The present invention generally relates to the forming of battery components and in particular, but not exclusively, to such apparatus for use in manufacturing cast on straps during the manufacture of batteries. More specifically the invention relates to a lead delivery apparatus for a cast on strap machine arranged to deliver a predetermined volume of molten lead to a mould.
In the manufacture of batteries, particularly for example lead acid batteries, it is known to cast connectors known as “straps” and other formations onto the “lugs” (or “tabs”) of battery plates. For example, straps are formed to provide a connection between a set of plates within a cell of the battery. Straps are generally cast using a “cast on strap machine” in which a mould cavity is filed with molten metal (normally molten lead) before the lugs of a group of battery plates are dipped into the cavity prior to the cooling of the lead. The mould for forming such straps general comprises a plurality of cavities each configured to form a separate strap across a “pack” or “group” comprising a plurality of battery plates. The mould may for example include a series of generally paired cavities spaced along the length of the mould such that each pair of cavities can form a positive and negative strap for a single group of batteries (and with the mould, therefore, forming a plurality of groups spaced along the length in a single process).
Typically, the mould cavities are filled by allowing lead to flow into channels at the sides of the cavities and spill over a weir into the mould. An example of such a moulding apparatus is shown in the Applicant's earlier published European patent EP0630526. In order to ensure a good connection between the lugs and casting, the lead must remain hot until the lugs are in position. However, in order to minimise cycle time in production, the lead must be cooled as quickly as possible once the plates are in position.
It is important that the volume of lead is carefully measured and controlled during strap casting, because excess lead (for example as a result of mould features such as weirs) will have an impact on both the cost and weight of the final battery produced.
The Applicants previously proposed a further battery moulding apparatus in published UK Patent Application GB2507485, which was later improved upon in UK Patent Application GB2536295. In both of these arrangements a reciprocating sliding block is used to provide an accurately measured volume of lead for each cavity of a mould.
Embodiments of the present invention seek to provide a new battery moulding apparatus and provide an alternative to the arrangement proposed in GB2536295 which may, for example, improve the measuring of molten lead delivered into the mould.
According to the first aspect of the present invention there is provided a lead delivery apparatus for a cast on strap machine arranged to deliver a predetermined volume of molten lead to a mould, comprising:
wherein the first needle valve is selectively moveable between a first position and a second position, such that in a first position the reservoir outlet is closed and the flow of molten lead between the reservoir and the volume block is prevented, and in a second position the reservoir outlet is open, such that the flow of molten lead between the reservoir and the volume block is permitted until an equilibrium position has been reached, which defines the predetermined volume; and
wherein the second needle valve is selectively moveable between a first position and a second position, such that in a first position the volume block outlet is closed and the flow of molten lead between the volume block and a mould is prevented, and in a second position the volume block outlet is open, such that the predefined volume of molten lead is permitted to flow between the volume block and the mould.
Advantageously, the present invention provides a lead delivery apparatus which comprises needle valves to control the flow of molten lead from the supply, through the reservoir and volume block, and into the mould. Advantageously, as will become apparent, the profile of the second needle valve provides an improved seal between the volume block and the mould which significantly reduces leaking, and thus reduces the volume of lead wasted.
The molten lead may be at least partly flowable from the reservoir into the volume block, and also from the volume block into the mould, due to gravity.
The first needle valve and the second needle valve may be angled relative to each other.
The first needle valve may be angled at around 20 degrees to the horizontal axis of the housing. Preferably, the second needle valve is substantially perpendicular to the horizontal axis of the housing.
According to a second aspect of the present invention there is provided a lead delivery apparatus for a cast on strap machine arranged to deliver a predetermined volume of molten metal to a mould comprising:
wherein the housing defines a sealed ullage space extending over the molten lead within the reservoir and
the metering cavity of the block is in fluid communication with the ullage space; and
a supply of inert gas in fluid communication with the ullage space.
The features of the lead delivery apparatus of the second aspect of the invention are the same as described above with regards to the first aspect of the invention.
The first and/or second needle valves may each comprise a gas seal, such as a Nitrogen seal, located at the intersection between the first and/or second needle valves and the housing.
The first needle valve may comprise an elongate body and a sealing portion. The sealing portion may have a profile corresponding to the profile of the reservoir outlet. The sealing portion may comprise a flat end positioned flush with an end of the reservoir outlet. Preferably, the end of the reservoir outlet corresponds to the volume block inlet.
The second needle valve preferably comprises an elongate body and a seat engaging portion. The seat engaging portion may comprise a first section having a profile corresponding with the profile of the volume block outlet, such that the first section and the volume block outlet interlock when the second needle valve is in the first position to prevent the flow of molten lead between the volume block and the mould.
The seat engaging portion preferably comprises a second section protruding beyond the volume block outlet when the second needle valve is in the first position. The volume block outlet may be located within a recess on an exterior surface of the volume block. The second section preferably protrudes into said recess when the second needle valve is in the first position.
In some embodiments, the second needle valve may be made of stainless steel or carbon steel. In such embodiments, at least a portion of the second needle valve may comprise a metal nitride coating. For example, at least the first and/or second sections of the seat engaging portion may comprise a metal nitride coating. At least a part of the surface of the through cavity may also comprise a metal nitride coating. The volume block outlet may also comprise a metal nitride coating. The metal nitride coating may be one or more of: Titanium Nitride, Chromium Nitride, Chromium Aluminium Nitride, and Titanium Aluminium Nitride.
It may be an advantage of embodiments of the present invention that the metal nitride coating can help to reduce friction of the surfaces on which the coating is applied, which helps to prevent or at least reduce the amount of molten lead sticking to these surfaces, e.g. the surface of the second needle valve, the surface of the through cavity and/or the volume block outlet.
In another embodiment, the second needle valve may be made of titanium. In such embodiments, a metal nitride coating may not be required. It may be an advantage of embodiments of the present invention that making the second needle valve out of titanium can itself help to reduce friction of the surface of the second needle valve, which in turn helps to prevent or at least reduce the amount of molten lead sticking to the surface of the second needle valve.
The second section may comprise an elongate portion and a substantially tapered portion. The substantially tapered portion may extend along the longitudinal axis of the elongate portion. In an embodiment, the substantially tapered portion may be inverted, and extend internally within the elongate portion. The internally extending tapered portion may form a cavity within the elongate portion.
In an alternative embodiment, the substantially tapered portion may extend externally away from the elongate portion. The externally extending tapered portion may protrude into said recess when the second needle valve is in the first position such that the second section is fully confined within the recess. The elongate portion preferably protrudes beyond the volume block outlet by at least around 0.5 mm to around 1 mm.
The elongate body preferably comprises an upper section furthest from the seat engaging portion having a greatest diameter. The elongate body also preferably comprises a lower section located between the upper section and the seat engaging portion having the same greatest diameter or one or more relatively different diameters, such as relatively smaller diameters. When the second needle valve is in the first position, the part of the through cavity immediately surrounding the upper section may have a diameter which provides a narrow clearance gap between the upper section and said part of the through cavity. The narrow clearance gap may define a metering space.
The second needle valve may be removable and interchangeable with a different second needle valve. The volume block may also be removable and interchangeable with a different volume block. Each different volume block may have a different volume defined by its through cavity. Each different through cavity together with each different second needle valve may define a different predetermined volume of molten lead received from the reservoir via the reservoir outlet.
The predetermined volume of molten lead received from the reservoir via the reservoir outlet may be from 0.06 kg up to 0.25 kg. The predetermined volume of molten lead may be changed by removing the second needle valve and replacing with a different needle valve having a different profile and/or removing the volume block and replacing with a different volume block having a different sized through cavity.
Preferably, the reservoir comprises an inert atmosphere, such as Nitrogen, above the molten lead. Furthermore, the volume block may also comprise an inert atmosphere, such as Nitrogen, above any molten lead in the through cavity. When the second needle valve is in the second position, the volume of inert atmosphere in the through cavity may increase as the volume of molten lead in the through cavity decreases.
The reservoir inlet may be constantly open, such that the molten lead is constantly replenished and maintained at said constant height.
According to a third aspect of the present invention there is provided a lead delivery apparatus for a cast on strap machine arranged to deliver a predetermined volume of molten lead to a mould, comprising:
a needle valve comprising an elongate body and a seat engaging portion; and
a volume block comprising an inlet, an outlet and a through cavity,
wherein the elongate body comprises an upper section furthest from the seat engaging portion having a greatest diameter, and a lower section between the upper section and the seat engaging portion having the same greatest diameter or one or more relatively different (e.g. smaller) diameters; and
wherein when the volume block outlet is closed by the needle valve, the part of the through cavity immediately surrounding the upper section has a diameter which provides a clearance gap between the upper section and said part of the through cavity.
The features of the lead delivery apparatus of the third aspect of the invention are the same as described above with regards to the first and second aspects of the invention.
Advantageously, as will be explained further in the examples, the clearance gap is narrow, and may provide a more accurate measurement of the predefined volume due to an improvement in the tolerance. The clearance gap may also help to prevent the needle valve from sticking, thus reducing the risk that the volume block outlet will not fully open and release the full predefined volume of molten lead. Furthermore, the clearance gap may also help to prevent a vacuum effect within the through cavity, which could otherwise hinder the release of molten lead from the through cavity into the mould.
The clearance gap may define a metering space. The lead delivery apparatus may further comprise a reservoir comprising an inlet and an outlet. The reservoir may be supplied with molten lead during use such that the molten lead in the reservoir may be maintained at a constant height. The molten lead may be flowable from the reservoir to the volume block until the level of molten lead in the volume block is substantially the same as the constant height level of molten lead in the reservoir.
Said level of molten lead in the volume block is preferably located within the clearance gap.
According to a fourth aspect of the present invention there is provided a lead delivery apparatus for a cast on strap machine arranged to deliver a predetermined volume of molten lead to a mould, comprising:
a needle valve comprising an elongate body and a seat engaging portion; and
a volume block comprising an inlet, an outlet and a through cavity,
wherein the seat engaging portion comprises a first section having a profile corresponding with the profile of the volume block outlet, such that the first section and the volume block outlet interlock when the volume block outlet is closed by the needle valve; and a second section protruding beyond the volume block outlet when the volume block outlet is closed by the needle valve.
The features of the lead delivery apparatus of the fourth aspect of the invention are the same as described above with regards to the first, second and third aspects of the invention.
Advantageously, the interlock feature between the needle valve and the volume block outlet may help to provide a tighter seal between the volume block and the mould, compared to known lead delivery apparatuses. Furthermore, the tight fit between these features can help to “squeeze” out any remaining molten lead from the base of the through cavity and into the mould. This can help to ensure the correct predetermined volume is being released into the mould, within the improved tolerances. It may also be an advantage of embodiments of the present invention that the part of the needle valve protruding beyond the volume block outlet can help to prevent tails of molten lead from forming on the protruding part by “flicking” them off and into the mould due to the force of the needle valve closing the volume block outlet.
The seat engaging portion preferably comprises a first tapered portion, a second tapered portion, the first and second tapered portions connected by an elongate portion. The first section may comprise the first tapered portion and a substantial part of the elongate portion. The second section may comprise the second tapered portion and the remaining part of the elongate portion.
The second tapered portion may extend along the longitudinal axis of the elongate portion. The second tapered portion may extend internally into the elongate portion, forming a cavity within the elongate portion. The second tapered portion may alternatively extend externally away from the elongate portion.
The remaining part of the elongate portion preferably protrudes beyond the volume block outlet from around 0.5 mm to around 1 mm.
According to a fifth aspect of the present invention there is provided a cast on strap machine comprising:
a lead delivery apparatus as substantially described herein;
a battery plate positioning device;
a mould comprising a plurality of mould cavities; and
a mould loading apparatus arranged to move the mould between an in use configuration and a configuration in which the mould is external to the cast on strap machine to allow access to the mould.
Whilst the invention has been described above, it extends to any inventive combination set out above, or in the following description or drawings.
The invention may be performed in various ways, and an embodiment thereof will now be described by way of example only, reference being made to the accompanying drawings, in which:
The reservoir 30 comprises an inlet 31 and an outlet 32. The inlet 31 (as seen in the cross-section of
The cover 36 encloses the reservoir 30 but is spaced apart from the lead fill level 34 of the reservoir 30, thus creating an ullage space 35 above the molten lead 33. The ullage space 35 comprises an inert atmosphere, such as Nitrogen, which helps to prevent the build up of oxides (which may otherwise form on the surface of the lead and accumulate on parts of the lead delivery apparatus).
The reservoir outlet 32 is located in a lower corner of the reservoir 30 and comprises a bore which fluidly connects the reservoir 30 to the volume block 20. As will be described in more detail below, the reservoir outlet 32 is selectively openable and closable by the first needle valve 40.
The volume block 20 comprises an inlet 22, an outlet 24 and a through cavity 26. The inlet 22 is in fluid communication with the reservoir outlet 32 via the bore, such that the end of the bore closest to the volume block 20 corresponds to the volume block inlet 22.
The exterior surface of the volume block 20 comprises a recess 28. The outlet 24 is located within the recess 28, such that it is set back from the exterior surface of the volume block 20. As will be described in more detail below, the volume block outlet 24 is selectively openable and closable by the second needle valve 50.
The through cavity 26 fluidly connects the volume block inlet 22 and the volume block outlet 24. The through cavity 26 also defines a predetermined volume of molten lead 33 to be received from the reservoir 30 via the reservoir outlet 32. The middle portion of the through cavity 26 has the largest diameter, and has a substantially circular cross-section (when viewed from above).
As will be described in more detail below, the predetermined volume of molten lead can be from 0.06 kg up to 0.25 kg. The second needle valve 50 is interchangeable with needle valves having different profiles (as can be seen, for example, by comparing
The ullage space 35 above molten lead 33 in reservoir 30 extends into the volume block 20. In use, the molten lead 25 in the through cavity 26 is filled to a pre-determined level (which is where the lead level in the both the through chamber and the reservoir are in equilibrium). The Nitrogen in ullage space 35 is then drawn into the through cavity 26 and accommodates the area 27 above said equilibrium level.
At the intersection between the housing 19 and the first needle valve 40, there is a Nitrogen seal 41. This helps to prevent the Nitrogen within the ullage space 35 from escaping and potentially being replaced with Oxygen rich air. It is a known problem that Oxygen can cause the lead to oxidise, thus causing oxides to form and build up within the reservoir. Over time, the build up of oxides can cause a reduction in the available volume within the reservoir for filling with molten lead.
The first needle valve 40 extends through the housing 19 and into the reservoir 30 at an angle of around 20 degrees to the horizontal axis of the housing 19. Advantageously, having the first needle valve at an angle to the horizontal axis of the housing, helps to keep the Nitrogen seal away from the molten lead in the reservoir. Furthermore, a vertical first needle valve would require a much larger volume block and through cavity, which would take up more space.
The first needle valve 40 comprises an elongate body 42 and a sealing portion 44. The sealing portion 44 has a profile corresponding to the profile of the bore of the reservoir outlet 32, that is the sealing portion 44 is partially tapered. The sealing portion 44 also comprises a flat end, which in use when the first needle valve 40 closes the reservoir outlet 32, is positioned flush with an end of the bore of the reservoir outlet 32.
In use, the first needle valve 40 is moveable between a first or extended position (shown in
The second needle valve 50 extends through the housing 19 and the volume block 20, and is substantially perpendicular to the horizontal axis of the housing 19. The first needle valve 40 and the second needle valve 50 are angled relative to each other, such that the volume block inlet 22 is located below the reservoir outlet 32.
At the intersection between the housing 19 and the second needle valve 50, there is a Nitrogen seal 51. This helps to prevent the Nitrogen within the area 27 from escaping and potentially being replaced with Oxygen, thus having the same consequences as detailed above. In this case, the build up of oxides will cause a reduction in the available volume within the through cavity, thus the through cavity will not be able to accommodate the predetermined volume of molten lead required for filling a particular mould. During the cast on process, the only time that Oxygen comes into contact with the molten lead is after it has been released into the mould.
The second needle valve 50 comprises a seat engaging portion 53 and an elongate body 52. The seat engaging portion 53 comprises a first section 54 and a second section 55. The first section 54 has a profile corresponding with the profile of the volume block outlet 24, that is there is a first tapered portion 57, followed by a substantial part of an elongate portion 59 (see
In use, when the second needle valve 50 closes the outlet 24, the elongate portion 59 of the second section 55 protrudes by around 1 mm beyond the volume block outlet 24 and into the recess 28. In use, the tip of the second tapered portion 58 is located in line with the exterior surface of the volume block 20, as shown in
The elongate body 52 comprises an upper section 52a which is located furthest from the seat engaging portion 53. The greatest diameter of the second needle valve 50 is along the upper section 52a. The elongate body 52 also comprises a lower section 52b which is located between the upper section 52a and the seat engaging portion 53. The lower section 52b has the same diameter as the upper section 52a in this embodiment, but in other embodiments, such as that shown in
When the second needle valve 50 closes the outlet 24, the part of the through cavity 26 immediately surrounding the upper section 52a of the second needle valve 50 has a diameter only slightly greater than the diameter of the upper section 52a. This creates a narrow clearance gap 56 between the upper section 52a and the through cavity 26. Such a clearance gap 56 defines a metering space, which advantageously improves the tolerance of the predetermined volume. For example, by providing the clearance gap in line with the fill level of the reservoir, the equilibrium level will be located within the region of the clearance gap, thus any changes in volume of the reservoir will only affect the predetermined volume in the volume block by an insignificant amount, thus improving the accuracy of the measured predetermined volume.
In use, the second needle valve 50 is moveable between a first or extended position (shown in
The first needle valve 40 is then moved into its second/retracted position, such that molten lead 33 is allowed to flow between the reservoir 30 and the volume block 20. Since the reservoir outlet 32 is located above the volume block inlet 22, the molten lead 33 flows from the reservoir 30 into the volume block 20, (and also from the volume block 20 into the mould) at least partly due to gravity.
The molten lead 33 flows into the through cavity 26, and fills up the through cavity 26 until the levels reach equilibrium and thus the predetermined volume is reached. As the molten lead 33 is flowing out of the reservoir 30 and into the through cavity 26, the feedpipe 12 continually replenishes the molten lead 33 within the reservoir, thus maintaining the molten lead 33 at the lead fill level 34 at all times.
The predetermined volume corresponds with the lead fill level 34. Therefore, the molten lead 33 flows from the reservoir 30 to the volume block 20 until the level of molten lead level 25 in the volume block 20 is substantially the same as the lead fill level 34 in the reservoir 30. The level 25 in the volume block 20 is located within the clearance gap 56. Advantageously, this may improve the tolerance of the volume measurements because if the lead fill level 34 of the molten lead 33 in the reservoir 30 were to increase, the level of molten lead 25 in the volume block will also increase. However, the volume of molten lead required to increase the lead fill level 34 in the reservoir 30 is much greater then the volume of molten lead required to increase the level 25 in the volume block by the same amount. Therefore, any changes in the volume of the reservoir 30 will only affect the predetermined volume in the volume block 20 by an insignificant amount (such as a difference of only tenths of a gram).
It may be an advantage of embodiments of the present invention that there is no seal provided between the reservoir and the volume block. It is difficult to provide a lead seal in such a location, however the inventors of the present invention have taken full advantage of these difficulties and designed the lead delivery apparatus to function without a seal. For example, not providing such a seal allows the balancing of the lead levels in the reservoir and the volume block, which are carefully defined such that a predetermined volume of molten lead is provided to the moulds. Furthermore, a lack of sealing allows Nitrogen to be drawn into at the top of the through cavity from the reservoir to fill the ullage space above the molten lead. Not only does this help to prevent the build-up of oxides, but drawing in Nitrogen at the top of the through cavity can also help to push the molten lead out of the through cavity and into the mould.
As the volume of molten lead 25 in the through cavity 26 decreases, the volume of the area 27 increases. Therefore, as the molten lead drains out of the volume block 20, it is replaced with an inert atmosphere, such as Nitrogen which is drawn in to the top of the through cavity via a gas inlet (not shown) provided at the rear of the housing 19 and/or from the ullage space 35 above the reservoir 30. Advantageously, drawing Nitrogen in at the top of the through cavity can help to push the molten lead out of the through cavity and into the mould. This arrangement helps to avoid any vacuum effect which may hinder the release of the lead from within the through cavity.
A further advantage of embodiments of the present invention is that the narrow gap helps to prevent the second needle valve seizing or sticking within the through cavity.
The volume block outlet 24 and the seat engaging portion 53 fit tightly together due to their corresponding profiles. Therefore, as the second needle valve 50 is closes, any remaining molten lead within the through cavity 26 is essentially “squeezed” out. Furthermore, the profile of the second section 55 of the seat engaging portion 53 (the elongate portion and the tapered portion) protruding beyond the volume block outlet 24 and into the recess 28 causes the remaining molten lead to be forcefully flicked off the end of the second section. This helps to prevent a “tail” of molten lead hanging from the second section. Advantageously, the profile of the seat engaging portion 53 helps to minimise the amount of molten lead remaining within the through cavity 26, thus helping to increase the accuracy of the volume of lead dispensed into the mould.
Since the second section 55 of the seat engaging portion 53 does not extend beyond the confines of the recess 28, the recess 28 acts as a shroud for the tapered portion. This can help to not only protect the end of the needle valve, but also help to ensure the molten lead is flicked off into the mould.
Making the second needle valve out of titanium helps to reduce the surface friction of the second needle valve. Alternatively, if the second needle valve is made from stainless steel or carbon steel, then a metal nitride coating can be applied to the surface of the second needle valve, in particular the second section of the seat engaging portion, to reduce the surface friction. The ability to flick the molten lead off into a mould is greatly improved as the amount of friction provided by the surface of the second needle valve is reduced.
The second needle valve 150 comprises a seat engaging portion 153 and an elongate body 152. Similar to the previous embodiment, the seat engaging portion 153 comprises a first section 154 and a second section 155 which are exactly the same as described above. The first section 154 comprises a first tapered portion 157 and a substantial part of an elongate portion 159, and the second section 155 comprises a second tapered portion 158 and the remaining part of the elongate portion 159.
The elongate body 152 comprises an upper section 152a which is located furthest from the seat engaging portion 153. As before, the greatest diameter of the second needle valve 150 is along the upper section 152a. The elongate body 152 also comprises a lower section 152b which is located between the upper section 152a and the seat engaging portion 153. In this embodiment, the lower section 152b has a single smaller diameter than the upper section 152a, giving the second needle valve 150 a narrower profile. Having a narrower profile creates more available space in the through cavity 126 to fill with molten lead from the reservoir. This increases the predetermined volume accommodated in the through cavity 126, and subsequently released into the mould. This is particularly beneficial if, for example, the cast on strap machine was required to process larger batteries, because larger straps would need to be cast on which would require larger moulds and a larger predetermined volume. As will be described in more detail in
A further advantage of embodiments of the present invention may be that the second valve needle is removable and interchangeable, because this allows the apparatus to process different sized batteries without having to substantially change the set-up of the machine. It is a very quick and simple procedure to remove one second needle valve and replace it with another which meets the requirements of the batteries to be processed.
The second needle valve 250 comprises a seat engaging portion 253 and an elongate body 252. The seat engaging portion 253 comprises a first section 254 and a second section 255. The first section 254 comprises a first tapered portion 257 and a substantial part of an elongate portion 259, and the second section 255 comprises a second tapered portion 258 and the remaining part of the elongate portion 259.
In contrast to the embodiment shown
In use, the second needle valve 250 works in exactly the same way as second needle valves 50 and 150. Advantageously however, the profile of the second section 255 has been found to further reduce the amount of molten lead sticking to the surface of the second section in use, which may be because there is a smaller surface area onto which the molten lead could potentially stick. Such a profile may help to further prevent “tails” of molten lead hanging from the second section.
As mentioned above, if a different pre-determined volume is required, for example for moulding different sized battery straps, this can be achieved by switching the second needle valve for one having a different profile, and/or switching the volume block for one having a different through cavity dimensions.
Typically, interchanging the volume block can provide a change of around 0.1 kg in the predetermined volume of the through cavity; and interchanging the second needle valve can provide a change of around 0.06 kg in the predetermined volume of the through cavity. Therefore, switching the volume block provides a course adjustment of the volume, whereas switching the second needle valve provides a finer adjustment of the volume.
It may be an advantage of embodiments of the present invention that having the option of interchanging the second needle valve and/or the volume block will provide the user with a much greater range of predetermined volumes to select from, thus the lead delivery apparatus is able to mould and cast on straps for a wide range of battery sizes.
Although the invention has been described above with reference to an exemplary embodiment, it will be appreciated that various changes or modifications may be made without departing from the scope of the invention as defined in the appended claims. For example, whilst embodiments have been described as having a single reservoir associated with a single volume block it will be appreciated by the skilled person that the invention is not limited to such an arrangement, for example a single reservoir may be provided with more than one outlet to supply a plurality of volume blocks.
Number | Date | Country | Kind |
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1713271.3 | Aug 2017 | GB | national |
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5146974 | Mayer et al. | Sep 1992 | A |
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20140116637 | Barge et al. | May 2014 | A1 |
Number | Date | Country |
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202752586 | Feb 2013 | CN |
106216641 | Dec 2016 | CN |
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2495516 | Jun 1982 | FR |
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Search Report for Great Britain Application No. GB1713271.3, dated Feb. 6, 2018. |
Search Report for Great Britain Application No. GB1713271.3, dated May 8, 2018. |
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Number | Date | Country | |
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20190084037 A1 | Mar 2019 | US |