The disclosure relates to a light detection element, a light sensor unit, and a receiving device. Priority is claimed on Japanese Patent Application No. 2022-011922, filed Jan. 28, 2022, the content of which is incorporated herein by reference.
Photoelectric conversion elements are used in various applications.
For example, Patent Document 1 discloses a receiving device which receives an optical signal using a photodiode. For example, the photodiode is a pn junction diode or the like using a semiconductor pn junction. In addition, for example, Patent Document 2 discloses a light sensor using a semiconductor pn junction and an image sensor using this light sensor.
[Patent Document 1] Japanese Unexamined Patent Application, First Publication No. 2001-292107
[Patent Document 2] Specification of U.S. Pat. No. 9,842,874
Light sensors using a semiconductor PN junction are widely utilized, but new breakthroughs are required for further development.
It is desirable to provide a light detection element, a light sensor unit, and a receiving device having novelty. The following means are provided.
A light detection element according to a first aspect includes a meta-lens that includes nanostructures which are two-dimensionally arranged; and a magnetic element that includes a first ferromagnetic layer, a second ferromagnetic layer, and a spacer layer sandwiched between the first ferromagnetic layer and the second ferromagnetic layer. Light which passes through the meta-lens is applied to the magnetic element.
A light sensor unit according to a second aspect includes a plurality of light detection elements. Each of the light detection elements is the light detection element according to the first aspect.
A receiving device according to a third aspect includes the light detection element according to the first aspect.
Hereinafter, embodiments will be described in detail suitably with reference to the drawings. In drawings used in the following description, in order to make characteristics easy to understand, characteristic portions may be illustrated in an enlarged manner for the sake of convenience, and dimensional ratios or the like of each constituent element may differ from actual values thereof. Exemplary materials, dimensions, and the like illustrated in the following description are merely examples. The disclosure is not limited thereto and can be suitably changed and performed within a range in which the effects of the disclosure are exhibited.
Directions will be defined. A lamination direction of a magnetic element 10 will be regarded as a z direction, one direction within a plane orthogonal to the z direction will be regarded as an x direction, and a direction orthogonal to the x direction and the z direction will be regarded as a y direction. Hereinafter, the positive z direction may be expressed as “upward”, and the negative z direction may be expressed as “downward”. The positive z direction is a direction toward a meta-lens 20 from the magnetic element 10. The upward and downward directions do not necessarily coincide with the direction in which the force of gravity acts.
The light detection element 100 has the magnetic element 10 and the meta-lens 20. Light which passes through the meta-lens 20 is applied to the magnetic element 10. The magnetic element 10 detects light applied to the magnetic element 10. The magnetic element 10 converts light applied to the magnetic element 10 into an electrical signal. The meta-lens 20 focuses light toward the magnetic element 10. For example, the magnetic element 10 is disposed at a focal position of light focused by the meta-lens 20. For example, an insulating layer 91 is provided between the magnetic element 10 and the meta-lens 20.
In this specification, light is not limited to visible rays and also includes infrared rays having a longer wavelength than visible rays and ultraviolet rays having a shorter wavelength than visible rays. The wavelength of visible rays is 380 nm or more and less than 800 nm, for example. The wavelength of infrared rays is 800 nm or more and 1 mm or less, for example. The wavelength of ultraviolet rays is 200 nm or more and less than 380 nm, for example.
The magnetic element 10 has at least a first ferromagnetic layer 1, a second ferromagnetic layer 2, and a spacer layer 3. The spacer layer 3 is positioned between the first ferromagnetic layer 1 and the second ferromagnetic layer 2. In addition to these, the magnetic element 10 may have a buffer layer 4, a seed layer 5, a third ferromagnetic layer 6, a magnetic coupling layer 7, a perpendicular magnetization inducing layer 8, a cap layer 9, and an insulating layer 90. The buffer layer 4, the seed layer 5, the third ferromagnetic layer 6, and the magnetic coupling layer 7 are positioned between the second ferromagnetic layer 2 and a second electrode 12, and the perpendicular magnetization inducing layer 8 and the cap layer 9 are positioned between the first ferromagnetic layer 1 and a first electrode 11. The insulating layer 90 is positioned between the first electrode 11 and the second electrode 12 and covers a part around a laminate 15.
For example, the magnetic element 10 is a magnetic tunnel junction (MTJ) element in which the spacer layer 3 is constituted using an insulating material. When light from the outside is applied to the magnetic element 10, a resistance value thereof changes. In the magnetic element 10, the resistance value in the z direction (the resistance value when a current flows in the z direction) changes in accordance with relative change between a state of a magnetization M1 of the first ferromagnetic layer 1 and a state of a magnetization M2 of the second ferromagnetic layer 2. Such an element is also referred to as a magnetoresistance effect element.
The first ferromagnetic layer 1 is a light detection layer of which the state of the magnetization changes when light is applied from the outside. The first ferromagnetic layer 1 is also referred to as a magnetization free layer. A magnetization free layer is a layer including a magnetic material of which the state of the magnetization changes when a predetermined energy from the outside is applied thereto. For example, a predetermined energy from the outside is light applied from the outside, a current flowing in the z direction of the magnetic element 10, or an external magnetic field. The state of the magnetization M1 of the first ferromagnetic layer 1 changes in accordance with the intensity of applied light.
The first ferromagnetic layer 1 includes a ferromagnetic material. For example, the first ferromagnetic layer 1 includes at least any of magnetic elements such as Co, Fe, and Ni. In addition to the magnetic elements described above, the first ferromagnetic layer 1 may include elements such as B, Mg, Hf, and Gd. For example, the first ferromagnetic layer 1 may be an alloy including a magnetic element and a non-magnetic element. The first ferromagnetic layer 1 may be constituted of a plurality of layers. For example, the first ferromagnetic layer 1 is a laminate in which a CoFeB alloy and a CoFeB alloy layer are sandwiched between Fe layers or a laminate in which a CoFeB alloy layer is sandwiched between CoFe layers. Generally, “ferromagnetism” includes “ferrimagnetism”. The first ferromagnetic layer 1 may exhibit ferrimagnetism. On the other hand, the first ferromagnetic layer 1 may exhibit ferromagnetism that is not ferrimagnetism. For example, a CoFeB alloy exhibits ferromagnetism that is not ferrimagnetism.
The first ferromagnetic layer 1 may be an in-plane magnetization film having an easy axis of magnetization in a direction within the film surface (any direction within an xy plane) or a perpendicular magnetization layer having an easy axis of magnetization in a direction perpendicular to the film surface (z direction).
The film thickness of the first ferromagnetic layer 1 is 1 nm to 5 nm, for example. The film thickness of the first ferromagnetic layer 1 may be 1 nm to 2 nm, for example. When the first ferromagnetic layer 1 is a perpendicular magnetization layer, if the film thickness of the first ferromagnetic layer 1 is small, perpendicular magnetic anisotropy application effects from layers on and beneath the first ferromagnetic layer 1 are enhanced, and the perpendicular magnetic anisotropy of the first ferromagnetic layer 1 increases. Namely, if the perpendicular magnetic anisotropy of the first ferromagnetic layer 1 is high, a force of the magnetization M1 tending to return in the z direction becomes stronger. On the other hand, if the film thickness of the first ferromagnetic layer 1 is large, perpendicular magnetic anisotropy application effects from layers on and beneath the first ferromagnetic layer 1 are relatively reduced, and the perpendicular magnetic anisotropy of the first ferromagnetic layer 1 decreases.
If the film thickness of the first ferromagnetic layer 1 is reduced, the volume of the ferromagnetic material decreases, and if it is increased, the volume of the ferromagnetic material increases. Magnetization responsiveness of the first ferromagnetic layer 1 when an energy from the outside is applied thereto is inversely proportional to the product (KuV) of a magnetic anisotropy (Ku) and a volume (V) of the first ferromagnetic layer 1. Namely, if the product of the magnetic anisotropy and the volume of the first ferromagnetic layer 1 becomes smaller, the responsiveness with respect to light increases. From such a viewpoint, to increase the reaction to light, the magnetic anisotropy of the first ferromagnetic layer 1 may be appropriately designed and then the volume of the first ferromagnetic layer 1 may be reduced.
When the film thickness of the first ferromagnetic layer 1 is larger than 2 nm, for example, an insertion layer made of Mo and W may be provided inside the first ferromagnetic layer 1. That is, a laminate in which a ferromagnetic layer, an insertion layer, and a ferromagnetic layer are laminated in order in the z direction may be adopted as the first ferromagnetic layer 1. The perpendicular magnetic anisotropy of the entire first ferromagnetic layer 1 increases due to interface magnetic anisotropy in interfaces between the insertion layer and the ferromagnetic layers. The film thickness of the insertion layer is 0.1 nm to 1.0 nm, for example.
The second ferromagnetic layer 2 is a magnetization fixed layer. A magnetization fixed layer is a layer made of a magnetic material of which the state of the magnetization is less likely to change than that of the magnetization free layer when a predetermined energy from the outside is applied thereto. For example, in a magnetization fixed layer, a direction of the magnetization when a predetermined energy from the outside is applied thereto is less likely to change than that of the magnetization free layer. In addition, for example, in a magnetization fixed layer, a magnitude of the magnetization is less likely to change than that of the magnetization free layer when a predetermined energy from the outside is applied thereto. For example, a coercive force of the second ferromagnetic layer 2 is greater than a coercive force of the first ferromagnetic layer 1. For example, the second ferromagnetic layer 2 has an easy axis of magnetization in the same direction as the first ferromagnetic layer 1. The second ferromagnetic layer 2 may be an in-plane magnetization film or may be a perpendicular magnetization layer.
For example, a material constituting the second ferromagnetic layer 2 is similar to that of the first ferromagnetic layer 1. For example, the second ferromagnetic layer 2 may be a multilayer film in which a Co layer having a thickness of 0.4 nm to 1.0 nm and a Pt layer having a thickness of 0.4 nm to 1.0 nm are alternately laminated several times. For example, the second ferromagnetic layer 2 may be a laminate in which a Co layer having a thickness of 0.4 nm to 1.0 nm, a Mo layer having a thickness of 0.1 nm to 0.5 nm, a CoFeB alloy layer having a thickness of 0.3 nm to 1.0 nm, and a Fe layer having a thickness of 0.3 nm to 1.0 nm are laminated in that order.
The magnetization of the second ferromagnetic layer 2 may be fixed, for example, through magnetic coupling with the third ferromagnetic layer 6 sandwiching the magnetic coupling layer 7. In this case, a combination of the second ferromagnetic layer 2, the magnetic coupling layer 7, and the third ferromagnetic layer 6 may be referred to as a magnetization fixed layer. Details of the magnetic coupling layer 7 and the third ferromagnetic layer 6 will be described below.
The spacer layer 3 is a layer disposed between the first ferromagnetic layer 1 and the second ferromagnetic layer 2. The spacer layer 3 is constituted of a layer constituted of an electric conductor, an insulator, or a semiconductor; or a layer including a current carrying point constituted of a conductor in an insulator. For example, the spacer layer 3 is a non-magnetic layer. The film thickness of the spacer layer 3 can be adjusted in accordance with orientation directions of the magnetization of the first ferromagnetic layer 1 and the magnetization of the second ferromagnetic layer 2 in the initial state, which will be described below.
When the spacer layer 3 is constituted using an insulating material, a material including aluminum oxide, magnesium oxide, titanium oxide, silicon oxide, or the like can be used as a material of the spacer layer 3. In addition, these insulating materials may include elements such as Al, B, Si, and Mg; or magnetic elements such as Co, Fe, and Ni. A high magnetoresistance change rate is obtained by adjusting the film thickness of the spacer layer 3 such that a high TMR effect is manifested between the first ferromagnetic layer 1 and the second ferromagnetic layer 2. In order to efficiently utilize a TMR effect, the film thickness of the spacer layer 3 may be approximately 0.5 to 5.0 nm and may be approximately 1.0 to 2.5 nm.
When the spacer layer 3 is constituted using a non-magnetic conductive material, a conductive material such as Cu, Ag, Au, or Ru can be used. In order to efficiently utilize a GMR effect, the film thickness of the spacer layer 3 may be approximately 0.5 to 5.0 nm and may be approximately 2.0 to 3.0 nm.
When the spacer layer 3 is constituted using a non-magnetic semiconductor material, a material such as zinc oxide, indium oxide, tin oxide, germanium oxide, gallium oxide, or ITO can be used. In this case, the film thickness of the spacer layer 3 may be approximately 1.0 to 4.0 nm.
When a layer including a current carrying point constituted of a conductor in a non-magnetic insulator is applied as the spacer layer 3, a structure including a current carrying point constituted of a non-magnetic conductor such as Cu, Au, or Al in a non-magnetic insulator constituted using aluminum oxide or magnesium oxide may be adopted. In addition, a conductor may be constituted using magnetic elements such as Co, Fe, and Ni. In this case, the film thickness of the spacer layer 3 may be approximately 1.0 to 2.5 nm. For example, the current carrying point is a columnar body having a diameter of 1 nm to 5 nm when view in a direction perpendicular to the film surface.
For example, the third ferromagnetic layer 6 is magnetically coupled to the second ferromagnetic layer 2. For example, magnetic coupling is anti-ferromagnetic coupling and occurs due to Ruderman-Kittel-Kasuya-Yosida (RKKY) interaction. The direction of the magnetization M2 of the second ferromagnetic layer 2 and the direction of a magnetization M6 of the third ferromagnetic layer 6 have an antiparallel relationship. For example, a material constituting the third ferromagnetic layer 6 is similar to that of the first ferromagnetic layer 1.
The magnetic coupling layer 7 is positioned between the second ferromagnetic layer 2 and the third ferromagnetic layer 6. For example, the magnetic coupling layer 7 is made of Ru, Ir, or the like.
The buffer layer 4 is a layer for relaxing lattice mismatch between different crystals. For example, the buffer layer 4 is a metal including at least one kind of element selected from the group consisting of Ta, Ti, Zr and Cr, or a nitride including at least one kind of element selected from the group consisting of Ta, Ti, Zr and Cu. More specifically, for example, the buffer layer 4 is made of Ta (single substance), a NiCr alloy, tantalum nitride (TaN), or copper nitride (CuN). For example, the film thickness of the buffer layer 4 is 1 nm to 5 nm. For example, the buffer layer 4 is amorphous. For example, the buffer layer 4 is positioned between the seed layer 5 and the second electrode 12 and comes into contact with the second electrode 12. The buffer layer 4 curbs an influence of crystal structures of the second electrode 12 on crystal structures of the second ferromagnetic layer 2.
The seed layer 5 enhances crystallinity of the layers laminated on the seed layer 5. For example, the seed layer 5 is positioned between the buffer layer 4 and the third ferromagnetic layer 6 and is provided on the buffer layer 4. For example, the seed layer 5 is made of Pt, Ru, Zr, or NiFeCr. The film thickness of the seed layer 5 is 1 nm to 5 nm, for example.
The cap layer 9 is provided between the first ferromagnetic layer 1 and the first electrode 11. The cap layer 9 may include the perpendicular magnetization inducing layer 8 which is laminated on the first ferromagnetic layer 1 and comes into contact with the first ferromagnetic layer 1. The cap layer 9 prevents damage to a lower layer during process steps and enhances the crystallinity of a lower layer at the time of annealing. The film thickness of the cap layer 9 is 10 nm or less, for example, such that sufficient light is applied to the first ferromagnetic layer 1.
The perpendicular magnetization inducing layer 8 induces the perpendicular magnetic anisotropy of the first ferromagnetic layer 1. For example, the perpendicular magnetization inducing layer 8 is made of magnesium oxide, W, Ta, Mo, or the like. When the perpendicular magnetization inducing layer 8 is made of magnesium oxide, in order to enhance the conductivity, magnesium oxide may be in an oxygen-deficient state. The film thickness of the perpendicular magnetization inducing layer 8 is 0.5 nm to 5.0 nm, for example.
For example, the insulating layer 90 is made of oxide, nitride, or oxynitride of Si, Al, or Mg. For example, the insulating layer 90 is made of silicon oxide (SiOx), silicon nitride (SiNx), silicon carbide (SiC), chromium nitride, silicon carbonitride (SiCN), silicon oxynitride (SiON), aluminum oxide (Al2O3), zirconium oxide (ZrOx), or the like.
For example, the first electrode 11 is disposed on the meta-lens 20 side of the magnetic element 10. Incident light is applied to the magnetic element 10 from the first electrode 11 side and is applied to at least the first ferromagnetic layer 1. The first electrode 11 is made of a conductive material. For example, the first electrode 11 is a transparent electrode having transparency with respect to light in a used wavelength range. For example, the first electrode 11 may allow 80% or more of light in a used wavelength range to be transmitted therethrough. For example, the first electrode 11 is made of oxide such as indium tin oxide (ITO), indium zinc oxide (IZO), zinc oxide (ZnO), or indium gallium zinc oxide (IGZO). The first electrode 11 may be constituted to have a plurality of columnar metals in these transparent electrode materials of these oxides. It is not essential to use the foregoing transparent electrode materials for the first electrode 11, and a metal material such as Au, Cu, or Al with a small film thickness may be used such that applied light reaches the first ferromagnetic layer 1. When a metal is used as a material of the first electrode 11, the film thickness of the first electrode 11 is 3 to 10 nm, for example. In addition, the first electrode 11 may have an antireflection film on an irradiation surface to which light is applied.
The second electrode 12 is made of a conductive material. For example, the second electrode 12 is constituted using a metal such as Cu, Al, or Au. A Ta layer or a Ti layer may be laminated on or beneath these metals. In addition, a laminated film made of Cu and Ta, a laminated film made of Ta, Cu, and Ti, and a laminated film made of Ta, Cu, and TaN may be used. In addition, TiN or TaN may be used for the second electrode 12. The film thickness of the second electrode 12 is 200 nm to 800 nm, for example.
The second electrode 12 may have transparency with respect to light applied to the magnetic element 10. Regarding a material of the second electrode 12, similar to the first electrode 11, for example, a transparent electrode material of oxide such as indium tin oxide (ITO), indium zinc oxide (IZO), zinc oxide (ZnO), or indium gallium zinc oxide (IGZO) may be used. Even when light is applied from a side of the first electrode 11, light may reach all the way to the second electrode 12 depending on the intensity of light. However, in this case, since the second electrode 12 is constituted to include a transparent electrode material of oxide, compared to a case in which the second electrode 12 is constituted using a metal, reflection of light in the interface between the second electrode 12 and a layer which comes into contact therewith can be curbed.
The meta-lens 20 has nanostructures 21. For example, the nanostructures 21 are formed on a base 22. The meta-lens 20 is a lens to which a metasurface is applied. The meta-lens 20 functions as a lens by controlling a phase distribution of light. A metasurface exhibits a function of a metamaterial due to a planar structure. A metamaterial is a medium having a negative refractive index or a medium designed to have a refractive index (permittivity, magnetic permeability) which does not exist in nature. Since a focal distance of the meta-lens 20 can be reduced, the light detection element 100 can be miniaturized. In addition, since a size of a focus of the meta-lens 20 can be reduced, light having a high energy can be efficiently applied to the magnetic element 10.
For example, the meta-lens 20 includes a dielectric in which surface plasmon excitation occurs. In addition, the meta-lens 20 transmits light in a bandwidth used. For example, the nanostructures 21 are made of titanium oxide or gallium nitride. When light incident on the light detection element 100 is infrared rays, the nanostructures 21 may be amorphous silicon. For example, the base 22 is made of silicon oxide or aluminum oxide.
The nanostructures 21 are two-dimensionally arranged in an xy plane. An xy plane is an example of an arrangement surface on which the nanostructures 21 are arranged.
For example, the nanostructures 21 are pillars having diameters ϕ and heights H. In the meta-lens 20, these nanostructures 21 are regularly arranged at intervals U. In the nanostructures 21, the diameters ϕ have multiple values. In the nanostructures 21, the heights H may have only one value or may have multiple values. The diameters ϕ and the intervals U are equal to or shorter than the wavelength of light used. In the example illustrated in
As illustrated in
For example, an area of each of the nanostructures 21 provided in the first region A1 in a plan view decreases toward the outward side from the center of the first region A1. For example, the diameters ϕ of the nanostructures 21 decrease toward the outward side from the center in the first region A1.
For example, an area of each of the nanostructures 21 provided in the annular region A2 in a plan view decreases toward an outer circumferential side from an inner circumferential side of the annular region A2. For example, the diameters ϕ of the nanostructures 21 decrease toward the outer circumferential side from the inner circumferential side in the annular region A2. For example, the areas of the nanostructures 21 arranged in the innermost circumference of the annular region A2 in a plan view are larger than the areas of the nanostructures 21 arranged in the outermost circumference of the first region A1 in a plan view.
In the meta-lens 20, the phase distribution of light can be controlled by adjusting disposition of the nanostructures 21, the size of each of the nanostructures 21, and the disposition intervals of the nanostructures 21.
For example, Table 1 shows the size of each of the nanostructures 21 and the disposition intervals of the nanostructures 21 w hen setting is performed with the diameter of the meta-lens 20 being 3 μm and the focal distance of light focused by the meta-lens 20 being 3 μm while the meta-lens 20 is constituted of only the first region A1. In this example, the nanostructures 21 are made of titanium oxide, and the insulating layer 91 is made of silicon oxide. In Table 1, λ represents the wavelength of light focused at the focal distance of 3 μm by the meta-lens 20, ϕmax represents the diameter of the largest nanostructure 21, ϕmin represents the diameter of the smallest nanostructure 21, H represents the heights of the nanostructures 21, and U represents the intervals between the nanostructures 21.
As shown in Table 1, even if the wavelength of incident light varies, the focal distance of the meta-lens 20 can be made the same by adjusting the sizes of the nanostructures 21 and the disposition intervals.
In addition, the structure of the meta-lens 20 is not limited to those illustrated in
Nanostructures 21A are two-dimensionally arranged in an xy plane. In a plan view of an xy plane, the shape of at least one of the nanostructures 21A in a plan view differs from the planar shape of another nanostructure 21A in a disposition angle. The disposition angle of the longitudinal direction of at least one of the nanostructures 21A is different from a disposition angle of the longitudinal direction of another nanostructure 21A.
For example, the shape of each of the nanostructures 21A in a plan view has a longitudinal direction and a transverse direction. The nanostructure 21A illustrated in
For example, Table 2 shows the size of each of the nanostructures 21A and the disposition intervals of the nanostructures 21A when setting is performed with the diameter of the meta-lens 20A being 3 μm and the focal distance of light focused by the meta-lens 20A being 3 μm while the distribution of the disposition angles θ of the nanostructures 21A satisfy the regularity of the Pancharatnam-Berry geometric phase. In this example, the nanostructures 21A are made of titanium oxide, and the insulating layer 91 is made of silicon oxide. In Table 2, λ represents the wavelength of light focused by the meta-lens 20 at the focal distance of 3 μm, W represents the widths of the nanostructures 21A in a plan view, L represents the lengths of the nanostructures 21A in a plan view, H represents the heights of the nanostructures 21A, and U represents the intervals between the nanostructures 21A.
As shown in Table 2, even if the wavelength of incident light varies, the focal distance of the meta-lens 20A can be made the same by adjusting the sizes of the nanostructures 21A and the disposition intervals.
The insulating layer 91 is provided between the magnetic element 10 and the meta-lens 20. The material of the insulating layer 91 is not particularly limited as long as light in a bandwidth used can be transmitted therethrough. For example, regarding the insulating layer 91, a substance similar to that of the insulating layer 90 can be used. The insulating layer 91 and the insulating layer 90 may be made of the same substances or different substances. In addition, the insulating layer 91 and the base 22 may be made of the same substances or different substances.
The light detection element 100 can be obtained by producing the second electrode 12, the magnetic element 10, the first electrode 11, the insulating layer 91, and the meta-lens 20 in order.
The magnetic element 10 is produced through a laminating step, a annealing step, and a processing step for each layer. First, the buffer layer 4, the seed layer 5, the third ferromagnetic layer 6, the magnetic coupling layer 7, the second ferromagnetic layer 2, the spacer layer 3, the first ferromagnetic layer 1, the perpendicular magnetization inducing layer 8, and the cap layer 9 are laminated on the second electrode 12 in order. For example, each layer is subjected to film formation by sputtering.
Next, the laminated film is annealed. An annealing temperature is 250° C. to 400° C., for example. Thereafter, the laminated film is processed into the laminate 15 which is columnar body by photolithography and etching. The laminate 15 may be a pillar or a prism. For example, the narrowest width when the laminate 15 is viewed in the z direction is 10 nm to 1,000 nm.
Next, the insulating layer 90 is formed such that a side surface of the laminate 15 is covered. The insulating layer 90 may be laminated multiple times. Next, an upper surface of the cap layer 9 is exposed from the insulating layer 90 by chemical mechanical polishing, and the first electrode 11 is subjected to film formation on the cap layer 9.
Next, the insulating layer 91 is subjected to film formation on the first electrode 11. A resist having a predetermined pattern formed thereon is formed on an upper surface of the insulating layer 91, and dry etching is performed. Through dry etching, a hole having a predetermined pattern is formed on the upper surface of the insulating layer 91. Next, the meta-lens 20 is formed by performing film formation while the hole is filled with the material constituting the nanostructures 21. The light detection element 100 is obtained through the foregoing step. When a wavelength filter 40 (which will be described below) is used, for example, a dielectric multilayer film which will serve as the wavelength filter 40 is subjected to film formation between the first electrode 11 and the insulating layer 91, for example. In this manner, in production of the light detection element 100, the magnetic element 10 and the meta-lens 20 can be consecutively formed through a vacuum film formation process.
Next, operation of the light detection element 100 according to the first embodiment will be described.
Light L incident on the light detection element 100 is focused by the meta-lens 20. As illustrated in
The magnetic element 10 is disposed at the focal position of the light L in a bandwidth used focused by the meta-lens 20. For example, the focal position of the light L in a bandwidth used may overlap the first ferromagnetic layer 1. For example, when visible rays are used, the magnetic element 10 is disposed at the focal position of light in a particular wavelength range of a wavelength range of 380 nm or more and less than 800 nm. In addition, for example, when infrared rays are used, the magnetic element 10 is disposed at the focal position of light in a particular wavelength range of a wavelength range of 800 nm or more and less than 1,000 nm. In addition, for example, when ultraviolet rays are used, the magnetic element 10 is disposed at the focal position of light in a particular wavelength range of a wavelength range of 200 nm or more and less than 380 nm.
In addition, the light L applied to the magnetic element 10 may be light which pusses through the wavelength filter 40. The light detection element 100 may have the wavelength filter 40. For example, the wavelength filter 40 is disposed between the magnetic element 10 and the meta-lens 20 or on a side of the meta-lens 20 opposite to the magnetic element 10. Further, light L which passes through the meta-lens 20 is applied to the magnetic element 10.
An output voltage from the magnetic element 10 changes due to change in intensity of the light L applied to the first ferromagnetic layer 1. Change in resistance value of the first ferromagnetic layer 1, the second ferromagnetic layer 2, and the spacer layer 3 in the lamination direction contributes to change in output voltage from the magnetic element 10. In a first operation example, a case in which the intensity of light applied to the first ferromagnetic layer 1 has two levels including a first intensity and a second intensity will be described as an example. The intensity of light of the second intensity is set to be larger than the intensity of light of the first intensity. The first intensity may be zero in the case in which the intensity of light is applied to the first ferromagnetic layer 1.
First, in a state in which light having the first intensity is applied to the first ferromagnetic layer 1 (which will hereinafter be referred to as an initial state), the magnetization M1 of the first ferromagnetic layer 1 and the magnetization M2 of the second ferromagnetic layer 2 have a parallel relationship. A first resistance value R1 represents the resistance value of the magnetic element 10 in the z direction, and a first value represents the magnitude of an output voltage from the magnetic element 10. The resistance value of the magnetic element 10 in the z-direction is obtained by causing a sense current Is to flow through the magnetic element 10 in the z-direction to generate a voltage across both ends of the magnetic element 10 in the z-direction and using Ohm's law from a voltage value. An output voltage from the magnetic element 10 is generated between the first electrode 11 and the second electrode 12. In the case of the example illustrated in
Next, the intensity of light applied to the first ferromagnetic layer 1 changes from the first intensity to the second intensity. The second intensity is greater than the first intensity, and the magnetization M1 of the first ferromagnetic layer 1 changes from the initial state. The state of the magnetization M1 of the first ferromagnetic layer 1 in a state in which light is not applied to the first ferromagnetic layer 1 and the state of the magnetization M1 of the first ferromagnetic layer 1 in a state in which light having the second intensity is applied to the first ferromagnetic layer 1 differ from each other. For example, the state of the magnetization M1 includes the inclination angle with respect to the z direction, the magnitude, and the like.
For example, as illustrated in
When the magnetization M1 of the first ferromagnetic layer 1 changes from the initial state, the resistance value of the magnetic element 10 in the z direction represents a second resistance value R2, and the magnitude of an output voltage from the magnetic element 10 represents a second value. The second resistance value R2 is larger than the first resistance value R1, and the second value of an output voltage is larger than the first value. The second resistance value R2 is a value between the resistance value when the magnetization M1 and the magnetization M2 are parallel to each other (first resistance value R1) and the resistance value when the magnetization M1 and the magnetization M2 are antiparallel to each other.
In the case illustrated in
An output voltage from the magnetic element 10 changes in response to the change in intensity of light applied to the first ferromagnetic layer 1, and the change in intensity of applied light can be converted into the change in output voltage from the magnetic element 10. That is, the magnetic element 10 can replace light with an electrical signal. For example, processing is performed while having an output voltage from the magnetic element 10 equal to or larger than a threshold as a first signal (for example, “1”) and having it smaller than the threshold as a second signal (for example, “0”).
Here, a case in which the magnetization M1 and the magnetization M2 are parallel to each other in the initial state has been described as an example. However, the magnetization M1 and the magnetization M2 may be antiparallel to each other in the initial state. In this case, the resistance value of the magnetic element 10 in the z direction decreases as the state of the magnetization M1 changes (for example, as change in angle from the initial state of the magnetization M1 increases). When a case in which the magnetization M1 and the magnetization M2 are antiparallel to each other is set as the initial state, the sense current Is may flow from the second ferromagnetic layer 2 toward the first ferromagnetic layer 1. When the sense current Is flows in this direction, a spin transfer torque in a direction opposite to the magnetization M2 of the second ferromagnetic layer 2 acts on the magnetization M1 of the first ferromagnetic layer 1, and the magnetization M1 and the magnetization M2 become antiparallel to each other in the initial state.
In the first operation example, a case in which light applied to the first ferromagnetic layer 1 has two levels including the first intensity and the second intensity has been described as an example. However, in a second operation example, a case in which the intensity of light applied to the first ferromagnetic layer 1 changes in a multi-level manner or an analog manner will be described.
In the case of
When the magnetization M1 of the first ferromagnetic layer 1 is inclined from the initial state, the resistance value of the magnetic element 10 in the z direction changes. Further, an output voltage from the magnetic element 10 changes. For example, the resistance value of the magnetic element 10 in the z direction changes to the second resistance value R2, a third resistance value R3, or a fourth resistance value R4 in accordance with the inclination of the magnetization M1 of the first ferromagnetic layer 1, and an output voltage from the magnetic element 10 changes to the second value, a third value, or a fourth value. The resistance value increases in order of the first resistance value R1, the second resistance value R2, the third resistance value R3, and the fourth resistance value R4. The output voltage from the magnetic element 10 increases in order of the first value, the second value, the third value, and the fourth value.
In the magnetic element 10, when the intensity of light applied to the first ferromagnetic layer 1 changes, an output voltage from the magnetic element 10 (resistance value of the magnetic element 10 in the z direction) changes. For example, when the first value (first resistance value R1) is defined as “0”, the second value (second resistance value R2) is defined as “1”, the third value (third resistance value R3) is defined as “2”, and the fourth value (fourth resistance value R4) is defined as “3”, information of four values can be read out from the magnetic element 10. Here, a case of reading out four values has been described as an example. However, the number of values to be read out can be freely designed by setting the threshold for an output voltage from the magnetic element 10 (resistance value of the magnetic element 10). In addition, an output analog value of the magnetic element 10 may be utilized as it is.
In addition, similarly in the case of
In addition, in the case of the second operation example as well, similar to the case of the first operation example, when the intensity of light applied to the first ferromagnetic layer 1 returns to the first intensity, the state of the magnetization M1 of the first ferromagnetic layer 1 returns to the original state, and the magnetic element 10 returns to the initial state.
Here, a case in which the magnetization M1 and the magnetization M2 are parallel to each other in the initial state has been described as an example. However, in the second operation example as well, the magnetization M1 and the magnetization M2 may be antiparallel to each other in the initial state.
In addition, in the first operation example and the second operation example, a case in which the magnetization M1 and the magnetization M2 are parallel or antiparallel to each other in the initial state has been described as an example. However, the magnetization M1 and the magnetization M2 may be orthogonal to each other in the initial state. For example, a case in which the first ferromagnetic layer 1 in the initial state is an in-plane magnetization film having the magnetization M1 oriented in any direction in an xy plane and the second ferromagnetic layer 2 is a perpendicular magnetization layer having the magnetization M2 oriented in the z direction corresponds to this case. When the magnetization M1 is oriented in any direction within an xy plane due to the magnetic anisotropy and the magnetization M2 is oriented in the z direction, the magnetization M1 and the magnetization M2 are orthogonal to each other in the initial state.
In both cases of
When the intensity of light applied to the first ferromagnetic layer 1 increases, the magnetization M1 of the first ferromagnetic layer 1 is inclined from the initial state due to an energy from the outside caused by applied light. This is because the sum of the action on magnetization M1 caused by applied light and the action caused by a spin transfer torque becomes larger than the action caused by the magnetic anisotropy related to the magnetization M1. When the intensity of light applied to the first ferromagnetic layer 1 increases, the magnetization M1 in the case of
When the intensity of light applied to the first ferromagnetic layer 1 increases, in the case of
When the intensity of light applied to the first ferromagnetic layer 1 returns to the first intensity, the state of the magnetization M1 of the first ferromagnetic layer 1 returns to the original state due to the action on the magnetization M1 caused by the magnetic anisotropy. As a result, the magnetic element 10 returns to the initial state.
Here, an example in which the first ferromagnetic layer 1 is an in-plane magnetization film and the second ferromagnetic layer 2 is a perpendicular magnetization layer has been described. However, this relationship may be reversed. That is, in the initial state, the magnetization M1 may be oriented in the z direction, and the magnetization M2 may be oriented in any direction within an xy plane.
As described above, in the light detection element 100 according to the first embodiment, light is focused toward the magnetic element 10 by the meta-lens 20, and light can be replaced with an electrical signal by replacing light applied to the magnetic element 10 with an output voltage from the magnetic element 10.
In addition, the magnetization M1 of the first ferromagnetic layer 1 is more likely to change with respect to applied light as the volume of the first ferromagnetic layer 1 decreases. Namely, the magnetization M1 of the first ferromagnetic layer 1 is more likely to be inclined due to applied light or is more likely to decrease due to applied light as the volume of the first ferromagnetic layer 1 decreases. In other words, when the volume of the first ferromagnetic layer 1 is reduced, the magnetization M1 can be changed even with a slight amount of light. That is, the light detection element 100 according to the first embodiment can detect light with high sensitivity.
To be more exact, the changeability of the magnetization M1 is determined by the size of the product (KuV) of the magnetic anisotropy (Ku) and the volume (V) of the first ferromagnetic layer 1. As the KuV decreases, the magnetization M1 changes even with a smaller amount of light, and as the KuV increases, the magnetization M1 does not change unless a larger amount of light is applied. Namely, the KuV of the first ferromagnetic layer 1 is designed in accordance with the amount of light applied from the outside in an application use. When it is assumed to detect a very small amount of light (extremely small amount) such as photons, such a small amount of light can be detected by reducing the KuV of the first ferromagnetic layer 1. Detection of such a small amount of light is a great advantage because it becomes difficult in pn-junction semiconductors in the related art when the element size is reduced. Namely, photons can also be detected by reducing the volume of the first ferromagnetic layer 1, namely, by reducing the element area or thinning the film thickness of the first ferromagnetic layer 1 in order to reduce the KuV.
In addition, the amount of light focused on the magnetic element 10 by the meta-lens 20 increases as the area of the meta-lens 20 increases. In the magnetic element 10, since light can be replaced with an electrical signal even if the amount of applied light is small, the area of the meta-lens 20 can be reduced. The light detection element 100 can be integrated at a high density by reducing the area of the meta-lens 20 in accordance with the magnetic element 10.
The light detection element according to the foregoing embodiment can be applied to receiving devices of communication systems, light sensor devices such as image sensors, and the like.
For example, the light sensor unit 110 has a plurality of light detection elements 100. Each of the light detection elements 100 is the light detection element described above. Each of the light detection elements 100 functions as a light sensor. The light detection elements 100 may be operated in the second operation example. For example, the light detection elements 100 are two-dimensionally arranged in a matrix shape. Each of the light detection elements 100 is connected to a first selection line extending in a row direction and a second selection line extending in a column direction. The light sensor unit 110 detects light using the light detection elements 100 and replaces the light with an electrical signal.
For example, the semiconductor circuit 120 is disposed on the outward side of the outer circumference of the light sensor unit 110. In addition, the semiconductor circuit 120 may be formed on a circuit substrate 101 (which will be described below) and may be at a position overlapping the light sensor unit 110 in the z direction.
The semiconductor circuit 120 is electrically connected to each of the light detection elements 100. The semiconductor circuit 120 computes an electrical signal sent from the light sensor unit 110. For example, the semiconductor circuit 120 has a row decoder 121 and a column decoder 122. The positions of the light detection elements 100 which have detected light are specified using row decoder 121 and the column decoder 122. In addition to the row decoder 121 and the column decoder 122, the semiconductor circuit 120 may have a memory, a computation circuit, a resistor, and the like.
Each of the red sensor 100R, the green sensor 100G, and the blue sensor 100B detects light in a particular wavelength range of a wavelength range of 380 nm or more and less than 800 nm (which will hereinafter be referred to as first wavelength ranges). For example, the blue sensor 100B detects light in a wavelength range of 380 nm or more and less than 490 nm. For example, the green sensor 100G detects light in a wavelength range of 490 nm or more and less than 590 nm. For example, the red sensor 100R detects light in a wavelength range of 590 nm or more and 800 nm or less. The infrared sensor 100IR detects light in a particular wavelength range of a wavelength range of 800 nm or more and 1 mm or less (which will hereinafter be referred to as a second wavelength range). The ultraviolet sensor 100UV detects light in a particular wavelength range of a wavelength range of 200 nm or more and less than 380 nm (which will hereinafter be referred to as third wavelength ranges).
In the example illustrated in
The semiconductor circuit 120 described above is formed on the circuit substrate 101. For example, the circuit substrate 101 has an analog-digital convener 102 and an output terminal 103. An electrical signal sent from the light detection elements 100 is replaced with digital data by the analog-digital converter 102 and is output from the output terminal 103.
The wiring layer 105 has a plurality of wirings 106. An interlayer insulating film 107 is provided between the wirings 106. The wirings 106 electrically connect each of the light detection elements 100 to the circuit substrate 101 and connect computation circuits formed on the circuit substrate 101 to each other. For example, each of the light detection elements 100 is connected to the circuit substrate 101 via a penetration wiring penetrating the interlayer insulating film 107 in the z direction. Noise can be reduced by shortening the distance between the wiring between each of the light detection elements 100 and the circuit substrate 101.
The wirings 106 have conductivity. For example, the wirings 106 are made of Al, Cu, or the like. The interlayer insulating film 107 is an insulator insulating the wirings of multilayer wirings from each other and the elements from each other. For example, the interlayer insulating film 107 is made of oxide, nitride, or oxynitride of Si, Al, or Mg, and a material similar to that of the insulating layer 90 can be used.
In addition, the wavelength filter 40 of each of the red sensor 100R, the green sensor 100G, the blue sensor 100B, the infrared sensor 100IR, and the ultraviolet sensor 100UV varies in wavelength range of light transmitted therethrough. For example, the wavelength filter 40 of the red sensor 100R allows light in wavelength ranges of 590 nm or more and less than 800 nm to be transmitted therethrough. For example, the wavelength filter 40 of the green sensor 100G allows light in wavelength ranges of 490 nm or and less than 590 nm to be transmitted therethrough. For example, the wavelength filter 40 of the blue sensor 100B allows light in wavelength ranges of 380 nm or more and less than 490 nm to be transmitted therethrough. For example, the wavelength filter 40 of the infrared sensor 100IR allows light in a particular wavelength range of a wavelength range of 800 nm or more and 1 mm or less to be transmitted therethrough. For example, the wavelength filter 40 of the ultraviolet sensor 100UV allows light in a particular wavelength range of a wavelength range of 200 nm or more and less than 380 nm to be transmitted therethrough.
In the light detection elements 100 constituting one pixel p1, the distances between the magnetic elements 10 and the meta-lens 20 may be equivalent to each other. In this case, at least one light detection element 100 constituting one pixel p1 among the light detection elements 100 differs from another light detection element 100 constituting one pixel p1 in constitutions of the nanostructures 21 in the meta-lens 20. For example, the constitutions of the nanostructures 21 in each meta-leas 20 of the red sensor 100R, the green sensor 100G, the blue sensor 100B, the infrared sensor 100IR, and the ultraviolet sensor 100UV differ from each other. For example, the constitutions of the nanostructures 21 include the size of the shape of each of the nanostructures 21 in a plan view, the disposition intervals between nanostructures, and the like. For example, the constitutions of the nanostructures 21 in each meta-lens 20 may be set such that the focal distance of the meta-lens 20 of the red sensor 100R with respect to light having a wavelength of 633 nm, the focal distance of the meta-lens 20 of the green sensor 100G with respect to light having a wavelength of 530 nm, the focal distance of the meta-lens 20 of the blue sensor 100B with respect to light having a wavelength of 430 nm, the focal distance of the meta-lens 20 of the infrared sensor 100IR with respect to light having a wavelength of 1530 nm, and the focal distance of the meta-lens 20 of the ultraviolet sensor 100UV with respect to light having a wavelength of 290 nm become equivalent to each other.
In the light detection elements 100 illustrated in
In addition, thus far, an example in which the light detection elements 100 are two-dimensionally arranged has been described. However, the light detection elements 100 may be one-dimensionally arranged as illustrated in
In addition, as in a light sensor device 201 illustrated in
For example, in the red sensor 100R, the green sensor 100G, and the blue sensor 100B, the distance between the meta-lens 20 and the magnetic element 10 differ from each other. In the meta-lens 20 having a certain one constitution, the focal distance of the meta-lens 20 with respect to the light L varies depending on the wavelength of the light L. In the red sensor 100R, the magnetic element 10 (the first ferromagnetic layer 1 in the example of
The light sensor devices 200 and 201 measure an output voltage from the magnetic element 10 of each of the light detection elements 100 in the light sensor units 110 and 110A (resistance value of the magnetic element 10) together with positional information obtained by the row decoder 121 and the column decoder 122 and reads the intensity of light applied to the light sensor unit 110. For example, the light sensor devices 200 and 201 are used in image sensors and the like. Such image sensors can be used in information terminal devices such as smartphones, tablet computers, personal computers, and digital cameras.
Thus far, examples of the light sensor devices 200 and 201 have been described. However, the light sensor device is not limited to these examples. For example, in the light sensor units 110 and 110A, when the meta-lens 20 is used as illustrated in
For example, the receiving device 310 includes a light detection element 100 and a signal processing unit 311. The light detection element 100 is the light detection element described above and converts the optical signal L1 into an electrical signal. Light including the optical signal L1 with light intensity change is applied to the light detection element 100. In addition, light which passes through a waveguide may be applied to the light detection element 100. Light applied to the light detection element 100 (magnetic element 10) is laser light, for example. The signal processing unit 311 performs processing of an electrical signal converted by the light detection element 100. The signal processing unit 311 receives a signal included in the optical signal L1 by processing an electrical signal generated from the light detection element 100.
For example, the transmitting device 320 includes a light source 321, an electrical signal generator 322, and a light modulation element 323. For example, the light source 321 is a laser element. For example, the light source 321 may be an LED element. Light emitted by the light source 321 may be light having a single wavelength (monochromatic light). The light source 321 may be provided outside the transmitting device 320. The electrical signal generator 322 generates an electrical signal based on transmission information. The electrical signal generator 322 may be integrated with a signal conversion element of the signal processing unit 311. The light modulation element 323 modulates light output from the light source 321 and outputs the optical signal L2 based on an electrical signal generated by the electrical signal generator 322.
In addition, thus far, an example in which a transceiver device is applied to the communication system 300 illustrated in
For example,
Each of the portable terminal devices 350 includes the receiving device 310 and the transmitting device 320. The receiving device 310 of the other portable terminal device 350 receives an optical signal transmitted from the transmitting device 320 of one portable terminal device 350. Transceiving of an optical signal between the portable terminal devices 350 is performed by radio. Light used for transceiving between the portable terminal devices 350 is visible light, for example. For example, light used for transceiving between the portable terminal devices 350 may be near infrared light having a wavelength of 800 nm or more and 2500 nm or less. The light detection element described above is applied as the light detection element 100 of each receiving device 310. In this case, light including an optical signal transmitted from the transmitting device 320 may be propagated in the waveguide provided in the receiving device 310 and applied to the light detection element 100 or may be applied to the light detection element 100 without going through a waveguide.
In addition, for example,
The portable terminal devices 350 includes the transmitting device 320, and the information processing device 360 includes the receiving device 310. An optical signal transmitted from the transmitting device 320 of the portable terminal devices 350 is received by the receiving device 310 of the information processing device 360. Transceiving of an optical signal between the portable terminal devices 350 and the information processing device 360 is performed by radio. Light used for transceiving between the portable terminal devices 350 and the information processing device 360 is visible light, for example. Light used for transceiving between the portable terminal devices 350 and the information processing device 360 may be near infrared light having a wavelength of 800 nm or more and 2500 nm or less, for example. The light detection element described above is applied as the light detection element 100 of the receiving device 310. The light detection element, the light sensor unit, and the receiving device according to the foregoing embodiment operate in accordance with a novel principle.
While embodiments of the invention have been described and illustrated above, it should be understood that these are exemplary of the invention and are not to be considered as limiting. Additions, omissions, substitutions, and other modifications can be made without departing from the spirit or scope of the disclosure. Accordingly, the invention is not to be considered as being limited by the foregoing description, and is only limited by the scope of the appended claims.
1 First ferromagnetic layer
2 Second ferromagnetic layer
3 Spacer layer
4 Buffer layer
5 Seed layer
6 Third ferromagnetic layer
7 Magnetic coupling layer
8 Perpendicular magnetization inducing layer
9 Cap layer
10 Magnetic element
11 First electrode
12 Second electrode
15 Laminate
20, 20A Meta-lens
21, 21A Nanostructure
22 Base
23, 23A Unit
30 Polarization filter
40 Wavelength filter
90, 91 Insulating layer
100 Light detection element
100B Blue sensor
100G Green sensor
100R Red sensor
100IK Infrared sensor
100UV Ultraviolet sensor
101 Circuit substrate
102 Analog-digital converter
103 Output terminal
105 Wiring layer
106 Wiring
107 Interlayer insulating layer
110 Sensor unit
120 Semiconductor circuit
121 Row decoder
122 Column decoder
200, 201 Light sensor device
300, 300A, 300B Communication system
301 Transceiver device
310 Receiving device
311 Signal processing unit
320 Transmitting device
321 Light source
322 Electrical signal generator
323 Light modulation element
350 Information terminal device
360 Information processing device
L Light
L1, L2 Optical signal
P1, p2 Pixel
Number | Date | Country | Kind |
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2022-011922 | Jan 2022 | JP | national |