inductance element. Therefore, the magnetic powder can easily bite into the insulating coating, and the thin-walled portions are easily formed.
In the above inductance element, the magnetic powder has a median diameter D50 of preferably from 1 μm to 15 μm inclusive from the viewpoint of the ease of formation of the thin-walled portions.
In the above inductance element, the insulating coating may contain a polyimide-based material. The inductance element may be produced by heating the wound portion of the coil embedded in the magnetic core and causing the magnetic powder to bite into the insulating coating by utilizing the difference between the thermal expansion coefficient of the wound portion and the thermal expansion coefficient of the magnetic core to thereby form the thin walled portions. In this case, when the insulating coating is formed of a material that deforms excessively under heating, the thickness of the thin-walled portions tends to be reduced excessively, and therefore the possibility of dielectric breakdown is high. Therefore, when the thin-walled portions are formed using the above method, it is preferable that the insulating coating contains a high-softening point material such as polyimide.
In the above inductance element, the conductive material may have a strip shape, and the wire-shaped coil material may be wound in the wound portion using an edgewise winding.
In the above inductance element, it is sometimes preferable that the thickness of the thin-walled portions is measured on the insulating coating on the wire-shaped coil material at an end of the wound portion in a direction along a winding center line.
The above inductance element may have a portion in which an embedded depth of the wire-shaped coil material into the magnetic core in a direction along a winding center line of the wound portion is 0.25 mm or less. To achieve a reduction in height of the inductance element while the basic characteristics are maintained, the embedded depth of the wire-shaped coil material in the above region tends to be small. However, as described above, in the inductance element according to the present invention, the withstand voltage and the basic characteristics (particularly L/DCR) can be appropriately maintained even when the inductance element is reduced in height. Therefore, the inductance element may have a portion with an embedded depth of 0.25 mm or less.
Another aspect of the present invention provides a method for producing the inductance element according to the present invention. The production method includes: a molding step of placing, in a mold, a raw material member for forming the magnetic core and the coil including the wound portion formed from the wire-shaped coil material including the insulating coating and the conductive material and subjecting the raw material member and the coil to compression molding to obtain a molded product in which the wound portion is embedded in the magnetic core; and a heat treatment step of heating the molded product to thermally expand the conductive material in the wound portion, the magnetic powder being pressed into the insulating coating on the wound portion to thereby form the thin-walled portion in which the insulating coating is reduced in thickness.
With the above production method, the inductance element having the thin-walled portion can be formed efficiently and stably. When the thermal treatment conditions in the heat treatment step are set appropriately, strain generated in the constituent materials (particularly, the magnetic powder) of the magnetic core in the molding step can be relaxed.
It is sometimes preferable that a pressurization direction in the molding step is a direction along a winding center line of the wound portion.
Preferably, a heating temperature in the heat treatment step is equal to or lower than two times the softening temperature of a material forming the insulating coating. In this case, the magnetic powder is prevented from excessively biting into the insulating coating in a stable manner in the heat treatment step.
An inductance element 1 according to an embodiment of the present invention includes a powder compact serving as a magnetic core 20 and a coil 10 embedded in the magnetic core 20. In
As shown in
The conductive material 11M of the conductive strip 11 is formed of a conductive material such as copper, a copper alloy, aluminum, or an aluminum alloy, and the coating resin layer 12 is formed of, for example, a polyimide-based material, an epoxy-based material, or a polyamide-imide-based material. As described later, it is preferable from the viewpoint of producing the inductance element 1 according to the embodiment of the present invention efficiently that the material forming the coating resin layer 12 has high heat resistance and, particularly, has a high softening temperature. Therefore, a polyimide-based material having high heat resistance is suitable for the material forming the coating resin layer 12.
In
As showing in
As shown in
A portion of the first end portion 13 that extends forward from the fourth fold line 14d is a first terminal portion 15, and a portion of the second end portion 16 that extends forward from the fourth fold line 17d is a second terminal portion 18.
When the inductance element 1 is placed on an unillustrated printed circuit board, the inductance element 1 is placed with the first terminal portion 15 and the second terminal portion 18 facing down. Therefore, the upward surface in
As shown in
As shown in
As shown in
In recent years, there is an increasing need for a inductance element 1 reduced in size, particularly in height. One method for meeting the need is to reduce the thickness of the coating resin layer 12. In practice, the thickness of a conventional coating resin layer 12 is about 10 μm or more. However, recently, the thickness is reduced to 5 μm or less. Only from the viewpoint of achieving a reduction in the height of the inductance element 1, it is preferable to reduce the thickness of the coating resin layer 12. However, if the thickness is excessively small, the influence of variations in thickness is significant, and the withstand voltage is reduced significantly. Therefore, in practice, the lower limit of the thickness is about 1 μm.
The magnetic core 20 is located around the wound portion 10C. To achieve a reduction in height of the inductance element 1, the volumes of regions 20A, 20B (see
As will be shown in Examples described later, when the thickness of the coating resin layer 12 is increased in order to increase the withstand voltage, L/DCR tends to decrease.
As described above, when the thickness of the coating resin layer 12 is simply reduced in order to reduce the height of the inductance element 1, the characteristics of the coil may deteriorate, and particularly the withstand voltage may be reduced. In particular, when the thickness of the coating resin layer 12 is less than 1 μm, variations in the thickness of the coating resin layer 12 increase. In this case, the conductive material 11M may not be fully covered with the coating resin layer 12, and it is highly possible that uncovered portions (such as pinholes) are formed. In this inductance element 1, the coil 10 has portions in which the conductive material 11M is exposed, so that the withstand voltage can be 0 V.
When the thickness of the coating resin layer 12 is increased to prevent a reduction in the withstand voltage, a reduction in L/DCR may occur. It is difficult to increase the L/DCR while the withstand voltage is maintain.
The inventors have conducted studies to solve the above problem and found that, by controlling the biting depth of magnetic powder into the coating resin layer 12 as described using
As shown in
Although the reason is not clear, the presence of the thin-walled portions 12t improves the coil characteristics, particularly L/DCR, of the inductance element 1. This could be because a larger amount of the magnetic powder can be charged into the inductance element 1. When these thin-walled portions 12t are not formed, it is not expected to further improve L/DCR even though the thickness of the coating resin layer 12 in the wound portion 10C is set to a producible thickness (2 to 5 μm) in order to achieve a reduction in size and height of the inductance element 1. However, by providing the thin-walled portions 12t appropriately, the coil characteristics, e.g., L/DCR, can be further improved.
Specifically, when the biting ratio R set based on the average thickness B of the inter-coil insulating coatings 12i and the biting depth d defined below is set appropriately, a reduction in the withstand voltage and deterioration in the coil characteristics can be properly prevented even when the inductance element is reduced in size and height.
In the present specification, “the average thickness B of the inter-coil insulating coatings 12i” means the arithmetic average (unit: μm) of measurement results obtained by measuring the thicknesses of the inter-coil insulating coatings 12i at 100 points or more. Each inter-coil insulating coating 12i is an insulating film (coating resin layer 12) disposed between two adjacent portions of the conductive material 11M in the wound portion 10C. Generally, two inter-coil insulating coatings 12i are disposed between two adjacent portions of the conductive material 11M so as to be close to each other (see
In the present specification, the “biting depth d” means a value (unit: μm) obtained by subtracting, from the average thickness B of the inter-coil insulating coatings 12i, the thickness “a” of a thin-walled portion 12t thinner than the average thickness B of the inter-coil insulating coatings 12i.
In the present specification, “the upper biting limit ds” is defined as follows. The biting depth d in one inductance element is measured at least 15 points, and the frequency distribution of the measurement results obtained is approximated by a normal distribution. The sum (unit: μm) of the mean da (unit: μm) of the normal distribution and the product of 3.99 and the standard deviation σ (unit: μm) of the normal distribution (i.e., da+3.99σ) is used as the upper biting limit ds. In this case, the process capability index Cpk is 1.33. The upper biting limit ds is a substantial upper limit of the biting depth d that is statistically inferred. The number of measurement points at which the biting depth d is measured to determine the normal distribution is preferably 20 or more and more preferably 30 or more. The upper limit of the number of measurement points is not set. From the viewpoint of further increasing the accuracy of the upper biting limit ds, it is sufficient that the number of measurement points be about 100.
In the present specification, the “biting ratio R” is defined by the following formula (I) using the average thickness B of the inter-coil insulating coatings 12i and the upper biting limit ds:
R=ds/B (I)
In the inductance element 1 according to the embodiment of the present invention, the biting ratio R is from 0.4 to 0.85 inclusive.
When the biting ratio R is 0.4 or more, deterioration in the coil characteristics, particularly a reduction in L/DCR, can be properly prevented. From the viewpoint of preventing the reduction in L/DCR more stably, it is sometimes preferable that the biting ratio R is 0.45 or more. When the biting ratio R is 0.85 or less, a reduction in the withstand voltage can be properly prevented. From the viewpoint of preventing the reduction in the withstand voltage more stably, it is sometimes preferable that the biting ratio R is 0.8 or less.
From the viewpoint of facilitating the control of the characteristics of the inductance element 1 appropriately using the biting ratio R, it is preferable that the components of the inductance element 1 satisfy the following conditions.
The average thickness B of the inter-coil insulating coatings 12i is preferably from 1 μm to 5 μm inclusive. When the average thickness B of the inter-coil insulating coatings 12i is 1 μm or more, a reduction in the withstand voltage of the inductance element 1 can be prevented more stably. From this point of view, it is sometimes preferable that the average thickness B of the inter-coil insulating coatings 12i is 1.5 μm or more and more preferably 2 μm or more.
Preferably, the magnetic powder 20P is composed at least partially of an amorphous alloy material. Generally, the amorphous alloy material is harder than crystalline alloy materials. With the amorphous alloy material, the thin-walled portions 12t are easily formed. From the viewpoint of forming the thin-walled portions 12t appropriately, it is sometimes preferable that the magnetic powder 20P contains the amorphous alloy material in an amount of 50% by mass or more. No limitation is imposed on the specific composition of the amorphous alloy material. Specific examples of the amorphous alloy material include Fe—Si—B-based alloys, Fe—P—C-based alloys, and Co—Fe—Si—B-based alloys. The amorphous alloy material may be composed of one material or a plurality of materials.
An Fe—P—C-based material is an example of the amorphous alloy material, and a specific example of the composition of the Fe—P—C-based material is an Fe-based amorphous alloy represented by a composition formula Fe100 at %-a-b-c-x-y-z-tNiaSnbCrcPxCyBzSit with 0 at %≤a≤10 at %, 0 at %≤b≤3 at %, 0 at %≤c≤6 at %, 6.8 at %≤x≤13 at %, 2.2 at %≤y≤13 at %, 0 at %≤z≤9 at %, and 0 at %≤t≤7 at %. In the above composition formula, Ni, Sn, Cr, B, and Si are optional additional elements.
Preferably, the median diameter D50 (a particle diameter at which the cumulative volume from the small diameter side in a volume-based particle size distribution is 50 vol %. The particle size distribution is typically determined by particle size distribution measurement using a laser diffraction-scattering method) of the magnetic powder is from 1 μm to 15 μm inclusive.
Preferably, the conductive material 11M has a strip shape, and the wire-shaped coil material 11 in the wound portion 10C is wound using an edgewise winding. With the edgewise winding, the density of the conductive material 11M in the wound portion 10C can be increased, and the coil characteristics can be easily improved. In this case, it is preferable that the thicknesses of the thin-walled portions 12t are measured on the insulating coating (insulating coating end portion 12o) on the wire-shaped coil material 11 at an end portion (a winding axis end portion 10c or 10d) in a direction along the winding center line O in the wound portion 10C. The winding axis end portions 10c and 10d are regions in which the magnetic flux tends to be high, and the thicknesses of the thin-walled portions 12t in these region can largely influence on the coil characteristics, particularly L/DCR.
When the above formula (I) is satisfied, a reduction in the withstand voltage and deterioration in the coil characteristics can be prevented properly even when the inductance element 1 is a low-height inductance element having a portion in which the embedded depth of the wire-shaped coil material 11 into the magnetic core 20 in the direction along the winding center line O of the wound portion 10 is 0.25 μm or less.
No limitation is imposed on the method for producing the inductance element 1 according to the embodiment of the present invention. When a production method described below is used, the inductance element 1 can be produced efficiently.
The method for producing the inductance element 1 according to the preceding embodiment of the present invention includes a molding step and a heat treatment step described below.
In the molding step, the raw material members for forming the magnetic core 20 and the coil 10 including the wound portion 10C formed by winding the wire-shaped coil material 11 including the insulating coating (the coating resin layer 12) and the conductive material 11M are placed in a mold 30 and subjected to compression molding. As shown in
When a member 1P composed of the first raw material member 201, the coil 10, and the second raw material member 202 is placed in the cavity of the mold 30, the upper mold 32 and the lower mold 33 are disposed close to each other in the direction along the winding center line O of the coil 10 as shown in
No limitation is imposed on the molding conditions. The pressure and heating temperature may be set in consideration of the amount of deformation and the materials (the magnetic powder 20P, resin components, etc.) contained in the first raw material member 201 and the second raw material member 202. When the pressure is applied under heating, the pressure applied may be set to a lower value. When the magnetic powder 20P contains a powder composed of an amorphous alloy, it is sometimes preferable to increase the pressure. In a non-limiting example of the pressure, the pressure is 0.01 GPa to 5 GPa. It may be preferable that the pressure is about 0.5 GPa to about 3 GPa when the magnetic powder 20P contains a powder composed of an amorphous alloy.
A molded product in which the wound portion 10C of the coil 10 is embedded in the magnetic core 20 is obtained through the molding step.
In the heat treatment step subsequent to the molding step, the molded product is heated to thermally expand the conductive material 11M in the wound portion 10C of the coil 10. From the viewpoint of appropriate thermal expansion, it is preferable that the thermal expansion coefficient of the conductive material 11M is larger than that of the magnetic core 20. From this point of view, the conductive material 11M is preferably a copper-based material or an aluminum-based material. When the conductive material 11M having a larger thermal expansion coefficient than the magnetic core 20 is expanded by heat, the coating resin layer 12 on the wound portion 10C of the coil 10 is pressed against the magnetic powder 20P. Part of the magnetic powder 20P thereby bites into the coating resin layer 12, and the thin-walled portions 12t with a reduced thickness are formed in the coating resin layer 12.
No limitation is imposed on the heat treatment conditions, so long as the thin-walled portions 12t are formed appropriately. In a non-limiting example of the heat treatment conditions, the maximum reachable temperature is 300° C. to 600° C., and the heating time is 10 minutes to 10 hours. Working strain in the molded product may be relaxed by the heat treatment in the heat treatment step.
As described above, in the heat treatment step, the formed product is heated. Therefore, when the coating resin layer 12 in the wound portion 10C of the coil 10 includes a fusible layer having a low softening point, the material forming the fusible layer (generally a resin material) is fused by heating and decomposed, so that the fusible layer does not function as the insulating coating for the conductive material 11M. When the inductance element 1 is produced by the production method according to the present embodiment of the invention, the coating resin layer 12 includes a layer of a material having a softening point high enough to allow the coating resin layer 12 to serve as the insulating coating even after the heat treatment step. Specific examples of the softening point of the material include 400° C. to 500° C., and specific examples of the high-softening point material include polyimide.
The exterior of the molded product subjected to the heat treatment step is optionally covered with a coating, and electrodes are formed by printing, plating, etc. The inductance element 1 according to the embodiment of the present invention is thereby obtained.
The above embodiments are described in order to facilitate understanding of the present invention and are not intended to limit the present invention. Therefore, the elements disclosed in the above embodiments involve all design changes and equivalents that fall within the technical scope of the present invention.
For example, in the wound portion 10C of the coil 10 included in the inductance element 1, the wire-shaped coil material 11 having a rectangular cross section is wound such that its short sides are disposed in the direction along the winding center line O, but this is not a limitation. The wire-shaped coil material 11 having a rectangular cross section may be wound such that its long sides are disposed in the direction along the winding center line O. Specific examples of such a winding method include a so-called a winding. The cross section of the wire-shaped coil material 11 may not be rectangular and may be square or circular.
The present invention will next be specifically described by way of Examples. However, the scope of the present invention is not limited to these Examples.
The inductance element according to the preceding embodiment of the present invention was produced by the above-described method. The shape and the production conditions are as described below. A plurality of wire-shaped coil materials (including insulating coatings different in thickness) were used to produce different inductance elements.
Shape and Materials:
External shape of element: 2.5 mm×2.0 mm×1.0 mm (thickness)
Cross sectional shape of wire-shaped coil material: rectangle of 0.2 to 0.25 mm×0.02 to 0.03 mm
Main constituent material of magnetic core: magnetic powder composed of Fe—P—C-based amorphous alloy material and having median diameter D50 of 5 to 8 μm
Constituent material of insulating coating: polyimide-based material
Constituent material of fusible layer: Nylon-based material
Constituent material of conductive material: copper-based material Shape of wound portion: number of turns 16 to 18, total thickness 0.4 to 0.5 mm
Molding step:
Temperature: room temperature (25° C.)
Pressure: 0.6 to 1.2 GPa
Heat treatment step:
Maximum reachable temperature: 350 to 500° C.
Heating time: 0.1 to 1 hour
For each of the 11 inductance elements obtained, the withstand voltage (unit: V) and L/DCR (unit: mH/Ω) were measured. The measurement results are shown in Table 1.
For each of the inductance elements, their partial discharge inception voltage (PDIV) was measured using the PROGRAMABLE HF AC TESTER MODEL 11802 manufactured by Chroma, and the withstand voltage was converted from the measurement results. In each of the Examples, a plurality of samples of the wire-shaped coil material were prepared, and the partial discharge inception voltage (PDIV) of each sample was measured at two frequencies of 20 kHz and 180 kHz. The arithmetic average of the results was used as the partial discharge inception voltage Vr (unit: V) of the wire-shaped coil material.
A cross section of each sample of the wire-shaped coil material was observed, and the thickness of the insulating coating in the observation image was measured at at least 30 points. The frequency distribution of the results of the measurement of the thickness of the insulating coating was approximated by a normal distribution, and the average thickness dar of the insulating coating and the standard deviation σr were determined. A value obtained as dar−3σr was used as the thickness dtr (unit: μm) of the thinnest portion of the insulating coating.
The withstand voltage Vn per unit thickness (unit: V/μm) was determined from the following formula using the above-determined partial discharge inception voltage Vr of the wire-shaped coil material and the thickness dtr of the thinnest portion:
Vn=Vr/dtr
The withstand voltage Vn per unit thickness determined by the above method was 86 V/μm. For each of the Examples, the upper biting limit ds (unit: μm) was determined by a method described later (the values are shown in Table 1), and the value obtained as Vn×ds was used as the withstand voltage (unit: V) in the Example.
L/DCR was determined as follows. The inductance L (unit: μH) was measured using the impedance analyzer 4294A manufactured by Agilent Technologies, and the DC resistance (unit: mΩ) was measured using the “milliohm HiTESTER 3540” manufactured by HIOKI E. E. CORPORATION. The measured L and DCR were used to compute L/DCR (unit: mH/Ω).
Each of the inductance elements produced in the Examples was cut along a plane including the winding center line, and the obtained cross section was observed under a scanning electron microscope.
The images shown in
66 points were arbitrarily selected in the insulating coating (the coating resin layer 12o) located on the surfaces 10c and 10d of the wound portion 10C that were oriented in the direction along the winding center line O, and the thickness of the insulating coating (unit: μm) was measured at these points. 32 thin-walled portions having a thickness equal to or less than the average thickness B of the inter-coil insulating coatings 12i were selected from the measurement results. Each of the thicknesses of the selected thin-walled portions was subtracted from the average thickness B of the inter-coil insulating coatings 12i to determine the biting depth d (unit: μm). The biting depths d at the 32 points are shown in Table 2.
The frequency distribution of the results of the measurement of the biting depth d was approximated by a normal distribution. In the normal distribution, the mean da was 0.469 μm, and the standard deviation σ was 0.334 μm. Therefore, the upper biting limit ds (=da+3.99σ) at which the process capability index Cpk was 1.33 was 1.80 μm, and the biting ratio R (=ds/B) was 0.59 (see Table 1).
For each of the inductance elements in other Examples, the same observation, measurement, computation as those in Example 4 were performed. In each of the Examples, the measurement was performed at at least 100 points on the inter-coil insulating coatings 12i to determine the average thickness B of the inter-coil insulating coatings 12i. In each of the Examples, the number of thin-walled portions having a thickness equal to or less than the average thickness B of the inter-coil insulating coatings 12i measured for the computation of the biting depth d was 15 or more. The results are shown in Table 1.
The inductance element according to the embodiment of the present invention can be preferably used as components of power source circuits for display units of portable electronic devices such as smartphones and notebook computers.
Number | Date | Country | Kind |
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JP2016217992 | Nov 2016 | JP | national |
This application is a Continuation of International Application No. PCT/JP2017/039152 filed on Oct. 30, 2017, which claims benefit of Japanese Patent Application No. 2016-217992 filed on Nov. 8, 2016. The entire contents of each application noted above are hereby incorporated by reference.
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Number | Date | Country | |
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20190244745 A1 | Aug 2019 | US |
Number | Date | Country | |
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Parent | PCT/JP2017/039152 | Oct 2017 | US |
Child | 16379406 | US |