This disclosure is generally related to photovoltaic (or “PV”) roof tiles. More specifically, this disclosure is related to a mechanical support and protection spacer for PV roof tiles.
In residential and commercial solar energy installations, a building's roof typically is installed with photovoltaic (PV) modules, also called PV or solar panels, that can include a two-dimensional array (e.g., 6×12) of solar cells. A PV roof tile (or a solar roof tile) can be a particular type of PV module offering weather protection for the home and a pleasing aesthetic appearance, while also functioning as a PV module to convert solar energy to electricity. The PV roof tile can be shaped like a conventional roof tile and can include one or more solar cells encapsulated between a front cover and a back cover, but typically encloses fewer solar cells than a conventional solar panel. The front and back covers can be fortified glass or other material that can protect the PV cells from the weather elements. Note that a typical roof tile may have a dimension of 15 in×8 in =120 in2=774 cm2, and a typical solar cell may have a dimension of 6 in×6 in =36 in2=232 cm2. Similar to a conventional PV panel, the PV roof tile can include an encapsulating layer, such as an organic polymer. A lamination process can seal the solar cells between the front and back covers.
To facilitate scalable production and easy installation of PV roof tiles, a group of tiles can be fabricated together and jointed in a rigid or semi-rigid way. Carefully designed spacers inserted between adjacent tiles are needed to facilitate the jointing of adjacent PV roof tiles.
One embodiment described herein provides a photovoltaic roof module. The roof module can include at least a first photovoltaic roof tile, a second photovoltaic roof tile positioned adjacent to the first photovoltaic roof tile, and a spacer coupled to and positioned between the first and second photovoltaic roof tiles. The spacer is configured to facilitate a semi-rigid joint between the first and second photovoltaic roof tiles.
In a variation on this embodiment, the spacer can be made of polyvinylidene fluoride (PVDF) or polytetrafluoroethylene (PTFE).
In a variation on this embodiment, each photovoltaic roof tile can include a front cover, a back cover, and encapsulant positioned between the front and the back covers.
In a further variation, the spacer can include a base and two wings extending from the base in opposite directions. A respective wing of the spacer can be embedded within the encapsulant positioned between the front and back covers of a respective photovoltaic roof tile.
In a further variation, the base of the spacer can include a groove extending along a longitudinal axis on its sun-facing surface, thereby creating a visual effect of a gap between the first and second photovoltaic roof tiles.
In a further variation, a length of a respective wing can be at least 3 mm.
In a further variation, the base can include a channel on its bottom surface configured to allow a metallic tab electrically coupling the first and second photovoltaic roof tiles to pass through.
In a further variation, a surface of the respective wing can be textured.
In a further variation, each photovoltaic roof tile comprises a cascaded string of photovoltaic structures embedded inside the encapsulant.
One embodiment described herein provides a system and method for fabricating a photovoltaic roof module. During operation, the system prepares first and second back covers, lays a first layer of encapsulant on the first and second back covers, and places first and second sets of photovoltaic structures on the first encapsulant layer. The first and second sets of photovoltaic structures are positioned above the first and second back covers, respectively. The system further places a reinforcement spacer between the first and second sets of photovoltaic structures. The reinforcement spacer comprises a base and first and second wings extending from the base in opposite directions, and the first and second wings are positioned above the first layer of encapsulant and above, respectively, the first and second back covers. Subsequently, the system places a second layer of encapsulant and places first and second front covers over the second layer of encapsulant, the first and second front covers being positioned above the first and second back covers, respectively. Finally, the system performs a lamination operation.
One embodiment described herein provides a reinforcement spacer for providing bonding and structural support to adjacent photovoltaic roof tiles within a photovoltaic roof module. The spacer can include a base positioned between the adjacent photovoltaic roof tiles and first and second wings extending from the base in opposite directions. A respective wing is embedded within encapsulant positioned between front and back covers of a respective photovoltaic roof tile.
A “solar cell” or “cell” is a photovoltaic structure capable of converting light into electricity. A cell may have any size and any shape, and may be created from a variety of materials. For example, a solar cell may be a photovoltaic structure fabricated on a silicon wafer or one or more thin films on a substrate material (e.g., glass, plastic, or any other material capable of supporting the photovoltaic structure), or a combination thereof.
A “solar cell strip,” “photovoltaic strip,” or “strip” is a portion or segment of a photovoltaic structure, such as a solar cell. A photovoltaic structure may be divided into a number of strips. A strip may have any shape and any size. The width and length of a strip may be the same or different from each other. Strips may be formed by further dividing a previously divided strip.
“Finger lines,” “finger electrodes,” and “fingers” refer to elongated, electrically conductive (e.g., metallic) electrodes of a photovoltaic structure for collecting carriers.
“Busbar,” “bus line,” “bussing,” or “bus electrode” refer to elongated, electrically conductive (e.g., metallic) electrodes of a photovoltaic structure for aggregating current collected by two or more finger lines. A busbar is usually wider than a finger line, and can be deposited or otherwise positioned anywhere on or within the photovoltaic structure. A single photovoltaic structure may have one or more busbars.
A “photovoltaic structure” can refer to a solar cell, a segment, or solar cell strip. A photovoltaic structure is not limited to a device fabricated by a particular method. For example, a photovoltaic structure can be a crystalline silicon-based solar cell, a thin film solar cell, an amorphous silicon-based solar cell, a polycrystalline silicon-based solar cell, or a strip thereof.
In the figures, like reference numerals refer to the same figure elements.
The following description is presented to enable any person skilled in the art to make and use the embodiments, and is provided in the context of a particular application and its requirements. Various modifications to the disclosed embodiments will be readily apparent to those skilled in the art, and the general principles defined herein may be applied to other embodiments and applications without departing from the spirit and scope of the present disclosure. Thus, the disclosed system is not limited to the embodiments shown, but is to be accorded the widest scope consistent with the principles and features disclosed herein.
Embodiments provide a solution to the problem of providing mechanical support to one or more pairs of photovoltaic (PV) roof tiles in a multi-tile group, by including a reinforcement spacer beam. In addition to providing mechanical support, the spacer beam can facilitate inter-tile electrical connections and protect the electrical bussing wires/tabs from the weather elements. Moreover, the spacer beams can play an important role during the manufacturing of the multi-tile modules. For example, they can assist in aligning of the multiple glass covers in a module, and limit and direct the flow of encapsulant during lamination. Carefully designed spacers can also improve the visual appearance of the multi-tile module. In general, the reinforcement spacer beams can enhance structural integrity during manufacturing, installation, and service.
Prefabricating individual PV tiles into multi-tile modules can considerably simplify the roofing process, since the tiles within the module have been electrically and mechanically connected at the time of manufacture. By improving the resilience, stability, and weather protection offered by the inter-tile spacers, the disclosed spacers improve the tiles' capacity to function jointly as a group.
The spacer beam can include a base (or base ridge) and two stability wings. The spacer can be positioned with its base ridge between two adjacent PV roof tiles, with the base ridge's long axis parallel to the tiles' edges. The two wings can be separately inserted between the glass covers of the two PV roof tiles, mechanically coupling the two roof tiles to the spacer beam. The base ridge can further include a groove on its top surface to provide a visual appearance of a gap between the two roof tiles, and a bottom channel to facilitate electrical connections between the two PV roof tiles.
PV Modules and Roof Tiles
One main function provided by the inter-tile spacer is mechanical support to a pair of photovoltaic (PV) roof tiles within a multi-tile module. A PV roof tile (or solar roof tile) is a type of PV module shaped like a roof tile and typically enclosing fewer solar cells than a conventional solar panel. Note that such PV roof tiles can function as both PV cells and roof tiles at the same time. PV roof tiles and modules are described in more detail in U.S. Provisional Patent Application No. 62/465,694, entitled “SYSTEM AND METHOD FOR PACKAGING PHOTOVOLTAIC ROOF TILES” filed Mar. 1, 2017, which is incorporated herein by reference. In some embodiments, the system disclosed herein can be applied to PV roof tiles and/or other types of PV module.
A PV roof tile can enclose multiple solar cells or PV structures, and a respective PV structure can include one or more electrodes such as busbars and finger lines. The PV structures within a PV roof tile can be electrically and optionally mechanically coupled to each other. For example, multiple PV structures can be electrically coupled together by a metallic tab, via their respective busbars, to create serial or parallel connections. Moreover, electrical connections can be made between two adjacent tiles, so that a number of PV roof tiles can jointly provide electrical power.
The tabbing strips can ensure sufficient electrical contact, thereby reducing the likelihood of detachment. Furthermore, the multiple (e.g., four) tabbing strips being sealed between glass cover 202 and backsheet 208 can improve the durability of the PV roof tile.
Multi-Unit Groups of PV Roof Tiles
To facilitate more scalable production and easier installation, multiple photovoltaic roof tiles can be fabricated together, while the tiles are linked in a rigid or semi-rigid way.
It is possible to use a single piece of glass as glass cover 420. In one embodiment, grooves 422 and 424 can be made on glass cover 420, so that the appearance of three separate roof tiles can be achieved. It is also possible to use three separate pieces of glass to cover the six cells, which are laid out on a common back sheet. In this case, gaps 422 and 424 can be sealed with an encapsulant material, establishing a semi-rigid coupling between adjacent tiles. Prefabricating multiple tiles into a rigid or semi-rigid multi-tile module can significantly reduce the complexity of roof installation, because the tiles within the module have been connected with the tabbing strips. Note that the numbers of tiles included in each multi-tile module can be more or fewer than what is shown in
The gap between two adjacent PV tiles can be filled with encapsulant, protecting tabbing strips interconnecting the two adjacent tiles from the weather elements. For example, encapsulant 470 fills the gap between tiles 454 and 456, protecting tabbing strip 468 from weather elements. Furthermore, the three glass covers, backsheet 452, and the encapsulant together form a semi-rigid construction for multi-tile module 450. This semi-rigid construction can facilitate easier installation while providing a certain degree of flexibility among the tiles.
In addition to the examples shown in
In the example shown in
A parallel connection among the tiles can be formed by electrically coupling all leftmost busbars together via metal tab 490 and all rightmost busbars together via metal tab 492. Metal tabs 490 and 492 are also known as connection buses and typically can be used for interconnecting individual solar cells or strings. A metal tab can be stamped, cut, or otherwise formed from conductive material, such as copper. Copper is a highly conductive and relatively low cost connector material. However, other conductive materials such as silver, gold, or aluminum can be used. In particular, silver or gold can be used as a coating material to prevent oxidation of copper or aluminum. In some embodiments, alloys that have been heat treated to have super-elastic properties can be used for all or part of the metal tab. Suitable alloys may include, for example, copper-zinc-aluminum (CuZnAl), copper-aluminum-nickel (CuAlNi), or copper-aluminum-beryllium (CuAlBe). In addition, the material of the metal tabs disclosed herein can be manipulated in whole or in part to alter mechanical properties. For example, all or part of metal tabs 490 and 492 can be forged (e.g., to increase strength), annealed (e.g., to increase ductility), and/or tempered (e.g. to increase surface hardness).
The coupling between a metal tab and a busbar can be facilitated by a specially designed strain-relief connector. In
Similar to the examples shown in
There remain several problems with the semi-rigid construction of multi-tile modules. Particularly, the inter-tile gap filled with encapsulant may be a structurally weak spot, providing insufficient flexibility and strength for reliable long-term usage. In addition, it can be difficult to deposit the encapsulant material precisely at the gaps. For example, encapsulant may overflow the gap during the lamination process, and be difficult to clean. Aesthetically, the encapsulant-filled gap can be ungainly, and appear noticeably different from standard roof tiles. Finally, weather elements such as rain and solar radiation can damage PV components, especially if there are exposed electrical connections.
Some embodiments can solve these problems by providing a reinforcement spacer to enhance flexibility and mechanical stability of a multi-tile module. In addition, the reinforcement spacer can protect inter-tile electrical bussing and direct/control the flow of encapsulant during lamination.
As will be described below, the reinforcement spacer (e.g., spacer 508) not only can enable mechanical coupling that offers both strength and flexibility, but also can facilitate and protect inter-tile electrical bussing. Moreover, the spacer can improve the aesthetic appearance and encapsulant utilization of the inter-tile spaces. Thus, a prefabricated multi-tile module that incorporates one or more reinforcement spacers can offer weather protection for the home, solar energy conversion, expedient installation, mechanical stability and flexibility, protection and insulation of electrical connections, encapsulant flow control, and an aesthetic appearance similar to conventional roof tiles.
Reinforcement Spacer
In some embodiments, instead of a groove, the visual effect of a “gap” can be created by a mark (e.g., a painted mark or a color variation) created on the top surface of base 602. Such a mark can generally provide a neater or more attractive aesthetic appearance compared with an encapsulant-filled inter-tile gap.
Spacer 600 can have two wings 606 and 608 attached to either side of base 602. The position and thickness of each wing are designed in such a way that, when in position, the wings can be inserted into the adjacent roof tiles. More specifically, each wing can be inserted between the top glass cover and backsheet of a corresponding roof tile. Therefore, after lamination, each PV tile can be mechanically bound to a wing, thus creating a rigid or semi-rigid bonding between the two adjacent PV tiles. More specifically, a rigid spacer can provide a rigid bonding, whereas a somewhat flexible spacer can provide a somewhat flexible or semi-rigid bonding. In practice, it can be desirable for the inter-tile bonding to be somewhat flexible in order to accommodate certain conditions, such as windy days.
In the example shown in
Likewise, the choice of material is important to the strength, performance, and long-term reliability of spacer 600. Because PV roof tiles are exposed to the sun and other weather elements (e.g., rain and snow), spacer 600 needs to be made of material that is ultraviolet (UV)-resistant as well as waterproof. Moreover, because it can be in contact with the inter-tile electrical connections, spacer 600 should be made of a material that is electrically insulating. The material also ideally can withstand the heating, cooling, and associated thermal expansion resulting from lamination. In particular, the material preferably will not thermally contract excessively when cooling after lamination. In an embodiment, spacer 600 can be made from a polymer or thermoplastic material, such as polyvinylidene fluoride (PVDF). Note that other materials are possible (e.g., polytetrafluoroethylene (PTFE)). In alternative embodiments, spacer 600 can be made of a soft material, such as silicone.
One important function provided by spacer 600 is to protect the inter-tile electrical bussing against weather elements such as rain, wind, or dirt. Note that, when driven by wind, rainwater can travel upwards along a roof. Because the PV roof tiles are typically laid in a way such that one row of tiles offsets an adjacent row of tiles, as shown in
The channel at the bottom side of the spacer base can be essential in facilitating inter-tile electrical connections. More specifically, tabbing strips (e.g., metallic tabs 490 and 492 shown in
Note that, because the bottom of the spacer faces inward toward the building, and because electrical connections (e.g., metallic tabs) elsewhere have been protected by encapsulant, it is possible to leave the electrical connections uninsulated within the bottom channel of the spacer. Laminating the bottom side of the inter-tile gap with encapsulant can be technically challenging to achieve a consistent coated thickness. To further protect the metallic tabs, in some embodiments, the bottom channel of the spacer can be covered by an additional plastic (e.g., PVDF or PTFE) piece.
The top surface of spacer 760 can be positioned in the same plane as the top surface of the front glass covers. In some embodiments, after lamination, the bottom surface of spacer 760 can be aligned to the bottom surface of the backsheets. For illustration purposes, in
The width of the base of the spacer can be determined based on the dimension of the roof tiles. In some embodiments, the width of the base can be chosen to achieve a good aesthetic effect. For example, for PV roof tiles having a standard size, the width of the base of the spacer can be a few millimeters. There are no particular requirements for the thickness of the wings as long as they can be structurally strong and can allow a sufficient amount of encapsulant to flow between the wings and the front cover/backsheet. In some embodiments, the thickness of wings of the spacer can vary along its length (e.g., a taper can be introduced). Moreover, the surface of the wings can be textured to provide better adhesion between the wings and the encapsulant. Any space between the wings and top glass cover 782/backsheet 792 can be filled with encapsulant, particularly after lamination. The encapsulant material used to laminate the roof tiles, spacer, and/or inter-tile gaps can include PVB, TPO, EVA, TPD, or other materials. In the example shown in
In addition to the exemplary spacers shown in
As discussed earlier, the reinforcement spacers can play an important role in the fabrication, installation, and operation of the PV roof tiles. The spacers in the various embodiments can offer a number of advantages over existing systems, including mechanical stability, encapsulant flow control, protection of electrical connections, and an aesthetic appearance similar to that of conventional roof tiles.
When inserted between the adjacent roof tiles, the spacer's wings can be embedded in encapsulant, and after lamination, the spacer's wings can be securely bound to the front and back covers of the adjacent roof tiles. The spacer can function as an ‘embedded skeleton,’ that is, it can provide a semi-rigid structure within the encapsulant material. Note that the encapsulant typically can be elastic but lack rigidity. By contrast, the combination of encapsulant and reinforcement spacer can provide an inter-tile joint or connection with both strength and flexibility. The disclosed spacer can also prevent reliability problems associated with delamination.
During the lamination process, the spacer can also direct and control the flow of encapsulant in the inter-tile space. In conventional approaches, it can be challenging to deposit encapsulant at the inter-tile gap in a consistent and controlled manner. The encapsulant may overflow, sometimes onto the glass top covers. The overflowed encapsulant can be aesthetically unsightly, and may impair the functioning of the inter-tile joint. It is also hard to remove the overflowed encapsulant from the glass top cover. The disclosed spacer can guide or direct the flow of encapsulant during lamination, preventing overflow. In some embodiments, the spacer can conceal the visual appearance of encapsulant.
During manufacturing, the spacer can facilitate alignment of the glass sheets within a multi-tile module. For example, the pre-laid spacers can be used as a visual guide for robotic arms that lay the top glass covers. Alternatively, the pre-laid spacers can be used as anchors for the glass covers. For example, when laying a glass cover, the robotic arm can push the glass cover against the spacer. Moreover, during final manufacturing steps (such as trimming and roof component attachment), it is necessary to handle the multi-tile module carefully to protect the bussing. The spacer can provide structural integrity and stiffness to the multi-tile module when the multi-tile module is being handled as a single piece.
The spacer and encapsulant together can also protect the PV structures and electrical bussing from weather elements, such as rain, condensation, and UV radiation, and can prevent moisture ingress into the roof tiles. Finally, the spacer can improve the aesthetic appearance of the roof tiles, reducing and/or hiding the presence of encapsulant, and providing the appearance of a clean gap between tiles.
Subsequently, one or more reinforcement spacers can be deposited in spaces between the sets of PV structures (operation 908). The location of each reinforcement spacer can be predetermined. For example, if the multi-tile module include three tiles, two spacers will be deposited, and the distance between the two spacers will be carefully controlled to allow a front glass cover of a tile to be fitted between the two spacers.
In some embodiments, the reinforcement spacer can include a base ridge and two side wings extending from the base ridge. The base ridge can shape like a rectangular prism that includes a groove on its top surface, providing a visual appearance of a gap between adjacent PV tiles. The base ridge of the spacer can further include a bottom channel configured to allow electrical connections (e.g., metallic tabs) connecting adjacent sets of PV structures to pass through.
In some embodiments, serial and/or parallel electrical connections among tiles within the same multi-tile module can be formed during fabrication, in order to simplify the installation of the tiles on a roof. More specifically, the inter-tile electrical connections have been made before the reinforcement spacers have been laid. Establishing the inter-tile connections can involve attaching the strain-relief connectors to edge busbars of each string of PV structures and then attaching metallic tabs to corresponding strain-relief connectors.
Subsequent to placing the spacers, a second layer of encapsulant can be laid, covering the PV structures and the wings of the spacers (operation 910). Using the spacers as visual guides or anchor points, top glass covers can then be placed on top of the newly laid encapsulant (operation 912). More specifically, each top glass cover can be placed above each set of PV structures. Next, heat and pressure can be applied to the entire multi-tile assembly, laminating the PV structures along with the wings of the spacers between the glass covers and backsheets (operation 914). As discussed previously, a particular set of PV structures is encapsulated between a particular front glass cover and a corresponding backsheet. Together they can form a PV roof tile. A spacer having its wings separately encapsulated within two PV adjacent roof tiles can mechanically couple these two PV roof tiles to each other.
Subsequent to cooling after lamination, the entire multi-tile assembly can go through post-lamination procedures, such as trimming (e.g., trimming of overflowed encapsulant), optional framing, and attachment of other roofing components (e.g., inter-module cable, nail strips, etc.) as a single piece to complete the module fabrication (operation 916).
The foregoing descriptions of various embodiments have been presented only for purposes of illustration and description. They are not intended to be exhaustive or to limit the present system to the forms disclosed. Accordingly, many modifications and variations will be apparent to practitioners skilled in the art. Additionally, the above disclosure is not intended to limit the present system.
Number | Name | Date | Kind |
---|---|---|---|
3076861 | Samulon | Feb 1963 | A |
3369939 | Myer | Feb 1968 | A |
3461602 | Hasel | Aug 1969 | A |
4239810 | Alameddine | Dec 1980 | A |
4724011 | Turner | Feb 1988 | A |
5118540 | Hutchison | Jun 1992 | A |
5338369 | Rawlings | Aug 1994 | A |
5427961 | Takenouchi | Jun 1995 | A |
5667596 | Tsuzuki | Sep 1997 | A |
5942048 | Fujisaki | Aug 1999 | A |
6133522 | Kataoka | Oct 2000 | A |
6311436 | Mimura | Nov 2001 | B1 |
6365824 | Nakazima | Apr 2002 | B1 |
6472594 | Ichinose | Oct 2002 | B1 |
6586271 | Hanoka | Jul 2003 | B2 |
6960716 | Matsumi | Nov 2005 | B2 |
7259321 | Oswald | Aug 2007 | B2 |
7276724 | Sheats | Oct 2007 | B2 |
7506477 | Flaherty | Mar 2009 | B2 |
7534956 | Kataoka | May 2009 | B2 |
7772484 | Li | Aug 2010 | B2 |
7833808 | Xu | Nov 2010 | B2 |
7851700 | Luch | Dec 2010 | B2 |
7858874 | Ruskin | Dec 2010 | B2 |
7902451 | Shimizu | Mar 2011 | B2 |
7964440 | Salleo | Jun 2011 | B2 |
8205400 | Allen | Jun 2012 | B2 |
8206664 | Lin | Jun 2012 | B2 |
8276329 | Lenox | Oct 2012 | B2 |
8471141 | Stancel | Jun 2013 | B2 |
8664030 | Luch | Mar 2014 | B2 |
8674377 | Farquhar | Mar 2014 | B2 |
8701360 | Ressler | Apr 2014 | B2 |
8713861 | Desloover | May 2014 | B2 |
8822810 | Luch | Sep 2014 | B2 |
9038330 | Bellavia | May 2015 | B2 |
9150966 | Xu | Oct 2015 | B2 |
9206520 | Barr | Dec 2015 | B2 |
9343592 | Hunt | May 2016 | B2 |
9362527 | Takemura | Jun 2016 | B2 |
9412884 | Heng | Aug 2016 | B2 |
9525092 | Mayer | Dec 2016 | B2 |
9825582 | Fernandes | Nov 2017 | B2 |
9899554 | Yang | Feb 2018 | B2 |
9966487 | Magnusdottir | May 2018 | B2 |
20010054435 | Nagao | Dec 2001 | A1 |
20020015782 | Abys | Feb 2002 | A1 |
20030010377 | Fukuda | Jan 2003 | A1 |
20030180983 | Oswald | Sep 2003 | A1 |
20040261840 | Schmit | Dec 2004 | A1 |
20050039788 | Blieske | Feb 2005 | A1 |
20050268963 | Jordan | Dec 2005 | A1 |
20060048798 | McCoy | Mar 2006 | A1 |
20060086620 | Chase | Apr 2006 | A1 |
20060204730 | Nakamura | Sep 2006 | A1 |
20070011898 | Frank | Jan 2007 | A1 |
20080135085 | Corrales | Jun 2008 | A1 |
20080231768 | Okabe | Sep 2008 | A1 |
20090101192 | Kothari | Apr 2009 | A1 |
20090120497 | Schetty | May 2009 | A1 |
20090133739 | Shiao | May 2009 | A1 |
20090133740 | Shiao | May 2009 | A1 |
20090233083 | Inoue | Sep 2009 | A1 |
20090242021 | Petkie | Oct 2009 | A1 |
20090287446 | Wang | Nov 2009 | A1 |
20090308435 | Caiger | Dec 2009 | A1 |
20100000603 | Tsuzuki | Jan 2010 | A1 |
20100006147 | Nakashima | Jan 2010 | A1 |
20100018568 | Nakata | Jan 2010 | A1 |
20100132762 | Graham | Jun 2010 | A1 |
20100147363 | Huang | Jun 2010 | A1 |
20100180929 | Raymond | Jul 2010 | A1 |
20110023937 | Daniel | Feb 2011 | A1 |
20110023942 | Soegding | Feb 2011 | A1 |
20110030761 | Kalkanoglu | Feb 2011 | A1 |
20110277825 | Fu | Nov 2011 | A1 |
20120012162 | Kobayashi | Jan 2012 | A1 |
20120031470 | Dimov | Feb 2012 | A1 |
20120048349 | Metin | Mar 2012 | A1 |
20120060911 | Fu | Mar 2012 | A1 |
20120125391 | Pinarbasi | May 2012 | A1 |
20120199184 | Nie | Aug 2012 | A1 |
20120237670 | Lim | Sep 2012 | A1 |
20130048062 | Min | Feb 2013 | A1 |
20130061913 | Willham | Mar 2013 | A1 |
20130160823 | Khouri | Jun 2013 | A1 |
20130206213 | He | Aug 2013 | A1 |
20130209776 | Kim | Aug 2013 | A1 |
20130233378 | Moslehi | Sep 2013 | A1 |
20130247959 | Kwon | Sep 2013 | A1 |
20130255755 | Chich | Oct 2013 | A1 |
20130280521 | Mori | Oct 2013 | A1 |
20140120699 | Hua | May 2014 | A1 |
20140124014 | Morad | May 2014 | A1 |
20140196768 | Beitel | Jul 2014 | A1 |
20140313574 | Bills | Oct 2014 | A1 |
20140360582 | Cui | Dec 2014 | A1 |
20150090314 | Yang | Apr 2015 | A1 |
20150155824 | Chien | Jun 2015 | A1 |
20150194552 | Ogasahara | Jul 2015 | A1 |
20150243931 | Fukuura | Aug 2015 | A1 |
20150270410 | Heng | Sep 2015 | A1 |
20150349145 | Morad | Dec 2015 | A1 |
20150349152 | Voss | Dec 2015 | A1 |
20150349703 | Morad | Dec 2015 | A1 |
20160013329 | Brophy | Jan 2016 | A1 |
20160105144 | Haynes | Apr 2016 | A1 |
20160163902 | Podlowski | Jun 2016 | A1 |
20160181446 | Kalkanoglu | Jun 2016 | A1 |
20160225931 | Heng | Aug 2016 | A1 |
20170033250 | Ballif | Feb 2017 | A1 |
20170077343 | Morad | Mar 2017 | A1 |
20170194516 | Reddy | Jul 2017 | A1 |
20170222082 | Lin | Aug 2017 | A1 |
20170358699 | Juliano | Dec 2017 | A1 |
20180166601 | Inaba | Jun 2018 | A1 |
Number | Date | Country |
---|---|---|
102544380 | Aug 2015 | CN |
103426957 | Mar 2016 | CN |
102956730 | Jun 2016 | CN |
102007054124 | May 2009 | DE |
1058320 | Dec 2000 | EP |
2051124 | Apr 2009 | EP |
2709160 | Mar 2014 | EP |
2278618 | Dec 1994 | GB |
S57141979 | Sep 1982 | JP |
S6020586 | Feb 1985 | JP |
H06140657 | May 1994 | JP |
H06264571 | Sep 1994 | JP |
2000058894 | Feb 2000 | JP |
2000091610 | Mar 2000 | JP |
2000216415 | Aug 2000 | JP |
2013211385 | Oct 2013 | JP |
2008136872 | Nov 2008 | WO |
WO-2008136872 | Nov 2008 | WO |
2009062106 | May 2009 | WO |
2009099418 | Aug 2009 | WO |
2010128375 | Nov 2010 | WO |
2011128757 | Oct 2011 | WO |
201359441 | Apr 2013 | WO |
2013067541 | May 2013 | WO |
2013102181 | Jul 2013 | WO |
2014178180 | Nov 2014 | WO |
2015155356 | Oct 2015 | WO |
2016090341 | Jun 2016 | WO |
Entry |
---|
JP-2000058894-A, Machine Translation, Oshima (Year: 2000). |
Bulucani et al., “A new approach: low cost masking material and efficient copper metallization for higher efficiency silicon solar cells” 2015 IEEE. |
Fan et al., “Laser micromachined wax-covered plastic paper as both sputter deposition shadow masks and deep-ultraviolet patterning masks for polymethylmacrylate-based microfluidic systems” via google scholar, downloaded Mar. 31, 2016. |
“An inorganic/organic hybrid coating for low cost metal mounted dye-sensitized solar cells” Vyas, N. et al. |
“Recovery Act: Organic Coatings as Encapsulants for Low Cost, High Performance PV Modules” Jim Poole et al. Nov. 16, 2011. |
Pelisset: “Efficiency of Silicon Thin-Film photovoltaic Modules with a Front Coloured Glass”, Preceedings CISBAT 2011, Jan. 1, 2011, pp. 37-42, XP055049695, the Whole Document. |
Number | Date | Country | |
---|---|---|---|
20190260328 A1 | Aug 2019 | US |