Patent Application
20190128498
Generally, most embodiments of the present invention pertain to optics. In particular, however not exclusively, the present invention concerns laminate structures with embedded, optically functional cavities and manufacturing thereof.
Traditionally microstructures such as microprisms or gratings of different optics-containing devices such as lighting apparatuses and electronic apparatuses have been exclusively produced on surface areas of optically transparent substrates. These structures may have been originally configured to (re)direct, couple or otherwise interact with the incident light in a certain predetermined manner, but positioning thereof on the surface of the material has typically caused a number of problems and defects arising, if not immediately, at least in the long term.
Namely, optically meaningful surface relief structures such as coupling optics are very often subjected, naturally depending on the use scenario, to stress caused by various external factors such as contamination due to dust, sand, water, grease and dirt in general. In addition, the surface forms are generally vulnerable to impacts by external objects, which may break, deform and damage these delicate structures of potentially just micrometer or nanometer size, for example. Even the pressure introduced by a purposefully contacted external element may damage the surface structure patterned on the contact surface and hinder the desired function thereof.
To illustrate some of the above issues,
To cope with the afore-explained interfaces and to improve the coupling efficiency, a solution substantially following the one of
Still staying in the exemplary context of solar cells, the achieved overall efficiency of the contemporary solutions may be surprisingly low, possibly around 15% or below, greatly due to the contamination-induced reflections and miscoupling, surface reflections, internal reflections, such as reflections at medium boundaries between e.g. ITO (indium tin oxide) layer and other layers commonly applied in the solar cells' optical structures. Major portion of the sunlight incident on the optical structure comprising the solar cell is not utilized because certain incident angles are basically disregarded by the conventional optics utilized therewith. In other words, in the illustrated context of solar energy one could say that only direct sunlight reaching the solar cell vertically adds to the efficiency of the solar cell that is thus extremely sensitive to the sun position.
Historically, even the use of laser has been suggested in generating internal, localized changes e.g. in the refractive index of a carrier material to emulate internal gratins therewith. Also specific coatings of predetermined high or low refractive index have been applied on the substrate structures for controlling light propagation therein. Nevertheless, even these and other contemporary solutions have turned out too restrictive, performance-wise inadequate, complex and expensive in the light of widespread industrial scale utilization.
Thereby, the objective is to alleviate one or more problems described hereinabove not yet satisfactorily addressed by the current arrangements, and to provide a feasible alternative for producing various functional structures such as optically functional structures.
The objective is achieved by the embodiments of a laminate structure and a related method of manufacture in accordance with the present invention. It shall be noted that this summary is generally provided to introduce a selection of concepts that are further described below in the detailed description. However, this summary is not intended to specifically identify the sole important or, in particular, essential features of the claimed subject matter and thus limit the claimed subject matter's scope.
Accordingly, in one aspect of the present invention an integrated laminate structure adapted for application in the context of solar technology, wafer technology, cooling channels, greenhouse illumination, window illumination, street lighting, traffic lighting, traffic reflectors or security films, comprises
Preferably either or both the carrier elements comprise optically substantially transparent material, but in some embodiments at least one of the elements may be optically substantially non-transparent and/or comprise non-transparent material depending on the particular use scenario in question. It may be e.g. opaque or translucent.
Preferably, the laminated elements are securely joined together by lamination so that no undesired gaps such as air gaps, naturally excluding the desired, preferably optically functional cavities created by the at least one embedded surface relief pattern, remain therebetween. Further, one shall generally notice that when a surface relief pattern or form of a carrier element is embedded during lamination, it does not appear on the surface of the constructed laminate structure and is not a surface relief pattern or form of the structure.
Yet, in optical applications the patterned laminate layers with the same refractive index may form a single element in terms of optical function relative to light incident thereon.
In some embodiments, the first carrier element may be provided with at least one surface relief pattern having a predetermined optical function relative to light incident thereon and comprising a number of surface relief forms. The pattern may be on the side facing the second carrier element upon and after lamination (embedded), or on the opposite side, for example. In the latter case, the pattern may remain on the surface of the structure or be covered e.g. by a further element and be thus embedded. The patterns of the first and second carrier elements may form an aggregate multilayer pattern having at least one common function, for example. A carrier element, such as the first or second carrier element, may generally be substantially planar, but also other shapes are possible.
In some embodiments, the at least one surface relief pattern of the second carrier and/or of the first carrier element preferably embedded within the laminate structure may indeed be configured to define a number of preferably optically functional cavities therein optionally together with the facing portion of the first carrier and/or second element, respectively, at the interface thereof. An embedded, closed cavity may be e.g. a micro-cavity or a nano-cavity as to the size thereof. The cavities may contain a number of materials potentially different from the materials of the first and/or second carrier elements. A cavity may include or be filled with fluid such as air, suitable liquid, and/or solid. A cavity may include gel. Ink may also be applied. Ink may be transparent or colored. The substances may have been selected so as to provide a predetermined optical performance in terms of e.g. refractive index. The refractive index may differ from the one of the associated carrier element, or it may be the same. A cavity may have a dot-like, an elongated or a more complex shape, for example.
In some embodiments, the at least one, optionally optical function of a utilized, potentially embedded, surface relief pattern comprising a number of surface relief forms may include a function selected from the group of: light directing function, light trapping function, reflective function, transmissive function, transreflective function, coupling function, incoupling function, outcoupling function, polarizing function, diffractive function, refractive function, anti-glare function, anti-clear function, anti-reflection function, collimating function, pre-collimation function, lens function, converging function, diverging function, wavelength modifying function, scattering function, coloring function, medium distribution function, and diffusing function. In the case of embedded patterns one or more functions may be achieved with the established related cavities at the element interfaces. The interfaces or predetermined portion thereof may be made optically transparent with e.g. proper selection of refractive indexes (same), if desired.
A plurality of surface relief forms of the pattern may bear the same function. Alternatively, different forms of the pattern may bear different functionalities. In one embodiment, a single form may provide several, at least two, functionalities. The same pattern or even a form may be configured to transmissively couple light and, on the other hand, reflect light, for instance. The functionality may depend on the nature, such as incident angle and/or wavelength, of light, and/or on the side of the form the light is incident on, for example. A surface relief form, either embedded or not, may be configured for a predetermined number of functions by properly selecting the associated material (contour material and fill material), dimensions, position and/or alignment, for instance.
In some embodiments, the laminate structure may include a third and optionally a number of subsequent carrier elements. These may include further surface relief patterns thereon. The surface relief patterns may be embedded within the laminate structure. Any of the first, second or optional further elements may be a laminate or other type of multi-layer and/or multi-portion element. A middle element may be thicker than the surrounding top and bottom elements such as films that may be provided with a number of surface relief patterns to be optionally embedded, for instance. Also the middle element may be provided with a surface relief pattern that is embedded within the laminate during the manufacturing of the laminate structure.
In some embodiments, the integrated laminate structure may comprise a plurality of layers of (originally) surface relief patters. Each laminated element, such as a film, foil or sheet, may comprise one or more surface relief patterns and construct one or more optically functional layers, respectively. Each layer may have a dedicated optical functionality or several functionalities. A multi-layer pattern may be formed by a single carrier element initially having a layer of surface relief forms on both sides thereof, and/or a plurality of carrier elements, each provided with at least one layer of surface relief forms, may be utilized to collectively form the multi-layer pattern. The layers of the multi-layer pattern may have at least one collective function.
In some embodiments, the first and/or second carrier element is substantially flexible and bendable. The degree of flexibility and bendability may differ embodiment-wise. For instance, a predetermined bend, e.g. 180 degrees, may be achieved with a predetermined bend radius without material breakage. Further carrier elements may be flexible and bendable as well. The laminate structure may be flexible and also bendable.
The carrier element may be thin such as a thin film. The thickness of a carrier element may also vary depending on the embodiment. It may be just a few nanometers up to several millimeters thick, for example. The above applies also to further carrier elements of the laminate structure. However, clearly thicker element(s) may be alternatively used.
In some embodiments, the first and/or second carrier element comprises plastic material such as polymer or elastomer, glass and/or ceramic material. Additionally or alternatively, other material(s) such as semiconductor materials, e.g. silicon or silicon wafer, may be used.
In some embodiments, a surface relief pattern to be optionally embedded comprises a number of surface relief forms defining at least one entity selected from the group consisting of: a grating, a grating groove, a binary shape, a slanted shape, a quadratic or rectangular shape, a triangular shape, a trapezoidal shape, a pixel, a grating pixel, a protrusion, a recess, a hollow, and a lens shape.
In some embodiments, the laminate structure may comprise or form at least part of a transmissive, reflective or transreflective element.
In some embodiments, the laminate structure contains or is provided with a functional surface layer such as a coating and/or a layer containing surface relief forms. These forms may indeed remain on the surface of the laminate structure. The function, or “property”, thereof may include anti-reflection function, hydrophobic function, hydrophilic function, and/or self-cleaning function, for example.
In some embodiments, the laminate structure contains, establishes or is included in an indicative element and/or layer, or it is at least disposed on top of one. It may include an indicative surface such as an indicative sign, a poster or a plate. The indicative window or display may be passive. It may contain one or more symbols, numbers and/or letters. The shown data may be substantially informative, such as traffic signs, warning signs or register plates, and/or commercial such as advertising data by nature. Data indication may have been actualized using optionally embedded surface relief forms to establish, via cooperation with the light coupled therewith, the predetermined visual message, and/or by printing on the surface. The element and the data indicated therewith may be controllable by electronics, for example. The laminate may have e.g. a light-providing or -directing function in that scenario.
In some embodiments, a surface relief form and/or related pattern to be embedded in or be otherwise provided to the laminate structure may substantially be of submicron size regarding the length, depth/height and/or width thereof. Alternatively, the size of the form and/or pattern may be few microns or several tens of microns, e.g. about 20 or about 30 microns up to a number of millimeters. Even larger sizes may be applied.
In another aspect, a method for constructing an integrated structure for optical applications in the context of solar technology, wafer technology, cooling channels, greenhouse illumination, window illumination, street lighting, traffic lighting, traffic reflectors or security films, comprises
obtaining a first carrier element, such as a piece of plastic or glass, preferably comprising optically substantially transparent material enabling light transmission therethrough,
obtaining a second carrier element, such as a piece of plastic or glass, provided with at least one surface relief pattern comprising a number of surface relief forms and having at least one predetermined optical function relative to incident light, said second carrier element preferably comprising optically substantially transparent material enabling light transmission therethrough,
laminating the first and second carrier elements together such that the at least one surface relief pattern is embedded within the established laminate structure.
Embedding the at least one surface relief pattern may practically cause a number of related cavities to be located substantially at the associated interface of the first and second carrier elements in the laminate. Portion of the cavity edges may be thus defined by the facing surface layer of the first carrier element.
In some embodiments, a roll-to-roll procedure is applied in the method. For instance, a roll-to-roll procedure such as roll-to-roll embossing or roll-to-roll imprinting may be applied for establishing the surface relief pattern on a carrier element. Alternatively or additionally, a surface relief pattern could be formed utilizing e.g. at least one technique selected from the group consisting of: embossing, imprinting, micromachining, UV embossing, UV imprinting, lithography, micro-molding, and casting. Yet, the lamination process may utilize roll-to-roll or planar processing technology.
In some embodiments, a carrier element, such as the second carrier element, is provided by at least one surface relief pattern such that a pre-master element, e.g. a pre-master plate comprising a pre-mastering pattern, is first formed utilizing a suitable technique such as electroforming, casting or molding, for example. A master element such as a nickel shim, plastic master plate, cast material plate, or a molded plate, may be formed based on the pre-master element.
Optionally, the pattern(s) of the pre-master element may be modulated by a suitable technique such as printing. Drop filling by inkjet device may be applied for modulation, for instance, such that ink-filled portions of the pre-master do not appear as such in the target element, i.e. the master element.
The previously presented considerations concerning the various embodiments of the laminate structure may be flexibly applied to the embodiments of the method mutatis mutandis and vice versa, as being appreciated by a skilled person.
The utility of the present invention generally arises from a plurality of issues depending on each particular embodiment. First of all, both simple and very complex high performance, integrated nano- or micro-scale structures with various functionalities, such as optical structures, fluidic structures (e.g. channels), cooling structures, or lubricant structures, may be embedded within a laminate structure comprising at least two elements defining at least two layers attached together. The utilized lamination technique may be preferably selected so that the attachment is secure and/or there substantially remain no (unintended) gaps between the laminated elements. Further integrated elements, layers or coatings may be provided on any side of the obtained laminate. In most embodiments, the laminate structure may be manufactured with a relatively simple and low cost industrial scale method. Yet, the embedded structures of the laminate remain protected from external impulses and contamination. Service life of the related products is extended and many of them may be practically maintenance-free.
Also multilevel/layer embedded structures may be easily constructed. Internal light-trapping structures utilizing e.g. specific geometries, refractive indexes and/or materials may be provided for internally reflecting light. Light capture layers effectively capturing and collimating light with a wide range of incident angles may be implemented. The laminate may be applied in connection with integrated electronics, semiconductors, (bio)medical systems, tribological systems, windows such as window lighting, solar cells, green house illumination, advertising, security applications, automotive and generally vehicle industry, street lighting, general lighting and various signs or plates such as traffic signs and luminous tags, for instance.
Particularly in the context of solar energy and especially solar cells (photovoltaic cells), improvements in the operation efficiency due to more efficient capturing of incident (surface) light to the solar cell, more efficient internal light trapping, and reduced if not completely eliminated contamination problems, may be achieved. The solar cell may remain static and implementing a moving means for adjusting the alignment thereof is unnecessary despite the increased efficiency. The laminate structure attached to the solar cell may be further provided with additional functionalities and layers such as self-cleaning nanostructures, coatings etc. Larger functional surfaces may be constructed. Rigid or flexible solar cell structures may be considered.
The expression “a number of” refers herein to any positive integer starting from one (1), e.g. to one, two, or three.
The expression “a plurality of” refers herein to any positive integer starting from two (2), e.g. to two, three, or four.
The expression “to comprise” is applied herein as an open limitation that neither requires nor excludes the existence of also unrecited features.
The terms “a” and “an” do not denote a limitation of quantity, but denote the presence of at least one of the referenced item.
Likewise, the terms “first” and “second” do not denote any order, quantity, or importance, but rather are used to distinguish one element from another.
The term “light” refers to electromagnetic radiation such as visible light but being not limited to visible light.
The term “carrier element” may generally refer herein to an element of the laminate that comprises predetermined material, such as material for carrying light, an element that comprises a predetermined functional element such as a coating or at least portion of a structure such as a surface relief pattern or a related cavity, and/or an element that supports, carries, protects or is at least fixed to other one or more elements in the finished laminate and therefore forms an integral part of the laminate.
Different embodiments of the present invention are disclosed in the dependent claims.
Next the invention is described in more detail with reference to the appended drawings in which
The principles of present invention may be applied in various use scenarios and contexts. The context may relate to the utilization of visible, infrared and/or UV light, for instance.
In some embodiments of the present invention, the laminate structure may be produced from bulk elements such as bulk plates or films. These may be provided with optical patterns having desired optical functions such as coupling, e.g. incoupling or outcoupling, function. Patterns with small surface relief forms such as gratings, binary, blazed, slanted and/or trapezoidal forms may be utilized. Discrete patterns such as grating pixels, small recesses, or continuous forms, elongated recesses or channels, basically almost any kind of two or three dimensional forms, may be utilized. Preferably there are at least small flat portions, i.e. contact surfaces, on the laminate junction areas (interfaces) to enhance adhesion of the associate laminate layers and/or to obtain desired light propagation and/or other behavior.
The embedded surface relief pattern may form and be considered to include a number of closed cavities such as micro-cavities filled with air or other medium on the junction area. Also a number of larger structures such as refractive structures may be established. Accordingly, the cavities are preferably optically functional and have at least one predetermined optical function. Thus, when designing a surface relief form/pattern to be embedded, one shall naturally contemplate the functionality of the form/pattern as embedded in the laminate such that the surrounding laminate materials, shapes and forms, established cavities at the interfaces, etc. are properly taken into account as to their e.g. optical effect.
In some embodiments, the outmost laminate element such as the top or bottom laminate element, when in use, may contain integral light coupling optics such as incoupling optics, outcoupling optics and/or polarization gratings such as wire grid or other grating solutions. The optics may include embedded optics and/or surface optics.
In some embodiments, a number of light sources may be functionally and/or physically connected to the laminate structure, via edge for example, using suitable optionally laminate- and/or light source-integrated coupling optics such as collimation and/or reflective optics. Bottom coupling is a further possibility.
In some embodiments, a multilayer such as dual-layer optic structure is implemented by the laminate for coupling or other purposes. A layer or other element of the laminate may be configured for certain wavelength of light such as a certain range of wavelengths. Another layer may be configured for other wavelengths. For instance, a surface layer or a layer closer to the surface may be configured for IR (longer wavelength) and another layer residing deeper in the structure for visible light (shorter wavelength), or vice versa. The layer thicknesses may be selected on target wavelength basis. With proper thicknesses, desired layers may be made practically invisible from the standpoint of desired wavelengths. The laminate may incorporate coupling optics, e.g. coupling layers with surface relief patterns, on multiple sides thereof.
In some embodiments, the laminate structure may be applied in advertising and indicative windows, displays, signs or marks. An optically functional element, such as a plate or film, which may be a laminate, may be disposed on top of a target picture or other target element as a separate element or integrated therewith (laminated, for instance). It may contain a surface relief pattern optionally located closer to the picture or the other target element than the opposite surface to enhance contrast. A binary grating or other patterns may be utilized e.g. with a panel element. Binary grating may be desired for larger viewing angle applications and a blazed grating for narrower angle. Hybrid grating solutions are possible as well. Diffusing optics may be utilized for hot spot avoidance and for more uniform illumination. The solution is also applicable to UI solutions and license plates for instance. With license plates or other elements with identification or other visual data provided thereon, the indicated numbers, letters, etc. may be laminated into contact with a front plate to make number/letter surroundings illuminated, for example, for improved contrast.
In various embodiments of the present invention, one or more elements of the laminate structure may be substantially optically transparent, translucent or opaque. The required degree of transparency of each element naturally depends on each particular use case. For example, in some embodiments the preferred transmittance in relation to predetermined wavelengths of light (e.g. infrared, visible or uv) may reside within the range of about 80 to 95%, for instance, for a material considered as substantially optically transparent in that context.
Reverting to the figures,
The top element 204 has been originally provided with a surface relief pattern comprising a number of protruding surface relief forms 208 on the bottom thereof with corresponding recesses 210 in between. The top element 204 and bottom element 206, which may be considered as a substrate carrier of the top element 204 and a partial substrate for the created cavities defining at least a portion of the walls thereof at the interface of the elements 204, 206, have been then laminated together so that the protrusions 208 of the surface relief pattern extending downwards with the shape of e.g. a truncated cone (note cross-sectional form of an isosceles trapezoid in the figure) have contacted the alignment-wise corresponding surface portions of the bottom element 206 having a substantially flat contact surface in the illustrated case. Thereupon, the recesses 210 have formed cavities potentially including material such as air trapped therein unless a vacuum has been provided. The material may thus have a refractive index different from the surrounding material. If the material of the element 204 is plastic, its refractive index is generally higher than the refractive index of air, for instance.
Regarding the use of different materials or refractive indexes in general, when multiple elements such as material layers bear the same index, these may be regarded as a single element by light, thus defining an optically transparent interface. On the contrary, different materials with unequal indexes may be utilized in order to modify light management, e.g. total internal reflectivity, as desired.
The utilized shapes and/or refractive indexes nair, n1, n2 of the materials carried by the elements 204, 206 may have been selected so as to provide a desired functional effect in terms of light propagation. It is illustrated in the figure by the arrows how a number of light rays with different incident angles may be collimated by the applied configuration of laminate layers and surface relief pattern therein to advance towards the bottom of the laminate in substantially perpendicular fashion. Thus the top element 204 may be considered to act as a light capture layer for the underlying one or more elements 206. In some embodiments, the element 204 may be thin, essentially a film, with only e.g. few nanometers thickness, whereas in some other embodiments it may be several millimeters thick or even considerably thicker. The same considerations apply to the bottom layer 206. The shown or a similar embodiment could be applied in the context of window illumination or solar cells, for instance.
The middle element 505 comprises a surface relief pattern of substantially rectangular (binary) forms 508, which may (being not visible in the cross-sectional figure) be dot or pixel like forms or longer grooves such as grating grooves or corresponding protrusions. The top element 504 comprises a pattern of triangular forms 510. The top element 504 may form in the laminate at least one optically functional layer the embedded surface relief pattern of which has at least one predetermined function such as incoupling or outcoupling function. The middle element 505 may form at least one other optically functional layer the embedded surface relief pattern of which has potentially other predetermined function such as reflective function. Again, a number of different forms and/or layers of microstructures may be configured regarding a common functionality from the standpoint of a desired functionality such as predetermined light incoupling or outcoupling property such as collimation or decollimation property. The cavities established by embedded surface relief forms may contain air and/or some other material(s).
The film element 702 and a carrier element 704 that may also act as the cover plastic or glass of the solar cell structure (indeed, often the solar cells are provided with integral cover glass) may be first laminated together and stored and delivered for later joining with the rest 706 of the complete solar cell structure as suggested herein, for example. This is highlighted at 702a of the figure wherein the vertical arrow depicts the fact how the already laminated film element 702 and cover glass 704 are to be joined with the solar cell stack 706 typically comprising a plurality of different layers and related elements illustrated in the figure by a plurality of horizontal lines. For example, the solar cell structure 706 potentially stacked below the cover glass 704, which preferably contains tempered glass, may incorporate one or more layers or elements selected from the group consisting of: a back contact, a p type semiconductor, an n type semiconductor, a front contact, transparent adhesive, and anti-reflective coating.
At 702b, a use situation after completing the manufacturing of the overall solar cell structure comprising also the film element 702 for light capturing as an integral part is shown. Alternatively, the film element 702 may be provided as such onto the solar cell structure having the front glass 704 already in place. As a further alternative or supplementary option, the element 702 may be provided between the glass 704 and the rest of the solar cell structure 706. Still as a further example, the glass 704 may be provided with a surface relief pattern. The established cavities 709 may contain air and/or some other material(s) left or specifically disposed therein during the manufacturing process of the laminate structure.
Generally, the described nano- and microcavity film techniques can be utilized in different layers of a solar cell product 702b. E.g. complex undercut profiles are possible. Also multi-layers with multi-profiles are suitable as contemplated hereinbefore. An optically functional layer can be produced/applied on the top surface, some internal surface (e.g. to the middle under the glass plate) or directly on the silicon surface/solar cell surface including possible nanoprofile in the silicon/photovoltaic surface to improve light absorption. The optical profiles are preferably fully integrated.
The arrows depict in the figure how the suggested construction may enhance the efficiency of the solar cell in a variety of ways. In addition to or instead of incident light coupling and/or directing (e.g. collimation) function 708a, reflective and generally “light-trapping” functions 710, 712 may be achieved by the utilized patterns including cavities, their positioning, alignment and material selections. The light traps may be thus formed without true, reflective mirror surfaces in the carrier material.
The solar cell structure suggested herein may provide about 20-40% higher efficiency than the conventional solutions, whereupon the overall efficiency may approach e.g. 40% or 50%. Both rigid and flexible solar cell materials and structures may be applied and constructed.
For example, a number of anti-reflective (AR) and/or self-cleaning (nano)profiles may be utilized to minimize surface reflection and contamination. The AR functionality may preferably enable incoupling sunlight even with very large incident angles relative to the structure surface (normal), such as angles of about 70 or 80 degrees, into the structure from the atmosphere so that the solar cell receives as much light as possible and the efficiency thereof may be maximized. This is indicated in the figure by the arrows 808b. The embedded surface relief pattern 802a of element 802 may be then utilized to direct and collimate the incoupled light towards the solar cell 806. The pattern 802a may also be designed so as to be capable of coupling a considerable range of incident angles, e.g. a total range of 120, 130, 140, 150 or 160 degrees, as desired.
For example, the pattern 802a may be configured to couple incident light such as sunlight having entered the structure so that the incident angles properly coupled optionally defining a range of at least about 120, 130, 140, 150 or 160 degrees, and wherein the pattern is configured to couple the incident light with a collimation function substantially towards a predetermined direction of a solar cell.
Also integrated reflectors with micro-cavities may be adopted for solar cell structures, which may improve maintaining the sunlight longer inside the structure, whereupon energy absorption can be potentially improved. Accordingly, the suggested laminate structure may in some embodiments improve the efficiency of the solar cell considerably.
It shall be mentioned that in some embodiments the constructed overall solar cell structure including the light capturing or other laminated element may contain multiple, e.g. two, functional, such as anti-reflective, layers. One may be disposed on either side of the cover glass and the other on the other side in connection with the light capture film element such that it preferably receives the external, incident light prior to the light capture film element.
The principal ideas presented hereinbefore relative to a solar cell coupling film or other element with a large incidence angle collimation are generally applicable to other scenarios as well including e.g. greenhouse related embodiments. These kinds of films may increase the use of sun light without extra mirrors, for instance. The transparency of the film may be enhanced by means of minimized pattern features relative e.g. to the size thereof.
In some embodiments, the principles described herein may be capitalized in the context of windows or displays. The windows/displays may be used for advertizing, safety or security purposes, for example.
In some embodiments, a number of embedded reflectors such as nanoreflectors may be manufactured by the techniques presented herein. Small patterns, e.g. grating based reflecting profiles can be laminated directly on e.g. a planar reflector and those small surface relief patterns of laminated elements may be completely embedded, unlike e.g. with conventional retroreflector films.
In some embodiments, a polarizer may be manufactured in accordance with the principles set forth herein. E.g. a grating/wire grid polarizer may be produced optionally by a roll-to-roll method. Basic profiles may be manufactured by applying UV curing and related curable material, for example, after which deposition coating by higher refractive index by means of laser assisted deposition may be executed on the line. The laser may be used to deposit many different materials. Also orientated directional deposition (on-side deposition, asymmetric deposition) is possible. A grating profile may be binary, slanted, quadrate, etc. with different slanted surfaces, etc.
In some embodiments, a number of features of the present invention may be utilized in connection with light incoupling and related solutions. Nowadays, e.g. LED light incoupling and collimation for a typically planar element is a critical issue. A flat ball lens bar optionally in a row form is a unique solution. It could contain 2D or 3D surface depending on the collimation axis. Principally, one axis collimation may be enough. Such an optical solution may be produced separately or together with the planar element. Possible manufacturing methods include injection molding, casting, laser cutting, etc. It is possible to use mirror surface on the top and bottom for the light direction control. Also special grating orientating patterns on the edge and/or e.g. top may provide desired solutions. A wedge type of collimation with air medium is a further feasible option.
At 930, potential, corresponding side views are shown with additional, preferably integrated, reflector elements 932. Lens shapes 924a, 924b are apparent in the figure.
Thus in various embodiments of the present invention, a laminated lens element such as lens film may be utilized to form nano- /microcavity coupling structures. Embossed/imprinted films can be laminated on a carrier material/film. This makes possible to produce new lens structures with multi layer patterns. Another benefit is that optical patterns are completely integrated/embedded and those can't be defected or destroyed easily. There are several feasible applications such as street lamps, halogen replacements, etc.
Another potential illumination lens is a non-direct transmission element, which couples light e.g. from the air medium and directs it to preferred angles. One surface may have a reflector (2D or 3D) and the other a surface coupling pattern (2D or 3D).
A light source, such as LED, bar may be collimated at least in 2D horizontal direction. This may make coupling pattern more simple and efficient. The solution may have applications in e.g. street lights, public illumination, etc.
Another application is a light bar, rod or tube, in which the coupling structure or film forms or is in the outer or inner surface thereof for coupling and directing the light. In the tube solution a reflector rod may be utilized in the center (inner part). A coupling film may also be laminated in the glass to direct the light to preferred angles (inside or outside).
One additional benefit with surface relief-based, optionally embedded, lenses such as grating lenses is efficiency, which is better than with conventional Fresnel lens, for example, due to e.g. smaller features having much less back reflection than conventional larger patterns, and also to the possible (bottom) location of the patterns. When those patterns are on the bottom side of the overall structure, there is not so much direct back reflection, because medium carrier is on the top side.
This may be a benefit for e.g. traffic signs due to the lower sun phantom effect (back reflection). Additionally, the solution is suitable for e.g. brake and signal lights in vehicles.
At start-up 1102 the necessary equipment such as embossing/imprinting gear, molding gear, casting gear, lamination gear, curing gear and/or roll-to-roll gear is obtained and configured. Yet, source materials for laminate layers and the lamination itself, such as necessary adhesives, if any, are obtained.
At 1104, a first carrier element defining at least one layer of the integrated laminate structure is obtained. The first element may be provided with desired surface relief patterns and coatings. Curable material such as lacquer may be provided, embossed or otherwise processed to contain a surface relief pattern and cured, for example. The element may be molded or cut to desired dimensions from a larger piece of source material such as plastic or glass. It may be subjected to a number of treatments and/or provided with adhesive for lamination purposes. Optionally, the first element is a multilayer element such as a laminate element itself. It may be contain e.g. a plurality of solar cell-constituting layers and/or elements.
At 1106, a second carrier element to be utilized in the integrated laminate structure is obtained. It contains a number of surface relief patterns that may be fabricated, as the ones of the first element, with different methods, such as roll-to-roll embossing/imprinting, lithography, micro-molding, casting etc. on the surface thereof. It may contain plastic, glass or ceramic material, for example. Suitable curing may be applied. Further, desired additional elements and/or coatings may be provided to the second element. The second element may be a multilayer element such as a laminate element.
In conjunction with the present invention, a surface relief pattern may be produced by means of pre-master pattern, master pattern and related elements. A pre-master element with a pre-mastering pattern may be first created by micro machining, lithography, imprinting, embossing and/or by some other method. This pre-mastering pattern may be then replicated by electroforming, casting or molding. Then formed nickel shim, a plastic master plate, a cast material plate, a molded plate may contain plurality of micro relief pattern on the surface, preferably small grooves, recesses, dots, pixels, etc.
The preferably negative relief patterns of the pre-master are advantageously suitable for the inkjet and/or printing modulation process. This modulation process may be based on a profile filling method, in which the existing groove, recess, dot, pixel, etc. is potentially completely filled with inkjet/printed material. This material is dispensed by forming small pico-drops in order to fill and “hide” the existing patterns. Method is suitable to complete a filling factor modulation on the surface of the target element, i.e. the master. Naturally the method is suitable for many other applications as well, and not only to filling factors. It's suitable also to design different discrete figures, icons, forms and shapes, for example. This makes it possible to create low cost optical designing process, which is fast, flexible and first of all, easy to utilize. A skilled person will realize that the profile filling method suggested herein is generally feasible also in other contexts than merely the laminate context of the present application.
The fill material such as ink could be transparent and optically clear, which has preferable the same refractive index than the plate material. This way it is possible to make real functional tests and trials. But e.g. colored ink is also possible, but then replication process may be needed in order to obtain a functional, optical test part.
One issue to consider may be the drop size and material viscosity. This might be important in terms of controlled and high quality filling. If the viscosity is too low, the drop will flow for large area and it goes along the groove bottom. Thus completely filled structure is getting more difficult to achieve. If the viscosity is high, the drop size is getting bigger, but the form is more compact and doesn't flow on the groove too much. A preferred solution may therefore include low viscous material, which guarantees small drop size. And if utilizing only a small pattern, discrete grooves, recesses, dots or pixels, the drop advantageously fills only preferred patterns in the desired location. Thus the pre-master may be preferably patterned with small pixels or discrete profiles.
At 1108, the first and second elements, and optionally further elements, are laminated together utilizing suitable pressure, heat and optionally adhesive(s) between the elements to be laminated together. Feasible curing may be applied. The embedded surface relief profiles basically establish associated micro- and/or nanocavity patterns. Potentially very complicated volumes (e.g. cavities) may be created, which is difficult if not impossible by other methods. Multilevel/multilayer patterns are possible by laminating several patterned medium carriers (elements) together. An element to be included in the laminate may comprise a surface relief pattern on multiple sides thereof. Different patterns can provide different functionalities in the laminate.
One realization implies laminating e.g. UV embossed/imprinted thin films (patterned films) on a thicker carrier such as plastic or glass plate and then executing the final curing in order to obtain good adhesion between laminated film and plate. Roll-to-roll lamination is possible provided that the laminated elements are suitable, i.e. thin/flexible enough, for the purpose.
At 1110 further elements and/or functionalities may be provided to the laminate. Post-processing actions such as cutting, excess material removal, (re-)reeling, testing etc. may be performed.
The method execution is ended at 1112.
The mutual ordering and overall presence of the method items of the method diagrams disclosed above may be altered by a skilled person based on the requirements set by each particular use scenario. Execution of some method items may be alternately repeated during the method as illustrated by the broken arrows.
After establishing 1316 a surface relief pattern “A” on the lacquer-provided foil by embossing or some other technique, the pattern may be, when needed, pre-cured 1318 by a suitable method such as UV curing potentially followed by lamination 1320 relative to a carrier element such as another film. The established laminate “A” including the pattern A preferably as embedded may be cured at 1322 after which it a further functional element such as foil may be coupled, preferably by lamination 1324, thereto, which is generally shown, by way of example only, at 1304 with substantially similar process items indicated by identical reference numerals supplemented by ‘b’, however. Nevertheless, these process items do not have to be similar and e.g. different pattern formation technique and/or curing technology could be applied. The further functional element may include a pattern “B” as indicated in the figure. The final laminate comprising both patterns A and B may be subjected to a number of applicable curing 1326 procedures and/or other treatments.
Consequently, a skilled person may, on the basis of this disclosure and general knowledge, apply the provided teachings in order to implement the scope of the present invention as defined by the appended claims in each particular use case with necessary modifications, deletions, and additions, if any.
For example, in some embodiments, one or more elements of the integrated laminate structure may contain the explained cavity optics for predetermined purpose such as uniform illumination or discrete illumination. The optically functional elements may be integrated by lamination with other elements such as covers of various electronic or other devices.
The present invention enables providing localized optical functions within integrated structures such as laminates. Local effects and visual indications, such as informative indications, may be created in certain embodiments thereof.
Generally in different embodiments of the present invention the relief forms may be positive or negative relative to the associated surface level of the carrier substrate.
In some embodiments, instead of or in addition to lamination, the elements of the integrated structure may be attached using some other methods such as mechanical fastening structures, mere adhesives, etc.
In some embodiments, a laminate structure according to the present invention may be further integrated with or configured to contain other elements such as chips, chip packages, solar cell structures, light sources, lighting elements, electronics, cover or body structures, etc.
Each of the afore-explained various functions/functionalities may be implemented in the laminate structure by a dedicated element, a shared element or by a plurality of cooperating elements.
Instead of or in addition to optics, the laminate solution presented herein could be utilized in other contexts such as microfluidics. E.g. cooling structures and cooling channels could be manufactured therewith. Also lubricant channels could be formed.
This application is a continuation application of U.S. patent application Ser. No. 13/640,066, filed Oct. 9, 2012, which is a U.S. national stage entry of PCT/FI2011/050300, filed Apr. 6, 2011, which claims priority to U.S. Provisional Patent Application No. 61/388,233, filed Sep. 30, 2010, and U.S. Provisional Patent Application No. 61/282,818, filed Apr. 6, 2010. The contents of U.S. patent application Ser. No. 13/640,066, international application no. PCT/FI2011/050300, U.S. Provisional Patent Application No. 61/388,233, and U.S. Provisional Patent Application No. 61/282,818 are incorporated herein by reference.
| Number | Date | Country | |
|---|---|---|---|
| 61282818 | Apr 2010 | US | |
| 61388233 | Sep 2010 | US |
| Number | Date | Country | |
|---|---|---|---|
| Parent | 13640066 | Oct 2012 | US |
| Child | 16232558 | US |
