The present invention relates to a light emitting device.
In recent years, there has been advancement in the development of light emitting devices including an organic electroluminescence (EL) element as a light emitting element. The organic EL element is configured of an organic layer interposed between a first electrode and a second electrode. Examples of the light emitting device with the organic EL element include an illumination device, a display device, and the like.
There is sometimes a demand for the light emitting device having the same organic layers in a light emitting region to have a light emission color in a portion of the light emitting region that is different from a light emission color in another portion of the light emitting region. In response to such a demand, Patent Document 1 discloses denaturing (deteriorating) an organic pigment in a portion of a light emitting region to differentiate the light emission color in that portion from a light emission color in another portion of the light emitting region. Patent Document 1 discloses a method of performing irradiation with electromagnetic waves, for example, i rays of a high pressure mercury lamp, as a method of denaturing (deteriorating) an organic pigment.
Meanwhile, Patent Document 2 discloses that an initial reduction in luminescence may be suppressed by irradiating a hole transfer layer with light from a side opposite to a substrate after forming a hole injection layer and the hole transfer layer and before forming a light emitting layer.
[Patent Document 1] International Publication No. WO1997/43874
[Patent Document 2] Japanese Laid-open Patent Publication No. 2011-210613
Patent Document 1 discloses a method of deteriorating an organic pigment of a portion of a light emitting region to thereby make the light emission color in the portion of the light emitting region different from the light emission color in another portion of the light emitting region. However, since the method allows the organic pigment in the light emitting layer to be deteriorated, there is a risk that the life span of the light emitting device may be reduced.
An exemplary object of the invention is to make a light emission color in a portion of a light emitting region different from a light emission color in another portion of the light emitting region without reducing the life span of a light emitting device.
According to a first aspect of the invention, there is provided a light emitting device including
a substrate and
a light emitting unit on the substrate,
in which the light emitting unit includes a first light emitting region and a second light emitting region, and
in which the first light emitting region and the second light emitting region are adjacent each other, each of the first light emitting region and the second light emitting region including a first electrode, a second electrode, and an organic layer between the first electrode and the second electrode,
the light emitting device further including
a light limiting layer on the substrate between the first light emitting region and the second light emitting region, the light emitting layer preventing light incident on the second light emitting region from being incident on the first light emitting region.
According to a second aspect of the invention, there is provided a light emitting device including
a substrate,
a first light emitting region and a second light emitting region adjacent each other on the substrate, and
a light limiting layer on the substrate between the first light emitting region and the second light emitting region,
in which the light limiting layer includes a low transmittance material having a light transmittance lower than a light transmittance of a material constituting the light limiting layer.
The above-described object, other objects, features and advantages will be further apparent from the preferred embodiments described below, and the accompanying drawings as follows.
Hereinafter, embodiments of the invention will be described with reference to the accompanying drawings. In all the drawings, like reference numerals denote like components, and a description thereof will not be repeated.
The light emitting device 10 according to the present exemplary embodiment includes a substrate 100 and a light emitting unit 140. The light emitting unit 140 is formed on the substrate 100 and includes a first light emitting region 140a and a second light emitting region 140b, as illustrated in
The substrate 100 is formed of a material, such as glass or a transmissive resin, which transmits visible light. However, in a case where the light emitting device 10 is a top-emission type, the substrate 100 may be formed of a non-transmissive material. The substrate 100 is a polygon such as a rectangle. The substrate 100 maybe flexible. In a case where the substrate 100 is flexible, the thickness of the substrate 100 is, for example, equal to or greater than 10 μm and equal to or less than 1,000 μm. In particular, in a case where the substrate 100 is glass, the thickness of the substrate 100 is, for example, equal to or less than 200 μm. In a case where the substrate 100 is a resin, the substrate 100 is formed of, for example, polyethylene naphthalate (PEN), polyethersulfone (PES), polyethylene terephthalate (PET), or polyimide. When the substrate 100 is a resin, the substrate 100 allows moisture to easily pass therethrough. In order to suppress transmission of moisture, an inorganic barrier film such as SiNx or SiON is formed on at least a light emission surface side (preferably, both surfaces) of the substrate 100.
The light emitting unit 140 includes an organic EL element. The organic EL element is configured by laminating the first electrode 110, the organic layer 120, and the second electrode 130 on a first surface 102 of the substrate 100 in this order.
The first electrode 110 is a transparent electrode that transmits visible light. A transparent conductive material constituting the transparent electrode contains a metal, and is for example, a metal oxide such as indium tin oxide (ITO), indium zinc oxide (IZO), indium tungsten zinc oxide (IWZO), or zinc oxide (ZnO). The thickness of the first electrode 110 is, for example, equal to or greater than 10 nm and equal to or less than 500 nm. The first electrode 110 is formed by, for example, sputtering or vapor deposition. Meanwhile, the first electrode 110 may be an organic conductive material such as carbon nanotubes or PEDOT/PSS.
The organic layer 120 includes a light emitting layer. The organic layer 120 is configured by laminating, for example, a hole injection layer, a light emitting layer, and an electron injection layer. In the present exemplary embodiment, the organic layer 120 includes plural light emitting layers. Details of the configuration of the organic layer 120 will be described later with reference to
For example, the second electrode 130 includes a metal layer constituted of a metal selected from a first group consisting of Al, Au, Ag, Pt, Mg, Sn, Zn, and In or an alloy of metals selected from the first group. The thickness of the second electrode 130 is, for example, equal to or greater than 10 nm and equal to or less than 500 nm. However, the second electrode 130 may be formed using the material exemplified as a material of the first electrode 110. The second electrode 130 is formed by, for example, sputtering or vapor deposition.
Meanwhile, the materials of the foregoing first electrode 110 and second electrode 130 are examples for when transmitting light through the substrate 100, that is, for performing light emission from the light emitting device 10 through the substrate 100 (bottom-emission light emitting device). As a different case, light may be transmitted through a side opposite to the substrate 100. That is, light emission from the light emitting device 10 is performed without passing through the substrate 100 (top-emission light emitting device). The laminating structure in the top emission light emitting device has one of an inverted layer sequence and a standard layer sequence. In the inverted layer sequence, the material of the first electrode 110 and the material of the second electrode 130 are reversed to those of the bottom emission light emitting device. That is, the foregoing material of the second electrode 130 is used as the material of the first electrode 110 and the foregoing material of the first electrode 110 is used as the material of the second electrode 130. In contrast, in the standard layer sequence, the material of the first electrode 110 is formed on the foregoing material of the second electrode 130, the organic layer 120 is formed on the first electrode 110, and the second electrode 130, made into a thin film, is further formed on the organic layer 120, thus achieving a structure for taking out light from the side of the device opposite to the substrate 100. The light emitting device 10 according to the present exemplary embodiment may have any type of structure among the bottom emission light emitting device and the foregoing two types of top emission light emitting devices.
In addition, the light emitting device 10 includes a first terminal 112 and a second terminal 132. The first terminal 112 is electrically connected to the first electrode 110. For example, the first terminal 112 includes a layer formed of the same material as that of the first electrode 110. Further, this layer may be formed integrally with the first electrode 110. In addition, the second terminal 132 is electrically connected to the second electrode 130. In addition, the second terminal 132 also includes a layer formed of the same material as that of the first electrode 110. However, this layer is separated from the first electrode 110.
Meanwhile, an extraction interconnect may be provided between the first terminal 112 and the first electrode 110. In addition, an extraction interconnect may also be provided between the second terminal 132 and the second electrode 130.
In addition, a conductive layer formed of a material having a resistance lower than that of the first electrode 110 may be formed on the first electrode 110, on the first terminal 112, and on the second terminal 132. The conductive layer is formed of, for example, a metal or an alloy. The conductive layer may have a single-layered structure or a multi-layered structure. The conductive layer is configured by forming, for example, a Mo alloy layer (for example, a MoNb layer), an Al alloy layer (for example, an AlNd layer), and a Mo alloy layer (for example, a MoNb layer) in this order. A portion of the conductive layer located on the first electrode 110 is formed as, for example, plural linear electrodes. In addition, a portion of the conductive layer located on the first terminal 112 maybe formed on the entire surface of the first terminal 112. Further, a portion of the conductive layer located on the second terminal 132 may be formed on the entire surface of the second terminal 132. The formation of the conductive layer enables to decrease the apparent resistances of the first electrode 110, the first terminal 112, and the second terminal 132.
In addition, the light emitting device 10 includes an insulating layer 150. The insulating layer 150 is provided on the first surface 102 of the substrate 100 in order to define the light emitting unit 140. In the example illustrated in
In the organic layer 120, an organic layer 120a is located in a region serving as the first light emitting region 140a, and an organic layer 120b is located in a region serving as the second light emitting region 140b. When the current density is a fixed value or less, the light emission color (color temperature) of the organic layer 120a is different from the light emission color (color temperature) of the organic layer 120b. However, as described later, as the current density increases, the difference between the color temperatures of the organic layer 120a and the organic layer 120b decreases, until finally there is hardly any difference therebetween.
The organic layers 120a and 120b have the same layered structure and are formed by the same process using the same material. For this reason, it is difficult to distinguish between the organic layer 120a and the organic layer 120b when the light emitting device 10 is not emitting light.
In addition, as illustrated in
As illustrated in
Meanwhile, the sealing member may be a film formed by atomic layer deposition (ALD) or chemical vapor deposition (CVD). The thickness of the sealing film is, for example, equal to or greater than 10 nm and equal to or less than 1,000 nm. In a case where the sealing film is formed by ALD, the sealing film may have, for example, at least one of an aluminum oxide film and a titanium oxide film or a laminated film of these materials. In a case where the sealing film is formed by CVD or sputtering, the sealing film is formed of an insulating film such as SiO2 or SiN.
Meanwhile, for example, the light emission output spectrum is shown by a result obtained by measuring the light emission of the lighted light emitting unit 140 from the outside thereof by a spectrophotometer. In addition, for example, the internal light emission spectrum is shown by a result obtained by measuring photoluminescence of a light emitting layer to be measured, by a micro photoluminescence measurement device. When a comparison is made between a light emission output spectrum in the first light emitting region 140a with a light emission output spectrum in the second light emitting region 140b measured in the above manner, the peak wavelengths thereof are in common with each other, but the peak intensity ratios thereof are different from each other. On the other hand, when a comparison is made between an internal light emission spectrum in the first light emitting region 140a with an internal light emission spectrum in the second light emitting region 140b, both the peak wave lengths and the peak intensity ratios are in common with each other (substantially the same).
Each of layers constituting the organic layer 120 may be formed by vapor deposition. In addition, at least one layer in the organic layer 120, for example, the hole injection layer 121 that is in contact with the first electrode 110 may be formed by inkjet printing, printing, or coating such as spraying. Meanwhile, in this case, the remaining layers of the organic layer 120 may be formed by vapor deposition. Alternatively, all of the layers of the organic layer 120 may be formed by coating. In addition, in a case where the second light emitting layer 123 is formed by coating, the first light emitting layer 124 may be formed by vapor deposition. Meanwhile, either a fluorescent material or a phosphorescent material may be used for the first light emitting layer 124 and the second light emitting layer 123. However, the phosphorescent material is preferably used from the viewpoint of an improvement in internal quantum efficiency. In this case, examples of the phosphorescent material to be used include a phosphorescent organometallic complex and the like containing one or two or more kinds of heavy atoms having an atomic weight of equal to or greater than 100 and equal to or less than 200, selected from iridium, platinum, osmium, rhenium, gold, tungsten, ruthenium, hafnium, europium, terbium, rhodium, palladium, silver and the like.
Next, a method of manufacturing the light emitting device 10 will be described. First, the first electrode 110 is formed on the first surface 102 of the substrate 100. In this process, the first terminal 112 and the second terminal 132 are also formed. Subsequently, a resin material to be the insulating layer 150 is coated onto the first surface 102 of the substrate 100 and then exposed and developed. Thereby, the insulating layer 150 is formed.
Subsequently, the organic layer 120 is formed in a region of the first electrode 110 surrounded by the first insulating layer 150. Subsequently, the second electrode 130 is formed. Thereafter, the sealing portion 160 is provided.
Subsequently, as illustrated in
Meanwhile, the reason for the difference between the peak intensity ratios of the organic layer 120a and the organic layer 120b is considered to be due to the carrier balance of at least one of the second light emitting layer 123 and the first light emitting layer 124 changing by the organic layer 120 being irradiated with light, and a portion (binding site) having the largest binding amount between holes and electrons moving. In addition, in a case where the light emitting device 10 is the above-described top-emission light emitting device, it is possible to irradiate the organic layer 120 with the above-mentioned light for heating from the sealing portion 160 side (side of the first surface 102 of the substrate 100) by selecting a transmissive material for the sealing portion 160.
Meanwhile, when comparing
Meanwhile, when the entirety of the light emitting unit 140 is the first light emitting region 140a, the light emission output spectrum of the light emitting unit 140 indicates the properties illustrated in
In this manner, according to the light emitting device 10 in the present exemplary embodiment, it is possible to make a region equivalent to the first light emitting region 140a appear or disappear in the light emitting unit 140 by changing the current density. Meanwhile, characters, signs, or pictures may be used for a display of the first light emitting region 140a and a display that can be expressed by a difference in the light emission colors between the first light emitting region 140a and the second light emitting region 140b. The shape of the first light emitting region 140a is freely set by adjusting a region of the light emitting unit 140 irradiated with light. In this manner, it is possible to provide, using the level difference in current values, an OFF mode, a display mode for displaying using the difference in light emission colors between the first light emitting region 140a and the second light emitting region 140b, and a light emission mode in which only light emission is performed without showing a display using the difference in currents. It is therefore not necessary to design a configuration of elements for a display or to finely adjust the current to be applied.
As described above, according to the present exemplary embodiment, since a portion of the organic layer 120 (organic layer 120a) located in the first light emitting region 140a is heated, the peak intensity ratio of a light emission output spectrum in the first light emitting region 140a of the light emitting unit 140 is different from the peak intensity ratio of a light emission output spectrum in the second light emitting region 140b. Therefore, it is possible to make the light emission color in the first light emitting region 140a different from the light emission color in the second light emitting region 140b. In addition, since the amount of irradiated light on the organic layer 120a is small, the organic pigment of the organic layer 120a is not deteriorated. Therefore, it is possible to suppress a reduction in the life span of the light emitting device 10.
In addition, the irradiation of the organic layer 120a with light is performed after the light emitting unit 140 is sealed using the sealing portion 160, thus allowing the step of irradiating the organic layer 120a with light to be performed outside a vacuum device. Consequently, an increase in manufacturing costs of the light emitting device 10 can be suppressed.
First, the insulating layer 150 includes plural openings 152 in a region overlapping the first electrode 110. The organic layer 120 is located in each of the plural openings 152. In other words, the light emitting unit 140 is divided into plural light emitting regions. In the example illustrated in the drawing, the first light emitting regions 140a and the second light emitting regions 140b are alternately disposed. However, the arrangement of the first light emitting regions 140a and the second light emitting regions 140b is not limited to the example illustrated in the drawing.
Further, the second electrode 130 is individually provided for each of the first light emitting regions 140a and the second light emitting regions 140b. However, the plural second electrodes 130 may be connected to a common second terminal 132. In addition, the plural second electrodes 130 maybe connected to the respective second terminals 132. In this manner, it is possible to individually control currents to be applied to the plural second electrodes 130, that is, currents to be applied to the first light emitting regions 140a and currents to be applied to the second light emitting regions 140b. It is possible to adjust the light emission colors of the light emitting device 10 as a whole by individually controlling the currents to be applied. Such control is performed by a control unit 200 to be described later. In the present modification example, the second electrode 130 is formed using a mask, for example. Meanwhile, the second electrode 130 may be formed into a predetermined pattern by etching.
In addition, the insulating layer 150 located between the first light emitting regions 140a and the second light emitting regions 140b serves as a light limiting layer 154. The light limiting layer 154 is provided in order to prevent light incident on the second light emitting region 140b from being incident on the first light emitting region 140a due to reflection, scattering, or the like when the organic layer 120 of the second light emitting region 140b is irradiated with light. The light transmittance of the light limiting layer 154 in a near-infrared region or an infrared region may be, for example, equal to or less than 50%, and a difference in the transmittance of infrared rays between the light limiting layer 154 and another portion may be equal to or greater than 10%. In order to achieve the above, the light limiting layer 154 is formed by adding a low transmittance material having a light (for example, light in a near-infrared region or an infrared region) transmittance lower than that of a resin material constituting the light limiting layer 154. In this case, a low transmittance material is also added to a portion of the insulating layer 150 other than the light limiting layer 154. The low transmittance material is, for example, carbon, but may be another material.
Meanwhile, the light limiting layer 154 of the insulating layer 150 may be formed by a separate step from that of another portion of the insulating layer 150, whereby the low transmittance material can be added only to the light limiting layer 154.
In addition, the light limiting layer 154 may include particles or a layer that reflects light (for example, metal particles such as Al or a metal layer). In a case where the metal layer is provided, the resin material of the light limiting layer 154 covers the metal layer.
Also in the present modification example, it is possible to make the light emission color in the first light emitting region 140a different from the light emission color in the second light emitting region 140b, similarly to the exemplary embodiment. In addition, a reduction in the life span of the light emitting device 10 can be suppressed.
In addition, the light limiting layer 154 is formed between the first light emitting region 140a and the second light emitting region 140b. The light limiting layer 154 prevents light incident on the second light emitting region 140b from being incident on the first light emitting region 140a due to reflection, scattering, or the like when the organic layer 120 of the second light emitting region 140b is irradiated with light. Therefore, it is possible to clearly define a boundary between the first light emitting region 140a and the second light emitting region 140b and to prevent the width of the first light emitting region 140a from becoming larger than a design value.
The light emitting device 10 according to the present modification example has the same configuration as that of the light emitting device 10 according to Modification Example 1 except that the first electrode 110 is divided into plural parts. Specifically, a set of a first electrode 110 and a first terminal 112 is provided for each first light emitting region 140a, and a set of a first electrode 110 and a first terminal 112 is provided for each second light emitting region 140b. Therefore, the first electrode 110 of the first light emitting region 140a is separated from the first electrode 110 of the second light emitting region 140b. The light limiting layer 154 is located between adjacent first electrodes 110.
In the present example, methods of applying heat to the organic layer 120a of the first light emitting region 140a include applying a current only to the first light emitting region 140a to cause heat generation in the organic layer 120, in addition to irradiating the organic layer 120a with light. In the case of causing heat generation in the organic layer 120, it is not necessary to provide a light limiting layer 154, and instead, an insulating layer 150 not including a low transmittance material is provided between adjacent first and second light emitting region 140a and 140b.
Meanwhile, in the present modification example, the second electrodes 130 may be connected to each other as illustrated in
Also in the present modification example, it is possible to make the light emission color in the first light emitting region 140a different from the light emission color in the second light emitting region 140b, similarly to Modification Example 1. Further, a reduction in the life span of the light emitting device 10 can be suppressed. Still further, it is possible to clearly define a boundary between the first light emitting region 140a and the second light emitting region 140b and to prevent the width of the first light emitting region 140a from becoming larger than a design value.
In addition, the first electrode 110 is individually provided for each of the plural first light emitting regions 140a and the plural second light emitting regions 140b. Therefore, as illustrated in
Also in the present modification example, it is possible to make the light emission color in the first light emitting region 140a different from the light emission color in the second light emitting region 140b. In addition, it is possible to suppress a reduction in the life span of the light emitting device 10. Further, it is possible to clearly define the boundary between the first light emitting region 140a and the second light emitting region 140b and to prevent the width of the first light emitting region 140a from becoming larger than a design value.
As described above, the exemplary embodiment and the examples have been described with reference to the accompanying drawings. However, these are just are illustrative of the invention, and various configurations other than the above-described configurations can also be adopted.
Filing Document | Filing Date | Country | Kind |
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PCT/JP2015/058966 | 3/24/2015 | WO | 00 |