1. Field of the Invention
The invention relates to structuring materials to obtain better light emitting diodes and lasers through high extraction efficiency or better isolation of active layers from metal electrodes, and specifically, to light emitting devices with embedded void-gap structures through bonding of structured materials on active devices.
2. Description of the Related Art
This invention relates to improving and fabricating semiconductor light emitting diodes (LEDs) and lasers relying on buried grating mirrors and photonic crystals (PhCs), and more particularly, to new structures beyond those obtained by growth on substrates patterned by these gratings and photonic crystals, as described in the cross-referenced patents, publications and applications set forth above. These cross-referenced patents, publications and applications describe ways to incorporate a low index layer in the grown structures, wherein the low index layer helps confine light in the vertical direction.
For PhC LEDs, as described in U.S. Patent Publication No. 2006/0192217, which is incorporated by reference herein, the purpose of that layer is to diminish or forbid optical modes that are not efficiently extracted by a surface PhC.
In typical PhC LEDs, buffer and active layers are typically made in GaN, the low index confining layer in AlGaN, and the quantum wells (QWs) in GaInN, as described in U.S. Patent Publication No. 2006/0192217, which is incorporated by reference herein. This structure differs from typical double heterostructure LEDs where two low index layers are used on both sides of the active region to confine carriers in the active layers. In U.S. Patent Publication No. 2006/0192217, which is incorporated by reference herein, only one low index layer is used on the side of the active layer opposite to the PhC, which will favor emission into guided optical modes which interact strongly with the PhC. Putting another low index layer, as used in double heterostructure LEDs, between the active layer and PhC would confine the modes around the active layer and prevent them from overlapping with the PhC, and therefore preventing the PhC from efficiently diffracting guided modes into air.
The confining layer can also be obtained through a lateral epitaxial overgrowth (LEO) of nitride-based material over a patterned growth masking layer, as described in U.S. Patent Publication No. 2008/0087909, which is incorporated by reference herein. In that case, the composite layer comprising the mask material and the overgrown material constitutes the low index confining layer and it can also act as the light extracting PhC by proper design.
In in-plane emitting lasers, the laser mode usually interacts quite strongly with the metal top electrode, leading to propagation losses which increase threshold current and diminish power efficiency. The doped semiconductor contact layers can also induce propagation losses, in particular, the p-type doped contact layer (see e.g. S. Uchida et al., IEEE Journal Of Selected Topics In Quantum Electronics, Vol. 9, No. 5, September/October 2003, p. 1252, which is incorporated by reference herein).
Usually, optical confining layers are used to confine the laser mode away from the metal top electrode and the contact layers. Such confining layers have an index of refraction lower than that of the active layer, and therefore somewhat confine the optical wave into the active region, thus leading to a stronger interaction of the laser mode with the active material, for instance decreasing the lasing threshold current, and to a weaker interaction between that mode and the contact layers and electrode.
However, there are compromises. Thick, high index (meaning high bandgap) confining layers (made of AlGaN material, for example), which would have good confinement properties, also have poor current conduction properties, leading to increased device resistance and operating voltage. Moreover, the growth of high Al content materials is also hard to achieve without introducing large dislocation densities or even cracks due to the lattice mismatch between AlGaN and the other materials of the structure. Due to these limitations, currently available indices and thicknesses of the confining layers in lasers have insufficient confinement properties and they lead to an overflow of the laser mode and its interaction with the metal electrode.
Better confining layers for lasers can be obtained through the LEO of nitride-based material over a patterned growth masking layer, as described in U.S. Patent Publication Nos. 2006/0194359 and 2007/0125995, which are incorporated by reference herein. Very good confinement properties can be obtained due to the high index difference between the mask material (it can even be air), while conserving good electrical conduction properties due to the perforations of the mask material containing good conductive semiconductor material.
While embedded dielectric structures can be obtained by various growth techniques such as LEO (see, e.g., U.S. Patent Publication Nos. 2006/0194359, 2007/0125995, 2006/0192217, and 2008/0087909, which are incorporated by reference herein), various structures of interest can be obtained by direct bonding of a passive structured material on the active LED structure, as described in more detail in this application.
To overcome the limitations in the prior art described above, and to overcome other limitations that will become apparent upon reading and understanding the present specification, the present invention discloses various bonding techniques and structures to obtain structured layers within semiconductors devices. The patterns of the structured layers can be random or periodic and arranged in one, two or three dimensions.
A simple method of fabricating optoelectronic devices with embedded void-gap structures through bonding on structured semiconductor materials is provided. Specifically, embedded void-gaps are fabricated on a semiconductor structure by bonding of a patterned material slab on a flat semiconductor surface or by bonding of a flat slab over a patterned structure. The void-gaps can be filled with air, conductive or dielectric materials and can be advantageous for optoelectronic device applications for several reasons such as better isolation of optical modes from dissipative regions in lasers or light extraction properties for LEDs.
This is an easy fabrication method, because it involves just materials bonding. This is a planar and manufacturable method for embedded void-gaps structures. The void-gaps can be filled with air or other materials. Multiple bondings can prove useful for given applications or implementations.
Referring now to the drawings in which like reference numbers represent corresponding parts throughout:
In the following description of the preferred embodiment, reference is made to the accompanying drawings which form a part hereof, and in which is shown by way of illustration a specific embodiment in which the invention may be practiced. It is to be understood that other embodiments may be utilized and structural changes may be made without departing from the scope of the present invention.
Overview
The present invention describes a method for creating embedded void-gap structures, such as void-gap PhCs, for optoelectronic devices, wherein the void-gap structures are embedded in one or more layers that are then bonded to a top or bottom surface of the active device structure. “Void-gap” as used herein is intended to mean voids, gaps, holes, perforations, etc., created in one or more of layers of the structure.
The void-gaps may be filled with air, gas, conductive material, dielectric material, or other substances. Moreover, the void-gaps may comprise polygonal, cylindrical or spherical shaped features, randomly shaped features, randomly distributed features, periodically or quasi-periodically distributed shaped features. In addition, the void-gaps may be arranged in one-dimensional (1D), two-dimensional (2D) or three-dimensional (3D) patterns. The void-gaps also may be contiguously connected, formed of connecting holes, formed of connecting pillars, or formed of both connecting holes and connecting pillars. These and further aspects of the present invention are described in more detail below.
The operation of the concept developed in this invention relies on refractive index differences. Creating patterns of void-gaps in the material layers to be bonded and leaving the resulting void-gaps empty or filling them with a substance having a refractive index different from the material layers or the active device structure achieves this property.
The method disclosed by the present invention does not make use of the growth of embedded material on some specific regions, such as dielectrics, to form the void-gaps. Instead, in the present invention, the void-gaps are naturally formed during bonding, either because the bonded layers have been patterned before being bonded to the active device structure, or because bonding is done over a patterned surface of the active device structure.
While the present invention discloses a simple method, the structure growth resulting therefrom retains a planar aspect that makes it manufacturable at low cost.
Technical Description
Void-gaps, which typically have a lower index of refraction as compared to surrounding material, are a desired feature in devices such as LEDs or lasers. They mainly serve two purposes. The first purpose is to provide optical confinement due to the lower average index of refraction of the layer that contains the void-gaps.
The AlGaN optical confining layers 310, 312 are low index layers that are in high demand for lasers for optical confinement purposes. Specifically, for an in-plane laser, such as shown in
The available materials to achieve such low index set limits to the reachable optical confinement properties. In a GaN-based system, the incorporation of Al is severely limited by metallurgical constraints (strain induces dislocation or crack formation at high Al fractions or large thicknesses), thus leading to small index contrast and insufficient optical confinement. Therefore, the high index contrast brought by void-gaps is most welcome.
The second purpose of low index layers relies on their capability, when they are patterned, to extract light efficiently in LEDs, either through diffraction effects (PhC extraction) or through ray randomization by multiple reflections in geometrical optics conditions. In lasers, such patterns can be used for making cavity mirrors, wavelength selection, such as by distributed feedback (DFB) lasers, or vertical emission, such as surface emitting in-plane lasers with second-order distributed Bragg reflector (DBR) mirrors.
Methods to obtain optoelectronic devices with embedded air or dielectric voids are described in the cross-referenced patents, publications and application set forth above, namely, U.S. Patent Publication Nos. 2006/0194359, 2007/0125995, and 2006/0192217, which are incorporated by reference herein. However, these methods rely on the semiconductor epitaxial overgrowth over a patterned layer (made of dielectric or semiconductor); hence, the fabrication of such devices is a more complex process, including an initial growth step followed by a fabrication step where the pattern is made and, subsequently, another growth step.
The present invention proposes an improved method of fabrication of embedded patterned structures by bonding a patterned material to an active device. The method according to the present invention decouples the device from the patterned layer fabrications, which allows a much more flexible design of the patterned structure, in terms of the materials filling the pattern holes, the period, shape, size and depth of the pattern holes. Additionally, separating (and possibly parallelizing) the process steps for the active device and the patterned material makes the overall process more robust and less sensitive to problems in separate steps.
Several configurations can be considered for the patterned layer bonded to the active device structure. The pattern of the bonded layer can be periodic, quasi-periodic or random. A periodic lattice would form an embedded photonic crystal structure, which could be useful due to its photonic band gap properties, as well its diffraction properties. Quasi-periodic patterns, such as Penrose lattices, could potentially increase the directions in which diffraction occurs, which would make light emission of the optoelectronic device more omnidirectional.
A completely random lattice could also be created. In this case, the light scattering due to the embedded pattern randomizes the guided light, thereby increasing the light extraction efficiency of the optoelectronic device.
The period of the pattern in the layer 614 can also vary depending on the application considered. In the case of diffraction applications (electromagnetic wave diffraction approach), the period should be on the order of half of the wavelength of the light generated by the optoelectronic device. For GaN-based LEDs, this would correspond to periods of a few hundreds of nanometers.
Several configurations containing the embedded periodic structures through bonding of a patterned material can be created.
In addition, multiple patterned layers can be bonded on top of each other forming special configurations of embedded void-gap structures. For example, the bonding process can be repeated two or more times, on each side of the active device, after substrate removal and the thinning of the structure, resulting in a thin layer with embedded void-gap structures on both top and bottom surfaces.
Some of the generated light by the optoelectronic device will also be guided in the patterned layer. The amount of guided light in the patterned layer can be controlled by changing the layer thickness or the depth of the objects in the pattern (i.e., the void-gaps or holes). The frequency of the guided light in the patterned layer can be changed, thereby resulting in white light emitting optoelectronic devices (or any other color composition). Light conversion active elements, such as dyes, quantum dots, phosphors, or GaInAlAsP-based material can be introduced in the patterned layer. These elements convert part of the light into other frequencies that combined to the original light emitted by the device can be used to produce secondary, ternary or any other color combination, including white. Guided light in the bonded layer interacts very well with the frequency converters (in the same layer) and the control over the amount of guided light (or the thickness of the patterned layer) provides control of the color mixing in the optoelectronic device (as illustrated in
Electrical and optical properties of the optoelectronic device can be both optimized by using a bonded patterned layer of conductive material. The patterned material can be a transparent conductor or semiconductor, such as ITO or ZnO. A thin conductive layer can be placed in between the active device structure and the bonded patterned layer for better current injection. A doped semiconductor layer could also be used as the bonded patterned layer, wherein an electrical contact is placed on the doped semiconductor layer.
A higher optical diffraction is obtained when the holes on the patterned layer are gaps or voids filled with air, due to the high refractive index contrast. Other materials can be used to fill the holes of the patterned layer to enhance some properties of this layer. For instance, the holes of the patterned layer can be partially or fully filled with dielectric, transparent conductive, metallic, semiconducting or frequency-converting materials.
The bonding of the patterned material can be made to a semiconductor whose active region (light emitting layer) is flat or patterned. A patterned active region means that the patterned holes are at least reaching the light-emitting layer. The patterned holes could extend partially or entirely through the active region.
Process Steps
Block 1500 represents the step of fabricating an active device structure.
Block 1502 represents step of fabricating at least one layer.
Note that steps 1500 and 1502 can be performed in parallel.
Block 1504 represents the step of bonding the active device structure to the layer, wherein one or more embedded void-gaps are formed at an interface where a surface of the active device structure is bonded to a surface of the layer. In one embodiment, the surface of the layer is patterned and the surface of the active device structure is flat. In another embodiment, the surface of the active device structure is patterned and the surface of the layer is flat.
Note that a substrate may be removed from the active device structure to expose the surface of the active device structure. Moreover, one or more layers of the active device structure may be thinned after the substrate is removed and before the surface of the layer is bonded to the surface of the active device structure.
The void-gaps may be filled with air, a gas, a conductive material, or a dielectric material. In addition, the void-gaps may have a lower average index of refraction than the layer. Also, the layer may have a lower average index of refraction than the active device structure.
The void-gaps may comprise polygonal, cylindrical or spherical shaped features. In addition, the void-gaps may comprise: randomly shaped features, randomly distributed features, or periodically or quasi-periodically distributed shaped features. Also, the void-gaps may be arranged in a one dimensional pattern, two dimensional pattern, or three dimensional pattern. Moreover, the void-gaps may be: contiguously connected, formed of connecting holes, formed of connecting pillars, or formed of both connecting holes and connecting pillars.
Block 1504 may also represent additional fabrication steps. For example, one or more additional layers may be stacked or piled on the layer bonded to the active device structure. In addition, one or more electrically conductive layers are placed on a bottom or top surface of the active device structure. Moreover, one or more electrically conductive layers may be placed between the layer and the active device structure.
Block 1506 represents a device fabricated using steps 1500, 1502 and 1504. Specifically, this Block represents an optoelectronic device with embedded void-gap structures, comprising an active device structure bonded to at least one layer, wherein one or more embedded void-gaps are formed at an interface where a surface of the active device structure is bonded to a surface of the layer. For example, the optoelectronic device may be a light emitting diode (LED) or a laser.
The following references are incorporated by reference herein:
This concludes the description of the preferred embodiment of the present invention. The foregoing description of one or more embodiments of the invention has been presented for the purposes of illustration and description. It is not intended to be exhaustive or to limit the invention to the precise form disclosed. Many modifications and variations are possible in light of the above teaching. It is intended that the scope of the invention be limited not by this detailed description, but rather by the claims appended hereto.
This application claims the benefit under 35 U.S.C. Section 119(e) of co-pending and commonly assigned U.S. Provisional Application Ser. No. 61/238,003, filed on Aug. 28, 2009, by James S. Speck, Claude C. A. Weisbuch, and Elison de Nazareth Matioli, entitled “LIGHT EMITTING DEVICES WITH EMBEDDED AIR GAP STRUCTURES THROUGH BINDING OF STRUCTURED MATERIALS ON ACTIVE DEVICES,” attorney's docket number 30794.310-US-P1 (2009-494-1), which application is incorporated by reference herein. This application is related to the following patents, publications and applications: U.S. Pat. No. 7,723,745, issued May 25, 2010, published Jun. 5, 2008, as U.S. Patent Publication 2008/0128737, filed Feb. 13, 2008, as U.S. Utility application Ser. No. 12/030,697, by Claude C. A. Weisbuch, Aurelien J. F. David, James S. Speck, and Steven P. DenBaars, entitled “HORIZONTAL EMITTING, VERTICLE EMITTING, BEAM SHAPED, DISTRIBUTED FEEDBACK (DFB) LASERS BY GROWTH OVER A PATTERNED SUBSTRATE,” attorneys' docket number 30794.121-US-C1 (2005-144-2), which is a continuation of U.S. Pat. No. 7,345,298, issued Mar. 18, 2008, published Aug. 31, 2006, as U.S. Patent Publication 2006/0194359, filed Feb. 28, 2005, as U.S. Utility application Ser. No. 11/067,957, by Claude C. A. Weisbuch, Aurelien J. F. David, James S. Speck and Steven P. DenBaars, entitled “HORIZONTAL EMITTING, VERTICAL EMITTING, BEAM SHAPED, DISTRIBUTED FEEDBACK (DFB) LASERS BY GROWTH OVER A PATTERNED SUBSTRATE,” attorneys docket number 2005-144-1 (30794.121-US-01); U.S. Utility application Ser. No. 12/822,888, filed on Jun. 24, 2010, by Claude C. A. Weisbuch and Shuji Nakamura, entitled “HORIZONTAL EMITTING, VERTICAL EMITTING, BEAM SHAPED, DISTRIBUTED FEEDBACK (DFB) LASERS FABRICATED BY GROWTH OVER PATTERNED SUBSTRATE WITH MULTIPLE OVERGROWTH,” attorneys docket number 2005-721-3 (30794.143-US-C1), which is a continuation of U.S. Pat. No. 7,768,024, issued Aug. 3, 2010, published Jun. 7, 2007, as U.S. Patent Publication No. 2007/0125995, filed Dec. 4, 2006, as U.S. Utility application Ser. No. 11/633,148, by Claude C. A. Weisbuch and Shuji Nakamura, entitled “IMPROVED HORIZONTAL EMITTING, VERTICAL EMITTING, BEAM SHAPED, DISTRIBUTED FEEDBACK (DFB) LASERS FABRICATED BY GROWTH OVER A PATTERNED SUBSTRATE WITH MULTIPLE OVERGROWTH,” attorneys docket number 2005-721-2 (30794.143-US-U1), which claims the benefit under 35 U.S.C Section 119(e) of U.S. Provisional Application Ser. No. 60/741,935, filed on Dec. 2, 2005, by Claude C. A. Weisbuch and Shuji Nakamura, entitled “IMPROVED HORIZONTAL EMITTING, VERTICAL EMITTING, BEAM SHAPED, DISTRIBUTED FEEDBACK (DFB) LASERS FABRICATED BY GROWTH OVER A PATTERNED SUBSTRATE WITH MULTIPLE OVERGROWTH,” attorneys' docket number 30794.143-US-P1 (2005-721); U.S. Utility application Ser. No. 12/834,453, filed on Jul. 12, 2010, by Aurelien J. F. David, Claude C. A. Weisbuch and Steven P. DenBaars, entitled “HIGH EFFICIENCY LIGHT EMITTING DIODE (LED) WITH OPTIMIZED PHOTONIC CRYSTAL EXTRACTOR,” attorneys docket number 2005-198-3 (30794.126-US-C1), which is a continuation of U.S. Patent Publication No. 2009/0305446, published on Dec. 10, 2009, filed on Aug. 13, 2009, as U.S. Utility application Ser. No. 12/541,061, by Aurelien J. F. David, Claude C. A. Weisbuch and Steven P. DenBaars, entitled “HIGH EFFICIENCY LIGHT EMITTING DIODE (LED) WITH OPTIMIZED PHOTONIC CRYSTAL EXTRACTOR,” attorneys docket number 2005-198-2 (30794.126-US-D1), which is a divisional of U.S. Pat. No. 7,582,910, issued Sep. 1, 2009, published Aug. 31, 2006, as U.S. Patent Publication No. 2006/0192217, filed Feb. 28, 2005, as U.S. Utility application Ser. No. 11/067,956, by Aurelien J. F. David, Claude C. A. Weisbuch and Steven P. DenBaars, entitled “HIGH EFFICIENCY LIGHT EMITTING DIODE (LED) WITH OPTIMIZED PHOTONIC CRYSTAL EXTRACTOR,” attorneys docket number 2005-198-1 (30794.126-US-01); U.S. Utility application Ser. No. 12/793,862, filed on Jun. 4, 2010, by Claude C. A. Weisbuch, Aurelien J. F. David, James S. Speck and Steven P. DenBaars, entitled “SINGLE OR MULTI-COLOR HIGH EFFICIENCY LIGHT EMITTING DIODE (LED) BY GROWTH OVER A PATTERNED SUBSTRATE,” attorneys docket number 2005-145-3 (30794.122-US-C2), which is a continuation of U.S. Pat. No. 7,755,096, issued Jul. 13, 2010, published Apr. 17, 2008, as U.S. Patent Publication No. 2008/0087909, filed Oct. 24, 2007, as U.S. Utility application Ser. No. 11/923,414, by Claude C. A. Weisbuch, Aurelien J. F. David, James S. Speck and Steven P. DenBaars, entitled “SINGLE OR MULTI-COLOR HIGH EFFICIENCY LIGHT EMITTING DIODE (LED) BY GROWTH OVER A PATTERNED SUBSTRATE,” attorneys docket number 2005-145-2 (30794.122-US-C1), which is a continuation of U.S. Pat. No. 7,291,864, issued Nov. 6, 2007, published Sep. 14, 2006, as U.S. Patent Publication 2006/0202226, filed Feb. 28, 2005, as U.S. Utility application Ser. No. 11/067,910, by Claude C. A. Weisbuch, Aurelien J. F. David, James S. Speck and Steven P. DenBaars, entitled “SINGLE OR MULTI-COLOR HIGH EFFICIENCY LIGHT EMITTING DIODE (LED) BY GROWTH OVER A PATTERNED SUBSTRATE,” attorneys docket number 2005-145-1 (30794.122-US-01); and U.S. Provisional Application Ser. No. 61/367,239, filed on Jul. 23, 2010, by Elison de Nazareth Matioli, Claude C. A. Weisbuch, James S. Speck and Evelyn L. Hu, entitled “OPTOELECTRONIC DEVICES WITH EMBEDDED VOID STRUTURES,” attorneys docket number 2009-493-1 (30794.385-US-P1); all of which are incorporated by reference herein.
Number | Date | Country | |
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61367239 | Jul 2010 | US |