Claims
- 1. A liquid developer useful for developing a latent image having been electrophotographically formed on a printing plate precursor into a toner image during manufacture of a printing plate, said printing plate precursor comprising an electrically conductive substrate having a hydrophilic surface and a layer containing an organic photoconductive compound on said hydrophilic surface, said toner image being fixed, and a non-image area of said layer other than said toner image area being removed by etching with an alkaline etching solution to provide said printing plate, said liquid developer comprising at least resin grains dispersed in a non-aqueous solvent having a volume specific resistivity of at least 10.sup.9 .OMEGA.cm, wherein said resin grains are obtained by polymerizing (a) at least one monomer selected from the group consisting of methyl methacrylate and ethyl methacrylate soluble in the non-aqueous solvent, and (b) at least one monomer selected from the group consisting of alkyl acrylate having an alkyl group of up to 4 carbon atoms and butyl methacrylate, said alkyl acrylate and butyl methacrylate being soluble in the non-aqueous solvent but which become insoluble therein upon being polymerized, in the presence of a dispersion stabilizing resin which is dissolved or dispersed in a colloidal form in the non-aqueous solvent and which comprises a graft copolymer composed of (1) at least one macromonomer (M) having a weight average molecular weight of from 1.times.10.sup.3 to 1.times.10.sup.5 and having a polymerizable double bond group represented by the general formula (II) below bonded at a terminal of the main chain of a polymer composed of at least one of a styrene polymer component and a polymer component represented by the general formula (I) described below, and (2) at least one monomer represented by the general formula (III) below; ##STR25## wherein X.sub.0 represents at least one linking group selected from the group consisting of --COO--, --OCO--, --CH.sub.2).sub.k --OCO--, --(CH.sub.2).sub.k --COO--, --O--, --CONHCOO--, --CONHCO--, --SO.sub.2 -- CO--, ##STR26## (wherein Z.sub.1 represents a hydrogen atom or a hydrocarbon group, and k represents an integer of 1 to 3); a.sub.1 and a.sub.2, which may be the came or different, each represents a hydrogen atom, a halogen atom, a cyano group, a hydrocarbon group, --COO--Z.sub.2 or --COO--Z.sub.2 bonded via a hydrocarbon group (wherein Z.sub.2 represents a hydrogen atom or a hydrocarbon group which may be substituted); and Q.sub.0 represents an aliphatic group having from 1 to 3 carbon atoms; ##STR27## wherein V represents --COO--, --OCO--, --(CH.sub.2).sub.k --OCO--, --(CH.sub.2).sub.k --COO--, --O--, --CONHCOO--, --CONHCO--, --SO.sub.2 --, --CO--, ##STR28## or a phenylene group (wherein Z.sub.1 represents a hydrogen atom or a hydrocarbon group, and k represents an integer of 1 to 3); b.sub.1 and b.sub.2, which may be the same or different, have the same meanings as a.sub.1 and a.sub.2 defined in the general formula (I); and ##STR29## wherein X.sub.1 has the same meaning as X.sub.0 defined in the general formula (I), Q.sub.1 represents an aliphatic group having from 4 to 22 carbon atoms, and c.sub.1 and c.sub.2, which may be the same or different, have the same meanings as a.sub.1 and a.sub.2 defined in the general formula (I).
- 2. The liquid developer as in claim 1, wherein said resin grains are resin grains obtained by polymerizing (a) at least one monomer selected from the group consisting of methyl methacrylate and ethyl methacrylate, (b) at least one monomer selected from the group consisting of alkyl acrylate having an alkyl group of up to 4 carbon atoms and butyl methacrylate, and (c) at least one vinyl monomer having a basic nitrogen atom or an amido group, in the presence of said dispersion stabilizing resin.
- 3. The liquid developer as in claim 2, wherein said vinyl monomers having a basic nitrogen atom or an amido group are vinyl monomers selected from the group consisting of aminoalkyl-substituted (meth)acrylates represented by the following formula (IV), quaternary salts of aminoalkyl-substituted (meth)acrylates represented by the following formula (V), N-vinylimidazole, N-vinyl-2-methylimidazole, 1-vinylpyrrole, N-.beta.-acryloxyethylindole, 2-vinylquinoline, 4-vinylpyridine, 5-vinyl-4-methylthiazole, 3-methyl-5-isopropenylpyrazole, N-vinyl-2-pyrrolidone, N-vinylpiperidone, N-vinyloxazolidone, dimethylaminostyrene, dialkylaminomethylstyrenes, quaternary salts of dialkylaminomethylstyrenes and (meth)acrylamide; ##STR30## wherein d.sub.1 and d.sub.2, which may be the same or different, each represents a hydrogen atom or a methyl group, Z.sub.3 and Z.sub.4, which may be the same or different, each has the same meaning as z.sub.1, and p represents an integer of 1 to 3; ##STR31## wherein d.sub.1, d.sub.2, p, Z.sub.3 and Z.sub.4 are as defined in the general formula (IV) above, Z.sub.5 represents an alkyl group having 1 to 18 carbon atoms or an aralkyl group having 7 to 24 carbon atoms, and X represents a halogen atom, an acetate, BF.sub.4, a sulfate, p-toluenesulfonate or an alkylsulfonate.
- 4. The liquid developer as in claim 2, wherein said monomer component (c) comprises not more than 30 mol % based on the total amount of monomers (a), (b) and (c).
- 5. The liquid developer as claimed in claim 2, wherein said (b) at least one monomer selected from the group consisting of alkyl acrylate having an alkyl group of up to 4 carbon atoms and butyl methacrylate is present in an amount of 0.1 to 9 mol per mol of said (a) at least one monomer selected from methyl methacrylate or ethyl methacrylate.
- 6. The liquid developer for electrostatic photography as in claim 1, wherein the liquid developer further contains a coloring agent.
Priority Claims (1)
Number |
Date |
Country |
Kind |
4-020786 |
Jan 1992 |
JPX |
|
Parent Case Info
This is a Continuation of application Ser. No. 08/002,029, abandoned, filed Jan. 8, 1993.
US Referenced Citations (3)
Number |
Name |
Date |
Kind |
5108864 |
Kato et al. |
Apr 1992 |
|
5112718 |
Kato et al. |
May 1992 |
|
5344694 |
Horie et al. |
Sep 1994 |
|
Non-Patent Literature Citations (1)
Entry |
Grant, Roger, and Claire Grant, editors, Grant and Hackh's Chemical Dictionary, fifth ed. New York: McGraw-Hill, Inc., 1987, p. 331. |
Continuations (1)
|
Number |
Date |
Country |
Parent |
2029 |
Jan 1993 |
|