Claims
- 1. A liquid developer useful for developing a latent image having been electrophotographically formed on a printing plate precursor into a toner image during manufacture of a printing plate, said printing plate precursor comprising an electrically conductive substrate having a hydrophilic surface and a layer containing an organic photoconductive compound on said hydrophilic surface, said toner image being fixed, and a non-image area of said layer other than said toner image area being removed by etching with an alkaline etching solution to provide said printing plate, said liquid developer comprising at least resin grains dispersed in a non-aqueous solvent having a volume specific resistivity of at least 10.sup.9 .OMEGA.cm, wherein said resin grains are obtained by polymerizing 10 to 70 mol % of (a) at least one monomer selected from the group consisting of benzyl methacrylate, benzyl acrylate, styrene and a substituted styrene monomer soluble in the non-aqueous solvent, and 30 to 90 mol % of (b) at least one monomer having an alkyl group of up to 3 carbon atoms and selected from the group consisting of acrylic acid esters and methacrylic acid esters soluble in the non-aqueous solvent but which become insoluble therein upon being polymerized, in the presence of a dispersion stabilizing resin which is dissolved or dispersed in a colloidal form in the non-aqueous solvent and which comprises a graft copolymer composed of (1) at least one macromonomer (M) having a weight average molecular weight of from 1.times.10.sup.3 to 1.times.10.sup.5 and having a polymerizable double bond group represented by the general formula (II) below bonded at a terminal of the main chain of a polymer composed of at least one polymer component represented by the general formula (Ia) or (Ib) described below, and (2) at least one monomer represented by the general formula (III) below; ##STR34## wherein X.sub.0 represents at least one linking group selected from the group consisting of --COO--, --OCO--, --(CH.sub.2).sub.k --OCO--, --(CH.sub.2).sub.k --COO--, --O--, --CONHCOO--, --CONHCO--, --SO.sub.2 ----CO--, ##STR35## wherein Z.sub.1 represents a hydrogen atom or a hydrocarbon group, and k represents an integer of 1 to 3); a.sub.1 and a.sub.2, which may be the same or different, each represents a hydrogen atom, a halogen atom, a cyano group, a hydrocarbon group, --COO--Z.sub.2 or --COO--Z.sub.2 bonded via a hydrocarbon group (wherein Z.sub.2 represents a hydrogen atom or a hydrocarbon group which may be substituted); and Q.sub.0 represents an aliphatic group having from 1 to 22 carbon atoms; ##STR36## wherein Q represents --CN or a substituted or unsubstituted phenyl group wherein the substituent is a halogen atom, an alkoxy group or --COOZ.sub.3 (wherein Z.sub.3 represents an alkyl group, an aralkyl group or an aryl group); and a.sub.1 and a.sub.2 have the same meanings as defined for a.sub.1 and a.sub.2 in the general formula (Ia) above; ##STR37## wherein V represents --COO--, --OCO--, --(CH.sub.2).sub.k --OCO--, --(CH.sub.2).sub.k --COO--, --O--, --CONHCOO--, --CONHCO--, --SO.sub.2 ----CO--, ##STR38## or a phenylene group (wherein Z.sub.1 represents a hydrogen atom or a hydrocarbon group, and k represents an integer of 1 to 3); b.sub.1 and b.sub.2, which may be the same or different, have the same meanings as a.sub.1 and a.sub.2 defined in the general formula (Ia) or (Ib); and ##STR39## wherein X.sub.1 has the same meaning as V defined in the general formula (II), Q.sub.1 represents a hydrogen atom, an aliphatic group having from 1 to 22 carbon atoms, or an aromatic group having from 6 to 12 carbon atoms, and c.sub.1 and c.sub.2, which may be the same or different, have the same meanings as a.sub.1 and a.sub.2 defined in the general formula (Ia) or (Ib), provided that in the macromonomer represented by the general formula (Ia) and the monomer component represented by the general formula (III), at least one of Q.sub.0 and Q.sub.1 represents an aliphatic group having from 4 to 22 carbon atoms, and that, when the graft copolymer is composed of a macromonomer represented by the general formula (Ib) and the monomer component represented by the general formula (III), Q.sub.1 represents an aliphatic group having from 4 to 22 carbon atoms.
- 2. The liquid developer as in claim 1, wherein the liquid developer further contains a coloring agent.
- 3. The liquid developer as in claim 1, wherein said (a) at least one monomer is selected from the group consisting of benzyl methacrylate and benzyl acrylate.
- 4. The liquid developer as in claim 3, wherein said alkyl group of up to 3 carbon atoms, contained in said (b) at least one monomer, is selected from the group consisting of methyl and ethyl.
- 5. The liquid developer as in claim 1, wherein said substituted styrene monomer is selected from the group consisting of methylstyrene, ethylstyrene, t-butylstyrene, ethoxymethylstyrene, n-oxtyloxymethylstyrene, n-propylcarbonyloxyethylstyrene, benzoyloxymethylstyrene, monochlorostyrene, dichlorostyrene, monobromostyrene, and dibromostyrene.
- 6. The liquid developer as in claim 1, wherein said alkyl group of up to 3 carbon atoms, contained in said (b) at least one monomer, is selected from the group consisting of methyl and ethyl.
Priority Claims (2)
Number |
Date |
Country |
Kind |
4-038404 |
Jan 1992 |
JPX |
|
4-075695 |
Feb 1992 |
JPX |
|
Parent Case Info
This is a Continuation of application Ser. No. 08/010,164 filed Jan. 28, 1993, now abandoned.
US Referenced Citations (4)
Number |
Name |
Date |
Kind |
5085966 |
Suzuki et al. |
Feb 1992 |
|
5106716 |
Kato et al. |
Apr 1992 |
|
5112718 |
Kato et al. |
May 1992 |
|
5344694 |
Horie et al. |
Sep 1994 |
|
Continuations (1)
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Number |
Date |
Country |
Parent |
10164 |
Jan 1993 |
|