The present invention relates generally to devices and methods for placing high pressure storage vessels into a vehicle structure, and more particularly to a way to integrate a vessel for storing a pressurized fuel source on a vehicle that employs a fuel cell-based architecture as a source of motive power such that the vessel increases the load-bearing capability of the vehicle.
In a typical fuel cell system, hydrogen or a hydrogen-rich gas is supplied through a flowpath to a catalytic electrode on one side of a fuel cell while oxygen (such as in the form of atmospheric oxygen) is supplied through a separate flowpath to another catalytic electrode situated elsewhere on the fuel cell. The electrochemical conversion of the elemental hydrogen and oxygen into hydrogen and oxygen ions on these electrodes (called anodes and cathodes, respectively) allows dissociated electrons to be routed through an electrically-conductive direct current (DC) circuit to produce useful work. One of the chief attributes of electric current production through fuel cells is their non-polluting nature, as the byproduct accompanying the use of hydrogen and oxygen reactants is water vapor. In one form of fuel cell, called the proton exchange membrane (PEM) fuel cell, an electrolyte in the form of a proton-transmissive membrane is sandwiched between the anode and cathode to produce a layered structure commonly referred to as a membrane electrode assembly (MEA). Each MEA forms a single fuel cell, and many such single cells can be combined to form a fuel cell stack, increasing the power output thereof. Multiple stacks can be coupled together to further increase power output. Because of its relatively simple and robust construction, as well as its non-polluting nature, the PEM fuel cell has shown particular promise for vehicular applications.
Nevertheless, one challenge for fuel cell vehicles is increasing their power-to-weight ratio relative to conventional propulsion systems, where much of the ancillary equipment weight associated with the fuel cell system is parasitic. One such component is the on-board fuel storage system, particularly as it relates to the hydrogen fuel storage tank, where its robustness and associated weight are dictated by the need to preserve tank integrity while containing a pressurized supply of hydrogen or related fuel (such as methanol or a hydrogen precursor) over the expected life of the vehicle, even in situations where both normal use (such as routine maneuvering and exposure to road irregularities) and extreme use (such as due to an accident or related impact) could otherwise damage the tank, vehicle or both. There accordingly exists a need to provide enhanced structural rigidity through the use of such components that are already present in a transportation vehicle. There further exists a need to reduce the penalties associated with placing a high pressure fuel storage vessel in a transportation vehicle.
These needs are met by the present invention, where high pressure fuel storage tanks and related vessels take are coupled to the vehicle in such a way to increase the stiffness of the vehicle. The structural advantage made possible by such integration is applicable to configurations where the fuel storage system comprises either a single storage tank or a plurality of tanks, especially in configurations where at least one of the vessels has a large diameter (and concomitant high torsional stiffness). According to a first aspect of the invention, a fuel vessel assembly for a fuel cell-powered vehicle includes a vessel and at least one shell cooperative with the vessel. The vessel forms a fuel storage container with an internal volume, and also includes one or more aperture formed through it to allow the introduction and removal of fuel as needed. The shells act as load-transmitting members so that structural loads that originate from the vessel (such as pressure loads from the fuel), as well as external loads (such as due to loads imparted to the shells through their connection to a vehicular frame or other structural component) are transmitted between the assembly and a load-bearing structure in the vehicle to enhance load-bearing capability inherent in the vehicle structure. In the present context, the term “frame” covers not only traditional body-on-frame vehicular architectures, but also the relatively more recent construction variant known as unibody construction, this latter configuration where the role traditionally played by the frame is replaced by high moment of inertia formations through a monocoque design where parts (for example, outer body panels, roofs or the like) that were not loaded in the more traditional body-on-frame design are now structural members. As such, the term “frame”, as it applies to a unibody vehicle without a separate frame, covers such an underlying part of the vehicle upon which many of the other components are attached to, rest upon, or otherwise derive at least a significant portion of their load-carrying capabilities from.
Optionally, the assembly also includes one or more clamping rings disposed about the shell or shells to provide enhanced connectivity between them. In another option, any or all of the vessel, shell and ring may be made from a metal or a composite material, such as a fiber-reinforced composite material. The shell may additionally include unidirectional (UD) fibers, ribs, beads or related structure as supplemental reinforcement against buckling or other damage-inducing modes of force. In another form, the assembly includes numerous shells that extend beyond the vessel to allow (upon connection to a vehicular frame or related load-bearing structural component) the transmission of loads between the assembly and the load-bearing structure. In a more particular form, the numerous shells are secured to the vessel such that upon attachment of the assembly into the vehicle, the attachment is formed along a substantial vertical axis of the vehicle. In one particular form, the shells are disposed about the generally cylindrical periphery of the vessel. In a situation involving two shells at each longitudinal end of the vessel, the two shells would be substantially diametrically opposed from one another. In yet another option, the vessel defines a substantially cylindrical structure with at least one end formed as a dome. The tapered region around the dome can allow a graduated ramp connection to be formed between the dome and the shell. In one form, such graduated connection may be made from successively larger numbers of composite plies or other material buildup.
The assembly may further include a relief valve placed relative to the vessel such that if an excessively high temperature is present around the vessel, the relief valve can open. In one preferred form, the relief valve can be coupled to a temperature sensor so that upon receipt of a signal indicative of such excessive temperature, the relief valve opens to reduce an internal pressure formed in the vessel by any fuel present in the vessel. In the present context, an excessive temperature is one that could be expected to cause damage to the assembly, particularly the vessel, either by reducing the structural properties of the materials making up the assembly, or by overpressure due to heating of the fuel contained in the vessel. In situations where exposure of such an excessive heat needs to more easily reach the relief valve, or temperature sensor that could be used to send a signal to a controller or the relief valve, the one or more shells may include openings formed in them to allow a more free flow of the heat stream that comes from the source of excessive temperature. In still another option, the one or more shells are configured as a free-shaped shell, while in another option, they may be formed as a cylindrical shell.
According to another aspect of the invention, a vehicular chassis includes a frame and a fuel vessel assembly. The vessel is secured to the frame through one or more connections in the form of shells. By its design configuration and material choice, the frame inherently has a resistance to deformation from an externally-applied load. The fuel vessel assembly includes one or more vessels defining a fuel storage containing volume with one or more apertures to allow fuel to be introduced into, contained within and removed from the vessel. The shell is secured to the vessel such that deformation-producing structural loads are transmitted between the assembly and the frame such that the inherent resistance to deformation defined in the frame is enhanced by the assembly.
Optionally, the frame defines a vertical component such that the structural coupling between the assembly and the frame forms numerous connection locations along the vertical component. By having such connections form predominantly along a vertical axis (for example, the Cartesian z-axis as described in more detail below) rather than along a horizontal axis, the overall moment of inertia of the frame is enhanced by giving it more of a box-like profile. The assembly may additionally include one or more clamping rings disposed about the shell to provide enhanced connectivity between the vessel and the shell. At least a portion of the assembly can be made from a metal or a fiber-reinforced composite material, and a temperature protection device may also be employed. Such as device could include a relief valve cooperative with the vessel such that upon being exposed to an excessive temperature, the relief valve opens to reduce an internal pressure caused by fuel in the vessel.
According to another aspect of the invention, a method of enhancing the structural resistance to deformation in a fuel cell-powered vehicle is disclosed. The method includes configuring a chassis of the fuel cell-powered vehicle to include a load-bearing frame, and connecting a fuel storage vessel assembly to the chassis such that at least a portion of the deflection loads imparted to the frame are transmitted through the assembly such that it enhances a resistance to deformation inherent in the frame. The assembly includes a vessel defining a volume therein for storage of hydrogen or a related fuel cell fuel, as well as the load-transmitting connection that helps the frame realize the enhanced structural rigidity.
Optionally, the load-transmitting connection comprises numerous shells coupled to the vessel. In a more particular form, the numerous shells are arranged such that the load-transmitting connection forms a plurality of connection locations along a vertical axis component of the vehicle. In another option, hoop-like rings can be used to add more robustness to the location where the shells and vessel are joined. As with the previous aspects, some or all of the vessel, shells and rings of the assembly are formed as a metal or a composite structure. Also as before, pressure on the vessel that might otherwise occur if the vessel is exposed to an excessively high temperature that could lead to expansion of the fuel in the vessel can be relieved. In one form, a pressure-relieving valve may be used in such a capacity.
The following detailed description of specific embodiments can be best understood when read in conjunction with the following drawings, where like structure is indicated with like reference numerals and in which:
The embodiments set forth in the drawings are illustrative in nature and are not intended to be limiting of the embodiments defined by the claims. Moreover, individual aspects of the drawings and the embodiments will be more fully apparent and understood in view of the detailed description that follows.
Referring first to
In a preferred form, four shells 124 and two rings 126 can be attached to a vessel 122 to create the vessel assembly 120, as well as the formation of a graduated ramp joint between the shells 124 and the vessel 122. In such a case, it would be preferable to have the two shells 124 that extend from the same end of vessel 122 to be diametrically opposed from one another. In this way, when the assembly 120 is mounted to the frame 10 (which preferably includes at least some extension vertically upward (for example, in the Cartesian z-direction in
Referring next to
This high degree of stiffness (whether, radial, tangential or longitudinal) may be particularly useful when integrated into the body of a vehicle (such as chassis 1 of
In automotive applications, significant load criteria have to be met for all major axes in the Cartesian coordinate system mentioned above. Examples include withstanding the aforementioned high acceleration forces F, loads due to the expansion of the vessel 122 by inner pressure and loads due to elastic and thermal deformation of the vehicle under normal operating conditions. Furthermore, while some of these loads may not interact with one another (for example, the acceleration forces generally arise only for high vehicular velocities, while the high elastic deformations of the vehicle only occur for lower velocities), consideration must be placed on the fact that some of these loads (such as expansion by inner pressure and thermal deformations) have a tendency to interact with other loads.
Modeling the vessel 122 within a notional vehicle (such as vehicle chassis 1 depicted in
As can be seen from the above table, the best reinforcing effect of the vessel 122 can be obtained for the position between the axles. Of course, because this would intrude into the passenger compartment, such placement will need to be reconsidered. These (as well as other design considerations) may be taken into consideration when modeling the vessel assembly 120.
Referring next to
In a preferred form, vessel 122 is of a composite structure made from a fiber-reinforced polymer. Numerous ply orientations are possible, such as a balanced ply laminate and a hoop ply. The necessary torsional stiffness of the cylindrical portion of vessel 122 can be determined based on the well-known formula:
where Gyθ is the shear modulus of the laminate, IP is the torsional moment area and lCA is the length of the cylindrical area. In one exemplary form, where carbon fiber is used as the reinforcement medium and assuming the above dimensions, CT is about 174 MNm/rad.
Referring with particularity to
The raised end (ledge) produced by the flanges 124A3, 124B3 reduces the risk of early buckling by providing a larger moment of inertia. Analyses conducted by the inventors shows that both shell variants should have sufficient stiffness, and that of the two, the cylindrical shell 124B is possessive of a greater resistance to buckling than the free shaped shell 124A, while the free shaped shell 124A is lighter than the cylindrical shell 124B. Separate analysis conducted by the inventors indicated that the stiffness of the cylindrical shell 124B is significantly higher (upwards of four times higher) than that for the free shaped shell 124A.
The shells 124 can be made from numerous materials, although in one preferred embodiment, such material can be sheet molding compound (SMC), which is a sheet material made up of a thermoset polymer as matrix and randomly oriented glass fibers. In one form, the fibers may be between 30 and 50 millimeters in length. SMC gets pressed to the desired shape and then cured in the heated tool. The shells 124 can be mounted to vessels 122 by clamping rings 126, which in one form are made from materials similar to those of the vessel 122 and shells 124, such as a glass fiber reinforced epoxy or related plastic. When configured as a fiber-reinforced composite, shells 124A and 124B can be made with various forms of fiber reinforcement, where a trade-off between shell mass and shell stiffness can be one of the determining factors. The inventors have determined that one particular form of reinforcement, made of substantially x-shaped fiber plies, achieved the highest increase in stiffness-to-weight ratio. Additionally the shells could be reinforced (especially against buckling) by stiffeners (such as UD layers, ribs and beads).
Vehicular integration concerns will also have to be taken into consideration for both material choices and shell 124 configurations. For example, the structural efficiency advantages of the cylindrical shell 124B may have to be balanced against the greater ease of joining the rectangular flange 124A3 of the free shaped shell 124A to the generally planar mating surface of the longitudinal bar 130 or related surface of frame 10. As such, integration concerns could make it more difficult to join the round flange 124B3 of the cylindrical shell 124B to the longitudinal bar 130. Considerations such as these leads to a trade-off in flange configurations.
Referring next to
The inventors conducted analyses comparing the stiffness of a notional vehicular frame with an integrated vessel 122 to one without the vessel 122 using a single 1000 N edgewise loading. In a first analysis (where the integrated vessel 122 was not present), the load causes a displacement of 0.16 millimeters, which corresponds to a frame stiffness of 6202 N/mm2. In a second analysis, the vessel 122 was assembled into the frame in an integrated fashion such that at least a portion of the applied load would pass through the vessel 122. The same 1000 N load caused a displacement of 0.1 millimeters, corresponding to a stiffness of 10000 N/mm2, or about a 1.6 factor of increase. While further refinements are possible, and other factors may or may not be included to increase or decrease this stiffness magnification, it will be appreciated by those skilled in the art that significant improvements in the load-bearing ability of a vehicular frame can be realized by following the approaches of the present invention. The above is given only by way of example as a way to compare known stiffnesses, and that by analogizing the edgewise loading scenario above, the present inventors believe that comparable improvements in even more relevant factors, such as vehicular torsional stiffness, could also be realized.
Referring with particularity to
As mentioned above, in one preferred form, both the vessel 122 and the shells 124 may be made from a composite material. In one representative manufacturing form, the vessel 122 (domes not shown in
Referring next to
Other features may be employed as well. For example, the assembly 120 may also include a generally compliant spacer to allow some degree of impact absorption. Because the vessel 122 and shells 124 are stiff structures, any dimensional increases in vessel 122 due to its being filled with the gaseous fuel would be imparted to the longitudinal bars 130 of frame 10. To avoid deformation of the longitudinal bar 130 (and derivatively, to the car body) a flexible spacer, such as in the form of a soft adhesive, may be placed between the shells 124 and the car body. In another form, longitudinal bar 130 may have a flexible region designed into it. In the case of relatively small deformations (for example, on the order of about 0.7 mm per shell, which may arise out of filling the vessel up to working pressure with fuel) will be absorbed by such a flexible spacer or related element.
Having described embodiments of the present invention in detail, and by reference to specific embodiments thereof, it will be apparent that modifications and variations are possible without departing from the scope of the embodiments defined in the appended claims. More specifically, although some aspects of embodiments of the present invention are identified herein as preferred or particularly advantageous, it is contemplated that the embodiments of the present invention are not necessarily limited to these preferred aspects.
Number | Name | Date | Kind |
---|---|---|---|
6257360 | Wozniak et al. | Jul 2001 | B1 |
6708719 | Idoguchi | Mar 2004 | B2 |
7137474 | Yokote | Nov 2006 | B2 |
7189040 | Sharp et al. | Mar 2007 | B2 |
7264277 | Ono et al. | Sep 2007 | B2 |
7270209 | Suess | Sep 2007 | B2 |
7543667 | Hwang et al. | Jun 2009 | B2 |
7624753 | Suess et al. | Dec 2009 | B2 |
7631901 | Diehl | Dec 2009 | B2 |
7658414 | Watanabe et al. | Feb 2010 | B2 |
7819431 | Minami | Oct 2010 | B2 |
8083263 | Yamanami et al. | Dec 2011 | B2 |
20040239095 | Wozniak et al. | Dec 2004 | A1 |
20060061081 | Kresse et al. | Mar 2006 | A1 |
20060197332 | Hashimura | Sep 2006 | A1 |
20090309349 | Yamanami et al. | Dec 2009 | A1 |
Number | Date | Country |
---|---|---|
24 12 310 | Sep 1975 | DE |
196 23 844 | Jan 1997 | DE |
298 22 006 | May 1999 | DE |
600 06 898 | May 2000 | DE |
200 05 887 | Sep 2000 | DE |
10 2005 037 636 | Aug 2005 | DE |
10 2005 037 637 | Aug 2005 | DE |
10 2009 033 023 | Jan 2010 | DE |
Number | Date | Country | |
---|---|---|---|
20120080875 A1 | Apr 2012 | US |