Patent Grant
11835296
The present invention relates to removing blockages in a solids injection lance. More particularly, the invention relates to a method and apparatus for removing blockages in a solids injection lance.
The present invention relates particularly, although not exclusively, to solids injection lances of a direct smelting vessel, such as a molten bath-based direct smelting vessel for producing molten metal, such as iron, in a direct smelting process.
The invention has application to molten bath-based metallurgical processes that involve injecting solid materials under pressure into the molten bath via an outlet submerged in the molten bath. The invention also has application to plants and processes that involve conveying solid feed materials by entrainment.
A known molten bath-based smelting process is generally referred to as the “HIsmelt” process and is described in a considerable number of patents and patent applications in the name of the applicant.
The HIsmelt process is applicable to smelting metalliferous material generally but is associated particularly with producing molten iron from iron ore or another iron-containing material.
In the context of producing molten iron, the HIsmelt process includes the steps of:
The term “smelting” is herein understood to mean thermal processing wherein chemical reactions that reduce metal oxides take place to produce molten metal.
Another known process for smelting a metalliferous material is referred to hereinafter as the “HIsarna” process. The process is carried out in a smelting apparatus that includes (a) a smelting vessel that includes solids injection lances and oxygen-containing gas injection lances and is adapted to contain a bath of molten metal and (b) a smelt cyclone for pre-treating a metalliferous feed material that is positioned above and communicates with the smelting vessel. The HIsarna process and apparatus are described in International application PCT/AU99/00884 (WO 00/022176) in the name of the applicant.
In the HIsmelt process solid feed materials in the form of metalliferous material (which may be pre-heated) and carbonaceous material and optionally flux material are injected with a carrier gas into the molten bath through a number of water-cooled solids injection lances which are inclined to the vertical so as to extend downwardly and inwardly through the side wall of the main chamber of the smelting vessel and into a lower region of the vessel so as to deliver at least part of the solid feed materials into the metal layer in the bottom of the main chamber. The solid feed materials and the carrier gas penetrate the molten bath and cause molten metal and/or slag to be projected into a space above the surface of the bath and form a transition zone. A blast of oxygen-containing gas, typically oxygen-enriched air or pure oxygen, is injected into an upper region of the main chamber of the vessel through a downwardly extending lance to cause post-combustion of reaction gases released from the molten bath in the upper region of the vessel. In the transition zone there is a favourable mass of ascending and thereafter descending droplets or splashes or streams of molten metal and/or slag which provide an effective medium to transfer to the bath the thermal energy generated by post-combusting reaction gases above the bath.
Typically, in the case of producing molten iron, when oxygen-enriched air is used, the oxygen-enriched air is generated in hot blast stoves and fed at a temperature of the order of 1200° C. into the upper region of the main chamber of the vessel. If technical-grade cold oxygen is used, the technical-grade cold oxygen is typically fed into the upper region of the main chamber at or close to ambient temperature.
Off-gases resulting from the post-combustion of reaction gases in the smelting vessel are taken away from the upper region of the smelting vessel through an off-gas duct.
The smelting vessel includes a main chamber for smelting metalliferous material and a forehearth connected to the main chamber via a forehearth connection that allows continuous metal product outflow from the vessel. The main chamber includes refractory-lined sections in a lower hearth and water-cooled panels in side walls and a roof of the main chamber. Water is circulated continuously through the panels in a continuous circuit. The forehearth operates as a molten metal-filled siphon seal, naturally “spilling” excess molten metal from the smelting vessel as it is produced. This allows the molten metal level in the main chamber of the smelting vessel to be known and controlled to within a small tolerance—this is essential for plant safety.
In the HIsarna process, carbonaceous feed material (typically coal) and flux (typically burnt lime) are injected into a molten bath in the smelting vessel via solids injection lances.
The solid feed materials in both the HIsmelt and HIsarna processes are typically in the form of fines and, under certain circumstances, a blockage of solid feed materials may occur in a liner of a solids injection lance.
One option for resolving this problem is to remove the blocked liner from the lance and to replace it with another liner. Another option is to drill out the blockage under atmospheric pressure conditions. This latter option requires production to stop and a slag layer of the molten bath to be partly tapped. Additionally, the blocked lance must be depressurised prior to being drilled or changed. The smelting process then needs to be restarted by replacing the tapped slag and by ramping up supply of solid feed material over a period of time.
The present invention provides a method of removing a blockage in a solids injection lance without a complete production stoppage and slag draining.
The above description is not to be taken as an admission of the common general knowledge in Australia or elsewhere.
The present invention is a method of removing a blockage in a solids injection lance under normal operating conditions of a direct smelting vessel containing a bath of molten metal and slag, wherein the solids injection lance extends into the direct smelting vessel and has an outlet end that is submerged in the molten slag and has a single inlet coupled to a section of supply line that conveys gas and solid feed material to the solids injection lance, the section of supply line is upstream and co-axial with the solids injection lance, the method comprising:
Removal of the blockage in this manner avoids the need to remove and replace the liner from the solids injection lance when it becomes blocked. This means that it is not necessary to stop production. It also means that it is not necessary to partly drain the slag inventory so that the molten slag in the bath is below of the outlet end of a lance. Reverting to normal production rates after these steps involves restoring the slag inventory because the slag inventory is important for operation of the HIsmelt process and involves ramping up supply of metalliferous material over a period of time to ensure that the temperature of the molten bath is maintained at an optimum temperature for smelting. The compound effect of both prolongs the time to return to normal production rates. The method described above, therefore, enables production to continue, albeit at a reduced rate, and reduces the time to return to normal production rates.
Under normal operating conditions, the solids injection lance is supplied with solids entrained in a carrier gas at a pressure higher than a gas pressure in the direct smelting vessel and the method may include maintaining the supply of carrier gas so that the supply line section and the lance upstream of the blockage remain at a pressure higher than the gas pressure in the direct smelting vessel.
The method may include ceasing supply of the carrier gas and may include providing the elevated gas pressure conditions by supplying a pressurised purge gas to the solids injection lance upstream of the blockage such that, upon removal of the blockage, the purge gas flows into the direct smelting vessel.
The method may further comprise re-commencing supply of the carrier gas after the blockage is removed and reducing and ultimately ceasing the supply of purge gas after commencing supply of the carrier gas.
The method may further comprise depressurising the solids injection lance and the upstream supply line section upstream of the blockage, advancing the blockage-removing tool to the blockage and re-pressurising the solids injection lance and the supply line section before operating the blockage-removing tool to remove the blockage.
Re-pressurising the solids injection lance and the supply line section may comprise supplying a purge gas to the supply line section and to the solids injection lance upstream of the blockage. Alternatively, re-pressurising the solids injection lance and the supply line section may comprise re-commencing supply of the carrier gas.
The pressure in the direct smelting vessel may be, under normal operating conditions, between 0.5 barg and 1.2 barg.
The method may further comprise after step (a) and prior to step (b) purging loose solid material from the solid injection lance and the section.
The tool may be a drill and the method may involve removing the blockage by drilling through the blockage.
Removing the blockage may involve drilling into the blockage adjacent an internal side wall of the solids injection lance to weaken the blockage at an interface with the side wall.
Step (b) may involve connecting the tool to a series of extension bars and advancing the bars into the supply line section and the solids injection lance until the tool reaches the blockage.
The entrained solid material may include metalliferous material.
The entrained solid material may include metalliferous material and carbonaceous material.
The entrained solid material may include metalliferous material, carbonaceous material, and flux material.
The metalliferous material may be iron ore. The iron ore may be pre-heated to a temperature of at least 500° C. The iron ore may be in the form of fines.
The entrained solid material may include carbonaceous material.
The carbonaceous material may be coal.
The invention extends to situations in which there is only metalliferous material injected into the direct smelting vessel by the lance.
The invention extends to situations in which there is only carbonaceous material injected into the direct smelting vessel by the lance.
The invention is also an apparatus for removing a blockage in a solids injection lance extending into a direct smelting vessel, the solids injection lance having a single inlet coupled to a section of supply line that conveys gas and solids to the solids injection lance and that is upstream and co-axial with the solids injection lance, the apparatus comprising a tool that extends through the supply line section and the solids injection lance to remove a blockage of solid material and an assembly for advancing the tool through the solids injection lance and the supply line section to the blockage from an upstream side of the blockage.
The apparatus may further comprise a gas-pressure seal that enables gas pressure within the solids injection lance and the supply line section to be maintained above the gas pressure in the direct smelting vessel during normal operation while the tool is advanced to the blockage, is operated to remove the blockage and is retracted from the supply line section and the solids injection lance.
The tool may comprise a drill head and a drill operably connected to the drill head to cause the drill head to rotate.
The advancing assembly may comprise a number of drill bar extensions that are sequentially connectable to extend the length of the operating connection between the drill and the drill head.
The advancing means may further comprise a driver for advancing and retracting the drill head and drill bar extensions within the solids injection lance.
The driver may be a rail-mounted car to which the drill is mounted for reciprocal movement co-axial with the solids injection lance and the drill bar extensions include inter-connecting links such that reciprocal movement of the rail-mounted car causes a corresponding movement of the drill bar extensions and the drill.
The apparatus may further comprise an isolation valve upstream of the lance to enable the tool to be introduced to and retrieved from the solids injection lance under atmospheric pressure.
The invention is described further, by way of example only, with reference to the accompanying drawings, of which:
The following description is in the context of smelting iron ore fines to produce molten iron in accordance with the HIsmelt process.
It will be appreciated that the present invention is applicable to smelting any metalliferous material, including ores, partly reduced ores, and metal-containing waste streams via any suitable molten bath-based direct smelting process and is not confined to the HIsmelt process. It will also be appreciated that the ores can be in the form of iron ore fines.
The vessel 11 has a hearth that includes a base 12 and sides 13 formed from refractory bricks, side walls 14, which form a generally cylindrical barrel extending upwardly from the sides 13 of the hearth, and a roof 17. Water-cooled panels (not shown) are provided for transferring heat from the side walls 14 and the roof 17. The vessel 11 is further provided with a forehearth 19, through which molten metal is continuously discharged during smelting, and a tap-hole 21, through which molten slag is periodically discharged during smelting. The roof 17 is provided with an outlet 18 through which process off gases are discharged.
In use of the vessel 11 to smelt iron ore fines to produce molten iron in accordance with the HIsmelt process, the vessel 11 contains a molten bath of iron and slag, which includes a layer 22 of molten metal and a layer 23 of molten slag on the metal layer 22. The position of the nominal quiescent surface of the metal layer 22 is indicated by arrow 24. The position of the nominal quiescent surface of the slag layer 23 is indicated by arrow 25. The term “quiescent surface” is understood to mean the surface when there is no injection of gas and solids into the vessel 11. Under normal operating conditions, the process operates in a range of pressures between 0.5 barg and 1.2 barg, and preferably between 0.6 to 1.0 barg.
The vessel 11 is provided with solids injection lances 27 that extend downwardly and inwardly through openings (not shown) in the side walls 14 of the vessel and into the slag layer 23. The solids injection lances 27 are described in more detail in relation to
The outlet ends 28 of the solids injection lances 27 are above the surface of the metal layer 22 during operation of the process and are submerged in the slag layer 23. This position of the lances 27 reduces the risk of damage through contact with molten metal and also makes it possible to cool the lances by forced internal water cooling, as described further below, without significant risk of water coming into contact with the molten metal in the vessel 11.
The vessel 11 also has a gas injection lance 26 for delivering a hot air blast into an upper region of the vessel 11. The lance 26 extends downwardly through the roof 17 of the vessel 11 into the upper region of the vessel 11. In use, the lance 26 receives an oxygen-enriched hot air flow through a hot gas delivery duct (not shown), which extends from a hot gas supply station (also not shown).
The plant includes the direct smelting vessel 11 shown in
The plant also includes a pre-treatment unit 34 in the form of a pre-heater for heating iron ore fines, typically to a temperature of at least 600° C. The pre-heater may be any suitable type of pre-heater.
The plant also includes an ore delivery system for supplying iron ore fines to the lances 27.
The ore delivery system includes (a) an ore storage/dispensing unit 32 for storing and dispensing heated iron ore fines and (b) an ore supply line 36 for supplying heated ore from the ore storage/dispensing unit 32 to the lances 27.
The ore storage/dispensing unit 32 is constructed to store and dispense heated iron ore fines entrained in nitrogen carrier gas. The ore storage/dispensing unit 32 can be in the form of a plurality of bins that allow heated iron ore fines to be transferred from standard atmospheric conditions to an environment of pressurized carrier gas. However, for the purposes of the present invention, the ore storage/dispensing unit 32 can be considered as a single unit. The carrier gas is pressurised so that the pressure drop from an inlet end 29 of the solids injection lance 27 to the outlet end 28 is at least 1 bar.
In use, iron ore fines are fed to the pre-heater 34 from a stockpile (not shown) and the pre-heater heats the fines. The pre-heater 34 is arranged to heat the fines such that the fines are at a temperature of at least 500° C. and typically of the order of 600° C. to 700° C. at the point of injection into the vessel 11. Off gases can be supplied from the outlet 18 to the pre-heater 34, such that heat can be transferred from the off gases to the iron ore fines. The pre-heater 34 is arranged to supply the heated iron ore fines to the ore storage/dispensing unit 32.
The ore supply line 36 for transporting heated iron ore fines from the storage/dispensing unit 32 to the lance 27 includes (a) a first section 48 that carries the fines to a location proximate the vessel 11, (b) an upwardly extending section 42 which conveys the fines from a position that is approximately level with the base 12 of the vessel 11 to at least the height of the lance 27, and (c) a downwardly extending section 46 which connects the line to an ore inlet in the lance 27. The section 46 is formed to be co-axial with the lance 27 when in an operating position as shown in
The plant also includes a separate coal delivery system for supplying coal to the lance 27.
The coal delivery system is in the same form as the ore delivery system described above with the exception that the coal is not pre-heated before supply to lance 27. Additionally, the coal delivery system typically supplies coal and flux material, such as lime.
The coal is delivered from a stockpile to a coal storage/dispensing unit 38 which stores the coal under ambient temperature. Flux 50 is supplied separately to the coal storage/dispensing unit 38. A supply line 40 connects the coal storage/dispensing unit 38 to the ore supply line 36. In the case of the ore being pre-heated, the supply line 40 delivers the coal and flux into the section 46. In each case, however, the solids injection lance 27 has a single inlet that is coupled to the section 46 which, itself, has a single passage for solids and gas. This means that there is, in effect, a single supply of solids and gas to the solids injection lance 27. For simplicity, however, the supply line is shown in
In use, coal and flux at ambient temperature are discharged from the coal storage/dispensing unit 38 entrained in nitrogen carrier gas and transferred via the coal supply line 40 into the first section 48 of the ore supply line 36 so that the ore and the coal are carried together into the lance 27.
The coal storage/dispensing unit 38 can be in the form of a plurality of bins that allow coal to be transferred from standard atmospheric conditions to an environment of a pressurized nitrogen carrier gas. However, for the purposes of the present invention, the coal storage/dispensing assembly 38 can be considered to be a single unit.
The lance-end of the ore supply line 36 is shown in
The lance drilling assembly 60 includes a ball valve 62 with flanges 64 disposed at each end. One flange 64 is connected to the flange 59 of the first section 46 and the other flange 64 is connected to an end flange 78 of a drill housing 76. A drill bar 90 (
Extending from the drill housing 76 is a support frame assembly 66 which comprises a zig-zag shaped mounting arm 68, a drill support rail 70 extending parallel to the drill housing 76 and a brace 72 extending between the mounting arm 68 and the drill support rail 70. A car 74 is mounted to the drill support rail 70 to travel freely along the rail 70. A drill 77 is mounted to the car 74 and has a drill head 75 having an axis of rotation that is coaxial with the section 46 and the solids injection lance 27.
The drill bar 90 includes a hollow cylindrical head 92 extending forwardly of the body 94 and has teeth extending from the head 92 for cutting into a blockage in the solids injection lance 27. The hollow cylindrical head 92 causes drilling of the blockage to occur adjacent an inner wall of a conveying tube in the solids injection lance 27. Drilling in this location dislodges fines from the blockage and will tend to weaken the blockage at an interface with the inner side wall of the solids injection lance 27. Accordingly, it is expected that the blockage will fall away from the side wall and the fines will flow into the direct smelting vessel 11 with a purge gas.
The body 94 includes a connection recess 96 in the end of the drill bar opposite to the head 92. The connection recess 96 has a profile corresponding to the profile of a connection lug 104 on an extension bar 102 (
The retaining holes 100 accommodate the retaining pin 88 so that extension bars 102 and the drill bar 90 can be locked relative to the housing 76 while further extension bars 102 are added or removed as the drill bar 90 is advance or retracted. Specifically, in the course of retracting the drill bar 90, the gas pressure in the section 46 will tend to force the drill bar 90 and extensions 102 out of the section 46. Accordingly, each extension bar 102 is locked by the retaining pin 88 with the gland bar 84 while the drill 77 is connected to the extension bar 102. When that connection is made, the retaining pin 88 is removed and the drill 77 and car 74 controls the extraction of the extension bar 102. The next consecutive extension bar 102 coming through the housing 76 will then be locked by the retaining pin 88 to the gland bar 84 while the drill 77 is further retracted and the exposed extension bar 102 is decoupled from the locked extension bar 102. the process is repeated until all extension bars are removed and the drill bar 90 is retained in the housing 76.
When a blockage occurs in the solids injection lance 27, the only access to the blockage is via the single inlet 29 in the solids injection lance 27. Given that removing the blockage in a timely manner is important, removing upstream sections of the supply line 48, such as section 46 and section 42, to access the inlet end 29 of the lance before removing the blockage and replacing the upstream sections after the blockage is removed would incur a considerable time penalty. For this reason, the blockage is removed without removing sections 42, 46 of the supply line. As a result, gas pressure control upstream of the blockage includes controlling the gas pressure in the section 46 upstream of the inlet end 29. Additionally, access to the blockage for the lance-drilling assembly 60 is limited to the access via the section 46 and the inlet end 29 of the lance.
When a blockage occurs in the solids injection lance 27, the supply of solids materials is cut off from the sections 42 and 46 by the blockage. To be more specific, the blockage prevents the flow of carrier gas which means that solids fall out of entrainment. However, the supply line 48, 42, 46 and the solids injection lance 27 upstream of the blockage remains pressurised at a pressure above the gas pressure in the direct smelting vessel under normal operating conditions.
In one embodiment, the lance drilling assembly 60 is advanced to the blockage, via the section 46 and the portion of the solids injection lance 27 that is upstream of the blockage. The assembly 60 is then operated to remove the blockage and, once the blockage is removed (whereon the carrier gas flows through the supply line 48, 42, 46 and into the vessel with solid materials entrained in the flowing gas), the assembly is retracted free of the section 46.
To be more specific, the lance drilling assembly 60 is then given access to the solids injection lance 27 by opening ball valve 62. The drill bar 90 is advanced along the section 46 by connecting a connection bar 102 to the rear end of the drill bar 90 by fitting the connection lug 104 into the connection recess 96 on the drill bar 90. The retaining pin 88 is removed from the drill bar 90 and placed in the connection hole 98 in the extension bar 102. The extension bar 102 is then advanced into the drill housing 76 up to the point where the retaining pin 88 abuts the gland bar 84. The process of connecting further extension bars 102 and advancing them into the drill housing 76 has the effect of advancing previous extension bars 102 and the drill bar 90 along the section 46 until the drill bar 90 reaches the blockage in the solids injection lance 27. At this point the gland bar 84 is rotated so that it advances within the sleeve section 79 to compact the graphite gland 80 and to form a gas-tight seal in the drill housing 76 about the extension bar 102. The locking bar 82 is then advanced to lock the gland bar 84 in position. The drill 77 is then advanced along the drill support rail 70 so that the drill head 75 engages a connection recess 76 on an extension bar 102 extending outwardly from the drill housing 76.
The drill 77 is then operated so that the drill bar drills through the blockage. Once the blockage is removed and the carrier gas flows through the section 46 and the solids injection lance 27, the drill 77 is retracted along the drill support rail 70 so that extension bars 102 can be retracted from the section 46 and sequentially removed until the drill bar 90 is contained within the drill housing 76. The retaining pin 88 is placed in the retaining hole 100 in the drill bar 90 to retain the drill bar 90 in the drill housing 76. The ball valve 62 is then closed to isolate the lance drilling assembly 60 from the section 46. At this stage, the gas pressure in the housing 76 is still at the elevated purge-gas pressure. Accordingly, the sleeve section 79 includes a bleed valve 81 for venting pressurised gas from the housing 76 in a controlled manner.
In an alternative embodiment, the blockage is removed by first closing valve 52 (shown schematically in
The lance drilling assembly 60 is then advanced along section 46 so that the drill bar 90 reaches the blockage. This procedure is the same as described above for the previous embodiment.
The sections 42 and 46 and the solids injection lance 27 upstream of the blockage are then re-pressurised with inert purge gas, typically nitrogen gas. The pressure in the sections 42 and 46 and the solids injection lance 27 is equivalent to the gas pressure inside the direct smelting vessel plus at least an additional 10 kPa such that when the drill head 92 breaks through the blockage, the gas pressure upstream of the blockage is greater than the gas pressure within the direct smelting vessel plus the hydrostatic pressure of the slag 23 at the outlet end 28 of the lance 27 so that the purge gas flows through the section 46 and the solids injection lance 27 and into the direct smelting vessel. Slag is therefore prevented from flowing back into the solids injection lance once the blockage is removed and during the time to retract the drill bar 90 and extension bars 102 from the solids injection lance 27 and the section 46.
The purge gas is supplied to the section 46 and the solids injection lance 27 by closing the venting valve 58 and supplying the purge gas through the take-off line 56 into the section 46.
Once the blockage is removed and the purge gas flows through the gas section 46 and the solids injection lance 27, the drill 77 is retracted along the drill support rail 70 so that extension bars can be retracted from the section 46 and sequentially removed until the drill bar 90 is contained within the drill housing 76. The retaining pin 88 is placed in the retaining hole 100 in the drill bar 90 to retain the drill bar 90 in the drill housing 76. The ball valve 62 is then closed to isolate the lance drilling assembly 60 from the section 46. At this stage, the gas pressure in the housing 76 is still at the elevated purge-gas pressure. Accordingly, the sleeve section 79 includes a bleed valve 81 for venting pressurised gas from the housing 76 in a controlled manner.
The supply of solid material is recommenced by opening the valve 52 in section 42. The return of this supply enables the supply of purge gas via the take-off line 56 to be stopped.
Whilst a number of specific apparatus and method embodiments have been described, it should be appreciated that the apparatus and method may be embodied in many other forms.
In the claims which follow, and in the preceding description, except where the context requires otherwise due to express language or necessary implication, the word “comprise” and variations such as “comprises” or “comprising” are used in an inclusive sense, i.e. to specify the presence of the stated features but not to preclude the presence or addition of further features in various embodiments of the apparatus and method as disclosed herein.
| Number | Date | Country | Kind |
|---|---|---|---|
| 2015900516 | Feb 2015 | AU | national |
The present application is a continuation of co-pending U.S. patent application Ser. No. 15/551,526, filed Aug. 16, 2017, which is a U.S. National Phase filing of International Application No. PCT/AU2016/050102, filed on Feb. 16, 2016, and claiming priority to Australian Patent Application No. 2015900516 filed Feb. 17, 2015. The present application claims priority to and the benefit of all the above-identified applications, which are all incorporated by reference herein in their entireties.
| Number | Name | Date | Kind |
|---|---|---|---|
| 3516651 | Honda et al. | Jun 1970 | A |
| 3618917 | Fredrikson et al. | Nov 1971 | A |
| 4637590 | Schneider | Jan 1987 | A |
| 4802655 | Bates | Feb 1989 | A |
| 5005807 | Mathews et al. | Apr 1991 | A |
| 5069430 | Woodings et al. | Dec 1991 | A |
| 5169256 | Woodings et al. | Dec 1992 | A |
| 5735647 | Woodings et al. | Apr 1998 | A |
| 6835229 | Brown et al. | Dec 2004 | B2 |
| 7422622 | Leigh | Sep 2008 | B2 |
| 7700035 | Orth et al. | Apr 2010 | B2 |
| 11162733 | Hayton | Nov 2021 | B2 |
| 20030071399 | Leigh | Apr 2003 | A1 |
| 20040031355 | Dry et al. | Feb 2004 | A1 |
| 20050127581 | Leigh | Jun 2005 | A1 |
| 20060124306 | Vail | Jun 2006 | A1 |
| 20070272058 | Orth et al. | Nov 2007 | A1 |
| 20080128128 | Vail et al. | Jun 2008 | A1 |
| 20090057964 | Colavito et al. | Mar 2009 | A1 |
| 20100287992 | Hayton | Nov 2010 | A1 |
| 20110180978 | Goedert et al. | Jul 2011 | A1 |
| 20140239562 | Dry | Aug 2014 | A1 |
| 20140263703 | Waitlevertch et al. | Sep 2014 | A1 |
| 20150284816 | Sakaguchi et al. | Oct 2015 | A1 |
| 20160017458 | Pilote et al. | Jan 2016 | A1 |
| Number | Date | Country |
|---|---|---|
| 2001342508 | Dec 2001 | JP |
| 2002-038867 | Feb 2002 | JP |
| 101277243 | Jun 2013 | KR |
| 1996031627 | Oct 1996 | WO |
| 00022176 | Apr 2000 | WO |
| 2013029092 | Mar 2013 | WO |
| Entry |
|---|
| 9 May 9, 2016—International Search Report and Written Opinion of PCT/AU2016/050102. |
| Number | Date | Country | |
|---|---|---|---|
| 20220042743 A1 | Feb 2022 | US |
| Number | Date | Country | |
|---|---|---|---|
| Parent | 15551526 | US | |
| Child | 17458695 | US |
