This invention pertains to two fields of scientific endeavor: electrochemistry, and nuclear physics, and several fields of technical endeavor, including but not limited to nuclear fusion, nuclear transmutation, heat energy generation, electrical energy generation, manufacture of metal ores, and stabilization/transmutation of radioactive wastes.
Low Energy Nuclear Reactions (LENR), also referred to as ‘cold fusion’ were reported in 1989 by Stanley Pons and Martin Fleischman (4) who had conducted electrolysis experiments of heavy water at the surface of a palladium electrode. They reported that their experiments produced excess heat, and nuclear reaction byproducts. These claims were met with skepticism in the scientific community after initial attempts to replicate their experiments either failed, or resulted in sporadic confirmation. More important to peer reviewers was the perception that there was no understandable means to overcome the coulombic repulsion of the fusing atomic nuclei.
Nevertheless, when one looks carefully at the experimental record, it becomes apparent that these are not flukes or erroneous experimental results. Excess heat is indeed produced in significant quantities in many, but not all, of these experiments. It has become evident that the post-experiment electrodes demonstrate exotic isotope changes that bear little resemblance to either natural abundance ratios or contaminants (Miley ref 5). Indeed, Szumski (1) has shown that it is possible to predict nuclear transmutations with the precision of physics using the LANP method.
One of the commonly cited shortcomings of the LENR experiments is that sometimes there is no excess heat production at the experiment's level of significance, and the experiment is considered a failure. LANP shows that both exothermal and endothermal reactions occur in these electrolysis experiments, and that excess heat occurs when exothermal processes predominate. Thus, the null result of producing no excess heat merely encompasses one of the valid LANP outcomes, as do experiments that produce different excess heat amounts.
LENR and Cold Fusion experiments are being conducted worldwide by experimentalists, and persons seeking to develop commercial applications of the technology. They observe anomalous excess heat by the interaction of hydrogen or deuterium on electrodes made of palladium, nickel, and platinum, however, this work is still largely dismissed because, although a variety of experimental designs do produce excess heat and nuclear transmutations, there is no theory that explains the underlying process.
The arguments against the types of nuclear processes that have been claimed include the following. The repulsive forces between positively charged reactants, specifically deuterons, are large, requiring solar core like temperatures and pressures to bring deuterium nuclei close enough to undergo fusion. Cold fusion was unlikely because the spacing between deuterium or hydrogen nuclei in a metal lattice is thought to be greater than that in the condensed gas state. Secondly, expected reaction products are not present. In particular, the experiments sometimes produce 4He, but without the gamma radiation in the known two step reaction:
4He*→4He+γ+24 MeV
In fact, experiments have shown that there are no radioactive products formed in LENR devices, and no gamma radiation.
Several other issues that cloud the LENR landscape are summarized as follows:
There have been many attempts to explain LENR experiments using various types of theoretical frameworks. These invariably fail to explain more than one or two of the observed effects, and for this reason theory is the single weakest element of LENR claims.
In light of these problems, there is a need for an internally consistent theoretical framework of the LENR process, as well as means to predict products, increase preferred reactions such as: increasing heat production, increasing production of desired isotopes, or increasing the consumption of unstable waste isotopes.
In one aspect, the invention comprises a method of loading hydrogen in any of its isotopic forms into a metal hydride lattice.
In another aspect, the invention comprises a method of loading hydrogen into a metal hydride lattice, wherein the resulting concentration of hydrogen within said metal hydride lattice is greater than could be loaded into a metal hydride lattice by naturally occurring metal hydride formation.
In another aspect, the invention comprises a method of stimulating nuclear transmutation within a metal hydride lattice which has a concentration of hydrogen within said metal hydride lattice that is greater that could be loaded into a metal hydride lattice by naturally occurring metal hydride formation, by applying an electric current to said lattice.
In another aspect, the invention comprises a method of generating heat energy by applying an electric current to a metal hydride lattice which has a concentration of hydrogen within said metal hydride lattice that is greater that could be loaded into a metal hydride lattice by naturally occurring metal hydride formation, wherein said heat energy is produced in excess of the electrical energy applied to said metal hydride lattice.
In another aspect, the invention comprises a method of decreasing the concentration of specific isotopes within a metal hydride lattice which has a concentration of hydrogen within said metal hydride lattice that is greater that could be loaded into a metal hydride lattice by naturally occurring metal hydride formation, wherein said decrease in concentration of specific isotopes is effected by applying an electric current to said metal hydride lattice.
In another aspect, the invention comprises a method of increasing the concentration of specific isotopes within a metal hydride lattice which has a concentration of hydrogen within said metal hydride lattice that is greater that could be loaded into a metal hydride lattice by naturally occurring metal hydride formation, wherein said increase in concentration of specific isotopes is produced by applying an electric current to said metal hydride lattice.
In another aspect, the invention comprises a method of generating heat energy by applying an electric current to a metal hydride lattice which has a concentration of hydrogen within said metal hydride lattice that is greater that could be loaded into a metal hydride lattice by naturally occurring metal hydride formation, wherein said heat energy is produced in excess of the electrical energy applied to said metal hydride lattice and wherein said metal hydride lattice has been doped with nuclear isotopes that enhance exothermic reactions.
In another aspect, the invention comprises a method of decreasing the concentration of specific isotopes within a metal hydride lattice which has a concentration of hydrogen within said metal hydride lattice that is greater that could be loaded into a metal hydride lattice by naturally occurring metal hydride formation, wherein said decrease in concentration of specific isotopes is effected by applying an electric current to said metal hydride lattice and wherein said metal hydride lattice has been doped with nuclear isotopes that enhance said specific isotope reductions.
In another aspect, the invention comprises a method of increasing the concentration of specific isotopes within a metal hydride lattice which has a concentration of hydrogen within said metal hydride lattice that is greater that could be loaded into a metal hydride lattice by naturally occurring metal hydride formation, wherein said increase in concentration of specific isotopes is produced by applying an electric current to said metal hydride lattice and wherein said metal hydride lattice has been doped with nuclear isotopes that enhance said specific isotope production.
In another aspect, the invention comprises a metal hydride lattice wherein the concentration of hydrogen within said metal hydride lattice is greater that could be loaded into a metal hydride lattice by naturally occurring metal hydride formation.
In another aspect, the invention comprises a metal hydride lattice wherein the concentration of hydrogen within said metal hydride lattice is greater that could be loaded into a metal hydride lattice by naturally occurring metal hydride formation and wherein said lattice has been doped with nuclear isotopes which enhance exothermic reactions when an electrical current is applied to said lattice.
In another aspect, the invention comprises a metal hydride lattice wherein the concentration of hydrogen within said metal hydride lattice is greater that could be loaded into a metal hydride lattice by naturally occurring metal hydride formation and wherein said lattice has been doped with nuclear isotopes which enhance specific isotope production when an electrical current is applied to said metal hydride lattice.
In another aspect, the invention comprises a metal hydride lattice wherein the concentration of hydrogen within said metal hydride lattice is greater that could be loaded into a metal hydride lattice by naturally occurring metal hydride formation and wherein said lattice has been doped with nuclear isotopes which enhance specific isotope reduction when an electrical current is applied to said metal hydride lattice.
with the LANP decay path. The Least Action decay is to 68167Er with subsequent alpha decay to 66163Dy. However, the decay to 66163Dy occurs as a single step without any radioactive intermediates, and without any of the normal half-life decays.
In this application, the following definitions will be utilized:
The following references have been attached as appendices to this application and are herein incorporated by reference into this application:
Least Action Nuclear Process (LANP) is a process which accomplishes both fusion and fission reactions at solar core temperatures. Nevertheless, its apparent operating temperature is generally less than 70° C. (343° K) on the scientifically accepted thermodynamic temperature scale. The fundamental difference between a device that uses the LANP, and others that have been patented to date, lies in the process that the device is designed to accomplish. Their devices are designed for low temperature nuclear reactions which take place at less than 373° K, and are claimed to produce fusion at that temperature. In other words they are relying on magic to accomplish what is impossible given the present understanding of physics and chemistry.
The LANP device on the other hand operates on principles derived from a new non-equilibrium theory of heat that includes two temperatures, both of which exist on the same Kelvin temperature scale. In particular, Szumski (1) has developed a far-from-equilibrium blackbody radiation theory having two temperature scales. The first is the thermodynamic temperature, Tm, which is measured by devices like thermometers and their digital descendants. Thermometers measure a derivative that we call the thermodynamic temperature, and which is most clearly understood in terms of the equilibrium blackbody theory of Planck (2). The equilibrium condition that the thermometer measures is one where the amount of heat absorption in the object being measured, is exactly equal to the emissivity, a measure of the total heat being emitted by that object. At equilibrium, the absorbed and emitted heat at the boundary of the object have identical rates(derivatives)(Planck (3)), and by assigning a temperature scale to quantify that derivative over a wide range of natural conditions science has made it possible for us to talk about the heat derivative in simple terms such as degrees Celsius, degrees Fahrenheit, and degrees Kelvin, rather than joules/sq m-sec.
Szumski's theory of heat includes a second temperature scale, which he calls the radiation temperature, denoted by the symbol TR. It is also a derivative, and can be measured on the same scales as the thermodynamic temperature, but it is fundamentally different in what this derivative is measuring. It is the rate of energy flux across the boundary of a fundamental particle, and in particular, a system where that fundamental particle is sharing electromagnetic energy with another identical fundamental particles in a process described as resonant and adiabatic.
A covalent bond is such a system. Each covalent electron alternately absorbs and emits a single quanta of energy that is shared between them in an equilibrium state that is undiminished in time. This is a true reversible process. There is no recoil or other loss of energy to ‘waste’ heat of motion. In the world of physics we say that the covalent process is adiabatic. The rate of heat exchange across the boundary of either electron can still be measured in Joules/sq m-sec or degrees Kelvin. The absolute value of any one energy exchange is infinitesimal, but because the exchange takes place at the speed of light, and billions or trillions of times per second, the aggregate heat exchange across the electrons boundary (per second) tends to be large.
In the current case the exchange of energy is most likely occurring between electrons at the beginning of the LANP process when the exchanged energy is small. However, as the process proceeds, the energy exchanges become great enough that they occur between excited nuclei in a resonant process called Mossbauer resonance or the Mossbauer effect. In effect electromagnetic energy in the gamma intensity range resonates between two nuclei, without recoil or any energy loss. This is a reversible adiabatic process, as is the rest of the LANP.
The electrolysis device which is in its simplest form is a container of heavy water (or plain H2O water) a cathode made of one of the metals (palladium, platinum, nickel, uranium, lanthanum, praseodymium, cerium, titanium, zirconium, vanadium, tantalum, hafnium and thorium). an anode, and an electrical source. The device is loaded by running it for several weeks or even months, all the time renewing the water or heavy water that is lost.
This process is called Least Action Nuclear Process (LANP) rather than the current acronym LENR because the process is fundamentally different than that envisioned by researchers working in this field over the past 24 years. In particular, those researchers believed that the process that they were studying occurred at low (laboratory) temperatures because the temperature of their electrolysis apparatus was always close to 50-60 degrees Celsius (323-333° K). This invention places the actual temperature of the nuclear reactions that are occurring at solar core temperatures, about 107° K. However, this temperature, although measured on the same scale as the thermodynamic temperature, is contained internally in the cathode's metal lattice as Mausbauer Resonance between identical nuclei. In this way the real temperature of the process is masked from detection. The process that is actually occurring follows the Principle of Least Action, and for this reason, the process is called Least Action Nuclear Process.
The theory behind the LANP process begins with a new theory of heat that allows non-equilibrium and far-from-equilibrium heat processes, the latter being operative in the LANP device. The theory in-so-far as it is currently known is presented in reference (6) which develops a far-from-equilibrium blackbody equation that differs from Plank's steady state formula in important respects. First the equation reveals a second temperature scale that I have called the radiation temperature, TR. The theory shows how in the LANP process, these two temperatures are separated in a far-from-equilibrium state where the thermodynamic temperature remains at the 50-60° C. thermodynamic temperature while the radiation temperature rises during the loading phase of the experiment to solar core temperatures where nuclear fusion and fission reactions are known to occur.
What makes the LANP process so special are first, the way that the nuclear reaction occurs at solar core temperatures, and even nucleosynthesis temperatures of supernovae; and secondly in the unique process by which certain nuclear reactions are selected to go forward, while all others are eliminated. The Principle of Least Action lies at the heart of this selection process. That Principle characterizes only thermodynamically reversible processes, or those that can, by adjustment of boundary conditions, be approximated as being thermodynamically reversible. The condition of reversibility requires that all of the systems energy, and most importantly, any heat of molecular motion, is available to the reaction. Under this condition, reactions that can occur do occur. The Principle of Least Action selects from all of the possible reactions that might occur in the system under consideration, the one that creates the least energy change. In this way, and at every step in the LANP process, there is one, and only one, next nuclear reaction that the overall process is evolving toward.
A peculiarity in the reaction that actually occurs is found in the way that the Principle of Least Action selects only for stable isotopes, i.e. those in their lowest energy state. The invention bypasses intermediate steps involving radioactive decay, and half life time delays. In this way, the LANP process eliminates the messy radiation signature of other nuclear processes, and makes it the ‘green alternative’ to other modes of nuclear energy production.
The LANP process produces excess heat which can be harvested and employed in human endeavors. It also mediates a wide range of predictable nuclear transmutation products that can be selected for, and ‘mined’ from the LANP residues. It is also a candidate process for the disposal of radioactive wastes. These and other LANP uses are itemized in the patent's claims.
There are five noteworthy advantageous effects of LANP, including several distinct advantages over other nuclear processes.
First, LANP is a nuclear process that, in theory, can provide an inexhaustible supply of energy for human purposes. The excess heat it produces (when it is designed to produce heat) can be converted into other electrical and chemical energy forms. It appears theoretically possible that there may even be sub-processes that consume excess heat.
Second, LANP is safe and environmentally friendly. It operates at an apparent temperature that approximates that of other industrial processes. There are no excessively high temperatures, no hot waste products, no need for cooling towers, and no need for water or air pollution controls, at least none that we are aware of at this time. The electrode recycle process may not be as benign.
Third, the LANP nuclear process is clean. It produces no radioactive waste products, and therefore eliminates the nuclear waste disposal problem. In fact, it is possible to use this process to neutralize existing radioactive wastes while producing heat for other industrial, agricultural, and domestic needs.
Fourth, LANP waste products are useful raw materials for industry. These include halogens and noble gasses, and a broad range of metals including the rare earths, and precious metals.
Fifth, the process can potentially provide extraordinary insights into new processes in physics, chemistry and biology, both for new technologies, and also new avenues for scientific inquiry. LANR has the potential to change the earth in very fundamental ways that can be good or detrimental to mankind and his society, and the ecosystem that we call home. It needs to be used responsibly.
We describe processes and materials for use with LENR, CANR, or cold fusion devices, or devices specifically designed for the LANP process. LENR, CANR, and cold fusion devices are thought to be low energy devices that operate at less than the boiling temperature of water. The LANP device achieves reactions at stellar temperatures.
Devices of either type consist of a vessel containing a medium (for example water or heavy water), an anode, a cathode, and an electrical source that activates an electrolysis process within the vessel. The cathode can take any of the forms described in the referenced patents, or others that are not yet invented. The cathode may be sophisticated in terms of its layered composition and shape, but must have as its active component a metal that forms hydrides, or other similarly acting material, possibly organic, that acts to absorb hydrogen nuclei or deuterons and convert their kinetic energy to stored radiation energy. Several such devices that use metal hydrides are described in the referenced patent searches. The rest of the discussion in this application will focus on metal hydrides as a good prototype for understanding LANP
The electrolytic cell housing consists of a non-conductive housing, and can have inlet and outlet ports so that flow through operation can be achieved. Conductive grids are interconnected within the housing.
The electrolysis vessel is (energy) loaded by running it for several weeks, or even months, all the time renewing the water or heavy water that is lost. Following this loading period, the nuclear process ignites fusion and fission reactions, and excess heat production/loss begins, lasting sometimes for weeks. Devices of this type are described in the US patents referenced in this application.
The Least Action Nuclear Process, LANP process is not difficult to understand. The process begins with the uptake of deuterium or hydrogen by a host lattice, generally metal, and most commonly palladium, platinum, or nickel, and less commonly uranium, lanthanum, praseodymium, cerium, titanium, zirconium, vanadium, tantalum, hafnium and thorium. The product of this uptake process is called a metal hydride. There is ample theory and experimental observation of metal hydrides (7) to establish that palladium, platinum, nickel and several other transition and rare earth metals possess the ability to uptake and store deuterium or hydrogen. These three are the most widely used in LENR experiments today. The process that underlies the uptake is known to be a reversible one, but its mechanisms are largely unknown. It is presumed that the captured deuterium or hydrogen nuclei migrate into the metal lattice, and occupy spaces between the face centered cubic host metal atoms. The hydrogen can be removed by heating the metal hydride.
The theoretical foundations lie in the reversible uptake of deuterons or hydrogen nuclei which are initially in random, temperature dependent motion near the surface of a metal cathode. The energy possessed by an individual nuclei is its kinetic energy given by E=m·v2/2 where m is the nuclei mass, and v is the temperature dependent, average velocity of the nucleus in the electrolysis chamber. The nucleus' motion ceases at the instant of uptake (1), and we say that it has been ‘quieted’. This energy is conserved in the uptake process in accordance with the First Law of Thermodynamics, and becomes a part of the metal lattices total energy. In this way, heat of random motion is harvested by the metal lattice and stored until the moment of nuclear ignition. The higher the temperature of the electrolysis reactor, the more quickly the ignition temperature is achieved.
The first step in LANP is loading the electrode according to the theory discussed in the previous step. An electrical current is applied across the electrolysis devise. The device is loaded by running it for several weeks or even months, all the time renewing the water or heavy water that is lost. As the electrode is loaded, there occurs a separation between the thermodynamic temperature of the device, and the internal radiation temperature of the metal lattice in the cathode. The thermodynamic temperature remains essentially constant at about Tm=60° C., while the radiation temperature increases in quantum amounts (equal to the harvested thermal motion of each deuteron), always storing the energy increase in a thermodynamically reversible way first as excited electronic states, then as excited nuclear states. The excited nuclear state energy storage is what eventually participates in the processes' nuclear reactions. It is stored as resonant exchange of gamma intensity, electromagnetic energy between two identical nuclei in accordance with the Mossbauer effects. This is a reversible process wherein no energy is lost to waste heat, and the exchange continues, unchanged, until the moment that it is needed to ignite the LANP process. I describe this kind of reversible energy exchange for the case of a covalent bond in Szumski (6), and for the case of an LANP device in Szumski (1). The first step of a two step absorption and emission process occurs adiabatically, without recourse to irreversibility, and energy loss to heat of motion.
Once TR reaches the LANP ignition temperature, around 107° K., nuclear reactions commence. In the case where exothermal processes predominate, excess heat is evolved. If on the other hand, endothermic nuclear processes predominate no excess heat production occurs.
Although within the context of the reversible reaction, any reaction that can occur is a candidate for what will happen next, it is the Principle of Least Action that selects one reaction among all of the candidates. The LANP process uses simple arithmetic calculations to simulate the Principle of Least Action's selection process. This is actually a least energy calculation. One first calculates the mass of the nuclear reactants in atomic mass units (amu). Then one calculates the mass of the stable, final reaction products. The difference between these, Δm=mreac tan ts|mproducts, is the mass change resulting from the reaction, and E=Δmc2 can be used to calculate the energy consumed(−) or produced(+) by the overall nuclear process. In practice, it is entirely proper to merely use the mass change, Δm as the energy change for determining which reaction actually occurs.
Consider the reaction where:
In words: nickel-62 fusion reacts with 1 deuteron to create copper-64 which in turn decays along two pathways. 61% of the copper-64 decays to nickel-64. 39% decays to zinc-64. The changes in atomic mass units is shown in the right hand column (for example the atomic mass of nickel-62 (61.928345 amu) plus the atomic mass of a deuteron (2.014101 amu) is (63.942446 amu), minus the atomic mass of the final stable product nickel-64 (63.927966 amu) yielding a mass change of 0.01448 amu. We also note that zinc-64 has a smaller mass change, but is absent from the isotope inventory in Miley's post-experiment electrode. When this happens, we look to see what other lower energy change reactions are occurring. We find that zinc-64 undergoing fission to two phosphorus-32's yields a lower mass change of 0.00536 amu and that this unstable product decays by beta-minus decay to sulpher-32 which is one of the stable isotopes found in Miley's post-experiment electrode, and also the minimum energy condition for this reaction. This example is a little complicated, but illustrates the technical steps in the method that is required to select final isotopes in accordance with the Principle of Least Action. The tables attached to Szumski (1) provide this same information for 210 nuclear reactions occurring in Miley's nickel electrode. These tables are reproduced below.
29
60Cu
28
60Ni
30
62Zn
28
62Ni
31
64Ga
30
64Zn
32
66Ge
30
66Zn
33
68As
30
68Zn
34
70Se
35
72Br ↑79 sec
32
72Ge
36
74Kr ↑11 min
34
74Se absent (2)1737Cl ↑
37
76Rb
34
76Se 3272Ge
38
78Sr
36
78Kr ↑
29
62Cu
28
62Ni
30
64Zn
30
64Zn
31
66Ga
30
66Zn
32
68Ge
30
68Zn
33
70As
34
72Se
32
72Ge
35
74Br ↑25 min
34
74Se absent (2)1737Cl ↑
36
76Kr ↑76 hr
34
76Se
37
78Rb
36
78Kr ↑
38
80Sr
36
80Kr ↑
29
63Cu
29
63Cu
30
65Zn
29
65Cu
31
67Ga
30
67Zn
32
69Ge
31
69Ga
33
71As
33
71Ga
34
73Se
32
73Ge
35
75Br ↑96 min
33
75As
36
77Kr ↑74 min
33
77Se
37
79Rb
35
79Br ↑
32
81Sr
35
81Br ↑
29
64Cu (2)1532P
28
64Ni 3064Zn absent(note 1) 2864Ni (2)1632S (4)816O Example
30
66Zn
30
66Zn
31
68Ge
30
68Zn
17
35Cl ↑
33
72As
31
72Ge
17
37Cl ↑
35
76Br ↑16 hrs
34
76Se
36
78Kr ↑
36
78Kr ↑
37
80Rb
36
80Kr ↑
38
84Sr
36
82Kr
29
66Cu
30
66Zn
30
68Zn
30
68Zn
31
70Ga
32
72Ge
34
76Se
35
78Br ↑6 min
36
80Kr ↑stable
36
80Kr ↑
3
80Rb
36
82Kr ↑
38
8
Sr
36
84Kr ↑
indicates data missing or illegible when filed
30
65Zn
29
65Cu
31
67Ga
30
67Zn
32
69Ge
31
69Ga
33
71As
31
71Ga
34
73Se
32
73Ge
35
75Br ↑96 min
33
75As
36
77Kr ↑74 min
34
77Se
37
79Rb
35
79Br ↑
38
81Sr
35
81Br ↑
30
67Zn
30
67Zn
31
69Ga
31
69Ga
32
71Ge
31
71Ga
33
73As
32
73Ge
34
75Se
33
75As
35
77Br ↑57 hrs
34
77Se
36
79Kr ↑35 hrs
35
79Br ↑
31
66Ga
30
66Zn
32
68Ge
30
68Zn
33
70As
32
70Ge absent (2)1735Cl ↑
34
72Se
32
72Ge
35
74Br ↑25 min
34
74Se absent (2)1737Cl ↑
36
76Kr ↑14.8 hrs
34
76Se
37
78Rb
36
78Kr ↑
38
80Sr
36
80Kr ↑
31
68Zn
31
68Zn
32
70Ge absent
33
72As
32
72Ge
34
74Se
35
76Br ↑16 hrs
34
76Se (2)1738Cl ↑37 min (2)1740Ar ↑
36
78Kr ↑
36
78Kr ↑
37
80Rb
36
80Kr ↑
38
82Sr
36
82Kr ↑
31
69Ga
31
69Ga
32
71Ge
31
71Ga
33
73As
32
73Ge
34
75Se
33
75As
35
77Br ↑57 hrs
34
77Se
36
79Kr ↑35 hrs
35
79Br ↑
37
81Rb
36
81Kr ↑
38
83Sr
36
83Kr ↑
31
70Ga
30
70Zn
32
72Ge
32
72Ge
33
74As
34
76Se
35
78Br ↑6 min
36
80Kr ↑
36
80Kr ↑
37
82Kr ↑
37
82Kr ↑
31
72Ga
32
72Ge
32
74Ge
32
74Ge
33
76As
35
80Br ↑18 min
36
82Kr ↑
37
84Rb
48
107Cd
47
109Ag
49
111In
48
111Cd
50
113Sn
49
113In
51
115Sb
52
117Te
50
117Sn
53
119I ↑19 min
50
119Sn
54
121Xe ↑40 min
51
121Sb
55
123Cs
52
123Te absent(note 4) 51123Sb absent 50119Sn
48
111Cd
49
113In
50
115Sn note2
51
117Sb
50
117Sn
52
119Te
50
119Sn
53
121I ↑2 hrs
51
121Sb
54
123Xe ↑2.1 hr
52
123Te absent(note 4) 51123Sb absent 50119Sn
55
125Cs
52
125Te
28
61Ni
29
63Cu
30
65Zn
29
65Cu
31
67Ga
30
67Zn
32
69Ge
31
69Ga
33
71As
31
71Ga
34
73As
32
73Ge
35
75Br ↑96 min
33
75As
36
77Kr ↑4 min
23
51V 2456Cr
26
56Fe
23
52V 2455Cr
24
52Cr 2555Mn
23
53V 2454Cr
24
53Cr
23
54V 2453Cr
24
54Cr
23
55V 2452Cr
25
55Mn
22
51Ti 2556Mn
23
51V 2656Fe
22
52Ti 2555Mn
24
52Cr
22
53Ti 2554Mn
22
54Ti 2553Mn
24
54Cr 2453Cr
22
55Ti 2552Mn
25
55Mn 2452Cr
21
45Sc 2662Fe
28
62Ni
20
50Ca 2759Co
22
50Ti
22
53Ti 2256Mn
24
53Cr 2656Fe
22
54Ti 2555Mn
24
54Cr
22
55Ti 2554Mn
22
56Ti 2553Mn
26
56Fe 2453Cr
23
53V 2456Cr
24
53Cr 2656Fe
23
55V 2454Cr
25
55Mn
23
56V 2453Cr
26
56Fe
26
57Fe
28
64Ni absent 3066Zn absent 2862Ni (note 6)
26
54Fe
26
54Fe
26
55Fe
25
55Mn
26
56Fe
26
56Fe
26
57Fe
26
57Fe
26
50Fe
26
60Ni
22
50Ti
24
51Cr
23
51V
24
52Cr
24
53Cr
24
54Cr
24
56Cr
26
56Fe
22
46Ti
22
46Ti
22
47Ti
22
47Ti
22
48Ti absent
22
49Ti
22
49Ti
22
50Ti
22
52Ti
24
52Cr
47
107Ag Alpha Decay in Miley's Nickle Coated Micro-spheres
45
103Rh (stable)
45
103Rh absent(note2) 2351V 2452Cr 2350V 2453Cr
43
99Tc
44
99Rh absent(note2) 2249Ti 2250Ti 2247Ti 2252Ti
41
95Nb
42
95Mo
39
91Y
40
91Zr absent 3887Sr
37
87Ru
38
87Sr
35
83Br ⇑2.9 min
37
85Rb
33
79As
35
79Br ⇑
29
71Cu
33
75As
47
109Ag Alpha Decay in Miley's Nickle Coated Micro-spheres
45
105Rh
46
105Pd (note 2) 2452Cr 2453Cr
43
101Tc
44
101Ru (note 2) 2250Ti 2351V
41
97Nb
42
97Mo (note 2) 2145Sc 2452Cr
38
93Y
41
93Nb
37
89Ru
38
89Y
35
85Br ⇑2.9 min
37
85Rb
33
81As
35
81Br ⇑
31
75Ga
34
77Se
56
116Ba
48
111Cd, 50112Sn, 50114Sn, 50115Sn, [50116Sn] absent (2)2658Fe
56
120Ba
50
116Sn, 50118Sn, [51120Te] absent (2)2860Ni
56
122Ba
50
118Sn, {52122Te} absent (2)2861Ni
56
124Ba
56
128Ba
57
118La
50
114Sn, 50116Sn, 50117Sn, [50118Sn]
57
122La
50
118Sn, 51121Sb, [52122Te] absent (note 3) (2)2861Ni
59
122Pr
50
118Sn, 52120Te, 51121Sb, [52122Te] absent (2)2861Ni 50118Sn + He
59
126Pr
52
125Te, [54126Xe ⇑]
54
117Xe
50
116Sn, [50117Sn]
54
118Xe
54
120Xe
52
110Te
47
109Ag, [48110Cd] absent [(2)2455Mn]
52
111Te
48
110Cd, [48111Cd]
52
112Te
52
114Te
76
167Os
60
143Nd, 62147Sm, 64155Gd, 65159Tb, 66163Dy, [68167Er] absent [66163Dy] + 24He*
77
172Ir
68
164Er, 70168Yb, [70172Yb]
77
169Ir
59
141Pr, 60145Nd, 62149Sm, 63153Eu, 64157Gd, 66161Dy, 67165Ho, [69169Tm] absent 67165Ho + 24He*
75
165Re
59
141Pr, 60145Nd, 62149Sm, 63153Eu, 64157Gd, 66161Dy, [67165Ho]
75
167Re
60
143Nd, 62147Sm, 63151Eu, 64155Gd, 65159Tb, [68167Er] absent, 69169Tm [66163Dy] + 24He*
76
169Os 76169Os
59
141Pr, 60145Nd, 62149Sm, 63153Eu, 64157Gd, 66161Dy, 68164Er, 67165Ho, [69169Tm] absent 67165Ho + 24He* same as above but with a different overall mass change
The observation that the Principle of Least Action is operative in the selection process for observed final isotopes is very strong evidence that we are dealing with a thermodynamically reversible process . . . the fundamental premise of this invention. The observation that this invention selects observed isotopes in all 210 cases is a remarkable test of the method that is unequaled by any other proposed theory.
The LANP process can be modified in predictable ways to customize its operation for specific purposes. The calculation procedure shown above in [0056] can be used to select impurities that can be added to the cathode to produce specific reactions (exothermic or endothermic), or to produce specific isotopes preferentially, but not exclusively.
For example, the reaction of 62Ni+2H+ shown above produces excess energy, as do all of the nuclear reactions having a positive mass change in Tables 1-10. Designing electrodes that favor excess energy, while minimizing energy consumption (negative Δm change) can be used to optimize the electrode for excess heat production.
As a second example, the selective production of specific isotopes can be achieved by doping the manufactured electrode with impurities that favor one isotope product over others. In Table 10, a reaction sequence is shown which results in dysprosium, 66163Dy. Using this reaction sequence as a template, the manufacture of cathodes made of nickel-58 with silver-107 impurities can select for the production of 66163Dy, not exclusively, but preferentially. The doping can include one or more isotopes to achieve specific LANP operational or product formation objectives.
Radioactive waste stabilization can be achieved by using an LANP device having specially manufactured electrodes containing radioactive wastes. This should produce stable isotopes of lead, and possibly other presently unknown products.
The LANP process ultimately exhausts the capacity of the electrode to produce heat or isotope product. The cathode then needs to be replaced. This can be done with a cathode made of metal coated microspheres that act as a fluid flowing through the LANP device, or some other technology that renews the cathode continuously. The used cathode is then reprocesses to recover specific products, re-purify the cathode's metal lattice material, and manufacture new cathode material.
LANP can be used as a scientific tool to study Sigma decay, or to study LANP technologies.
Further, LANP has several industrial uses. The first and most widely acclaimed is the recovery of process heat energy that can be used for other human activities. These include heat energy conversion to electricity of chemical energy, heating domestic, industrial, agricultural, or commercial spaces (or any other space), and other uses for heat energy that are either not yet apparent or not yet invented.
Second, the nuclear reaction selection process can be used to calculate the end products of a specially doped LANP electrode. For example, the first two reactions shown in Table 10 show how two rare earth metals can be produced from a nickel electrode electrolysis in heavy water. The secret lies in doping the electrode with an impurity, silver-107. The process can be made even more selective by refining the nickel so that more of it is in the nickel-58 or nickel-61 isotopic forms. This kind of predictive tool can be used to produce custom designed impurities in the final electrode. These can then be refined out of the post-LANP electrode material using known industrial separation processes.
A third application that has been proposed is using an LANP to convert radioactive wastes to stable, non-radioactive material, primarily lead-206, lead-207, lead-208.
LANP will become the fundamental process employed in domestic, industrial, commercial, and agricultural machines/devices that have already been invented or will be invented in the future.
Some examples drawn from the very limited nuclear reactions that have been analyzed thus far will clarify these claims.
The LANP process alters the natural isotope distribution from the isotope percentages normally found on earth. This occurs because LANP uses isotopes within the electrolysis electrode to produce new isotopes. The resulting isotope distributions are known (George Miley experiments cited elsewhere in this application) to be far from those that occur naturally on planet earth. This illustrates the basic concept here. The LANP methods allow doping of the electrode materials in very specific ways that enhance beneficial outcomes including, but not limited to:
Consider the first equation in Table 1, where amu=atomic mass units
Given that the final products are 0.0181096 amu lighter than the reactants, this means that 0.0181096 amu or approximately 16.869 MeV were produced as heat energy. Table 1 also shows that the other stable isotopes of Nickel, 2860Ni, 2861Ni, 28
Furthermore the heat production of a nickel electrode could be enhanced by doping the electrode material with additional 2858Ni. This might be accomplished, for example, by:
1. Adding 2858Ni to an electrode that is being designed to enhance heat production.
2. Running a LANP electrode that preferentially produced 2858Ni. This electrode might initially be used for heat production or another LANP method.
Conversely, an electrode could be designed with proportionally more 2860Ni to reduce heat production.
This example is presented to illustrate some of the design considerations involved in altering heat production from the LANP process. The combination of such doping modifications is not known at this time.
58Ni
59Ni
59Co
60Ni
61Ni
62Ni[n 4]
63Ni
63Cu
63mNi
64Ni
Consider the opportunity to harvest Xenon from a LANP reactor that uses nickel electrodes. The reactions in Table 9 might be useful in the design of an electrode for this purpose. The table shows three pathways to Xenon:
Each of these reactions consumes heat in the LANP reactor. If a secondardy design consideration is heat production, doping the nickel electrode with 2862Ni or 2864Ni would consume less heat from the overall process thereby optimizing heat production as a secondardy industrial objective. However, If heat production needs to be minimized during the xenon production process, proportionally more 2860Ni might be designed into the electrode. These are again examples of how industrial objectives may govern the doping of electrode material.
There can be any number of industrial reasons for wanting to reduce specific isotopes in an LANP electrode or in an LANP reactor.
Radioactive nuclei could possibly be disposed of in LANP reactors. The great virtue of the process is found in the way that it produces only stable isotope products and no radioactivity. It could be possible to dope electrodes with radioactive waste products that would then be converted to stable end products. The permissible amount of this type of doping (as a percentage by weight) is completely unknown, as are the operational variables. The limiting variable may be the percentage of radioactive waste additive in an electrode before the process leaves the realm of reversible thermodynamic processes, and ceases.
There might be cases where the evolution of gas products from the LANP reactor needs to be modified. This could be, for example, limiting the total volume of gas, or elimination of a specific type of gas such as chlorine or bromine. You will note that many of the reactions presented in the tables produce gaseous products. In these instances, it may be necessary to dope the electrode in specific ways that react away isotope fractions that will produce these gasses. This might be done as a pretreatment step in a sensitive industrial process, or for environmental health reasons.
There are no other applications related to this process filed by Daniel S Szumski with the United States Patent Office.
Related US PTO patents for devices that use a process similar to that described in this application include:
This application is a continuation in part of international application serial number PCT/US2012/000265, filed on Jun. 4, 2012.
Number | Date | Country | |
---|---|---|---|
Parent | PCT/US2012/000265 | Jun 2012 | US |
Child | 14544169 | US |